Patent Application
20230097469
The present invention relates to an improved feeding system for melters, more particularly melters of clinker or vitreous or glassy material, including but not limited to submerged combustion melters. The invention further relates to melters equipped with a feeding system and to a process for feeding material under melt level.
Melters, more particularly melters of vitreous material and clinker, are generally operated at high temperatures with a more or less agitated or stirred melt bath. Raw material may be loaded from above the melt but it may in certain instances also be desirable to charge material into the melt below melt level.
Underlevel feeding devices require particular attention as they are subject to high stresses and wear due to the corrosive effect of the melt and melt pressure and temperatures, in addition to the wear due to the feeding of the material they are intended to feed.
Submerged combustion melters are characterized by the fact that they have one or more burner nozzles arranged below the surface of the melt, in a lance, in the melter walls and/or melter bottom, preferably in the melter bottom, such that the burner flame and/or combustion products pass through the melt and transfer energy directly to the melt. The submerged combustion melter provides efficient mixing in the melt and homogenizes the melt in terms of temperature profile and composition leading to a high quality product. It also favors the absorption of raw material into the melt and improves heat transfer to fresh raw material. This reduces required residence time in the melter prior to withdrawal for downstream treatment. Overall the energy efficiency of submerged combustion melters is significantly improved compared to conventional shaft melters or rotary kilns.
The present invention now seeks to provide a suitable material feeding system for a melter comprising:
The skilled person will easily determine the maximum distance at which the internal feeder may operate, taking all relevant parameters, including but not limited to pressure in the melter, feed material temperature, barrel temperature, mechanical stress due to friction in the feeding barrel, mechanical limit of the unit activating the internal feeder, into consideration.
The feeding barrel wall or walls of the material feeding system may comprise double steel walls separated by circulating cooling liquid, preferably water. The internal feeder may be a feeding piston, preferably hydraulically activated. In the alternative, it may be a feeding screw. In view of the high thermic stress, the screw may be water cooled, such as by water circulation through the screw axis.
The material feeding system may be used with a method and/or melter disclosed in any of WO 2015/014917, WO 2015/014918, WO 2015/014919, WO 2015/014920 or WO 2015/014921, each of which is hereby incorporated by reference.
A material charge chute may advantageously be connected to the material input opening. Such a charge chute has the advantage of providing a material buffer upstream of the feeding barrel. Preferably, in the case of a feeding piston, a screw feeder may be arranged between the charge chute and the feeder input opening. The screw feeder charges the material under pressure into the feeding barrel and ensures tight closure or sealing of the material input opening. The screw feeder may advantageously be arranged inclined to the longitudinal barrel axis. Preferably, the screw feeder is arranged perpendicularly to the longitudinal barrel axis, even more preferably vertically.
The melter may be any type of melter, but the invention feeder is particularly advantageous in the case of submerged combustion melters. It is known that submerged combustion melters generate a highly agitated or highly stirred melt. Loading raw material at the top of the melt may lead to entrainment of fines by the fumes of the melter into the chimney. It may thus be desirable to charge raw materials under the melt level of submerged combustion melters. Underlevel raw material charging thus reduces the risk of fines escaping through the chimney. A further advantage consists in the provision of improved incorporation of the raw material in the melt with concomitant improved energy transfer from the melt to the fresh raw material.
The term “feeding barrel” is used in this context to define a longitudinal substantially tubular element which shows a substantially circular or polygonal cross-section. In the case of a polygonal cross-section, the feeding barrel diameter is understood to mean the smallest diagonal.
The terms “below the level of the melt” are understood to mean in this context “at a height from the melter bottom at which liquid melt is continuously present during an operational melting period”; that is between two halts at which the melter is not operational to melt vitreous material. This definition excludes the height from the melter bottom at which liquid melt appears sporadically as a consequence of the agitation of the melt.
According to further aspect, the present invention also provides a process for feeding material into a melter, below the level of the melt contained in the said melter, comprising pushing the said material substantially horizontally through a feeding barrel into the melt by way of an internal feeder, thereby maintaining the internal feeder at a minimum at a distance from the internal melter surface of two (2) to ten (10) times the diameter of the feeding barrel, preferably three (3) to eight (8) times the diameter of the feeding barrel, more preferably three (3) to six (6) times the diameter of the feeding barrel or three (3) to five (5) times the diameter of the feeding barrel.
The internal feeder advantageously is a feeding piston moved from a position uncovering the material input opening to allow for admission of material under pressure, to a position closing the material input opening, thereby pushing the material into the melt.
According to yet another aspect, the invention provides a melter, preferably a submerged combustion melter, comprising a material feeding system as described above.
Preferably, the submerged combustion is performed such that a substantially toroidal melt flow pattern is generated in the melt, having a substantially vertical central axis of revolution, comprising major centrally inwardly convergent flows at the melt surface; the melt moves downwardly at proximity of the vertical central axis of revolution and is recirculated in an ascending movement back to the melt surface, thus defining a substantially toroidal flow pattern. The generation of such a toroidal flow pattern ensures highly efficient mixing of the melt and absorption of raw material into the melt, and homogenizes the melt in terms of temperature profile and composition, thus leading to high quality melt product. At the vertical axis of revolution of said toroidal flow pattern, the flow vectors have a downward component reflecting significant downward movement of the melt in proximity of said axis. Towards the melter bottom, the flow vectors change orientation showing outward and then upward components.
A toroidal melt flow pattern may be obtained using submerged combustion burners arranged at the melter bottom in a substantially annular burner zone imparting a substantially vertically upward directed speed component to the combustion gases. Advantageously, the burners are arranged with a distance between adjacent burners of about 250-1250 mm, advantageously 500-900 mm, preferably about 600-800, even more preferably about 650-750 mm. It is preferred that adjacent flames do not merge.
Each burner axis and/or a speed vector of the melt moving upwards over or adjacent to the submerged burners may be slightly inclined from the vertical, for example by an angle which is ≥1°, ≥2°, ≥3° or ≥5 ° and/or which is ≤30°, preferably ≤15°, more preferably ≤10°, notably towards the center of the melter. Such an arrangement may improve the flow and directs melt flow away from the outlet opening and/or towards a center of the melter thus favoring a toroidal flow.
Each central burner axis may be inclined by a swirl angle with respect to a vertical plane passing through a central vertical axis of melter and the burner center. The swirl angle may be 1≥°, ≥2°, ≥3°, ≥5° and/or ≤30°, ≤20°, ≤15° or ≤10°. Preferably, the swirl angle of each burner is about the same. Arrangement of each burner axis at a swirl angle imparts a slightly tangential speed component to the upward blowing flames, thus imparting a swirling movement to the melt, in addition to the toroidal flow pattern.
The burner zone is defined as a substantially annular zone. Burner arrangements, for example on an elliptical or ovoid line within the relevant zone are possible, but the burners are preferably arranged on a substantially circular burner line.
Preferably, the flow pattern comprises an inwardly convergent flow at the melt surface followed by a downwardly oriented flow in proximity of the central axis of revolution of the toroid. Said central axis of revolution advantageously corresponds to the vertical axis of symmetry of the melter. By axis of symmetry is meant the central axis of symmetry and, if the melter shows a transversal cross-section which does not have any single defined axis of symmetry, then the axis of symmetry of the circle in which the melter section is inscribed. The downwardly oriented flow is followed by an outwardly oriented flow at the bottom of the melter and a substantially annular upward flow at proximity of the burners, reflecting recirculation of melt toward the burner zone and in an ascending movement back to the melt surface, thus defining a substantially toroidal flow pattern.
The inwardly convergent flow vectors at the melt surface advantageously show a speed comprised between 0.1-3 m/s. The downward oriented speed vectors at proximity of the vertical central axis of revolution are preferably of significant magnitude reflecting a relatively high speed of material flowing downwardly. The downward speed vectors may be between 0.1-3 m/s. The melt and/or the raw materials within the melter, at least at one portion of the melter and notably at the melt surface (particularly inwardly convergent flow vectors at the melt surface) and/or at or proximate a vertical central axis of revolution, may reach a speed which is ≥1 m/s, ≥0.2 m/s, ≥0.3 m/s or ≥0.5 m/s and/or which is ≤2.5 m/s, ≤2 m/s, ≤1.8 m/s or ≤1.5 m/s.
The preferred toroidal flow pattern ensures highly efficient mixing and homogenizes the melt in terms of temperature profile and composition. It also favors the absorption of raw material into the melt and improves heat transfer to fresh raw material. This reduces required residence time in the melter prior to withdrawal, while avoiding or at least reducing the risk of raw material short cutting the melt circulation.
In one preferred embodiment, the burners are arranged at a distance of about 250-750 mm from the side wall of said melting chamber; this favors the preferred flow described above and avoids flame attraction to the melting chamber side walls. Too small a distance between burners and side wall may damage or unnecessarily stress the side wall. While a certain melt flow between burner and wall may not be detrimental and may even be desirable, too large a distance will tend to generate undesirable melt flows and may create dead zones which mix less with the melt in the center of the melter and lead to reduced homogeneity of the melt.
The distance between submerged burners is advantageously chosen such as to provide the desired toroidal flow pattern within the melt but also to avoid that adjacent flames merge. While this phenomenon depends on many parameters such as temperature and viscosity of the melt, pressure and other characteristics of the burners, it has been found advantageous to select a burner circle diameter comprised between about 1200 and 2000 mm. Depending on burner type, operating pressure and other parameters, too large a diameter will lead to diverging flames; too narrow a diameter will lead to merging flames.
Preferably at least 6 burners are provided, for example arranged on a burner circle line, more preferably 6 to 10 burners, even more preferably 6 to 8 burners, depending on the melter dimensions, burner dimensions, operating pressure and other design parameters.
Each burner or each of a plurality of a group of burners, for example opposed burners, may be individually controlled. Burners close to a raw material discharge may be controlled at different, preferably higher gas speeds and/or pressures than adjacent burners, thus allowing for improved heat transfer to the fresh raw material that is being loaded into the melter. Higher gas speeds may be required only temporarily, that is, in the case of batch wise loading of fresh raw material, just during the time period required for absorption of the relevant load into the melt contained in the melter.
The melting chamber is preferably substantially cylindrical in cross section; nevertheless, it may have an elliptical cross section or polygonal cross section showing more than 4 sides, preferably more than 5 sides.
The composition of a glass melt produced in a melter of the invention may typically comprise:
An embodiment of a feeding system suitable for use in accordance with the present invention is described below, with reference to the appended drawings of which:
With reference to
According to a preferred embodiment, the feeding barrel wall or walls 5 are cooled and comprise double steel walls 5′,5″ separated by circulating cooling liquid, preferably water.
As shown in
In an alternative, the internal feeder 20 could also be a feeding screw, the melt oriented end of which extending at a distance to the internal melter surface 19 of no less than 2 to 10 times the feeding barrel diameter.
As shown in
As more specifically shown at
The temperature within the melt may be between 1100° C. and 1600° C., or 1200° C. and 1500° C., or 1200° C. and 1450° C., preferably 1250° C. and 1400° C., depending on the composition of the melt, desired viscosity and other parameters. Preferably, the melter wall 9 is a double steel wall cooled by a cooling liquid, preferably water. Cooling water connections provided at the external melter wall allow a flow sufficient to withdraw energy from the inside wall such that melt can solidify on the internal wall 19 and the cooling liquid, here water, does not boil.
The submerged burners may comprise concentric tube burners operated at gas flow rates of 100 to 200 m/s, preferably 110 to 160 m/s and generate combustion of fuel gas and oxygen containing gas within the melt. The combustion and combustion gases generate agitation within the melt before they escape into the upper chamber and then through the chimney. These hot gases may be used to preheat the raw material and/or the fuel gas and/or oxidant gas (eg oxygen, industrial oxygen have an oxygen content 95% by weight or oxygen enriched air) used in the burners. The fumes are preferably filtered prior to release to the environment, optionally using dilution with ambient air to reduce their temperature prior to filtering.
The obtained melt is of high quality. The above described production process is less energy demanding then known processes, because of the choice of submerged combustion melters that allow for improved energy transfer to the melt, shorter residence times and thus less heat loss, and because the high stirring leads to a more homogenous melt at reduced melt viscosity, which in turn may allow for operation at reduced temperatures. Furthermore, submerged combustion may advantageously be performed in water-cooled melters which are more easy and less costly to maintain and repair and which further allow for recycling of the energy withdrawn from the cooling fluid.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1501312.1 | Jan 2015 | GB | national |
This application is a continuation of U.S. application Ser. No. 15/546,329, filed Jul. 26, 2017, which is a U.S. national counterpart application of International Application Serial No. PCT/EP2016/051735, filed Jan. 27, 2016, under 35 U.S.C. § 371, which claims priority to GB Application Serial No. 1501312.1, filed Jan. 27, 2015, the disclosures of which are hereby incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15546329 | Jul 2017 | US |
| Child | 17952612 | US |
