This invention relates to membrane modules for water treatment.
Immersed membranes are used for extracting clean water (permeate) from a tank of contaminated water or mixed liquor. The membranes are often provided in the form of assembled modules, each module having many hollow fiber membranes extending between two headers for collecting permeate that passes through pores of the membrane walls into the lumina of the membranes. Streams of air bubbles may be provided in the tank to rub against the membranes for cleaning purposes. The air bubbles also help to create circulation patterns in the tank.
Although these features improve filtration along a central portion of the length of the fibers, a dead zone remains at either end of the fibers where sufficient cleaning of the fibers and circulation of the water does not occur, thereby causing the fibers at either end to become plugged or fouled by contaminants, and resulting in a corresponding decrease in the filtration capacity of the system. Presence of the dead zone is primarily caused by the headers themselves, which interfere with the flow of air bubbles and water circulation at either end of the fibers, and which inhibit movement of the fibers since the ends of the fibers are fixed to the headers.
Efforts have been made to overcome these drawbacks associated with two-header membrane modules by using single-header modules. However, single header modules involve various issues such as supporting the fibres, aerating the fibres and building groups of modules. There is a need for improvements relating to these and other issues.
It is an object of the invention to improve on the prior art. It is another object of the present invention to provide a membrane module and elements of a membrane system and a process for a liquid with a membrane module or system. These and other objects are provided by the features described in the claims. The following summary provides an introduction to the invention which may reside in a combination or sub-combination of features provided in this summary or in other parts of this document.
According to one aspect of the present invention, a filtration apparatus for filtering liquid has a filtration cell which may have generally vertical front and rear panels spaced apart to define a cell length, and generally vertical side panels extending between the front and rear panels and spaced apart to define a cell width. A plurality of header segments are provided in the cell, each header segment having a permeate channel. Spaces between the header segments allow water to flow upwards into the cell. A plurality of hollow fiber membranes are associated with each header segment and extend generally upwards from the header segments, each membrane having a lumen in flow communication with the permeate channel of the associated header segment. Each membrane has a lower end secured to the associated header segment and a loose upper end.
According to a second aspect of the present invention, a filtration apparatus for filtering liquid has an enclosure with a divider structure in the enclosure and dividing the enclosure into a plurality of filtration cells. Each cell has generally vertical front and rear panels spaced apart to define a cell length, and generally vertical side panels extending between the front and rear panels and spaced apart to define a cell width. A plurality of header segments are provided in each cell, each header segment having a permeate channel. A plurality of hollow fiber membranes are associated with each header segment and extend generally upwards from the associated header segment. Each membrane has a lumen in flow communication with the permeate channel of the associated header segment, a lower end secured to the associated header, and a loose upper end.
According to a third aspect of the present invention, a filtration apparatus for filtering liquid has a plurality of cartridges, each cartridge defining a filtration cell and having generally vertical front and rear panels spaced apart to define a cell length, and generally vertical side panels extending between the front and rear panels and spaced apart to define a cell width. A plurality of header segments are provided in each cell, each header segment having a permeate channel and a first and second releasable resealable connection fitting at either end of the permeate channel. A plurality of hollow fiber membranes are associated with each header segment and extend generally upwards from the associated header segment. Each membrane has a lumen in flow communication with the permeate channel of the associated header, a lower end secured to the associated header segment, and a loose upper end. A frame is provided for holding the cartridges in at least one row of aligned cartridges wherein the first and second connection fittings of adjacent aligned cartridges cooperate to connect the corresponding permeate channels of the header segments of the aligned cartridges in operative fluid communication.
In any one filtration apparatus according to the first, second, or third aspects of the present invention, the header segments can be elongate and aligned generally parallel to the cell length. The header segments can be arranged in spaced apart parallel relationship across the cell width, the spacing between the header segments providing a passage for a liquid to be filtered to flow upwards into the cell. The cell length can be about 10 to 40 percent longer than the cell width. The cell length can be about 20 to 30 cm, and the cell width can be about 15 to 25 cm. The apparatus can have from 2 to 4 header segments, and in particular can have three header segments. The panels can include one or more structures of the group of structures consisting of generally solid plastic plates, apertures, and horizontal rungs. The apparatus can have about 700 to 1200 membranes associated with each header segment. The membranes can be potted to the header segment in about 8 to 12 rows, each row having about 70 to 130 membranes.
The filtration apparatus according to the third aspect of the invention can include releasable attachments between at least one of the header segments of each cartridge and the frame, the releasable attachments allowing the frame to releasably hold the cartridges by the at least one header segment. The releasable attachments can include keys extending from the headers and slots in the frame to receive the keys in sliding fit.
According to a fourth aspect of the present invention, a method for filtering liquid includes providing a filtration apparatus having (i) a filtration cell with generally vertical front and rear panels spaced apart to define a cell length, and generally vertical side panels extending between the front and rear panels and spaced apart to define a cell width, (ii) a plurality of header segments the cell, each header segment having a permeate channel, and (iii) a plurality of hollow fiber membranes associated with each header segment and extending generally upwards from the associated header segment, each membrane having a lumen in flow communication with the permeate channel of the associated header segment and a lower end secured to the associated header segment and a loose upper end. The method further includes immersing the apparatus in a liquid at ambient pressure, applying suction to the lumens to withdraw permeate, and aerating the liquid such that fluid currents rise upwards along the outer surfaces of the hollow fiber membranes, urging the membranes to a generally vertical position when aerated.
According to a fifth aspect of the present invention, a method for filtering liquid includes providing a filtration apparatus having (i) an enclosure, (ii) a divider structure in the enclosure and dividing the enclosure into a plurality of filtration cells, each cell having generally vertical front and rear panels spaced apart to define a cell length, and generally vertical side panels extending between the front and rear panels and spaced apart to define a cell width, (iii) a plurality of header segments in each cell, each header segment having a permeate channel, and (iv) a plurality of hollow fiber membranes associated with each header segment and extending generally upwards from the associated header segment, each membrane having a lumen in flow communication with the permeate channel of the associated header segment and a lower end secured to the associated header and a loose upper end. The method for filtering a liquid further includes immersing the apparatus in a liquid at ambient pressure, applying suction to the lumens to withdraw permeate, and aerating the liquid such that fluid currents rise upwards along the outer surfaces of the hollow fiber membranes, urging the membranes to a generally vertical position when aerated.
According to a sixth aspect of the present invention, a method for filtering liquid includes providing a filtration apparatus having (i) a plurality of cartridges, each cartridge defining a filtration cell and having generally vertical front and rear panels spaced apart to define a cell length, and generally vertical side panels extending between the front and rear panels and spaced apart to define a cell width, (ii) a plurality of header segments in each cell, each header segment having a permeate channel and a first and second releasable resealable connection fitting at either end of the permeate channel, (iii) a plurality of hollow fiber membranes associated with each header segment and extending generally upwards from the associated header segment, each membrane having a lumen in flow communication with the permeate channel of the associated header and a lower end secured to the associated header segment and a loose upper end, and (iv) a frame for holding the cartridges in at least one row of aligned cartridges wherein the first and second connection fittings of adjacent aligned cartridges cooperate to connect the corresponding permeate channels of the header segments of the aligned cartridges in operative fluid communication. The method for filtering a liquid further includes immersing the apparatus in a liquid at ambient pressure, applying suction to the lumens to withdraw permeate, and aerating the liquid such that fluid currents rise upwards along the outer surfaces of the hollow fiber membranes, urging the membranes to a generally vertical position when aerated.
In any one of the filtration methods according to the fourth, fifth, and sixth aspects of the present invention, the aeration can be intermittent, having a supply of air that is cycled on and off in cycles of between about 15 and 120 seconds in duration. Furthermore, the cycle time for which the air supply for aeration is off can have a duration limited to not more than 30 seconds.
According to a seventh aspect of the present invention, a filtration apparatus for filtering liquid includes a filtration cell having a perimeter defined by generally vertical panels. A plurality of header segments are provided in the cell, the header segments oriented in spaced relationship providing a passage between the header segments for a liquid to be filtered to flow upwards into the cell, and each header segment having a permeate channel. A plurality of hollow fiber membranes are associated with each header segment and extend generally upwards from the associated header segment, each membrane having a lumen in flow communication with the permeate channel of the associated header segment and a lower end secured to the associated header segment and a loose upper end.
For a better understanding of the present invention and to show more clearly how it may be carried into effect, reference will now be made by way of example, to the accompanying drawings that show embodiments of the present invention, and in which:
a and 10b are perspective views showing optional embodiments of the structure of
a is a side view of the apparatus of
b is an exploded view showing a portion of the apparatus of
a side view of a optional embodiment of the apparatus of
b is a side view of another optional embodiment of the apparatus of
A filtration apparatus according to the present invention is shown generally at 100 in
The apparatus 100 has a housing 106 with vertical side panels that define a filtration cell 104. More specifically, the housing 106 has opposed vertical end panels 105, and vertical side panels 107 extending between the end panels 105 (
The apparatus 100 is further provided with a plurality of header segments 108, each having a plurality of hollow fiber membranes 110 extending therefrom. The header segments have permeate collection channels 109 for collecting permeate from the membranes 110, as discussed further hereinafter.
Various constructions and dimensions of membranes 110 and headers 108 are possible for obtaining satisfactory results with the apparatus 100 of the present invention. It has been determined that particularly satisfactory filtration results may be obtained by using generally narrow, elongate header segments to form rectangular skeins of vertically oriented membranes 110. Such a configuration permits close-packing of a plurality of skeins to efficiently use the available space in the tank for filtration, while allowing adequate circulation of fluid around the interior fibers. Narrow spacing can be provided between adjacent skeins to permit efficient aeration and circulation around the membranes 110 of the apparatus 100.
Accordingly, in the embodiment illustrated, three header segments 108a, 108b and 108c, are provided in the cell 104. The header segments 108 are elongate and are oriented generally horizontally and parallel to each other, extending between the opposed end panels 105 of the housing 106. In particular, the header segments 108 in the illustrated embodiment have dimensions of about 6 cm high by 4 cm wide by 25 cm long. The header segments 108 are spaced apart by about 1.3 cm.
The header segments 108 need not be separate header elements, but may be distinct portions of a single header. In the embodiment illustrated in
A plurality of hollow fiber membranes 110 extends upwardly from each of the header segments 108. The membranes 110 are flexible, tube-like elements, each having a hollow interior channel or lumen 111 and a water permeable wall structure. Each membrane 110 is secured to its associated header segment 108 such that the lumen 111 is in flow communication with the permeate collecting channel 109 of the header segment 108.
In the illustrated embodiment, the membranes 110 are of a braid reinforced construction, having a tubular braided inner layer that is coated with a coagulated film-forming polymer. Further details of such membranes can be found in U.S. Pat. No. 5,472,607 (Zenon Environmental Inc.), which is incorporated herein in its entirety by this reference to it. The membranes 110 can have an outer diameter of about 2.3 mm, and a length of about 160 cm. This configuration provides membranes 110 that are flexible and nearly buoyant so that they stand generally upright in the liquid 103 when aerated, and can sway back and forth under the influence of currents in the liquid 103, despite having some stiffness to inhibit their collapse when not aerated.
The membranes 110 have lower ends 112 that are secured to the header segments 108, and upper ends 114 that are loose. As mentioned previously, the header segments 108 each have a hollow channel 109 for collecting permeate. The lower ends 112 of the membranes 110 are secured to the header segments 108 such that the lumens 111 of the membranes 110 are in flow communication with the permeate collecting channels of the header segments 108. In the illustrated embodiment, the lower ends 112 of the membranes 110 are potted in the header segments 108 using known potting techniques. The membranes 110 are potted in rows of about 9 by 100 membranes 110 along the upper surface of the header segments 108.
The upper ends 114 of the membranes 110 are loose, meaning that they are not secured in a fixed position relative to the housing 106 of the cell 104 or to a fixed upper header, but are able to sway back and forth. The loose upper ends 114 may be free from connection to any other member of the apparatus 100, or the ends 114 may be tethered to each other and to the housing 106. In this embodiment, the upper ends 114 of the membranes are free, having no connection to other membranes or to any fixed structural number. Other configurations of the loose upper ends 114 of the membranes 110 will be described hereinafter.
The upper ends 114 of each individual membrane 110 may be plugged, sealed, or otherwise obstructed to prevent the flow of raw liquid 103 into the lumens of the membranes 110. In the illustrated embodiment, the upper ends 114 of the membranes 110 are sealed by subjecting the ends 114 to ultrasonic waves and squeezing or pinching the ends 114 closed. In particular, as best seen in
The filtration apparatus 100 can advantageously be provided with aerators 118 for providing streams of air bubbles directed upwards along the outer surfaces of the hollow fiber membranes 110. In the embodiment illustrated, two aerators 118 are provided, positioned below and between the pairs of headers 108a, 108b, and 108b, 108c. Other locations and numbers of aerators may also be used. Further, the header 108 may be adapted to form part of an inverted air box aerator used in conjunction with continuous cyclic air as described in U.S. application Ser. No. 10/171,997 which is incorporated herein in its entirety by this reference to it. The air bubbles can be provided continuously or cyclically as described in U.S. Pat. No. 6,550,747 which is incorporated herein in its entirety by this reference to it.
During normal operation of the filtration apparatus 100, a pressure gradient (or trans-membrane pressure) is applied across the walls of the hollow fiber membranes, such that the liquid 103 side of the membranes is at a higher pressure than the permeate side of the membranes. For example, the trans-membrane pressure may be provided by suction on the lumens. As a result, permeate is drawn from the liquid 103 through the porous layers of the hollow fiber membranes 110 and into the lumens 111. The permeate is then collected by the header segments 108. The streams of air bubbles from the aerators 118 help to keep the membranes from becoming plugged or fouled by scrubbing the outer surfaces of the membranes, and by inducing flow currents in the liquid 103 that circulate liquid 103 with more concentrated contaminant levels away from the fibers 110, being replaced by liquid 103 with less concentrated contaminant levels. Aeration may be provided continuously or intermittently.
The panels 105, 107 of the housing 106 of each cell 104 corral or fence-in a group 124 of membranes 110. The group 124 of membranes 110 is supported in a generally upright configuration by the housing 106. The vertical panels 105, 107 of the housing 106 of the cell 104 provide support surfaces that limit the lateral distance that the membranes 110 can curl under the force of gravity when no liquid 103 surrounds the membranes 110 or when they are not aerated.
An example of the support provided to the groups 124 of hollow fiber membranes 110 by the housing 106 is shown in
It has been determined that the spacing apart of the panels 105, 107 of the housing 106 requires careful consideration to achieve optimal results with the apparatus 100 of the present invention. If the panels 105, 107 are spaced too far apart, entanglement of the membranes 110 may not be sufficiently alleviated. Also, too great a space between the partitions 121 may reduce the effectiveness of aeration supplied in the apparatus 100, since streams of air bubbles emitted from the aerators may more easily disperse horizontally, particularly since the upper ends 114 of the membranes 110 are loose. If the panels 105, 107 are spaced too closely together, the swaying motion of the membranes 110 may be reduced, and it may be more difficult to circulate highly contaminated water away from the membranes 110. This may increase the susceptibility of the membranes 110 to becoming fouled with contamination. The total number of cells and panels is also increased unnecessarily.
It has been determined that satisfactory results can be obtained for the apparatus 100 having headers 108 and membranes 110 as described above, using rectangular shaped cells 104 having a width W and a length L. The width W can be sized to accommodate, for example, from 2 to 4 header segments 108, spaced apart as described above. The length L can be sized to be greater than the selected width. The width W, being perpendicular to the axis of the header segments 108, is advantageously smaller than the length L because the membranes tend to collapse into the space between the header segments 108.
In the embodiment illustrated, each cell 104 of the apparatus 100 has a length L of about 25 cm and a width W of about 20 cm. Each cell 104 holds three header segments 108 and a group 124 of membranes 110 having about 2700 hollow fiber membranes 110.
It will be appreciated that the shape of the apparatus 100 facilitates the efficient packing of multiple filtration elements 100 in a side-by-side arrangement to obtain a desired filtration capacity. Furthermore, the filtration capacity provided by the apparatus 100, either singly or in multiple elements, provides an efficient use of space, i.e. high filtration capacity for a given sized tank 102.
Referring now to
Three headers 208a, 208b and 208c are provided in the illustrated embodiment of the apparatus 200. The headers 208 are arranged in parallel in the enclosure 206, each extending between the opposed end plates 205. A plurality of hollow fiber membranes 110 extend from each header 208.
The apparatus 200 is fitted with a divider structure 220 having generally vertical partitions 221 that divide the interior space of the housing 206 into a plurality of fenced cells 104. The partitions 221 of the divider structure 220 can by themselves or in combination with the plates 205, 207 provide the panels 105, 107 of the housing 106 for each cell 104. In other words, the partitions 221 of the divider structure 220 can comprise unique longitudinal panels 226 and transverse panels 228 to define the housing 106 of the cells 104, or alternatively, the partitions 221 can comprise some unique panels 226, 228 and some panels 205, 207 of the enclosure 206 to define the cells 104. Some unique panels 226, 228 of the divider structure 220 can be provided in flush contact with panels 205, 207 of the enclosure 206 to provide additional support and reinforcement for the enclosure 206 and cells 104.
As best seen in
As best seen in
Referring now to
The longitudinal panels 226 can be in the form of plastic panels, having upper and lower edges 230 and 232, respectively. The transverse panels 228 can also be plastic panels, having upper and lower edges 234 and 236 respectively. The upper edges 230 and 234 of the panels 226, 228 need not lie in the same horizontal plane, but can be offset. In particular, the upper edges 234 of the transverse panels 228 can be lower than the upper edge 230 of the longitudinal panels 226 so that circulation of liquid 103 between adjacent cells 104 is facilitated. Similarly, the lower edges 232 and 236 can be offset from each other to enhance flow characteristics between adjacent cells 104.
Referring now to
By having the lower edges 232 of the longitudinal divider panels 226 extend below the aerators 218, the stream of air bubbles emitted from the aerators 218 remains confined in a narrower vertical channel which can improve the cleaning action of the membranes 110 by the air bubbles as they travel upwards in the tank 102.
The apparatus 200 may have the aerators 218 situated below the headers 208 (as shown in
The apparatus 200 can be advantageously supported above the bottom of the tank 102 to further facilitate circulation of liquid 103 through the housing 206 of the apparatus 200, or to provide a sludge collection and removal zone in the tank 102 below the apparatus 200.
Referring now to
Another alternate embodiment of a filtration apparatus according to the present invention is shown generally at 300 in
Details of the cartridge 302 are best seen in
Each cartridge 302 further has a plurality of header segments 308 in the housing interior. In the embodiment illustrated, each header segment 308 is elongate and has a permeate channel 309 extending through the header segment 308 (
A plurality of hollow fiber membranes 110 are associated with each header segment 308 in each cartridge 302. The membranes 110 extend generally vertically when aerated between the panels 321 of the housing 306. The membranes 110 of each plurality of membranes are in flow communication with the permeate channel 309 of the corresponding associated header segment 308. The membranes 110 have lower ends 112 secured to the header segments 308, and loose upper ends 114, as described previously. In the embodiment illustrated, the upper ends 114 of the membranes 110 are free.
Referring again to
The base 360 of the frame 304 is sized to hold the cartridges 302 in at least one row 370 of aligned cartridges 302. In the illustrated embodiment, three rows 370 of three aligned cartridges 302 are held in the frame 304. In each row 370 of aligned cartridges 302, the header segments 308 of each cartridge 302 extend parallel to the row 370, and the first and second connection fittings 340, 342 of adjacent cartridges 302 cooperate to connect the corresponding permeate channels 309 of the header segments 308 of the aligned cartridges 202 in operative fluid communication.
More specifically, as best seen in
To pack or assemble multiple cartridges 302 into filtration units of larger capacity, rows 370 of cartridges 302 can easily be formed by aligning the connection fittings 340, 342 of two adjacent cartridges 302 and moving the cartridges together in the direction of arrow 372 in
Referring again to
Referring now to
In the embodiment illustrated, the releasable attachments 380 comprise T-shaped slots 382 provided in the transverse members 364, 366, 367 of the base 360 of the frame 304. Matching keys 384 are provided on the underside of the header segments 308 so that the cartridges 302 can be assembled to the frame 304 by sliding the keys 384 into the slots. As well, releasable clamps (not shown) can be provided to clamp the cartridges 302 to the frame 304.
As best seen in
As best seen in
Other configurations of a filtration apparatus according to the present invention are also possible. For example, a filtration apparatus can have fiber membranes that are 80 cm long, contained in a cell that has L and W dimensions of 25 cm and 8 cm, respectively. Such a configuration was found to provide satisfactory (no tangling, no sludge fouling) operation in mixed liquor having solids concentration levels of 5-35 g/L, using 5-10 scfm cyclic aeration. Furthermore, the aerators can be optimized for use with membranes having free upper ends. In particular, fewer holes can be provided along the sides of aerators adjacent the panels defining each cell, and more holes can be provided for aeration between header segments in a cell.
As well, the loose upper ends 114 of the membranes 110 need not be free from all attachment to fall within the scope of the present invention. For example, with reference now to
Securing the upper ends 114 of the membranes 110 to the support strips 402 can advantageously eliminate the need for sealing the upper ends 114, as described earlier. For example, the support strip can take the form of plastic or resin into which the upper ends 114 are plotted, thereby simultaneously closing off the upper ends 114 of the membranes 110. Furthermore, the support strips 402 can be tethered to the housing 106 of the cell 104 by tethering strings 410 (
Another embodiment providing loose upper ends 114 of the membranes 110 in the apparatus 100 is shown in
While preferred embodiments of the invention have been described herein in detail, it is to be understood that this description is by way of example only, and is not intended to be limiting. The full scope of the invention is to be determined by reference to the appended claims.
This is an application claiming the benefit under 35 USC 119(e) of U.S. Provisional Application Nos. 60/512,700, which was filed on Oct. 21, 2003, and U.S. Application No. [Attorney Ref: 4320-610], entitled “Membrane Bioreactor Having Single Header Membrane Module”, which was filed on Oct. 1, 2004. The entire contents of U.S. Ser. No. 60/512,700 and U.S. Ser. No. [Attorney Ref: 4320-610] are hereby incorporated herein in their entirety by this reference to them.
Number | Date | Country | |
---|---|---|---|
60512700 | Oct 2003 | US | |
60614980 | Oct 2004 | US |