Patent Application
20220023801
The present invention is related to a spiral wound reverse osmosis membrane element. Particularly, the present invention provides a spiral wound reverse osmosis membrane element having prolonged life and a more convenient process for making such a spiral wound reverse osmosis membrane element.
Pressure driven spiral wound reverse osmosis membrane elements are widely used in household water purifiers to provide purified water for consumers. The use of spiral wound reverse osmosis membranes is advantageous in that it affords very high quality of water to consumers.
Traditionally, the spiral wound reverse osmosis membrane elements are formed by winding a plurality of purification membrane groups around a central perforated treated water tube. The purification membrane group is formed by laminating a mesh-like treated water guiding member, a dual-folded reverse osmosis membrane and a mesh-like feed water guiding member inside of the dual-folded reverse osmosis membrane. A feed water flow channel is formed along the inner surfaces of the dual-folded reverse osmosis membrane and a treated water flow channel is formed between the outside surfaces of the adjacent dual-folded reverse osmosis membrane.
When such membrane element is in operation, the feed water enters the feed water flow channel from one end, either side surface or outside surface, of the spiral wound reverse osmosis membrane element. Treated water is obtained by passing the feed water through the membrane. The treated water flows along the treated water guiding member and into the central treated water tube through the water collection hole. The remaining water which as not filtered flows along the feed water guiding member and is discharged from another end of the spiral wound reverse osmosis membrane element as concentrated water. In such traditional spiral wound reverse osmosis membrane elements, the water flow channel is short and thus the velocity of the feed water is relatively slow. Therefore, the impurities would easily contaminate the membrane, resulting in shorter lifetime of the reverse osmosis membrane element.
A lot of efforts have been made to improve the lifetime of the spiral wound reverse osmosis membrane element. However, few of them may be produced in a suitable way for factory manufacture. Therefore, the present inventors have recognized that there is a need to develop a spiral wound reverse osmosis membrane element with a prolonged lifetime and easy to be made and a process for making such membrane element which is suitable for industrialization.
In a first aspect, the present invention is directed to a spiral wound reverse osmosis membrane element (1) comprising (a) a first reverse osmosis membrane set (2) spirally wound around a first central water collection tube (3); (b) a second reverse osmosis membrane set (4) spirally wound around a second central water collection tube (5); and (c) a connector (6) connecting the first central water collection tube (3) in fluid communication with the second central water collection tube (5); wherein the outer area (221) remote from the first central tube (3) of the side surface (22) of downstream end (21) of the first reverse osmosis membrane set (2), and the outer area (421) remote from the second central tube (5) of the side surface (42) of the upstream end (41) of the second reverse osmosis membrane set (4) are both sealed; and the outside area (71) of joint (7) between the two reverse osmosis membrane sets are sealed such that the flow path of concentrated water from the downstream end (21) of the first reverse osmosis membrane set (2) is in fluid communication with the upstream end (41) of the second reverse osmosis membrane set (4).
In a second aspect, the present invention is directed to a reverse osmosis module comprising (a) a pressure vessel (8); and (b) a spiral wound reverse osmosis membrane element (1) of the present invention.
In a third aspect, the present invention is directed to a process for making the membrane element of the present invention comprising the steps of:
These and other aspects of the present invention will more readily become apparent upon considering the detailed description and examples which follow.
Except in the examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of material or conditions of reaction, physical properties of materials and/or use may optionally be understood as modified by the word “about”.
It should be noted that in specifying any range of values, any particular upper value can be associated with any particular lower value.
For the avoidance of doubt, the word “comprising” is intended to mean “including” but not necessarily “consisting of” or “composed of”. In other words, the listed steps or options need not be exhaustive.
The disclosure of the invention as found herein is to be considered to cover all embodiments as found in the claims as being multiply dependent upon each other irrespective of the fact that claims may be found without multiple dependency or redundancy.
Where a feature is disclosed with respect to a particular aspect of the invention (for example a product of the invention), such disclosure is also to be considered to apply to any other aspect of the invention (for example a process of the invention) mutatis mutandis.
Preferably, the side surface of the upstream end of the first reverse osmosis membrane set, and the side surface of the downstream end of the second set of reverse membrane are sealed, preferably by means of glue. Preferably, the longitudinal length of the first reverse osmosis membrane set is larger that of the second reverse osmosis membrane. To provide an optimal lifetime of the reverse osmosis element, the ratio of longitudinal length of the first reverse osmosis membrane set to the longitudinal length of the second reverse osmosis membrane is preferably 1:3 to 5:1, more preferably 1:1 to 4:1, even more preferably 1.2:1 to 4:1 and most preferably from 1.5:1 to 3:1. Preferably, the feed water flows into the first reverse osmosis membrane set through the outside surface of the first reverse osmosis membrane set. The feed water flows through the first reverse osmosis membrane set and then to the second reverse osmosis membrane set. The outside surface refers to the curved lateral surface of the reverse osmosis membrane set.
To provide a higher velocity of the feed water, preferably at least part of the outside surface of the first reverse osmosis membrane set and at least part of the outside surface of the second reverse osmosis membrane set are not wrapped by plastic strips. Alternatively, the outside surfaces of the first and second sets of reverse osmosis membrane are preferably wrapped by perforated plastic strips. In such way, the feed water may flow into the outside surface of the first reverse osmosis membrane set and the concentrated water may flow out from the outside surface of the second reverse osmosis membrane set.
Preferably, the sealed outer areas of the side surfaces of downstream end of the first reverse osmosis membrane set and of the upstream end of the second reverse osmosis membrane set are annular. Preferably, the area of the sealed portion to that of the unsealed portion in the side surface is 1:1 to 15:1, preferably 2:1 to 8:1.
For sake of improved durability for the connected central water collection pipes, a connector is used. Preferably, the connector comprises a communication tube engaged with the two central water collection tubes, preferably by means of friction fastening. Preferably, the outer diameter of the communication tube is substantially same as the inner diameter of the central water collection tube. In such way, the communication tube may be inserted into the inner surface of the two central water collection tubes to ensure these two central water collection tubes are water-tightly connected in fluid communication with each other.
Preferably, the connector comprises an annular portion surrounding the communication tube and a plurality of ribs coupling the communication tube and the annular portion together. The concentrated water may flow through the spaces between the ribs.
Preferably, the annular portion is surrounding the longitudinal center of the communication tube. Preferably, the connector comprises 3 to 10 of ribs coupling the communication tube and the annular portion. Preferably, the thickness of the annual portion is substantially same as the thickness of the rib. Preferably, the thickness of the joint is substantially same as the thickness of the annular portion. Preferably, the radius of the annular portion is substantially same as the radius of the inner area of the side surfaces of downstream end of the first reverse osmosis membrane set and of the upstream end of the second reverse osmosis membrane set.
Preferably, the joint between the two sets of reverse osmosis membrane is wrapped and sealed by plastic strips at the outside surface. Thus, the concentrated water is capable of flowing out from the inner area of the side surface of the downstream end of the first set of reverse osmosis membrane and flowing into the second set of reverse osmosis membrane through the inner area of the side surface of the upstream end of the second set of reverse osmosis membrane.
Preferably, the pressure vessel comprises a tubular container and a cap engaged with the tubular container, preferably at the upstream end of the pressure vessel. Preferably, the cap is engaged with the tubular container by means of thread. Preferably, the pressure vessel comprises a feed water inlet at the upstream end of the pressure vessel, a treated water outlet and a concentrated water outlet at the downstream end of the pressure vessel. Preferably the feed water inlet is provided at the cap, more preferably at the middle of cap.
Preferably, the downstream end of the second central water collection tube are water tightly connected with the treated water outlet such that the treated water may be discharged from the treated water outlet. Preferably, the upstream end of the first central water collection tube are sealed.
Preferably, the reverse osmosis module comprises a brine seal between the reverse osmosis membrane element and the inner wall of the vessel to prevent the feed water flow from bypassing element, wherein the brine seal is provided around the joint between the two sets of reverse osmosis membranes.
The present invention also provides a process for making the spiral wound reverse osmosis membrane element. Preferably, the step (i) is replaced by conducting step (a) to (d):
Preferably, in step (iv) the sealing of the outer areas is conducted by means of glue. Preferably, in step (vi), the sealing of outer area of the joint between the two sets of reverse osmosis membrane is conducted by wrapping a plastic strip at the outside surface of the joint.
Preferably, a step (e) of drying the glue is conducted before step (v), preferably by means of naturally drying.
In some embodiments, a step of wrapping the spiral wound reverse osmosis membrane by plastic strips at the outside surface is preferably conducted before step (iii) and a step of removing the plastic strips wrapped at the outside surfaces of the first and second reverse osmosis membrane sets. In other embodiments, a step of wrapping the spiral wound reverse osmosis membrane by perforated plastic strips at the outside surface is preferably conducted.
The following example is provided in
As illustrated in
Each reverse osmosis membrane set comprises at least one folded reverse osmosis membrane. A feed water flow channel is formed between the inner surfaces of the folded reverse osmosis membrane. A mesh-like feed water flow guiding member is placed into the feed water flow channel. A treated water flow channel is formed between outside surfaces of the adjacent folded reverse membranes. A mesh-like treat water flow guiding member is placed into the treated water flow channel. The treated water flow channel is glued at the two sides along the direction of spirally winding and one side remote from the central treated tube such that the treated water flow channel has one opening toward the central water collection tube. The central water collection tube has a plurality of perforated holes to gather the treated water.
As illustrated in
As illustrated
As illustrated in
When the reverse osmosis module operates, the feed water is pumped inside of the pressure vessel 8 through the feed water inlet 83 and pushed inside of the first reverse osmosis membrane set 2 through the outside surface 24 of the first reverse osmosis membrane set 2. Thus, the feed water is filtered by the first reverse osmosis membrane set 2 to generate treated water and concentrated water. The treated water flows inside of the first central water collection tube 3. The concentrated water flows out from the inner annular area 222 of the side surface 22 of the downstream end 21 of the first reverse osmosis membrane set 2 and into the inner annular area 422 of the side surface 42 of the upstream end 41 of the second reverse osmosis membrane set 4. The concentrated water is filtered again by the second reverse osmosis membrane set 4 and flows out from the outside surface 44 of the second reverse osmosis membrane set 4. The treated water is discharged through the treated water outlet 84 and the concentrated are discharged through the concentrated water outlet 85.
The water flow path is significantly increased and provides a lot of benefits including increase of the water flow velocity and lifetime improvement of the spiral wound reverse osmosis membrane element.
Then, a reverse osmosis membrane was folded dually and a mesh-like rectangular feed water flow guiding member inside of the folded reverse osmosis membrane. The dual folded reverse osmosis membrane 17 was placed onto the treated water flow guiding member. The water flow guiding member 12 and the folded reverse osmosis membrane 17 were adhered to each other by the glue belts to provide a reverse osmosis membrane group 18. The steps of providing treated water flow guiding member, forming glue belts and adhering the folded reverse osmosis membrane with feed water flow guiding member inside was repeated again and a second reverse osmosis membrane group are formed onto the second reverse osmosis membrane group.
The reverse osmosis membrane groups 18 are spirally wound around the whole central water collection tube 11 as shown in
Then, the outer annular areas (221, 421) of the side surfaces (22, 42) of downstream end 21 of the first reverse osmosis membrane set 2 and the upstream end 41 of the second reverse osmosis membrane set 4 are sealed by means of glue as shown in
The side surfaces of the upstream end 23 of the first reverse osmosis membrane set 2 and the downstream end 43 of the second reverse osmosis membrane set 4 are fully sealed by means of glue. The upstream end of the first central water collection tube 3 was also sealed by means of glue. An annular sealing member 9 is disposed outside the plastic strip and around the joint 7. The spiral wound reverse osmosis membrane element 1 was then mounted into a pressure vessel 8 to produce the reverse osmosis module.
A comparison test was conducted between a traditional reverse osmosis module A and a reverse osmosis module as prepared in this example (named as E) using the same feed water. A and E are substantially same except that the A has integrated reverse osmosis membrane spirally wound around a whole central treated water collection pipe. When the rate of flow of the treated water is below 150 ml/min, it is considered the reverse osmosis module needs to be replaced. The lifetime of the reverse osmosis module is the total volume of generated water when the rate of flow of the treated water is no less than 150 ml/min. For module A, the initial rate of flow of the treated water was 240 ml/min and dropped to 150 ml/min after it generated treated water with volume of 750 L. In contrast, Module E had an initial rate of flow of the treated water of 350 ml/min and generated 1380 L of treated water when the rate of flow of the treated water dropped to 150 ml/min. Therefore, it was demonstrated that the lifetime of the reverse osmosis membrane element of was significantly improved.
The process of the present invention only needs one step of reverses osmosis membrane group spirally winding to achieve a longer water flow channel. In addition, the glue coating is easily to be operated on dissected side surfaces. Therefore, this process is suitable for factory manufacture which has high efficiency and improved reliability.
| Number | Date | Country | Kind |
|---|---|---|---|
| PCT/CN2018/121037 | Dec 2018 | CN | national |
| 19154458.4 | Jan 2019 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2019/083412 | 12/3/2019 | WO | 00 |
