This invention relates to membrane modules for water treatment.
Hollow fiber membranes can advantageously be used in water treatment units to extract permeate from a supply of water. The hollow fiber membranes may be potted in headers. A source of suction is provided to the headers to withdraw permeate through the membrane walls and into the lumens of the fibers. The permeate is then drawn into a permeate collection cavity in or adjacent to the headers.
Immersed membranes may be used for extracting clean water (permeate) from a tank of contaminated water containing solids or mixed liquor. The membranes are often provided in the form of assembled modules, each module having many hollow fiber membranes extending from a header for collecting permeate that passes through pores of the membrane walls into the lumens of the membranes. Streams of air bubbles may be provided in the tank to rise past the membranes for cleaning purposes. The air bubbles also help to create circulation patterns in the tank.
However, the air bubbles or circulating water in the tank apply forces to the membranes. These forces may cause the fibers to break. A broken fiber allows unfiltered water from the tank to enter the permeate collection cavity. Since this is undesirable, the broken fiber must be located and repaired resulting in loss of productivity and additional expense.
It is an object of the invention to improve on, or at least provide a useful alternative to, the prior art. It is another object of the present invention to provide a membrane module of hollow fiber membranes and a method of making such a membrane module or a method of potting hollow fiber membranes. It is another object of the present invention to provide a membrane module having hollow fiber membranes that are protected, or have been potted, to inhibit their breakage. The following summary provides an introduction to the invention but is not intended to define or limit the invention which may reside in a combination or sub-combination of features provided in this summary or in other parts of this document for example the claims.
When using immersed membrane modules, the fiber membranes can sway or vibrate back and forth. The inventors have observed that this motion can induce some stress in the fibers, particularly near the headers where the fibers exit the potting material which seals and secures the outsides of the membranes, and particularly in fibers positioned at the outer periphery of any particular bundle of potted fibers. As a result, the fibers at the outer periphery of a bundle of fibers, and any stray fibers sticking out from a bundle of fibers into a circulation channel for the water in the tank, are particularly susceptible to breakage. By protecting even only these fibers, the rate of breakage in the bundle may be drastically reduced. Alternately, a thinner or weaker, but less expensive, fiber may be used and result in the same breakage rate as a strong fiber that is not so protected.
According to one aspect of the present invention, an assembly of hollow fiber membranes has at least one bundle of permeating hollow fiber membranes that are potted in a block of solid potting material, and a cushioning wall extending along at least a portion of the axial length of the fibers adjacent the potting material around at least a portion of the perimeter of the bundle. The portion of the perimeter may be an area where forces on the fibers from bubbles or circulating water are highest. Optionally, the entire perimeter may be protected.
The cushioning wall can have a fixed edge adjacent the potting material, and the wall can extend away from the potting material in a direction generally parallel to the length of the hollow fiber membranes. The wall may extend away from the potting material for only a short distance, for example, less than 15 cm, since the need for protection is primarily where the fibers join the potting material. If the potting material has wicking asperities with upper edges extending away from the potting material, and the cushioning wall can extend past the upper edges of the wicking asperities. The cushioning wall can be attached to the potting material of the header. Alternately, the header can be provided with a shell in which the potting material is held, and the cushioning wall can be attached to the shell.
The cushioning wall can have a free edge opposite the fixed edge. The cushioning wall can comprise a layer of liquid material solidified after application to the potting material or shell. Alternatively, the cushioning wall can comprise a strip of flexible material applied as a solid and the fixed edge can be attached to or potted in the potting material.
In other aspects, protective or non-permeating fibers can be added to a bundle to form a cushioning wall protecting the other fibers. For example, a layer of protective fibers of generally the same length as the other bundled fibers, may be provided on the outside of a bundle, either in one or more selected high stress locations, or around the entire perimeter of the bundle. The layer of protective fibers can include non-permeating hollow fibers, with ends that terminate and are embedded within the potting material. Alternatively, the non-permeating hollow fibers can have fluid isolating obstructions within the fibers, between the ends of the non-permeating fibers and where the non-permeating fibers exit the potting material. The fluid isolating obstructions can be plugs or pinch seals. Because the fibers are non-permeating they may break without allowing water in the tank to enter the permeate collection cavity. But even when broken, the protective fibers continue to protect the other fibers in the bundle from breakage. As a further alternative, the layer of protective fibers can include non-permeating solid filaments. The solid filaments can have at least an outer layer of fiber material that is generally the same as the material from which the permeating hollow fiber membranes are constructed or be of such a material throughout. As yet a further alternative, the layer of protective fibers can comprise reinforced permeating fibers having ends potted in the cured resin. The reinforced hollow fibers can be hollow fibers supported on a braided tube.
The layer of protective fibers can additionally or alternatively include a porous fabric sheet. The fabric sheet can be constructed of, for example, but without limitation, cheesecloth or gauze or other macroporous fabric constructions, and can extend along substantially the entire axial length of the bundled permeating hollow fibers.
In another aspect of the present invention, a method of constructing a header having potted filtering hollow fiber membranes and breakage protection for the membranes is provided. The method includes providing a bundle of permeating hollow fiber membranes inside a header shell or other potting container in a first layer of potting material and providing a cushioning wall along at least a portion of the axial length of the fibers and along at least a portion of the perimeter of the bundle to reduce stress on the fibers where the fibers exit the resin and to prevent stray fibers from sticking out beyond the periphery of the bundle.
The cushioning wall can be provided around substantially the entire perimeter of the bundle. Providing the wall can include applying a liquid along a portion of the perimeter of the bundle which is to have the wall and allowing the liquid to solidify in contact with the potting material or shell. Alternatively, the cushioning wall can be in the form of a strip of solid flexible material having a first edge positioned to generally abut the first layer of potting material, and the method can include supplying a second layer of potting material to pot the first edge of the cushioning wall, fixing the first edge of the cushioning wall to the header.
In another aspect of the present invention, a method of potting hollow fiber membranes in a header that controls against potting stray fibers is provided. The method includes arranging a plurality of hollow fiber membranes in a bundle, providing gathering elements around the perimeter of the bundle of fibers and/or adjacent one end of the bundle and providing a solidifying potting material such that the potting material flows between adjacent fibers in the bundle.
The gathering elements can be substantially inelastic, and can be provided between groups of fibers in each bundle to form sub-bundles. The gathering elements can comprise, for example, but not limited to, string-like elements such as fiber membranes, filaments, or yarn. The method for providing the gather elements can include threading, stitching, or weaving the gathering elements in a matrix pattern around and/or through the bundle, in a plane generally perpendicular to the axis of the fibers.
For a better understanding of the present invention and to show more clearly how it may be carried into effect, reference will now be made by way of example, to the accompanying drawings that show embodiments of the present invention, and in which:
a and 9b are partial cross-sectional views of the header of
A filtration module 90 having a header potted according to the present invention is shown generally in
As best seen in
The header 100 can have a shell 108, and the resin 106 can fill an upper portion of the shell. A permeate cavity 110 is provided between the underside of the resin and the inner surface of the shell. The permeating fibers 104 have lumens 112 that are in fluid communication with the permeate cavity 110. The resin 106 serves to hold and seal the fibers of the bundles in the shell, and to seal off the permeate cavity 110. In a module 90 with two headers 100, one header 100 can be a non-permeating header with the resin 106 filling the shell 108 entirely, that is the area occupied by the permeate cavity 101 in
Referring to
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The material of the strip 120 can be any flexible material that is able to yield to a force exerted on it by a fiber 104 that may be attached to, or pressed against, the wall 123, while providing some resistance to such force so that any stress induced on the fiber 104 at its point of exit from the resin 106 is reduced. Furthermore, the strip 120 should be sufficiently soft and/or smooth so that any rubbing action that may occur between the strip 120 and the fibers 104 does not damage the fibers 104.
In the embodiment illustrated, the strip 120 is formed of a silicone material that is applied in a generally liquid form around the perimeter 103 of each bundle 102, near the resin 106. The silicone solidifies to form the flexible strip 120. The lower edge 122 of the strip 120 so formed bonds to an exposed surface of the header 100, which can include at least one of the surfaces consisting of the resin 106 and the shell 108. The silicone may also bond to the membranes 104, although that bond may be broken as the membranes move in service.
Another embodiment of a header 200 according to the present invention is best seen in
To facilitate construction of the header 200, a two-stage potting process can be employed. The bundle is prepared with the protection strip 220 wrapped around one end. The protective strip 220 may have a circumference the same as or slightly longer than the circumference of the bundle to inhibit fibers from straying from the bundle. The lower ends of the fibers 104 in the bundle 102 can be potted in a first layer of resin 106a. The lower edge 222 of the strip 220 can then be positioned along the perimeter 103 of the bundle 102 and against the upper surface of the resin layer 106a, and a second, final layer of resin 106b can then be provided on top of the first layer 106a and around the lower edge 222 of the strip 220. The layers 106a and 106b together form the cured resin 106 of the header 200, and hold the fibers 104 and the strip 220 securely in place. Alternatively, one or more strips 220 may be provided only at selected locations, for example along the two long sides of a bundle, and inserted into the resin before it cures, or provided on top of a first layer 106a as described above.
In the embodiment illustrated, the strip 220 of the header 200 has an upper edge 224 opposite the first edge 222, and the cushioning wall 223 extends between the edges 222 and 224. The resin 106 has wicking asperities 128 with upper edges 130 extending away from the exposed surface of the resin 106 and adjacent the fibers 104. The upper edge 224 of the strip 220 extends past the upper edges 130 of the wicking asperities 128. Accordingly, the cushioning wall 223 straddles the axial position of the upper edges 130 of the wicking asperities 128 along the bundle 102. The wall 123, 223 may be, for example, between 1 cm and 15 cm high.
A third embodiment of a header according to the present invention is illustrated at 300 in
The cushioning wall 323 can be provided in the form of a protective layer 325 of non-permeating fibers 327. The non-permeating fibers 327 are fibers that do not provide fluid communication between an external surface of the fibers and the permeate cavity 110 in the header 300. The non-permeating fibers 327 may be potted in the resin 106, around at least a portion of the perimeter 103 of each bundle 102 of fibers 104, and may be potted at a spacing or potting density generally equal to that of the permeating fibers 104 in the bundle 102. The protective layer 325 may comprise about one to five or two to three rows of fibers 327 in thickness. In the embodiment illustrated, the protective layer 325 comprises two rows of non-permeating fibers 327.
Referring to
Referring to
Alternatively, as best seen in
In use, the non-permeating fibers 327 of the protective layer 325 protect against breakage of the permeating fibers 104 by acting as sacrificial elements that can fracture or break without causing undesirable consequences, such as contamination of the permeate. As well, the protective layer can inhibit the occurrence of “stray” permeating fibers 104 potted in the header 300, since the permeating fibers 104 in the bundle 102 are gathered within the non-permeating fibers 327 of the outer protective layer 325. In other words, if any stray fibers were potted in the header 300, such a stray fiber would more likely be a non-permeating fiber 327, rather than a permeating fiber 104.
In use, it is expected that a certain proportion of the outermost fibers 327 in the header 300 will experience sufficient stress forces to cause those fibers 327 to fracture, rupture, or otherwise break. Since the fibers 327 in the outermost layer 325 are non-permeating, no contamination of the permeate results from such breakage. Furthermore, even if some of the fibers 327 in the layer 325 break, enough of the fibers 327 of the protective layer 325 can remain intact to provide sufficient breakage protection to the underlying permeating fibers 104. As well, any broken fibers may leave stubs emerging from the resin 106 that may continue to act as a cushioning wall 323. Stubs of non-permeating fibers may also be used as the protective layer 325. Ultimately, some of the permeating fibers 104 may also eventually break, but the protective layer 325 will have delayed the breakage, so that the mean operating time between servicing the module 92 has been extended.
Referring now to
Referring now to
Referring now to
The gathering elements 401 can comprise yarn coarsely weaved in a plane perpendicular to the axis of the fibers 104. The grid pattern formed by the coarsely weaved gathering elements 401 can thereby provide sub-bundles 403 of fibers 104 within each bundle 102. Grouping the fibers 104 into sub-bundles can facilitate the corralling function of the gathering elements 401 in the bundle 102.
While preferred embodiments of the invention have been described herein in detail, it is to be understood that this description is by way of example only, and is not intended to be limiting. The full scope of the invention is to be determined by reference to the appended claims.
This is an application claiming the benefit under 35 USC 119(e) of U.S. Provisional Patent Application Ser. No. 60/528,493, filed Dec. 11, 2003. U.S. Ser. No. 60/528,493 is incorporated herein, in its entirety, by this reference to it.
Number | Date | Country | |
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60528493 | Dec 2003 | US |