The embodiments discussed herein are related to a micro electro-mechanical system (MEMS) sensor and a MEMS sensor manufacture method.
A MEMS sensor such as an acceleration sensor, a vibration gyroscope and a vibration sensor is known which converts a displacement of flexible beam coupling a mass body to an electric signal. Silicon fabrication techniques have been developed sophisticatedly along with the advancement of integrated circuits, and are suitable for MEMS manufacture. Charge carriers (electrons, holes) in silicon are under influence of stress application. Mobility of electrons increases as a tensile stress is applied along a transport direction, and decreases as a compressive stress is applied along a transport direction. Mobility of holes increases as a compressive stress is applied along transport direction, and decreases as a tensile stress is applied along transport direction. If the surface of a semiconductor layer is deformed in a convex shape, the surface receives a tensile stress, whereas if the surface is deformed in a concave shape, it receives a compressive stress. Change in the mobility of charge carriers in semiconductor can be detected by fabricating a semiconductor element such as a resistor and a MOS transistor in a silicon region intensively receiving stress. Mass body is coupled to a flexible beam unit whose distal ends are supported by support body. Since the mass body has inertia, as the mass body moves, the flexible beam deforms and receives stress. As a cross sectional area of the beam is made small, stress applied on the beam becomes large.
Assuming xyz orthogonal coordinate system, for example, two flexible beams along x-direction and two flexible beams along y-direction are connected via a joint region to form a flexible beam unit of cross shape, mass body is coupled to the lower surface of the crossed region, and four distal ends are supported by support body. This structure is that the mass body is supported by the support body via two flexible beams in x-direction and two flexible beams in y-direction. As the support body starts moving along the x-direction, the upper region of the mass body is driven along the x-direction so that the mass body tilts along the x-direction and two flexible beams along the x-direction undergo deflection. Deformations of two flexible beams along the x-direction are opposite (concave and convex) in the z-direction and change depending on distance from the joint region. When a bridge circuit is formed by forming four piezo resistors disposed on the flexible beams along the x-direction, acceleration along the x-direction can be detected. When a bridge circuit is formed by forming four piezo resistors disposed on the flexible beams along the y-direction, acceleration along the y-direction can be detected. Motion along the z-direction causes symmetrical deformation of respective flexible beams on both sides of the joint region. Deformation becomes opposite in sign between motion along +z-direction and −z-direction. When a bridge circuit is formed by forming four piezo resistors on the flexible beams along the x-direction and/or along the y-direction, acceleration along the z-direction can be detected.
Silicon on insulator (SOI) substrate has usually the structure that a single crystal silicon semiconductor layer is bonded via a silicon oxide insulating layer to a single crystal silicon support substrate. One method of forming the SOI substrate is to abut two silicon substrates each having a silicon oxide layer, with the silicon oxide layers being faced each other, to perform high temperature annealing to bond two substrates, and to polish one of the silicon substrate to a desired thickness to provide a semiconductor layer. Another known method is to implant oxygen ions into a silicon substrate, and to form a buried silicon oxide layer through heat treatment. In this case, the buried silicon oxide layer does not have a bonding function, and is merely an intermediate insulating layer. The SOI substrate is used for forming dielectrically isolated high speed transistors or forming MEMS.
Japanese Patent Unexamined Publication No. 8-274349 discloses that an n-type epitaxial layer is grown on a p-type silicon substrate, piezo resistors are formed by p-type regions formed by doping boron (B) into the n-type epitaxial layer, a hollow or cavity is formed through the substrate and epitaxial layer by etching, a flexible beam unit is formed from the epitaxial layer and traversing the hollow, and a weight formed of metal is attached on the lower surface of the central area of the beam.
Japanese Patent Unexamined Publication No. 8-248061 discloses a MEMS sensor formed by bonding beam and weight respectively made from different silicon substrates.
Japanese Patent Unexamined Publication No. 9-15257 discloses that a looped recess is formed on the surface of a first substrate, a second substrate is bonded to the first substrate, the second substrate is thinned, thereafter a weight is formed by the first substrate, and a beam is formed from the second substrate.
Japanese Patent Unexamined Publication No. 2003-270262 discloses that a weight is coupled via a beam to a frame, a glass stopper facing the weight for limiting a movable range of the weight is coupled to the frame, and adhesion preventive portion is formed on at least one of opposing surfaces of the weight and glass stopper.
Japanese Patent Unexamined Publication No. 2004-233072 and U.S. Pat. No. 6,892,578 disclose that a plurality of recesses are formed on the surface of an acceleration sensor, and a regulating plate is bonded to the recesses using spacers having a diameter larger than a depth of the recesses to thereby define a narrow gap between a weight and the regulating plate.
Japanese Patent Unexamined Publication No. 2006-208272 discloses a structure in which a sensor is formed by an SOI substrate, wherein a main weight supported via a beam by a frame has additional weights continuous to and integral with the main weight at four corners thereof, and a cover covering the upper portion of the sensor has stoppers facing the additional weights.
Japanese Patent Unexamined Publication No. 2006-153519 discloses a structure in which a flat plate stopper for regulating a displacement of a weight is provided above the surface of an acceleration sensor, a plurality of convex portions with a preset projection height are bonded to a frame, and a recess portion for storing adhesive is formed in each convex portion. The acceleration sensor is formed by an SOI substrate having an insulating film and a semiconductor layer formed on a support substrate, a frame and a core portion of a weight are formed of the support substrate, insulating layer and an active layer, a flexible beam unit is formed of the active layer, and additional portions continuous to the core portion at four corners are formed of the support substrate.
Japanese Patent Unexamined Publication No. 2006-64532 discloses a structure in which a main weight supported via a beam to a frame has additional weights continuous to and integral with the main weight at four corners, a thin stopper for regulating a displacement of each additional weight protrudes from each corner of the frame, and is provided with a reinforcing portion.
An object of the present invention is to provide a MEMS sensor having a novel structure and its manufacture method.
Another object of the present invention is to provide a MEMS sensor equipped with a mass body stopper integral with the MEMS sensor and its manufacture method.
According to one aspect of the present invention, there is provided a MEMS sensor including:
a mass body;
a support body surrounding and separated from said mass body by a looped trench, the support body and the mass body being formed from a common substrate;
flexible beam having piezo resistors and formed by a semiconductor layer separated upward from an upper surface of said substrate by a first distance;
first connector extending through a central region of said flexible beam and reaching said mass body, said first connector mechanically coupling said flexible beam and said mass body; and
second connector contacting distal ends of said flexible beam, extending through said semiconductor layer, and reaching said support body, said second connector mechanically coupling said flexible beam and said support body.
According to another aspect of the present invention, there is provided a method for manufacturing a MEMS sensor comprising steps of:
defining a region for a mass body, a region for a trench surrounding said mass body and a region for a support body outside said trench region, on a lamination substrate laminating a semiconductor layer above a substrate via an intermediate layer having etching characteristics different from etching characteristics of said semiconductor layer and said substrate;
etching said semiconductor layer and said intermediate layer in a region of a central area of said mass body region and in a looped region above said support body region to form recesses exposing said substrate;
burying a support material layer having different etching characteristics from those of said intermediate layer, in said recesses;
etching said semiconductor layer to pattern cross-shaped flexible beam unit including said region of the central area in a crossed region, above said mass body region;
etching said trench region of said substrate to form a trench exposing said intermediate layer; and
wet etching said intermediate layer.
The object and advantages of the invention will be realized and attained by means of the elements and combinations particularly pointed out in the claims.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are not restrictive of the invention, as claimed.
The present inventor has studied for an acceleration sensor having a mass body and a support body patterned from a support substrate of an SOI substrate and a flexible beam unit patterned from a semiconductor layer of the SOI. In this case, the support substrate may be called a lower substrate because of its positive function, and the semiconductor layer may be called an upper semiconductor layer. A looped trench is formed through the lower substrate, a central region is used as a mass body, and a peripheral region is used as a support body. The upper semiconductor layer is patterned to form a flexible beam unit coupling the mass body and having piezo resistors for detecting strain caused by stress.
The mass body and flexible beam unit are overlapped as viewed in plan. In order to separate the mass body from the flexible beam unit except for the coupling region, etched is an intermediate insulating layer between the upper semiconductor layer and lower substrate. The mass body is however required to be coupled to the flexible beam unit. The distal ends of the flexible beam unit are required to be supported by the support body. Connectors are formed between the flexible beam unit and mass body and between the support body and flexible beam unit. The connectors are made of support material having etching characteristics different from those of the intermediate insulating layer. The upper semiconductor layer and intermediate insulating layer in the connector regions are etched, and a support material layer is buried in the etched recesses. When the support material layer or upper semiconductor layer is configured to extend or protrude above the mass body, this extension can function as stopper for rising motion of the mass body.
With reference to
As illustrated in
As illustrated in
As illustrated in
In a rectangular region 15 within the crossed region of the flexible beam unit FB and regions 16 contiguous with the distal ends of the flexible beam unit FB, the upper semiconductor layer 13 and intermediate insulating layer 12 are etched, and a support material layer is buried in the etched regions to form the two kinds of connectors. Rise stopper for the mass body M can be formed in the following manner. In regions 17 outside the corners of the mass body M (on the support body S), the upper semiconductor layer 13 and intermediate insulating layer 12 are etched, and in regions 18 extending in a triangular shape above the corners of the mass body from the inner edges of the regions 17, the upper semiconductor layer 13 is etched without etching the intermediate insulating layer 12. The support material layer is thereafter buried in the etched regions. The support material layer contacts the lower substrate in the regions 17, and is separated from the lower substrate in the region 18. For example, the rectangular region 15 has a square shape of 200 μm×200 μm, and the region 18 has an isosceles right triangle shape having two sides of 350 μm forming a right angle.
In this embodiment, although the regions 16 and 17 are contiguous to define a looped region on the support member S, these regions may be separated regions. The position where the rise stopper is disposed is not limited to the corners of the rectangular mass body M. A number of sensor chips are formed on one SOI wafer. Scribe regions between chips are preferably semiconductor regions. In order to form the scribe regions, the upper semiconductor layer 13 is left in a narrow frame region 19 along the chip outer periphery.
The upper semiconductor layer 13 in the regions 15, 16, 17 and 18 are etched to expose the intermediate insulating layer 12. Next, the intermediate insulating layer 12 exposed in the regions 15, 16 and 17 except for the region 18 is etched and removed to expose the lower substrate 11. The intermediate insulating layer 12 is left in the region 18 to form a step relative to the region 17.
As illustrated in
The film formed by CVD is conformal to the underlying topology. The support material layer at the level higher than the upper semiconductor layer is not necessary. The unnecessary region is removed by etch back, chemical mechanical polishing (CMP) or the like to expose the upper semiconductor layer 13.
The support material layer 30 buried in the region 15 constitutes a connector C1, which directly contacts and is mechanically coupled with the mass body S, and the upper region of which is mechanically coupled with the crossed region of the flexible beam unit FB. The connector C1 couples the mass body M to the flexible beam unit FB. The support material layer 30 buried in the region 16 constitutes a connector C2, which directly contacts and is mechanically coupled with the support body S, and the upper region of which is mechanically coupled with the distal end of the flexible beam unit FB. The connector C2 couples the flexible beam unit FB to the support body S. The support material layer 30 buried in the region 17 constitutes a contact region CT directly contacting and mechanically coupled with the support body S. The support material layer 30 buried in the region 18 constitutes a non-contact region isolated from the lower substrate 11 by the intermediate insulating layer 12. The non-contact region NC is contiguous with the contact region CT to constitute stopper ST. The non-contact region NC of the stopper ST forms a step to separate upward from the lower substrate 11, and extends above the mass body M. The frame region 19 of the upper semiconductor layer 13 surrounds the outer peripheries of the connectors C2 and stoppers ST.
As illustrated in
The intermediate insulating film 12 exposed in the trench T is wet etched, and the intermediate insulating film 12 between the flexible beam unit FB and mass body M is also etched and removed. If the intermediate insulating layer is made of silicon oxide, the intermediate insulating layer can be etched by wet etching using dilute hydrofluoric acid or buffered hydrofluoric acid. Vapor phase isotropic etching with mixed gas of anhydrous hydrofluoric acid and alcohol may also be used. The support material layer 30 of silicon nitride is hardly etched because the layer has etching characteristics different from those of the intermediate insulating layer of silicon oxide. Instead of etching the intermediate insulting layer from the trench T on the bottom surface side, the intermediate Insulating layer may be etched from the top surface or from both the top and bottom surfaces, while covering the flexible beam unit with resist or the like. Since the frame region 19 is continuous with adjacent chips, the underlying intermediate insulating layer 12 will not be etched.
When the support substrate 11 illustrated in
Since the mass body M is supported at the upper surface by the flexible beam FB, the mass body M tilts upon application of an acceleration in the in-plane directions. Therefore, the stoppers have function of tilt (in-plane direction) stopper also.
With reference to
As shown in
As shown in FIGS. 2B and 2BX, an insulating protective film 20 of about 0.5 μm thick of silicon dioxide is formed on the upper semiconductor layer 13 by thermal oxidation or CVD. Then, recesses for burying connectors and stoppers are etched. A photoresist pattern PR2 is formed on the insulating protective film 20, having apertures of a shape of the connectors and stoppers including the non-contact regions.
FIG. 2BP is a plan view illustrating the photoresist pattern PR2. The photoresist pattern PR2 has: a pattern PA2 having a rectangular aperture AP1 corresponding to the connector C1 in the central area; and a pattern PB2 surrounding the pattern PA2 and formed along a chip periphery. An aperture AP2 between the patterns PA2 and PB2 becomes a region for connectors C2 and stoppers ST. The aperture AP2 extends in triangular shape at rectangle corners to form the non-contact regions NC of the stoppers ST. This shape corresponds to the stopper ST illustrated in
As illustrated in FIGS. 2B and 2BX, by using as an etching mask the photoresist pattern PR2 including the patterns PA2 and PB2, the insulating protective film 20 and upper semiconductor layer 13 are sequentially and anisotropically etched by reactive ion etching (RIE). For example, the insulating protective film 20 is etched by reactive ion etching using CHF3, and then the upper semiconductor layer 13 is etched by reactive ion etching using CF4 gas and O2 gas. The photoresist pattern PR2 is thereafter removed.
As illustrated in FIGS. 2C and 2CX, a photoresist pattern PR3 is formed on the SOI substrate.
FIG. 2CP is a plan view illustrating the photoresist pattern PR3. The photoresist pattern PR3 has: a pattern PA3 having a rectangular aperture AP1 in the central area; and a pattern PB3 surrounding the pattern PA3 and formed along a chip periphery. An aperture AP3 between the patterns PA3 and PB3 becomes a region for the connectors C2 and contact regions CT of the stoppers ST.
As illustrated in FIGS. 2C and 2CX, the intermediate insulating layer 12 exposed in the apertures is etched to expose the lower substrate 11. For example, the intermediate insulating layer 12 is etched by reactive ion etching using CHF3 gas. In this manner, recesses for the connectors C1 and C2 and stoppers ST are formed. The connectors C2 and the contact regions CT of the stoppers ST are disposed outside the trench position where the lower substrate will be separated. The regions where the upper semiconductor layer 13 is etched, and the intermediate insulating layer 12 is left, become the non-contact regions NC of the stoppers ST. The photoresist pattern PR3 is thereafter removed.
As illustrated in FIGS. 2D and 2DX, a support material layer 30 is deposited burying the recesses for the connectors and stoppers. For example, a silicon nitride layer (SixNy) layer is deposited by plasma enhanced (PE) CVD at a substrate temperature of 400° C. and to a thickness of at least 11.5 μm which is a total thickness of the intermediate insulating layer 12, upper semiconductor layer 13 and insulating protective film 20. The support material layer 30 formed by CVD or the like has conformal surface topology reflecting the underlying topology. When a layer having an uneven surface is etched back, the processed surface will also be uneven. A flat surface is desired to form wirings and the like thereon.
As illustrated in FIGS. 2E and 2EX, a planarizing film PR4 is formed on the surface of the support material layer 30 if necessary. The planarizing film PR4 is made of material capable of realizing an etching rate approximately equal to that of the support material layer 30 so that it is possible to realize a flat surface. For example, photoresist, spin-on glass (SOG), polyimide or the like is coated and baked to form the planarizing film PR4 having a flat surface. The planarizing film PR4 is a film desired to be used when etch-back is to be performed, and is not an essential constituent element. Silicon nitride layer may be etched using, for example, SF6/He.
As illustrated in FIGS. 2F and 2FX, the planarizing film PR4 and support material layer 30 above the surface of the insulating protective film 20 are etched back under the condition that etching rates of the planarizing film PR4 and support material layer 30 are approximately equal. As a result, the upper surfaces of the insulating protective film 20 are exposed, the support material layer 30 is left in the recesses, and the upper surface of the support material layer 30 and the upper surfaces of the insulating protective film 20 are generally flush. As a result, the flexible beam unit FB is supported by the support body S via the support material layer 30a, and the mass body M is coupled to the crossed region of the flexible beam unit FB via the support material layer 30b. However, at this stage, the flexible beam unit is not patterned yet, the mass body M is not separated yet from the support body S, and the intermediate insulating layer 12 exists between the mass body M and flexible beam unit FB.
In the state as illustrated in FIGS. 2D and 2DX, where the planarizing film PR4 is not formed, polishing such as chemical mechanical polishing (CMP) may be performed to remove the support material layer 30 on the insulating protective film 20.
As illustrated in
A photoresist pattern PR5 having apertures at positions corresponding to the contact regions of the piezo resistors 131 is formed on the insulating passivation film 40. Contact holes are formed by etching the insulation passivation layer 40 and insulating protective film 20. For example, the insulating passivation layer 40 and insulation protective film 20 are anisotropically etched by reactive ion etching using mixed gas of CF4+H2, or CHF3 gas. Contact holes may be formed by wet etching using dilute hydrofluoric acid (HF) or buffered hydrofluoric acid (BHF). The photoresist pattern PR5 is thereafter removed.
As illustrated in
As illustrated in
As illustrated in FIGS. 2JX and 2JP, a photoresist pattern PR7 having window apertures which define flexible beam unit is formed on the insulation passivation layer 40, covering the conductive layer 50. As illustrated in FIG. 2JP, the photoresist pattern PR7 has four windows W1 for defining the shapes of the flexible beam unit FB, and covers the connectors C2 and stoppers ST in the outer peripheral portion. As illustrated in FIG. 2JX, by using the photoresist pattern PR7 as an etching mask, the insulating passivation layer 40, insulating protective film 20 and upper semiconductor layer 13 are etched. For example, the insulating passivation layer 40 and insulating protective film 20 are etched by reactive ion etching using CHF3 gas, and the upper semiconductor layer 13 is etched by reactive ion etching using CF4 gas and O2 gas. The silicon oxide layers 40 and 20 may be etched by wet etching using dilute hydrofluoric acid or buffered hydrofluoric acid. The etched windows W1 define the flexible beam unit FB. The insulating passivation layer 40, insulating protective film 20 and upper semiconductor layer 13 constitute the flexible beam unit FB. The intermediate insulating layer 12 is exposed in the windows W1. The photoresist pattern PR7 is thereafter removed. At this stage, the intermediate insulating layer 12 is left.
As illustrated in FIGS. 2K and 2KX, a sacrificial substrate 99 is bonded via an adhesive layer 98 to the insulating passivation layer 40 formed with patterns of the conductive layer 50, and the substrate is turned upside down. More specifically, the adhesive layer 98 may use wax, photoresist, double-stick tape or the like. The sacrificial substrate 99 provides a physical support, and may be a silicon substrate.
A photoresist pattern PR8 having a looped aperture for forming trench is formed on the bottom surface of the lower substrate 11. By using the photoresist pattern PR8 as an etching mask, a looped trench T is etched through the lower substrate 11. For example, the lower substrate of single crystal silicon is anisotropically etched by deep-RIE (so-called Bosch process) which alternately repeats passivation step using C4F8 plasma and etching step using SF6 plasma. The trench T separates the inner mass body M and the outer support body S.
In the state that the surface of the insulating passivation layer 40 is covered with the sacrificial substrate 99 via the adhesive layer 98, the interlayer insulating film 12 is wet-etched with dilute hydrofluoric acid or buffered hydrofluoric acid. Etchant entered from the trench T etches and removes the intermediate insulating film 12. The sacrificial substrate 99 may be removed before etching. In this case, a resist film or the like is formed on the insulating passivation layer 40. Then, the intermediate insulating film 12 is etched by dilute hydrofluoric acid or buffered hydrofluoric acid. Then, the resist film on surface side is removed. In the state of
Instead of etching the intermediate insulating layer from the trench in the rear surface, the intermediate insulating layer may be etched from the front surface side or from both the front and rear sides. This alteration process will be described referring to
As shown in
As illustrated in FIGS. 2LX and 2L, gaps G1 and G2 are formed between the rise stopper 30a and mass body M and between the flexible beam FB and mass body M, respectively. The gaps G1 and G2 are defined by a thickness of the intermediate insulating layer 12. Post-processes such as dicing and packaging are thereafter executed.
According to the first embodiment described above, motion range of the mass body along a positive z-axis direction can be limited at high precision by the thickness of the intermediate insulating layer 12. Since the intermediate insulating layer 12 can be formed very thin, the motion range of the mass body M along the positive z-axis direction can be made very narrow. The function of limiting the motion range of the mass body along the positive z-axis direction can be realized by the material constituting the connector C2 so that this function can be provided without thickening a package 90, 94. An acceleration sensor can be realized which is thin and has a high impact resistance performance. An area of the mass body M facing the non-contact region of the stopper is limitative so that a sensitivity can be suppressed from being lowered by air dumping more than limiting the motion range of the mass body M by plate components.
The support material is not limited to silicon nitride, provided that it has etching characteristics different from those of the intermediate insulating layer and will not be etched when the intermediate insulating layer is etched. The support material may be other insulating material such as silicon oxynitride, semiconductor such as polysilicon and amorphous silicon, or metal such as copper, nickel, and Ni—Fe alloy. A metal film may be formed by sputtering or plating. Electrolytic plating may be performed by first forming a seed layer by sputtering and then electrolytically plating a metal layer using the seed layer as one electrode. The material of the seed layer may be metal different from that of the plated layer.
The support material layer 30 formed by sputtering, CVD or the like has a conformal surface topology reflecting the underlying topology. The surface of a metal layer formed by electrolytic plating may be planarized by selecting additive to be added to plating liquid.
An etching process for the trench may be executed as the first process of processing the SOI wafer, or may be executed immediately after the insulating protective film 20 is formed.
As illustrated In
As illustrated in
In the modification illustrated in
It becomes easy to remove the intermediate insulating layer 12 between the non-contact region NC and lower substrate 11. Even if the area where the non-contact region NC faces the mass body M is broadened, it is possible to suppress a defective product forming percentage from being lowered by residues of the intermediate insulating film 12.
Further, even if the area where the non-contact region NX faces the mass body M is broadened, it is possible to suppress a sensitivity from being lowered by air dumping of the non-contact region NC.
The through holes can be formed in the non-contact region, not only in the case when the non-contact region of the stopper is formed by the upper semiconductor layer but also in the case when the non-contact region of the stopper is formed by the connector material.
The shape of the non-contact region of the stopper may be selected from various shapes.
Silicon nitride film formed by CVD often applies a tensile stress to a silicon layer. The tensile stress lowers the mobility of carriers (holes) in the p-type silicon region. A piezo resistor is preferably formed in the p-type region because of its characteristics.
A trench may have a shape other than a rectangle.
In the first embodiment, the intermediate insulating film is etched and removed almost completely. Although the intermediate insulating film is left in the chip peripheral portion, it demonstrates no positive function.
Both the SOI substrate and epitaxial substrate have the lamination substrate structure that a semiconductor layer is laminated via an intermediate layer having different etching characteristics on a lower substrate.
The rise stopper is supported by a support body and extends or projects above the mass body. When a structure is formed which is supported by the mass body and extends or projects above the support body, a fall stopper is realized limiting a displacement amount while the mass body lowers.
As illustrated in
As illustrated in
The fall stopper 30c is made of the support material layer 30 similar to the rise stopper 30a and the connector 30b. In the modification illustrated in
The fall stopper 30c can limit a motion range of the mass body along the negative z-axis direction at high precision by a thickness of the intermediate insulating layer 12. Since the intermediate insulating layer 12 can be formed very thin, the motion range of the mass body along the negative z-axis direction can be made extremely narrow. Even if the function of limiting the motion range of the mass body along the negative z-axis direction is added, the package 90, 94 does not become thick.
Although the present invention has been described above in connection with the embodiments, the embodiments are not intended to be limitative. It is obvious for those skilled in the art to make various alterations, improvements, replacements, combinations and the like. For example, the shape of the flexible beam FB can be changed in various ways.
It is obvious to combine various constituent elements illustratively described in the different embodiments and modifications, in as many ways as possible. The materials, sizes, film forming methods, pattern transfer methods and process orders described in the embodiments and modifications are only illustrative. Addition and deletion of processes, and a change in process orders are possible which are obvious for those skilled in the art.
Number | Date | Country | Kind |
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2008-334018 | Dec 2008 | JP | national |