This disclosure relates to compositions and methods for cleaning and refinishing of surfaces.
Material surfaces of many types may be spoiled over time. Iron and steel surfaces can rust. Tile surfaces may be soiled. Wooden surface finishes may change color or opacity. Stone of buildings, statues, fountains, or the like may accumulate grime.
The process of restoration often begins with removing accumulated corrosion or deposited substances. Further, the removal is often accomplished with physical or chemical means.
In an aspect, the invention relates to a a method of making a surface treatment composition. The method comprises preparing a first mixture comprising borax (sodium tetraborate decahydrate), baking soda, linseed oil and water and ripening the first mixture to prepare a first solution. The method also comprises preparing a second mixture comprising water, sweeter, and at least one of muriatic acid, ammonia, and mineral spirits and ripening the second mixture to prepare a second solution. The method also comprises preparing a third solution comprising water and at least one of liquid dish detergent or soap. The method also comprises combining the first solution, the second solution, and the third solution to form a fourth solution and ripening the fourth solution.
In an aspect, the invention relates to a composition comprising borax (sodium tetraborate decahydrate); baking soda; linseed oil; sweetener; at least one of muriatic acid, ammonia, vegetable oil, and mineral spirits; at least one of liquid dish detergent or soap; and water.
In an aspect, the invention relates to a method of treating a surface. The method comprises applying a surface treatment composition herein to the surface.
The following detailed description of the preferred embodiment of the present invention will be better understood when read in conjunction with the appended drawings. For the purpose of illustrating the invention, there are shown in the drawings embodiments which are presently preferred. It is understood, however, that the invention is not limited to the precise arrangements and instrumentalities shown. In the drawings:
Certain terminology is used in the following description for convenience only and is not limiting. The words “a” and “one,” as used in the claims and in the corresponding portions of the specification, are defined as including one or more of the referenced item unless specifically stated otherwise. This terminology includes the words above specifically mentioned, derivatives thereof, and words of similar import. The phrase “at least one” followed by a list of two or more items, such as “A, B, or C,” or “A, B, and C,” means any individual one of A, B, or C as well as any combination thereof.
Embodiments herein list measures of substances, concentration, numeric values in a ratio, volume, mass, time, temperature, or the like by specific values. In further embodiments, any measure herein may be adjusted in 1% increments of the specific value out to plus or minus 50% from the specific value. Still further embodiments may include a range of the measure selected from any two 1% increments from minus 50% of the specific value to plus 50% of the specific value; i.e., from 0.5× to 1.5× of the specific value. For example, a specific value of one cup in an embodiment may be adjusted in further embodiments to be any value from one half cup to one and one half cup, where the values are selected from 0.5 cup, 0.6, cup, 0.7 cup, 0.8 cup, 0.9 cup, 1.0 cup, 1.1 cup, 1.2 cup, 1.3 cup, 1.4 cup, and 1.5 cup. The specific value of one cup in a still further embodiment may be a range of values where the endpoints of the range are selected from 0.5 cup, 1.5 cup, and every 0.1 cup increment from 0.5 to 1.5 cup; that is, the endpoints may be selected from any two of 0.5 cup, 0.6, cup, 0.7 cup, 0.8, cup, 0.9 cup, 1.0 cup, 1.1 cup, 1.2 cup, 1.3 cup, 1.4 cup, and 1.5 cup. A particular embodiment may include only the specific values listed, only the values arrived at under the further embodiments, or only the values arrived at under the still further embodiments. A particular embodiment may include a combination at least two of the specific values listed, the values arrived at under the further embodiments, or the values arrived at under the still further embodiments.
The term “comprise,” or its derivatives (comprising, comprises, or the like), means that the items gathered are part of the embodiment, but the embodiment may include any other element. Yet further embodiments herein include replacing one or more instance of “comprise,” or its derivatives with “consists essentially of” (or “consisting essentially of” or the like) or “consists of” (or “consisting of” or the like). “Consists essentially of” means that the items gathered are those that do not change material operation or properties of the embodiment and are part of the yet further embodiment. “Consists of” means that only the listed items are part of the yet further embodiment.
Methods of making a surface treatment herein arrive at compositions that may be safer that prior compositions used for surface treatment, particularly rust removal. Likewise, compositions herein may be safer that prior compositions used for surface treatment, particularly rust removal. In addition, the compositions may be more effective and work within minutes, in some cases 1-2 minutes, which is unlike prior surface treatment compositions.
An embodiment comprises a method of making a surface treatment composition. The method comprises preparing a first mixture comprising borax (sodium tetraborate decahydrate), baking soda, linseed oil and water. The volume ratio of the first mixture components used to make the first mixture may be 1-2:1:1-2:80 of the borax, baking soda, linseed oil and water, respectively. The ratio may be 2:1:2:80. The ratio may be 1:1:1:80. The first mixture may further comprise at least one of trisodium phosphate, oxidizing agent, or abrasive. The volume ratio of the first mixture components used to make the first mixture may be 1-2:1:1-2:0.5:0.5:0.5:80 of the borax (sodium tetraborate decahydrate), baking soda, linseed oil, trisodium phosphate (when present), oxidizing agent (when present), sea salt (when present), abrasive (when present), and water. The ratio may be 2:1:2:0.5:0.5:0.5:80. The ratio may be 1:1:1:0.5:0.5:0.5:80. The method may also comprise ripening the first mixture to prepare a first solution. Ripening may comprise letting the first solution sit. The ripening may occur over a period of time. The period may be one day or two days. Ripening of the first solution may occur at room temperature.
The method of making a surface treatment composition also comprises preparing a second mixture comprising sweetener and at least one of muriatic acid, ammonia, optionally vegetable oil, mineral spirits, and water. The volume ratio of the muriatic acid, ammonia, vegetable oil (when present), sweetener, mineral spirits, and water used to prepare the second mixture may be 0.5-1:0.5-1:2:3:1.5-2:80, respectively. The ratio may be 1:1:2:3:2:80. The ratio may be 0.5:0.5:2:3:1.5:80. The second mixture may also comprise at least one of sea salt, turpentine, hydrogen peroxide, and acrylic paint. The volume ratio of the muriatic acid, ammonia, vegetable oil (when present), sweetener, sea salt, turpentine (when present), hydrogen peroxide (when present), acrylic paint (when present), mineral spirits, and water used to prepare the second mixture may be 0.5-1:0.5-1:2:3:1:0.5:2:2:1.5-2:80, respectively. The ratio may be 1:1:2:3:1:0.5:2:2:2:80. The ratio may be 0.5:0.5:2:3:1:0.5:2:2:1.5:80. The ammonia may be HDX® lemon scent, which comprises ammonia at 1-3% by weight. The sweetener may be Splenda® (95% dextrose and maltodextrin (by volume) plus sucralose [4, 1, 6-trichloro-galacto-sucrose]). The method may also comprise ripening the second mixture to prepare a second solution. Ripening may comprise letting the second solution sit. The ripening may occur over a period of time. The period may be one day, two days, about one day, or about two days. Ripening of the second solution may occur at room temperature. Ripening of the second solution may occur at 100° F.
The method of making a surface treatment composition also comprises preparing a third solution comprising water and at least one of liquid dish detergent or soap. The volume ratio of the liquid dish detergent or soap to water may be 0.5:80. The liquid dish detergent may be Palmolive®. The liquid dish detergent may comprise ammonium lauryl sulfate, sodium lauryl sulfate, methylisothiazolinone, glycol distearate, or cocamiode DEA. The water may be hot. The temperature of the hot water may be 100° F.
The method of making a surface treatment composition also comprises preparing a fourth mixture by mixing together the first solution, the second solution and the third solution. The method may also comprise ripening the fourth mixture to prepare the surface treatment composition. The ripening may comprise letting the fourth solution sit. The ripening may occur over a period of time, which may be for one, two, or three days. The ripening of the fourth solution may be at room temperature.
Referring to
The method of making a surface treatment composition may further comprise a step 112 of combining trisodium phosphate with the water to prepare the first combination. The volume ratio of the borax, baking soda, linseed oil, and trisodium phosphate and water in preparing the first combination may be 1-2:1:1-2:0.5-1:32, respectively. The ratio may be 2:1:2:1:32. The ratio may be 1:1:1:0.5:32. The amount of one the trisodium phosphate may be one half cup or one cup when the volume of water for the first combination is 32 cups (2 gallons).
The method of making a surface treatment composition may further comprise in step 112 combining oxidizing agent with the water to prepare the first combination. The volume ratio of the borax, baking soda, linseed oil, trisodium phosphate, oxidizing agent, and water in preparing the first combination may be 1-2:1:1-2:0.5-1:0.5-1:32, respectively. The ratio may be 2:1:2:1:1:32. The ratio may be 1:1:1:0.5:0.5:32. The amount of oxidizing agent may be one half cup or one cup when the volume of water for the first combination is 32 cups (2 gallons). The oxidizing agent may comprise a peroxide. The oxidizing agent may comprise a percarbonate. The oxidizing agent may comprise percarbonate, carbonate, hydrogen peroxide, and surfactants. The oxidizing agent may comprise sodium percarbonate, sodium carbonate, hydrogen peroxide, and surfactants. The oxidizing agent may comprise disodium carbonate, sodium percarbonate, and C12-C15 ethoxylated alcohols. The disodium carbonate may be at 55-63.4% (w/w). The sodium carbonate may be at 50-60% (w/w) or 55-63.4% (w/w). The sodium percarbonate may be at 23.5-38.4% (w/w). The C12-C15 ethoxylated alcohols may be at 2.7-3.14% (w/w). The foregoing concentrations are the values in the oxidizing agent prior to the combining the water. The oxidizing agent may comprise Oxi-Clean®.
The method of making a surface treatment composition may further comprise in step 112 combining an abrasive with the water to prepare the first combination. The volume ratio of the borax, baking soda, linseed oil, trisodium phosphate, oxidizing agent, abrasive, and water in preparing the first combination may be 1:1:1:0.5:0.5:0.5:32, respectively. The amount of abrasive may be one half cup when the volume of water for the first combination is 32 cups (2 gallons). The abrasive may comprise pumice stone. The pumice stone may be in the form of particles having mesh size in a range between and including two mesh sizes selected from 60, 120, 160, or 200. The particles may have a mesh size of 120. The abrasive may comprise Pumice Stone FF (Rainbow®).
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An embodiment comprises a method of making a surface treatment composition comprising: combining one cup borax, one cup baking soda, optionally ½ cup trisodium phosphate, optionally ½ cup of oxidizing agent, optionally ½ cup pumice stone FF, and one cup linseed oil with two gallons of water to prepare a first combination, and mixing the first combination with three additional gallons of water to prepare a first mixture, and ripening the first mixture for two days to prepare a first solution. The method may include boiling the first combination. The oxidizing agent may comprise sodium percarbonate, sodium carbonate, hydrogen peroxide, and surfactants. The oxidizing agent may comprise disodium carbonate, sodium percarbonate, and C12-C15 ethoxylated alcohols. The disodium carbonate may be at 55-63.4% (w/w). The sodium carbonate may be at 50-60% (w/w) or 55-63.4% (w/w). The sodium percarbonate may be at 23.5-38.4% (w/w). The C12-C15 ethoxylated alcohols may be at 2.7-3.14% (w/w). The method also comprises combining ½ cup muriatic acid, ½ cup ammonia, optionally 2 cup vegetable oil, three cups sweetener, optionally 1 cup sea salt, optionally ½ cup turpentine, optionally 2 cups hydrogen peroxide, optionally 2 cups acrylic paint, and 1½ cup mineral spirits with two gallons water to prepare a second combination, mixing the second combination with an additional three gallons of water to prepare a second mixture, and ripening the second mixture for one day or two days to prepare a second solution. The water added may be 80°−90° F. The ammonia may be a solution comprising 1-3% by weight ammonia. The ammonia may be HDX® lemon scent, which comprises ammonia at 1-3% by weight. The sweetener may comprise sucralose (4, 1, 6-trichloro-galacto-sucrose). The sweetener may be 95% dextrose and maltodextrin (by volume) plus sucralose [4, 1, 6-trichloro-galacto-sucrose]. The sweetener may be Splenda®. The method also comprises dissolving ½ cup of liquid dish detergent or soap in 1, 2, 3, 4, or 5 gallons, preferably 5, of water to prepare a third solution. The liquid dish detergent may comprise ammonium lauryl sulfate, sodium lauryl sulfate, methylisothiazolinone, glycol distearate, or cocamiode DEA. The liquid dish detergent or soap may be Palmolive®. The method also comprises combining the first solution, the second solution, and the third solution to prepare a fourth combination, mixing the fourth combination to prepare a fourth mixture, and ripening the fourth mixture for one, two, or three days to prepare the surface treatment composition.
An embodiment comprises a method of making a surface treatment composition comprising: combining one cup borax, one cup baking soda, ½ cup trisodium phosphate, ½ cup Oxiclean®, ½ cup pumice stone FF, and one cup linseed oil with two gallons of water to prepare a first combination, mixing the first combination with three additional gallons of water to prepare a first mixture, and ripening the first mixture for one day or two days to prepare a first solution. The method also comprises combining ½ cup muriatic acid, ½ cup ammonia (HDX®) lemon scent, optionally 1 cup sea salt, optionally 2 cup vegetable oil, three cups Splenda®, optionally ½ cup turpentine, optionally 2 cups hydrogen peroxide, optionally 2 cups acrylic paint, and 1½ cup mineral spirits with two gallons of water to prepare a second combination, mixing the second combination with three additional gallons of water to prepare a second mixture, and ripening the second mixture for one day or two days to prepare a second solution. The method also comprises dissolving ½ cup of Palmolive® in five gallons of water to prepare a third solution. The method also comprises combining the first solution, the second solution, and the third solution, to prepare a fourth combination, mixing the fourth combination to prepare a fourth mixture, and ripening the fourth mixture for one day, two days, or three days to prepare the surface treatment composition.
An embodiment comprises any composition made by any method of making a surface treatment composition herein.
An embodiment comprises a first composition comprising borax (sodium tetraborate decahydrate), baking soda, linseed oil, and water. The volume ratio may be 1:1:1:32 of the borax, baking soda, linseed oil and water, respectively. The composition may further comprise at least one of trisodium phosphate, an oxidizing agent, and an abrasive. The volume ratio of the borax, baking soda, linseed oil, trisodium phosphate (when present), oxidizing agent (when present), abrasive (when present), and water may be 1-2:1:1-2:0.5-1:0.5-1:0.5:32, respectively. The ratio may be 2:1:2:1:1:1:32. The ratio may be 1:1:1:0.5:0.5.5:32. The measure in the above ratios may be cups. The oxidizing agent may comprise sodium percarbonate, sodium carbonate, hydrogen peroxide, and surfactants. The oxidizing agent may comprise disodium carbonate, sodium percarbonate, and C12-C15 ethoxylated alcohols. The disodium carbonate may be at 55-63.4% (w/w) in the oxidizing agent. The sodium carbonate may be at 50-60% (w/w) or 55-63.4% (w/w) in the oxidizing agent. The sodium percarbonate may be at 23.5-38.4% (w/w) in the oxidizing agent. The C12-C15 ethoxylated alcohols may be at 2.7-3.14% (w/w) in the oxidizing agent. The abrasive may comprise pumice stone. The pumice stone may be in the form of particles having mesh size in a range between and including two mesh sizes selected from 60, 120, 160, or 200. The particles may have a mesh size of 120. The abrasive may comprise Pumice Stone FF (Rainbow®). The first composition may be a first combination in a method herein. An embodiment comprises a first mixture composition comprising the products of mixing the first composition with additional water, adjusting the water from 32 parts to 80 parts. An embodiment comprises a first solution composition comprising the products of ripening the first mixture composition.
An embodiment comprises a second composition comprising water, sweetener at least one of muriatic acid, ammonia, optionally sea salt, optionally vegetable oil, optionally turpentine, optionally hydrogen peroxide, optionally acrylic paint, and mineral spirits. The volume ratio of the muriatic acid to the water may be 0.5-1:32, 0.5:32, or 1:32. The volume ratio of the ammonia to the water may be 0.5-1:32, 0.5:32, or 1:32. The volume ratio of the sea salt (when present) to the water may be 1:32. The volume ratio of the vegetable oil (when present) to the water may be 2:32. The volume ratio of the sweetener to the water may be 3:32. The volume ratio of the turpentine (when present) to the water may be 0.5:32. The volume ratio of the hydrogen peroxide (when present) to the water may be 2:32. The volume ratio of the acrylic paint to the water may be 2:32. The volume ratio of the mineral spirits to the water may be 1.5-2:32, 1.5:32, or 2:32. The measure in the foregoing ratios may be cups. The ammonia may be a solution comprising 1-3% by weight ammonia. The ammonia may be HDX® lemon scent, which comprises ammonia at 1-3% by weight. The sweetener may be Splenda® (95% dextrose and maltodextrin (by volume) plus sucralose [4, 1, 6-trichloro-galacto-sucrose]). The second composition may be a second combination in a method herein. An embodiment comprises a second mixture composition comprising the products of mixing the second composition with additional water. The additional water may adjust the 32 parts of water to 80 parts. An embodiment comprises a second solution composition comprising the products of ripening the second mixture composition.
An embodiment comprises a third composition comprising at least one of liquid dish detergent or soap and water. The summed volume of the at least one of liquid dish detergent or soap to the water volume ratio may be 0.5:80. The measure in the foregoing ratio may be cups.
An embodiment comprises a composition comprising borax (sodium tetraborate decahydrate); baking soda; linseed oil; at least one of muriatic acid, ammonia, sweetener, and mineral spirits; at least one of liquid dish detergent or soap; and water. The composition may further comprise at least one of vegetable oil, trisodium phosphate, an oxidizing agent, an abrasive, sea salt, turpentine, hydrogen peroxide, and acrylic paint. The following ratios refer to the starting volume of the listed constituent used in preparing the composition compared to the volume of water used in preparing in the composition. The volume ratio of the borax to the water may be 1-2:240, 1:240, or 2:240. The volume ratio of the baking soda to the water may be 1:240. The volume ratio of the linseed oil to the water may be 1-2:240, 1:240, or 2:240. The volume ratio of the muriatic acid to the water may be 0.5-1:240, 0.5:240, or 1:240. The volume ratio of the ammonia to the water may be 0.5-1:240, 0.5:240, or 1:240. The volume ratio of the sweetener to the water may be 3:240. The volume ratio of the mineral spirits to the water may be 1.5-2:240, 1.5:240, or 2:240. The summed volume of the at least one of liquid dish detergent or soap to the water volume ratio may be 0.5:240. The volume ratio of the vegetable oil (when present) to the water may be 2:240. The volume ratio of the trisodium phosphate (when present) to the water may be 0.5-1:240, 0.5:240, or 1:240. The volume ratio of the oxidizing agent (when present) to the water may be 0.5-1:240, 0.5:240, or 1:240. The volume ratio of the abrasive (when present) to the water may be 0.5:240. The volume ratio of the sea salt (when present) to the water may be 1:240. The volume ratio of the turpentine (when present) to the water may be 0.5:240. The volume ratio of the hydrogen peroxide to the water may be 2:240. The volume ratio of the acrylic paint to the water may be 2:240. The volume measured in the foregoing ratios may be cups. The oxidizing agent may comprise sodium percarbonate, sodium carbonate, hydrogen peroxide, and surfactants. The oxidizing agent may comprise disodium carbonate, sodium percarbonate, and C12-C15 ethoxylated alcohols. The disodium carbonate may be at 55-63.4% (w/w) in the oxidizing agent. The sodium carbonate may be at 50-60% (w/w) or 55-63.4% (w/w) in the oxidizing agent. The sodium percarbonate may be at 23.5-38.4% (w/w) in the oxidizing agent. The C12-C15 ethoxylated alcohols may be at 2.7-3.14% (w/w) in the oxidizing agent. The abrasive may comprise pumice stone. The pumice stone may be in the form of particles having mesh size in a range between and including two mesh sizes selected from 60, 120, 160, or 200. The particles may have a mesh size of 120. The abrasive may comprise Pumice Stone FF (Rainbow®). The ammonia may be a solution comprising 1-3% by weight ammonia. The ammonia may be HDX® lemon scent, which comprises ammonia at 1-3% by weight. The sweetener may be Splenda® (95% dextrose and maltodextrin (by volume) plus sucralose [4, 1, 6-trichloro-galacto-sucrose]).
An embodiment comprises a method of treating a surface. The method may comprise a step 210 of applying any surface treatment composition herein to the surface. The method may comprise a step 220 of removing the surface treatment composition from the surface. The surface treatment composition may be prepared by any method of making a surface treatment composition herein. The method may comprise a step 230 of leaving the surface treatment composition on the surface for a period of time prior to the removing. The period of time may be two to three minutes. The removing may comprise spraying off the surface treatment composition. The spraying may comprise spraying water. The removing may comprise brushing off the surface treatment composition. The brushing off may comprise brushing the surface with a brush. The brush may be a brass brush. The removing may comprise scraping off the surface treatment composition. The removing may also comprise removal of surface debris, corrosion, soil, coatings, or the like. The surface may be but is not limited to a metal, brass, steel, iron, stone, brick, or wood surface. The surface may be at least partially covered by corrosion, soil, or a coating. The corrosion may comprise oxidation products. The soil may comprise at least one of dirt, grease, animal waste products, or plant residues. The coating may comprise at least one of paint, stain, varnish, a polymeric coating, polyurethane, or lacquer.
The following listing is not limiting to embodiments otherwise described herein.
It is understood, therefore, that this invention is not limited to the particular embodiments disclosed, but is intended to cover all modifications which are within the spirit and scope of the invention as defined by the appended claims; the above description; and/or shown in the attached drawings.
This application claims priority to U.S. Provisional Application No. 63/346,037, which was filed May 26, 2022 and is incorporated herein by reference as if fully set forth.
Number | Name | Date | Kind |
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20160010037 | Wainman | Jan 2016 | A1 |
20170029743 | Wainman | Feb 2017 | A1 |
20230383217 | Choi | Nov 2023 | A1 |
Number | Date | Country |
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2005154560 | Jun 2005 | JP |
WO-2015040445 | Mar 2015 | WO |
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English Translation of JP 2005154560 A. (Year: 2005). |
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20230383217 A1 | Nov 2023 | US |
Number | Date | Country | |
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63346037 | May 2022 | US |