Metal complex compound and organic electroluminescent device using same

TECHNICAL FIELD

The present invention relates to a novel metal complex compound and an organic electroluminescence device using the compound. Particularly, the present invention relates to an organic electroluminescence device (“electroluminescence” will be referred to as “EL”, hereinafter) having excellent efficiency of light emission and prolonged lifetime, and to a metal complex compound realizing it.

BACKGROUND ART

The organic EL devices have been expected to be applied to color wide screen image display devices replacing liquid crystal display devices, and have been intensively developed. Recently, although displays using the organic EL devices have now been used in practical applications, full-color image display devices using the same are still in the course of development because they lack in sufficient light emitting property. Very high efficiency green organic light emitting devices based on electrophosphorescence employing ortho metalized iridium complex (fac-tris(2-phenylpyridine) iridium) as a phosphorus light emitting material for improving properties of the organic EL device are proposed. (refer to, for example, D. F. O'Brien and M. A. Baldo et al “Improved energy transferring electrophosphorescent devices” Applied Physics letters Vol. 74 No. 3, pp 442-444, Jan. 18, 1999; and M. A. Baldo et al “Very high-efficiency green organic light emitting devices based on electrophosphorescence” Applied Physics letters Vol. 75 No. 1, pp 4-6, Jul. 5, 1999).

Because the current organic EL devices employing the phosphorus photoluminescence are limited to emitting only green light, coverage as the color display devices is narrow. Therefore, it has been demanded to develop organic EL devices which emit light of different colors from green with improved light emission property. Regarding particularly with EL devices which emit blue light, those having an external quantum yield exceeding 5% is not reported yet. Accordingly, an improvement in the EL devices which emit blue light, if possible, enables the display devices to display full colors or white light resultantly advancing toward practical use of phosphorus light EL device greatly.

Further, although International PCT Patent Publication No. WO 02/15645 discloses following structures of ligands (A) and (B):

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wherein R₁to R₅each independently represents a hydrogen atom, a halogen atom, an alkyl group, an aromatic group and an arylene group; and R₁′ and R₂′ an aromatic group, which may bond each other;

any practical synthesis example of real complex with the use of the ligands is not described.

DISCLOSURE OF THE INVENTION

The present invention has been made to overcome the above problems and has an object of providing an organic EL device having an enhanced efficiency of light emission and prolonged lifetime, and an object of providing a metal complex compound realizing it.

As a result of intensive researches and studies to achieve the above object by the present inventors, it was found that the iridium complex proposed in the former patent literature neither generates nor isolates stably in a case where R is H in the above ligands (A) and (B) and that it is important for stably isolating the iridium complex to replace an atom on a side of N without forming a coordinate bond with a metal to an atom except a hydrogen atom. Then, the inventors designed ligands having various kinds of substituent on N, and succeeded in synthesizing iridium complex for the first time. Further, it was found that an employment of a metal complex compound having a partial structure represented by a following general formula (I) provides the EL device achieving an external quantum yield of 8% and exhibits an enhanced efficiency of light emission not only in blue region but also about various phosphorus photoluminescence and prolonged lifetime, resultantly completing the present invention.

Namely, the present invention provides a metal complex compound having a partial structure represented by a following general formula (I):

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wherein R¹to R⁵each independently represents a hydrogen atom, a cyano group, a nitro group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkylsilyl group having 1 to 20 carbon atoms, a substituted or unsubstituted acyl group having 1 to 20 carbon atoms or a substituted or unsubstituted aromatic group having 1 to 30 carbon atoms; and a couple of R¹and R², a couple of R²and R³, a couple of R³and R⁴and a couple of R⁴and R⁵may bond each other to form a ring structure;

p and q each independently represents an integer of 0 to 3; p+q being 2 or 3; further, when p is an integer of 2 or greater, plural of R³may bond each other to form a ring structure; when q is an integer of 2 or greater, plural of R⁵may bond each other to form a ring structure; and

M represents any one metal atom selected from iridium (Ir) atom, rhodium (Rh) atom, platinum (Pt) atom or palladium (Pd) atom.

Further, the present invention provides an organic EL device which comprises at least one organic thin film layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises the above metal complex compound, which emits light by applying an electric voltage between the pair of electrode.

THE PREFERRED EMBODIMENT TO CARRY OUT THE INVENTION

The present invention provides a metal complex compound having a partial structure represented by a following general formula (I):

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In the general formula (I), R¹to R⁵each independently represents a hydrogen atom, a cyano group, a nitro group atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkylsilyl group having 1 to 20 carbon atoms, a substituted or unsubstituted acyl group having 1 to 20 carbon atoms or a substituted or unsubstituted aromatic group having 1 to 30 carbon atoms; and a couple of R¹and R², a couple of R²and R³, a couple of R³and R⁴and a couple of R⁴and R⁵may bond each other to form a ring structure.

Examples of the halogen atom include fluorine atom, chlorine atom, bromine atom and iodine atom.

Examples of the alkyl group described above include methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, s-butyl group, isobutyl group, t-butyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, etc.

The alkoxy group is expressed as —OY, wherein Y represents the same as the foregoing description about the alkyl group.

Examples of the alkylsilyl group include trimethylsilyl group, t-butyldimethylsilyl group, etc.

Examples of the acyl group include acetyl group, propionyl group, butyryl group, isobutyryl group, etc.

Examples of the above aromatic group include benzene, naphthalene, anthracene, phenanthrene, pyrene, coronene, biphenyl, terphenyl, pyrrole, furan, thiophene, benzothiophene, oxadiazoline, diphenylanthracene, indoline, carbazole, pyridine, benzoquinone, fluoranthene, acenaphtho fluoranthene, etc.

Further, examples of the substituent for those groups include cyano group, hydroxyl group, nitro group, halogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted amino group, substituted or unsubstituted alkoxyl group, substituted or unsubstituted alkylsilyl group, substituted or unsubstituted acyl group, substituted or unsubstituted aromatic group, substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, substituted or unsubstituted heterocyclic group, substituted or unsubstituted arylalkyl group, a substituted or unsubstituted aryloxy group, substituted or unsubstituted alkoxycarbonyl group, carboxyl group, etc.

Examples of the ring structure formed by bonding R¹and R², R³and R⁴, or R⁴and R⁵each independently include benzene, pyridine, naphthalene, benzothiazole, quinoline, etc.

It is preferable that R¹to R⁵each independently represents a hydrogen atom, a cyano group, a nitro group, a fluorine atom, a trifluoromethyl group, a dimethylamino group, a methoxy group, a t-butyl group, a trimethylsilyl group and an acetyl group.

In the general formula (I), p and q each independently represents an integer of 0 to 3 (preferably 0 to 2); p+q being 2 or 3; further, when p is an integer of 2 or greater, plural of R³may bond each other to form a ring structure; when q is an integer of 2 or greater, plural of R⁵may bond each other to form a ring structure.

Examples of the ring structure formed by plural of R³and plural of R⁵each independently include benzene, pyridine, etc.

In the general formula (I), M represents any one metal atom selected from iridium (Ir) atom, rhodium (Rh) atom, platinum (Pt) atom or palladium (Pd) atom; while Ir and Pt are preferable and Ir is more preferable.

Further, it is preferable that the partial structure represented by general formula (I) is expressed by any one of (i) to (vii) or (i′) to (vii′) below, while (i) to (iii) being further preferable.

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Furthermore, it is preferable that the metal complex compound of the present invention has basic skeletal structure expressed by following general formulae 1 to 7 and 1′ to 7′.

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In the general formulae 1 to 7 and 1′ to 7′, T⁵to T⁹each independently represents a hydrogen atom, a cyano group, a nitro group atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkylsilyl group having 1 to 20 carbon atoms, a substituted or unsubstituted acyl group having 1 to 20 carbon atoms or a substituted or unsubstituted aromatic group having 1 to 30 carbon atom. Further, a couple of T⁵and T⁶, a couple of T⁶and T⁷, a couple of T⁷and T⁸and a couple of T⁸and T⁹may bond each other to form a ring structure.

Examples of the above halogen atom, alkyl group, alkoxyl group, alkylsilyl group, acyl group, aromatic group, these substituents, and these preferable examples are the same as explained about R¹to R⁵in the general formula (I).

Moreover, examples of the ring structure formed by bonding the couple of T⁵and T⁶, the couple of T⁶and T⁷, the couple of T⁷and T⁸and the couple of T⁸and T⁹each independently include benzene, pyridine, etc.

In the general formulae 1 to 7 and 1′ to 7′, M is the same as the forgoing description.

In the general formulae 1 to 7 and 1′ to 7′, L¹and L²are each expressed by any one of the following structures:

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In the general formulae 1 to 7 and 1′ to 7′, n represents an integer of 0 to 2, preferably 0 or 1, m represents an integer of 0 or 1.

In the general formulae 1 to 7 and 1′ to 7′, G is a group expressed by any one of groups below.

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In the above groups, a dotted line custom character represents a covalent bond with M.

T¹to T⁴in the above Ph and OL each may independently represents a hydrogen atom, a cyano group, a nitro group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkylsilyl group having 1 to 20 carbon atoms, a substituted or unsubstituted acyl group having 1 to 20 carbon atoms or a substituted or unsubstituted aromatic group having 1 to 30 carbon atom. Examples of those groups, their substituents and those preferable examples are the same as explained about R¹to R⁵in the general formula (I).

Further, examples of the substituent forming the ring structure by bonding the couple of T¹and T², the couple of T²and T³or the couple of T³and T⁴in the Ph include a divalent group expressed by any one of groups below, while BL, MES1, MES2, PS1 and PS2 being preferable.

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However, the group with a smaller number of superscript among T¹to T⁴bonds to the left of the divalent group and the group with a greater number superscript among T¹to T⁴bonds to the right of the divalent group.

Specific examples of the metal complex compound having any one basic skeletal structure among the general formulae 1′ to 7′ will be shown in Tables below, though not limited thereto.

In the Tables below, T¹to T⁹, L¹and L²(in the cases of the basic skeletal structures 1 to 4 and 1′ to 4′) or T¹to T⁷, L¹and L²(in the cases of the basic skeletal structures 5 to 7 and 5′ to 7′) are described within the columns righter to the basic skeletal structures.

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Further in the Tables below, “BBS” means Basic Skeletal Structure, and “BS” means Skeletal Structure.

TABLE 1

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1-1
Ir
1
1
Ph
H
H
H
H
H
H
H
H
H
pic

1-1X
Ir
1
1
Ph
H
H
H
H
H
H
H
H
H
acac

1-1Y
Ir
0
1
Ph
H
H
H
H
H
H
H
H
H
—
—

1-2
Ir
1
1
Ph
H
F
H
F
H
H
H
H
H
pic

1-2X
Ir
1
1
Ph
H
F
H
F
H
H
H
H
H
acac

1-2Y
Ir
0
1
Ph
H
F
H
F
H
H
H
H
H
—
—

1-3
Ir
1
1
Ph
F
H
H
F
H
H
H
H
H
pic

1-3X
Ir
1
1
Ph
F
H
H
F
H
H
H
H
H
acac

1-3Y
Ir
0
1
Ph
F
H
H
F
H
H
H
H
H
—
—

1-4
Ir
1
1
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

1-4X
Ir
1
1
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

1-4Y
Ir
0
1
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

1-5
Ir
1
1
Ph
H
F
CF₃
H
H
H
H
H
H
pic

1-5X
Ir
1
1
Ph
H
F
CF₃
H
H
H
H
H
H
acac

1-5Y
Ir
0
1
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

1-6
Ir
1
1
Ph
F
H
CF₃
H
H
H
H
H
H
pic

1-6X
Ir
1
1
Ph
F
H
CF₃
H
H
H
H
H
H
acac

1-6Y
Ir
0
1
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

1-7
Ir
1
1
Ph
F
F
F
F
H
H
H
H
H
pic

1-7X
Ir
1
1
Ph
F
F
F
F
H
H
H
H
H
acac

1-7Y
Ir
0
1
Ph
F
F
F
F
H
H
H
H
H
—
—

1-8
Ir
1
1
Ph
H
F
H
CH₃
H
H
H
H
H
pic

1-8X
Ir
1
1
Ph
H
F
H
CH₃
H
H
H
H
H
acac

1-8Y
Ir
0
1
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

1-9
Ir
1
1
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

1-9X
Ir
1
1
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

1-9Y
Ir
0
1
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

1-10
Ir
1
1
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

1-10X
Ir
1
1
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

1-10Y
Ir
0
1
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

1-11
Ir
1
1
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

1-11X
Ir
1
1
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

1-11Y
Ir
0
1
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

1-12
Ir
1
1
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

1-12X
Ir
1
1
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

1-12Y
Ir
0
1
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

1-13
Ir
1
1
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

1-13X
Ir
1
1
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

1-13Y
Ir
0
1
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

1-14
Ir
1
1
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

1-14X
Ir
1
1
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

1-14Y
Ir
0
1
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

1-15
Ir
1
1
Ph
H
H
NO₂
H
H
H
H
H
H
pic

1-15X
Ir
1
1
Ph
H
H
NO₂
H
H
H
H
H
H
acac

1-15Y
Ir
0
1
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

1-16
Ir
1
1
Ph
F
H
NO₂
H
H
H
H
H
H
pic

1-16X
Ir
1
1
Ph
F
H
NO₂
H
H
H
H
H
H
acac

1-16Y
Ir
0
1
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

1-17
Ir
1
1
Ph
F
H
NO₂
F
H
H
H
H
H
pic

1-17X
Ir
1
1
Ph
F
H
NO₂
F
H
H
H
H
H
acac

1-17Y
Ir
0
1
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

1-18
Ir
1
1
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

1-18X
Ir
1
1
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

1-18Y
Ir
0
1
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

1-19
Ir
1
1
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

1-19X
Ir
1
1
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

1-19Y
Ir
0
1
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

1-20
Ir
1
1
Ph
H
H
CF₃
H
H
H
H
H
H
pic

1-20X
Ir
1
1
Ph
H
H
CF₃
H
H
H
H
H
H
acac

1-20Y
Ir
0
1
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

1-21
Ir
1
1
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

1-21X
Ir
1
1
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

1-21Y
Ir
0
1
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

1-22
Ir
1
1
Ph
H
NO₂
H
H
H
H
H
H
H
pic

1-22X
Ir
1
1
Ph
H
NO₂
H
H
H
H
H
H
H
acac

1-22Y
Ir
0
1
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

1-23
Ir
1
1
Ph
H
CF₃
H
H
H
H
H
H
H
pic

1-23X
Ir
1
1
Ph
H
CF₃
H
H
H
H
H
H
H
acac

1-23Y
Ir
0
1
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

1-24
Ir
1
1
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

1-24X
Ir
1
1
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

1-24Y
Ir
0
1
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

1-25
Ir
1
1
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

1-25X
Ir
1
1
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

1-25Y
Ir
0
1
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

1-26
Ir
1
1
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

1-26X
Ir
1
1
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

1-26Y
Ir
0
1
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

1-27
Ir
1
1
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

1-27X
Ir
1
1
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

1-27Y
Ir
0
1
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

1-28
Ir
1
1
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

1-28X
Ir
1
1
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

1-28Y
Ir
0
1
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

1-29
Ir
1
1
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

1-29X
Ir
1
1
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

1-29Y
Ir
0
1
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

1-30
Ir
1
1
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

1-30X
Ir
1
1
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

1-30Y
Ir
0
1
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

1-31
Ir
1
1
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

1-31X
Ir
1
1
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

1-31Y
Ir
0
1
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

1-32
Ir
1
1
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

1-32X
Ir
1
1
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

1-32Y
Ir
0
1
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

1-33
Ir
1
1
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

1-33X
Ir
1
1
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

1-33Y
Ir
0
1
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

1-34
Ir
1
1
Ph
H
F
H
F
H
CH₃
H
H
H
pic

1-34X
Ir
1
1
Ph
H
F
H
F
H
CH₃
H
H
H
acac

1-34Y
Ir
0
1
Ph
H
F
H
F
H
CH₃
H
H
H
—
—

1-35
Ir
1
1
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
pic

1-35X
Ir
1
1
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
acac

1-35Y
Ir
0
1
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
—
—

1-36
Ir
1
1
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

1-36X
Ir
1
1
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

1-36Y
Ir
0
1
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

1-37
Ir
1
1
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1-37X
Ir
1
1
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1-37Y
Ir
0
1
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1-38
Ir
1
1
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

1-38X
Ir
1
1
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

1-38Y
Ir
0
1
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

1-39
Ir
1
1
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

1-39X
Ir
1
1
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

1-39Y
Ir
0
1
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

1-40
Ir
1
1
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

1-40X
Ir
1
1
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

1-40Y
Ir
0
1
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

1-41
Ir
1
1
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

1-41X
Ir
1
1
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

1-41Y
Ir
0
1
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

1-42
Ir
1
1
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

1-42X
Ir
1
1
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

1-42Y
Ir
0
1
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

1-43
Ir
1
1
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1-43X
Ir
1
1
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1-43Y
Ir
0
1
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1-44
Ir
1
1
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

1-44X
Ir
1
1
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

1-44Y
Ir
0
1
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

1-45
Ir
1
1
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

1-45X
Ir
1
1
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

1-45Y
Ir
0
1
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

1-46
Ir
1
1
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

1-46X
Ir
1
1
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

1-46Y
Ir
0
1
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

1-47
Ir
1
1
Ph
H
H
BL
H
H
H
H
H
pic

1-47X
Ir
1
1
Ph
H
H
BL
H
H
H
H
H
acac

1-47Y
Ir
0
1
Ph
H
H
BL
H
H
H
H
H
—
—

1-48
Ir
1
1
Ph
H
BL
H
H
H
H
H
H
pic

1-48X
Ir
1
1
Ph
H
BL
H
H
H
H
H
H
acac

1-48Y
Ir
0
1
Ph
H
BL
H
H
H
H
H
H
—
—

1-49
Ir
1
1
Ph
H
H
PL
H
H
H
H
H
pic

1-49X
Ir
1
1
Ph
H
H
PL
H
H
H
H
H
acac

1-49Y
Ir
0
1
Ph
H
H
PL
H
H
H
H
H
—
—

1-50
Ir
1
1
Ph
H
PL
H
H
H
H
H
H
pic

1-50X
Ir
1
1
Ph
H
PL
H
H
H
H
H
H
acac

1-50Y
Ir
0
1
Ph
H
PL
H
H
H
H
H
H
—
—

1-51
Ir
1
1
Ph
H
H
MEE1
H
H
H
H
H
pic

1-51X
Ir
1
1
Ph
H
H
MEE1
H
H
H
H
H
acac

1-51Y
Ir
0
1
Ph
H
H
MEE1
H
H
H
H
H
—
—

1-52
Ir
1
1
Ph
H
MEE1
H
H
H
H
H
H
pic

1-52X
Ir
1
1
Ph
H
MEE1
H
H
H
H
H
H
acac

1-52Y
Ir
0
1
Ph
H
MEE1
H
H
H
H
H
H
—
—

1-53
Ir
1
1
Ph
H
H
MEE2
H
H
H
H
H
pic

1-53X
Ir
1
1
Ph
H
H
MEE2
H
H
H
H
H
acac

1-53Y
Ir
0
1
Ph
H
H
MEE2
H
H
H
H
H
—
—

1-54
Ir
1
1
Ph
H
MEE2
H
H
H
H
H
H
pic

1-54X
Ir
1
1
Ph
H
MEE2
H
H
H
H
H
H
acac

1-54Y
Ir
0
1
Ph
H
MEE2
H
H
H
H
H
H
—
—

1-55
Ir
1
1
Ph
H
H
PA1
H
H
H
H
H
pic

1-55X
Ir
1
1
Ph
H
H
PA1
H
H
H
H
H
acac

1-55Y
Ir
0
1
Ph
H
H
PA1
H
H
H
H
H
—
—

1-56
Ir
1
1
Ph
H
PA1
H
H
H
H
H
H
pic

1-56X
Ir
1
1
Ph
H
PA1
H
H
H
H
H
H
acac

1-56Y
Ir
0
1
Ph
H
PA1
H
H
H
H
H
H
—
—

1-57
Ir
1
1
Ph
H
H
PA2
H
H
H
H
H
pic

1-57X
Ir
1
1
Ph
H
H
PA2
H
H
H
H
H
acac

1-57Y
Ir
0
1
Ph
H
H
PA2
H
H
H
H
H
—
—

1-58
Ir
1
1
Ph
H
PA2
H
H
H
H
H
H
pic

1-58X
Ir
1
1
Ph
H
PA2
H
H
H
H
H
H
acac

1-58Y
Ir
0
1
Ph
H
PA2
H
H
H
H
H
H
—
—

1-59
Ir
1
1
Ph
H
H
EA1
H
H
H
H
H
pic

1-59X
Ir
1
1
Ph
H
H
EA1
H
H
H
H
H
acac

1-59Y
Ir
0
1
Ph
H
H
EA1
H
H
H
H
H
—
—

1-60
Ir
1
1
Ph
H
EA2
H
H
H
H
H
H
pic

1-60X
Ir
1
1
Ph
H
EA2
H
H
H
H
H
H
acac

1-60Y
Ir
0
1
Ph
H
EA2
H
H
H
H
H
H
—
—

1-61
Ir
1
1
Ph
H
H
ME
H
H
H
H
H
pic

1-61X
Ir
1
1
Ph
H
H
ME
H
H
H
H
H
acac

1-61Y
Ir
0
1
Ph
H
H
ME
H
H
H
H
H
—
—

1-62
Ir
1
1
Ph
H
ME
H
H
H
H
H
H
pic

1-62X
Ir
1
1
Ph
H
ME
H
H
H
H
H
H
acac

1-62Y
Ir
0
1
Ph
H
ME
H
H
H
H
H
H
—
—

1-63
Ir
1
1
Ph
H
H
AT
H
H
H
H
H
pic

1-63X
Ir
1
1
Ph
H
H
AT
H
H
H
H
H
acac

1-63Y
Ir
0
1
Ph
H
H
AT
H
H
H
H
H
—
—

1-64
Ir
1
1
Ph
H
AT
H
H
H
H
H
H
pic

1-64X
Ir
1
1
Ph
H
AT
H
H
H
H
H
H
acac

1-64Y
Ir
0
1
Ph
H
AT
H
H
H
H
H
H
—
—

1-65
Ir
1
1
Ph
H
H
MES1
H
H
H
H
H
pic

1-65X
Ir
1
1
Ph
H
H
MES1
H
H
H
H
H
acac

1-65Y
Ir
0
1
Ph
H
H
MES1
H
H
H
H
H
—
—

1-66
Ir
1
1
Ph
H
MES1
H
H
H
H
H
H
pic

1-66X
Ir
1
1
Ph
H
MES1
H
H
H
H
H
H
acac

1-66Y
Ir
0
1
Ph
H
MES1
H
H
H
H
H
H
—
—

1-67
Ir
1
1
Ph
H
H
MES2
H
H
H
H
H
pic

1-67X
Ir
1
1
Ph
H
H
MES2
H
H
H
H
H
acac

1-67Y
Ir
0
1
Ph
H
H
MES2
H
H
H
H
H
—
—

1-68
Ir
1
1
Ph
H
MES2
H
H
H
H
H
H
pic

1-68X
Ir
1
1
Ph
H
MES2
H
H
H
H
H
H
acac

1-68Y
Ir
0
1
Ph
H
MES2
H
H
H
H
H
H
—
—

1-69
Ir
1
1
Ph
H
H
PS1
H
H
H
H
H
pic

1-69X
Ir
1
1
Ph
H
H
PS1
H
H
H
H
H
acac

1-69Y
Ir
0
1
Ph
H
H
PS1
H
H
H
H
H
—
—

1-70
Ir
1
1
Ph
H
PS1
H
H
H
H
H
H
pic

1-70X
Ir
1
1
Ph
H
PS1
H
H
H
H
H
H
acac

1-70Y
Ir
0
1
Ph
H
PS1
H
H
H
H
H
H
—
—

1-71
Ir
1
1
Ph
H
H
PS2
H
H
H
H
H
pic

1-71X
Ir
1
1
Ph
H
H
PS2
H
H
H
H
H
acac

1-71Y
Ir
0
1
Ph
H
H
PS2
H
H
H
H
H
—
—

1-72
Ir
1
1
Ph
H
PS2
H
H
H
H
H
H
pic

1-72X
Ir
1
1
Ph
H
PS2
H
H
H
H
H
H
acac

1-72Y
Ir
0
1
Ph
H
PS2
H
H
H
H
H
H
—
—

1-73
Ir
1
1
Ph
H
H
BAL1
H
H
H
H
H
pic

1-73X
Ir
1
1
Ph
H
H
BAL1
H
H
H
H
H
acac

1-73Y
Ir
0
1
Ph
H
H
BAL1
H
H
H
H
H
—
—

1-74
Ir
1
1
Ph
H
BAL1
H
H
H
H
H
H
pic

1-74X
Ir
1
1
Ph
H
BAL1
H
H
H
H
H
H
acac

1-74Y
Ir
0
1
Ph
H
BAL1
H
H
H
H
H
H
—
—

1-75
Ir
1
1
Ph
H
H
BAL2
H
H
H
H
H
pic

1-75X
Ir
1
1
Ph
H
H
BAL2
H
H
H
H
H
acac

1-75Y
Ir
0
1
Ph
H
H
BAL2
H
H
H
H
H
—
—

1-76
Ir
1
1
Ph
H
BAL2
H
H
H
H
H
H
pic

1-76X
Ir
1
1
Ph
H
BAL2
H
H
H
H
H
H
acac

1-76Y
Ir
0
1
Ph
H
BAL2
H
H
H
H
H
H
—
—

1-77
Ir
1
1
Ph
H
H
MEK1
H
H
H
H
H
pic

1-77X
Ir
1
1
Ph
H
H
MEK1
H
H
H
H
H
acac

1-77Y
Ir
0
1
Ph
H
H
MEK1
H
H
H
H
H
—
—

1-78
Ir
1
1
Ph
H
MEK1
H
H
H
H
H
H
pic

1-78X
Ir
1
1
Ph
H
MEK1
H
H
H
H
H
H
acac

1-78Y
Ir
0
1
Ph
H
MEK1
H
H
H
H
H
H
—
—

1-79
Ir
1
1
Ph
H
H
MEK2
H
H
H
H
H
pic

1-79X
Ir
1
1
Ph
H
H
MEK2
H
H
H
H
H
acac

1-79Y
Ir
0
1
Ph
H
H
MEK2
H
H
H
H
H
—
—

1-80
Ir
1
1
Ph
H
MEK2
H
H
H
H
H
H
pic

1-80X
Ir
1
1
Ph
H
MEK2
H
H
H
H
H
H
acac

1-80Y
Ir
0
1
Ph
H
MEK2
H
H
H
H
H
H
—
—

1-81
Ir
1
1
Ph
H
H
PAL1
H
H
H
H
H
pic

1-81X
Ir
1
1
Ph
H
H
PAL1
H
H
H
H
H
acac

1-81Y
Ir
0
1
Ph
H
H
PAL1
H
H
H
H
H
—
—

1-82
Ir
1
1
Ph
H
PAL1
H
H
H
H
H
H
pic

1-82X
Ir
1
1
Ph
H
PAL1
H
H
H
H
H
H
acac

1-82Y
Ir
0
1
Ph
H
PAL1
H
H
H
H
H
H
—
—

1-83
Ir
1
1
Ph
H
H
PAL2
H
H
H
H
H
pic

1-83X
Ir
1
1
Ph
H
H
PAL2
H
H
H
H
H
acac

1-83Y
Ir
0
1
Ph
H
H
PAL2
H
H
H
H
H
—
—

1-84
Ir
1
1
Ph
H
PAL2
H
H
H
H
H
H
pic

1-84X
Ir
1
1
Ph
H
PAL2
H
H
H
H
H
H
acac

1-84Y
Ir
0
1
Ph
H
PAL2
H
H
H
H
H
H
—
—

1-85
Ir
1
1
Ph
H
H
MMK
H
H
H
H
H
pic

1-85X
Ir
1
1
Ph
H
H
MMK
H
H
H
H
H
acac

1-85Y
Ir
0
1
Ph
H
H
MMK
H
H
H
H
H
—
—

1-86
Ir
1
1
Ph
H
MMK
H
H
H
H
H
H
pic

1-86X
Ir
1
1
Ph
H
MMK
H
H
H
H
H
H
acac

1-86Y
Ir
0
1
Ph
H
MMK
H
H
H
H
H
H
—
—

1-87
Ir
1
1
Ph
H
H
EES1
H
H
H
H
H
pic

1-87X
Ir
1
1
Ph
H
H
EES1
H
H
H
H
H
acac

1-87Y
Ir
0
1
Ph
H
H
EES1
H
H
H
H
H
—
—

1-88
Ir
1
1
Ph
H
EES2
H
H
H
H
H
H
pic

1-88X
Ir
1
1
Ph
H
EES2
H
H
H
H
H
H
acac

1-88Y
Ir
0
1
Ph
H
EES2
H
H
H
H
H
H
—
—

1-89
Ir
1
1
Ph
H
H
PAE1
H
H
H
H
H
pic

1-89X
Ir
1
1
Ph
H
H
PAE1
H
H
H
H
H
acac

1-89Y
Ir
0
1
Ph
H
H
PAE1
H
H
H
H
H
—
—

1-90
Ir
1
1
Ph
H
PAE2
H
H
H
H
H
H
pic

1-90X
Ir
1
1
Ph
H
PAE2
H
H
H
H
H
H
acac

1-90Y
Ir
0
1
Ph
H
PAE2
H
H
H
H
H
H
—
—

1-91
Ir
1
1
Ph
H
H
AME1
H
H
H
H
H
pic

1-91X
Ir
1
1
Ph
H
H
AME1
H
H
H
H
H
acac

1-91Y
Ir
0
1
Ph
H
H
AME1
H
H
H
H
H
—
—

1-92
Ir
1
1
Ph
H
AME1
H
H
H
H
H
H
pic

1-92X
Ir
1
1
Ph
H
AME1
H
H
H
H
H
H
acac

1-92Y
Ir
0
1
Ph
H
AME1
H
H
H
H
H
H
—
—

1-93
Ir
1
1
Ph
H
H
AME2
H
H
H
H
H
pic

1-93X
Ir
1
1
Ph
H
H
AME2
H
H
H
H
H
acac

1-93Y
Ir
0
1
Ph
H
H
AME2
H
H
H
H
H
—
—

1-94
Ir
1
1
Ph
H
AME2
H
H
H
H
H
H
pic

1-94X
Ir
1
1
Ph
H
AME2
H
H
H
H
H
H
acac

1-94Y
Ir
0
1
Ph
H
AME2
H
H
H
H
H
H
—
—

1-95
Ir
1
1
Ph
H
H
EAE1
H
H
H
H
H
pic

1-95X
Ir
1
1
Ph
H
H
EAE1
H
H
H
H
H
acac

1-95Y
Ir
0
1
Ph
H
H
EAE1
H
H
H
H
H
—
—

1-96
Ir
1
1
Ph
H
EAE1
H
H
H
H
H
H
pic

1-96X
Ir
1
1
Ph
H
EAE1
H
H
H
H
H
H
acac

1-96Y
Ir
0
1
Ph
H
EAE1
H
H
H
H
H
H
—
—

1-97
Ir
1
1
Ph
H
H
EAE2
H
H
H
H
H
pic

1-97X
Ir
1
1
Ph
H
H
EAE2
H
H
H
H
H
acac

1-97Y
Ir
0
1
Ph
H
H
EAE2
H
H
H
H
H
—
—

1-98
Ir
1
1
Ph
H
EAE2
H
H
H
H
H
H
pic

1-98X
Ir
1
1
Ph
H
EAE2
H
H
H
H
H
H
acac

1-98Y
Ir
0
1
Ph
H
EAE2
H
H
H
H
H
H
—
—

1-99
Ir
1
1
Ph
H
H
AAE1
H
H
H
H
H
pic

1-99X
Ir
1
1
Ph
H
H
AAE1
H
H
H
H
H
acac

1-99Y
Ir
0
1
Ph
H
H
AAE1
H
H
H
H
H
—
—

1-100
Ir
1
1
Ph
H
AAE1
H
H
H
H
H
H
pic

1-100X
Ir
1
1
Ph
H
AAE1
H
H
H
H
H
H
acac

1-100Y
Ir
0
1
Ph
H
AAE1
H
H
H
H
H
H
—
—

1-101
Ir
1
1
Ph
H
H
AAE2
H
H
H
H
H
pic

1-101X
Ir
1
1
Ph
H
H
AAE2
H
H
H
H
H
acac

1-101Y
Ir
0
1
Ph
H
H
AAE2
H
H
H
H
H
—
—

1-102
Ir
1
1
Ph
H
AAE2
H
H
H
H
H
H
pic

1-102X
Ir
1
1
Ph
H
AAE2
H
H
H
H
H
H
acac

1-102Y
Ir
0
1
Ph
H
AAE2
H
H
H
H
H
H
—
—

1-103
Ir
1
1
Ph
H
H
PME1
H
H
H
H
H
pic

1-103X
Ir
1
1
Ph
H
H
PME1
H
H
H
H
H
acac

1-103Y
Ir
0
1
Ph
H
H
PME1
H
H
H
H
H
—
—

1-104
Ir
1
1
Ph
H
PME1
H
H
H
H
H
H
pic

1-104X
Ir
1
1
Ph
H
PME1
H
H
H
H
H
H
acac

1-104Y
Ir
0
1
Ph
H
PME1
H
H
H
H
H
H
—
—

1-105
Ir
1
1
Ph
H
H
PME2
H
H
H
H
H
pic

1-105X
Ir
1
1
Ph
H
H
PME2
H
H
H
H
H
acac

1-105Y
Ir
0
1
Ph
H
H
PME2
H
H
H
H
H
—
—

1-106
Ir
1
1
Ph
H
PME2
H
H
H
H
H
H
pic

1-106X
Ir
1
1
Ph
H
PME2
H
H
H
H
H
H
acac

1-106Y
Ir
0
1
Ph
H
PME2
H
H
H
H
H
H
—
—

1-107
Ir
1
1
Ph
H
H
MET1
H
H
H
H
H
pic

1-107X
Ir
1
1
Ph
H
H
MET1
H
H
H
H
H
acac

1-107Y
Ir
0
1
Ph
H
H
MET1
H
H
H
H
H
—
—

1-108
Ir
1
1
Ph
H
MET1
H
H
H
H
H
H
pic

1-108X
Ir
1
1
Ph
H
MET1
H
H
H
H
H
H
acac

1-108Y
Ir
0
1
Ph
H
MET1
H
H
H
H
H
H
—
—

1-109
Ir
1
1
Ph
H
H
MET2
H
H
H
H
H
pic

1-109X
Ir
1
1
Ph
H
H
MET2
H
H
H
H
H
acac

1-109Y
Ir
0
1
Ph
H
H
MET2
H
H
H
H
H
—
—

1-110
Ir
1
1
Ph
H
MET2
H
H
H
H
H
H
pic

1-110X
Ir
1
1
Ph
H
MET2
H
H
H
H
H
H
acac

1-110Y
Ir
0
1
Ph
H
MET2
H
H
H
H
H
H
—
—

1-111
Ir
1
1
Ph
H
H
EE1
H
H
H
H
H
pic

1-111X
Ir
1
1
Ph
H
H
EE1
H
H
H
H
H
acac

1-111Y
Ir
0
1
Ph
H
H
EE1
H
H
H
H
H
—
—

1-112
Ir
1
1
Ph
H
EE1
H
H
H
H
H
H
pic

1-112X
Ir
1
1
Ph
H
EE1
H
H
H
H
H
H
acac

1-112Y
Ir
0
1
Ph
H
EE1
H
H
H
H
H
H
—
—

1-113
Ir
1
1
Ph
H
H
EE2
H
H
H
H
H
pic

1-113X
Ir
1
1
Ph
H
H
EE2
H
H
H
H
H
acac

1-113Y
Ir
0
1
Ph
H
H
EE2
H
H
H
H
H
—
—

1-114
Ir
1
1
Ph
H
EE2
H
H
H
H
H
H
pic

1-114X
Ir
1
1
Ph
H
EE2
H
H
H
H
H
H
acac

1-114Y
Ir
0
1
Ph
H
EE2
H
H
H
H
H
H
—
—

1-115
Ir
1
1
Ph
H
H
MS1
H
H
H
H
H
pic

1-115X
Ir
1
1
Ph
H
H
MS1
H
H
H
H
H
acac

1-115Y
Ir
0
1
Ph
H
H
MS1
H
H
H
H
H
—
—

1-116
Ir
1
1
Ph
H
MS1
H
H
H
H
H
H
pic

1-116X
Ir
1
1
Ph
H
MS1
H
H
H
H
H
H
acac

1-116Y
Ir
0
1
Ph
H
MS1
H
H
H
H
H
H
—
—

1-117
Ir
1
1
Ph
H
H
MS2
H
H
H
H
H
pic

1-117X
Ir
1
1
Ph
H
H
MS2
H
H
H
H
H
acac

1-117Y
Ir
0
1
Ph
H
H
MS2
H
H
H
H
H
—
—

1-118
Ir
1
1
Ph
H
MS2
H
H
H
H
H
H
pic

1-118X
Ir
1
1
Ph
H
MS2
H
H
H
H
H
H
acac

1-118Y
Ir
0
1
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 2

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2-1
Ir
1
2
Ph
H
H
H
H
H
H
H
H
H
pic

2-1X
Ir
1
2
Ph
H
H
H
H
H
H
H
H
H
acac

2-1Y
Ir
0
2
Ph
H
H
H
H
H
H
H
H
H
—
—

2-2
Ir
1
2
Ph
H
F
H
F
H
H
H
H
H
pic

2-2X
Ir
1
2
Ph
H
F
H
F
H
H
H
H
H
acac

2-2Y
Ir
0
2
Ph
H
F
H
F
H
H
H
H
H
—
—

2-3
Ir
1
2
Ph
F
H
H
F
H
H
H
H
H
pic

2-3X
Ir
1
2
Ph
F
H
H
F
H
H
H
H
H
acac

2-3Y
Ir
0
2
Ph
F
H
H
F
H
H
H
H
H
—
—

2-4
Ir
1
2
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

2-4X
Ir
1
2
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

2-4Y
Ir
0
2
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

2-5
Ir
1
2
Ph
H
F
CF₃
H
H
H
H
H
H
pic

2-5X
Ir
1
2
Ph
H
F
CF₃
H
H
H
H
H
H
acac

2-5Y
Ir
0
2
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

2-6
Ir
1
2
Ph
F
H
CF₃
H
H
H
H
H
H
pic

2-6X
Ir
1
2
Ph
F
H
CF₃
H
H
H
H
H
H
acac

2-6Y
Ir
0
2
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

2-7
Ir
1
2
Ph
F
F
F
F
H
H
H
H
H
pic

2-7X
Ir
1
2
Ph
F
F
F
F
H
H
H
H
H
acac

2-7Y
Ir
0
2
Ph
F
F
F
F
H
H
H
H
H
—
—

2-8
Ir
1
2
Ph
H
F
H
CH₃
H
H
H
H

pic

2-8X
Ir
1
2
Ph
H
F
H
CH₃
H
H
H
H
H
acac

2-8Y
Ir
0
2
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

2-9
Ir
1
2
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

2-9X
Ir
1
2
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

2-9Y
Ir
0
2
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

2-10
Ir
1
2
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

2-10X
Ir
1
2
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

2-10Y
Ir
0
2
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

2-11
Ir
1
2
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

2-11X
Ir
1
2
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

2-11Y
Ir
1
2
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

2-12
Ir
1
2
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

2-12X
Ir
1
2
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

2-12Y
Ir
0
2
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

2-13
Ir
1
2
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

2-13X
Ir
1
2
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

2-13Y
Ir
0
2
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

2-14
Ir
1
2
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

2-14X
Ir
1
2
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

2-14Y
Ir
0
2
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

2-15
Ir
1
2
Ph
H
H
NO₂
H
H
H
H
H
H
pic

2-15X
Ir
1
2
Ph
H
H
NO₂
H
H
H
H
H
H
acac

2-15Y
Ir
0
2
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

2-16
Ir
1
2
Ph
F
H
NO₂
H
H
H
H
H
H
pic

2-16X
Ir
1
2
Ph
F
H
NO₂
H
H
H
H
H
H
acac

2-16Y
Ir
0
2
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

2-17
Ir
1
2
Ph
F
H
NO₂
F
H
H
H
H
H
pic

2-17X
Ir
1
2
Ph
F
H
NO₂
F
H
H
H
H
H
acac

2-17Y
Ir
0
2
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

2-18
Ir
1
2
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

2-18X
Ir
1
2
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

2-18Y
Ir
0
2
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

2-19
Ir
1
2
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

2-19X
Ir
1
2
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

2-19Y
Ir
0
2
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

2-20
Ir
1
2
Ph
H
H
CF₃
H
H
H
H
H
H
pic

2-20X
Ir
1
2
Ph
H
H
CF₃
H
H
H
H
H
H
acac

2-20Y
Ir
0
2
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

2-21
Ir
1
2
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

2-21X
Ir
1
2
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

2-21Y
Ir
0
2
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

2-22
Ir
1
2
Ph
H
NO₂
H
H
H
H
H
H
H
pic

2-22X
Ir
1
2
Ph
H
NO₂
H
H
H
H
H
H
H
acac

2-22Y
Ir
0
2
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

2-23
Ir
1
2
Ph
H
CF₃
H
H
H
H
H
H
H
pic

2-23X
Ir
1
2
Ph
H
CF₃
H
H
H
H
H
H
H
acac

2-23Y
Ir
0
2
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

2-24
Ir
1
2
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

2-24X
Ir
1
2
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

2-24Y
Ir
0
2
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

2-25
Ir
1
2
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

2-25X
Ir
1
2
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

2-25Y
Ir
0
2
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

2-26
Ir
1
2
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

2-26X
Ir
1
2
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

2-26Y
Ir
0
2
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

2-27
Ir
1
2
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

2-27X
Ir
1
2
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

2-27Y
Ir
0
2
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

2-28
Ir
1
2
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

2-28X
Ir
1
2
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

2-28Y
Ir
0
2
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

2-29
Ir
1
2
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

2-29X
Ir
1
2
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

2-29Y
Ir
0
2
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

2-30
Ir
1
2
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

2-30X
Ir
1
2
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

2-30Y
Ir
0
2
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

2-31
Ir
1
2
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

2-31X
Ir
1
2
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

2-31Y
Ir
0
2
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

2-32
Ir
1
2
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

2-32X
Ir
1
2
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

2-32Y
Ir
0
2
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

2-33
Ir
1
2
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

2-33X
Ir
1
2
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

2-33Y
Ir
0
2
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

2-34
Ir
1
2
Ph
H
F
H
F
H
H
H
CH₃
H
pic

2-34X
Ir
1
2
Ph
H
F
H
F
H
H
H
CH₃
H
acac

2-34Y
Ir
0
2
Ph
H
F
H
F
H
H
H
CH₃
H
—
—

2-35
Ir
1
2
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
pic

2-35X
Ir
1
2
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
acac

2-35Y
Ir
0
2
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
—
—

2-36
Ir
1
2
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

2-36X
Ir
1
2
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

2-36Y
Ir
0
2
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

2-37
Ir
1
2
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2-37X
Ir
1
2
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

2-37Y
Ir
0
2
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2-38
Ir
1
2
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

2-38X
Ir
1
2
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

2-38Y
Ir
0
2
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

2-39
Ir
1
2
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

2-39X
Ir
1
2
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

2-39Y
Ir
0
2
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

2-40
Ir
1
2
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

2-40X
Ir
1
2
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

2-40Y
Ir
0
2
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

2-41
Ir
1
2
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

2-41X
Ir
1
2
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

2-41Y
Ir
0
2
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

2-42
Ir
1
2
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

2-42X
Ir
1
2
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

2-42Y
Ir
0
2
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

2-43
Ir
1
2
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2-43X
Ir
1
2
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

2-43Y
Ir
0
2
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2-44
Ir
1
2
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

2-44X
Ir
1
2
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

2-44Y
Ir
0
2
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

2-45
Ir
1
2
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

2-45X
Ir
1
2
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

2-45Y
Ir
0
2
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

2-46
Ir
1
2
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

2-46X
Ir
1
2
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

2-46Y
Ir
0
2
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

2-47
Ir
1
2
Ph
H
H
BL
H
H
H
H
H
pic

2-47X
Ir
1
2
Ph
H
H
BL
H
H
H
H
H
acac

2-47Y
Ir
0
2
Ph
H
H
BL
H
H
H
H
H
—
—

2-48
Ir
1
2
Ph
H
BL
H
H
H
H
H
H
pic

2-48X
Ir
1
2
Ph
H
BL
H
H
H
H
H
H
acac

2-48Y
Ir
0
2
Ph
H
BL
H
H
H
H
H
H
—
—

2-49
Ir
1
2
Ph
H
H
PL
H
H
H
H
H
pic

2-49X
Ir
1
2
Ph
H
H
PL
H
H
H
H
H
acac

2-49Y
Ir
0
2
Ph
H
H
PL
H
H
H
H
H
—
—

2-50
Ir
1
2
Ph
H
PL
H
H
H
H
H
H
pic

2-50X
Ir
1
2
Ph
H
PL
H
H
H
H
H
H
acac

2-50Y
Ir
0
2
Ph
H
PL
H
H
H
H
H
H
—
—

2-51
Ir
1
2
Ph
H
H
MEE1
H
H
H
H
H
pic

2-51X
Ir
1
2
Ph
H
H
MEE1
H
H
H
H
H
acac

2-51Y
Ir
0
2
Ph
H
H
MEE1
H
H
H
H
H
—
—

2-52
Ir
1
2
Ph
H
MEE1
H
H
H
H
H
H
pic

2-52X
Ir
1
2
Ph
H
MEE1
H
H
H
H
H
H
acac

2-52Y
Ir
0
2
Ph
H
MEE1
H
H
H
H
H
H
—
—

2-53
Ir
1
2
Ph
H
H
MEE2
H
H
H
H
H
pic

2-53X
Ir
1
2
Ph
H
H
MEE2
H
H
H
H
H
acac

2-53Y
Ir
0
2
Ph
H
H
MEE2
H
H
H
H
H
—
—

2-54
Ir
1
2
Ph
H
MEE2
H
H
H
H
H
H
pic

2-54X
Ir
1
2
Ph
H
MEE2
H
H
H
H
H
H
acac

2-54Y
Ir
0
2
Ph
H
MEE2
H
H
H
H
H
H
—
—

2-55
Ir
1
2
Ph
H
H
PA1
H
H
H
H
H
pic

2-55X
Ir
1
2
Ph
H
H
PA1
H
H
H
H
H
acac

2-55Y
Ir
0
2
Ph
H
H
PA1
H
H
H
H
H
—
—

2-56
Ir
1
2
Ph
H
PA1
H
H
H
H
H
H
pic

2-56X
Ir
1
2
Ph
H
PA1
H
H
H
H
H
H
acac

2-56Y
Ir
0
2
Ph
H
PA1
H
H
H
H
H
H
—
—

2-57
Ir
1
2
Ph
H
H
PA2
H
H
H
H
H
pic

2-57X
Ir
1
2
Ph
H
H
PA2
H
H
H
H
H
acac

2-57Y
Ir
0
2
Ph
H
H
PA2
H
H
H
H
H
—
—

2-58
Ir
1
2
Ph
H
PA2
H
H
H
H
H
H
pic

2-58X
Ir
1
2
Ph
H
PA2
H
H
H
H
H
H
acac

2-58Y
Ir
0
2
Ph
H
PA2
H
H
H
H
H
H
—
—

2-59
Ir
1
2
Ph
H
H
EA1
H
H
H
H
H
pic

2-59X
Ir
1
2
Ph
H
H
EA1
H
H
H
H
H
acac

2-59Y
Ir
0
2
Ph
H
H
EA1
H
H
H
H
H
—
—

2-60
Ir
1
2
Ph
H
EA2
H
H
H
H
H
H
pic

2-60X
Ir
1
2
Ph
H
EA2
H
H
H
H
H
H
acac

2-60Y
Ir
0
2
Ph
H
EA2
H
H
H
H
H
H
—
—

2-61
Ir
1
2
Ph
H
H
ME
H
H
H
H
H
pic

2-61X
Ir
1
2
Ph
H
H
ME
H
H
H
H
H
acac

2-61Y
Ir
0
2
Ph
H
H
ME
H
H
H
H
H
—
—

2-62
Ir
1
2
Ph
H
ME
H
H
H
H
H
H
pic

2-62X
Ir
1
2
Ph
H
ME
H
H
H
H
H
H
acac

2-62Y
Ir
0
2
Ph
H
ME
H
H
H
H
H
H
—
—

2-63
Ir
1
2
Ph
H
H
AT
H
H
H
H
H
pic

2-63X
Ir
1
2
Ph
H
H
AT
H
H
H
H
H
acac

2-63Y
Ir
0
2
Ph
H
H
AT
H
H
H
H
H
—
—

2-64
Ir
1
2
Ph
H
AT
H
H
H
H
H
H
pic

2-64X
Ir
1
2
Ph
H
AT
H
H
H
H
H
H
acac

2-64Y
Ir
0
2
Ph
H
AT
H
H
H
H
H
H
—
—

2-65
Ir
1
2
Ph
H
H
MES1
H
H
H
H
H
pic

2-65X
Ir
1
2
Ph
H
H
MES1
H
H
H
H
H
acac

2-65Y
Ir
0
2
Ph
H
H
MES1
H
H
H
H
H
—
—

2-66
Ir
1
2
Ph
H
MES1
H
H
H
H
H
H
pic

2-66X
Ir
1
2
Ph
H
MES1
H
H
H
H
H
H
acac

2-66Y
Ir
0
2
Ph
H
MES1
H
H
H
H
H
H
—
—

2-67
Ir
1
2
Ph
H
H
MES2
H
H
H
H
H
pic

2-67X
Ir
1
2
Ph
H
H
MES2
H
H
H
H
H
acac

2-67Y
Ir
0
2
Ph
H
H
MES2
H
H
H
H
H
—
—

2-68
Ir
1
2
Ph
H
MES2
H
H
H
H
H
H
pic

2-68X
Ir
1
2
Ph
H
MES2
H
H
H
H
H
H
acac

2-68Y
Ir
0
2
Ph
H
MES2
H
H
H
H
H
H
—
—

2-69
Ir
1
2
Ph
H
H
PS1
H
H
H
H
H
pic

2-69X
Ir
1
2
Ph
H
H
PS1
H
H
H
H
H
acac

2-69Y
Ir
0
2
Ph
H
H
PS1
H
H
H
H
H
—
—

2-70
Ir
1
2
Ph
H
PS1
H
H
H
H
H
H
pic

2-70X
Ir
1
2
Ph
H
PS1
H
H
H
H
H
H
acac

2-70Y
Ir
0
2
Ph
H
PS1
H
H
H
H
H
H
—
—

2-71
Ir
1
2
Ph
H
H
PS2
H
H
H
H
H
pic

2-71X
Ir
1
2
Ph
H
H
PS2
H
H
H
H
H
acac

2-71Y
Ir
0
2
Ph
H
H
PS2
H
H
H
H
H
—
—

2-72
Ir
1
2
Ph
H
PS2
H
H
H
H
H
H
pic

2-72X
Ir
1
2
Ph
H
PS2
H
H
H
H
H
H
acac

2-72Y
Ir
0
2
Ph
H
PS2
H
H
H
H
H
H
—
—

2-73
Ir
1
2
Ph
H
H
BAL1
H
H
H
H
H
pic

2-73X
Ir
1
2
Ph
H
H
BAL1
H
H
H
H
H
acac

2-73Y
Ir
0
2
Ph
H
H
BAL1
H
H
H
H
H
—
—

2-74
Ir
1
2
Ph
H
BAL1
H
H
H
H
H
H
pic

2-74X
Ir
1
2
Ph
H
BAL1
H
H
H
H
H
H
acac

2-74Y
Ir
0
2
Ph
H
BAL1
H
H
H
H
H
H
—
—

2-75
Ir
1
2
Ph
H
H
BAL2
H
H
H
H
H
pic

2-75X
Ir
1
2
Ph
H
H
BAL2
H
H
H
H
H
acac

2-75Y
Ir
0
2
Ph
H
H
BAL2
H
H
H
H
H
—
—

2-76
Ir
1
2
Ph
H
BAL2
H
H
H
H
H
H
pic

2-76X
Ir
1
2
Ph
H
BAL2
H
H
H
H
H
H
acac

2-76Y
Ir
0
2
Ph
H
BAL2
H
H
H
H
H
H
—
—

2-77
Ir
1
2
Ph
H
H
MEK1
H
H
H
H
H
pic

2-77X
Ir
1
2
Ph
H
H
MEK1
H
H
H
H
H
acac

2-77Y
Ir
0
2
Ph
H
H
MEK1
H
H
H
H
H
—
—

2-78
Ir
1
2
Ph
H
MEK1
H
H
H
H
H
H
pic

2-78X
Ir
1
2
Ph
H
MEK1
H
H
H
H
H
H
acac

2-78Y
Ir
0
2
Ph
H
MEK1
H
H
H
H
H
H
—
—

2-79
Ir
1
2
Ph
H
H
MEK2
H
H
H
H
H
pic

2-79X
Ir
1
2
Ph
H
H
MEK2
H
H
H
H
H
acac

2-79Y
Ir
0
2
Ph
H
H
MEK2
H
H
H
H
H
—
—

2-80
Ir
1
2
Ph
H
MEK2
H
H
H
H
H
H
pic

2-80X
Ir
1
2
Ph
H
MEK2
H
H
H
H
H
H
acac

2-80Y
Ir
0
2
Ph
H
MEK2
H
H
H
H
H
H
—
—

2-81
Ir
1
2
Ph
H
H
PAL1
H
H
H
H
H
pic

2-81X
Ir
1
2
Ph
H
H
PAL1
H
H
H
H
H
acac

2-81Y
Ir
0
2
Ph
H
H
PAL1
H
H
H
H
H
—
—

2-82
Ir
1
2
Ph
H
PAL1
H
H
H
H
H
H
pic

2-82X
Ir
1
2
Ph
H
PAL1
H
H
H
H
H
H
acac

2-82Y
Ir
0
2
Ph
H
PAL1
H
H
H
H
H
H
—
—

2-83
Ir
1
2
Ph
H
H
PAL2
H
H
H
H
H
pic

2-83X
Ir
1
2
Ph
H
H
PAL2
H
H
H
H
H
acac

2-83Y
Ir
0
2
Ph
H
H
PAL2
H
H
H
H
H
—
—

2-84
Ir
1
2
Ph
H
PAL2
H
H
H
H
H
H
pic

2-84X
Ir
1
2
Ph
H
PAL2
H
H
H
H
H
H
acac

2-84Y
Ir
0
2
Ph
H
PAL2
H
H
H
H
H
H
—
—

2-85
Ir
1
2
Ph
H
H
MMK
H
H
H
H
H
pic

2-85X
Ir
1
2
Ph
H
H
MMK
H
H
H
H
H
acac

2-85Y
Ir
0
2
Ph
H
H
MMK
H
H
H
H
H
—
—

2-86
Ir
1
2
Ph
H
MMK
H
H
H
H
H
H
pic

2-86X
Ir
1
2
Ph
H
MMK
H
H
H
H
H
H
acac

2-86Y
Ir
0
2
Ph
H
MMK
H
H
H
H
H
H
—
—

2-87
Ir
1
2
Ph
H
H
EES1
H
H
H
H
H
pic

2-87X
Ir
1
2
Ph
H
H
EES1
H
H
H
H
H
acac

2-87Y
Ir
0
2
Ph
H
H
EES1
H
H
H
H
H
—
—

2-88
Ir
1
2
Ph
H
EES2
H
H
H
H
H
H
pic

2-88X
Ir
1
2
Ph
H
EES2
H
H
H
H
H
H
acac

2-88Y
Ir
0
2
Ph
H
EES2
H
H
H
H
H
H
—
—

2-89
Ir
1
2
Ph
H
H
PAE1
H
H
H
H
H
pic

2-89X
Ir
1
2
Ph
H
H
PAE1
H
H
H
H
H
acac

2-89Y
Ir
0
2
Ph
H
H
PAE1
H
H
H
H
H
—
—

2-90
Ir
1
2
Ph
H
PAE2
H
H
H
H
H
H
pic

2-90X
Ir
1
2
Ph
H
PAE2
H
H
H
H
H
H
acac

2-90Y
Ir
0
2
Ph
H
PAE2
H
H
H
H
H
H
—
—

2-91
Ir
1
2
Ph
H
H
AME1
H
H
H
H
H
pic

2-91X
Ir
1
2
Ph
H
H
AME1
H
H
H
H
H
acac

2-91Y
Ir
0
2
Ph
H
H
AME1
H
H
H
H
H
—
—

2-92
Ir
1
2
Ph
H
AME1
H
H
H
H
H
H
pic

2-92X
Ir
1
2
Ph
H
AME1
H
H
H
H
H
H
acac

2-92Y
Ir
0
2
Ph
H
AME1
H
H
H
H
H
H
—
—

2-93
Ir
1
2
Ph
H
H
AME2
H
H
H
H
H
pic

2-93X
Ir
1
2
Ph
H
H
AME2
H
H
H
H
H
acac

2-93Y
Ir
0
2
Ph
H
H
AME2
H
H
H
H
H
—
—

2-94
Ir
1
2
Ph
H
AME2
H
H
H
H
H
H
pic

2-94X
Ir
1
2
Ph
H
AME2
H
H
H
H
H
H
acac

2-94Y
Ir
0
2
Ph
H
AME2
H
H
H
H
H
H
—
—

2-95
Ir
1
2
Ph
H
H
EAE1
H
H
H
H
H
pic

2-95X
Ir
1
2
Ph
H
H
EAE1
H
H
H
H
H
acac

2-95Y
Ir
0
2
Ph
H
H
EAE1
H
H
H
H
H
—
—

2-96
Ir
1
2
Ph
H
EAE1
H
H
H
H
H
H
pic

2-96X
Ir
1
2
Ph
H
EAE1
H
H
H
H
H
H
acac

2-96Y
Ir
0
2
Ph
H
EAE1
H
H
H
H
H
H
—
—

2-97
Ir
1
2
Ph
H
H
EAE2
H
H
H
H
H
pic

2-97X
Ir
1
2
Ph
H
H
EAE2
H
H
H
H
H
acac

2-97Y
Ir
0
2
Ph
H
H
EAE2
H
H
H
H
H
—
—

2-98
Ir
1
2
Ph
H
EAE2
H
H
H
H
H
H
pic

2-98X
Ir
1
2
Ph
H
EAE2
H
H
H
H
H
H
acac

2-98Y
Ir
0
2
Ph
H
EAE2
H
H
H
H
H
H
—
—

2-99
Ir
1
2
Ph
H
H
AAE1
H
H
H
H
H
pic

2-99X
Ir
1
2
Ph
H
H
AAE1
H
H
H
H
H
acac

2-99Y
Ir
0
2
Ph
H
H
AAE1
H
H
H
H
H
—
—

2-100
Ir
1
2
Ph
H
AAE1
H
H
H
H
H
H
pic

2-100X
Ir
1
2
Ph
H
AAE1
H
H
H
H
H
H
acac

2-100Y
Ir
0
2
Ph
H
AAE1
H
H
H
H
H
H
—
—

2-101
Ir
1
2
Ph
H
H
AAE2
H
H
H
H
H
pic

2-101X
Ir
1
2
Ph
H
H
AAE2
H
H
H
H
H
acac

2-101Y
Ir
0
2
Ph
H
H
AAE2
H
H
H
H
H
—
—

2-102
Ir
1
2
Ph
H
AAE2
H
H
H
H
H
H
pic

2-102X
Ir
1
2
Ph
H
AAE2
H
H
H
H
H
H
acac

2-102Y
Ir
0
2
Ph
H
AAE2
H
H
H
H
H
H
—
—

2-103
Ir
1
2
Ph
H
H
PME1
H
H
H
H
H
pic

2-103X
Ir
1
2
Ph
H
H
PME1
H
H
H
H
H
acac

2-103Y
Ir
0
2
Ph
H
H
PME1
H
H
H
H
H
—
—

2-104
Ir
1
2
Ph
H
PME1
H
H
H
H
H
H
pic

2-104X
Ir
1
2
Ph
H
PME1
H
H
H
H
H
H
acac

2-104Y
Ir
0
2
Ph
H
PME1
H
H
H
H
H
H
—
—

2-105
Ir
1
2
Ph
H
H
PME2
H
H
H
H
H
pic

2-105X
Ir
1
2
Ph
H
H
PME2
H
H
H
H
H
acac

2-105Y
Ir
0
2
Ph
H
H
PME2
H
H
H
H
H
—
—

2-106
Ir
1
2
Ph
H
PME2
H
H
H
H
H
H
pic

2-106X
Ir
1
2
Ph
H
PME2
H
H
H
H
H
H
acac

2-106Y
Ir
0
2
Ph
H
PME2
H
H
H
H
H
H
—
—

2-107
Ir
1
2
Ph
H
H
MET1
H
H
H
H
H
pic

2-107X
Ir
1
2
Ph
H
H
MET1
H
H
H
H
H
acac

2-107Y
Ir
0
2
Ph
H
H
MET1
H
H
H
H
H
—
—

2-108
Ir
1
2
Ph
H
MET1
H
H
H
H
H
H
pic

2-108X
Ir
1
2
Ph
H
MET1
H
H
H
H
H
H
acac

2-108Y
Ir
0
2
Ph
H
MET1
H
H
H
H
H
H
—
—

2-109
Ir
1
2
Ph
H
H
MET2
H
H
H
H
H
pic

2-109X
Ir
1
2
Ph
H
H
MET2
H
H
H
H
H
acac

2-109Y
Ir
0
2
Ph
H
H
MET2
H
H
H
H
H
—
—

2-110
Ir
1
2
Ph
H
MET2
H
H
H
H
H
H
pic

2-110X
Ir
1
2
Ph
H
MET2
H
H
H
H
H
H
acac

2-110Y
Ir
0
2
Ph
H
MET2
H
H
H
H
H
H
—
—

2-111
Ir
1
2
Ph
H
H
EE1
H
H
H
H
H
pic

2-111X
Ir
1
2
Ph
H
H
EE1
H
H
H
H
H
acac

2-111Y
Ir
0
2
Ph
H
H
EE1
H
H
H
H
H
—
—

2-112
Ir
1
2
Ph
H
EE1
H
H
H
H
H
H
pic

2-112X
Ir
1
2
Ph
H
EE1
H
H
H
H
H
H
acac

2-112Y
Ir
0
2
Ph
H
EE1
H
H
H
H
H
H
—
—

2-113
Ir
1
2
Ph
H
H
EE2
H
H
H
H
H
pic

2-113X
Ir
1
2
Ph
H
H
EE2
H
H
H
H
H
acac

2-113Y
Ir
0
2
Ph
H
H
EE2
H
H
H
H
H
—
—

2-114
Ir
1
2
Ph
H
EE2
H
H
H
H
H
H
pic

2-114X
Ir
1
2
Ph
H
EE2
H
H
H
H
H
H
acac

2-114Y
Ir
0
2
Ph
H
EE2
H
H
H
H
H
H
—
—

2-115
Ir
1
2
Ph
H
H
MS1
H
H
H
H
H
pic

2-115X
Ir
1
2
Ph
H
H
MS1
H
H
H
H
H
acac

2-115Y
Ir
0
2
Ph
H
H
MS1
H
H
H
H
H
—
—

2-116
Ir
1
2
Ph
H
MS1
H
H
H
H
H
H
pic

2-116X
Ir
1
2
Ph
H
MS1
H
H
H
H
H
H
acac

2-116Y
Ir
0
2
Ph
H
MS1
H
H
H
H
H
H
—
—

2-117
Ir
1
2
Ph
H
H
MS2
H
H
H
H
H
pic

2-117X
Ir
1
2
Ph
H
H
MS2
H
H
H
H
H
acac

2-117Y
Ir
0
2
Ph
H
H
MS2
H
H
H
H
H
—
—

2-118
Ir
1
2
Ph
H
MS2
H
H
H
H
H
H
pic

2-118X
Ir
1
2
Ph
H
MS2
H
H
H
H
H
H
acac

2-118Y
Ir
0
2
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 3

No.
M
n
BBS
BS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3-1
Ir
1
3
Ph
H
H
H
H
H
H
H
H
H
pic

3-1X
Ir
1
3
Ph
H
H
H
H
H
H
H
H
H
acac

3-1Y
Ir
0
3
Ph
H
H
H
H
H
H
H
H
H
—
—

3-2
Ir
1
3
Ph
H
F
H
F
H
H
H
H
H
pic

3-2X
Ir
1
3
Ph
H
F
H
F
H
H
H
H
H
acac

3-2Y
Ir
0
3
Ph
H
F
H
F
H
H
H
H
H
—
—

3-3
Ir
1
3
Ph
F
H
H
F
H
H
H
H
H
pic

3-3X
Ir
1
3
Ph
F
H
H
F
H
H
H
H
H
acac

3-3Y
Ir
0
3
Ph
F
H
H
F
H
H
H
H
H
—
—

3-4
Ir
1
3
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

3-4X
Ir
1
3
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

3-4Y
Ir
0
3
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

3-5
Ir
1
3
Ph
H
F
CF₃
H
H
H
H
H
H
pic

3-5X
Ir
1
3
Ph
H
F
CF₃
H
H
H
H
H
H
acac

3-5Y
Ir
0
3
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

3-6
Ir
1
3
Ph
F
H
CF₃
H
H
H
H
H
H
pic

3-6X
Ir
1
3
Ph
F
H
CF₃
H
H
H
H
H
H
acac

3-6Y
Ir
0
3
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

3-7
Ir
1
3
Ph
F
F
F
F
H
H
H
H
H
pic

3-7X
Ir
1
3
Ph
F
F
F
F
H
H
H
H
H
acac

3-7Y
Ir
0
3
Ph
F
F
F
F
H
H
H
H
H
—
—

3-8
Ir
1
3
Ph
H
F
H
CH₃
H
H
H
H
H
pic

3-8X
Ir
1
3
Ph
H
F
H
CH₃
H
H
H
H
H
acac

3-8Y
Ir
0
3
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

3-9
Ir
1
3
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

3-9X
Ir
1
3
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

3-9Y
Ir
0
3
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

3-10
Ir
1
3
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

3-10X
Ir
1
3
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

3-10Y
Ir
0
3
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

3-11
Ir
1
3
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

3-11X
Ir
1
3
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

3-11Y
Ir
0
3
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

3-12
Ir
1
3
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

3-12X
Ir
1
3
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

3-12Y
Ir
0
3
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

3-13
Ir
1
3
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

3-13X
Ir
1
3
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

3-13Y
Ir
0
3
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

3-14
Ir
1
3
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

3-14X
Ir
1
3
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

3-14Y
Ir
0
3
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

3-15
Ir
1
3
Ph
H
H
NO₂
H
H
H
H
H
H
pic

3-15X
Ir
1
3
Ph
H
H
NO₂
H
H
H
H
H
H
acac

3-15Y
Ir
0
3
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

3-16
Ir
1
3
Ph
F
H
NO₂
H
H
H
H
H
H
pic

3-16X
Ir
1
3
Ph
F
H
NO₂
H
H
H
H
H
H
acac

3-16Y
Ir
0
3
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

3-17
Ir
1
3
Ph
F
H
NO₂
F
H
H
H
H
H
pic

3-17X
Ir
1
3
Ph
F
H
NO₂
F
H
H
H
H
H
acac

3-17Y
Ir
0
3
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

3-18
Ir
1
3
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

3-18X
Ir
1
3
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

3-18Y
Ir
0
3
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

3-19
Ir
1
3
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

3-19X
Ir
1
3
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

3-19Y
Ir
0
3
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

3-20
Ir
1
3
Ph
H
H
CF₃
H
H
H
H
H
H
pic

3-20X
Ir
1
3
Ph
H
H
CF₃
H
H
H
H
H
H
acac

3-20Y
Ir
0
3
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

3-21
Ir
1
3
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

3-21X
Ir
1
3
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

3-21Y
Ir
0
3
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

3-22
Ir
1
3
Ph
H
NO₂
H
H
H
H
H
H
H
pic

3-22X
Ir
1
3
Ph
H
NO₂
H
H
H
H
H
H
H
acac

3-22Y
Ir
0
3
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

3-23
Ir
1
3
Ph
H
CF₃
H
H
H
H
H
H
H
pic

3-23X
Ir
1
3
Ph
H
CF₃
H
H
H
H
H
H
H
acac

3-23Y
Ir
0
3
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

3-24
Ir
1
3
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

3-24X
Ir
1
3
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

3-24Y
Ir
0
3
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

3-25
Ir
1
3
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

3-25X
Ir
1
3
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

3-25Y
Ir
0
3
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

3-26
Ir
1
3
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

3-26X
Ir
1
3
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

3-26Y
Ir
0
3
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

3-27
Ir
1
3
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

3-27X
Ir
1
3
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

3-27Y
Ir
0
3
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

3-28
Ir
1
3
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

3-28X
Ir
1
3
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

3-28Y
Ir
0
3
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

3-29
Ir
1
3
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

3-29X
Ir
1
3
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

3-29Y
Ir
0
3
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

3-30
Ir
1
3
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

3-30X
Ir
1
3
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

3-30Y
Ir
0
3
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

3-31
Ir
1
3
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

3-31X
Ir
1
3
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

3-31Y
Ir
0
3
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

3-32
Ir
1
3
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

3-32X
Ir
1
3
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

3-32Y
Ir
0
3
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

3-33
Ir
1
3
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

3-33X
Ir
1
3
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

3-33Y
Ir
0
3
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

3-34
Ir
1
3
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

3-34X
Ir
1
3
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

3-34Y
Ir
0
3
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

3-35
Ir
1
3
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3-35X
Ir
1
3
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3-35Y
Ir
0
3
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3-36
Ir
1
3
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

3-36X
Ir
1
3
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

3-36Y
Ir
0
3
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

3-37
Ir
1
3
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

3-37X
Ir
1
3
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

3-37Y
Ir
0
3
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

3-38
Ir
1
3
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

3-38X
Ir
1
3
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

3-38Y
Ir
0
3
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

3-39
Ir
1
3
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

3-39X
Ir
1
3
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

3-39Y
Ir
0
3
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

3-40
Ir
1
3
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

3-40X
Ir
1
3
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

3-40Y
Ir
0
3
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

3-41
Ir
1
3
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3-41X
Ir
1
3
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3-41Y
Ir
0
3
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3-42
Ir
1
3
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

3-42X
Ir
1
3
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

3-42Y
Ir
0
3
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

3-43
Ir
1
3
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

3-43X
Ir
1
3
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

3-43Y
Ir
0
3
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

3-44
Ir
1
3
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

3-44X
Ir
1
3
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

3-44Y
Ir
0
3
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

3-45
Ir
1
3
Ph
H
H
BL
H
H
H
H
H
pic

3-45X
Ir
1
3
Ph
H
H
BL
H
H
H
H
H
acac

3-45Y
Ir
0
3
Ph
H
H
BL
H
H
H
H
H
—
—

3-46
Ir
1
3
Ph
H
BL
H
H
H
H
H
H
pic

3-46X
Ir
1
3
Ph
H
BL
H
H
H
H
H
H
acac

3-46Y
Ir
0
3
Ph
H
BL
H
H
H
H
H
H
—
—

3-47
Ir
1
3
Ph
H
H
PL
H
H
H
H
H
pic

3-47X
Ir
1
3
Ph
H
H
PL
H
H
H
H
H
acac

3-47Y
Ir
0
3
Ph
H
H
PL
H
H
H
H
H
—
—

3-48
Ir
1
3
Ph
H
PL
H
H
H
H
H
H
pic

3-48X
Ir
1
3
Ph
H
PL
H
H
H
H
H
H
acac

3-48Y
Ir
0
3
Ph
H
PL
H
H
H
H
H
H
—
—

3-49
Ir
1
3
Ph
H
H
MEE1
H
H
H
H
H
pic

3-49X
Ir
1
3
Ph
H
H
MEE1
H
H
H
H
H
acac

3-49Y
Ir
0
3
Ph
H
H
MEE1
H
H
H
H
H
—
—

3-50
Ir
1
3
Ph
H
MEE1
H
H
H
H
H
H
pic

3-50X
Ir
1
3
Ph
H
MEE1
H
H
H
H
H
H
acac

3-50Y
Ir
0
3
Ph
H
MEE1
H
H
H
H
H
H
—
—

3-51
Ir
1
3
Ph
H
H
MEE2
H
H
H
H
H
pic

3-51X
Ir
1
3
Ph
H
H
MEE2
H
H
H
H
H
acac

3-51Y
Ir
0
3
Ph
H
H
MEE2
H
H
H
H
H
—
—

3-52
Ir
1
3
Ph
H
MEE2
H
H
H
H
H
H
pic

3-52X
Ir
1
3
Ph
H
MEE2
H
H
H
H
H
H
acac

3-52Y
Ir
0
3
Ph
H
MEE2
H
H
H
H
H
H
—
—

3-53
Ir
1
3
Ph
H
H
PA1
H
H
H
H
H
pic

3-53X
Ir
1
3
Ph
H
H
PA1
H
H
H
H
H
acac

3-53Y
Ir
0
3
Ph
H
H
PA1
H
H
H
H
H
—
—

3-54
Ir
1
3
Ph
H
PA1
H
H
H
H
H
H
pic

3-54X
Ir
1
3
Ph
H
PA1
H
H
H
H
H
H
acac

3-54Y
Ir
0
3
Ph
H
PA1
H
H
H
H
H
H
—
—

3-55
Ir
1
3
Ph
H
H
PA2
H
H
H
H
H
pic

3-55X
Ir
1
3
Ph
H
H
PA2
H
H
H
H
H
acac

3-55Y
Ir
0
3
Ph
H
H
PA2
H
H
H
H
H
—
—

3-56
Ir
1
3
Ph
H
PA2
H
H
H
H
H
H
pic

3-56X
Ir
1
3
Ph
H
PA2
H
H
H
H
H
H
acac

3-56Y
Ir
0
3
Ph
H
PA2
H
H
H
H
H
H
—
—

3-57
Ir
1
3
Ph
H
H
EA1
H
H
H
H
H
pic

3-57X
Ir
1
3
Ph
H
H
EA1
H
H
H
H
H
acac

3-57Y
Ir
0
3
Ph
H
H
EA1
H
H
H
H
H
—
—

3-58
Ir
1
3
Ph
H
EA2
H
H
H
H
H
H
pic

3-58X
Ir
1
3
Ph
H
EA2
H
H
H
H
H
H
acac

3-58Y
Ir
0
3
Ph
H
EA2
H
H
H
H
H
H
—
—

3-59
Ir
1
3
Ph
H
H
ME
H
H
H
H
H
pic

3-59X
Ir
1
3
Ph
H
H
ME
H
H
H
H
H
acac

3-59Y
Ir
0
3
Ph
H
H
ME
H
H
H
H
H
—
—

3-60
Ir
1
3
Ph
H
ME
H
H
H
H
H
H
pic

3-60X
Ir
1
3
Ph
H
ME
H
H
H
H
H
H
acac

3-60Y
Ir
0
3
Ph
H
ME
H
H
H
H
H
H
—
—

3-61
Ir
1
3
Ph
H
H
AT
H
H
H
H
H
pic

3-61X
Ir
1
3
Ph
H
H
AT
H
H
H
H
H
acac

3-61Y
Ir
0
3
Ph
H
H
AT
H
H
H
H
H
—
—

3-62
Ir
1
3
Ph
H
AT
H
H
H
H
H
H
pic

3-62X
Ir
1
3
Ph
H
AT
H
H
H
H
H
H
acac

3-62Y
Ir
0
3
Ph
H
AT
H
H
H
H
H
H
—
—

3-63
Ir
1
3
Ph
H
H
MES1
H
H
H
H
H
pic

3-63X
Ir
1
3
Ph
H
H
MES1
H
H
H
H
H
acac

3-63Y
Ir
0
3
Ph
H
H
MES1
H
H
H
H
H
—
—

3-64
Ir
1
3
Ph
H
MES1
H
H
H
H
H
H
pic

3-64X
Ir
1
3
Ph
H
MES1
H
H
H
H
H
H
acac

3-64Y
Ir
0
3
Ph
H
MES1
H
H
H
H
H
H
—
—

3-65
Ir
1
3
Ph
H
H
MES2
H
H
H
H
H
pic

3-65X
Ir
1
3
Ph
H
H
MES2
H
H
H
H
H
acac

3-65Y
Ir
0
3
Ph
H
H
MES2
H
H
H
H
H
—
—

3-66
Ir
1
3
Ph
H
MES2
H
H
H
H
H
H
pic

3-66X
Ir
1
3
Ph
H
MES2
H
H
H
H
H
H
acac

3-66Y
Ir
0
3
Ph
H
MES2
H
H
H
H
H
H
—
—

3-67
Ir
1
3
Ph
H
H
PS1
H
H
H
H
H
pic

3-67X
Ir
1
3
Ph
H
H
PS1
H
H
H
H
H
acac

3-67Y
Ir
0
3
Ph
H
H
PS1
H
H
H
H
H
—
—

3-68
Ir
1
3
Ph
H
PS1
H
H
H
H
H
H
pic

3-68X
Ir
1
3
Ph
H
PS1
H
H
H
H
H
H
acac

3-68Y
Ir
0
3
Ph
H
PS1
H
H
H
H
H
H
—
—

3-69
Ir
1
3
Ph
H
H
PS2
H
H
H
H
H
pic

3-69X
Ir
1
3
Ph
H
H
PS2
H
H
H
H
H
acac

3-69Y
Ir
0
3
Ph
H
H
PS2
H
H
H
H
H
—
—

3-70
Ir
1
3
Ph
H
PS2
H
H
H
H
H
H
pic

3-70X
Ir
1
3
Ph
H
PS2
H
H
H
H
H
H
acac

3-70Y
Ir
0
3
Ph
H
PS2
H
H
H
H
H
H
—
—

3-71
Ir
1
3
Ph
H
H
BAL1
H
H
H
H
H
pic

3-71X
Ir
1
3
Ph
H
H
BAL1
H
H
H
H
H
acac

3-71Y
Ir
0
3
Ph
H
H
BAL1
H
H
H
H
H
—
—

3-72
Ir
1
3
Ph
H
BAL1
H
H
H
H
H
H
pic

3-72X
Ir
1
3
Ph
H
BAL1
H
H
H
H
H
H
acac

3-72Y
Ir
0
3
Ph
H
BAL1
H
H
H
H
H
H
—
—

3-73
Ir
1
3
Ph
H
H
BAL2
H
H
H
H
H
pic

3-73X
Ir
1
3
Ph
H
H
BAL2
H
H
H
H
H
acac

3-73Y
Ir
0
3
Ph
H
H
BAL2
H
H
H
H
H
—
—

3-74
Ir
1
3
Ph
H
BAL2
H
H
H
H
H
H
pic

3-74X
Ir
1
3
Ph
H
BAL2
H
H
H
H
H
H
acac

3-74Y
Ir
0
3
Ph
H
BAL2
H
H
H
H
H
H
—
—

3-75
Ir
1
3
Ph
H
H
MEK1
H
H
H
H
H
pic

3-75X
Ir
1
3
Ph
H
H
MEK1
H
H
H
H
H
acac

3-75Y
Ir
0
3
Ph
H
H
MEK1
H
H
H
H
H
—
—

3-76
Ir
1
3
Ph
H
MEK1
H
H
H
H
H
H
pic

3-76X
Ir
1
3
Ph
H
MEK1
H
H
H
H
H
H
acac

3-76Y
Ir
0
3
Ph
H
MEK1
H
H
H
H
H
H
—
—

3-77
Ir
1
3
Ph
H
H
MEK2
H
H
H
H
H
pic

3-77X
Ir
1
3
Ph
H
H
MEK2
H
H
H
H
H
acac

3-77Y
Ir
0
3
Ph
H
H
MEK2
H
H
H
H
H
—
—

3-78
Ir
1
3
Ph
H
MEK2
H
H
H
H
H
H
pic

3-78X
Ir
1
3
Ph
H
MEK2
H
H
H
H
H
H
acac

3-78Y
Ir
0
3
Ph
H
MEK2
H
H
H
H
H
H
—
—

3-79
Ir
1
3
Ph
H
H
PAL1
H
H
H
H
H
pic

3-79X
Ir
1
3
Ph
H
H
PAL1
H
H
H
H
H
acac

3-79Y
Ir
0
3
Ph
H
H
PAL1
H
H
H
H
H
—
—

3-80
Ir
1
3
Ph
H
PAL1
H
H
H
H
H
H
pic

3-80X
Ir
1
3
Ph
H
PAL1
H
H
H
H
H
H
acac

3-80Y
Ir
0
3
Ph
H
PAL1
H
H
H
H
H
H
—
—

3-81
Ir
1
3
Ph
H
H
PAL2
H
H
H
H
H
pic

3-81X
Ir
1
3
Ph
H
H
PAL2
H
H
H
H
H
acac

3-81Y
Ir
0
3
Ph
H
H
PAL2
H
H
H
H
H
—
—

3-82
Ir
1
3
Ph
H
PAL2
H
H
H
H
H
H
pic

3-82X
Ir
1
3
Ph
H
PAL2
H
H
H
H
H
H
acac

3-82Y
Ir
0
3
Ph
H
PAL2
H
H
H
H
H
H
—
—

3-83
Ir
1
3
Ph
H
H
MMK
H
H
H
H
H
pic

3-83X
Ir
1
3
Ph
H
H
MMK
H
H
H
H
H
acac

3-83Y
Ir
0
3
Ph
H
H
MMK
H
H
H
H
H
—
—

3-84
Ir
1
3
Ph
H
MMK
H
H
H
H
H
H
pic

3-84X
Ir
1
3
Ph
H
MMK
H
H
H
H
H
H
acac

3-84Y
Ir
0
3
Ph
H
MMK
H
H
H
H
H
H
—
—

3-85
Ir
1
3
Ph
H
H
EES1
H
H
H
H
H
pic

3-85X
Ir
1
3
Ph
H
H
EES1
H
H
H
H
H
acac

3-85Y
Ir
0
3
Ph
H
H
EES1
H
H
H
H
H
—
—

3-86
Ir
1
3
Ph
H
EES2
H
H
H
H
H
H
pic

3-86X
Ir
1
3
Ph
H
EES2
H
H
H
H
H
H
acac

3-86Y
Ir
0
3
Ph
H
EES2
H
H
H
H
H
H
—
—

3-87
Ir
1
3
Ph
H
H
PAE1
H
H
H
H
H
pic

3-87X
Ir
1
3
Ph
H
H
PAE1
H
H
H
H
H
acac

3-87Y
Ir
0
3
Ph
H
H
PAE1
H
H
H
H
H
—
—

3-88
Ir
1
3
Ph
H
PAE2
H
H
H
H
H
H
pic

3-88X
Ir
1
3
Ph
H
PAE2
H
H
H
H
H
H
acac

3-88Y
Ir
0
3
Ph
H
PAE2
H
H
H
H
H
H
—
—

3-89
Ir
1
3
Ph
H
H
AME1
H
H
H
H
H
pic

3-89X
Ir
1
3
Ph
H
H
AME1
H
H
H
H
H
acac

3-89Y
Ir
0
3
Ph
H
H
AME1
H
H
H
H
H
—
—

3-90
Ir
1
3
Ph
H
AME1
H
H
H
H
H
H
pic

3-90X
Ir
1
3
Ph
H
AME1
H
H
H
H
H
H
acac

3-90Y
Ir
0
3
Ph
H
AME1
H
H
H
H
H
H
—
—

3-91
Ir
1
3
Ph
H
H
AME2
H
H
H
H
H
pic

3-91X
Ir
1
3
Ph
H
H
AME2
H
H
H
H
H
acac

3-91Y
Ir
0
3
Ph
H
H
AME2
H
H
H
H
H
—
—

3-92
Ir
1
3
Ph
H
AME2
H
H
H
H
H
H
pic

3-92X
Ir
1
3
Ph
H
AME2
H
H
H
H
H
H
acac

3-92Y
Ir
0
3
Ph
H
AME2
H
H
H
H
H
H
—
—

3-93
Ir
1
3
Ph
H
H
EAE1
H
H
H
H
H
pic

3-93X
Ir
1
3
Ph
H
H
EAE1
H
H
H
H
H
acac

3-93Y
Ir
0
3
Ph
H
H
EAE1
H
H
H
H
H
—
—

3-94
Ir
1
3
Ph
H
EAE1
H
H
H
H
H
H
pic

3-94X
Ir
1
3
Ph
H
EAE1
H
H
H
H
H
H
acac

3-94Y
Ir
0
3
Ph
H
EAE1
H
H
H
H
H
H
—
—

3-95
Ir
1
3
Ph
H
H
EAE2
H
H
H
H
H
pic

3-95X
Ir
1
3
Ph
H
H
EAE2
H
H
H
H
H
acac

3-95Y
Ir
0
3
Ph
H
H
EAE2
H
H
H
H
H
—
—

3-96
Ir
1
3
Ph
H
EAE2
H
H
H
H
H
H
pic

3-96X
Ir
1
3
Ph
H
EAE2
H
H
H
H
H
H
acac

3-96Y
Ir
0
3
Ph
H
EAE2
H
H
H
H
H
H
—
—

3-97
Ir
1
3
Ph
H
H
AAE1
H
H
H
H
H
pic

3-97X
Ir
1
3
Ph
H
H
AAE1
H
H
H
H
H
acac

3-97Y
Ir
0
3
Ph
H
H
AAE1
H
H
H
H
H
—
—

3-98
Ir
1
3
Ph
H
AAE1
H
H
H
H
H
H
pic

3-98X
Ir
1
3
Ph
H
AAE1
H
H
H
H
H
H
acac

3-98Y
Ir
0
3
Ph
H
AAE1
H
H
H
H
H
H
—
—

3-99
Ir
1
3
Ph
H
H
AAE2
H
H
H
H
H
pic

3-99X
Ir
1
3
Ph
H
H
AAE2
H
H
H
H
H
acac

3-99Y
Ir
0
3
Ph
H
H
AAE2
H
H
H
H
H
—
—

3-100
Ir
1
3
Ph
H
AAE2
H
H
H
H
H
H
pic

3-100X
Ir
1
3
Ph
H
AAE2
H
H
H
H
H
H
acac

3-100Y
Ir
0
3
Ph
H
AAE2
H
H
H
H
H
H
—
—

3-101
Ir
1
3
Ph
H
H
PME1
H
H
H
H
H
pic

3-101X
Ir
1
3
Ph
H
H
PME1
H
H
H
H
H
acac

3-101Y
Ir
0
3
Ph
H
H
PME1
H
H
H
H
H
—
—

3-102
Ir
1
3
Ph
H
PME1
H
H
H
H
H
H
pic

3-102X
Ir
1
3
Ph
H
PME1
H
H
H
H
H
H
acac

3-102Y
Ir
0
3
Ph
H
PME1
H
H
H
H
H
H
—
—

3-103
Ir
1
3
Ph
H
H
PME2
H
H
H
H
H
pic

3-103X
Ir
1
3
Ph
H
H
PME2
H
H
H
H
H
acac

3-103Y
Ir
0
3
Ph
H
H
PME2
H
H
H
H
H
—
—

3-104
Ir
1
3
Ph
H
PME2
H
H
H
H
H
H
pic

3-104X
Ir
1
3
Ph
H
PME2
H
H
H
H
H
H
acac

3-104Y
Ir
0
3
Ph
H
PME2
H
H
H
H
H
H
—
—

3-105
Ir
1
3
Ph
H
H
MET1
H
H
H
H
H
pic

3-105X
Ir
1
3
Ph
H
H
MET1
H
H
H
H
H
acac

3-105Y
Ir
0
3
Ph
H
H
MET1
H
H
H
H
H
—
—

3-106
Ir
1
3
Ph
H
MET1
H
H
H
H
H
H
pic

3-106X
Ir
1
3
Ph
H
MET1
H
H
H
H
H
H
acac

3-106Y
Ir
0
3
Ph
H
MET1
H
H
H
H
H
H
—
—

3-107
Ir
1
3
Ph
H
H
MET2
H
H
H
H
H
pic

3-107X
Ir
1
3
Ph
H
H
MET2
H
H
H
H
H
acac

3-107Y
Ir
0
3
Ph
H
H
MET2
H
H
H
H
H
—
—

3-108
Ir
1
3
Ph
H
MET2
H
H
H
H
H
H
pic

3-108X
Ir
1
3
Ph
H
MET2
H
H
H
H
H
H
acac

3-108Y
Ir
0
3
Ph
H
MET2
H
H
H
H
H
H
—
—

3-109
Ir
1
3
Ph
H
H
EE1
H
H
H
H
H
pic

3-109X
Ir
1
3
Ph
H
H
EE1
H
H
H
H
H
acac

3-109Y
Ir
0
3
Ph
H
H
EE1
H
H
H
H
H
—
—

3-110
Ir
1
3
Ph
H
EE1
H
H
H
H
H
H
pic

3-110X
Ir
1
3
Ph
H
EE1
H
H
H
H
H
H
acac

3-110Y
Ir
0
3
Ph
H
EE1
H
H
H
H
H
H
—
—

3-111
Ir
1
3
Ph
H
H
EE2
H
H
H
H
H
pic

3-111X
Ir
1
3
Ph
H
H
EE2
H
H
H
H
H
acac

3-111Y
Ir
0
3
Ph
H
H
EE2
H
H
H
H
H
—
—

3-112
Ir
1
3
Ph
H
EE2
H
H
H
H
H
H
pic

3-112X
Ir
1
3
Ph
H
EE2
H
H
H
H
H
H
acac

3-112Y
Ir
0
3
Ph
H
EE2
H
H
H
H
H
H
—
—

3-113
Ir
1
3
Ph
H
H
MS1
H
H
H
H
H
pic

3-113X
Ir
1
3
Ph
H
H
MS1
H
H
H
H
H
acac

3-113Y
Ir
0
3
Ph
H
H
MS1
H
H
H
H
H
—
—

3-114
Ir
1
3
Ph
H
MS1
H
H
H
H
H
H
pic

3-114X
Ir
1
3
Ph
H
MS1
H
H
H
H
H
H
acac

3-114Y
Ir
0
3
Ph
H
MS1
H
H
H
H
H
H
—
—

3-115
Ir
1
3
Ph
H
H
MS2
H
H
H
H
H
pic

3-115X
Ir
1
3
Ph
H
H
MS2
H
H
H
H
H
acac

3-115Y
Ir
0
3
Ph
H
H
MS2
H
H
H
H
H
—
—

3-116
Ir
1
3
Ph
H
MS2
H
H
H
H
H
H
pic

3-116X
Ir
1
3
Ph
H
MS2
H
H
H
H
H
H
acac

3-116Y
Ir
0
3
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 4

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4-1
Ir
1
4
Ph
H
H
H
H
CH₃
H
H
H
H
pic

4-1X
Ir
1
4
Ph
H
H
H
H
CH₃
H
H
H
H
acac

4-1Y
Ir
0
4
Ph
H
H
H
H
CH₃
H
H
H
H
—
—

4-2
Ir
1
4
Ph
H
H
H
H

^tCH₄H₉
H
H
H
H
pic

4-2X
Ir
1
4
Ph
H
H
H
H

^tCH₄H₉
H
H
H
H
acac

4-2Y
Ir
0
4
Ph
H
H
H
H

^tCH₄H₉
H
H
H
H
—
—

4-3
Ir
1
4
Ph
H
F
H
F
CH₃
H
H
H
H
pic

4-3X
Ir
1
4
Ph
H
F
H
F
CH₃
H
H
H
H
acac

4-3Y
Ir
0
4
Ph
H
F
H
F
CH₃
H
H
H
H
—
—

4-4
Ir
1
4
Ph
H
F
H
F

^tCH₄H₉
H
H
H
H
pic

4-4X
Ir
1
4
Ph
H
F
H
F

^tCH₄H₉
H
H
H
H
acac

4-4Y
Ir
0
4
Ph
H
F
H
F

^tCH₄H₉
H
H
H
H
—
—

4-5
Ir
1
4
Ph
F
H
H
F
CH₃
H
H
H
H
pic

4-5X
Ir
1
4
Ph
F
H
H
F
CH₃
H
H
H
H
acac

4-5Y
Ir
0
4
Ph
F
H
H
F
CH₃
H
H
H
H
—
—

4-6
Ir
1
4
Ph
F
H
H
F

^tCH₄H₉
H
H
H
H
pic

4-6X
Ir
1
4
Ph
F
H
H
F

^tCH₄H₉
H
H
H
H
acac

4-6Y
Ir
0
4
Ph
F
H
H
F

^tCH₄H₉
H
H
H
H
—
—

4-7
Ir
1
4
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
pic

4-7X
Ir
1
4
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
acac

4-7Y
Ir
0
4
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
—
—

4-8
Ir
1
4
Ph
CF₃
H
CF₃
H

^tCH₄H₉
H
H
H
H
pic

4-8X
Ir
1
4
Ph
CF₃
H
CF₃
H

^tCH₄H₉
H
H
H
H
acac

4-8Y
Ir
0
4
Ph
CF₃
H
CF₃
H

^tCH₄H₉
H
H
H
H
—
—

4-9
Ir
1
4
Ph
H
F
CF₃
H
CH₃
H
H
H
H
pic

4-9X
Ir
1
4
Ph
H
F
CF₃
H
CH₃
H
H
H
H
acac

4-9Y
Ir
0
4
Ph
H
F
CF₃
H
CH₃
H
H
H
H
—
—

4-10
Ir
1
4
Ph
F
H
CF₃
H
CH₃
H
H
H
H
pic

4-10X
Ir
1
4
Ph
F
H
CF₃
H
CH₃
H
H
H
H
acac

4-10Y
Ir
0
4
Ph
F
H
CF₃
H
CH₃
H
H
H
H
—
—

4-11
Ir
1
4
Ph
F
F
F
F
CH₃
H
H
H
H
pic

4-11X
Ir
1
4
Ph
F
F
F
F
CH₃
H
H
H
H
acac

4-11Y
Ir
0
4
Ph
F
F
F
F
CH₃
H
H
H
H
—
—

4-12
Ir
1
4
Ph
H
F
H
CH₃
CH₃
H
H
H
H
pic

4-12X
Ir
1
4
Ph
H
F
H
CH₃
CH₃
H
H
H
H
acac

4-12Y
Ir
0
4
Ph
H
F
H
CH₃
CH₃
H
H
H
H
—
—

4-13
Ir
1
4
Ph
H
F
H
CH₃

^tCH₄H₉
H
H
H
H
pic

4-13X
Ir
1
4
Ph
H
F
H
CH₃

^tCH₄H₉
H
H
H
H
acac

4-13Y
Ir
0
4
Ph
H
F
H
CH₃

^tCH₄H₉
H
H
H
H
—
—

4-14
Ir
1
4
Ph
H
F
H

^tCH₄H₉
CH₃
H
H
H
H
pic

4-14X
Ir
1
4
Ph
H
F
H

^tCH₄H₉
CH₃
H
H
H
H
acac

4-14Y
Ir
0
4
Ph
H
F
H

^tCH₄H₉
CH₃
H
H
H
H
—
—

4-15
Ir
1
4
Ph
H
F
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
pic

4-15X
Ir
1
4
Ph
H
F
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
acac

4-15Y
Ir
0
4
Ph
H
F
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
—
—

4-16
Ir
1
4
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
pic

4-16X
Ir
1
4
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
acac

4-16Y
Ir
0
4
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
—
—

4-17
Ir
1
4
Ph
H
CF₃
H
CF₃

^tCH₄H₉
H
H
H
H
pic

4-17X
Ir
1
4
Ph
H
CF₃
H
CF₃

^tCH₄H₉
H
H
H
H
acac

4-17Y
Ir
0
4
Ph
H
CF₃
H
CF₃

^tCH₄H₉
H
H
H
H
—
—

4-18
Ir
1
4
Ph
CF₃
H
H

^tCH₄H₉
CH₃
H
H
H
H
pic

4-18X
Ir
1
4
Ph
CF₃
H
H

^tCH₄H₉
CH₃
H
H
H
H
acac

4 -18Y
Ir
0
4
Ph
CF₃
H
H

^tCH₄H₉
CH₃
H
H
H
H
—
—

4-19
Ir
1
4
Ph
CF₃
H
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
pic

4-19X
Ir
1
4
Ph
CF₃
H
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
acac

4-19Y
Ir
0
4
Ph
CF₃
H
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
—
—

4-20
Ir
1
4
Ph
H
CF₃
H

^tCH₄H₉
CH₃
H
H
H
H
pic

4-20X
Ir
1
4
Ph
H
CF₃
H

^tCH₄H₉
CH₃
H
H
H
H
acac

4-20Y
Ir
0
4
Ph
H
CF₃
H

^tCH₄H₉
CH₃
H
H
H
H
—
—

4-21
Ir
1
4
Ph
H
CF₃
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
pic

4-21X
Ir
1
4
Ph
H
CF₃
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
acac

4-21Y
Ir
0
4
Ph
H
CF₃
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
—
—

4-22
Ir
1
4
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
pic

4-22X
Ir
1
4
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
acac

4-22Y
Ir
0
4
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
—
—

4-23
Ir
1
4
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
pic

4-23X
Ir
1
4
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
acac

4-23Y
Ir
0
4
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
—
—

4-24
Ir
1
4
Ph
H
H
NO₂
H
CH₃
H
H
H
H
pic

4-24X
Ir
1
4
Ph
H
H
NO₂
H
CH₃
H
H
H
H
acac

4-24Y
Ir
0
4
Ph
H
H
NO₂
H
CH₃
H
H
H
H
—
—

4-25
Ir
1
4
Ph
H
H
NO₂
H

^tCH₄H₉
H
H
H
H
pic

4-25X
Ir
1
4
Ph
H
H
NO₂
H

^tCH₄H₉
H
H
H
H
acac

4-25Y
Ir
0
4
Ph
H
H
NO₂
H

^tCH₄H₉
H
H
H
H
—
—

4-26
Ir
1
4
Ph
F
H
NO₂
H
CH₃
H
H
H
H
pic

4-26X
Ir
1
4
Ph
F
H
NO₂
H
CH₃
H
H
H
H
acac

4-26Y
Ir
0
4
Ph
F
H
NO₂
H
CH₃
H
H
H
H
—
—

4-27
Ir
1
4
Ph
F
H
NO₂
F
CH₃
H
H
H
H
pic

4-27X
Ir
1
4
Ph
F
H
NO₂
F
CH₃
H
H
H
H
acac

4-27Y
Ir
0
4
Ph
F
H
NO₂
F
CH₃
H
H
H
H
—
—

4-28
Ir
1
4
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
pic

4-28X
Ir
1
4
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
acac

4-28Y
Ir
0
4
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
—
—

4-29
Ir
1
4
Ph
H
NO₂
H
NO₂

^tCH₄H₉
H
H
H
H
pic

4-29X
Ir
1
4
Ph
H
NO₂
H
NO₂

^tCH₄H₉
H
H
H
H
acac

4-29Y
Ir
0
4
Ph
H
NO₂
H
NO₂

^tCH₄H₉
H
H
H
H
—
—

4-30
Ir
1
4
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
pic

4-30X
Ir
1
4
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
acac

4-30Y
Ir
0
4
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
—
—

4-31
Ir
1
4
Ph
NO₂
H
H
NO₂

^tCH₄H₉
H
H
H
H
pic

4-31X
Ir
1
4
Ph
NO₂
H
H
NO₂

^tCH₄H₉
H
H
H
H
acac

4-31Y
Ir
0
4
Ph
NO₂
H
H
NO₂

^tCH₄H₉
H
H
H
H
—
—

4-32
Ir
1
4
Ph
H
H
CF₃
H
CH₃
H
H
H
H
pic

4-32X
Ir
1
4
Ph
H
H
CF₃
H
CH₃
H
H
H
H
acac

4-32Y
Ir
0
4
Ph
H
H
CF₃
H
CH₃
H
H
H
H
—
—

4-33
Ir
1
4
Ph
H
H
CF₃
H

^tCH₄H₉
H
H
H
H
pic

4-33X
Ir
1
4
Ph
H
H
CF₃
H

^tCH₄H₉
H
H
H
H
acac

4-33Y
Ir
0
4
Ph
H
H
CF₃
H

^tCH₄H₉
H
H
H
H
—
—

4-34
Ir
1
4
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
pic

4-34X
Ir
1
4
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
acac

4-34Y
Ir
0
4
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
—
—

4-35
Ir
1
4
Ph
H
Cl
CF₃
H

^tCH₄H₉
H
H
H
H
pic

4-35X
Ir
1
4
Ph
H
Cl
CF₃
H

^tCH₄H₉
H
H
H
H
acac

4-35Y
Ir
0
4
Ph
H
Cl
CF₃
H

^tCH₄H₉
H
H
H
H
—
—

4-36
Ir
1
4
Ph
H
NO₂
H
H
CH₃
H
H
H
H
pic

4-36X
Ir
1
4
Ph
H
NO₂
H
H
CH₃
H
H
H
H
acac

4-36Y
Ir
0
4
Ph
H
NO₂
H
H
CH₃
H
H
H
H
—
—

4-37
Ir
1
4
Ph
H
CF₃
H
H
CH₃
H
H
H
H
pic

4-37X
Ir
1
4
Ph
H
CF₃
H
H
CH₃
H
H
H
H
acac

4-37Y
Ir
0
4
Ph
H
CF₃
H
H
CH₃
H
H
H
H
—
—

4-38
Ir
1
4
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
pic

4-38X
Ir
1
4
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
acac

4-38Y
Ir
0
4
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
—
—

4-39
Ir
1
4
Ph
H
NO₂
H
CH₃

^tCH₄H₉
H
H
H
H
pic

4-39X
Ir
1
4
Ph
H
NO₂
H
CH₃

^tCH₄H₉
H
H
H
H
acac

4-39Y
Ir
0
4
Ph
H
NO₂
H
CH₃

^tCH₄H₉
H
H
H
H
—
—

4-40
Ir
1
4
Ph
H
NO₂
H

^tCH₄H₉
CH₃
H
H
H
H
pic

4-40X
Ir
1
4
Ph
H
NO₂
H

^tCH₄H₉
CH₃
H
H
H
H
acac

4-40Y
Ir
0
4
Ph
H
NO₂
H

^tCH₄H₉
CH₃
H
H
H
H
—
—

4-41
Ir
1
4
Ph
H
NO₂
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
pic

4-41X
Ir
1
4
Ph
H
NO₂
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
acac

4-41Y
Ir
0
4
Ph
H
NO₂
H

^tCH₄H₉

^tCH₄H₉
H
H
H
H
—
—

4-42
Ir
1
4
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
pic

4-42X
Ir
1
4
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
acac

4-42Y
Ir
0
4
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
—
—

4-43
Ir
1
4
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
pic

4-43X
Ir
1
4
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
acac

4-43Y
Ir
0
4
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
—
—

4-44
Ir
1
4
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
pic

4-44X
Ir
1
4
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
acac

4-44Y
Ir
0
4
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
—
—

4-45
Ir
1
4
Ph
H
CH₃O
H

^tCH₄H₉
CH₃
H
H
H
H
pic

4-45X
Ir
1
4
Ph
H
CH₃O
H

^tCH₄H₉
CH₃
H
H
H
H
acac

4-45Y
Ir
0
4
Ph
H
CH₃O
H

^tCH₄H₉
CH₃
H
H
H
H
—
—

4-46
Ir
1
4
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
pic

4-46X
Ir
1
4
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
acac

4-46Y
Ir
0
4
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
—
—

4-47
Ir
1
4
Ph
H
Si(CH₃)₃
H
H

^tCH₄H₉
H
H
H
H
pic

4-47X
Ir
1
4
Ph
H
Si(CH₃)₃
H
H

^tCH₄H₉
H
H
H
H
acac

4-47Y
Ir
0
4
Ph
H
Si(CH₃)₃
H
H

^tCH₄H₉
H
H
H
H
—
—

4-48
Ir
1
4
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4-48X
Ir
1
4
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4-48Y
Ir
0
4
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4-49
Ir
1
4
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4-49X
Ir
1
4
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4-49Y
Ir
0
4
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4-50
Ir
1
4
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4-50X
Ir
1
4
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4-50Y
Ir
0
4
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4-51
Ir
1
4
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4-51X
Ir
1
4
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4-51Y
Ir
0
4
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4-52
Ir
1
4
Ph
H
CF₃
H
Si(CH₃)₃

^tCH₄H₉
H
H
H
H
pic

4-52X
Ir
1
4
Ph
H
CF₃
H
Si(CH₃)₃

^tCH₄H₉
H
H
H
H
acac

4-52Y
Ir
0
4
Ph
H
CF₃
H
Si(CH₃)₃

^tCH₄H₉
H
H
H
H
—
—

4-53
Ir
1
4
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
pic

4-53X
Ir
1
4
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
acac

4-53Y
Ir
0
4
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
—
—

4-54
Ir
1
4
Ph
H
Si(CH₃)₃
H
F

^tCH₄H₉
H
H
H
H
pic

4-54X
Ir
1
4
Ph
H
Si(CH₃)₃
H
F

^tCH₄H₉
H
H
H
H
acac

4-54Y
Ir
0
4
Ph
H
Si(CH₃)₃
H
F

^tCH₄H₉
H
H
H
H
—
—

4 -55
Ir
1
4
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
pic

4-55X
Ir
1
4
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
acac

4-55Y
Ir
0
4
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
—
—

4-56
Ir
1
4
Ph
H
Si(CH₃)₃
H
CF₃

^tCH₄H₉
H
H
H
H
pic

4-56X
Ir
1
4
Ph
H
Si(CH₃)₃
H
CF₃

^tCH₄H₉
H
H
H
H
acac

4-56Y
Ir
0
4
Ph
H
Si(CH₃)₃
H
CF₃

^tCH₄H₉
H
H
H
H
—
—

4-57
Ir
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4-57X
Ir
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4-57Y
Ir
0
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4-58
Ir
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tCH₄H₉
H
H
H
H
pic

4-58X
Ir
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tCH₄H₉
H
H
H
H
acac

4-58Y
Ir
0
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tCH₄H₉
H
H
H
H
—
—

4-59
Ir
1
4
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
pic

4-59X
Ir
1
4
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
acac

4-59Y
Ir
0
4
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
—
—

4-60
Ir
1
4
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
pic

4-60X
Ir
1
4
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
acac

4-60Y
Ir
0
4
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
—
—

4-61
Ir
1
4
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
pic

4-61X
Ir
1
4
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
acac

4 -61Y
Ir
0
4
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
—
—

4-62
Ir
1
4
Ph
H
H
BL
CH₃
H
H
H
H
pic

4-62X
Ir
1
4
Ph
H
H
BL
CH₃
H
H
H
H
acac

4-62Y
Ir
0
4
Ph
H
H
BL
CH₃
H
H
H
H
—
—

4-63
Ir
1
4
Ph
H
H
BL

^tCH₄H₉
H
H
H
H
pic

4-63X
Ir
1
4
Ph
H
H
BL

^tCH₄H₉
H
H
H
H
acac

4-63Y
Ir
0
4
Ph
H
H
BL

^tCH₄H₉
H
H
H
H
—
—

4-64
Ir
1
4
Ph
H
BL
H
CH₃
H
H
H
H
pic

4-64X
Ir
1
4
Ph
H
BL
H
CH₃
H
H
H
H
acac

4-64Y
Ir
0
4
Ph
H
BL
H
CH₃
H
H
H
H
—
—

4-65
Ir
1
4
Ph
H
BL
H

^tCH₄H₉
H
H
H
H
pic

4-65X
Ir
1
4
Ph
H
BL
H

^tCH₄H₉
H
H
H
H
acac

4-65Y
Ir
0
4
Ph
H
BL
H

^tCH₄H₉
H
H
H
H
—
—

4-66
Ir
1
4
Ph
H
H
PL
CH₃
H
H
H
H
pic

4-66X
Ir
1
4
Ph
H
H
PL
CH₃
H
H
H
H
acac

4-66Y
Ir
0
4
Ph
H
H
PL
CH₃
H
H
H
H
—
—

4-67
Ir
1
4
Ph
H
H
PL

^tCH₄H₉
H
H
H
H
pic

4-67X
Ir
1
4
Ph
H
H
PL

^tCH₄H₉
H
H
H
H
acac

4-67Y
Ir
0
4
Ph
H
H
PL

^tCH₄H₉
H
H
H
H
—
—

4-68
Ir
1
4
Ph
H
PL
H
CH₃
H
H
H
H
pic

4-68X
Ir
1
4
Ph
H
PL
H
CH₃
H
H
H
H
acac

4-68Y
Ir
0
4
Ph
H
PL
H
CH₃
H
H
H
H
—
—

4-69
Ir
1
4
Ph
H
PL
H

^tCH₄H₉
H
H
H
H
pic

4-69X
Ir
1
4
Ph
H
PL
H

^tCH₄H₉
H
H
H
H
acac

4-69Y
Ir
0
4
Ph
H
PL
H

^tCH₄H₉
H
H
H
H
—
—

4-70
Ir
1
4
Ph
H
H
MEE1
CH₃
H
H
H
H
pic

4-70X
Ir
1
4
Ph
H
H
MEE1
CH₃
H
H
H
H
acac

4-70Y
Ir
0
4
Ph
H
H
MEE1
CH₃
H
H
H
H
—
—

4-71
Ir
1
4
Ph
H
MEE1
H
CH₃
H
H
H
H
pic

4-71X
Ir
1
4
Ph
H
MEE1
H
CH₃
H
H
H
H
acac

4-71Y
Ir
0
4
Ph
H
MEE1
H
CH₃
H
H
H
H
—
—

4-72
Ir
1
4
Ph
H
H
MEE2
CH₃
H
H
H
H
pic

4-72X
Ir
1
4
Ph
H
H
MEE2
CH₃
H
H
H
H
acac

4-72Y
Ir
0
4
Ph
H
H
MEE2
CH₃
H
H
H
H
—
—

4-73
Ir
1
4
Ph
H
MEE2
H
CH₃
H
H
H
H
pic

4-73X
Ir
1
4
Ph
H
MEE2
H
CH₃
H
H
H
H
acac

4-73Y
Ir
0
4
Ph
H
MEE2
H
CH₃
H
H
H
H
—
—

4-74
Ir
1
4
Ph
H
H
PA1
CH₃
H
H
H
H
pic

4-74X
Ir
1
4
Ph
H
H
PA1
CH₃
H
H
H
H
acac

4-74Y
Ir
0
4
Ph
H
H
PA1
CH₃
H
H
H
H
—
—

4-75
Ir
1
4
Ph
H
PA1
H
CH₃
H
H
H
H
pic

4-75X
Ir
1
4
Ph
H
PA1
H
CH₃
H
H
H
H
acac

4-75Y
Ir
0
4
Ph
H
PA1
H
CH₃
H
H
H
H
—
—

4-76
Ir
1
4
Ph
H
H
PA2
CH₃
H
H
H
H
pic

4-76X
Ir
1
4
Ph
H
H
PA2
CH₃
H
H
H
H
acac

4-76Y
Ir
0
4
Ph
H
H
PA2
CH₃
H
H
H
H
—
—

4-77
Ir
1
4
Ph
H
PA2
H
CH₃
H
H
H
H
pic

4-77X
Ir
1
4
Ph
H
PA2
H
CH₃
H
H
H
H
acac

4-77Y
Ir
0
4
Ph
H
PA2
H
CH₃
H
H
H
H
—
—

4-78
Ir
1
4
Ph
H
H
EA1
CH₃
H
H
H
H
pic

4-78X
Ir
1
4
Ph
H
H
EA1
CH₃
H
H
H
H
acac

4-78Y
Ir
0
4
Ph
H
H
EA1
CH₃
H
H
H
H
—
—

4-79
Ir
1
4
Ph
H
EA2
H
CH₃
H
H
H
H
pic

4-79X
Ir
1
4
Ph
H
EA2
H
CH₃
H
H
H
H
acac

4-79Y
Ir
0
4
Ph
H
EA2
H
CH₃
H
H
H
H
—
—

4-80
Ir
1
4
Ph
H
H
ME
CH₃
H
H
H
H
pic

4-80X
Ir
1
4
Ph
H
H
ME
CH₃
H
H
H
H
acac

4-80Y
Ir
0
4
Ph
H
H
ME
CH₃
H
H
H
H
—
—

4-81
Ir
1
4
Ph
H
ME
H
CH₃
H
H
H
H
pic

4-81X
Ir
1
4
Ph
H
ME
H
CH₃
H
H
H
H
acac

4-81Y
Ir
0
4
Ph
H
ME
H
CH₃
H
H
H
H
—
—

4-82
Ir
1
4
Ph
H
H
AT
CH₃
H
H
H
H
pic

4-82X
Ir
1
4
Ph
H
H
AT
CH₃
H
H
H
H
acac

4-82Y
Ir
0
4
Ph
H
H
AT
CH₃
H
H
H
H
—
—

4-83
Ir
1
4
Ph
H
AT
H
CH₃
H
H
H
H
pic

4-83X
Ir
1
4
Ph
H
AT
H
CH₃
H
H
H
H
acac

4-83Y
Ir
0
4
Ph
H
AT
H
CH₃
H
H
H
H
—
—

4-84
Ir
1
4
Ph
H
H
MES1
CH₃
H
H
H
H
pic

4-84X
Ir
1
4
Ph
H
H
MES1
CH₃
H
H
H
H
acac

4-84Y
Ir
0
4
Ph
H
H
MES1
CH₃
H
H
H
H
—
—

4-85
Ir
1
4
Ph
H
MES1
H
CH₃
H
H
H
H
pic

4-85X
Ir
1
4
Ph
H
MES1
H
CH₃
H
H
H
H
acac

4-85Y
Ir
0
4
Ph
H
MES1
H
CH₃
H
H
H
H
—
—

4-86
Ir
1
4
Ph
H
H
MES2
CH₃
H
H
H
H
pic

4-86X
Ir
1
4
Ph
H
H
MES2
CH₃
H
H
H
H
acac

4-86Y
Ir
0
4
Ph
H
H
MES2
CH₃
H
H
H
H
—
—

4-87
Ir
1
4
Ph
H
MES2
H
CH₃
H
H
H
H
pic

4-87X
Ir
1
4
Ph
H
MES2
H
CH₃
H
H
H
H
acac

4-87Y
Ir
0
4
Ph
H
MES2
H
CH₃
H
H
H
H
—
—

4-88
Ir
1
4
Ph
H
H
PS1
CH₃
H
H
H
H
pic

4-88X
Ir
1
4
Ph
H
H
PS1
CH₃
H
H
H
H
acac

4-88Y
Ir
0
4
Ph
H
H
PS1
CH₃
H
H
H
H
—
—

4-89
Ir
1
4
Ph
H
PS1
H
CH₃
H
H
H
H
pic

4-89X
Ir
1
4
Ph
H
PS1
H
CH₃
H
H
H
H
acac

4-89Y
Ir
0
4
Ph
H
PS1
H
CH₃
H
H
H
H
—
—

4-90
Ir
1
4
Ph
H
H
PS2
CH₃
H
H
H
H
pic

4-90X
Ir
1
4
Ph
H
H
PS2
CH₃
H
H
H
H
acac

4-90Y
Ir
0
4
Ph
H
H
PS2
CH₃
H
H
H
H
—
—

4-91
Ir
1
4
Ph
H
PS2
H
CH₃
H
H
H
H
pic

4-91X
Ir
1
4
Ph
H
PS2
H
CH₃
H
H
H
H
acac

4-91Y
Ir
0
4
Ph
H
PS2
H
CH₃
H
H
H
H
—
—

4-92
Ir
1
4
Ph
H
H
BAL1
CH₃
H
H
H
H
pic

4-92X
Ir
1
4
Ph
H
H
BAL1
CH₃
H
H
H
H
acac

4-92Y
Ir
0
4
Ph
H
H
BAL1
CH₃
H
H
H
H
—
—

4-93
Ir
1
4
Ph
H
BAL1
H
CH₃
H
H
H
H
pic

4-93X
Ir
1
4
Ph
H
BAL1
H
CH₃
H
H
H
H
acac

4-93Y
Ir
0
4
Ph
H
BAL1
H
CH₃
H
H
H
H
—
—

4-94
Ir
1
4
Ph
H
H
BAL2
CH₃
H
H
H
H
pic

4-94X
Ir
1
4
Ph
H
H
BAL2
CH₃
H
H
H
H
acac

4-94Y
Ir
0
4
Ph
H
H
BAL2
CH₃
H
H
H
H
—
—

4-95
Ir
1
4
Ph
H
BAL2
H
CH₃
H
H
H
H
pic

4-95X
Ir
1
4
Ph
H
BAL2
H
CH₃
H
H
H
H
acac

4-95Y
Ir
0
4
Ph
H
BAL2
H
CH₃
H
H
H
H
—
—

4-96
Ir
1
4
Ph
H
H
MEK1
CH₃
H
H
H
H
pic

4-96X
Ir
1
4
Ph
H
H
MEK1
CH₃
H
H
H
H
acac

4-96Y
Ir
0
4
Ph
H
H
MEK1
CH₃
H
H
H
H
—
—

4-97
Ir
1
4
Ph
H
MEK1
H
CH₃
H
H
H
H
pic

4-97X
Ir
1
4
Ph
H
MEK1
H
CH₃
H
H
H
H
acac

4-97Y
Ir
0
4
Ph
H
MEK1
H
CH₃
H
H
H
H
—
—

4-98
Ir
1
4
Ph
H
H
MEK2
CH₃
H
H
H
H
pic

4-98X
Ir
1
4
Ph
H
H
MEK2
CH₃
H
H
H
H
acac

4-98Y
Ir
0
4
Ph
H
H
MEK2
CH₃
H
H
H
H
—
—

4-99
Ir
1
4
Ph
H
MEK2
H
CH₃
H
H
H
H
pic

4-99X
Ir
1
4
Ph
H
MEK2
H
CH₃
H
H
H
H
acac

4-99Y
Ir
0
4
Ph
H
MEK2
H
CH₃
H
H
H
H
—
—

4-100
Ir
1
4
Ph
H
H
PAL1
CH₃
H
H
H
H
pic

4-100X
Ir
1
4
Ph
H
H
PAL1
CH₃
H
H
H
H
acac

4-100Y
Ir
0
4
Ph
H
H
PAL1
CH₃
H
H
H
H
—
—

4-101
Ir
1
4
Ph
H
PAL1
H
CH₃
H
H
H
H
pic

4-101X
Ir
1
4
Ph
H
PAL1
H
CH₃
H
H
H
H
pic

4-101Y
Ir
0
4
Ph
H
PAL1
H
CH₃
H
H
H
H
—
—

4-102
Ir
1
4
Ph
H
H
PAL2
CH₃
H
H
H
H
pic

4-102X
Ir
1
4
Ph
H
H
PAL2
CH₃
H
H
H
H
acac

4-102Y
Ir
0
4
Ph
H
H
PAL2
CH₃
H
H
H
H
—
—

4-103
Ir
1
4
Ph
H
PAL2
H
CH₃
H
H
H
H
pic

4-103X
Ir
1
4
Ph
H
PAL2
H
CH₃
H
H
H
H
acac

4-103Y
Ir
0
4
Ph
H
PAL2
H
CH₃
H
H
H
H
—
—

4-104
Ir
1
4
Ph
H
H
MMK
CH₃
H
H
H
H
pic

4-104X
Ir
1
4
Ph
H
H
MMK
CH₃
H
H
H
H
acac

4-104Y
Ir
0
4
Ph
H
H
MMK
CH₃
H
H
H
H
—
—

4-105
Ir
1
4
Ph
H
MMK
H
CH₃
H
H
H
H
pic

4-105X
Ir
1
4
Ph
H
MMK
H
CH₃
H
H
H
H
acac

4-105Y
Ir
0
4
Ph
H
MMK
H
CH₃
H
H
H
H
—
—

4-106
Ir
1
4
Ph
H
H
EES1
CH₃
H
H
H
H
pic

4-106X
Ir
1
4
Ph
H
H
EES1
CH₃
H
H
H
H
acac

4-106Y
Ir
0
4
Ph
H
H
EES1
CH₃
H
H
H
H
—
—

4-107
Ir
1
4
Ph
H
EES2
H
CH₃
H
H
H
H
pic

4-107X
Ir
1
4
Ph
H
EES2
H
CH₃
H
H
H
H
acac

4-107Y
Ir
0
4
Ph
H
EES2
H
CH₃
H
H
H
H
—
—

4-108
Ir
1
4
Ph
H
H
PAE1
CH₃
H
H
H
H
pic

4-108X
Ir
1
4
Ph
H
H
PAE1
CH₃
H
H
H
H
acac

4-108Y
Ir
0
4
Ph
H
H
PAE1
CH₃
H
H
H
H
—
—

4-109
Ir
1
4
Ph
H
PAE2
H
CH₃
H
H
H
H
pic

4-109X
Ir
1
4
Ph
H
PAE2
H
CH₃
H
H
H
H
acac

4-109Y
Ir
0
4
Ph
H
PAE2
H
CH₃
H
H
H
H
—
—

4-110
Ir
1
4
Ph
H
H
AME1
CH₃
H
H
H
H
pic

4-110X
Ir
1
4
Ph
H
H
AME1
CH₃
H
H
H
H
acac

4-110Y
Ir
0
4
Ph
H
H
AME1
CH₃
H
H
H
H
—
—

4-111
Ir
1
4
Ph
H
AME1
H
CH₃
H
H
H
H
pic

4-111X
Ir
1
4
Ph
H
AME1
H
CH₃
H
H
H
H
acac

4-111Y
Ir
0
4
Ph
H
AME1
H
CH₃
H
H
H
H
—
—

4-112
Ir
1
4
Ph
H
H
AME2
CH₃
H
H
H
H
pic

4-112X
Ir
1
4
Ph
H
H
AME2
CH₃
H
H
H
H
acac

4-112Y
Ir
0
4
Ph
H
H
AME2
CH₃
H
H
H
H
—
—

4-113
Ir
1
4
Ph
H
AME2
H
CH₃
H
H
H
H
pic

4-113X
Ir
1
4
Ph
H
AME2
H
CH₃
H
H
H
H
acac

4-113Y
Ir
0
4
Ph
H
AME2
H
CH₃
H
H
H
H
—
—

4-114
Ir
1
4
Ph
H
H
EAE1
CH₃
H
H
H
H
pic

4-114X
Ir
1
4
Ph
H
H
EAE1
CH₃
H
H
H
H
acac

4-114Y
Ir
0
4
Ph
H
H
EAE1
CH₃
H
H
H
H
—
—

4-115
Ir
1
4
Ph
H
EAE1
H
CH₃
H
H
H
H
pic

4-115X
Ir
1
4
Ph
H
EAE1
H
CH₃
H
H
H
H
acac

4-115Y
Ir
0
4
Ph
H
EAE1
H
CH₃
H
H
H
H
—
—

4-116
Ir
1
4
Ph
H
H
EAE2
CH₃
H
H
H
H
pic

4-116X
Ir
1
4
Ph
H
H
EAE2
CH₃
H
H
H
H
acac

4-116Y
Ir
0
4
Ph
H
H
EAE2
CH₃
H
H
H
H
—
—

4-117
Ir
1
4
Ph
H
EAE2
H
CH₃
H
H
H
H
pic

4-117X
Ir
1
4
Ph
H
EAE2
H
CH₃
H
H
H
H
acac

4-117Y
Ir
0
4
Ph
H
EAE2
H
CH₃
H
H
H
H
—
—

4-118
Ir
1
4
Ph
H
H
AAE1
CH₃
H
H
H
H
pic

4-118X
Ir
1
4
Ph
H
H
AAE1
CH₃
H
H
H
H
acac

4-118Y
Ir
0
4
Ph
H
H
AAE1
CH₃
H
H
H
H
—
—

4-119
Ir
1
4
Ph
H
AAE1
H
CH₃
H
H
H
H
pic

4-119X
Ir
1
4
Ph
H
AAE1
H
CH₃
H
H
H
H
acac

4-119Y
Ir
0
4
Ph
H
AAE1
H
CH₃
H
H
H
H
—
—

4-120
Ir
1
4
Ph
H
H
AAE2
CH₃
H
H
H
H
pic

4-120X
Ir
1
4
Ph
H
H
AAE2
CH₃
H
H
H
H
acac

4-120Y
Ir
0
4
Ph
H
H
AAE2
CH₃
H
H
H
H
—
—

4-121
Ir
1
4
Ph
H
AAE2
H
CH₃
H
H
H
H
pic

4-121X
Ir
1
4
Ph
H
AAE2
H
CH₃
H
H
H
H
acac

4-121Y
Ir
0
4
Ph
H
AAE2
H
CH₃
H
H
H
H
—
—

4-122
Ir
1
4
Ph
H
H
PME1
CH₃
H
H
H
H
pic

4-122X
Ir
1
4
Ph
H
H
PME1
CH₃
H
H
H
H
acac

4-122Y
Ir
0
4
Ph
H
H
PME1
CH₃
H
H
H
H
—
—

4-123
Ir
1
4
Ph
H
PME1
H
CH₃
H
H
H
H
pic

4-123X
Ir
1
4
Ph
H
PME1
H
CH₃
H
H
H
H
acac

4-123Y
Ir
0
4
Ph
H
PME1
H
CH₃
H
H
H
H
—
—

4-124
Ir
1
4
Ph
H
H
PME2
CH₃
H
H
H
H
pic

4-124X
Ir
1
4
Ph
H
H
PME2
CH₃
H
H
H
H
acac

4-124Y
Ir
0
4
Ph
H
H
PME2
CH₃
H
H
H
H
—
—

4-125
Ir
1
4
Ph
H
PME2
H
CH₃
H
H
H
H
pic

4-125X
Ir
1
4
Ph
H
PME2
H
CH₃
H
H
H
H
acac

4-125Y
Ir
0
4
Ph
H
PME2
H
CH₃
H
H
H
H
—
—

4-126
Ir
1
4
Ph
H
H
MET1
CH₃
H
H
H
H
pic

4-126X
Ir
1
4
Ph
H
H
MET1
CH₃
H
H
H
H
acac

4-126Y
Ir
0
4
Ph
H
H
MET1
CH₃
H
H
H
H
—
—

4-127
Ir
1
4
Ph
H
MET1
H
CH₃
H
H
H
H
pic

4-127X
Ir
1
4
Ph
H
MET1
H
CH₃
H
H
H
H
acac

4-127Y
Ir
0
4
Ph
H
MET1
H
CH₃
H
H
H
H
—
—

4-128
Ir
1
4
Ph
H
H
MET2
CH₃
H
H
H
H
pic

4-128X
Ir
1
4
Ph
H
H
MET2
CH₃
H
H
H
H
acac

4-128Y
Ir
0
4
Ph
H
H
MET2
CH₃
H
H
H
H
—
—

4-129
Ir
1
4
Ph
H
MET2
H
CH₃
H
H
H
H
pic

4-129X
Ir
1
4
Ph
H
MET2
H
CH₃
H
H
H
H
acac

4-129Y
Ir
0
4
Ph
H
MET2
H
CH₃
H
H
H
H
—
—

4-130
Ir
1
4
Ph
H
H
EE1
CH₃
H
H
H
H
pic

4-130X
Ir
1
4
Ph
H
H
EE1
CH₃
H
H
H
H
acac

4-130Y
Ir
0
4
Ph
H
H
EE1
CH₃
H
H
H
H
—
—

4-131
Ir
1
4
Ph
H
EE1
H
CH₃
H
H
H
H
pic

4-131X
Ir
1
4
Ph
H
EE1
H
CH₃
H
H
H
H
acac

4-131Y
Ir
0
4
Ph
H
EE1
H
CH₃
H
H
H
H
—
—

4-132
Ir
1
4
Ph
H
H
EE2
CH₃
H
H
H
H
pic

4-132X
Ir
1
4
Ph
H
H
EE2
CH₃
H
H
H
H
acac

4-132Y
Ir
0
4
Ph
H
H
EE2
CH₃
H
H
H
H
—
—

4-133
Ir
1
4
Ph
H
EE2
H
CH₃
H
H
H
H
pic

4-133X
Ir
1
4
Ph
H
EE2
H
CH₃
H
H
H
H
acac

4-133Y
Ir
0
4
Ph
H
EE2
H
CH₃
H
H
H
H
—
—

4-134t
Ir
1
4
Ph
H
H
MS1
CH₃
H
H
H
H
pic

4-134X
Ir
1
4
Ph
H
H
MS1
CH₃
H
H
H
H
acac

4-134Y
Ir
0
4
Ph
H
H
MS1
CH₃
H
H
H
H
—
—

4-135
Ir
1
4
Ph
H
MS1
H
CH₃
H
H
H
H
pic

4-135X
Ir
1
4
Ph
H
MS1
H
CH₃
H
H
H
H
acac

4-135Y
Ir
0
4
Ph
H
MS1
H
CH₃
H
H
H
H
—
—

4-136
Ir
1
4
Ph
H
H
MS2
CH₃
H
H
H
H
pic

4-136X
Ir
1
4
Ph
H
H
MS2
CH₃
H
H
H
H
acac

4-136Y
Ir
0
4
Ph
H
H
MS2
CH₃
H
H
H
H
—
—

4-137
Ir
1
4
Ph
H
MS2
H
CH₃
H
H
H
H
pic

4-137X
Ir
1
4
Ph
H
MS2
H
CH₃
H
H
H
H
acac

4-137Y
Ir
0
4
Ph
H
MS2
H
CH₃
H
H
H
H
—
—

TABLE 5

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

5-1
Ir
1
5
Ph
H
H
H
H
H
CH3
H
pic

5-1X
Ir
1
5
Ph
H
H
H
H
H
CH3
H
acac

5-1Y
Ir
0
5
Ph
H
H
H
H
H
CH3
H
—
—

5-2
Ir
1
5
Ph
H
H
H
H
H

^tCH₄H₉
H
pic

5-2X
Ir
1
5
Ph
H
H
H
H
H

^tCH₄H₉
H
acac

5-2Y
Ir
0
5
Ph
H
H
H
H
H

^tCH₄H₉
H
—
—

5-3
Ir
1
5
Ph
H
F
H
F
H
CH₃
H
pic

5-3X
Ir
1
5
Ph
H
F
H
F
H
CH₃
H
acac

5-3Y
Ir
0
5
Ph
H
F
H
F
H
CH₃
H
—
—

5-4
Ir
1
5
Ph
H
F
H
F
H

^tCH₄H₉
H
pic

5-4X
Ir
1
5
Ph
H
F
H
F
H

^tCH₄H₉
H
acac

5-4Y
Ir
0
5
Ph
H
F
H
F
H

^tCH₄H₉
H
—
—

5-5
Ir
1
5
Ph
CF₃
H
CF₃
H
H
CH₃
H
pic

5-5X
Ir
1
5
Ph
CF₃
H
CF₃
H
H
CH₃
H
acac

5-5Y
Ir
0
5
Ph
CF₃
H
CF₃
H
H
CH₃
H
—
—

5-6
Ir
1
5
Ph
CF₃
H
CF₃
H
H

^tCH₄H₉
H
pic

5-6X
Ir
1
5
Ph
CF₃
H
CF₃
H
H

^tCH₄H₉
H
acac

5-6Y
Ir
0
5
Ph
CF₃
H
CF₃
H
H

^tCH₄H₉
H
—
—

5-7
Ir
1
5
Ph
H
F
CF₃
H
H
CH₃
H
pic

5-7X
Ir
1
5
Ph
H
F
CF₃
H
H
CH₃
H
acac

5-7Y
Ir
0
5
Ph
H
F
CF₃
H
H
CH₃
H
—
—

5-8
Ir
1
5
Ph
F
H
CF₃
H
H
CH₃
H
pic

5-8X
Ir
1
5
Ph
F
H
CF₃
H
H
CH₃
H
acac

5-8Y
Ir
0
5
Ph
F
H
CF₃
H
H
CH₃
H
—
—

5-9
Ir
1
5
Ph
F
F
F
F
H
CH₃
H
pic

5-9X
Ir
1
5
Ph
F
F
F
F
H
CH₃
H
acac

5-9Y
Ir
0
5
Ph
F
F
F
F
H
CH₃
H
—
—

5-10
Ir
1
5
Ph
H
F
H
CH₃
H
CH₃
H
pic

5-10X
Ir
1
5
Ph
H
F
H
CH₃
H
CH₃
H
acac

5-10Y
Ir
0
5
Ph
H
F
H
CH₃
H
CH₃
H
—
—

5-11
Ir
1
5
Ph
H
F
H
CH₃
H

^tCH₄H₉
H
pic

5-11X
Ir
1
5
Ph
H
F
H
CH₃
H

^tCH₄H₉
H
acac

5-11Y
Ir
0
5
Ph
H
F
H
CH₃
H

^tCH₄H₉
H
—
—

5-12
Ir
1
5
Ph
H
F
H

^tCH₄H₉
H
CH₃
H
pic

5-12X
Ir
1
5
Ph
H
F
H

^tCH₄H₉
H
CH₃
H
acac

5-12Y
Ir
0
5
Ph
H
F
H

^tCH₄H₉
H
CH₃
H
—
—

5-13
Ir
1
5
Ph
H
F
H

^tCH₄H₉
H

^tCH₄H₉
H
pic

5-13X
Ir
1
5
Ph
H
F
H

^tCH₄H₉
H

^tCH₄H₉
H
acac

5-13Y
Ir
0
5
Ph
H
F
H

^tCH₄H₉
H

^tCH₄H₉
H
—
—

5-14
Ir
1
5
Ph
H
CF₃
H
CF₃
H
CH₃
H
pic

5-14X
Ir
1
5
Ph
H
CF₃
H
CF₃
H
CH₃
H
acac

5-14Y
Ir
0
5
Ph
H
CF₃
H
CF₃
H
CH₃
H
—
—

5-15
Ir
1
5
Ph
H
CF₃
H
CF₃
H

^tCH₄H₉
H
pic

5-15X
Ir
1
5
Ph
H
CF₃
H
CF₃
H

^tCH₄H₉
H
acac

5-15Y
Ir
0
5
Ph
H
CF₃
H
CF₃
H

^tCH₄H₉
H
—
—

5-16
Ir
1
5
Ph
CF₃
H
H

^tCH₄H₉
H
CH₃
H
pic

5-16X
Ir
1
5
Ph
CF₃
H
H

^tCH₄H₉
H
CH₃
H
acac

5-16Y
Ir
0
5
Ph
CF₃
H
H

^tCH₄H₉
H
CH₃
H
—
—

5-17
Ir
1
5
Ph
CF₃
H
H

^tCH₄H₉
H

^tCH₄H₉
H
pic

5-17X
Ir
1
5
Ph
CF₃
H
H

^tCH₄H₉
H

^tCH₄H₉
H
acac

5-17Y
Ir
0
5
Ph
CF₃
H
H

^tCH₄H₉
H

^tCH₄H₉
H
—
—

5-18
Ir
1
5
Ph
H
CF₃
H

^tCH₄H₉
H
CH₃
H
pic

5-18X
Ir
1
5
Ph
H
CF₃
H

^tCH₄H₉
H
CH₃
H
acac

5-18Y
Ir
0
5
Ph
H
CF₃
H

^tCH₄H₉
H
CH₃
H
—
—

5-19
Ir
1
5
Ph
H
CF₃
H

^tCH₄H₉
H

^tCH₄H₉
H
pic

5-19X
Ir
1
5
Ph
H
CF₃
H

^tCH₄H₉
H

^tCH₄H₉
H
acac

5-19Y
Ir
0
5
Ph
H
CF₃
H

^tCH₄H₉
H

^tCH₄H₉
H
—
—

5-20
Ir
1
5
Ph
H
CF₃
H
CH₃
H
CH₃
H
pic

5-20X
Ir
1
5
Ph
H
CF₃
H
CH₃
H
CH₃
H
acac

5-20Y
Ir
0
5
Ph
H
CF₃
H
CH₃
H
CH₃
H
—
—

5-21
Ir
1
5
Ph
H
CF₃
CF₃
H
H
CH₃
H
pic

5-21X
Ir
1
5
Ph
H
CF₃
CF₃
H
H
CH₃
H
acac

5-21Y
Ir
0
5
Ph
H
CF₃
CF₃
H
H
CH₃
H
—
—

5-22
Ir
1
5
Ph
H
H
NO₂
H
H
CH₃
H
pic

5-22X
Ir
1
5
Ph
H
H
NO₂
H
H
CH₃
H
acac

5-22Y
Ir
0
5
Ph
H
H
NO₂
H
H
CH₃
H
—
—

5-23
Ir
1
5
Ph
H
H
NO₂
H
H

^tCH₄H₉
H
pic

5-23X
Ir
1
5
Ph
H
H
NO₂
H
H

^tCH₄H₉
H
acac

5-23Y
Ir
0
5
Ph
H
H
NO₂
H
H

^tCH₄H₉
H
—
—

5-24
Ir
1
5
Ph
F
H
NO₂
H
H
CH₃
H
pic

5-24X
Ir
1
5
Ph
F
H
NO₂
H
H
CH₃
H
acac

5-24Y
Ir
0
5
Ph
F
H
NO₂
H
H
CH₃
H
—
—

5-25
Ir
1
5
Ph
F
H
NO₂
H
H

^tCH₄H₉
H
pic

5-25X
Ir
1
5
Ph
F
H
NO₂
H
H

^tCH₄H₉
H
acac

5-25Y
Ir
0
5
Ph
F
H
NO₂
H
H

^tCH₄H₉
H
—
—

5-026
Ir
1
5
Ph
F
H
NO₂
F
H
CH₃
H
pic

5-26X
Ir
1
5
Ph
F
H
NO₂
F
H
CH₃
H
acac

5-26Y
Ir
0
5
Ph
F
H
NO₂
F
H
CH₃
H
—
—

5-27
Ir
1
5
Ph
F
H
NO₂
F
H

^tCH₄H₉
H
pic

5-27X
Ir
1
5
Ph
F
H
NO₂
F
H

^tCH₄H₉
H
acac

5-27Y
Ir
0
5
Ph
F
H
NO₂
F
H

^tCH₄H₉
H
—
—

5-28
Ir
1
5
Ph
H
NO₂
H
NO₂
H
CH₃
H
pic

5-28X
Ir
1
5
Ph
H
NO₂
H
NO₂
H
CH₃
H
acac

5-28Y
Ir
0
5
Ph
H
NO₂
H
NO₂
H
CH₃
H
—
—

5-29
Ir
1
5
Ph
H
NO₂
H
NO₂
H

^tCH₄H₉
H
pic

5-29X
Ir
1
5
Ph
H
NO₂
H
NO₂
H

^tCH₄H₉
H
acac

5-29Y
Ir
0
5
Ph
H
NO₂
H
NO₂
H

^tCH₄H₉
H
—
—

5-30
Ir
1
5
Ph
NO₂
H
H
NO₂
H
CH₃
H
pic

5-30X
Ir
1
5
Ph
NO₂
H
H
NO₂
H
CH₃
H
acac

5-30Y
Ir
0
5
Ph
NO₂
H
H
NO₂
H
CH₃
H
—
—

5-31
Ir
1
5
Ph
H
H
CF₃
H
H
CH₃
H
pic

5-31X
Ir
1
5
Ph
H
H
CF₃
H
H
CH₃
H
acac

5-31Y
Ir
0
5
Ph
H
H
CF₃
H
H
CH₃
H
—
—

5-32
Ir
1
5
Ph
H
Cl
CF₃
H
H
CH₃
H
pic

5-32X
Ir
1
5
Ph
H
Cl
CF₃
H
H
CH₃
H
acac

5-32Y
Ir
0
5
Ph
H
Cl
CF₃
H
H
CH₃
H
—
—

5-33
Ir
1
5
Ph
H
Cl
CF₃
H
H

^tCH₄H₉
H
pic

5-33X
Ir
1
5
Ph
H
Cl
CF₃
H
H

^tCH₄H₉
H
acac

5-33Y
Ir
0
5
Ph
H
Cl
CF₃
H
H

^tCH₄H₉
H
—
—

5-34
Ir
1
5
Ph
H
NO₂
H
H
H
CH₃
H
pic

5-34X
Ir
1
5
Ph
H
NO₂
H
H
H
CH₃
H
acac

5-34Y
Ir
0
5
Ph
H
NO₂
H
H
H
CH₃
H
—
—

5-35
Ir
1
5
Ph
H
CF₃
H
H
H
CH₃
H
pic

5-35X
Ir
1
5
Ph
H
CF₃
H
H
H
CH₃
H
acac

5-35Y
Ir
0
5
Ph
H
CF₃
H
H
H
CH₃
H
—
—

5-36
Ir
1
5
Ph
H
NO₂
H
CH₃
H
CH₃
H
pic

5-36X
Ir
1
5
Ph
H
NO₂
H
CH₃
H
CH₃
H
acac

5-36Y
Ir
0
5
Ph
H
NO₂
H
CH₃
H
CH₃
H
—
—

5-37
Ir
1
5
Ph
H
NO₂
H
CH₃
H

^tCH₄H₉
H
pic

5-37X
Ir
1
5
Ph
H
NO₂
H
CH₃
H

^tCH₄H₉
H
acac

5-37Y
Ir
0
5
Ph
H
NO₂
H
CH₃
H

^tCH₄H₉
H
—
—

5-38
Ir
1
5
Ph
H
NO₂
H

^tCH₄H₉
H
CH₃
H
pic

5-38X
Ir
1
5
Ph
H
NO₂
H

^tCH₄H₉
H
CH₃
H
acac

5-38Y
Ir
0
5
Ph
H
NO₂
H

^tCH₄H₉
H
CH₃
H
—
—

5-39
Ir
1
5
Ph
H
H
CH₃O
H
H
CH₃
H
pic

5-39X
Ir
1
5
Ph
H
H
CH₃O
H
H
CH₃
H
acac

5-39Y
Ir
0
5
Ph
H
H
CH₃O
H
H
CH₃
H
—
—

5-40
Ir
1
5
Ph
H
CH₃O
H
H
H
CH₃
H
pic

5-40X
Ir
1
5
Ph
H
CH₃O
H
H
H
CH₃
H
acac

5-40Y
Ir
0
5
Ph
H
CH₃O
H
H
H
CH₃
H
—
—

5-41
Ir
1
5
Ph
H
CH₃O
H
CH₃
H
CH₃
H
pic

5-41X
Ir
1
5
Ph
H
CH₃O
H
CH₃
H
CH₃
H
acac

5-41Y
Ir
0
5
Ph
H
CH₃O
H
CH₃
H
CH₃
H
—
—

5-42
Ir
1
5
Ph
H
CH₃O
H

^tCH₄H₉
H
CH₃
H
pic

5-42X
Ir
1
5
Ph
H
CH₃O
H

^tCH₄H₉
H
CH₃
H
acac

5-42Y
Ir
0
5
Ph
H
CH₃O
H

^tCH₄H₉
H
CH₃
H
—
—

5-43
Ir
1
5
Ph
H
H
H
H

^tCH₄H₉
CH₃
H
pic

5-43X
Ir
1
5
Ph
H
H
H
H

^tCH₄H₉
CH₃
H
acac

5-43Y
Ir
0
5
Ph
H
H
H
H

^tCH₄H₉
CH₃
H
—
—

5-44
Ir
1
5
Ph
H
F
H
F

^tCH₄H₉
CH₃
H
pic

5-44X
Ir
1
5
Ph
H
F
H
F

^tCH₄H₉
CH₃
H
acac

5-44Y
Ir
0
5
Ph
H
F
H
F

^tCH₄H₉
CH₃
H
—
—

5-45
Ir
1
5
Ph
H
F
H
F

^tCH₄H₉

^tCH₄H₉
H
pic

5-45X
Ir
1
5
Ph
H
F
H
F

^tCH₄H₉

^tCH₄H₉
H
acac

5-45Y
Ir
0
5
Ph
H
F
H
F

^tCH₄H₉

^tCH₄H₉
H
—
—

5-46
Ir
1
5
Ph
CF₃
H
CF₃
H

^tCH₄H₉
CH₃
H
pic

5-46X
Ir
1
5
Ph
CF₃
H
CF₃
H

^tCH₄H₉
CH₃
H
acac

5-46Y
Ir
0
5
Ph
CF₃
H
CF₃
H

^tCH₄H₉
CH₃
H
—
—

5-47
Ir
1
5
Ph
CF₃
H
CF₃
H

^tCH₄H₉

^tCH₄H₉
H
pic

5-47X
Ir
1
5
Ph
CF₃
H
CF₃
H

^tCH₄H₉

^tCH₄H₉
H
acac

5-47Y
Ir
0
5
Ph
CF₃
H
CF₃
H

^tCH₄H₉

^tCH₄H₉
H
—
—

5-48
Ir
1
5
Ph
H
CF₃
H
CH₃

^tCH₄H₉
CH₃
H
pic

5-48X
Ir
1
5
Ph
H
CF₃
H
CH₃

^tCH₄H₉
CH₃
H
acac

5-48Y
Ir
0
5
Ph
H
CF₃
H
CH₃

^tCH₄H₉
CH₃
H
—
—

5-49
Ir
1
5
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
pic

5-49X
Ir
1
5
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
acac

5-49Y
Ir
0
5
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
—
—

5-50
Ir
1
5
Ph
H
Si(CH₃)₃
H
H
H

^tCH₄H₉
H
pic

5-50X
Ir
1
5
Ph
H
Si(CH₃)₃
H
H
H

^tCH₄H₉
H
acac

5-50Y
Ir
0
5
Ph
H
Si(CH₃)₃
H
H
H

^tCH₄H₉
H
—
—

5-51
Ir
1
5
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
pic

5-51X
Ir
1
5
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
acac

5-51Y
Ir
0
5
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
—
—

5-52
Ir
1
5
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
pic

5-52X
Ir
1
5
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
acac

5-52Y
Ir
0
5
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
—
—

5-53
Ir
1
5
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
pic

5-53X
Ir
1
5
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
acac

5-53Y
Ir
0
5
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
—
—

5-54
Ir
1
5
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
pic

5-54X
Ir
1
5
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
acac

5-54Y
Ir
0
5
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
—
—

5-55
Ir
1
5
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
pic

5-55X
Ir
1
5
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
acac

5-55Y
Ir
0
5
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
—
—

5-56
Ir
1
5
Ph
H
Si(CH₃)₃
H
F
H

^tCH₄H₉
H
pic

5-56X
Ir
1
5
Ph
H
Si(CH₃)₃
H
F
H

^tCH₄H₉
H
acac

5-56Y
Ir
0
5
Ph
H
Si(CH₃)₃
H
F
H

^tCH₄H₉
H
—
—

5-57
Ir
1
5
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
pic

5-57X
Ir
1
5
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
acac

5-57Y
Ir
0
5
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
—
—

5-58
Ir
1
5
Ph
H
Si(CH₃)₃
H
CF₃
H

^tCH₄H₉
H
pic

5-58X
Ir
1
5
Ph
H
Si(CH₃)₃
H
CF₃
H

^tCH₄H₉
H
acac

5-58Y
Ir
0
5
Ph
H
Si(CH₃)₃
H
CF₃
H

^tCH₄H₉
H
—
—

5-59
Ir
1
5
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
pic

5-59X
Ir
1
5
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
acac

5-59Y
Ir
0
5
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
—
—

5-60
Ir
1
5
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tCH₄H₉
H
pic

5-60X
Ir
1
5
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tCH₄H₉
H
acac

5-60Y
Ir
0
5
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tCH₄H₉
H
—
—

5-61
Ir
1
5
Ph
H
H
H
COCH₃
H
CH₃
H
pic

5-61X
Ir
1
5
Ph
H
H
H
COCH₃
H
CH₃
H
acac

5-61Y
Ir
0
5
Ph
H
H
H
COCH₃
H
CH₃
H
—
—

5-62
Ir
1
5
Ph
H
H
COCH₃
H
H
CH₃
H
pic

5-62X
Ir
1
5
Ph
H
H
COCH₃
H
H
CH₃
H
acac

5-62Y
Ir
0
5
Ph
H
H
COCH₃
H
H
CH₃
H
—
—

5-63
Ir
1
5
Ph
H
COCH₃
H
H
H
CH₃
H
pic

5-63X
Ir
1
5
Ph
H
COCH₃
H
H
H
CH₃
H
acac

5-63Y
Ir
0
5
Ph
H
COCH₃
H
H
H
CH₃
H
—
—

5-64
Ir
1
5
Ph
H
H
BL
H
CH₃
H
pic

5-64X
Ir
1
5
Ph
H
H
BL
H
CH₃
H
acac

5-64Y
Ir
0
5
Ph
H
H
BL
H
CH₃
H
—
—

5-65
Ir
1
5
Ph
H
H
BL
H

^tCH₄H₉
H
pic

5-65X
Ir
1
5
Ph
H
H
BL
H

^tCH₄H₉
H
acac

5-65Y
Ir
0
5
Ph
H
H
BL
H

^tCH₄H₉
H
—
—

5-66
Ir
1
5
Ph
H
BL
H
H
CH₃
H
pic

5-66X
Ir
1
5
Ph
H
BL
H
H
CH₃
H
acac

5-66Y
Ir
0
5
Ph
H
BL
H
H
CH₃
H
—
—

5-67
Ir
1
5
Ph
H
BL
H

^tCH₄H₉
H
H
pic

5-67X
Ir
1
5
Ph
H
BL
H

^tCH₄H₉
H
H
acac

5-67Y
Ir
0
5
Ph
H
BL
H

^tCH₄H₉
H
H
—
—

5-68
Ir
1
5
Ph
H
H
PL
H
CH₃
H
pic

5-68X
Ir
1
5
Ph
H
H
PL
H
CH₃
H
acac

5-68Y
Ir
0
5
Ph
H
H
PL
H
CH₃
H
—
—

5-69
Ir
1
5
Ph
H
H
PL
H

^tCH₄H₉
H
pic

5-69X
Ir
1
5
Ph
H
H
PL
H

^tCH₄H₉
H
acac

5-69Y
Ir
0
5
Ph
H
H
PL
H

^tCH₄H₉
H
—
—

5-70
Ir
1
5
Ph
H
PL
H
H
CH₃
H
pic

5-70X
Ir
1
5
Ph
H
PL
H
H
CH₃
H
acac

5-70Y
Ir
0
5
Ph
H
PL
H
H
CH₃
H
—
—

5-71
Ir
1
5
Ph
H
PL
H
H

^tCH₄H₉
H
pic

5-71X
Ir
1
5
Ph
H
PL
H
H

^tCH₄H₉
H
acac

5-71Y
Ir
0
5
Ph
H
PL
H
H

^tCH₄H₉
H
—
—

5-72
Ir
1
5
Ph
H
H
MEE1
H
CH₃
H
pic

5-72X
Ir
1
5
Ph
H
H
MEE1
H
CH₃
H
acac

5-72Y
Ir
0
5
Ph
H
H
MEE1
H
CH₃
H
—
—

5-73
Ir
1
5
Ph
H
MEE1
H
H
CH₃
H
pic

5-73X
Ir
1
5
Ph
H
MEE1
H
H
CH₃
H
acac

5-73Y
Ir
0
5
Ph
H
MEE1
H
H
CH₃
H
—
—

5-74
Ir
1
5
Ph
H
H
MEE2
H
CH₃
H
pic

5-74X
Ir
1
5
Ph
H
H
MEE2
H
CH₃
H
acac

5-74Y
Ir
0
5
Ph
H
H
MEE2
H
CH₃
H
—
—

5-75
Ir
1
5
Ph
H
MEE2
H
H
CH₃
H
pic

5-75X
Ir
1
5
Ph
H
MEE2
H
H
CH₃
H
acac

5-75Y
Ir
0
5
Ph
H
MEE2
H
H
CH₃
H
—
—

5-76
Ir
1
5
Ph
H
H
PA1
H
CH₃
H
pic

5-76X
Ir
1
5
Ph
H
H
PA1
H
CH₃
H
acac

5-76Y
Ir
0
5
Ph
H
H
PA1
H
CH₃
H
—
—

5-77
Ir
1
5
Ph
H
PA1
H
H
CH₃
H
pic

5-77X
Ir
1
5
Ph
H
PA1
H
H
CH₃
H
acac

5-77Y
Ir
0
5
Ph
H
PA1
H
H
CH₃
H
—
—

5-78
Ir
1
5
Ph
H
H
PA2
H
CH₃
H
pic

5-78X
Ir
1
5
Ph
H
H
PA2
H
CH₃
H
acac

5-78Y
Ir
0
5
Ph
H
H
PA2
H
CH₃
H
—
—

5-79
Ir
1
5
Ph
H
PA2
H
H
CH₃
H
pic

5-79X
Ir
1
5
Ph
H
PA2
H
H
CH₃
H
acac

5-79Y
Ir
0
5
Ph
H
PA2
H
H
CH₃
H
—
—

5-80
Ir
1
5
Ph
H
H
EA1
H
CH₃
H
pic

5-80X
Ir
1
5
Ph
H
H
EA1
H
CH₃
H
acac

5-80Y
Ir
0
5
Ph
H
H
EA1
H
CH₃
H
—
—

5-81
Ir
1
5
Ph
H
EA2
H
H
CH₃
H
pic

5-81X
Ir
1
5
Ph
H
EA2
H
H
CH₃
H
acac

5-81Y
Ir
0
5
Ph
H
EA2
H
H
CH₃
H
—
—

5-82
Ir
1
5
Ph
H
H
ME
H
CH₃
H
pic

5-82X
Ir
1
5
Ph
H
H
ME
H
CH₃
H
acac

5-82Y
Ir
0
5
Ph
H
H
ME
H
CH₃
H
—
—

5-83
Ir
1
5
Ph
H
ME
H
H
CH₃
H
pic

5-83X
Ir
1
5
Ph
H
ME
H
H
CH₃
H
acac

5-83Y
Ir
0
5
Ph
H
ME
H
H
CH₃
H
—
—

5-84
Ir
1
5
Ph
H
H
AT
H
CH₃
H
pic

5-84X
Ir
1
5
Ph
H
H
AT
H
CH₃
H
acac

5-84Y
Ir
0
5
Ph
H
H
AT
H
CH₃
H
—
—

5-85
Ir
1
5
Ph
H
AT
H
H
CH₃
H
pic

5-85X
Ir
1
5
Ph
H
AT
H
H
CH₃
H
acac

5-85Y
Ir
0
5
Ph
H
AT
H
H
CH₃
H
—
—

5-86
Ir
1
5
Ph
H
H
MES1
H
CH₃
H
pic

5-86X
Ir
1
5
Ph
H
H
MES1
H
CH₃
H
acac

5-86Y
Ir
0
5
Ph
H
H
MES1
H
CH₃
H
—
—

5-87
Ir
1
5
Ph
H
MES1
H
H
CH₃
H
pic

5-87X
Ir
1
5
Ph
H
MES1
H
H
CH₃
H
acac

5-87Y
Ir
0
5
Ph
H
MES1
H
H
CH₃
H
—
—

5-88
Ir
1
5
Ph
H
H
MES2
H
CH₃
H
pic

5-88X
Ir
1
5
Ph
H
H
MES2
H
CH₃
H
acac

5-88Y
Ir
0
5
Ph
H
H
MES2
H
CH₃
H
—
—

5-89
Ir
1
5
Ph
H
MES2
H
H
CH₃
H
pic

5-89X
Ir
1
5
Ph
H
MES2
H
H
CH₃
H
acac

5-89Y
Ir
0
5
Ph
H
MES2
H
H
CH₃
H
—
—

5-90
Ir
1
5
Ph
H
H
PS1
H
CH₃
H
pic

5-90X
Ir
1
5
Ph
H
H
PS1
H
CH₃
H
acac

5-90Y
Ir
0
5
Ph
H
H
PS1
H
CH₃
H
—
—

5-91
Ir
1
5
Ph
H
PS1
H
H
CH₃
H
pic

5-91X
Ir
1
5
Ph
H
PS1
H
H
CH₃
H
acac

5-91Y
Ir
0
5
Ph
H
PS1
H
H
CH₃
H
—
—

5-92
Ir
1
5
Ph
H
H
PS2
H
CH₃
H
pic

5-92X
Ir
1
5
Ph
H
H
PS2
H
CH₃
H
acac

5-92Y
Ir
0
5
Ph
H
H
PS2
H
CH₃
H
—
—

5-93
Ir
1
5
Ph
H
PS2
H
H
CH₃
H
pic

5-93X
Ir
1
5
Ph
H
PS2
H
H
CH₃
H
acac

5-93Y
Ir
0
5
Ph
H
PS2
H
H
CH₃
H
—
—

5-94
Ir
1
5
Ph
H
H
BAL1
H
CH₃
H
pic

5-94X
Ir
1
5
Ph
H
H
BAL1
H
CH₃
H
acac

5-94Y
Ir
0
5
Ph
H
H
BAL1
H
CH₃
H
—
—

5-95
Ir
1
5
Ph
H
BAL1
H
H
CH₃
H
pic

5-95X
Ir
1
5
Ph
H
BAL1
H
H
CH₃
H
acac

5-95Y
Ir
0
5
Ph
H
BAL1
H
H
CH₃
H
—
—

5-96
Ir
1
5
Ph
H
H
BAL2
H
CH₃
H
pic

5-96X
Ir
1
5
Ph
H
H
BAL2
H
CH₃
H
acac

5-96Y
Ir
0
5
Ph
H
H
BAL2
H
CH₃
H
—
—

5-97
Ir
1
5
Ph
H
BAL2
H
H
CH₃
H
pic

5-97X
Ir
1
5
Ph
H
BAL2
H
H
CH₃
H
acac

5-97Y
Ir
0
5
Ph
H
BAL2
H
H
CH₃
H
—
—

5-98
Ir
1
5
Ph
H
H
MEK1
H
CH₃
H
pic

5-98X
Ir
1
5
Ph
H
H
MEK1
H
CH₃
H
acac

5-98Y
Ir
0
5
Ph
H
H
MEK1
H
CH₃
H
—
—

5-99
Ir
1
5
Ph
H
MEK1
H
H
CH₃
H
pic

5-99X
Ir
1
5
Ph
H
MEK1
H
H
CH₃
H
acac

5-99Y
Ir
0
5
Ph
H
MEK1
H
H
CH₃
H
—
—

5-100
Ir
1
5
Ph
H
H
MEK2
H
CH₃
H
pic

5-100X
Ir
1
5
Ph
H
H
MEK2
H
CH₃
H
acac

5-100Y
Ir
0
5
Ph
H
H
MEK2
H
CH₃
H
—
—

5-101
Ir
1
5
Ph
H
MEK2
H
H
CH₃
H
pic

5-101X
Ir
1
5
Ph
H
MEK2
H
H
CH₃
H
acac

5-101Y
Ir
0
5
Ph
H
MEK2
H
H
CH₃
H
—
—

5-102
Ir
1
5
Ph
H
H
PAL1
H
CH₃
H
pic

5-102X
Ir
1
5
Ph
H
H
PAL1
H
CH₃
H
acac

5-102Y
Ir
0
5
Ph
H
H
PAL1
H
CH₃
H
—
—

5-103
Ir
1
5
Ph
H
PAL1
H
H
CH₃
H
pic

5-103X
Ir
1
5
Ph
H
PAL1
H
H
CH₃
H
acac

5-103Y
Ir
0
5
Ph
H
PAL1
H
H
CH₃
H
—
—

5-104
Ir
1
5
Ph
H
H
PAL2
H
CH₃
H
pic

5-104X
Ir
1
5
Ph
H
H
PAL2
H
CH₃
H
acac

5-104Y
Ir
0
5
Ph
H
H
PAL2
H
CH₃
H
—
—

5-105
Ir
1
5
Ph
H
PAL2
H
H
CH₃
H
pic

5-105X
Ir
1
5
Ph
H
PAL2
H
H
CH₃
H
acac

5-105Y
Ir
0
5
Ph
H
PAL2
H
H
CH₃
H
—
—

5-106
Ir
1
5
Ph
H
H
MMK
H
CH₃
H
pic

5-106X
Ir
1
5
Ph
H
H
MMK
H
CH₃
H
acac

5-106Y
Ir
0
5
Ph
H
H
MMK
H
CH₃
H
—
—

5-107
Ir
1
5
Ph
H
MMK
H
H
CH₃
H
pic

5-107X
Ir
1
5
Ph
H
MMK
H
H
CH₃
H
acac

5-107Y
Ir
0
5
Ph
H
MMK
H
H
CH₃
H
—
—

5-108
Ir
1
5
Ph
H
H
EES1
H
CH₃
H
pic

5-108X
Ir
1
5
Ph
H
H
EES1
H
CH₃
H
acac

5-108Y
Ir
0
5
Ph
H
H
EES1
H
CH₃
H
—
—

5-109
Ir
1
5
Ph
H
EES2
H
H
CH₃
H
pic

5-109X
Ir
1
5
Ph
H
EES2
H
H
CH₃
H
acac

5-109Y
Ir
0
5
Ph
H
EES2
H
H
CH₃
H
—
—

5-110
Ir
1
5
Ph
H
H
PAE1
H
CH₃
H
pic

5-110X
Ir
1
5
Ph
H
H
PAE1
H
CH₃
H
acac

5-110Y
Ir
0
5
Ph
H
H
PAE1
H
CH₃
H
—
—

5-111
Ir
1
5
Ph
H
PAE2
H
H
CH₃
H
pic

5-111X
Ir
1
5
Ph
H
PAE2
H
H
CH₃
H
acac

5-111Y
Ir
0
5
Ph
H
PAE2
H
H
CH₃
H
—
—

5-112
Ir
1
5
Ph
H
H
AME1
H
CH₃
H
pic

5-112X
Ir
1
5
Ph
H
H
AME1
H
CH₃
H
acac

5-112Y
Ir
0
5
Ph
H
H
AME1
H
CH₃
H
—
—

5-113
Ir
1
5
Ph
H
AME1
H
H
CH₃
H
pic

5-113X
Ir
1
5
Ph
H
AME1
H
H
CH₃
H
acac

5-113Y
Ir
0
5
Ph
H
AME1
H
H
CH₃
H
—
—

5-114
Ir
1
5
Ph
H
H
AME2
H
CH₃
H
pic

5-114X
Ir
1
5
Ph
H
H
AME2
H
CH₃
H
acac

5-114Y
Ir
0
5
Ph
H
H
AME2
H
CH₃
H
—
—

5-115
Ir
1
5
Ph
H
AME2
H
H
CH₃
H
pic

5-115X
Ir
1
5
Ph
H
AME2
H
H
CH₃
H
acac

5-115Y
Ir
0
5
Ph
H
AME2
H
H
CH₃
H
—
—

5-116
Ir
1
5
Ph
H
H
EAE1
H
CH₃
H
pic

5-116X
Ir
1
5
Ph
H
H
EAE1
H
CH₃
H
acac

5-116Y
Ir
0
5
Ph
H
H
EAE1
H
CH₃
H
—
—

5-117
Ir
1
5
Ph
H
EAE1
H
H
CH₃
H
pic

5-117X
Ir
1
5
Ph
H
EAE1
H
H
CH₃
H
acac

5-117Y
Ir
0
5
Ph
H
EAE1
H
H
CH₃
H
—
—

5-118
Ir
1
5
Ph
H
H
EAE2
H
CH₃
H
pic

5-118X
Ir
1
5
Ph
H
H
EAE2
H
CH₃
H
acac

5-118Y
Ir
0
5
Ph
H
H
EAE2
H
CH₃
H
—
—

5-119
Ir
1
5
Ph
H
EAE2
H
H
CH₃
H
pic

5-119X
Ir
1
5
Ph
H
EAE2
H
H
CH₃
H
acac

5-119Y
Ir
0
5
Ph
H
EAE2
H
H
CH₃
H
—
—

5-120
Ir
1
5
Ph
H
H
AAE1
H
CH₃
H
pic

5-120X
Ir
1
5
Ph
H
H
AAE1
H
CH₃
H
acac

5-120Y
Ir
0
5
Ph
H
H
AAE1
H
CH₃
H
—
—

5-121
Ir
1
5
Ph
H
AAE1
H
H
CH₃
H
pic

5-121X
Ir
1
5
Ph
H
AAE1
H
H
CH₃
H
acac

5-121Y
Ir
0
5
Ph
H
AAE1
H
H
CH₃
H
—
—

5-122
Ir
1
5
Ph
H
H
AAE2
H
CH₃
H
pic

5-122X
Ir
1
5
Ph
H
H
AAE2
H
CH₃
H
acac

5-122Y
Ir
0
5
Ph
H
H
AAE2
H
CH₃
H
—
—

5-123
Ir
1
5
Ph
H
AAE2
H
H
CH₃
H
pic

5-123X
Ir
1
5
Ph
H
AAE2
H
H
CH₃
H
acac

5-123Y
Ir
0
5
Ph
H
AAE2
H
H
CH₃
H
—
—

5-124
Ir
1
5
Ph
H
H
PME1
H
CH₃
H
pic

5-124X
Ir
1
5
Ph
H
H
PME1
H
CH₃
H
acac

5-124Y
Ir
0
5
Ph
H
H
PME1
H
CH₃
H
—
—

5-125
Ir
1
5
Ph
H
PME1
H
H
CH₃
H
pic

5-125X
Ir
1
5
Ph
H
PME1
H
H
CH₃
H
acac

5-125Y
Ir
0
5
Ph
H
PME1
H
H
CH₃
H
—
—

5-126
Ir
1
5
Ph
H
H
PME2
H
CH₃
H
pic

5-126X
Ir
1
5
Ph
H
H
PME2
H
CH₃
H
acac

5-126Y
Ir
0
5
Ph
H
H
PME2
H
CH₃
H
—
—

5-127
Ir
1
5
Ph
H
PME2
H
H
CH₃
H
pic

5-127X
Ir
1
5
Ph
H
PME2
H
H
CH₃
H
acac

5-127Y
Ir
0
5
Ph
H
PME2
H
H
CH₃
H
—
—

5-128
Ir
1
5
Ph
H
H
MET1
H
CH₃
H
pic

5-128X
Ir
1
5
Ph
H
H
MET1
H
CH₃
H
acac

5-128Y
Ir
0
5
Ph
H
H
MET1
H
CH₃
H
—
—

5-129
Ir
1
5
Ph
H
MET1
H
H
CH₃
H
pic

5-129X
Ir
1
5
Ph
H
MET1
H
H
CH₃
H
acac

5-129Y
Ir
0
5
Ph
H
MET1
H
H
CH₃
H
—
—

5-130
Ir
1
5
Ph
H
H
MET2
H
CH₃
H
pic

5-130X
Ir
1
5
Ph
H
H
MET2
H
CH₃
H
acac

5-130Y
Ir
0
5
Ph
H
H
MET2
H
CH₃
H
—
—

5-131
Ir
1
5
Ph
H
MET2
H
H
CH₃
H
pic

5-131X
Ir
1
5
Ph
H
MET2
H
H
CH₃
H
acac

5-131Y
Ir
0
5
Ph
H
MET2
H
H
CH₃
H
—
—

5-132
Ir
1
5
Ph
H
H
EE1
H
CH₃
H
pic

5-132X
Ir
1
5
Ph
H
H
EE1
H
CH₃
H
acac

5-132Y
Ir
0
5
Ph
H
H
EE1
H
CH₃
H
—
—

5-133
Ir
1
5
Ph
H
EE1
H
H
CH₃
H
pic

5-133X
Ir
1
5
Ph
H
EE1
H
H
CH₃
H
acac

5-133Y
Ir
0
5
Ph
H
EE1
H
H
CH₃
H
—
—

5-134
Ir
1
5
Ph
H
H
EE2
H
CH₃
H
pic

5-134X
Ir
1
5
Ph
H
H
EE2
H
CH₃
H
acac

5-134Y
Ir
0
5
Ph
H
H
EE2
H
CH₃
H
—
—

5-135
Ir
1
5
Ph
H
EE2
H
H
CH₃
H
pic

5-135X
Ir
1
5
Ph
H
EE2
H
H
CH₃
H
acac

5-135Y
Ir
0
5
Ph
H
EE2
H
H
CH₃
H
—
—

5-136
Ir
1
5
Ph
H
H
MS1
H
CH₃
H
pic

5-136X
Ir
1
5
Ph
H
H
MS1
H
CH₃
H
acac

5-136Y
Ir
0
5
Ph
H
H
MS1
H
CH₃
H
—
—

5-137
Ir
1
5
Ph
H
MS1
H
H
CH₃
H
pic

5-137X
Ir
1
5
Ph
H
MS1
H
H
CH₃
H
acac

5-137Y
Ir
0
5
Ph
H
MS1
H
H
CH₃
H
—
—

5-138
Ir
1
5
Ph
H
H
MS2
H
CH₃
H
pic

5-138X
Ir
1
5
Ph
H
H
MS2
H
CH₃
H
acac

5-138Y
Ir
0
5
Ph
H
H
MS2
H
CH₃
H
—
—

5-139
Ir
1
5
Ph
H
MS2
H
H
CH₃
H
pic

5-139X
Ir
1
5
Ph
H
MS2
H
H
CH₃
H
acac

5-139Y
Ir
0
5
Ph
H
MS2
H
H
CH₃
H
—
—

TABLE 6

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

6-1
Ir
1
6
Ph
H
H
H
H
CH₃
H
H
pic

6-1X
Ir
1
6
Ph
H
H
H
H
CH₃
H
H
acac

6-1Y
Ir
0
6
Ph
H
H
H
H
CH₃
H
H
—
—

6-2
Ir
1
6
Ph
H
H
H
H

^tC₄H₉
H
H
pic

6-2X
Ir
1
6
Ph
H
H
H
H

^tC₄H₉
H
H
acac

6-2Y
Ir
0
6
Ph
H
H
H
H

^tC₄H₉
H
H
—
—

6-3
Ir
1
6
Ph
H
F
H
F
CH₃
H
H
pic

6-3X
Ir
1
6
Ph
H
F
H
F
CH₃
H
H
acac

6-3Y
Ir
0
6
Ph
H
F
H
F
CH₃
H
H
—
—

6-4
Ir
1
6
Ph
H
F
H
F

^tC₄H₉
H
H
pic

6-4X
Ir
1
6
Ph
H
F
H
F

^tC₄H₉
H
H
acac

6-4Y
Ir
0
6
Ph
H
F
H
F

^tC₄H₉
H
H
—
—

6-5
Ir
1
6
Ph
F
H
H
F
CH₃
H
H
pic

6-5X
Ir
1
6
Ph
F
H
H
F
CH₃
H
H
acac

6-5Y
Ir
0
8
Ph
F
H
H
F
CH₃
H
H
—
—

6-6
Ir
1
8
Ph
F
H
H
F

^tC₄H₉
H
H
pic

6-6X
Ir
1
8
Ph
F
H
H
F

^tC₄H₉
H
H
acac

6-6Y
Ir
0
8
Ph
F
H
H
F

^tC₄H₉
H
H
—
—

6-7
Ir
1
6
Ph
CF₃
H
CF₃
H
CH₃
H
H
pic

6-7X
Ir
1
6
Ph
CF₃
H
CF₃
H
CH₃
H
H
acac

6-7Y
Ir
0
6
Ph
CF₃
H
CF₃
H
CH₃
H
H
—
—

6-8
Ir
1
6
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

6-8X
Ir
1
6
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

6-8Y
Ir
0
6
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
—
—

6-9
Ir
1
6
Ph
H
F
CF₃
H
CH₃
H
H
pic

6-9X
Ir
1
6
Ph
H
F
CF₃
H
CH₃
H
H
acac

6-9Y
Ir
0
6
Ph
H
F
CF₃
H
CH₃
H
H
—
—

6-10
Ir
1
6
Ph
F
H
CF₃
H
CH₃
H
H
pic

6-10X
Ir
1
8
Ph
F
H
CF₃
H
CH₃
H
H
acac

6-10Y
Ir
0
6
Ph
F
H
CF₃
H
CH₃
H
H
—
—

6-11
Ir
1
6
Ph
F
F
F
F
CH₃
H
H
pic

6-11X
Ir
1
6
Ph
F
F
F
F
CH₃
H
H
acac

6-11Y
Ir
0
8
Ph
F
F
F
F
CH₃
H
H
—
—

6-12
Ir
1
6
Ph
H
F
H
CH₃
CH₃
H
H
pic

6-12X
Ir
1
6
Ph
H
F
H
CH₃
CH₃
H
H
acac

6-12Y
Ir
0
6
Ph
H
F
H
CH₃
CH₃
H
H
—
—

6-13
Ir
1
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

6-13X
Ir
1
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

6-13y
Ir
0
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
—
—

6-14
Ir
1
6
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

6-14X
Ir
1
6
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

6-14Y
Ir
0
6
Ph
H
F
H

^tC₄H₉
CH₃
H
H
—
—

6-15
Ir
1
6
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-15X
Ir
1
6
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-15Y
Ir
0
6
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-16
Ir
1
6
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

6-16X
Ir
1
6
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

6-16Y
Ir
0
6
Ph
H
CF₃
H
CF₃
CH₃
H
H
—
—

6-17
Ir
1
6
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

6-17X
Ir
1
6
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

6-17Y
Ir
0
6
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
—
—

6-18
Ir
1
6
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

6-18X
Ir
1
6
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

6-18Y
Ir
0
6
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
—
—

6-19
Ir
1
6
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-19X
Ir
1
6
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-19Y
Ir
0
6
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-20
Ir
1
6
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
pic

6-20X
Ir
1
6
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

6-20Y
Ir
0
6
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
—
—

6-21
Ir
1
6
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-21X
Ir
1
6
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-21Y
Ir
0
6
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-22
Ir
1
6
Ph
H
CF₃
H
CH₃
CH₃
H
H
pic

6-22X
Ir
1
6
Ph
H
CF₃
H
CH₃
CH₃
H
H
acac

6-22Y
Ir
0
6
Ph
H
CF₃
H
CH₃
CH₃
H
H
—
—

6-23
Ir
1
6
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

6-23X
Ir
1
6
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

6-23Y
Ir
0
6
Ph
H
CF₃
CF₃
H
CH₃
H
H
—
—

6-24
Ir
1
6
Ph
H
H
NO₂
H
CH₃
H
H
pic

6-24X
Ir
1
6
Ph
H
H
NO₂
H
CH₃
H
H
acac

6-24Y
Ir
0
6
Ph
H
H
NO₂
H
CH₃
H
H
—
—

6-25
Ir
1
6
Ph
H
H
NO₂
H

^tC₄H₉
H
H
pic

6-25X
Ir
1
6
Ph
H
H
NO₂
H

^tC₄H₉
H
H
acac

6-25Y
Ir
0
6
Ph
H
H
NO₂
H

^tC₄H₉
H
H
—
—

6-26
Ir
1
6
Ph
F
H
NO₂
H
CH₃
H
H
pic

6-26X
Ir
1
6
Ph
F
H
NO₂
H
CH₃
H
H
acac

6-26Y
Ir
0
6
Ph
F
H
NO₂
H
CH₃
H
H
—
—

6-27
Ir
1
6
Ph
F
H
NO₂
F
CH₃
H
H
pic

6-27X
Ir
1
6
Ph
F
H
NO₂
F
CH₃
H
H
acac

6-27Y
Ir
0
6
Ph
F
H
NO₂
F
CH₃
H
H
—
—

6-28
Ir
1
6
Ph
H
NO₂
H
NO₂
CH₃
H
H
pic

6-28X
Ir
1
6
Ph
H
NO₂
H
NO₂
CH₃
H
H
acac

6-28Y
Ir
0
6
Ph
H
NO₂
H
NO₂
CH₃
H
H
—
—

6-29
Ir
1
6
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
pic

6-29X
Ir
1
6
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
acac

6-29Y
Ir
0
6
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
—
—

6-30
Ir
1
6
Ph
NO₂
H
H
NO₂
CH₃
H
H
pic

6-30X
Ir
1
6
Ph
NO₂
H
H
NO₂
CH₃
H
H
acac

6-30Y
Ir
0
6
Ph
NO₂
H
H
NO₂
CH₃
H
H
—
—

6-31
Ir
1
6
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
pic

6-31X
Ir
1
6
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
acac

6-31Y
Ir
0
6
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
—
—

6-32
Ir
1
6
Ph
H
H
CF₃
H
CH₃
H
H
pic

6-32X
Ir
1
6
Ph
H
H
CF₃
H
CH₃
H
H
acac

6-32Y
Ir
0
6
Ph
H
H
CF₃
H
CH₃
H
H
—
—

6-33
Ir
1
6
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

6-33X
Ir
1
6
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

6-33Y
Ir
0
6
Ph
H
H
CF₃
H

^tC₄H₉
H
H
—
—

6-34
Ir
1
6
Ph
H
Cl
CF₃
H
CH₃
H
H
pic

6-34X
Ir
1
6
Ph
H
Cl
CF₃
H
CH₃
H
H
acac

6-34Y
Ir
0
6
Ph
H
Cl
CF₃
H
CH₃
H
H
—
—

6-35
Ir
1
6
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
pic

6-35X
Ir
1
6
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
acac

6-35Y
Ir
0
6
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
—
—

6-36
Ir
1
6
Ph
H
NO₂
H
H
CH₃
H
H
pic

6-36X
Ir
1
6
Ph
H
NO₂
H
H
CH₃
H
H
acac

6-36Y
Ir
0
6
Ph
H
NO₂
H
H
CH₃
H
H
—
—

6-37
Ir
1
6
Ph
H
CF₃
H
H
CH₃
H
H
pic

6-37X
Ir
1
6
Ph
H
CF₃
H
H
CH₃
H
H
acac

6-37Y
Ir
0
6
Ph
H
CF₃
H
H
CH₃
H
H
—
—

6-38
Ir
1
6
Ph
H
NO₂
H
CH₃
CH₃
H
H
pic

6-38X
Ir
1
6
Ph
H
NO₂
H
CH₃
CH₃
H
H
acac

6-38Y
Ir
0
6
Ph
H
NO₂
H
CH₃
CH₃
H
H
—
—

6-39
Ir
1
6
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
pic

6-39X
Ir
1
6
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
acac

6-39Y
Ir
0
6
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
—
—

6-40
Ir
1
6
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
pic

6-40X
Ir
1
6
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
acac

6-40Y
Ir
0
6
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
—
—

6-41
Ir
1
6
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-41X
Ir
1
6
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-41Y
Ir
0
6
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-42
Ir
1
6
Ph
H
H
CH₃O
H
CH₃
H
H
pic

6-42X
Ir
1
6
Ph
H
H
CH₃O
H
CH₃
H
H
acac

6-42Y
Ir
0
6
Ph
H
H
CH₃O
H
CH₃
H
H
—
—

6-43
Ir
1
6
Ph
H
CH₃O
H
H
CH₃
H
H
pic

6-43X
Ir
1
6
Ph
H
CH₃O
H
H
CH₃
H
H
acac

6-43Y
Ir
0
6
Ph
H
CH₃O
H
H
CH₃
H
H
—
—

6-44
Ir
1
6
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

6-44X
Ir
1
6
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

6-44Y
Ir
0
6
Ph
H
CH₃O
H
CH₃
CH₃
H
H
—
—

6-45
Ir
1
6
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

6-45X
Ir
1
6
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

6-45Y
Ir
0
6
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
—
—

6-46
Ir
1
6
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
pic

6-46X
Ir
1
6
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
acac

6-46Y
Ir
0
6
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
—
—

6-47
Ir
1
6
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
pic

6-47X
Ir
1
6
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
acac

6-47Y
Ir
0
6
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
—
—

6-48
Ir
1
6
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
pic

6-48X
Ir
1
6
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
acac

6-48Y
Ir
0
6
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
—
—

6-49
Ir
1
6
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
pic

6-49X
Ir
1
6
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
acac

6-49Y
Ir
0
6
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
—
—

6-50
Ir
1
6
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
pic

6-50X
Ir
1
6
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
acac

6-50Y
Ir
0
6
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
—
—

6-51
Ir
1
6
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
pic

6-51X
Ir
1
6
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
acac

6-51Y
Ir
0
6
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
—
—

6-52
Ir
1
6
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
pic

6-52X
Ir
1
6
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
acac

6-52Y
Ir
0
6
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
—
—

6-53
Ir
1
6
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
pic

6-53X
Ir
1
6
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
acac

6-53Y
Ir
0
6
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
—
—

6-54
Ir
1
6
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
pic

6-54X
Ir
1
6
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
acac

6-54Y
Ir
0
6
Ph .
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
—
—

6-55
Ir
1
6
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
pic

6-55X
Ir
1
6
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
acac

6-55Y
Ir
0
6
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
—
—

6-56
Ir
1
6
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

6-56X
Ir
1
6
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

6-56Y
Ir
0
6
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
—
—

6-57
Ir
1
6
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
pic

6-57X
Ir
1
6
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
acac

6-57Y
Ir
0
6
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
—
—

6-58
Ir
1
6
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
pic

6-58X
Ir
1
6
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
acac

6-58Y
Ir
0
6
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
—
—

6-59
Ir
1
6
Ph
H
H
H
COCH₃
CH₃
H
H
pic

6-59X
Ir
1
6
Ph
H
H
H
COCH₃
CH₃
H
H
acac

6-59Y
Ir
0
6
Ph
H
H
H
COCH₃
CH₃
H
H
—
—

6-60
Ir
1
6
Ph
H
H
COCH₃
H
CH₃
H
H
pic

6-60X
Ir
1
6
Ph
H
H
COCH₃
H
CH₃
H
H
acac

6-60Y
Ir
0
6
Ph
H
H
COCH₃
H
CH₃
H
H
—
—

6-61
Ir
1
6
Ph
H
COCH₃
H
H
CH₃
H
H
pic

6-61X
Ir
1
6
Ph
H
COCH₃
H
H
CH₃
H
H
acac

6-61Y
Ir
0
6
Ph
H
COCH₃
H
H
CH₃
H
H
—
—

6-62
Ir
1
6
Ph
H
H
BL
CH₃
H
H
pic

6-62X
Ir
1
6
Ph
H
H
BL
CH₃
H
H
acac

6-62Y
Ir
0
6
Ph
H
H
BL
CH₃
H
H
—
—

6-63
Ir
1
6
Ph
H
H
BL

^tC₄H₉
H
H
pic

6-63X
Ir
1
6
Ph
H
H
BL

^tC₄H₉
H
H
acac

6-63Y
Ir
0
6
Ph
H
H
BL

^tC₄H₉
H
H
—
—

6-64
Ir
1
6
Ph
H
BL
H
CH₃
H
H
pic

6-64X
Ir
1
6
Ph
H
BL
H
CH₃
H
H
acac

6-64Y
Ir
0
6
Ph
H
BL
H
CH₃
H
H
—
—

6-65
Ir
1
6
Ph
H
BL
H

^tC₄H₉
H
H
pic

6-65X
Ir
1
6
Ph
H
BL
H

^tC₄H₉
H
H
acac

6-65Y
Ir
0
6
Ph
H
BL
H

^tC₄H₉
H
H
—
—

6-66
Ir
1
6
Ph
H
H
PL
CH₃
H
H
pic

6-66X
Ir
1
6
Ph
H
H
PL
CH₃
H
H
acac

6-66Y
Ir
0
6
Ph
H
H
PL
CH₃
H
H
—
—

6-67
Ir
1
6
Ph
H
H
PL

^tC₄H₉
H
H
pic

6-67X
Ir
1
6
Ph
H
H
PL

^tC₄H₉
H
H
acac

6-67Y
Ir
0
6
Ph
H
H
PL

^tC₄H₉
H
H
—
—

6-68
Ir
1
6
Ph
H
PL
H
CH₃
H
H
pic

6-68X
Ir
1
6
Ph
H
PL
H
CH₃
H
H
acac

6-68Y
Ir
0
6
Ph
H
PL
H
CH₃
H
H
—
—

6-69
Ir
1
6
Ph
H
PL
H

^tC₄H₉
H
H
pic

6-69X
Ir
1
8
Ph
H
PL
H

^tC₄H₉
H
H
acac

6-69Y
Ir
0
8
Ph
H
PL
H

^tC₄H₉
H
H
—
—

6-70
Ir
1
6
Ph
H
H
MEE1
CH₃
H
H
pic

6-70X
Ir
1
6
Ph
H
H
MEE1
CH₃
H
H
acac

6-70Y
Ir
0
8
Ph
H
H
MEE1
CH₃
H
H
—
—

6-71
Ir
1
6
Ph
H
MEE1
H
CH₃
H
H
pic

6-71X
Ir
1
6
Ph
H
MEE1
H
CH₃
H
H
acac

6-71Y
Ir
0
6
Ph
H
MEE1
H
CH₃
H
H
—
—

6-72
Ir
1
6
Ph
H
H
MEE2
CH₃
H
H
pic

6-72X
Ir
1
6
Ph
H
H
MEE2
CH₃
H
H
acac

6-72Y
Ir
0
6
Ph
H
H
MEE2
CH₃
H
H
—
—

6-73
Ir
1
6
Ph
H
MEE2
H
CH₃
H
H
pic

6-73X
Ir
1
6
Ph
H
MEE2
H
CH₃
H
H
acac

6-73Y
Ir
0
6
Ph
H
MEE2
H
CH₃
H
H
—
—

6-74
Ir
1
6
Ph
H
H
PA1
CH₃
H
H
pic

6-74X
Ir
1
6
Ph
H
H
PA1
CH₃
H
H
acac

6-74Y
Ir
0
6
Ph
H
H
PA1
CH₃
H
H
—
—

6-75
Ir
1
6
Ph
H
PA1
H
CH₃
H
H
pic

6-75X
Ir
1
6
Ph
H
PA1
H
CH₃
H
H
acac

6-75Y
Ir
0
6
Ph
H
PA1
H
CH₃
H
H
—
—

6-76
Ir
1
6
Ph
H
H
PA2
CH₃
H
H
pic

6-76X
Ir
1
8
Ph
H
H
PA2
CH₃
H
H
acac

6-76Y
Ir
0
6
Ph
H
H
PA2
CH₃
H
H
—
—

6-77
Ir
1
6
Ph
H
PA2
H
CH₃
H
H
pic

6-77X
Ir
1
6
Ph
H
PA2
H
CH₃
H
H
acac

6-77Y
Ir
0
6
Ph
H
PA2
H
CH₃
H
H
—
—

6-78
Ir
1
6
Ph
H
H
EA1
CH₃
H
H
pic

6-78X
Ir
1
6
Ph
H
H
EA1
CH₃
H
H
acac

6-78Y
Ir
0
6
Ph
H
H
EA1
CH₃
H
H
—
—

6-79
Ir
1
6
Ph
H
EA2
H
CH₃
H
H
pic

6-79X
Ir
1
6
Ph
H
EA2
H
CH₃
H
H
acac

6-79Y
Ir
0
8
Ph
H
EA2
H
CH₃
H
H
—
—

6-80
Ir
1
8
Ph
H
H
ME
CH₃
H
H
pic

6-80X
Ir
1
6
Ph
H
H
ME
CH₃
H
H
acac

6-80Y
Ir
0
6
Ph
H
H
ME
CH₃
H
H
—
—

6-81
Ir
1
6
Ph
H
ME
H
CH₃
H
H
pic

6-81X
Ir
1
6
Ph
H
ME
H
CH₃
H
H
acac

6-81Y
Ir
0
6
Ph
H
ME
H
CH₃
H
H
—
—

6-82
Ir
1
6
Ph
H
H
AT
CH₃
H
H
pic

6-82X
Ir
1
6
Ph
H
H
AT
CH₃
H
H
acac

6-82Y
Ir
0
6
Ph
H
H
AT
CH₃
H
H
—
—

6-83
Ir
1
6
Ph
H
AT
H
CH₃
H
H
pic

6-83X
Ir
1
6
Ph
H
AT
H
CH₃
H
H
acac

6-83Y
Ir
0
6
Ph
H
AT
H
CH₃
H
H
—
—

6-84
Ir
1
6
Ph
H
H
MES1
CH₃
H
H
pic

6-84X
Ir
1
6
Ph
H
H
MES1
CH₃
H
H
acac

6-84Y
Ir
0
8
Ph
H
H
MES1
CH₃
H
H
—
—

6-85
Ir
1
6
Ph
H
MES1
CH₃
H
H
H
pic

6-85X
Ir
1
8
Ph
H
MES1
CH₃
H
H
H
acac

6-85Y
Ir
0
6
Ph
H
MES1
CH₃
H
H
H
—
—

6-86
Ir
1
8
Ph
H
H
MES2
CH₃
H
H
pic

6-86X
Ir
1
8
Ph
H
H
MES2
CH₃
H
H
acac

6-86Y
Ir
0
6
Ph
H
H
MES2
CH₃
H
H
—
—

6-87
Ir
1
6
Ph
H
MES2
H
CH₃
H
H
pic

6-87X
Ir
1
6
Ph
H
MES2
H
CH₃
H
H
acac

6-87Y
Ir
0
6
Ph
H
MES2
H
CH₃
H
H
—
—

6-88
Ir
1
6
Ph
H
H
PS1
CH₃
H
H
pic

6-88X
Ir
1
6
Ph
H
H
PS1
CH₃
H
H
acac

6-88Y
Ir
0
6
Ph
H
H
PS1
CH₃
H
H
—
—

6-89
Ir
1
6
Ph
H
PS1
H
CH₃
H
H
pic

6-89X
Ir
1
6
Ph
H
PS1
H
CH₃
H
H
acac

6-89Y
Ir
0
6
Ph
H
PS1
H
CH₃
H
H
—
—

6-90
Ir
1
6
Ph
H
H
PS2
CH₃
H
H
pic

6-90X
Ir
1
6
Ph
H
H
PS2
CH₃
H
H
acac

6-90Y
Ir
0
6
Ph
H
H
PS2
CH₃
H
H
—
—

6-91
Ir
1
6
Ph
H
PS2
H
CH₃
H
H
pic

6-91X
Ir
1
6
Ph
H
PS2
H
CH₃
H
H
acac

6-91Y
Ir
0
6
Ph
H
PS2
H
CH₃
H
H
—
—

6-92
Ir
1
8
Ph
H
H
BAL1
CH₃
H
H
pic

6-92X
Ir
1
6
Ph
H
H
BAL1
CH₃
H
H
acac

6-92Y
Ir
0
6
Ph
H
H
BAL1
CH₃
H
H
—
—

6-93
Ir
1
6
Ph
H
BAL1
H
CH₃
H
H
pic

6-93X
Ir
1
6
Ph
H
BAL1
H
CH₃
H
H
acac

6-93Y
Ir
0
6
Ph
H
BAL1
H
CH₃
H
H
—
—

6-94
Ir
1
6
Ph
H
H
BAL2
CH₃
H
H
pic

6-94X
Ir
1
6
Ph
H
H
BAL2
CH₃
H
H
acac

6-94Y
Ir
0
6
Ph
H
H
BAL2
CH₃
H
H
—
—

6-95
Ir
1
6
Ph
H
BAL2
H
CH₃
H
H
pic

6-95X
Ir
1
6
Ph
H
BAL2
H
CH₃
H
H
acac

6-95Y
Ir
0
6
Ph
H
BAL2
H
CH₃
H
H
—
—

6-96
Ir
1
6
Ph
H
H
MEK1
CH₃
H
H
pic

6-96X
Ir
1
6
Ph
H
H
MEK1
CH₃
H
H
acac

6-96Y
Ir
0
6
Ph
H
H
MEK1
CH₃
H
H
—
—

6-97
Ir
1
6
Ph
H
MEK1
H
CH₃
H
H
pic

6-97X
Ir
1
6
Ph
H
MEK1
H
CH₃
H
H
acac

6-97Y
Ir
0
6
Ph
H
MEK1
H
CH₃
H
H
—
—

6-98
Ir
1
6
Ph
H
H
MEK2
CH₃
H
H
pic

6-98X
Ir
1
6
Ph
H
H
MEK2
CH₃
H
H
acac

6-98Y
Ir
0
6
Ph
H
H
MEK2
CH₃
H
H
—
—

6-99
Ir
1
6
Ph
H
MEK2
H
CH₃
H
H
pic

6-99X
Ir
1
6
Ph
H
MEK2
H
CH₃
H
H
acac

6-99Y
Ir
0
6
Ph
H
MEK2
H
CH₃
H
H
—
—

6-100
Ir
1
6
Ph
H
H
PAL1
CH₃
H
H
pic

6-100X
Ir
1
6
Ph
H
H
PAL1
CH₃
H
H
acac

6-100Y
Ir
0
6
Ph
H
H
PAL1
CH₃
H
H
—
—

6-101
Ir
1
6
Ph
H
PAL1
H
CH₃
H
H
pic

6-101X
Ir
1
6
Ph
H
PAL1
H
CH₃
H
H
acac

6-101Y
Ir
0
6
Ph
H
PAL1
H
CH₃
H
H
—
—

6-102
Ir
1
6
Ph
H
H
PAL2
CH₃
H
H
pic

6-102X
Ir
1
6
Ph
H
H
PAL2
CH₃
H
H
acac

6-102Y
Ir
0
6
Ph
H
H
PAL2
CH₃
H
H
—
—

6-103
Ir
1
6
Ph
H
PAL2
H
CH₃
H
H
pic

6-103X
Ir
1
6
Ph
H
PAL2
H
CH₃
H
H
acac

6-103Y
Ir
0
6
Ph
H
PAL2
H
CH₃
H
H
—
—

6-104
Ir
1
6
Ph
H
H
MMK
CH₃
H
H
pic

6-104X
Ir
1
6
Ph
H
H
MMK
CH₃
H
H
acac

6-104Y
Ir
0
6
Ph
H
H
MMK
CH₃
H
H
—
—

6-105
Ir
1
6
Ph
H
MMK
H
CH₃
H
H
pic

6-105X
Ir
1
6
Ph
H
MMK
H
CH₃
H
H
acac

6-105Y
Ir
0
6
Ph
H
MMK
H
CH₃
H
H
—
—

6-106
Ir
1
6
Ph
H
H
EES1
CH₃
H
H
pic

6-106X
Ir
1
6
Ph
H
H
EES1
CH₃
H
H
acac

6-106Y
Ir
0
6
Ph
H
H
EES1
CH₃
H
H
—
—

6-107
Ir
1
6
Ph
H
EES2
H
CH₃
H
H
pic

6-107X
Ir
1
6
Ph
H
EES2
H
CH₃
H
H
acac

6-107Y
Ir
0
6
Ph
H
EES2
H
CH₃
H
H
—
—

6-108
Ir
1
6
Ph
H
H
PAE1
CH₃
H
H
pic

6-108X
Ir
1
6
Ph
H
H
PAE1
CH₃
H
H
acac

6-108Y
Ir
0
6
Ph
H
H
PAE1
CH₃
H
H
—
—

6-109
Ir
1
6
Ph
H
PAE2
H
CH₃
H
H
pic

6-109X
Ir
1
6
Ph
H
PAE2
H
CH₃
H
H
acac

6-109Y
Ir
0
6
Ph
H
PAE2
H
CH₃
H
H
—
—

6-110
Ir
1
6
Ph
H
H
AME1
CH₃
H
H
pic

6-110X
Ir
1
6
Ph
H
H
AME1
CH₃
H
H
acac

6-110Y
Ir
0
6
Ph
H
H
AME1
CH₃
H
H
—
—

6-111
Ir
1
6
Ph
H
AME1
H
CH₃
H
H
pic

6-111X
Ir
1
6
Ph
H
AME1
H
CH₃
H
H
acac

6-111Y
Ir
0
6
Ph
H
AME1
H
CH₃
H
H
—
—

6-112
Ir
1
6
Ph
H
H
AME2
CH₃
H
H
pic

6-112X
Ir
1
6
Ph
H
H
AME2
CH₃
H
H
acac

6-112Y
Ir
0
6
Ph
H
H
AME2
CH₃
H
H
—
—

6-113
Ir
1
6
Ph
H
AME2
H
CH₃
H
H
pic

6-113X
Ir
1
6
Ph
H
AME2
H
CH₃
H
H
acac

6-113Y
Ir
0
6
Ph
H
AME2
H
CH₃
H
H
—
—

6-114
Ir
1
6
Ph
H
H
EAE1
CH₃
H
H
pic

6-114X
Ir
1
6
Ph
H
H
EAE1
CH₃
H
H
acac

6-114Y
Ir
0
6
Ph
H
H
EAE1
CH₃
H
H
—
—

6-115
Ir
1
6
Ph
H
EAE1
H
CH₃
H
H
pic

6-115X
Ir
1
6
Ph
H
EAE1
H
CH₃
H
H
acac

6-115Y
Ir
0
6
Ph
H
EAE1
H
CH₃
H
H
—
—

6-116
Ir
1
6
Ph
H
H
EAE2
CH₃
H
H
pic

6-116X
Ir
1
6
Ph
H
H
EAE2
CH₃
H
H
acac

6-116Y
Ir
0
6
Ph
H
H
EAE2
CH₃
H
H
—
—

6-117
Ir
1
6
Ph
H
EAE2
H
CH₃
H
H
pic

6-117X
Ir
1
6
Ph
H
EAE2
H
CH₃
H
H
acac

6-117Y
Ir
0
6
Ph
H
EAE2
H
CH₃
H
H
—
—

6-118
Ir
1
6
Ph
H
H
AAE1
CH₃
H
H
pic

6-118X
Ir
1
6
Ph
H
H
AAE1
CH₃
H
H
acac

6-118Y
Ir
0
6
Ph
H
H
AAE1
CH₃
H
H
—
—

6-119
Ir
1
6
Ph
H
AAE1
H
CH₃
H
H
pic

6-119X
Ir
1
6
Ph
H
AAE1
H
CH₃
H
H
acac

6-119Y
Ir
0
6
Ph
H
AAE1
H
CH₃
H
H
—
—

6-120
Ir
1
6
Ph
H
H
AAE2
CH₃
H
H
pic

6-120X
Ir
1
6
Ph
H
H
AAE2
CH₃
H
H
acac

6-120Y
Ir
0
6
Ph
H
H
AAE2
CH₃
H
H
—
—

6-121
Ir
1
6
Ph
H
AAE2
H
CH₃
H
H
pic

6-121X
Ir
1
6
Ph
H
AAE2
H
CH₃
H
H
acac

6-121Y
Ir
0
6
Ph
H
AAE2
H
CH₃
H
H
—
—

6-122
Ir
1
6
Ph
H
H
PME1
CH₃
H
H
pic

6-122X
Ir
1
6
Ph
H
H
PME1
CH₃
H
H
acac

6-122Y
Ir
0
6
Ph
H
H
PME1
CH₃
H
H
—
—

6-123
Ir
1
6
Ph
H
PME1
H
CH₃
H
H
pic

6-123X
Ir
1
6
Ph
H
PME1
H
CH₃
H
H
acac

6-123Y
Ir
0
6
Ph
H
PME1
H
CH₃
H
H
—
—

6-124
Ir
1
6
Ph
H
H
PME2
CH₃
H
H
pic

6-124X
Ir
1
6
Ph
H
H
PME2
CH₃
H
H
acac

6-124Y
Ir
0
6
Ph
H
H
PME2
CH₃
H
H
—
—

6-125
Ir
1
6
Ph
H
PME2
H
CH₃
H
H
pic

6-125X
Ir
1
6
Ph
H
PME2
H
CH₃
H
H
acac

6-125Y
Ir
0
6
Ph
H
PME2
H
CH₃
H
H
—
—

6-126
Ir
1
6
Ph
H
H
MET1
CH₃
H
H
pic

6-126X
Ir
1
6
Ph
H
H
MET1
CH₃
H
H
acac

6-126Y
Ir
0
6
Ph
H
H
MET1
CH₃
H
H
—
—

6-127
Ir
1
6
Ph
H
MET1
H
CH₃
H
H
pic

6-127X
Ir
1
6
Ph
H
MET1
H
CH₃
H
H
acac

6-127Y
Ir
0
6
Ph
H
MET1
H
CH₃
H
H
—
—

6-128
Ir
1
6
Ph
H
H
MET2
CH₃
H
H
pic

6-128X
Ir
1
6
Ph
H
H
MET2
CH₃
H
H
acac

6-128Y
Ir
0
6
Ph
H
H
MET2
CH₃
H
H
—
—

6-129
Ir
1
6
Ph
H
MET2
H
CH₃
H
H
pic

6-129X
Ir
1
6
Ph
H
MET2
H
CH₃
H
H
acac

6-129Y
Ir
0
6
Ph
H
MET2
H
CH₃
H
H
—
—

6-130
Ir
1
6
Ph
H
H
EE1
CH₃
H
H
pic

6-130X
Ir
1
6
Ph
H
H
EE1
CH₃
H
H
acac

6-130Y
Ir
0
6
Ph
H
H
EE1
CH₃
H
H
—
—

6-131
Ir
1
6
Ph
H
EE1
H
CH₃
H
H
pic

6-131X
Ir
1
6
Ph
H
EE1
H
CH₃
H
H
acac

6-131Y
Ir
0
6
Ph
H
EE1
H
CH₃
H
H
—
—

6-132
Ir
1
6
Ph
H
H
EE2
CH₃
H
H
pic

6-132X
Ir
1
6
Ph
H
H
EE2
CH₃
H
H
acac

6-132Y
Ir
0
6
Ph
H
H
EE2
CH₃
H
H
—
—

6-133
Ir
1
6
Ph
H
EE2
H
CH₃
H
H
pic

6-133X
Ir
1
6
Ph
H
EE2
H
CH₃
H
H
acac

6-133Y
Ir
0
6
Ph
H
EE2
H
CH₃
H
H
—
—

6-134
Ir
1
6
Ph
H
H
MS1
CH₃
H
H
pic

6-134X
Ir
1
6
Ph
H
H
MS1
CH₃
H
H
acac

6-134Y
Ir
0
6
Ph
H
H
MS1
CH₃
H
H
—
—

6-135
Ir
1
6
Ph
H
MS1
H
CH₃
H
H
pic

6-135X
Ir
1
6
Ph
H
MS1
H
CH₃
H
H
acac

6-135Y
Ir
0
6
Ph
H
MS1
H
CH₃
H
H
—
—

6-136
Ir
1
6
Ph
H
H
MS2
CH₃
H
H
pic

6-136X
Ir
1
6
Ph
H
H
MS2
CH₃
H
H
acac

6-136Y
Ir
0
6
Ph
H
H
MS2
CH₃
H
H
—
—

6-137
Ir
1
6
Ph
H
MS2
H
CH₃
H
H
pic

6-137X
Ir
1
6
Ph
H
MS2
H
CH₃
H
H
acac

6-137Y
Ir
0
6
Ph
H
MS2
H
CH₃
H
H
—
—

TABLE 7

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

7-1
Ir
1
7
Ph
H
H
H
H
CH₃
H
H
pic

7-1X
Ir
1
7
Ph
H
H
H
H
CH₃
H
H
acac

7-1Y
Ir
0
7
Ph
H
H
H
H
CH₃
H
H
—
—

7-2
Ir
1
7
Ph
H
H
H
H

^tC₄H₉
H
H
pic

7-2X
Ir
1
7
Ph
H
H
H
H

^tC₄H₉
H
H
acac

7-2Y
Ir
0
7
Ph
H
H
H
H

^tC₄H₉
H
H
—
—

7-3
Ir
1
7
Ph
H
F
H
F
CH₃
H
H
pic

7-3X
Ir
1
7
Ph
H
F
H
F
CH₃
H
H
acac

7-3Y
Ir
0
7
Ph
H
F
H
F
CH₃
H
H
—
—

7-4
Ir
1
7
Ph
H
F
H
F

^tC₄H₉
H
H
pic

7-4X
Ir
1
7
Ph
H
F
H
F

^tC₄H₉
H
H
acac

7-4Y
Ir
0
7
Ph
H
F
H
F

^tC₄H₉
H
H
—
—

7-5
Ir
1
7
Ph
F
H
H
F
CH₃
H
H
pic

7-5X
Ir
1
7
Ph
F
H
H
F
CH₃
H
H
acac

7-5Y
Ir
0
7
Ph
F
H
H
F
CH₃
H
H
—
—

7-6
Ir
1
7
Ph
F
H
H
F

^tC₄H₉
H
H
pic

7-6X
Ir
1
7
Ph
F
H
H
F

^tC₄H₉
H
H
acac

7-6Y
Ir
0
7
Ph
F
H
H
F

^tC₄H₉
H
H
—
—

7-7
Ir
1
7
Ph
CF₃
H
CF₃
H
CH₃
H
H
pic

7-7X
Ir
1
7
Ph
CF₃
H
CF₃
H
CH₃
H
H
acac

7-7Y
Ir
0
7
Ph
CF₃
H
CF₃
H
CH₃
H
H
—
—

7-8
Ir
1
7
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

7-8X
Ir
1
7
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

7-8Y
Ir
0
7
Ph
CF₃
H
CF₃
H
H
H
H
—
—

7-9
Ir
1
7
Ph
H
F
CF₃
H
CH₃
H
H
pic

7-9X
Ir
1
7
Ph
H
F
CF₃
H
CH₃
H
H
acac

7-9Y
Ir
0
7
Ph
H
F
CF₃
H
CH₃
H
H
—
—

7-10
Ir
1
7
Ph
F
H
CF₃
H
CH₃
H
H
pic

7-10X
Ir
1
7
Ph
F
H
CF₃
H
CH₃
H
H
acac

7-10Y
Ir
0
7
Ph
F
H
CF₃
H
CH₃
H
H
—
—

7-11
Ir
1
7
Ph
F
F
F
F
CH₃
H
H
pic

7-11X
Ir
1
7
Ph
F
F
F
F
CH₃
H
H
acac

7-11Y
Ir
0
7
Ph
F
F
F
F
CH₃
H
H
—
—

7-12
Ir
1
7
Ph
H
F
H
CH₃
CH₃
H
H
pic

7-12X
Ir
1
7
Ph
H
F
H
CH₃
CH₃
H
H
acac

7-12Y
Ir
0
7
Ph
H
F
H
CH₃
CH₃
H
H
—
—

7-13
Ir
1
7
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

7-13X
Ir
1
7
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

7-13Y
Ir
0
7
Ph
H
F
H
CH₃

^tC₄H₉
H
H
—
—

7-14
Ir
1
7
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

7-14X
Ir
1
7
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

7-14Y
Ir
0
7
Ph
H
F
H

^tC₄H₉
CH₃
H
H
—
—

7-15
Ir
1
7
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-15X
Ir
1
7
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-15Y
Ir
0
7
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-16
Ir
1
7
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

7-16X
Ir
1
7
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

7-16Y
Ir
0
7
Ph
H
CF₃
H
CF₃
CH₃
H
H
—
—

7-17
Ir
1
7
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

7-17X
Ir
1
7
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

7-17Y
Ir
0
7
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
—
—

7-18
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

7-18X
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

7-18Y
Ir
0
7
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
—
—

7-19
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-19X
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-19Y
Ir
0
7
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-20
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
CH₃
pic

7-20X
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

7-20Y
Ir
0
7
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
—
—

7-21
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-21X
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-21Y
Ir
0
7
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H

—

7-22
Ir
1
7
Ph
H
CF₃
H
CH3
CH₃
H
H
pic

7-22X
Ir
1
7
Ph
H
CF₃
H
CH3
CH₃
H
H
acac

7-22Y
Ir
0
7
Ph
H
CF₃
H
CH3
CH₃
H
H
—
—

7-23
Ir
1
7
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

7-23X
Ir
1
7
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

7-23Y
Ir
0
7
Ph
H
CF₃
CF₃
H
CH₃
H
H
—
—

7-24
Ir
1
7
Ph
H
H
NO₂
H
CH₃
H
H
pic

7-24X
Ir
1
7
Ph
H
H
NO₂
H
CH₃
H
H
acac

7-24Y
Ir
0
7
Ph
H
H
NO₂
H
CH₃
H
H

—

7-25
Ir
1
7
Ph
H
H
NO₂
H

^tC₄H₉
H
H
pic

7-25X
Ir
1
7
Ph
H
H
NO₂
H

^tC₄H₉
H
H
acac

7-25Y
Ir
0
7
Ph
H
H
NO₂
H

^tC₄H₉
H
H
—
—

7-26
Ir
1
7
Ph
F
H
NO₂
H
CH₃
H
H
pic

7-26X
Ir
1
7
Ph
F
H
NO₂
H
CH₃
H
H
acac

7-26Y
Ir
0
7
Ph
F
H
NO₂
H
CH₃
H
H
—
—

7-27
Ir
1
7
Ph
F
H
NO₂
F
CH₃
H
H
pic

7-27X
Ir
1
7
Ph
F
H
NO₂
F
CH₃
H
H
acac

7-27Y
Ir
0
7
Ph
F
H
NO₂
F
CH₃
H
H
—
—

7-28
Ir
1
7
Ph
H
NO₂
H
NO₂
CH₃
H
H
pic

7-28X
Ir
1
7
Ph
H
NO₂
H
NO₂
CH₃
H
H
acac

7-28Y
Ir
0
7
Ph
H
NO₂
H
NO₂
CH₃
H
H
—
—

7-29
Ir
1
7
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
pic

7-29X
Ir
1
7
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
acac

7-29Y
Ir
0
7
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
—
—

7-30
Ir
1
7
Ph
NO₂
H
H
NO₂
CH₃
H
H
pic

7-30X
Ir
1
7
Ph
NO₂
H
H
NO₂
CH₃
H
H
acac

7-30Y
Ir
0
7
Ph
NO₂
H
H
NO₂
CH₃
H
H
—
—

7-31
Ir
1
7
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
pic

7-31X
Ir
1
7
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
acac

7-31Y
Ir
0
7
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
—
—

7-32
Ir
1
7
Ph
H
H
CF₃
H
CH₃
H
H
pic

7-32X
Ir
1
7
Ph
H
H
CF₃
H
CH₃
H
H
acac

7-32Y
Ir
0
7
Ph
H
H
CF₃
H
CH₃
H
H
—
—

7-33
Ir
1
7
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

7-33X
Ir
1
7
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

7-33Y
Ir
0
7
Ph
H
H
CF₃
H

^tC₄H₉
H
H
—
—

7-34
Ir
1
7
Ph
H
Cl
CF₃
H
CH₃
H
H
pic

7-34X
Ir
1
7
Ph
H
Cl
CF₃
H
CH₃
H
H
acac

7-34Y
Ir
0
7
Ph
H
Cl
CF₃
H
CH₃
H
H
—
—

7-35
Ir
1
7
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
pic

7-35X
Ir
1
7
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
acac

7-35Y
Ir
0
7
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
—
—

7-36
Ir
1
7
Ph
H
NO₂
H
H
CH₃
H
H
pic

7-36X
Ir
1
7
Ph
H
NO₂
H
H
CH₃
H
H
acac

7-36Y
Ir
0
7
Ph
H
NO₂
H
H
CH₃
H
H
—
—

7-37
Ir
1
7
Ph
H
CF₃
H
H
CH₃
H
H
pic

7-37X
Ir
1
7
Ph
H
CF₃
H
H
CH₃
H
H
acac

7-37Y
Ir
0
7
Ph
H
CF₃
H
H
CH₃
H
H
—
—

7-38
Ir
1
7
Ph
H
NO₂
H
CH3
CH₃
H
H
pic

7-38X
Ir
1
7
Ph
H
NO₂
H
CH3
CH₃
H
H
acac

7-38Y
Ir
0
7
Ph
H
NO₂
H
CH3
CH₃
H
H
—
—

7-39
Ir
1
7
Ph
H
NO₂
H
CH3

^tC₄H₉
H
H
pic

7-39X
Ir
1
7
Ph
H
NO₂
H
CH3

^tC₄H₉
H
H
acac

7-39Y
Ir
0
7
Ph
H
NO₂
H
CH3

^tC₄H₉
H
H
—
—

7-40
Ir
1
7
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
pic

7-40X
Ir
1
7
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
acac

7-40Y
Ir
1
7
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
—
—

7-41
Ir
1
7
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-41X
Ir
1
7
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-41Y
Ir
0
7
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-42
Ir
1
7
Ph
H
H
CH₃O
H
CH₃
H
H
pic

7-42X
Ir
1
7
Ph
H
H
CH₃O
H
CH₃
H
H
acac

7-42Y
Ir
0
7
Ph
H
H
CH₃O
H
CH₃
H
H
—
—

7-43
Ir
1
7
Ph
H
CH₃O
H
H
CH₃
H
H
pic

7-43X
Ir
1
7
Ph
H
CH₃O
H
H
CH₃
H
H
acac

7-43Y
Ir
0
7
Ph
H
CH₃O
H
H
CH₃
H
H
—
—

7-44
Ir
1
7
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

7-44X
Ir
1
7
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

7-44Y
Ir
0
7
Ph
H
CH₃O
H
CH₃
CH₃
H
H
—
—

7-45
Ir
1
7
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

7-45X
Ir
1
7
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

7-45Y
Ir
0
7
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
—
—

7-46
Ir
1
7
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
pic

7-46X
Ir
1
7
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
acac

7-46Y
Ir
0
7
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
—
—

7-47
Ir
1
7
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
pic

7-47X
Ir
1
7
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
acac

7-47Y
Ir
0
7
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
—
—

7-48
Ir
1
7
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
pic

7-48X
Ir
1
7
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
acac

7-48Y
Ir
0
7
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
—
—

7-49
Ir
1
7
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
pic

7-49X
Ir
1
7
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
acac

7-49Y
Ir
0
7
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
—
—

7-50
Ir
1
7
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
pic

7-50X
Ir
1
7
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
acac

7-50Y
Ir
0
7
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
—
—

7-51
Ir
1
7
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
pic

7-51X
Ir
1
7
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
acac

7-51Y
Ir
0
7
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
—
—

7-52
Ir
1
7
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
pic

7-52X
Ir
1
7
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
acac

7-52Y
Ir
0
7
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
—
—

7-53
Ir
1
7
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
pic

7-53X
Ir
1
7
Ph
H
Si (CH₃)₃
H
F
CH₃
H
H
acac

7-53Y
Ir
0
7
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
—
—

7-54
Ir
1
7
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
pic

7-54X
Ir
1
7
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
acac

7-54Y
Ir
0
7
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
—
—

7-55
Ir
1
7
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
pic

7-55X
Ir
1
7
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
acac

7-55Y
Ir
0
7
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
—
—

7-56
Ir
1
7
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

7-56X
Ir
1
7
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

7-56Y
Ir
0
7
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
—
—

7-57
Ir
1
7
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
pic

7-57X
Ir
1
7
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
acac

7-57Y
Ir
0
7
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
—
—

7-58
Ir
1
7
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
pic

7-58X
Ir
1
7
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
acac

7-58Y
Ir
0
7
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
—
—

7-59
Ir
1
7
Ph
H
H
H
COCH₃
CH₃
H
H
pic

7-59X
Ir
1
7
Ph
H
H
H
COCH₃
CH₃
H
H
acac

7-59Y
Ir
0
7
Ph
H
H
H
COCH₃
CH₃
H
H
—
—

7-60
Ir
1
7
Ph
H
H
COCH₃
H
CH₃
H
H
pic

7-60X
Ir
1
7
Ph
H
H
COCH₃
H
CH₃
H
H
acac

7-60Y
Ir
0
7
Ph
H
H
COCH₃
H
CH₃
H
H
—
—

7-61
Ir
1
7
Ph
H
COCH₃
H
H
CH₃
H
H
pic

7-61X
Ir
1
7
Ph
H
COCH₃
H
H
CH₃
H
H
acac

7-61Y
Ir
0
7
Ph
H
COCH₃
H
H
CH₃
H
H

—

7-62
Ir
1
7
Ph
H
H
BL
CH₃
H
H
pic

7-62X
Ir
1
7
Ph
H
H
BL
CH₃
H
H
acac

7-62Y
Ir
0
7
Ph
H
H
BL
CH₃
H
H
—
—

7-63
Ir
1
7
Ph
H
H
BL

^tC₄H₉
H
H
pic

7-63X
Ir
1
7
Ph
H
H
BL

^tC₄H₉
H
H
acac

7-63Y
Ir
0
7
Ph
H
H
BL

^tC₄H₉
H
H
—
—

7-64
Ir
1
7
Ph
H
BL
H
CH₃
H
H
pic

7-64X
Ir
1
7
Ph
H
BL
H
CH₃
H
H
acac

7-64Y
Ir
0
7
Ph
H
BL
H
CH₃
H
H
—
—

7-65
Ir
1
7
Ph
H
BL
H

^tC₄H₉
H
H
pic

7-65X
Ir
1
7
Ph
H
BL
H

^tC₄H₉
H
H
acac

7-65Y
Ir
0
7
Ph
H
BL
H

^tC₄H₉
H
H
—
—

7-66
Ir
1
7
Ph
H
H
PL
CH₃
H
H
pic

7-66X
Ir
1
7
Ph
H
H
PL
CH₃
H
H
acac

7-66Y
Ir
0
7
Ph
H
H
PL
CH₃
H
H
—
—

7-67
Ir
1
7
Ph
H
H
PL

^tC₄H₉
H
H
pic

7-67X
Ir
1
7
Ph
H
H
PL

^tC₄H₉
H
H
acac

7-67Y
Ir
0
7
Ph
H
H
PL

^tC₄H₉
H
H
—
—

7-68
Ir
1
7
Ph
H
PL
H
CH₃
H
H
pic

7-68X
Ir
1
7
Ph
H
PL
H
CH₃
H
H
acac

7-68Y
Ir
0
7
Ph
H
PL
H
CH₃
H
H
—
—

7-69
Ir
1
7
Ph
H
PL
H

^tC₄H₉
H
H
pic

7-69X
Ir
1
7
Ph
H
PL
H

^tC₄H₉
H
H
acac

7-69Y
Ir
0
7
Ph
H
PL
H

^tC₄H₉
H
H
—
—

7-70
Ir
1
7
Ph
H
H
MEE1
CH₃
H
H
pic

7-70X
Ir
1
7
Ph
H
H
MEE1
CH₃
H
H
acac

7-70Y
Ir
0
7
Ph
H
H
MEE1
CH₃
H
H
—
—

7-71
Ir
1
7
Ph
H
MEE1
H
CH₃
H
H
pic

7-71X
Ir
1
7
Ph
H
MEE1
H
CH₃
H
H
acac

7-71Y
Ir
0
7
Ph
H
MEE1
H
CH₃
H
H
—
—

7-72
Ir
1
7
Ph
H
H
MEE2
CH₃
H
H
pic

7-72X
Ir
1
7
Ph
H
H
MEE2
CH₃
H
H
acac

7-72Y
Ir
0
7
Ph
H
H
MEE2
CH₃
H
H
—
—

7-73
Ir
1
7
Ph
H
MEE2
H
CH₃
H
H
pic

7-73X
Ir
1
7
Ph
H
MEE2
H
CH₃
H
H
acac

7-73Y
Ir
0
7
Ph
H
MEE2
H
CH₃
H
H
—
—

7-74
Ir
1
7
Ph
H
H
PA1
CH₃
H
H
pic

7-74X
Ir
1
7
Ph
H
H
PA1
CH₃
H
H
acac

7-74Y
Ir
0
7
Ph
H
H
PA1
CH₃
H
H
—
—

7-75
Ir
1
7
Ph
H
PA1
H
CH₃
H
H
pic

7-75X
Ir
1
7
Ph
H
PA1
H
CH₃
H
H
acac

7-75Y
Ir
0
7
Ph
H
PA1
H
CH₃
H
H
—
—

7-76
Ir
1
7
Ph
H
H
PA2
CH₃
H
H
pic

7-76X
Ir
1
7
Ph
H
H
PA2
CH₃
H
H
acac

7-76Y
Ir
0
7
Ph
H
H
PA2
CH₃
H
H
—
—

7-77
Ir
1
7
Ph
H
PA2
H
CH₃
H
H
pic

7-77X
Ir
1
7
Ph
H
PA2
H
CH₃
H
H
acac

7-77Y
Ir
0
7
Ph
H
PA2
H
CH₃
H
H
—
—

7-78
Ir
1
7
Ph
H
H
EA1
CH₃
H
H
pic

7-78X
Ir
1
7
Ph
H
H
EA1
CH₃
H
H
acac

7-78Y
Ir
0
7
Ph
H
H
EA1
CH₃
H
H
—
—

7-79
Ir
1
7
Ph
H
EA2
H
CH₃
H
H
pic

7-79X
Ir
1
7
Ph
H
EA2
H
CH₃
H
H
acac

7-79Y
Ir
0
7
Ph
H
EA2
H
CH₃
H
H
—
—

7-80
Ir
1
7
Ph
H
H
ME
CH₃
H
H
pic

7-80X
Ir
1
7
Ph
H
H
ME
CH₃
H
H
acac

7-80Y
Ir
0
7
Ph
H
H
ME
CH₃
H
H
—
—

7-81
Ir
1
7
Ph
H
ME
H
CH₃
H
H
pic

7-81X
Ir
1
7
Ph
H
ME
H
CH₃
H
H
acac

7-81Y
Ir
0
7
Ph
H
ME
H
CH₃
H
H
—
—

7-82
Ir
1
7
Ph
H
H
AT
CH₃
H
H
pic

7-82X
Ir
1
7
Ph
H
H
AT
CH₃
H
H
acac

7-82Y
Ir
0
7
Ph
H
H
AT
CH₃
H
H
—
—

7-83
Ir
1
7
Ph
H
AT
H
CH₃
H
H
pic

7-83X
Ir
1
7
Ph
H
AT
H
CH₃
H
H
acac

7-83Y
Ir
0
7
Ph
H
AT
H
CH₃
H
H
—
—

7-84
Ir
1
7
Ph
H
H
MES1
CH₃
H
H
pic

7-84X
Ir
1
7
Ph
H
H
MES1
CH₃
H
H
acac

7-84Y
Ir
0
7
Ph
H
H
MES1
CH₃
H
H
—
—

7-85
Ir
1
7
Ph
H
MES1
H
CH₃
H
H
pic

7-85X
Ir
1
7
Ph
H
MES1
H
CH₃
H
H
acac

7-85Y
Ir
0
7
Ph
H
MES1
H
CH₃
H
H
—
—

7-86
Ir
1
7
Ph
H
H
MES2
CH₃
H
H
pic

7-86X
Ir
1
7
Ph
H
H
MES2
CH₃
H
H
acac

7-86Y
Ir
0
7
Ph
H
H
MES2
CH₃
H
H
—
—

7-87
Ir
1
7
Ph
H
MES2
H
CH₃
H
H
pic

7-87X
Ir
1
7
Ph
H
MES2
H
CH₃
H
H
acac

7-87Y
Ir
0
7
Ph
H
MES2
H
CH₃
H
H
—
—

7-88
Ir
1
7
Ph
H
H
PS1
CH₃
H
H
pic

7-88X
Ir
1
7
Ph
H
H
PS1
CH₃
H
H
acac

7-88Y
Ir
0
7
Ph
H
H
PS1
CH₃
H
H
—
—

7-89
Ir
1
7
Ph
H
PS1
H
CH₃
H
H
pic

7-89X
Ir
1
7
Ph
H
PS1
H
CH₃
H
H
acac

7-89Y
Ir
0
7
Ph
H
PS1
H
CH₃
H
H
—
—

7-90
Ir
1
7
Ph
H
H
PS2
CH₃
H
H
pic

7-90X
Ir
1
7
Ph
H
H
PS2
CH₃
H
H
acac

7-90Y
Ir
0
7
Ph
H
H
PS2
CH₃
H
H
—
—

7-91
Ir
1
7
Ph
H
PS2
H
CH₃
H
H
pic

7-91X
Ir
1
7
Ph
H
PS2
H
CH₃
H
H
acac

7-91Y
Ir
0
7
Ph
H
PS2
H
CH₃
H
H
—
—

7-92
Ir
1
7
Ph
H
H
BAL1
CH₃
H
H
pic

7-92X
Ir
1
7
Ph
H
H
BAL1
CH₃
H
H
acac

7-92Y
Ir
0
7
Ph
H
H
BAL1
CH₃
H
H
—
—

7-93
Ir
1
7
Ph
H
BAL1
H
CH₃
H
H
pic

7-93X
Ir
1
7
Ph
H
BAL1
H
CH₃
H
H
acac

7-93Y
Ir
0
7
Ph
H
BAL1
H
CH₃
H
H
—
—

7-94
Ir
1
7
Ph
H
H
BAL2
CH₃
H
H
pic

7-94X
Ir
1
7
Ph
H
H
BAL2
CH₃
H
H
acac

7-94Y
Ir
0
7
Ph
H
H
BAL2
CH₃
H
H
—
—

7-95
Ir
1
7
Ph
H
BAL2
H
CH₃
H
H
pic

7-95X
Ir
1
7
Ph
H
BAL2
H
CH₃
H
H
acac

7-95Y
Ir
0
7
Ph
H
BAL2
H
CH₃
H
H
—
—

7-96
Ir
1
7
Ph
H
H
MEK1
CH₃
H
H
pic

7-96X
Ir
1
7
Ph
H
H
MEK1
CH₃
H
H
acac

7-96Y
Ir
0
7
Ph
H
H
MEK1
CH₃
H
H
—
—

7-97
Ir
1
7
Ph
H
MEK1
H
CH₃
H
H
pic

7-97X
Ir
1
7
Ph
H
MEK1
H
CH₃
H
H
acac

7-97Y
Ir
0
7
Ph
H
MEK1
H
CH₃
H
H
—
—

7-98
Ir
1
7
Ph
H
H
MEK2
CH₃
H
H
pic

7-98X
Ir
1
7
Ph
H
H
MEK2
CH₃
H
H
acac

7-98Y
Ir
0
7
Ph
H
H
MEK2
CH₃
H
H
—
—

7-99
Ir
1
7
Ph
H
MEK2
H
CH₃
H
H
pic

7-99X
Ir
1
7
Ph
H
MEK2
H
CH₃
H
H
acac

7-99Y
Ir
0
7
Ph
H
MEK2
H
CH₃
H
H
—
—

7-100
Ir
1
7
Ph
H
H
PAL1
CH₃
H
H
pic

7-100X
Ir
1
7
Ph
H
H
PAL1
CH₃
H
H
acac

7-100Y
Ir
0
7
Ph
H
H
PAL1
CH₃
H
H
—
—

7-101
Ir
1
7
Ph
H
PAL1
H
CH₃
H
H
pic

7-101X
Ir
1
7
Ph
H
PAL1
H
CH₃
H
H
acac

7-101Y
Ir
0
7
Ph
H
PAL1
H
CH₃
H
H
—
—

7-102
Ir
1
7
Ph
H
H
PAL2
CH₃
H
H
pic

7-102X
Ir
1
7
Ph
H
H
PAL2
CH₃
H
H
acac

7-102Y
Ir
0
7
Ph
H
H
PAL2
CH₃
H
H
—
—

7-103
Ir
1
7
Ph
H
PAL2
H
CH₃
H
H
pic

7-103X
Ir
1
7
Ph
H
PAL2
H
CH₃
H
H
acac

7-103Y
Ir
0
7
Ph
H
PAL2
H
CH₃
H
H
—
—

7-104
Ir
1
7
Ph
H
H
MMK
CH₃
H
H
pic

7-104X
Ir
1
7
Ph
H
H
MMK
CH₃
H
H
acac

7-104Y
Ir
0
7
Ph
H
H
MMK
CH₃
H
H
—
—

7-105
Ir
1
7
Ph
H
MMK
H
CH₃
H
H
pic

7-105X
Ir
1
7
Ph
H
MMK
H
CH₃
H
H
acac

7-105Y
Ir
0
7
Ph
H
MMK
H
CH₃
H
H
—
—

7-106
Ir
1
7
Ph
H
H
EES1
CH₃
H
H
pic

7-106X
Ir
1
7
Ph
H
H
EES1
CH₃
H
H
acac

7-106Y
Ir
0
7
Ph
H
H
EES1
CH₃
H
H
—
—

7-107
Ir
1
7
Ph
H
EES2
H
CH₃
H
H
pic

7-107X
Ir
1
7
Ph
H
EES2
H
CH₃
H
H
acac

7-107Y
Ir
0
7
Ph
H
EES2
H
CH₃
H
H
—
—

7-108
Ir
1
7
Ph
H
H
PAE1
CH₃
H
H
pic

7-108X
Ir
1
7
Ph
H
H
PAE1
CH₃
H
H
acac

7-108Y
Ir
0
7
Ph
H
H
PAE1
CH₃
H
H
—
—

7-109
Ir
1
7
Ph
H
PAE2
H
CH₃
H
H
pic

7-109X
Ir
1
7
Ph
H
PAE2
H
CH₃
H
H
acac

7-109Y
Ir
0
7
Ph
H
PAE2
H
CH₃
H
H
—
—

7-110
Ir
1
7
Ph
H
H
AME1
CH₃
H
H
pic

7-110X
Ir
1
7
Ph
H
H
AME1
CH₃
H
H
acac

7-110Y
Ir
0
7
Ph
H
H
AME1
CH₃
H
H
—
—

7-111
Ir
1
7
Ph
H
AME1
H
CH₃
H
H
pic

7-111X
Ir
1
7
Ph
H
AME1
H
CH₃
H
H
acac

7-111Y
Ir
0
7
Ph
H
AME1
H
CH₃
H
H
—
—

7-112
Ir
1
7
Ph
H
H
AME2
CH₃
H
H
pic

7-112X
Ir
1
7
Ph
H
H
AME2
CH₃
H
H
acac

7-112Y
Ir
0
7
Ph
H
H
AME2
CH₃
H
H
—
—

7-113
Ir
1
7
Ph
H
AME2
H
CH₃
H
H
pic

7-113X
Ir
1
7
Ph
H
AME2
H
CH₃
H
H
acac

7-113Y
Ir
0
7
Ph
H
AME2
H
CH₃
H
H
—
—

7-114
Ir
1
7
Ph
H
H
EAE1
CH₃
H
H
pic

7-114X
Ir
1
7
Ph
H
H
EAE1
CH₃
H
H
acac

7-114Y
Ir
0
7
Ph
H
H
EAE1
CH₃
H
H
—
—

7-115
Ir
1
7
Ph
H
EAE1
H
CH₃
H
H
pic

7-115X
Ir
1
7
Ph
H
EAE1
H
CH₃
H
H
acac

7-115Y
Ir
0
7
Ph
H
EAE1
H
CH₃
H
H
—
—

7-116
Ir
1
7
Ph
H
H
EAE2
CH₃
H
H
pic

7-116X
Ir
1
7
Ph
H
H
EAE2
CH₃
H
H
acac

7-116Y
Ir
0
7
Ph
H
H
EAE2
CH₃
H
H
—
—

7-117
Ir
1
7
Ph
H
EAE2
H
CH₃
H
H
pic

7-117X
Ir
1
7
Ph
H
EAE2
H
CH₃
H
H
acac

7-117Y
Ir
0
7
Ph
H
EAE2
H
CH₃
H
H
—
—

7-118
Ir
1
7
Ph
H
H
AAE1
CH₃
H
H
pic

7-118X
Ir
1
7
Ph
H
H
AAE1
CH₃
H
H
acac

7-118Y
Ir
0
7
Ph
H
H
AAE1
CH₃
H
H
—
—

7-119
Ir
1
7
Ph
H
AAE1
H
CH₃
H
H
pic

7-119X
Ir
1
7
Ph
H
AAE1
H
CH₃
H
H
acac

7-119Y
Ir
0
7
Ph
H
AAE1
H
CH₃
H
H
—
—

7-120
Ir
1
7
Ph
H
H
AAE2
CH₃
H
H
pic

7-120X
Ir
1
7
Ph
H
H
AAE2
CH₃
H
H
acac

7-120Y
Ir
0
7
Ph
H
H
AAE2
CH₃
H
H
—
—

7-121
Ir
1
7
Ph
H
AAE2
H
CH₃
H
H
pic

7-121X
Ir
1
7
Ph
H
AAE2
H
CH₃
H
H
acac

7-121Y
Ir
0
7
Ph
H
AAE2
H
CH₃
H
H
—
—

7-122
Ir
1
7
Ph
H
H
PME1
CH₃
H
H
pic

7-122X
Ir
1
7
Ph
H
H
PME1
CH₃
H
H
acac

7-122Y
Ir
0
7
Ph
H
H
PME1
CH₃
H
H
—
—

7-123
Ir
1
7
Ph
H
PME1
H
CH₃
H
H
pic

7-123X
Ir
1
7
Ph
H
PME1
H
CH₃
H
H
acac

7-123Y
Ir
0
7
Ph
H
PME1
H
CH₃
H
H
—
—

7-124
Ir
1
7
Ph
H
H
PME2
CH₃
H
H
pic

7-124X
Ir
1
7
Ph
H
H
PME2
CH₃
H
H
acac

7-124Y
Ir
0
7
Ph
H
H
PME2
CH₃
H
H
—
—

7-125
Ir
1
7
Ph
H
PME2
H
CH₃
H
H
pic

7-125X
Ir
1
7
Ph
H
PME2
H
CH₃
H
H
acac

7-125Y
Ir
0
7
Ph
H
PME2
H
CH₃
H
H
—
—

7-126
Ir
1
7
Ph
H
H
MET1
CH₃
H
H
pic

7-126X
Ir
1
7
Ph
H
H
MET1
CH₃
H
H
acac

7-126Y
Ir
0
7
Ph
H
H
MET1
CH₃
H
H
—
—

7-127
Ir
1
7
Ph
H
MET1
H
CH₃
H
H
pic

7-127X
Ir
1
7
Ph
H
MET1
H
CH₃
H
H
acac

7-127Y
Ir
0
7
Ph
H
MET1
H
CH₃
H
H
—
—

7-128
Ir
1
7
Ph
H
H
MET2
CH₃
H
H
pic

7-128X
Ir
1
7
Ph
H
H
MET2
CH₃
H
H
acac

7-128Y
Ir
0
7
Ph
H
H
MET2
CH₃
H
H
—
—

7-129
Ir
1
7
Ph
H
MET2
H
CH₃
H
H
pic

7-129X
Ir
1
7
Ph
H
MET2
H
CH₃
H
H
acac

7-129Y
Ir
0
7
Ph
H
MET2
H
CH₃
H
H
—
—

7-130
Ir
1
7
Ph
H
H
EE1
CH₃
H
H
pic

7-130X
Ir
1
7
Ph
H
H
EE1
CH₃
H
H
acac

7-130Y
Ir
0
7
Ph
H
H
EE1
CH₃
H
H
—
—

7-131
Ir
1
7
Ph
H
EE1
H
CH₃
H
H
pic

7-131X
Ir
1
7
Ph
H
EE1
H
CH₃
H
H
acac

7-131Y
Ir
0
7
Ph
H
EE1
H
CH₃
H
H
—
—

7-132
Ir
1
7
Ph
H
H
EE2
CH₃
H
H
pic

7-132X
Ir
1
7
Ph
H
H
EE2
CH₃
H
H
acac

7-132Y
Ir
0
7
Ph
H
H
EE2
CH₃
H
H
—
—

7-133
Ir
1
7
Ph
H
EE2
H
CH₃
H
H
pic

7-133X
Ir
1
7
Ph
H
EE2
H
CH₃
H
H
acac

7-133Y
Ir
0
7
Ph
H
EE2
H
CH₃
H
H
—
—

7-134
Ir
1
7
Ph
H
H
MS1
CH₃
H
H
pic

7-134X
Ir
1
7
Ph
H
H
MS1
CH₃
H
H
acac

7-134Y
Ir
0
7
Ph
H
H
MS1
CH₃
H
H
—
—

7-135
Ir
1
7
Ph
H
MS1
H
CH₃
H
H
pic

7-135X
Ir
1
7
Ph
H
MS1
H
CH₃
H
H
acac

7-135Y
Ir
0
7
Ph
H
MS1
H
CH₃
H
H
—
—

7-136
Ir
1
7
Ph
H
H
MS2
CH₃
H
H
pic

7-136X
Ir
1
7
Ph
H
H
MS2
CH₃
H
H
acac

7-136Y
Ir
0
7
Ph
H
H
MS2
CH₃
H
H
—
—

7-137
Ir
1
7
Ph
H
MS2
H
CH₃
H
H
pic

7-137X
Ie
1
7
Ph
H
MS2
H
CH₃
H
H
acac

7-137Y
Ir
0
7
Ph
H
MS2
H
CH₃
H
H
—
—

embedded image

TABLE 8

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1-119
Ir
1
1
Nap1
—
—
H
H
H
H
H
pic

1-119X
Ir
1
1
Nap1
—
—
H
H
H
H
H
acac

1-119Y
Ir
0
1
Nap1
—
—
H
H
H
H
H
—
—

1-120
Ir
1
1
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

1-120X
Ir
1
1
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

1-120Y
Ir
0
1
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

1-121
Ir
1
1
Nap1
—
—
CH₃
H
H
H
H
pic

1-121X
Ir
1
1
Nap1
—
—
CH₃
H
H
H
H
acac

1-121Y
Ir
0
1
Nap1
—
—
CH₃
H
H
H
H
—
—

1-122
Ir
1
1
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-122X
Ir
1
1
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-122Y
Ir
0
1
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-123
Ir
1
1
Nap1
—
—
CH₃
CH₃
H
H
H
pic

1-123X
Ir
1
1
Nap1
—
—
CH₃
CH₃
H
H
H
acac

1-123Y
Ir
0
1
Nap1
—
—
CH₃
CH₃
H
H
H
—
—

1-124
Ir
1
1
Nap1
—
—
H
CH₃
H
H
H
pic

1-124X
Ir
1
1
Nap1
—
—
H
CH₃
H
H
H
acac

1-124Y
Ir
0
1
Nap1
—
—
H
CH₃
H
H
H
—
—

1-125
Ir
1
1
Nap2
—
—
H
H
H
H
H
pic

1-125X
Ir
1
1
Nap2
—
—
H
H
H
H
H
acac

1-125Y
Ir
0
1
Nap2
—
—
H
H
H
H
H
—
—

1-126
Ir
1
1
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

1-126X
Ir
1
1
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

1-126Y
Ir
0
1
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

1-127
Ir
1
1
Nap2
—
—
CH₃
H
H
H
H
pic

1-127X
Ir
1
1
Nap2
—
—
CH₃
H
H
H
H
acac

1-127Y
Ir
0
1
Nap2
—
—
CH₃
H
H
H
H
—
—

1-128
Ir
1
1
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-128X
Ir
1
1
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-128Y
Ir
0
1
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-129
Ir
1
1
Nap2
—
—
CH₃
CH₃
H
H
H
pic

1-129X
Ir
1
1
Nap2
—
—
CH₃
CH₃
H
H
H
acac

1-129Y
Ir
0
1
Nap2
—
—
CH₃
CH₃
H
H
H
—
—

1-130
Ir
1
1
Nap2
—
—
H
CH₃
H
H
H
pic

1-130X
Ir
1
1
Nap2
—
—
H
CH₃
H
H
H
acac

1-130Y
Ir
0
1
Nap2
—
—
H
CH₃
H
H
H
—
—

1-131
Ir
1
1
Nap3
—
—
H
H
H
H
H
pic

1-131X
Ir
1
1
Nap3
—
—
H
H
H
H
H
acac

1-131Y
Ir
0
1
Nap3
—
—
H
H
H
H
H
—
—

1-132
Ir
1
1
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

1-132X
Ir
1
1
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

1-132Y
Ir
0
1
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

1-133
Ir
1
1
Nap3
—
—
CH₃
H
H
H
H
pic

1-133X
Ir
1
1
Nap3
—
—
CH₃
H
H
H
H
acac

1-133Y
Ir
0
1
Nap3
—
—
CH₃
H
H
H
H
—
—

1-134
Ir
1
1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-134X
Ir
1
1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-134Y
Ir
0
1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-135
Ir
1
1
Nap3
—
—
CH3
CH₃
H
H
H
pic

1-135X
Ir
1
1
Nap3
—
—
CH3
CH₃
H
H
H
acac

1-135Y
Ir
0
1
Nap3
—
—
CH3
CH₃
H
H
H
—
—

1-136
Ir
1
1
Nap3
—
—
H
CH₃
H
H
H
pic

1-136X
Ir
1
1
Nap3
—
—
H
CH₃
H
H
H
acac

1-138Y
Ir
0
1
Nap3
—
—
H
CH₃
H
H
H
—
—

1-137
Ir
1
1
TB
—
—
H
H
H
H
H
pic

1-137X
Ir
1
1
TB
—
—
H
H
H
H
H
acac

1-137Y
Ir
0
1
TB
—
—
H
H
H
H
H
—
—

1-138
Ir
1
1
TB
—
—

^tC₄H₉
H
H
H
H
pic

1-138X
Ir
1
1
TB
—
—

^tC₄H₉
H
H
H
H
acac

1-138Y
Ir
0
1
TB
—
—

^tC₄H₉
H
H
H
H
—
—

1-139
Ir
1
1
TB
—
—
CH₃
H
H
H
H
pic

1-139X
Ir
1
1
TB
—
—
CH₃
H
H
H
H
acac

1-139Y
Ir
0
1
TB
—
—
CH₃
H
H
H
H
—
—

1-140
Ir
1
1
TB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-140X
Ir
1
1
TB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-140Y
Ir
0
1
TB
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-141
Ir
1
1
TB
—
—
CH₃
CH₃
H
H
H
pic

1-141X
Ir
1
1
TB
—
—
CH₃
CH₃
H
H
H
acac

1-141Y
Ir
0
1
TB
—
—
CH₃
CH₃
H
H
H
—
—

1-142
Ir
1
1
TB
—
—
H
CH₃
H
H
H
pic

1-142X
Ir
1
1
TB
—
—
H
CH₃
H
H
H
acac

1-142Y
Ir
0
1
TB
—
—
H
CH₃
H
H
H
—
—

1-143
Ir
1
1
TF
—
—
H
H
H
H
H
pic

1-143X
Ir
1
1
TF
—
—
H
H
H
H
H
acac

1-143Y
Ir
0
1
TF
—
—
H
H
H
H
H
—
—

1-144
Ir
1
1
TF
—
—

^tC₄H₉
H
H
H
H
pic

1-144X
Ir
1
1
TF
—
—

^tC₄H₉
H
H
H
H
acac

1-144Y
Ir
0
1
TF
—
—

^tC₄H₉
H
H
H
H
—
—

1-145
Ir
1
1
TF
—
—
CH₃
H
H
H
H
pic

1-145X
Ir
1
1
TF
—
—
CH₃
H
H
H
H
acac

1-145Y
Ir
0
1
TF
—
—
CH₃
H
H
H
H
—
—

1-146
Ir
1
1
TF
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-146X
Ir
1
1
TF
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-146Y
Ir
0
1
TF
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-147
Ir
1
1
TF
—
—
CH₃
CH₃
H
H
H
pic

1-147X
Ir
1
1
TF
—
—
CH₃
CH₃
H
H
H
acac

1-147Y
Ir
0
1
TF
—
—
CH₃
CH₃
H
H
H
—
—

1-148
Ir
1
1
TF
—
—
H
CH₃
H
H
H
pic

1-148X
Ir
1
1
TF
—
—
H
CH₃
H
H
H
acac

1-148Y
Ir
0
1
TF
—
—
H
CH₃
H
H
H
—
—

1-149
Ir
1
1
OB
—
—
H
H
H
H
H
pic

1-149X
Ir
1
1
OB
—
—
H
H
H
H
H
acac

1-149Y
Ir
0
1
OB
—
—
H
H
H
H
H
—
—

1-150
Ir
1
1
OB
—
—

^tC₄H₉
H
H
H
H
pic

1-150X
Ir
1
1
OB
—
—

^tC₄H₉
H
H
H
H
acac

1-150Y
Ir
0
1
OB
—
—

^tC₄H₉
H
H
H
H
—
—

1-151
Ir
1
1
OB
—
—
CH₃
H
H
H
H
pic

1-151X
Ir
1
1
OB
—
—
CH₃
H
H
H
H
acac

1-151Y
Ir
0
1
OB
—
—
CH₃
H
H
H
H
—
—

1-152
Ir
1
1
OB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-152X
Ir
1
1
OB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-152Y
Ir
0
1
OB
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-153
Ir
1
1
OB
—
—
CH₃
CH₃
H
H
H
pic

1-153X
Ir
1
1
OB
—
—
CH₃
CH₃
H
H
H
acac

1-153Y
Ir
0
1
OB
—
—
CH₃
CH₃
H
H
H
—
—

1-154
Ir
1
1
OB
—
—
H
CH₃
H
H
H
pic

1-154X
Ir
1
1
OB
—
—
H
CH₃
H
H
H
acac

1-154Y
Ir
0
1
OB
—
—
H
CH₃
H
H
H
—
—

1-155
Ir
1
1
Fu
—
—
H
H
H
H
H
pic

1-155X
Ir
1
1
Fu
—
—
H
H
H
H
H
acac

1-155Y
Ir
0
1
Fu
—
—
H
H
H
H
H
—
—

1-156
Ir
1
1
Fu
—
—

^tC₄H₉
H
H
H
H
pic

1-156X
Ir
1
1
Fu
—
—

^tC₄H₉
H
H
H
H
acac

1-156Y
Ir
0
1
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

1-157
Ir
1
1
Fu
—
—
CH3
H
H
H
H
pic

1-157X
Ir
1
1
Fu
—
—
CH3
H
H
H
H
acac

1-157Y
Ir
0
1
Fu
—
—
CH3
H
H
H
H
—
—

1-158
Ir
1
1
Fu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-158X
Ir
1
1
Fu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-158Y
Ir
0
1
Fu
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-159
Ir
1
1
Fu
—
—
CH₃
CH₃
H
H
H
pic

1-159X
Ir
1
1
Fu
—
—
CH₃
CH₃
H
H
H
acac

1-159Y
Ir
0
1
Fu
—
—
CH₃
CH₃
H
H
H
—
—

1-160
Ir
1
1
Fu
—
—
H
CH₃
H
H
H
pic

1-160X
Ir
1
1
Fu
—
—
H
CH₃
H
H
H
acac

1-160Y
Ir
0
1
Fu
—
—
H
CH₃
H
H
H
—
—

1-161
Ir
1
1
Fl
—
—
H
H
H
H
H
pic

1-161X
Ir
1
1
Fl
—
—
H
H
H
H
H
acac

1-161Y
Ir
0
1
Fl
—
—
H
H
H
H
H
—
—

1-162
Ir
1
1
Fl
—
—

^tC₄H₉
H
H
H
H
pic

1-162X
Ir
1
1
Fl
—
—

^tC₄H₉
H
H
H
H
acac

1-162Y
Ir
0
1
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

1-163
Ir
1
1
Fl
—
—
CH₃
H
H
H
H
pic

1-163X
Ir
1
1
Fl
—
—
CH₃
H
H
H
H
acac

1-163Y
Ir
0
1
Fl
—
—
CH₃
H
H
H
H
—
—

1-164
Ir
1
1
Fl
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-164X
Ir
1
1
Fl
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-164Y
Ir
0
1
Fl
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-165
Ir
1
1
Fl
—
—
CH₃
CH₃
H
H
H
pic

1-165X
Ir
1
1
Fl
—
—
CH₃
CH₃
H
H
H
acac

1-165Y
Ir
0
1
Fl
—
—
CH₃
CH₃
H
H
H
—
—

1-166
Ir
1
1
Fl
—
—
H
CH₃
H
H
H
pic

1-166X
Ir
1
1
Fl
—
—
H
CH₃
H
H
H
acac

1-166Y
Ir
0
1
Fl
—
—
H
CH₃
H
H
H
—
—

1-167
Ir
1
1
Bz
—
—
H
H
H
H
H
pic

1-167X
Ir
1
1
Bz
—
—
H
H
H
H
H
acac

1-167Y
Ir
0
1
Bz
—
—
H
H
H
H
H
—
—

1-168
Ir
1
1
Bz
—
—

^tC₄H₉
H
H
H
H
pic

1-168X
Ir
1
1
Bz
—
—

^tC₄H₉
H
H
H
H
acac

1-168Y
Ir
0
1
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

1-169
Ir
1
1
Bz
—
—
CH₃
H
H
H
H
pic

1-169X
Ir
1
1
Bz
—
—
CH₃
H
H
H
H
acac

1-169Y
Ir
0
1
Bz
—
—
CH₃
H
H
H
H
—
—

1-170
Ir
1
1
Bz
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-170X
Ir
1
1
Bz
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-170Y
Ir
0
1
Bz
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-171
Ir
1
1
Bz
—
—
CH₃
CH₃
H
H
H
pic

1-171X
Ir
1
1
Bz
—
—
CH₃
CH₃
H
H
H
acac

1-171Y
Ir
0
1
Bz
—
—
CH₃
CH₃
H
H
H
—
—

1-172
Ir
1
1
Bz
—
—
H
CH₃
H
H
H
pic

1-172X
Ir
1
1
Bz
—
—
H
CH₃
H
H
H
acac

1-172Y
Ir
0
1
Bz
—
—
H
CH₃
H
H
H
—
—

1-173
Ir
1
1
Qu
—
—
H
H
H
H
H
pic

1-173X
Ir
1
1
Qu
—
—
H
H
H
H
H
acac

1-173Y
Ir
0
1
Qu
—
—
H
H
H
H
H
—
—

1-174
Ir
1
1
Qu
—
—

^tC₄H₉
H
H
H
H
pic

1-174X
Ir
1
1
Qu
—
—

^tC₄H₉
H
H
H
H
acac

1-174Y
Ir
0
1
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

1-175
Ir
1
1
Qu
—
—
CH₃
H
H
H
H
pic

1-175X
Ir
1
1
Qu
—
—
CH₃
H
H
H
H
acac

1-175Y
Ir
0
1
Qu
—
—
CH₃
H
H
H
H
—
—

1-176
Ir
1
1
Qu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-176X
Ir
1
1
Qu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-176Y
Ir
0
1
Qu
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1-177
Ir
1
1
Qu
—
—
CH₃
CH₃
H
H
H
pic

1-177X
Ir
1
1
Qu
—
—
CH₃
CH₃
H
H
H
acac

1-177y
Ir
0
1
Qu
—
—
CH₃
CH₃
H
H
H
—
—

1-178
Ir
1
1
Qu
—
—
H
CH₃
H
H
H
pic

1-178X
Ir
1
1
Qu
—
—
H
CH₃
H
H
H
acac

1-178y
Ir
0
1
Qu
—
—
H
CH₃
H
H
H
—
—

1-179
Ir
1
1
OL
H

^tC₄H₉
H
H
H
H
H
pic

1-179X
Ir
1
1
OL
H

^tC₄H₉
H
H
H
H
H
acac

1-179Y
Ir
0
1
OL
H

^tC₄H₉
H
H
H
H
H
—
—

1-180
Ir
1
1
OL
H

^tC₄H₉
H
H
H
H
H
pic

1-180X
Ir
1
1
OL
H

^tC₄H₉
H
H
H
H
H
acac

1-180Y
Ir
0
1
OL
H

^tC₄H₉
H
H
H
H
H
—
—

1-181
Ir
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

1-181X
Ir
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

1-181Y
Ir
0
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

1-182
Ir
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

1-182X
Ir
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

1-182Y
Ir
0
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

1-183
Ir
1
1
OL
H
H
H
H
H
H
H
pic

1-183X
Ir
1
1
OL
H
H
H
H
H
H
H
acac

1-183Y
Ir
0
1
OL
H
H
H
H
H
H
H
—
—

1-184
Ir
1
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

1-184X
Ir
1
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

1-184Y
Ir
0
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

1-185
Ir
1
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

1-185X
Ir
1
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

1-185Y
Ir
0
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

1-186
Ir
1
1
OL
—CH₂Ch₂CH₂—
H
H
H
H
H
pic

1-186X
Ir
1
1
OL
—CH₂Ch₂CH₂—
H
H
H
H
H
acac

1-186Y
Ir
0
1
OL
—CH₂Ch₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 9

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2-119
Ir
1
2
Nap1
—
—
H
H
H
H
H
pic

2-119X
Ir
1
2
Nap1
—
—
H
H
H
H
H
acac

2-119Y
Ir
0
2
Nap1
—
—
H
H
H
H
H
—
—

2-120
Ir
1
2
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

2-120X
Ir
1
2
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

2-120Y
Ir
0
2
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

2-121
Ir
1
2
Nap1
—
—
CH₃
H
H
H
H
pic

2-121X
Ir
1
2
Nap1
—
—
CH₃
H
H
H
H
acac

2-121Y
Ir
0
2
Nap1
—
—
CH₃
H
H
H
H
—
—

2-122
Ir
1
2
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-122X
Ir
1
2
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-122Y
Ir
0
2
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-123
Ir
1
2
Nap1
—
—
CH₃
H
H
CH₃
H
pic

2-123X
Ir
1
2
Nap1
—
—
CH₃
H
H
CH₃
H
acac

2-123Y
Ir
0
2
Nap1
—
—
CH₃
H
H
CH₃
H
—
—

2-124
Ir
1
2
Nap1
—
—
H
H
H
CH₃
H
pic

2-124X
Ir
1
2
Nap1
—
—
H
H
H
CH₃
H
acac

2-124Y
Ir
0
2
Nap1
—
—
H
H
H
CH₃
H
—
—

2-125
Ir
1
2
Nap2
—
—
H
H
H
H
H
pic

2-125X
Ir
1
2
Nap2
—
—
H
H
H
H
H
acac

2-125Y
Ir
0
2
Nap2
—
—
H
H
H
H
H
—
—

2-126
Ir
1
2
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

2-126X
Ir
1
2
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

2-126Y
Ir
0
2
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

2-127
Ir
1
2
Nap2
—
—
CH₃
H
H
H
H
pic

2-127X
Ir
1
2
Nap2
—
—
CH₃
H
H
H
H
acac

2-127Y
Ir
0
2
Nap2
—
—
CH₃
H
H
H
H
—
—

2-128
Ir
1
2
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-128X
Ir
1
2
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-128Y
Ir
0
2
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-129
Ir
1
2
Nap2
—
—
CH₃
H
H
CH₃
H
pic

2-129X
Ir
1
2
Nap2
—
—
CH₃
H
H
CH₃
H
acac

2-129Y
Ir
0
2
Nap2
—
—
CH₃
H
H
CH₃
H
—
—

2-130
Ir
1
2
Nap2
—
—
H
H
H
CH₃
H
pic

2-130X
Ir
1
2
Nap2
—
—
H
H
H
CH₃
H
acac

2-130Y
Ir
0
2
Nap2
—
—
H
H
H
CH₃
H
—
—

2-131
Ir
1
2
Nap3
—
—
H
H
H
H
H
pic

2-131X
Ir
1
2
Nap3
—
—
H
H
H
H
H
acac

2-131Y
Ir
0
2
Nap3
—
—
H
H
H
H
H
—
—

2-132
Ir
1
2
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

2-132X
Ir
1
2
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

2-132Y
Ir
0
2
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

2-133
Ir
1
2
Nap3
—
—
CH₃
H
H
H
H
pic

2-133X
Ir
1
2
Nap3
—
—
CH₃
H
H
H
H
acac

2-133Y
Ir
0
2
Nap3
—
—
CH₃
H
H
H
H
—
—

2-134
Ir
1
2
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-134X
Ir
1
2
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-134Y
Ir
0
2
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-135
Ir
1
2
Nap3
—
—
CH₃
H
H
CH₃
H
pic

2-135X
Ir
1
2
Nap3
—
—
CH₃
H
H
CH₃
H
acac

2-135Y
Ir
0
2
Nap3
—
—
CH₃
H
H
CH₃
H
—
—

2-136
Ir
1
2
Nap3
—
—
H
H
H
CH₃
H
pic

2-136X
Ir
1
2
Nap3
—
—
H
H
H
CH₃
H
acac

2-136Y
Ir
0
2
Nap3
—
—
H
H
H
CH₃
H
—
—

2-137
Ir
1
2
TB
—
—
H
H
H
H
H
pic

2-137X
Ir
1
2
TB
—
—
H
H
H
H
H
acac

2-137Y
Ir
0
2
TB
—
—
H
H
H
H
H
—
—

2-138
Ir
1
2
TB
—
—

^tC₄H₉
H
H
H
H
pic

2-138X
Ir
1
2
TB
—
—

^tC₄H₉
H
H
H
H
acac

2-138Y
Ir
0
2
TB
—
—

^tC₄H₉
H
H
H
H
—
—

2-139
Ir
1
2
TB
—
—
CH₃
H
H
H
H
pic

2-139X
Ir
1
2
TB
—
—
CH₃
H
H
H
H
acac

2-139Y
Ir
0
2
TB
—
—
CH₃
H
H
H
H
—
—

2-140
Ir
1
2
TB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-140X
Ir
1
2
TB
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-140Y
Ir
0
2
TB
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-141
Ir
1
2
TB
—
—
CH₃
H
H
CH₃
H
pic

2-141X
Ir
1
2
TB
—
—
CH₃
H
H
CH₃
H
acac

2-141Y
Ir
0
2
TB
—
—
CH₃
H
H
CH₃
H
—
—

2-142
Ir
1
2
TB
—
—
H
H
H
CH₃
H
pic

2-142X
Ir
1
2
TB
—
—
H
H
H
CH₃
H
acac

2-142Y
Ir
0
2
TB
—
—
H
H
H
CH₃
H
—
—

2-143
Ir
1
2
TF
—
—
H
H
H
H
H
pic

2-143X
Ir
1
2
TF
—
—
H
H
H
H
H
acac

2-143Y
Ir
0
2
TF
—
—
H
H
H
H
H
—
—

2-144
Ir
1
2
TF
—
—

^tC₄H₉
H
H
H
H
pic

2-144X
Ir
1
2
TF
—
—

^tC₄H₉
H
H
H
H
acac

2-144Y
Ir
0
2
TF
—
—

^tC₄H₉
H
H
H
H
—
—

2-145
Ir
1
2
TF
—
—
CH₃
H
H
H
H
pic

2-145X
Ir
1
2
TF
—
—
CH₃
H
H
H
H
acac

2-145Y
Ir
0
2
TF
—
—
CH₃
H
H
H
H
—
—

2-146
Ir
1
2
TF
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-146X
Ir
1
2
TF
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-146Y
Ir
0
2
TF
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-147
Ir
1
2
TF
—
—
CH₃
H
H
CH₃
H
pic

2-147X
Ir
1
2
TF
—
—
CH₃
H
H
CH₃
H
acac

2-147Y
Ir
0
2
TF
—
—
CH₃
H
H
CH₃
H
—
—

2-148
Ir
1
2
TF
—
—
H
H
H
CH₃
H
pic

2-148X
Ir
1
2
TF
—
—
H
H
H
CH₃
H
acac

2-148Y
Ir
0
2
TF
—
—
H
H
H
CH₃
H
—
—

2-149
Ir
1
2
OB
—
—
H
H
H
H
H
pic

2-149X
Ir
1
2
OB
—
—
H
H
H
H
H
acac

2-149Y
Ir
0
2
OB
—
—
H
H
H
H
H
—
—

2-150
Ir
1
2
OB
—
—

^tC₄H₉
H
H
H
H
pic

2-150X
Ir
1
2
OB
—
—

^tC₄H₉
H
H
H
H
acac

2-150Y
Ir
0
2
OB
—
—

^tC₄H₉
H
H
H
H

2-151
Ir
1
2
OB
—
—
CH₃
H
H
H
H
pic

2-151X
Ir
1
2
OB
—
—
CH₃
H
H
H
H
acac

2-151Y
Ir
0
2
OB
—
—
CH₃
H
H
H
H
—
—

2-152
Ir
1
2
OB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-152X
Ir
1
2
OB
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-152Y
Ir
0
2
OB
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-153
Ir
1
2
OB
—
—
CH₃
H
H
CH₃
H
pic

2-153X
Ir
1
2
OB
—
—
CH₃
H
H
CH₃
H
acac

2-153Y
Ir
0
2
OB
—
—
CH₃
H
H
CH₃
H
—
—

2-154
Ir
1
2
OB
—
—
H
H
H
CH₃
H
pic

2-154X
Ir
1
2
OB
—
—
H
H
H
CH
H
acac

2-154Y
Ir
0
2
OB
—
—
H
H
H
CH₃
H
—
—

2-155
Ir
1
2
Fu
—
—
H
H
H
H
H
pic

2-155X
Ir
1
2
Fu
—
—
H
H
H
H
H
acac

2-155Y
Ir
0
2
Fu
—
—
H
H
H
H
H
—
—

2-156
Ir
1
2
Fu
—
—

^tC₄H₉
H
H
H
H
pic

2-156X
Ir
1
2
Fu
—
—

^tC₄H₉
H
H
H
H
acac

2-156Y
Ir
0
2
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

2-157
Ir
1
2
Fu
—
—
CH₃
H
H
H
H
pic

2-157X
Ir
1
2
Fu
—
—
CH₃
H
H
H
H
acac

2-157Y
Ir
0
2
Fu
—
—
CH₃
H
H
H
H
—
—

2-158
Ir
1
2
Fu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-158X
Ir
1
2
Fu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-158Y
Ir
0
2
Fu
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-159
Ir
1
2
Fu
—
—
CH₃
H
H
CH₃
H
pic

2-159X
Ir
1
2
Fu
—
—
CH₃
H
H
CH₃
H
acac

2-159Y
Ir
0
2
Fu
—
—
CH₃
H
H
CH₃
H
—
—

2-160
Ir
1
2
Fu
—
—
H
H
H
CH₃
H
pic

2-160X
Ir
1
2
Fu
—
—
H
H
H
CH₃
H
acac

2-160Y
Ir
0
2
Fu
—
—
H
H
H
CH₃
H
—
—

2-161
Ir
1
2
Fl
—
—
H
H
H
H
H
pic

2-161X
Ir
1
2
Fl
—
—
H
H
H
H
H
acac

2-161Y
Ir
0
2
Fl
—
—
H
H
H
H
H
—
—

2-162
Ir
1
2
Fl
—
—

^tC₄H₉
H
H
H
H
pic

2-162X
Ir
1
2
Fl
—
—

^tC₄H₉
H
H
H
H
acac

2-162Y
Ir
0
2
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

2-163
Ir
1
2
F1
—
—
CH₃
H
H
H
H
pic

2-163X
Ir
1
2
Fl
—
—
CH₃
H
H
H
H
acac

2-163Y
Ir
0
2
Fl
—
—
CH₃
H
H
H
H
—
—

2-164
Ir
1
2
Fl
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-164X
Ir
1
2
Fl
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-164Y
Ir
0
2
Fl
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-165
Ir
1
2
Fl
—
—
CH₃
H
H
CH₃
H
pic

2-165X
Ir
1
2
Fl
—
—
CH₃
H
H
CH₃
H
acac

2-165Y
Ir
0
2
Fl
—
—
CH₃
H
H
CH₃
H
—
—

2-166
Ir
1
2
Fl
—
—
H
H
H
CH₃
H
pic

2-166X
Ir
1
2
Fl
—
—
H
H
H
CH₃
H
acac

2-166Y
Ir
0
2
Fl
—
—
H
H
H
CH₃
H
—
—

2-167
Ir
1
2
Bz
—
—
H
H
H
H
H
pic

2-167X
Ir
1
2
Bz
—
—
H
H
H
H
H
acac

2-167Y
Ir
0
2
Bz
—
—
H
H
H
H
H
—
—

2-168
Ir
1
2
Bz
—
—

^tC₄H₉
H
H
H
H
pic

2-168X
Ir
1
2
Bz
—
—

^tC₄H₉
H
H
H
H
acac

2-168Y
Ir
0
2
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

2-169
Ir
1
2
Bz
—
—
CH₃
H
H
H
H
pic

2-169X
Ir
1
2
Bz
—
—
CH₃
H
H
H
H
acac

2-169Y
Ir
0
2
Bz
—
—
CH₃
H
H
H
H
—
—

2-170
Ir
1
2
Bz
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-170X
Ir
1
2
Bz
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-170Y
Ir
0
2
Bz
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-171
Ir
1
2
Bz
—
—
CH₃
H
H
CH₃
H
pic

2-171X
Ir
1
2
Bz
—
—
CH₃
H
H
CH₃
H
acac

2-171Y
Ir
0
2
Bz
—
—
CH₃
H
H
CH₃
H
—
—

2-172
Ir
1
2
Bz
—
—
H
H
H
CH₃
H
pic

2-172X
Ir
1
2
Bz
—
—
H
H
H
CH₃
H
acac

2-172Y
Ir
0
2
Bz
—
—
H
H
H
CH₃
H
—
—

2-173
Ir
1
2
Qu
—
—
H
H
H
H
H
pic

2-173X
Ir
1
2
Qu
—
—
H
H
H
H
H
acac

2-173Y
Ir
0
2
Qu
—
—
H
H
H
H
H
—
—

2-174
Ir
1
2
Qu
—
—

^tC₄H₉
H
H
H
H
pic

2-174X
Ir
1
2
Qu
—
—

^tC₄H₉
H
H
H
H
acac

2-174Y
Ir
0
2
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

2-175
Ir
1
2
Qu
—
—
CH₃
H
H
H
H
pic

2-175X
Ir
1
2
Qu
—
—
CH₃
H
H
H
H
acac

2-175Y
Ir
0
2
Qu
—
—
CH₃
H
H
H
H
—
—

2-176
Ir
1
2
Qu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-176X
Ir
1
2
Qu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-176Y
Ir
0
2
Qu
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2-177
Ir
1
2
Qu
—
—
CH₃
H
H
CH₃
H
pic

2-177X
Ir
1
2
Qu
—
—
CH₃
H
H
CH₃
H
acac

2-177Y
Ir
0
2
Qu
—
—
CH₃
H
H
CH₃
H
—
—

2-178
Ir
1
2
Qu
—
—
H
H
H
CH₃
H
pic

2-178X
Ir
1
2
Qu
—
—
H
H
H
CH₃
H
acac

2-178Y
Ir
0
2
Qu
—
—
H
H
H
CH₃
H
—
—

2-179
Ir
1
2
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

2-179X
Ir
1
2
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

2-179Y
Ir
0
2
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

2-180
Ir
1
2
OL
H

^tC₄H₉
H
H
H
H
H
pic

2-180X
Ir
1
2
OL
H

^tC₄H₉
H
H
H
H
H
acac

2-180Y
Ir
0
2
OL
H

^tC₄H₉
H
H
H
H
H
—
—

2-181
Ir
1
2
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

2-181X
Ir
1
2
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

2-181Y
Ir
0
2
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

2-182
Ir
1
2
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

2-182X
Ir
1
2
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

2-182Y
Ir
0
2
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

2-183
Ir
1
2
OL
H
H
H
H
H
H
H
pic

2-183X
Ir
1
2
OL
H
H
H
H
H
H
H
acac

2-183Y
Ir
0
2
OL
H
H
H
H
H
H
H
—
—

2-184
Ir
1
2
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

2-184X
Ir
1
2
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

2-184Y
Ir
0
2
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

2-185
Ir
1
2
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

2-185X
Ir
1
2
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

2-185Y
Ir
0
2
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

2-186
Ir
1
2
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

2-188X
Ir
1
2
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

2-186Y
Ir
0
2
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 10

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3-117
Ir
1
3
Nap1
—
—
H
H
H
H
H
pic

3-117X
Ir
1
3
Nap 1
—
—
H
H
H
H
H
acac

3-117Y
Ir
0
3
Nap1
—
—
H
H
H
H
H
—
—

3-118
Ir
1
3
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

3-118X
Ir
1
3
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

3-118Y
Ir
0
3
Nap 1
—
—

^tC₄H₉
H
H
H
H
—
—

3-119
Ir
1
3
Nap1
—
—
CH₃
H
H
H
H
pic

3-119X
Ir
1
3
Nap1
—
—
CH₃
H
H
H
H
acac

3-119Y
Ir
0
3
Nap1
—
—
CH₃
H
H
H
H
—
—

3-120
Ir
1
3
Nap2
—
—
H
H
H
H
H
pic

3-120X
Ir
1
3
Nap2
—
—
H
H
H
H
H
acac

3-120Y
Ir
0
3
Nap2
—
—
H
H
H
H
H
—
—

3-121
Ir
1
3
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

3-121X
Ir
1
3
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

3-121Y
Ir
0
3
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

3-122
Ir
1
3
Nap2
—
—
CH₃
H
H
H
H
pic

3-122X
Ir
1
3
Nap2
—
—
CH₃
H
H
H
H
acac

3-122Y
Ir
0
3
Nap2
—
—
CH₃
H
H
H
H
—
—

3-123
Ir
1
3
Nap3
—
—
H
H
H
H
H
pic

3-123X
Ir
1
3
Nap3
—
—
H
H
H
H
H
acac

3-123Y
Ir
0
3
Nap3
—
—
H
H
H
H
H
—
—

3-124
Ir
1
3
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

3-124X
Ir
1
3
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

3-124Y
Ir
0
3
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

3-125
Ir
1
3
Nap3
—
—
CH₃
H
H
H
H
pic

3-125X
Ir
1
3
Nap3
—
—
CH₃
H
H
H
H
acac

3-125Y
Ir
0
3
Nap3
—
—
CH₃
H
H
H
H
—
—

3-126
Ir
1
3
TB
—
—
H
H
H
H
H
pic

3-126X
Ir
1
3
TB
—
—
H
H
H
H
H
acac

3-126Y
Ir
0
3
TB
—
—
H
H
H
H
H
—
—

3-127
Ir
1
3
TB
—
—

^tC₄H₉
H
H
H
H
pic

3-127X
Ir
1
3
TB
—
—

^tC₄H₉
H
H
H
H
acac

3-127Y
Ir
0
3
TB
—
—

^tC₄H₉
H
H
H
H
—
—

3-128
Ir
1
3
TB
—
—
CH₃
H
H
H
H
pic

3-128X
Ir
1
3
TB
—
—
CH₃
H
H
H
H
acac

3-128Y
Ir
0
3
TB
—
—
CH₃
H
H
H
H
—
—

3-129
Ir
1
3
TF
—
—
H
H
H
H
H
pic

3-129X
Ir
1
3
TF
—
—
H
H
H
H
H
acac

3-129Y
Ir
0
3
TF
—
—
H
H
H
H
H
—
—

3-130
Ir
1
3
TF
—
—

^tC₄H₉
H
H
H
H
pic

3-130X
Ir
1
3
TF
—
—

^tC₄H₉
H
H
H
H
acac

3-130Y
Ir
0
3
TF
—
—

^tC₄H₉
H
H
H
H
—
—

3-131
Ir
1
3
TF
—
—
CH₃
H
H
H
H
pic

3-131X
Ir
1
3
TF
—
—
CH₃
H
H
H
H
acac

3-131Y
Ir
0
3
TF
—
—
CH₃
H
H
H
H
—
—

3-132
Ir
1
3
OB
—
—
H
H
H
H
H
pic

3-132X
Ir
1
3
OB
—
—
H
H
H
H
H
acac

3-132Y
Ir
0
3
OB
—
—
H
H
H
H
H
—
—

3-133
Ir
1
3
OB
—
—

^tC₄H₉
H
H
H
H
pic

3-133X
Ir
1
3
OB
—
—

^tC₄H₉
H
H
H
H
acac

3-133Y
Ir
0
3
OB
—
—

^tC₄H₉
H
H
H
H
—
—

3-134
Ir
1
3
OB
—
—
CH₃
H
H
H
H
pic

3-134X
Ir
1
3
OB
—
—
CH₃
H
H
H
H
acac

3-134Y
Ir
0
3
OB
—
—
CH₃
H
H
H
H
—
—

3-135
Ir
1
3
Fu
—
—
H
H
H
H
H
pic

3-135X
Ir
1
3
Fu
—
—
H
H
H
H
H
acac

3-135Y
Ir
0
3
Fu
—
—
H
H
H
H
H
—
—

3-136
Ir
1
3
Fu
—
—

^tC₄H₉
H
H
H
H
pic

3-136X
Ir
1
3
Fu
—
—

^tC₄H₉
H
H
H
H
acac

3-136Y
Ir
0
3
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

3-137
Ir
1
3
Fu
—
—
CH₃
H
H
H
H
pic

3-137X
Ir
1
3
Fu
—
—
CH₃
H
H
H
H
acac

3-137Y
Ir
0
3
Fu
—
—
CH₃
H
H
H
H
—
—

3-138
Ir
1
3
Fl
—
—
H
H
H
H
H
pic

3-138X
Ir
1
3
Fl
—
—
H
H
H
H
H
acac

3-138Y
Ir
o
3
Fl
—
—
H
H
H
H
H
—
—

3-139
Ir
1
3
Fl
—
—

^tC₄H₉
H
H
H
H
pic

3-139X
Ir
1
3
Fl
—
—

^tC₄H₉
H
H
H
H
acac

3-139Y
Ir
0
3
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

3-140
Ir
1
3
Fl
—
—
CH₃
H
H
H
H
pic

3-140X
Ir
1
3
Fl
—
—
CH₃
H
H
H
H
acac

3-140Y
Ir
0
3
Fl
—
—
CH₃
H
H
H
H
—
—

3-141
Ir
1
3
Bz
—
—
H
H
H
H
H
pic

3-141X
Ir
1
3
Bz
—
—
H
H
H
H
H
acac

3-141Y
Ir
0
3
Bz
—
—
H
H
H
H
H
—
—

3-142
Ir
1
3
Bz
—
—

^tC₄H₉
H
H
H
H
pic

3-142X
Ir
1
3
Bz
—
—

^tC₄H₉
H
H
H
H
acac

3-142Y
Ir
0
3
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

3-143
Ir
1
3
Bz
—
—
CH₃
H
H
H
H
pic

3-143X
Ir
1
3
Bz
—
—
CH₃
H
H
H
H
acac

3-143Y
Ir
0
3
Bz
—
—
CH₃
H
H
H
H
—
—

3-144
Ir
1
3
Qu
—
—
H
H
H
H
H
pic

3-144X
Ir
1
3
Qu
—
—
H
H
H
H
H
acac

3-144Y
Ir
0
3
Qu
—
—
H
H
H
H
H
—
—

3-145
Ir
1
3
Qu
—
—

^tC₄H₉
H
H
H
H
pic

3-145X
Ir
1
3
Qu
—
—

^tC₄H₉
H
H
H
H
acac

3-145Y
Ir
0
3
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

3-146
Ir
1
3
Qu
—
—
CH₃
H
H
H
H
pic

3-146X
Ir
1
3
Qu
—
—
CH₃
H
H
H
H
acac

3-146Y
Ir
0
3
Qu
—
—
CH₃
H
H
H
H
—
—

3-147
Ir
1
3
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

3-147X
Ir
1
3
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

3-147Y
Ir
0
3
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

3-148
Ir
1
3
OL
H

^tC₄H₉
H
H
H
H
H
pic

3-148X
Ir
1
3
OL
H

^tC₄H₉
H
H
H
H
H
acac

3-148Y
Ir
0
3
OL
H

^tC₄H₉
H
H
H
H
H
—
—

3-149
Ir
1
3
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

3-149X
Ir
1
3
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

3-149Y
Ir
0
3
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

3-150
Ir
1
3
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

3-150X
Ir
1
3
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

3-150Y
Ir
0
3
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

3-151
Ir
1
3
OL
H
H
H
H
H
H
H
pic

3-151X
Ir
1
3
OL
H
H
H
H
H
H
H
acac

3-151Y
Ir
0
3
OL
H
H
H
H
H
H
H
—
—

3-152
Ir
1
3
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

3-152X
Ir
1
3
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

3-152Y
Ir
0
3
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

3-153
Ir
1
3
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

3-153X
Ir
1
3
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

3-153Y
Ir
0
3
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

3-154
Ir
1
3
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

3-154X
Ir
1
3
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

3-154Y
Ir
0
3
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 11

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4-138
Ir
1
4
Nap1
—
—
CH₃
H
H
H
H
pic

4-138X
Ir
1
4
Nap1
—
—
CH₃
H
H
H
H
acac

4-138Y
Ir
0
4
Nap1
—
—
CH₃
H
H
H
H
—
—

4-139
Ir
1
4
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

4-139X
Ir
1
4
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

4-139Y
Ir
0
4
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

4-140
Ir
1
4
Nap2
—
—
CH₃
H
H
H
H
pic

4-140X
Ir
1
4
Nap2
—
—
CH₃
H
H
H
H
acac

4-140Y
Ir
0
4
Nap2
—
—
CH₃
H
H
H
H
—
—

4-141
Ir
1
4
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

4-141X
Ir
1
4
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

4-141Y
Ir
0
4
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

4-142
Ir
1
4
Nap3
—
—
CH₃
H
H
H
H
pic

4-142X
Ir
1
4
Nap3
—
—
CH₃
H
H
H
H
acac

4-142Y
Ir
0
4
Nap3
—
—
CH₃
H
H
H
H
—
—

4-143
Ir
1
4
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

4-143X
Ir
1
4
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

4-143Y
Ir
0
4
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

4-144
Ir
1
4
TB
—
—
CH₃
H
H
H
H
pic

4-144X
Ir
1
4
TB
—
—
CH₃
H
H
H
H
acac

4-144Y
Ir
0
4
TB
—
—
CH₃
H
H
H
H
—
—

4-145
Ir
1
4
TB
—
—

^tC₄H₉
H
H
H
H
pic

4-145X
Ir
1
4
TB
—
—

^tC₄H₉
H
H
H
H
acac

4-145Y
Ir
0
4
TB
—
—

^tC₄H₉
H
H
H
H
—
—

4-146
Ir
1
4
TF
—
—
CH₃
H
H
H
H
pic

4-146X
Ir
1
4
TF
—
—
CH₃
H
H
H
H
acac

4-146Y
Ir
o
4
TF
—
—
CH₃
H
H
H
H
—
—

4-147
Ir
1
4
TF
—
—

^tC₄H₉
H
H
H
H
pic

4-147X
Ir
1
4
TF
—
—

^tC₄H₉
H
H
H
H
acac

4-147Y
Ir
0
4
TF
—
—

^tC₄H₉
H
H
H
H
—
—

4-148
Ir
1
4
OB
—
—
CH₃
H
H
H
H
pic

4-148X
Ir
1
4
OB
—
—
CH₃
H
H
H
H
acac

4-148Y
Ir
0
4
OB
—
—
CH₃
H
H
H
H
—
—

4-149
Ir
1
4
OB
—
—

^tC₄H₉
H
H
H
H
pic

4-149X
Ir
1
4
OB
—
—

^tC₄H₉
H
H
H
H
acac

4-149Y
Ir
0
4
OB
—
—

^tC₄H₉
H
H
H
H
—
—

4-150
Ir
1
4
Fu
—
—
CH₃
H
H
H
H
pic

4-150X
Ir
1
4
Fu
—
—
CH₃
H
H
H
H
acac

4-150Y
Ir
0
4
Fu
—
—
CH₃
H
H
H
H
—
—

4-151
Ir
1
4
Fu
—
—

^tC₄H₉
H
H
H
H
pic

4-151X
Ir
1
4
Fu
—
—

^tC₄H₉
H
H
H
H
acac

4-151Y
Ir
0
4
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

4-152
Ir
1
4
Fl
—
—
CH₃
H
H
H
H
pic

4-152X
Ir
1
4
Fl
—
—
CH₃
H
H
H
H
acac

4-152Y
Ir
0
4
Fl
—
—
CH₃
H
H
H
H
—
—

4-153
Ir
1
4
Fl
—
—

^tC₄H₉
H
H
H
H
pic

4-153X
Ir
1
4
Fl
—
—

^tC₄H₉
H
H
H
H
acac

4-153Y
Ir
0
4
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

4-154
Ir
1
4
Bz
—
—
CH₃
H
H
H
H
pic

4-154X
Ir
1
4
Bz
—
—
CH₃
H
H
H
H
acac

4-154Y
Ir
0
4
Bz
—
—
CH₃
H
H
H
H
—
—

4-155
Ir
1
4
Bz
—
—

^tC₄H₉
H
H
H
H
pic

4-155X
Ir
1
4
Bz
—
—

^tC₄H₉
H
H
H
H
acac

4-155Y
Ir
0
4
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

4-156
Ir
1
4
Qu
—
—
CH₃
H
H
H
H
pic

4-156X
Ir
1
4
Qu
—
—
CH₃
H
H
H
H
acac

4-156Y
Ir
0
4
Qu
—
—
CH₃
H
H
H
H
—
—

4-157
Ir
1
4
Qu
—
—

^tC₄H₉
H
H
H
H
pic

4-157X
Ir
1
4
Qu
—
—

^tC₄H₉
H
H
H
H
acac

4-157Y
Ir
0
4
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

4-158
Ir
1
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-158X
Ir
1
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-158Y
Ir
0
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-159
Ir
1
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-159X
Ir
1
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4-159Y
Ir
0
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4-160
Ir
1
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-160X
Ir
1
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-160Y
Ir
0
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-161
Ir
1
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-161X
Ir
1
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4-161Y
Ir
0
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4-162
Ir
1
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
pic

4-162X
Ir
1
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
acac

4-162Y
Ir
0
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
—
—

4-163
Ir
1
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
pic

4-163X
Ir
1
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
acac

4-163Y
Ir
0
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
—
—

4-164
Ir
1
4
OL
H
H
CH₃
H
H
H
H
pic

4-164X
Ir
1
4
OL
H
H
CH₃
H
H
H
H
acac

4-164Y
Ir
0
4
OL
H
H
CH₃
H
H
H
H
—
—

4-165
Ir
1
4
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
pic

4-165X
Ir
1
4
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
acac

4-165Y
Ir
0
4
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
—
—

4-166
Ir
1
4
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
pic

4-168X
Ir
1
4
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
acac

4-166Y
Ir
0
4
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
—
—

embedded image

TABLE 12

No.
M
n

BSS
SS G

T¹
T²

T⁵
T⁶
T⁷
L¹
L²

5-140
Ir
1

5
Nap1

—
—

H
CH₃
H
pic

5-140X
Ir
1

5
Nap1

—
—

H
CH₃
H
acac

5-140Y
Ir
0

5
Nap1

—
—

H
CH₃
H
—
—

5-141
Ir
1

5
Nap1

—
—

H

^tC₄H₉
H
pic

5-141X
Ir
1

5
Nap1

—
—

H

^tC₄H₉
H
acac

5-141Y
Ir
0

5
Nap1

—
—

H

^tC₄H₉
H
—
—

5-142
Ir
1

5
Nap1

—
—

^tC₄H₉
CH₃
H
pic

5-142X
Ir
1

5
Nap1

—
—

^tC₄H₉
CH₃
H
acac

5-142Y
Ir
0

5
Nap 1

—
—

^tC₄H₉
CH₃
H
—
—

5-143
Ir
1

5
Nap1

—
—

^tC₄H₉
CH₃
H
pic

5-143X
Ir
1

5
Nap1

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-143Y
Ir
0

5
Nap1

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-144
Ir
1

5
Nap1

—
—

CH₃
CH₃
H
pic

5-144X
Ir
1

5
Nap1

—
—

CH₃
CH₃
H
acac

5-144Y
Ir
0

5
Nap1

—
—

CH₃
CH₃
H
—
—

5-145
Ir
1

5
Nap1

—
—

CH₃

^tC₄H₉
H
pic

5-145X
Ir
1

5
Nap1

—
—

CH₃

^tC₄H₉
H
acac

5-145Y
Ir
0

5
Nap1

—
—

CH₃

^tC₄H₉
H
—
—

5-146
Ir
1

5
Nap2

—
—

H
CH₃
H
pic

5-146X
Ir
1

5
Nap2

—
—

H
CH₃
H
acac

5-146Y
Ir
0

5
Nap2

—
—

H
CH₃
H
—
—

5-147
Ir
1

5
Nap2

—
—

H

^tC₄H₉
H
pic

5-147X
Ir
1

5
Nap2

—
—

H

^tC₄H₉
H
acac

5-147Y
Ir
0

5
Nap2

—
—

H

^tC₄H₉
H
—
—

5-148
Ir
1

5
Nap2

—
—

^tC₄H₉
CH₃
H
pic

5-146X
Ir
1

5
Nap2

—
—

^tC₄H₉
CH₃
H
acac

5-148Y
Ir
0

5
Nap2

—
—

^tC₄H₉
CH₃
H
—
—

5-149
Ir
1

5
Nap2

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-149X
Ir
1

5
Nap2

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-149Y
Ir
0

5
Nap2

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-150
Ir
1

5
Nap2

—
—

CH₃
CH₃
H
pic

5-150X
Ir
1

5
Nap2

—
—

CH₃
CH₃
H
acac

5-150Y
Ir
0

5
Nap2

—
—

CH₃
CH₃
H
—
—

5-151
Ir
1

5
Nap2

—
—

CH₃

^tC₄H₉
H
pic

5-151X
Ir
1

5
Nap2

—
—

CH₃

^tC₄H₉
H
acac

5-151Y
Ir
0

5
Nap2

—
—

CH₃

^tC₄H₉
H
—
—

5-152
Ir
1

5
Nap3

—
—

H
CH₃
H
pic

5-152X
Ir
1

5
Nap3

—
—

H
CH₃
H
acac

5-152Y
Ir
0

5
Nap3

—
—

H
CH₃
H
—
—

5-153
Ir
1

5
Nap3

—
—

H

^tC₄H₉
H
pic

5-153X
Ir
1

5
Nap3

—
—

H

^tC₄H₉
H
acac

5-153Y
Ir
0

5
Nap3

—
—

H

^tC₄H₉
H
—
—

5-154
Ir
1

5
Nap3

—
—

^tC₄H₉
CH₃
H
pic

5-154X
Ir
1

5
Nap3

—
—

^tC₄H₉
CH₃
H
acac

5-154Y
Ir
0

5
Nap3

—
—

^tC₄H₉
CH₃
H
—
—

5-155
Ir
1

5
Nap3

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-155X
Ir
1

5
Nap3

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-155Y
Ir
0

5
Nap3

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-156
Ir
1

5
Nap3

—
—

CH₃
CH₃
H
pic

5-156X
Ir
1

5
Nap3

—
—

CH₃
CH₃
H
acac

5-156Y
Ir
0

5
Nap3

—
—

CH₃
CH₃
H
—
—

5-157
Ir
1

5
Nap3

—
—

CH₃

^tC₄H₉
H
pic

5-157X
Ir
1

5
Nap3

—
—

CH₃

^tC₄H₉
H
acac

5-157Y
Ir
0

5
Nap3

—
—

CH₃

^tC₄H₉
H
—
—

5-158
Ir
1

5
TB

—
—

H
CH₃
H
pic

5-158X
Ir
1

5
TB

—
—

H
CH₃
H
acac

5-158Y
Ir
0

5
TB

—
—

H
CH₃
H
—
—

5-159
Ir
1

5
TB

—
—

H

^tC₄H₉
H
pic

5-159X
Ir
1

5
TB

—
—

H

^tC₄H₉
H
acac

5-159Y
Ir
0

5
TB

—
—

H

^tC₄H₉
H
—
—

5-160
Ir
1

5
TB

—
—

^tC₄H₉
CH₃
H
pic

5-160X
Ir
1

5
TB

—
—

^tC₄H₉
CH₃
H
acac

5-160Y
Ir
0

5
TB

—
—

^tC₄H₉
CH₃
H
—
—

5-161
Ir
1

5
TB

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-161X
Ir
1

5
TB

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-161Y
Ir
0

5
TB

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-162
Ir
1

5
TB

—
—

CH₃
CH₃
H
pic

5-162X
Ir
1

5
TB

—
—

CH₃
CH₃
H
acac

5-162Y
Ir
0

5
TB

—
—

CH₃
CH₃
H
—
—

5-163
Ir
1

5
TB

—
—

CH₃

^tC₄H₉
H
pic

5-163X
Ir
1

5
TB

—
—

CH₃

^tC₄H₉
H
acac

5-163Y
Ir
0

5
TB

—
—

CH₃

^tC₄H₉
H
—
—

5-164
Ir
1

5
TF

—
—

H
CH₃
H
pic

5-164X
Ir
1

5
TF

—
—

H
CH₃
H
acac

5-164Y
Ir
0

5
TF

—
—

H
CH₃
H
—
—

5-165
Ir
1

5
TF

—
—

H

^tC₄H₉
H
pic

5-165X
Ir
1

5
TF

—
—

H

^tC₄H₉
H
acac

5-165Y
Ir
0

5
TF

—
—

H

^tC₄H₉
H
—
—

5-166
Ir
1

5
TF

—
—

^tC₄H₉
CH₃
H
pic

5-166X
Ir
1

5
TF

—
—

^tC₄H₉
CH₃
H
acac

5-166Y
Ir
0

5
TF

—
—

^tC₄H₉
CH₃
H
—
—

5-167
Ir
1

5
TF

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-167X
Ir
1

5
TF

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-167Y
Ir
0

6
TF

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-168
Ir
1

5
TF

—
—

CH₃
CH₃
H
pic

5-168X
Ir
1

5
TF

—
—

CH₃
CH₃
H
acac

5-168Y
Ir
0

5
TF

—
—

CH₃
CH₃
H
—
—

5-169
Ir
1

5
TF

—
—

CH₃

^tC₄H₉
H
pic

5-169X
Ir
1

5
TF

—
—

CH₃

^tC₄H₉
H
acac

5-169Y
Ir
0

5
TF

—
—

CH₃

^tC₄H₉
H
—
—

5-170
Ir
1

5
OB

—
—

H
CH₃
H
pic

5-170X
Ir
1

5
OB

—
—

H
CH₃
H
acac

5-170Y
Ir
0

5
OB

—
—

H
CH₃
H
—
—

5-171
Ir
1

5
OB

—
—

H

^tC₄H₉
H
pic

5-171X
Ir
1

5
OB

—
—

H

^tC₄H₉
H
acac

5-171Y
Ir
0

5
OB

—
—

H

^tC₄H₉
H
—
—

5-172
Ir
1

5
OB

—
—

^tC₄H₉
CH₃
H
pic

5-172X
Ir
1

5
OB

—
—

^tC₄H₉
CH₃
H
acac

5-172Y
Ir
0

5
OB

—
—

^tC₄H₉
H
—
—

5-173
Ir
1

5
OB

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-173X
Ir
1

5
OB

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-173Y
Ir
0

5
OB

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-174
Ir
1

5
OB

—
—

CH₃
CH₃
H
pic

5-174X
Ir
1

5
OB

—
—

CH₃
CH₃
H
acac

5-174Y
Ir
0

5
OB

—
—

CH₃
CH₃
H
—
—

5-175
Ir
1

5
OB

—
—

CH₃

^tC₄H₉
H
pic

5-175X
Ir
1

5
OB

—
—

CH₃

^tC₄H₉
H
acac

5-175Y
Ir
0

5
OB

—
—

CH₃

^tC₄H₉
H
—
—

5-176
Ir
1

5
Fu

—
—

H
CH₃
H
pic

5-176X
Ir
1

5
Fu

—
—

H
CH₃
H
acac

5-176Y
Ir
0

5
Fu

—
—

H
CH₃
H
—
—

5-177
Ir
1

5
Fu

—
—

H

^tC₄H₉
H
pic

5-177X
Ir
1

5
Fu

—
—

H

^tC₄H₉
H
acac

5-177Y
Ir
0

5
Fu

—
—

H

^tC₄H₉
H
—
—

5-178
Ir
1

5
Fu

—
—

^tC₄H₉
CH₃
H
pic

5-178X
Ir
1

5
Fu

—
—

^tC₄H₉
CH₃
H
acac

5-178Y
Ir
0

5
Fu

—
—

^tC₄H₉
CH₃
H
—
—

5-179
Ir
1

5
Fu

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-179X
Ir
1

5
Fu

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-179Y
Ir
0

5
Fu

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-180
Ir
1

5
Fu

—
—

CH₃
CH₃
H
pic

5-180X
Ir
1

5
Fu

—
—

CH₃
CH₃
H
acac

5-180Y
Ir
0

5
Fu

—
—

CH₃
CH₃
H
—
—

5-181
Ir
1

5
Fu

—
—

CH₃

^tC₄H₉
H
pic

5-181X
Ir
1

5
Fu

—
—

CH₃

^tC₄H₉
H
acac

5-181Y
Ir
0

5
Fu

—
—

CH₃

^tC₄H₉
H
—
—

5-182
Ir
1

5
Fl

—
—

H
CH₃
H
pic

5-182X
Ir
1

5
Fl

—
—

H
CH₃
H
acac

5-182Y
Ir
0

5
Fl

—
—

H
CH₃
H
—
—

5-183
Ir
1

5
Fl

—
—

H

^tC₄H₉
H
pic

5-183X
Ir
1

5
Fl

—
—

H

^tC₄H₉
H
acac

5-183Y
Ir
0

5
Fl

—
—

H

^tC₄H₉
H
—
—

5-184
Ir
1

5
Fl

—
—

^tC₄H₉
CH₃
H
pic

5-184X
Ir
1

5
Fl

—
—

^tC₄H₉
CH₃
H
acac

5-184Y
Ir
0

5
Fl

—
—

^tC₄H₉
CH₃
H
—
—

5-185
Ir
1

5
Fl

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-185X
Ir
1

5
Fl

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-185Y
Ir
0

5
Fl

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-186
Ir
1

5
Fl

—
—

CH₃
CH₃
H
pic

5-186X
Ir
1

5
Fl

—
—

CH₃
CH₃
H
acac

5-186Y
Ir
0

5
Fl

—
—

CH₃
CH₃
H
—
—

5-187
Ir
1

5
Fl

—
—

CH₃

^tC₄H₉
H
pic

5-187X
Ir
1

5
Fl

—
—

CH₃

^tC₄H₉
H
acac

5-187Y
Ir
0

5
Fl

—
—

CH₃

^tC₄H₉
H
—
—

5-188
Ir
1

5
Bz

—
—

H
CH₃
H
pic

5-188X
Ir
1

5
Bz

—
—

H
CH₃
H
acac

5-188Y
Ir
0

5
Bz

—
—

H
CH₃
H
—
—

5-189
Ir
1

5
Bz

—
—

H

^tC₄H₉
H
pic

5-189X
Ir
1

5
Bz

—
—

H

^tC₄H₉
H
acac

5-189Y
Ir
0

5
Bz

—
—

H

^tC₄H₉
H
—
—

5-190
Ir
1

5
Bz

—
—

^tC₄H₉
CH₃
H
pic

5-190X
Ir
1

5
Bz

—
—

^tC₄H₉
CH₃
H
acac

5-190Y
Ir
0

5
Bz

—
—

^tC₄H₉
CH₃
H
—
—

5-191
Ir
1

5
Bz

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-191X
Ir
1

5
Bz

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-191Y
Ir
0

5
Bz

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-192
Ir
1

5
Bz

—
—

CH₃
CH₃
H
pic

5-192X
Ir
1

5
Bz

—
—

CH₃
CH₃
H
acac

5-192Y
Ir
0

5
Bz

—
—

CH₃
CH₃
H
—
—

5-193
Ir
1

5
Bz

—
—

CH₃

^tC₄H₉
H
pic

5-193X
Ir
1

5
Bz

—
—

CH₃

^tC₄H₉
H
acac

5-193Y
Ir
0

5
Bz

—
—

CH₃

^tC₄H₉
H
—
—

5-194
Ir
1

5
Qu

—
—

H
CH₃
H
pic

5-194X
Ir
1

5
Bz

—
—

H
CH₃
H
acac

5-194Y
Ir
0

5
Bz

—
—

H
CH₃
H
—
—

5-195
Ir
1

5
Bz

—
—

H

^tC₄H₉
H
pic

5-195X
Ir
1

5
Bz

—
—

H

^tC₄H₉
H
acac

5-195Y
Ir
0

5
Bz

—
—

H

^tC₄H₉
H
—
—

5-196
Ir
1

5
Bz

—
—

^tC₄H₉
CH₃
H
pic

5-196X
Ir
1

5
Bz

—
—

^tC₄H₉
CH₃
H
acac

5-196Y
Ir
0

5
Bz

—
—

^tC₄H₉
CH₃
H
—
—

5-197
Ir
1

5
Bz

—
—

^tC₄H₉

^tC₄H₉
H
pic

5-197X
Ir
1

5
Bz

—
—

^tC₄H₉

^tC₄H₉
H
acac

5-197Y
Ir
0

5
Bz

—
—

^tC₄H₉

^tC₄H₉
H
—
—

5-198
Ir
1

5
Bz

—
—

CH₃
CH₃
H
pic

5-198X
Ir
1

5
Bz

—
—

CH₃
CH₃
H
acac

5-198Y
Ir
0

5
Bz

—
—

CH₃
CH₃
H
—
—

5-199
Ir
1

5
Bz

—
—

CH₃

^tC₄H₉
H
pic

5-199X
Ir
1

5
Bz

—
—

CH₃

^tC₄H₉
H
acac

5-199Y
Ir
0

5
Bz

—
—

CH₃

^tC₄H₉
H
—
—

5-200
Ir
1

5
OL

H

ⁿC₄H₉

H
CH₃
H
pic

5-200X
Ir
1

5
OL

H

ⁿC₄H₉

H
CH₃
H
acac

5-200Y
Ir
0

5
OL

H

ⁿC₄H₉

H
CH₃
H
—
—

5-201
Ir
1

5
OL

H

ⁿC₄H₉

H

^tC₄H₉
H
pic

5-201X
Ir
1

5
OL

H

ⁿC₄H₉

H

^tC₄H₉
H
acac

5-201Y
Ir
0

5
OL

H

ⁿC₄H₉

H

^tC₄H₉
H
—
—

5-202
Ir
1

5
OL

H

^tC₄H₉

H
CH₃
H
pic

5-202X
Ir
1

5
OL

H

^tC₄H₉

H
CH₃
H
acac

5-202Y
Ir
0

5
OL

H

^tC₄H₉

H
CH₃
H
—
—

5-203
Ir
1

5
OL

H

^tC₄H₉

H

^tC₄H₉
H
pic

5-203X
Ir
1

5
OL

H

^tC₄H₉

H

^tC₄H₉
H
acac

5-203Y
Ir
0

5
OL

H

^tC₄H₉

H

^tC₄H₉
H
—
—

5-204
Ir
1

5
OL

CH₃

ⁿC₄H₉

H
CH₃
H
pic

5-204X
Ir
1

5
OL

CH₃

ⁿC₄H₉

H
CH₃
H
acac

5-204Y
Ir
0

5
OL

CH₃

ⁿC₄H₉

H
CH₃
H
—
—

5-205
Ir
1

5
OL

CH₃

^tC₄H₉

H
CH₃
H
pic

5-205X
Ir
1

5
OL

CH₃

^tC₄H₉

H
CH₃
H
acac

5-205Y
Ir
0

5
OL

CH₃

^tC₄H₉

H
CH₃
H
—
—

5-206
Ir
1

5
OL

H
H

H
CH₃
H
pic

5-206X
Ir
1

5
OL

H
H

H
CH₃
H
acac

5-206Y
Ir
0

5
OL

H
H

H
CH₃
H
—
—

5-207
Ir
1

5
OL

H

ⁿC₄H₉

CH₃

^tC₄H₉
H
pic

5-207X
Ir
1

5
OL

H

ⁿC₄H₉

CH₃

^tC₄H₉
H
acac

5-207Y
Ir
0

5
OL

H

ⁿC₄H₉

CH₃

^tC₄H₉
H
—
—

5-208
Ir
1

5
OL

H

^tC₄H₉

CH₃

^tC₄H₉
H
pic

5-208X
Ir
1

5
OL

H

^tC₄H₉

CH₃

^tC₄H₉
H
acac

5-208Y
Ir
0

5
OL

H

^tC₄H₉

CH₃

^tC₄H₉
H
—
—

5-209
Ir
1

5
OL

—CH₂CH₂CH₂—

H
CH₃
H
pic

5-209X
Ir
1

5
OL

—CH₂CH₂CH₂—

H
CH₃
H
acac

5-209Y
Ir
0

5
OL

—CH₂CH₂CH₂—

H
CH₃
H
—
—

5-210
Ir
1

5
OL

—CH₂CH₂CH₂—

H

^tC₄H₉
H
pic

5-210X
Ir
1

5
OL

—CH₂CH₂CH₂—

H

^tC₄H₉
H
acac

5-210Y
Ir
0

5
OL

—CH₂CH₂CH₂—

H

^tC₄H₉
H
—
—

embedded image

TABLE 13

No.

M
n
BSS

SS G

T¹
T²
T⁵

T⁶
T⁷
L¹
L²

6-138

Ir
1
6

Nap1

—
—
CH₃

H
H
pic

6-138X

Ir
1
6

Nap1

—
—
CH₃

H
H
acac

6-138Y

Ir
0
6

Nap1

—
—
CH₃

H
H
—
—

6-139

Ir
1
6

Nap1

—
—

^tC₄H₉

H
H
pic

6-139X

Ir
1
6

Nap1

—
—

^tC₄H₉

H
H
acac

6-139Y

Ir
0
6

Nap1

—
—

^tC₄H₉

H
H
—
—

6-140

Ir
1
6

Nap2

—
—
CH₃

H
H
pic

6-140X

Ir
1
6

Nap2

—
—
CH₃

H
H
acac

6-140Y

Ir
0
6

Nap2

—
—
CH₃

H
H
—
—

6-141

Ir
1
6

Nap2

—
—

^tC₄H₉

H
H
pic

6-141X

Ir
1
6

Nap2

—
—

^tC₄H₉

H
H
acac

6-141Y

Ir
0
6

Nap2

—
—

^tC₄H₉

H
H
—
—

6-142

Ir
1
6

Nap3

—
—
CH₃

H
H
pic

6-142X

Ir
1
6

Nap3

—
—
CH₃

H
H
acac

6-142Y

Ir
0
6

Nap3

—
—
CH₃

H
H
—
—

6-143

Ir
1
6

Nap3

—
—

^tC₄H₉

H
H
pic

6-143X

Ir
1
6

Nap3

—
—

^tC₄H₉

H
H
acac

6-143Y

Ir
0
6

Nap3

—
—

^tC₄H₉

H
H
—
—

6-144

Ir
1
6

TB

—
—
CH₃

H
H
pic

6-144X

Ir
1
6

TB

—
—
CH₃

H
H
acac

6-144Y

Ir
0
6

TB

—
—
CH₃

H
H
—
—

6-145

Ir
1
6

TB

—
—

^tC₄H₉

H
H
pic

6-145X

Ir
1
6

TB

—
—

^tC₄H₉

H
H
acac

6-145Y

Ir
0
6

TB

—
—

^tC₄H₉

H
H
—
—

6-146

Ir
1
6

TF

—
—
CH₃

H
H
pic

6-146X

Ir
1
6

TF

—
—
CH₃

H
H
acac

6-146Y

Ir
0
6

TF

—
—
CH₃

H
H
—
—

6-147

Ir
1
6

TF

—
—

^tC₄H₉

H
H
pic

6-147X

Ir
1
6

TF

—
—

^tC₄H₉

H
H
acac

6-147Y

Ir
0
6

TF

—
—

^tC₄H₉

H
H
—
—

6-148

Ir
1
6

OB

—
—
CH₃

H
H
pic

6-148X

Ir
1
6

OB

—
—
CH₃

H
H
acac

6-148Y

Ir
0
6

OB

—
—
CH₃

H
H
—
—

6-149

Ir
1
6

OB

—
—

^tC₄H₉

H
H
pic

6-149X

Ir
1
6

OB

—
—

^tC₄H₉

H
H
acac

6-149Y

Ir
0
6

OB

—
—

^tC₄H₉

H
H
—
—

6-150

Ir
1
6

Fu

—
—
CH₃

H
H
pic

6-150X

Ir
1
6

Fu

—
—
CH₃

H
H
acac

6-150Y

Ir
0
6

Fu

—
—
CH₃

H
H
—
—

6-151

Ir
1
6

Fu

—
—

^tC₄H₉

H
H
pic

6-151X

Ir
1
6

Fu

—
—

^tC₄H₉

H
H
acac

6-151Y

Ir
0
6

Fu

—
—

^tC₄H₉

H
H
—
—

6-152

Ir
1
6

Fl

—
—
CH₃

H
H
pic

6-152X

Ir
1
6

Fl

—
—
CH₃

H
H
acac

6-152Y

Ir
0
6

Fl

—
—
CH₃

H
H
—
—

6-153

Ir
1
6

Fl

—
—

^tC₄H₉

H
H
pic

6-153X

Ir
1
6

Fl

—
—

^tC₄H₉

H
H
acac

6-153Y

Ir
0
6

Fl

—
—

^tC₄H₉

H
H
—
—

6-154

Ir
1
6

Bz

—
—
CH₃

H
H
pic

6-154X

Ir
1
6

Bz

—
—
CH₃

H
H
acac

6-154Y

Ir
0
6

Bz

—
—
CH₃

H
H
—
—

6-155

Ir
1
6

Bz

—
—

^tC₄H₉

H
H
pic

6-155X

Ir
1
6

Bz

—
—

^tC₄H₉

H
H
acac

6-155Y

Ir
0
6

Bz

—
—

^tC₄H₉

H
H
—
—

6-156

Ir
1
6

Qu

—
—
CH₃

H
H
pic

6-156X

Ir
1
6

Qu

—
—
CH₃

H
H
acac

6-156Y

Ir
0
6

Qu

—
—
CH₃

H
H
—
—

6-157

Ir
1
6

Qu

—
—

^tC₄H₉

H
H
pic

6-157X

Ir
1
6

Qu

—
—

^tC₄H₉

H
H
acac

6-157Y

Ir
0
6

Qu

—
—

^tC₄H₉

H
H
—
—

6-158

Ir
1
6

OL

H

ⁿC₄H₉
CH₃

H
H
pic

6-158X

Ir
1
6

OL

H

ⁿC₄H₉
CH₃

H
H
acac

6-158Y

Ir
0
6

OL

H

ⁿC₄H₉
CH₃

H
H
—
—

6-159

Ir
1
6

OL

H

ⁿC₄H₉

^tC₄H₉

H
H
pic

6-159X

Ir
1
6

OL

H

ⁿC₄H₉

^tC₄H₉

H
H
acac

6-159Y

Ir
0
6

OL

H

ⁿC₄H₉

^tC₄H₉

H
H
—
—

6-160

Ir
1
6

OL

H

^tC₄H₉
CH₃

H
H
pic

6-160X

Ir
1
6

OL

H

^tC₄H₉
CH₃

H
H
acac

6-160Y

Ir
0
6

OL

H

^tC₄H₉
CH₃

H
H
—
—

6-161

Ir
1
6

OL

H

^tC₄H₉

^tC₄H₉

H
H
pic

6-161X

Ir
1
6

OL

H

^tC₄H₉

^tC₄H₉

H
H
acac

6-161Y

Ir
0
6

OL

H

^tC₄H₉

^tC₄H₉

H
H
—
—

6-162

Ir
1
6

OL

CH₃

ⁿC₄H₉
CH₃

H
H
pic

6-162X

Ir
1
6

OL

CH₃

ⁿC₄H₉
CH₃

H
H
acac

6-162Y

Ir
0
6

OL

CH₃

ⁿC₄H₉
CH₃

H
H
—
—

6-163

Ir
1
6

OL

CH₃

^tC₄H₉
CH₃

H
H
pic

6-163X

Ir
1
6

OL

CH₃

^tC₄H₉
CH₃

H
H
acac

6-163Y

Ir
0
6

OL

CH₃

^tC₄H₉
CH₃

H
H
—
—

6-164

Ir
1
6

OL

H
H
CH₃

H
H
pic

6-164X

Ir
1
6

OL

H
H
CH₃

H
H
acac

6-164Y

Ir
0
6

OL

H
H
CH₃

H
H
—
—

6-165

Ir
1
6

OL

—CH₂CH₂CH₂—
CH₃

H
H
pic

6-165X

Ir
1
6

OL

—CH₂CH₂CH₂—
CH₃

H
H
acac

6-165Y

Ir
0
6

OL

—CH₂CH₂CH₂—
CH₃

H
H
—
—

6-166

Ir
1
6

OL

—CH₂CH₂CH₂—

^tC₄H₉

H
H
pic

6-166X

Ir
1
6

OL

—CH₂CH₂CH₂—

^tC₄H₉

H
H
acac

6-166Y

Ir
0
6

OL

—CH₂CH₂CH₂—

^tC₄H₉

H
H
—
—

embedded image

TABLE 14

No.

M
n
BSS

SS G

T¹
T²
T⁵

T⁶
T⁷
L¹
L²

7-138

Ir
1
7

Nap1

—
—
CH₃

H
H
pic

7-138X

Ir
1
7

Nap1

—
—
CH₃

H
H
acac

7-138Y

Ir
0
7

Nap1

—
—
CH₃

H
H
—
—

7-139

Ir
1
7

Nap1

—
—

^tC₄H₉

H
H
pic

7-139X

Ir
1
7

Nap1

—
—

^tC₄H₉

H
H
acac

7-139Y

Ir
0
7

Nap1

—
—

^tC₄H₉

H
H
—
—

7-140

Ir
1
7

Nap2

—
—
CH₃

H
H
pic

7-140X

Ir
1
7

Nap2

—
—
CH₃

H
H
acac

7-140Y

Ir
0
7

Nap2

—
—
CH₃

H
H
—
—

7-141

Ir
1
7

Nap2

—
—

^tC₄H₉

H
H
pic

7-141X

Ir
1
7

Nap2

—
—

^tC₄H₉

H
H
acac

7-141Y

Ir
0
7

Nap2

—
—

^tC₄H₉

H
H
—
—

7-142

Ir
1
7

Nap3

—
—
CH₃

H
H
pic

7-142X

Ir
1
7

Nap3

—
—
CH₃

H
H
acac

7-142Y

Ir
0
7

Nap3

—
—
CH₃

H
H
—
—

7-143

Ir
1
7

Nap3

—
—

^tC₄H₉

H
H
pic

7-143X

Ir
1
7

Nap3

—
—

^tC₄H₉

H
H
acac

7-143Y

Ir
0
7

Nap3

—
—

^tC₄H₉

H
H
—
—

7-144

Ir
1
7

TB

—
—
CH₃

H
H
pic

7-144X

Ir
1
7

TB

—
—
CH₃

H
H
acac

7-144Y

Ir
0
7

TB

—
—
CH₃

H
H
—
—

7-145

Ir
1
7

TB

—
—

^tC₄H₉

H
H
pic

7-145X

Ir
1
7

TB

—
—

^tC₄H₉

H
H
acac

7-145Y

Ir
0
7

TB

—
—

^tC₄H₉

H
H
—
—

7-146

Ir
1
7

TF

—
—
CH₃

H
H
pic

7-146X

Ir
1
7

TF

—
—
CH₃

H
H
acac

7-146Y

Ir
0
7

TF

—
—
CH₃

H
H
—
—

7-147

Ir
1
7

TF

—
—

^tC₄H₉

H
H
pic

7-147X

Ir
1
7

TF

—
—

^tC₄H₉

H
H
acac

7-147Y

Ir
0
7

TF

—
—

^tC₄H₉

H
H
—
—

7-148

Ir
1
7

OB

—
—
CH₃

H
H
pic

7-148X

Ir
1
7

OB

—
—
CH₃

H
H
acac

7-148Y

Ir
0
7

OB

—
—
CH₃

H
H
—
—

7-149

Ir
1
7

OB

—
—

^tC₄H₉

H
H
pic

7-149X

Ir
1
7

OB

—
—

^tC₄H₉

H
H
acac

7-149Y

Ir
0
7

OB

—
—

^tC₄H₉

H
H
—
—

7-150

Ir
1
7

Fu

—
—
CH₃

H
H
pic

7-150X

Ir
1
7

Fu

—
—
CH₃

H
H
acac

7-150Y

Ir
0
7

Fu

—
—
CH₃

H
H
—
—

7-151

Ir
1
7

Fu

—
—

^tC₄H₉

H
H
pic

7-151X

Ir
1
7

Fu

—
—

^tC₄H₉

H
H
acac

7-151Y

Ir
0
7

Fu

—
—

^tC₄H₉

H
H
—
—

7-152

Ir
1
7

Fl

—
—
CH₃

H
H
pic

7-152X

Ir
1
7

Fl

—
—
CH₃

H
H
acac

7-152Y

Ir
0
7

Fl

—
—
CH₃

H
H
—
—

7-153

Ir
1
7

Fl

—
—

^tC₄H₉

H
H
pic

7-153X

Ir
1
7

Fl

—
—

^tC₄H₉

H
H
acac

7-153Y

Ir
0
7

Fl

—
—

^tC₄H₉

H
H
—
—

7-154

Ir
1
7

Bz

—
—
CH₃

H
H
pic

7-154X

Ir
1
7

Bz

—
—
CH₃

H
H
acac

7-154Y

Ir
0
7

Bz

—
—
CH₃

H
H
—
—

7-155

Ir
1
7

Bz

—
—

^tC₄H₉

H
H
pic

7-155X

Ir
1
7

Bz

—
—

^tC₄H₉

H
H
acac

7-155Y

Ir
0
7

Bz

—
—

^tC₄H₉

H
H
—
—

7-156

Ir
1
7

Qu

—
—
CH₃

H
H
pic

7-156X

Ir
1
7

Qu

—
—
CH₃

H
H
acac

7-156Y

Ir
0
7

Qu

—
—
CH₃

H
H
—
—

7-157

Ir
1
7

Qu

—
—

^tC₄H₉

H
H
pic

7-157X

Ir
1
7

Qu

—
—

^tC₄H₉

H
H
acac

7-157Y

Ir
0
7

Qu

—
—

^tC₄H₉

H
H
—
—

7-158

Ir
1
7

OL

H

ⁿC₄H₉
CH₃

H
H
pic

7-158X

Ir
1
7

OL

H

ⁿC₄H₉
CH₃

H
H
acac

7-158Y

Ir
0
7

OL

H

ⁿC₄H₉
CH₃

H
H
—
—

7-159

Ir
1
7

OL

H

ⁿC₄H₉

^tC₄H₉

H
H
pic

7-159X

Ir
1
7

OL

H

ⁿC₄H₉

^tC₄H₉

H
H
acac

7-159Y

Ir
0
7

OL

H

ⁿC₄H₉

^tC₄H₉

H
H
—
—

7-160

Ir
1
7

OL

H

^tC₄H₉
CH₃

H
H
pic

7-160X

Ir
1
7

OL

H

^tC₄H₉
CH₃

H
H
acac

7-160Y

Ir
0
7

OL

H

^tC₄H₉
CH₃

H
H
—
—

7-161

Ir
1
7

OL

H

^tC₄H₉

^tC₄H₉

H
H
pic

7-161X

Ir
1
7

OL

H

^tC₄H₉

^tC₄H₉

H
H
acac

7-161Y

Ir
0
7

OL

H

^tC₄H₉

^tC₄H₉

H
H
—
—

7-162

Ir
1
7

OL

CH₃

ⁿC₄H₉
CH₃

H
H
pic

7-162X

Ir
1
7

OL

CH₃

ⁿC₄H₉
CH₃

H
H
acac

7-162Y

Ir
0
7

OL

CH₃

ⁿC₄H₉
CH₃

H
H
—
—

7-163

Ir
1
7

OL

CH₃

^tC₄H₉
CH₃

H
H
pic

7-163X

Ir
1
7

OL

CH₃

^tC₄H₉
CH₃

H
H
acac

7-163Y

Ir
0
7

OL

CH₃

^tC₄H₉
CH₃

H
H
—
—

7-164

Ir
1
7

OL

H
H
CH₃

H
H
pic

7-164X

Ir
1
7

OL

H
H
CH₃

H
H
acac

7-164Y

Ir
0
7

OL

H
H
CH₃

H
H
—
—

7-165

Ir
1
7

OL

—CH₂CH₂CH₂—
CH₃

H
H
pic

7-165X

Ir
1
7

OL

—CH₂CH₂CH₂—
CH₃

H
H
acac

7-165Y

Ir
0
7

OL

—CH₂CH₂CH₂—
CH₃

H
H
—
—

7-166

Ir
1
7

OL

—CH₂CH₂CH₂—
CH₃

H
H
pic

7-166X

Ir
1
7

OL

—CH₂CH₂CH₂—
CH₃

H
H
acac

7-166Y

Ir
0
7

OL

—CH₂CH₂CH₂—
CH₃

H
H
—
—

embedded image

TABLE 15

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1-187
Rh
1
1
Ph
H
H
H
H
H
H
H
H
H
pic

1-187X
Rh
1
1
Ph
H
H
H
H
H
H
H
H
H
acac

1-187Y
Rh
0
1
Ph
H
H
H
H
H
H
H
H
H
—
—

1-188
Rh
1
1
Ph
H
F
H
F
H
H
H
H
H
pic

1-188X
Rh
1
1
Ph
H
F
H
F
H
H
H
H
H
acac

1-188Y
Rh
0
1
Ph
H
F
H
F
H
H
H
H
H
—
—

1-189
Rh
1
1
Ph
F
H
H
F
H
H
H
H
H
pic

1-189X
Rh
1
1
Ph
F
H
H
F
H
H
H
H
H
acac

1-189Y
Rh
0
1
Ph
F
H
H
F
H
H
H
H
H
—
—

1-190
Rh
1
1
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

1-190X
Rh
1
1
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

1-190Y
Rh
0
1
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

1-191
Rh
1
1
Ph
H
F
CF₃
H
H
H
H
H
H
pic

1-191X
Rh
1
1
Ph
H
F
CF₃
H
H
H
H
H
H
acac

1-191Y
Rh
0
1
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

1-192
Rh
1
1
Ph
F
H
CF₃
H
H
H
H
H
H
pic

1-192X
Rh
1
1
Ph
F
H
CF₃
H
H
H
H
H
H
acac

1-192Y
Rh
0
1
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

1-193
Rh
1
1
Ph
F
F
F
F
H
H
H
H
H
pic

1-193X
Rh
1
1
Ph
F
F
F
F
H
H
H
H
H
acac

1-193Y
Rh
0
1
Ph
F
F
F
F
H
H
H
H
H
—
—

1-194
Rh
1
1
Ph
H
F
H
CH₃
H
H
H
H
H
pic

1-194X
Rh
1
1
Ph
H
F
H
CH₃
H
H
H
H
H
acac

1-194Y
Rh
0
1
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

1-195
Rh
1
1
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

1-195X
Rh
1
1
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

1-195Y
Rh
0
1
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

1-196
Rh
1
1
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

1-196X
Rh
1
1
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

1-196Y
Rh
0
1
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

1-197
Rh
1
1
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

1-197X
Rh
1
1
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

1-197Y
Rh
0
1
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

1-198
Rh
1
1
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

1-198X
Rh
1
1
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

1-198Y
Rh
0
1
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

1-199
Rh
1
1
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

1-199X
Rh
1
1
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

1-199Y
Rh
0
1
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

1-200
Rh
1
1
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

1-200X
Rh
1
1
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

1-200Y
Rh
0
1
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

1-201
Rh
1
1
Ph
H
H
NO₂
H
H
H
H
H
H
pic

1-201X
Rh
1
1
Ph
H
H
NO₂
H
H
H
H
H
H
acac

1-201Y
Rh
0
1
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

1-202
Rh
1
1
Ph
F
H
NO₂
H
H
H
H
H
H
pic

1-202X
Rh
1
1
Ph
F
H
NO₂
H
H
H
H
H
H
acac

1-202Y
Rh
0
1
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

1-203
Rh
1
1
Ph
F
H
NO₂
F
H
H
H
H
H
pic

1-203X
Rh
1
1
Ph
F
H
NO₂
F
H
H
H
H
H
acac

1-203Y
Rh
0
1
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

1-204
Rh
1
1
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

1-204X
Rh
1
1
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

1-204Y
Rh
0
1
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

1-205
Rh
1
1
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

1-205X
Rh
1
1
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

1-205Y
Rh
0
1
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

1-206
Rh
1
1
Ph
H
H
CF₃
H
H
H
H
H
H
pic

1-206X
Rh
1
1
Ph
H
H
CF₃
H
H
H
H
H
H
acac

1-206Y
Rh
0
1
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

1-207
Rh
1
1
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

1-207X
Rh
1
1
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

1-207Y
Rh
0
1
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

1-208
Rh
1
1
Ph
H
NO₂
H
H
H
H
H
H
H
pic

1-208X
Rh
1
1
Ph
H
NO₂
H
H
H
H
H
H
H
acac

1-208Y
Rh
0
1
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

1-209
Rh
1
1
Ph
H
CF₃
H
H
H
H
H
H
H
pic

1-209X
Rh
1
1
Ph
H
CF₃
H
H
H
H
H
H
H
acac

1-209Y
Rh
0
1
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

1-210
Rh
1
1
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

1-210X
Rh
1
1
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

1-210Y
Rh
0
1
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

1-211
Rh
1
1
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

1-211X
Rh
1
1
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

1-211Y
Rh
0
1
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

1-212
Rh
1
1
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

1-212X
Rh
1
1
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

1-212Y
Rh
0
1
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

1-213
Rh
1
1
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

1-213X
Rh
1
1
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

1-213Y
Rh
0
1
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

1-214
Rh
1
1
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

1-214X
Rh
1
1
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

1-214Y
Rh
0
1
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

1-215
Rh
1
1
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

1-215X
Rh
1
1
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

1-215Y
Rh
0
1
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

1-216
Rh
1
1
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

1-216X
Rh
1
1
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

1-216Y
Rh
0
1
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

1-217
Rh
1
1
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

1-217X
Rh
1
1
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

1-217Y
Rh
0
1
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

1-218
Rh
1
1
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

1-218X
Rh
1
1
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

1-218Y
Rh
0
1
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

1-219
Rh
1
1
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

1-219X
Rh
1
!
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

1-219Y
Rh
0
1
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

1-220
Rh
1
1
Ph
H
F
H
F
H
CH₃
H
H
H
pic

1-220X
Rh
1
1
Ph
H
F
H
F
H
CH₃
H
H
H
acac

1-220Y
Rh
0
1
Ph
H
F
H
F
H
CH₃
H
H
H
—
—

1-221
Rh
1
1
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
pic

1-221X
Rh
1
1
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
acac

1-221Y
Rh
0
1
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
—
—

1-222
Rh
1
1
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

1-222X
Rh
1
1
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

1-222Y
Rh
0
1
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

1-223
Rh
1
1
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1-223X
Rh
1
1
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1-223Y
Rh
0
1
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1-224
Rh
1
1
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

1-224X
Rh
1
1
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

1-224Y
Rh
0
!
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

1-225
Rh
1
1
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

1-225X
Rh
1
1
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

1-225Y
Rh
0
1
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

1-226
Rh
1
1
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

1-226X
Rh
1
1
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

1-226Y
Rh
0
1
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

1-227
Rh
1
1
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

1-227X
Rh
1
1
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

1-227Y
Rh
0
1
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

1-228
Rh
1
1
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

1-228X
Rh
1
1
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

1-228Y
Rh
0
1
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

1-229
Rh
1
1
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1-229X
Rh
1
1
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1-229Y
Rh
0
1
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1-230
Rh
1
1
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

1-230X
Rh
1
1
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

1-230Y
Rh
0
1
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

1-231
Rh
1
1
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

1-231X
Rh
1
1
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

1-231Y
Rh
0
1
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

1-232
Rh
1
1
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

1-232X
Rh
1
1
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

1-232Y
Rh
0
1
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

1-233
Rh
1
1
Ph
H
H
BL
H
H
H
H
H
pic

1-233X
Rh
1
1
Ph
H
H
BL
H
H
H
H
H
acac

1-233Y
Rh
0
1
Ph
H
H
BL
H
H
H
H
H
—
—

1-234
Rh
1
1
Ph
H
BL
H
H
H
H
H
H
pic

1-234X
Rh
1
1
Ph
H
BL
H
H
H
H
H
H
acac

1-234Y
Rh
0
1
Ph
H
BL
H
H
H
H
H
H
—
—

1-235
Rh
1
1
Ph
H
H
PL
H
H
H
H
H
pic

1-235X
Rh
1
1
Ph
H
H
PL
H
H
H
H
H
acac

1-235Y
Rh
0
1
Ph
H
H
PL
H
H
H
H
H
—
—

1-236
Rh
1
1
Ph
H
PL
H
H
H
H
H
H
pic

1-236X
Rh
1
1
Ph
H
PL
H
H
H
H
H
H
acac

1-236Y
Rh
0
1
Ph
H
PL
H
H
H
H
H
H
—
—

1-237
Rh
1
1
Ph
H
H
MEE1
H
H
H
H
H
pic

1-237X
Rh
1
1
Ph
H
H
MEE1
H
H
H
H
H
acac

1-237Y
Rh
0
1
Ph
H
H
MEE1
H
H
H
H
H
—
—

1-238
Rh
1
1
Ph
H
MEE1
H
H
H
H
H
H
pic

1-238X
Rh
1
1
Ph
H
MEE1
H
H
H
H
H
H
acac

1-238Y
Rh
0
1
Ph
H
MEE1
H
H
H
H
H
H
—
—

1-239
Rh
1
1
Ph
H
H
MEE2
H
H
H
H
H
pic

1-239X
Rh
1
1
Ph
H
H
MEE2
H
H
H
H
H
acac

1-239Y
Rh
0
1
Ph
H
H
MEE2
H
H
H
H
H
—
—

1-240
Rh
1
1
Ph
H
MEE2
H
H
H
H
H
H
pic

1-240X
Rh
1
1
Ph
H
MEE2
H
H
H
H
H
H
acac

1-240Y
Rh
0
1
Ph
H
MEE2
H
H
H
H
H
H
—
—

1-241
Rh
1
1
Ph
H
H
PA1
H
H
H
H
H
pic

1-241X
Rh
1
1
Ph
H
H
PA1
H
H
H
H
H
acac

1-241Y
Rh
0
1
Ph
H
H
PA1
H
H
H
H
H
—
—

1-242
Rh
1
1
Ph
H
PA1
H
H
H
H
H
H
pic

1-242X
Rh
1
1
Ph
H
PA1
H
H
H
H
H
H
acac

1-242Y
Rh
0
1
Ph
H
PA1
H
H
H
H
H
H
—
—

1-243
Rh
1
1
Ph
H
H
PA2
H
H
H
H
H
pic

1-243X
Rh
1
1
Ph
H
H
PA2
H
H
H
H
H
acac

1-243Y
Rh
0
1
Ph
H
H
PA2
H
H
H
H
H
—
—

1-244
Rh
1
1
Ph
H
PA2
H
H
H
H
H
H
pic

1-244X
Rh
1
1
Ph
H
PA2
H
H
H
H
H
H
acac

1-244Y
Rh
0
1
Ph
H
PA2
H
H
H
H
H
H
—
—

1-245
Rh
1
1
Ph
H
H
EA1
H
H
H
H
H
pic

1-245X
Rh
1
1
Ph
H
H
EA1
H
H
H
H
H
acac

1-245Y
Rh
0
1
Ph
H
H
EA1
H
H
H
H
H
—
—

1-246
Rh
1
1
Ph
H
EA2
H
H
H
H
H
H
pic

1-246X
Rh
1
1
Ph
H
EA2
H
H
H
H
H
H
acac

1-246Y
Rh
0
1
Ph
H
EA2
H
H
H
H
H
H
—
—

1-247
Rh
1
1
Ph
H
H
ME
H
H
H
H
H
pic

1-247X
Rh
1
1
Ph
H
H
ME
H
H
H
H
H
acac

1-247Y
Rh
0
1
Ph
H
H
ME
H
H
H
H
H
—
—

1-248
Rh
1
1
Ph
H
ME
H
H
H
H
H
H
pic

1-248X
Rh
1
1
Ph
H
ME
H
H
H
H
H
H
acac

1-248Y
Rh
0
1
Ph
H
ME
H
H
H
H
H
H
—
—

1-249
Rh
1
1
Ph
H
H
AT
H
H
H
H
H
pic

1-249X
Rh
1
1
Ph
H
H
AT
H
H
H
H
H
acac

1-249Y
Rh
0
1
Ph
H
H
AT
H
H
H
H
H
—
—

1-250
Rh
1
1
Ph
H
AT
H
H
H
H
H
H
pic

1-250X
Rh
1
1
Ph
H
AT
H
H
H
H
H
H
acac

1-250Y
Rh
0
1
Ph
H
AT
H
H
H
H
H
H
—
—

1-251
Rh
1
1
Ph
H
H
MES1
H
H
H
H
H
pic

1-251X
Rh
1
1
Ph
H
H
MES1
H
H
H
H
H
acac

1-251Y
Rh
0
1
Ph
H
H
MES1
H
H
H
H
H
—
—

1-252
Rh
1
1
Ph
H
MES1
H
H
H
H
H
H
pic

1-252X
Rh
1
1
Ph
H
MES1
H
H
H
H
H
H
acac

1-252Y
Rh
0
1
Ph
H
MES1
H
H
H
H
H
H
—
—

1-253
Rh
1
1
Ph
H
H
MES2
H
H
H
H
H
pic

1-253X
Rh
1
1
Ph
H
H
MES2
H
H
H
H
H
acac

1-253Y
Rh
0
1
Ph
H
H
MES2
H
H
H
H
H
—
—

1-254
Rh
1
1
Ph
H
MES2
H
H
H
H
H
H
pic

1-254X
Rh
1
1
Ph
H
MES2
H
H
H
H
H
H
acac

1-254Y
Rh
0
1
Ph
H
MES2
H
H
H
H
H
H
—
—

1-255
Rh
1
1
Ph
H
H
PS1
H
H
H
H
H
pic

1-255X
Rh
1
1
Ph
H
H
PS1
H
H
H
H
H
acac

1-255Y
Rh
0
1
Ph
H
H
PS1
H
H
H
H
H
—
—

1-256
Rh
1
1
Ph
H
PS1
H
H
H
H
H
H
pic

1-256X
Rh
1
1
Ph
H
PS1
H
H
H
H
H
H
acac

1-256Y
Rh
0
1
Ph
H
PS1
H
H
H
H
H
H
—
—

1-257
Rh
1
1
Ph
H
H
PS2
H
H
H
H
H
pic

1-257X
Rh
1
1
Ph
H
H
PS2
H
H
H
H
H
acac

1-257Y
Rh
0
1
Ph
H
H
PS2
H
H
H
H
H
—
—

1-258
Rh
1
1
Ph
H
PS2
H
H
H
H
H
H
pic

1-258X
Rh
1
1
Ph
H
PS2
H
H
H
H
H
H
acac

1-258Y
Rh
0
1
Ph
H
PS2
H
H
H
H
H
H
—
—

1-259
Rh
1
1
Ph
H
H
BAL1
H
H
H
H
H
pic

1-259X
Rh
1
1
Ph
H
H
BAL1
H
H
H
H
H
acac

1-259Y
Rh
0
1
Ph
H
H
BAL1
H
H
H
H
H
—
—

1-260
Rh
1
1
Ph
H
BAL1
H
H
H
H
H
H
pic

1-260X
Rh
1
1
Ph
H
BAL1
H
H
H
H
H
H
acac

1-260Y
Rh
0
1
Ph
H
BAL1
H
H
H
H
H
H
—
—

1-261
Rh
1
1
Ph
H
H
BAL2
H
H
H
H
H
pic

1-261X
Rh
1
1
Ph
H
H
BAL2
H
H
H
H
H
acac

1-261Y
Rh
0
1
Ph
H
H
BAL2
H
H
H
H
H
—
—

1-262
Rh
1
1
Ph
H
BAL2
H
H
H
H
H
H
pic

1-262X
Rh
1
1
Ph
H
BAL2
H
H
H
H
H
H
acac

1-262Y
Rh
0
1
Ph
H
BAL2
H
H
H
H
H
H
—
—

1-263
Rh
1
1
Ph
H
H
MEK1
H
H
H
H
H
pic

1-263X
Rh
1
1
Ph
H
H
MEK1
H
H
H
H
H
acac

1-263Y
Rh
0
1
Ph
H
H
MEK1
H
H
H
H
H
—
—

1-264
Rh
1
1
Ph
H
MEK1
H
H
H
H
H
H
pic

1-264X
Rh
1
1
Ph
H
MEK1
H
H
H
H
H
H
acac

1-264Y
Rh
0
1
Ph
H
MEK1
H
H
H
H
H
H
—
—

1-265
Rh
1
1
Ph
H
H
MEK2
H
H
H
H
H
pic

1-265X
Rh
1
1
Ph
H
H
MEK2
H
H
H
H
H
acac

1-265Y
Rh
0
1
Ph
H
H
MEK2
H
H
H
H
H
—
—

1-266
Rh
1
1
Ph
H
MEK2
H
H
H
H
H
H
pic

1-266X
Rh
1
1
Ph
H
MEK2
H
H
H
H
H
H
acac

1-266Y
Rh
0
1
Ph
H
MEK2
H
H
H
H
H
H
—
—

1-267
Rh
1
1
Ph
H
H
PAL1
H
H
H
H
H
pic

1-267X
Rh
1
1
Ph
H
H
PAL1
H
H
H
H
H
acac

1-267Y
Rh
0
1
Ph
H
H
PAL1
H
H
H
H
H
—
—

1-268
Rh
1
1
Ph
H
PAL1
H
H
H
H
H
H
pic

1-268X
Rh
1
1
Ph
H
PAL1
H
H
H
H
H
H
acac

1-268Y
Rh
0
1
Ph
H
PAL1
H
H
H
H
H
H
—
—

1-269
Rh
1
1
Ph
H
H
PAL2
H
H
H
H
H
pic

1-269X
Rh
1
1
Ph
H
H
PAL2
H
H
H
H
H
acac

1-269Y
Rh
0
1
Ph
H
H
PAL2
H
H
H
H
H
—
—

1-270
Rh
1
1
Ph
H
PAL2
H
H
H
H
H
H
pic

1-270X
Rh
1
1
Ph
H
PAL2
H
H
H
H
H
H
acac

1-270Y
Rh
0
1
Ph
H
PAL2
H
H
H
H
H
H
—
—

1-271
Rh
1
1
Ph
H
H
MMK
H
H
H
H
H
pic

1-271X
Rh
1
1
Ph
H
H
MMK
H
H
H
H
H
acac

1-271Y
Rh
0
1
Ph
H
H
MMK
H
H
H
H
H
—
—

1-272
Rh
1
1
Ph
H
MMK
H
H
H
H
H
H
pic

1-272X
Rh
1
1
Ph
H
MMK
H
H
H
H
H
H
acac

1-272Y
Rh
0
1
Ph
H
MMK
H
H
H
H
H
H
—
—

1-273
Rh
1
1
Ph
H
H
EES1
H
H
H
H
H
pic

1-273X
Rh
1
1
Ph
H
H
EES1
H
H
H
H
H
acac

1-273Y
Rh
0
1
Ph
H
H
EES1
H
H
H
H
H
—
—

1-274
Rh
1
1
Ph
H
EES2
H
H
H
H
H
H
pic

1-274X
Rh
1
1
Ph
H
EES2
H
H
H
H
H
H
acac

1-274Y
Rh
0
1
Ph
H
EES2
H
H
H
H
H
H
—
—

1-275
Rh
1
1
Ph
H
H
PAE1
H
H
H
H
H
pic

1-275X
Rh
1
1
Ph
H
H
PAE1
H
H
H
H
H
acac

1-275Y
Rh
0
1
Ph
H
H
PAE1
H
H
H
H
H
—
—

1-276
Rh
1
1
Ph
H
PAE2
H
H
H
H
H
H
pic

1-276X
Rh
1
1
Ph
H
PAE2
H
H
H
H
H
H
acac

1-276Y
Rh
0
1
Ph
H
PAE2
H
H
H
H
H
H
—
—

1-277
Rh
1
1
Ph
H
H
AME1
H
H
H
H
H
pic

1-277X
Rh
1
1
Ph
H
H
AME1
H
H
H
H
H
acac

1-277Y
Rh
0
1
Ph
H
H
AME1
H
H
H
H
H
—
—

1-278
Rh
1
1
Ph
H
AME1
H
H
H
H
H
H
pic

1-278X
Rh
1
1
Ph
H
AME1
H
H
H
H
H
H
acac

1-278Y
Rh
0
1
Ph
H
AME1
H
H
H
H
H
H
—
—

1-279
Rh
1
1
Ph
H
H
AME2
H
H
H
H
H
pic

1-279X
Rh
1
1
Ph
H
H
AME2
H
H
H
H
H
acac

1-279Y
Rh
0
1
Ph
H
H
AME2
H
H
H
H
H
—
—

1-280
Rh
1
1
Ph
H
AME2
H
H
H
H
H
H
pic

1-280X
Rh
1
1
Ph
H
AME2
H
H
H
H
H
H
acac

1-280Y
Rh
0
1
Ph
H
AME2
H
H
H
H
H
H
—
—

1-281
Rh
1
1
Ph
H
H
EAE1
H
H
H
H
H
pic

1-281X
Rh
1
1
Ph
H
H
EAE1
H
H
H
H
H
acac

1-281Y
Rh
0
1
Ph
H
H
EAE1
H
H
H
H
H
—
—

1-282
Rh
1
1
Ph
H
EAE1
H
H
H
H
H
H
pic

1-282X
Rh
1
1
Ph
H
EAE1
H
H
H
H
H
H
acac

1-282Y
Rh
0
1
Ph
H
EAE1
H
H
H
H
H
H
—
—

1-283
Rh
1
1
Ph
H
H
EAE2
H
H
H
H
H
pic

1-283X
Rh
1
1
Ph
H
H
EAE2
H
H
H
H
H
acac

1-283Y
Rh
0
1
Ph
H
H
EAE2
H
H
H
H
H
—
—

1-284
Rh
1
1
Ph
H
EAE2
H
H
H
H
H
H
pic

1-284X
Rh
1
1
Ph
H
EAE2
H
H
H
H
H
H
acac

1-284Y
Rh
0
1
Ph
H
EAE2
H
H
H
H
H
H
—
—

1-285
Rh
1
1
Ph
H
H
AAE1
H
H
H
H
H
pic

1-285X
Rh
1
1
Ph
H
H
AAE1
H
H
H
H
H
acac

1-285Y
Rh
0
1
Ph
H
H
AAE1
H
H
H
H
H
—
—

1-286
Rh
1
1
Ph
H
AAE1
H
H
H
H
H
H
pic

1-286X
Rh
1
1
Ph
H
AAE1
H
H
H
H
H
H
acac

1-286Y
Rh
0
1
Ph
H
AAE1
H
H
H
H
H
H
—
—

1-287
Rh
1
1
Ph
H
H
AAE2
H
H
H
H
H
pic

1-287X
Rh
1
1
Ph
H
H
AAE2
H
H
H
H
H
acac

1-287Y
Rh
0
1
Ph
H
H
AAE2
H
H
H
H
H
—
—

1-288
Rh
1
1
Ph
H
AAE2
H
H
H
H
H
H
pic

1-288X
Rh
1
1
Ph
H
AAE2
H
H
H
H
H
H
acac

1-288Y
Rh
0
1
Ph
H
AAE2
H
H
H
H
H
H
—
—

1-289
Rh
1
1
Ph
H
H
PME1
H
H
H
H
H
pic

1-289X
Rh
1
1
Ph
H
H
PME1
H
H
H
H
H
acac

1-289Y
Rh
0
1
Ph
H
H
PME1
H
H
H
H
H
—
—

1-290
Rh
1
1
Ph
H
PME1
H
H
H
H
H
H
pic

1-290X
Rh
1
1
Ph
H
PME1
H
H
H
H
H
H
acac

1-290Y
Rh
0
1
Ph
H
PME1
H
H
H
H
H
H
—
—

1-291
Rh
1
1
Ph
H
H
PME2
H
H
H
H
H
pic

1-291X
Rh
1
1
Ph
H
H
PME2
H
H
H
H
H
acac

1-291Y
Rh
0
1
Ph
H
H
PME2
H
H
H
H
H
—
—

1-292
Rh
1
1
Ph
H
PME2
H
H
H
H
H
H
pic

1-292X
Rh
1
1
Ph
H
PME2
H
H
H
H
H
H
acac

1-292Y
Rh
0
1
Ph
H
PME2
H
H
H
H
H
H
—
—

1-293
Rh
1
1
Ph
H
H
MET1
H
H
H
H
H
pic

1-293X
Rh
1
1
Ph
H
H
MET1
H
H
H
H
H
acac

1-293Y
Rh
0
1
Ph
H
H
MET1
H
H
H
H
H
—
—

1-294
Rh
1
1
Ph
H
MET1
H
H
H
H
H
H
pic

1-294X
Rh
1
1
Ph
H
MET1
H
H
H
H
H
H
acac

1-294Y
Rh
0
1
Ph
H
MET1
H
H
H
H
H
H
—
—

1-295
Rh
1
1
Ph
H
H
MET2
H
H
H
H
H
pic

1-295X
Rh
1
1
Ph
H
H
MET2
H
H
H
H
H
acac

1-295Y
Rh
0
1
Ph
H
H
MET2
H
H
H
H
H
—
—

1-296
Rh
1
1
Ph
H
MET2
H
H
H
H
H
H
pic

1-296X
Rh
1
1
Ph
H
MET2
H
H
H
H
H
H
acac

1-296Y
Rh
0
1
Ph
H
MET2
H
H
H
H
H
H
—
—

1-297
Rh
1
1
Ph
H
H
EE1
H
H
H
H
H
pic

1-297X
Rh
1
1
Ph
H
H
EE1
H
H
H
H
H
acac

1-297Y
Rh
0
1
Ph
H
H
EE1
H
H
H
H
H
—
—

1-298
Rh
1
1
Ph
H
EE1
H
H
H
H
H
H
pic

1-298X
Rh
1
1
Ph
H
EE1
H
H
H
H
H
H
acac

1-298Y
Rh
0
1
Ph
H
EE1
H
H
H
H
H
H
—
—

1-299
Rh
1
1
Ph
H
H
EE2
H
H
H
H
H
pic

1-299X
Rh
1
1
Ph
H
H
EE2
H
H
H
H
H
acac

1-299Y
Rh
0
1
Ph
H
H
EE2
H
H
H
H
H
—
—

1-300
Rh
1
1
Ph
H
EE2
H
H
H
H
H
H
pic

1-300X
Rh
1
1
Ph
H
EE2
H
H
H
H
H
H
acac

1-300Y
Rh
0
1
Ph
H
EE2
H
H
H
H
H
H
—
—

1-301
Rh
1
1
Ph
H
H
MS1
H
H
H
H
H
pic

1-301X
Rh
1
1
Ph
H
H
MS1
H
H
H
H
H
acac

1-301Y
Rh
0
1
Ph
H
H
MS1
H
H
H
H
H
—
—

1-302
Rh
1
1
Ph
H
MS1
H
H
H
H
H
H
pic

1-302X
Rh
1
1
Ph
H
MS1
H
H
H
H
H
H
acac

1-302Y
Rh
0
1
Ph
H
MS1
H
H
H
H
H
H
—
—

1-303
Rh
1
1
Ph
H
H
MS2
H
H
H
H
H
pic

1-303X
Rh
1
1
Ph
H
H
MS2
H
H
H
H
H
acac

1-303Y
Rh
0
1
Ph
H
H
MS2
H
H
H
H
H
—
—

1-304
Rh
1
1
Ph
H
MS2
H
H
H
H
H
H
pic

1-304X
Rh
1
1
Ph
H
MS2
H
H
H
H
H
H
acac

1-304Y
Rh
0
1
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 16

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2-187
Rh
1
2
Ph
H
H
H
H
H
H
H
H
H
pic

2-187X
Rh
1
2
Ph
H
H
H
H
H
H
H
H
H
acac

2-187Y
Rh
0
2
Ph
H
H
H
H
H
H
H
H
H
—
—

2-188
Rh
1
2
Ph
H
F
H
F
H
H
H
H
H
pic

2-188X
Rh
1
2
Ph
H
F
H
F
H
H
H
H
H
acac

2-188Y
Rh
0
2
Ph
H
F
H
F
H
H
H
H
H
—
—

2-189
Rh
1
2
Ph
F
H
H
F
H
H
H
H
H
pic

2-189X
Rh
1
2
Ph
F
H
H
F
H
H
H
H
H
acac

2-189Y
Rh
0
2
Ph
F
H
H
F
H
H
H
H
H
—
—

2-190
Rh
1
2
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

2-190X
Rh
1
2
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

2-190Y
Rh
0
2
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

2-191
Rh
1
2
Ph
H
F
CF₃
H
H
H
H
H
H
pic

2-191X
Rh
1
2
Ph
H
F
CF₃
H
H
H
H
H
H
acac

2-191Y
Rh
0
2
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

2-192
Rh
1
2
Ph
F
H
CF₃
H
H
H
H
H
H
pic

2-192X
Rh
1
2
Ph
F
H
CF₃
H
H
H
H
H
H
acac

2-192Y
Rh
0
2
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

2-193
Rh
1
2
Ph
F
F
F
F
H
H
H
H
H
pic

2-193X
Rh
1
2
Ph
F
F
F
F
H
H
H
H
H
acac

2-193Y
Rh
0
2
Ph
F
F
F
F
H
H
H
H
H
—
—

2-194
Rh
1
2
Ph
H
F
H
CH₃
H
H
H
H
H
pic

2-194X
Rh
1
2
Ph
H
F
H
CH₃
H
H
H
H
H
acac

2-194Y
Rh
0
2
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

2-195
Rh
1
2
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

2-195X
Rh
1
2
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

2-195Y
Rh
0
2
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

2-196
Rh
1
2
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

2-196X
Rh
1
2
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

2-196Y
Rh
0
2
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

2-197
Rh
1
2
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

2-197X
Rh
1
2
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

2-197Y
Rh
0
2
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

2-198
Rh
1
2
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

2-198X
Rh
1
2
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

2-198Y
Rh
0
2
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

2-199
Rh
1
2
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

2-199X
Rh
1
2
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

2-199Y
Rh
0
2
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

2-200
Rh
1
2
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

2-200X
Rh
1
2
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

2-200Y
Rh
0
2
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

2-201
Rh
1
2
Ph
H
H
NO₂
H
H
H
H
H
H
pic

2-201X
Rh
1
2
Ph
H
H
NO₂
H
H
H
H
H
H
acac

2-201Y
Rh
0
2
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

2-202
Rh
1
2
Ph
F
H
NO₂
H
H
H
H
H
H
pic

2-202X
Rh
1
2
Ph
F
H
NO₂
H
H
H
H
H
H
acac

2-202Y
Rh
0
2
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

2-203
Rh
1
2
Ph
F
H
NO₂
F
H
H
H
H
H
pic

2-203X
Rh
1
2
Ph
F
H
NO₂
F
H
H
H
H
H
acac

2-203Y
Rh
0
2
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

2-204
Rh
1
2
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

2-204X
Rh
1
2
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

2-204Y
Rh
0
2
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

2-205
Rh
1
2
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

2-205X
Rh
1
2
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

2-205Y
Rh
0
2
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

2-206
Rh
1
2
Ph
H
H
CF₃
H
H
H
H
H
H
pic

2-206X
Rh
1
2
Ph
H
H
CF₃
H
H
H
H
H
H
acac

2-206Y
Rh
0
2
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

2-207
Rh
1
2
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

2-207X
Rh
1
2
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

2-207Y
Rh
0
2
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

2-208
Rh
1
2
Ph
H
NO₂
H
H
H
H
H
H
H
pic

2-208X
Rh
1
2
Ph
H
NO₂
H
H
H
H
H
H
H
acac

2-208Y
Rh
0
2
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

2-209
Rh
1
2
Ph
H
CF₃
H
H
H
H
H
H
H
pic

2-209X
Rh
1
2
Ph
H
CF₃
H
H
H
H
H
H
H
acac

2-209Y
Rh
0
2
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

2-210
Rh
1
2
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

2-210X
Rh
1
2
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

2-210Y
Rh
0
2
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

2-211
Rh
1
2
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

2-211X
Rh
1
2
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

2-211Y
Rh
0
2
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

2-212
Rh
1
2
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

2-212X
Rh
1
2
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

2-212Y
Rh
0
2
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

2-213
Rh
1
2
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

2-213X
Rh
1
2
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

2-213Y
Rh
0
2
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

2-214
Rh
1
2
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

2-214X
Rh
1
2
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

2-214Y
Rh
0
2
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

2-215
Rh
1
2
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

2-215X
Rh
1
2
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

2-215Y
Rh
0
2
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

2-216
Rh
1
2
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

2-216X
Rh
1
2
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

2-216Y
Rh
0
2
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

2-217
Rh
1
2
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

2-217X
Rh
1
2
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

2-217Y
Rh
0
2
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

2-218
Rh
1
2
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

2-218X
Rh
1
2
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

2-218Y
Rh
0
2
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

2-219
Rh
1
2
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

2-219X
Rh
1
2
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

2-219Y
Rh
0
2
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

2-220
Rh
1
2
Ph
H
F
H
F
H
H
H
CH₃
H
pic

2-220X
Rh
1
2
Ph
H
F
H
F
H
H
H
CH₃
H
acac

2-220Y
Rh
0
2
Ph
H
F
H
F
H
H
H
CH₃
H
—
—

2-221
Rh
1
2
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
pic

2-221X
Rh
1
2
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
acac

2-221Y
Rh
0
2
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
—
—

2-222
Rh
1
2
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

2-222X
Rh
1
2
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

2-222Y
Rh
0
2
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

2-223
Rh
1
2
Ph
H
H
Si(CH₃₎₃
H
H
H
H
H
H
pic

2-223X
Rh
1
2
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

2-223Y
Rh
0
2
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2-224
Rh
1
2
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

2-224X
Rh
1
2
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

2-224Y
Rh
0
2
Ph
H
H
H
Si(CH₃₎₃
H
H
H
H
H
—
—

2-225
Rh
1
2
Ph
H
F
H
Si(CH₃₎₃
H
H
H
H
H
pic

2-225X
Rh
1
2
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

2-225Y
Rh
0
2
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

2-226
Rh
1
2
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

2-226X
Rh
1
2
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

2-226Y
Rh
0
2
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

2-227
Rh
1
2
Ph
H
Si(CH₃₎₃
H
F
H
H
H
H
H
pic

2-227X
Rh
1
2
Ph
H
Si(CH₃₎₃
H
F
H
H
H
H
H
acac

2-227Y
Rh
0
2
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

2-228
Rh
1
2
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

2-228X
Rh
1
2
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

2-228Y
Rh
0
2
Ph
H
Si(CH₃₎₃
H
CF₃
H
H
H
H
H
—
—

2-229
Rh
1
2
Ph
Si(CH₃₎₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2-229X
Rh
1
2
Ph
Si(CH₃)₃
H
Si(CH₃₎₃
H
H
H
H
H
H
acac

2-229Y
Rh
0
2
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2-230
Rh
1
2
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

2-230X
Rh
1
2
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

2-230Y
Rh
0
2
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

2-231
Rh
1
2
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

2-231X
Rh
1
2
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

2-231Y
Rh
0
2
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

2-232
Rh
1
2
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

2-232X
Rh
1
2
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

2-232Y
Rh
0
2
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

2-233
Rh
1
2
Ph
H
H
BL
H
H
H
H
H
pic

2-233X
Rh
1
2
Ph
H
H
BL
H
H
H
H
H
acac

2-233Y
Rh
0
2
Ph
H
H
BL
H
H
H
H
H
—
—

2-234
Rh
1
2
Ph
H
BL
H
H
H
H
H
H
pic

2-234X
Rh
1
2
Ph
H
BL
H
H
H
H
H
H
acac

2-234Y
Rh
0
2
Ph
H
BL
H
H
H
H
H
H
—
—

2-235
Rh
1
2
Ph
H
H
PL
H
H
H
H
H
pic

2-235X
Rh
1
2
Ph
H
H
PL
H
H
H
H
H
acac

2-235Y
Rh
0
2
Ph
H
H
PL
H
H
H
H
H
—
—

2-236
Rh
1
2
Ph
H
PL
H
H
H
H
H
H
pic

2-236X
Rh
1
2
Ph
H
PL
H
H
H
H
H
H
acac

2-236Y
Rh
0
2
Ph
H
PL
H
H
H
H
H
H
—
—

2-237
Rh
1
2
Ph
H
H
MEE1
H
H
H
H
H
pic

2-237X
Rh
1
2
Ph
H
H
MEE1
H
H
H
H
H
acac

2-237Y
Rh
0
2
Ph
H
H
MEE1
H
H
H
H
H
—
—

2-238
Rh
1
2
Ph
H
MEE1
H
H
H
H
H
H
pic

2-238X
Rh
1
2
Ph
H
MEE1
H
H
H
H
H
H
acac

2-238Y
Rh
0
2
Ph
H
MEE1
H
H
H
H
H
H
—
—

2-239
Rh
1
2
Ph
H
H
MEE2
H
H
H
H
H
pic

2-239X
Rh
1
2
Ph
H
H
MEE2
H
H
H
H
H
acac

2-239Y
Rh
0
2
Ph
H
H
MEE2
H
H
H
H
H
—
—

2-240
Rh
1
2
Ph
H
MEE2
H
H
H
H
H
H
pic

2-240X
Rh
1
2
Ph
H
MEE2
H
H
H
H
H
H
acac

2-240Y
Rh
0
2
Ph
H
MEE2
H
H
H
H
H
H
—
—

2-241
Rh
1
2
Ph
H
H
PA1
H
H
H
H
H
pic

2-241X
Rh
1
2
Ph
H
H
PA1
H
H
H
H
H
acac

2-241Y
Rh
0
2
Ph
H
H
PA1
H
H
H
H
H
—
—

2-242
Rh
1
2
Ph
H
PA1
H
H
H
H
H
H
pic

2-242X
Rh
1
2
Ph
H
PA1
H
H
H
H
H
H
acac

2-242Y
Rh
0
2
Ph
H
PA1
H
H
H
H
H
H
—
—

2-243
Rh
1
2
Ph
H
H
PA2
H
H
H
H
H
pic

2-243X
Rh
1
2
Ph
H
H
PA2
H
H
H
H
H
acac

2-243Y
Rh
0
2
Ph
H
H
PA2
H
H
H
H
H
—
—

2-244
Rh
1
2
Ph
H
PA2
H
H
H
H
H
H
pic

2-244X
Rh
1
2
Ph
H
PA2
H
H
H
H
H
H
acac

2-244Y
Rh
0
2
Ph
H
PA2
H
H
H
H
H
H
—
—

2-245
Rh
1
2
Ph
H
H
EA1
H
H
H
H
H
pic

2-245X
Rh
1
2
Ph
H
H
EA1
H
H
H
H
H
acac

2-245Y
Rh
0
2
Ph
H
H
EA1
H
H
H
H
H
—
—

2-246
Rh
1
2
Ph
H
EA2
H
H
H
H
H
H
pic

2-246X
Rh
1
2
Ph
H
EA2
H
H
H
H
H
H
acac

2-246Y
Rh
0
2
Ph
H
EA2
H
H
H
H
H
H
—
—

2-247
Rh
1
2
Ph
H
H
ME
H
H
H
H
H
pic

2-247X
Rh
1
2
Ph
H
H
ME
H
H
H
H
H
acac

2-247Y
Rh
0
2
Ph
H
H
ME
H
H
H
H
H
—
—

2-248
Rh
1
2
Ph
H
ME
H
H
H
H
H
H
pic

2-248X
Rh
1
2
Ph
H
ME
H
H
H
H
H
H
acac

2-248Y
Rh
0
2
Ph
H
ME
H
H
H
H
H
H
—
—

2-249
Rh
1
2
Ph
H
H
AT
H
H
H
H
H
pic

2-249X
Rh
1
2
Ph
H
H
AT
H
H
H
H
H
acac

2-249Y
Rh
0
2
Ph
H
H
AT
H
H
H
H
H
—
—

2-250
Rh
1
2
Ph
H
AT
H
H
H
H
H
H
pic

2-250X
Rh
1
2
Ph
H
AT
H
H
H
H
H
H
acac

2-250Y
Rh
0
2
Ph
H
AT
H
H
H
H
H
H
—
—

2-251
Rh
1
2
Ph
H
H
MES1
H
H
H
H
H
pic

2-251X
Rh
1
2
Ph
H
H
MES1
H
H
H
H
H
acac

2-251Y
Rh
0
2
Ph
H
H
MES1
H
H
H
H
H
—
—

2-252
Rh
1
2
Ph
H
MES1
H
H
H
H
H
H
pic

2-252X
Rh
1
2
Ph
H
MES1
H
H
H
H
H
H
acac

2-252Y
Rh
0
2
Ph
H
MES1
H
H
H
H
H
H
—
—

2-253
Rh
1
2
Ph
H
H
MES2
H
H
H
H
H
pic

2-253X
Rh
1
2
Ph
H
H
MES2
H
H
H
H
H
acac

2-253Y
Rh
0
2
Ph
H
H
MES2
H
H
H
H
H
—
—

2-254
Rh
1
2
Ph
H
MES2
H
H
H
H
H
H
pic

2-254X
Rh
1
2
Ph
H
MES2
H
H
H
H
H
H
acac

2-254Y
Rh
0
2
Ph
H
MES2
H
H
H
H
H
H
—
—

2-255
Rh
1
2
Ph
H
H
PS1
H
H
H
H
H
pic

2-255X
Rh
1
2
Ph
H
H
PS1
H
H
H
H
H
acac

2-255Y
Rh
0
2
Ph
H
H
PS1
H
H
H
H
H
—
—

2-256
Rh
1
2
Ph
H
PS1
H
H
H
H
H
H
pic

2-256X
Rh
1
2
Ph
H
PS1
H
H
H
H
H
H
acac

2-256Y
Rh
0
2
Ph
H
PS1
H
H
H
H
H
H
—
—

2-257
Rh
1
2
Ph
H
H
PS2
H
H
H
H
H
pic

2-257X
Rh
1
2
Ph
H
H
PS2
H
H
H
H
H
acac

2-257Y
Rh
0
2
Ph
H
H
PS2
H
H
H
H
H
—
—

2-258
Rh
1
2
Ph
H
PS2
H
H
H
H
H
H
pic

2-258X
Rh
1
2
Ph
H
PS2
H
H
H
H
H
H
acac

2-258Y
Rh
0
2
Ph
H
PS2
H
H
H
H
H
H
—
—

2-259
Rh
1
2
Ph
H
H
BAL1
H
H
H
H
H
pic

2-259X
Rh
1
2
Ph
H
H
BAL1
H
H
H
H
H
acac

2-259Y
Rh
0
2
Ph
H
H
BAL1
H
H
H
H
H
—
—

2-260
Rh
1
2
Ph
H
BAL1
H
H
H
H
H
H
pic

2-260X
Rh
1
2
Ph
H
BAL1
H
H
H
H
H
H
acac

2-260Y
Rh
0
2
Ph
H
BAL1
H
H
H
H
H
H
—
—

2-261
Rh
1
2
Ph
H
H
BAL2
H
H
H
H
H
pic

2-261X
Rh
1
2
Ph
H
H
BAL2
H
H
H
H
H
acac

2-261Y
Rh
0
2
Ph
H
H
BAL2
H
H
H
H
H
—
—

2-262
Rh
1
2
Ph
H
BAL2
H
H
H
H
H
H
pic

2-262X
Rh
1
2
Ph
H
BAL2
H
H
H
H
H
H
acac

2-262Y
Rh
0
2
Ph
H
BAL2
H
H
H
H
H
H
—
—

2-263
Rh
1
2
Ph
H
H
MEK1
H
H
H
H
H
pic

2-263X
Rh
1
2
Ph
H
H
MEK1
H
H
H
H
H
acac

2-263Y
Rh
0
2
Ph
H
H
MEK1
H
H
H
H
H
—
—

2-264
Rh
1
2
Ph
H
MEK1
H
H
H
H
H
H
pic

2-264X
Rh
1
2
Ph
H
MEK1
H
H
H
H
H
H
acac

2-264Y
Rh
0
2
Ph
H
MEK1
H
H
H
H
H
H
—
—

2-265
Rh
1
2
Ph
H
H
MEK2
H
H
H
H
H
pic

2-265X
Rh
1
2
Ph
H
H
MEK2
H
H
H
H
H
acac

2-265Y
Rh
0
2
Ph
H
H
MEK2
H
H
H
H
H
—
—

2-266
Rh
1
2
Ph
H
MEK2
H
H
H
H
H
H
pic

2-266X
Rh
1
2
Ph
H
MEK2
H
H
H
H
H
H
acac

2-266Y
Rh
0
2
Ph
H
MEK2
H
H
H
H
H
H
—
—

2-267
Rh
1
2
Ph
H
H
PAL1
H
H
H
H
H
pic

2-267X
Rh
1
2
Ph
H
H
PAL1
H
H
H
H
H
acac

2-267Y
Rh
0
2
Ph
H
H
PAL1
H
H
H
H
H
—
—

2-268
Rh
1
2
Ph
H
PAL1
H
H
H
H
H
H
pic

2-268X
Rh
1
2
Ph
H
PAL1
H
H
H
H
H
H
acac

2-268Y
Rh
0
2
Ph
H
PAL1
H
H
H
H
H
H
—
—

2-269
Rh
1
2
Ph
H
H
PAL2
H
H
H
H
H
pic

2-269X
Rh
1
2
Ph
H
H
PAL2
H
H
H
H
H
acac

2-269Y
Rh
0
2
Ph
H
H
PAL2
H
H
H
H
H
—
—

2-270
Rh
1
2
Ph
H
PAL2
H
H
H
H
H
H
pic

2-270X
Rh
1
2
Ph
H
PAL2
H
H
H
H
H
H
acac

2-270Y
Rh
0
2
Ph
H
PAL2
H
H
H
H
H
H
—
—

2-271
Rh
1
2
Ph
H
H
MMK
H
H
H
H
M
pic

2-271X
Rh
1
2
Ph
H
H
MMK
H
H
H
H
H
acac

2-271Y
Rh
0
2
Ph
H
H
MMK
H
H
H
H
H
—
—

2-272
Rh
1
2
Ph
H
MMK
H
H
H
H
H
H
pic

2-272X
Rh
1
2
Ph
H
MMK
H
H
H
H
H
H
acac

2-272Y
Rh
0
2
Ph
H
MMK
H
H
H
H
H
H
—
—

2-273
Rh
1
2
Ph
H
H
EES1
H
H
H
H
H
pic

2-273X
Rh
1
2
Ph
'H
H
EES1
H
H
H
H
H
acac

2-273Y
Rh
0
2
Ph
H
H
EES1
H
H
H
H
H
—
—

2-274
Rh
1
2
Ph
H
EES2
H
H
H
H
H
H
pic

2-274X
Rh
1
2
Ph
H
EES2
H
H
H
H
H
H
acac

2-274Y
Rh
0
2
Ph
H
EES2
H
H
H
H
H
H
—
—

2-275
Rh
1
2
Ph
H
H
PAE1
H
H
H
H
H
pic

2-275X
Rh
1
2
Ph
H
H
PAE1
H
H
H
H
H
acac

2-275Y
Rh
0
2
Ph
H
H
PAE1
H
H
H
H
H
—
—

2-276
Rh
1
2
Ph
H
PAE2
H
H
H
H
H
H
pic

2-276X
Rh
1
2
Ph
H
PAE2
H
H
H
H
H
H
acac

2-276Y
Rh
0
2
Ph
H
PAE2
H
H
H
H
H
H
—
—

2-277
Rh
1
2
Ph
H
H
AME1
H
H
H
H
H
pic

2-277X
Rh
1
2
Ph
H
H
AME1
H
H
H
H
H
acac

2-277Y
Rh
0
2
Ph
H
H
AME1
H
H
H
H
H
—
—

2-278
Rh
1
2
Ph
H
AME1
H
H
H
H
H
H
pic

2-278X
Rh
1
2
Ph
H
AME1
H
H
H
H
H
H
acac

2-278Y
Rh
0
2
Ph
H
AME1
H
H
H
H
H
H
—
—

2-279
Rh
1
2
Ph
H
H
AME2
H
H
H
H
H
pic

2-279X
Rh
1
2
Ph
H
H
AME2
H
H
H
H
H
acac

2-279Y
Rh
0
2
Ph
H
H
AME2
H
H
H
H
H
—
—

2-280
Rh
1
2
Ph
H
AME2
H
H
H
H
H
H
pic

2-280X
Rh
1
2
Ph
H
AME2
H
H
H
H
H
H
acac

2-280Y
Rh
0
2
Ph
H
AME2
H
H
H
H
H
H
—
—

2-281
Rh
1
2
Ph
H
H
EAE1
H
H
H
H
H
pic

2-281X
Rh
1
2
Ph
H
H
EAE1
H
H
H
H
H
acac

2-281Y
Rh
0
2
Ph
H
H
EAE1
H
H
H
H
H
—
—

2-282
Rh
1
2
Ph
H
EAE1
H
H
H
H
H
H
pic

2-282X
Rh
1
2
Ph
H
EAE1
H
H
H
H
H
H
acac

2-282Y
Rh
0
2
Ph
H
EAE1
H
H
H
H
H
H
—
—

2-283
Rh
1
2
Ph
H
H
EAE2
H
H
H
H
H
pic

2-283X
Rh
1
2
Ph
H
H
EAE2
H
H
H
H
H
acac

2-283Y
Rh
0
2
Ph
H
H
EAE2
H
H
H
H
H
—
—

2-284
Rh
1
2
Ph
H
EAE2
H
H
H
H
H
H
pic

2-284X
Rh
1
2
Ph
H
EAE2
H
H
H
H
H
H
acac

2-284Y
Rh
0
2
Ph
H
EAE2
H
H
H
H
H
H
—
—

2-285
Rh
1
2
Ph
H
H
AAE1
H
H
H
H
H
pic

2-285X
Rh
1
2
Ph
H
H
AAE1
H
H
H
H
H
acac

2-285Y
Rh
0
2
Ph
H
H
AAE1
H
H
H
H
H
—
—

2-286
Rh
1
2
Ph
H
AAE1
H
H
H
H
H
H
pic

2-286X
Rh
1
2
Ph
H
AAE1
H
H
H
H
H
H
acac

2-266Y
Rh
0
2
Ph
H
AAE1
H
H
H
H
H
H
—
—

2-287
Rh
1
2
Ph
H
H
AAE2
H
H
H
H
H
pic

2-287X
Rh
1
2
Ph
H
H
AAE2
H
H
H
H
H
acac

2-287Y
Rh
0
2
Ph
H
H
AAE2
H
H
H
H
H
—
—

2-288
Rh
1
2
Ph
H
AAE2
H
H
H
H
H
H
pic

2-288X
Rh
1
2
Ph
H
AAE2
H
H
H
H
H
H
acac

2-288Y
Rh
0
2
Ph
H
AAE2
H
H
H
H
H
H
—
—

2-289
Rh
1
2
Ph
H
H
PME1
H
H
H
H
H
pic

2-289X
Rh
1
2
Ph
H
H
PME1
H
H
H
H
H
acac

2-289Y
Rh
0
2
Ph
H
H
PME1
H
H
H
H
H
—
—

2-290
Rh
1
2
Ph
H
PME1
H
H
H
H
H
H
pic

2-290X
Rh
1
2
Ph
H
PME1
H
H
H
H
H
H
acac

2-290Y
Rh
0
2
Ph
H
PME1
H
H
H
H
H
H
—
—

2-291
Rh
1
2
Ph
H
H
PME2
H
H
H
H
H
pic

2-291X
Rh
1
2
Ph
H
H
PME2
H
H
H
H
H
acac

2-291Y
Rh
0
2
Ph
H
H
PME2
H
H
H
H
H
—
—

2-292
Rh
1
2
Ph
H
PME2
H
H
H
H
H
H
pic

2-292X
Rh
1
2
Ph
H
PME2
H
H
H
H
H
H
acac

2-292Y
Rh
0
2
Ph
H
PME2
H
H
H
H
H
H
—
—

2-293
Rh
1
2
Ph
H
H
MET1
H
H
H
H
H
pic

2-293X
Rh
1
2
Ph
H
H
MET1
H
H
H
H
H
acac

2-293Y
Rh
0
2
Ph
H
H
MET1
H
H
H
H
H
—
—

2-294
Rh
1
2
Ph
H
MET1
H
H
H
H
H
H
pic

2-294X
Rh
1
2
Ph
H
MET1
H
H
H
H
H
A
acac

2-294Y
Rh
0
2
Ph
H
MET1
H
H
H
H
H
H
—
—

2-295
Rh
1
2
Ph
H
H
MET2
H
H
H
H
H
pic

2-295X
Rh
1
2
Ph
H
H
MET2
H
H
H
H
H
acac

2-295Y
Rh
0
2
Ph
H
H
MET2
H
H
H
H
H
—
—

2-296
Rh
1
2
Ph
H
MET2
H
H
H
H
H
H
pic

2-296X
Rh
1
2
Ph
H
MET2
H
H
H
H
H
H
acac

2-296Y
Rh
0
2
Ph
H
MET2
H
H
H
H
H
H
—
—

2-297
Rh
1
2
Ph
H
H
EE1
H
H
H
H
H
pic

2-297X
Rh
1
2
Ph
H
H
EE1
H
H
H
H
H
acac

2-297Y
Rh
0
2
Ph
H
H
EE1
H
H
H
H
H
—
—

2-298
Rh
1
2
Ph
H
EE1
H
H
H
H
H
H
pic

2-298X
Rh
1
2
Ph
H
EE1
H
H
H
H
H
H
acac

2-298Y
Rh
0
2
Ph
H
EE1
H
H
H
H
H
H
—
—

2-299
Rh
1
2
Ph
H
H
EE2
H
H
H
H
H
pic

2-299X
Rh
1
2
Ph
H
H
EE2
H
H
H
H
H
acac

2-299Y
Rh
0
2
Ph
H
H
EE2
H
H
H
H
H
—
—

2-300
Rh
1
2
Ph
H
EE2
H
H
H
H
H
H
pic

2-300X
Rh
1
2
Ph
H
EE2
H
H
H
H
H
H
acac

2-300Y
Rh
0
2
Ph
H
EE2
H
H
H
H
H
H
—
—

2-301
Rh
1
2
Ph
H
H
MS1
H
H
H
H
H
pic

2-301X
Rh
1
2
Ph
H
H
MS1
H
H
H
H
H
acac

2-301Y
Rh
0
2
Ph
H
H
MS1
H
H
H
H
H
—
—

2-302
Rh
1
2
Ph
H
MS1
H
H
H
H
H
H
pic

2-302X
Rh
1
2
Ph
H
MS1
H
H
H
H
H
H
acac

2-302Y
Rh
0
2
Ph
H
MS1
H
H
H
H
H
H
—
—

2-303
Rh
1
2
Ph
H
H
MS2
H
H
H
H
H
pic

2-303X
Rh
1
2
Ph
H
H
MS2
H
H
H
H
H
acac

2-303Y
Rh
0
2
Ph
H
H
MS2
H
H
H
H
H
—
—

2-304
Rh
1
2
Ph
H
MS2
H
H
H
H
H
H
pic

2-304X
Rh
1
2
Ph
H
MS2
H
H
H
H
H
H
acac

2-304Y
Rh
0
2
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 17

No.
M
N
BBS
BS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3-155
Rh
1
3
Ph
H
H
H
H
H
H
H
H
H
pic

3-155X
Rh
1
3
Ph
H
H
H
H
H
H
H
H
H
acac

3-155Y
Rh
0
3
Ph
H
H
H
H
H
H
H
H
H
—
—

3-156
Rh
1
3
Ph
H
F
H
F
H
H
H
H
H
pic

3-156X
Rh
1
3
Ph
H
F
H
F
H
H
H
H
H
acac

3-156Y
Rh
0
3
Ph
H
F
H
F
H
H
H
H
H
—
—

3-157
Rh
1
3
Ph
F
H
H
F
H
H
H
H
H
pic

3-157X
Rh
1
3
Ph
F
H
H
F
H
H
H
H
H
acac

3-157Y
Rh
0
3
Ph
F
H
H
F
H
H
H
H
H
—
—

3-158
Rh
1
3
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

3-158X
Rh
1
3
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

3-158Y
Rh
0
3
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

3-159
Rh
1
3
Ph
H
F
CF₃
H
H
H
H
H
H
pic

3-159X
Rh
1
3
Ph
H
F
CF₃
H
H
H
H
H
H
acac

3-159Y
Rh
0
3
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

3-160
Rh
1
3
Ph
F
H
CF₃
H
H
H
H
H
H
pic

3-160X
Rh
1
3
Ph
F
H
CF₃
H
H
H
H
H
H
acac

3-160Y
Rh
0
3
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

3-161
Rh
1
3
Ph
F
F
F
F
H
H
H
H
H
pic

3-161X
Rh
1
3
Ph
F
F
F
F
H
H
H
H
H
acac

3-161Y
Rh
0
3
Ph
F
F
F
F
H
H
H
H
H
—
—

3-162
Rh
1
3
Ph
H
F
H
CH₃
H
H
H
H
H
pic

3-162X
Rh
1
3
Ph
H
F
H
CH₃
H
H
H
H
H
acac

3-162Y
Rh
0
3
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

3-163
Rh
1
3
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

3-163X
Rh
1
3
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

3-163Y
Rh
0
3
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

3-164
Rh
1
3
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

3-164X
Rh
1
3
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

3-164Y
Rh
0
3
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

3-165
Rh
1
3
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

3-165X
Rh
1
3
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

3-165Y
Rh
0
3
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

3-166
Rh
1
3
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

3-166X
Rh
1
3
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

3-166Y
Rh
0
3
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

3-167
Rh
1
3
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

3-167X
Rh
1
3
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

3-167Y
Rh
0
3
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

3-168
Rh
1
3
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

3-168X
Rh
1
3
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

3-168Y
Rh
0
3
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

3-169
Rh
1
3
Ph
H
H
NO₂
H
H
H
H
H
H
pic

3-169X
Rh
1
3
Ph
H
H
NO₂
H
H
H
H
H
H
acac

3-169Y
Rh
0
3
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

3-170
Rh
1
3
Ph
F
H
NO₂
H
H
H
H
H
H
pic

3-170X
Rh
1
3
Ph
F
H
NO₂
H
H
H
H
H
H
acac

3-170Y
Rh
0
3
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

3-171
Rh
1
3
Ph
F
H
NO₂
F
H
H
H
H
H
pic

3-171X
Rh
1
3
Ph
F
H
NO₂
F
H
H
H
H
H
acac

3-171Y
Rh
0
3
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

3-172
Rh
1
3
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

3-172X
Rh
1
3
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

3-172Y
Rh
0
3
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

3-173
Rh
1
3
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

3-173X
Rh
1
3
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

3-173Y
Rh
0
3
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

3-174
Rh
1
3
Ph
H
H
CF₃
H
H
H
H
H
H
pic

3-174X
Rh
1
3
Ph
H
H
CF₃
H
H
H
H
H
H
acac

3-174Y
Rh
0
3
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

3-175
Rh
1
3
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

3-175X
Rh
1
3
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

3-175Y
Rh
0
3
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

3-176
Rh
1
3
Ph
H
NO₂
H
H
H
H
H
H
H
pic

3-176X
Rh
1
3
Ph
H
NO₂
H
H
H
H
H
H
H
acac

3-176Y
Rh
0
3
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

3-177
Rh
1
3
Ph
H
CF₃
H
H
H
H
H
H
H
pic

3-177X
Rh
1
3
Ph
H
CF₃
H
H
H
H
H
H
H
acac

3-177Y
Rh
0
3
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

3-178
Rh
1
3
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

3-178X
Rh
1
3
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

3-178Y
Rh
0
3
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

3-179
Rh
1
3
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

3-179X
Rh
1
3
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

3-179Y
Rh
0
3
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

3-180
Rh
1
3
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

3-180X
Rh
1
3
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

3-180Y
Rh
0
3
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

3-181
Rh
1
3
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

3-181X
Rh
1
3
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

3-181Y
Rh
0
3
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

3-182
Rh
1
3
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

3-182X
Rh
1
3
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

3-182Y
Rh
0
3
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

3-183
Rh
1
3
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

3-183X
Rh
1
3
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

3-183Y
Rh
0
3
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

3-184
Rh
1
3
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

3-184X
Rh
1
3
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

3-184Y
Rh
0
3
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

3-185
Rh
1
3
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

3-185X
Rh
1
3
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

3-185Y
Rh
0
3
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

3-186
Rh
1
3
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

3-186X
Rh
1
3
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

3-186Y
Rh
0
3
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

3-187
Rh
1
3
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

3-187X
Rh
1
3
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

3-187Y
Rh
0
3
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

3-188
Rh
1
3
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

3-188X
Rh
1
3
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

3-188Y
Rh
0
3
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

3-189
Rh
1
3
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3-189X
Rh
1
3
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3-189Y
Rh
0
3
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3-190
Rh
1
3
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

3-190X
Rh
1
3
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

3-190Y
Rh
0
3
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

3-191
Rh
1
3
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

3-191X
Rh
1
3
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

3-191Y
Rh
0
3
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

3-192
Rh
1
3
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

3-192X
Rh
1
3
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

3-192Y
Rh
0
3
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

3-193
Rh
1
3
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

3-193X
Rh
1
3
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

3-193Y
Rh
0
3
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

3-194
Rh
1
3
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

3-194X
Rh
1
3
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

3-194Y
Rh
0
3
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

3-195
Rh
1
3
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3-195X
Rh
1
3
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3-195Y
Rh
0
3
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3-196
Rh
1
3
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

3-196X
Rh
1
3
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

3-196Y
Rh
0
3
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

3-197
Rh
1
3
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

3-197X
Rh
1
3
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

3-197Y
Rh
0
3
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

3-198
Rh
1
3
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

3-198X
Rh
1
3
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

3-198Y
Rh
0
3
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

3-199
Rh
1
3
Ph
H
H
BL
H
H
H
H
H
pic

3-199X
Rh
1
3
Ph
H
H
BL
H
H
H
H
H
acac

3-199Y
Rh
0
3
Ph
H
H
BL
H
H
H
H
H
—
—

3-200
Rh
1
3
Ph
H
BL
H
H
H
H
H
H
pic

3-200X
Rh
1
3
Ph
H
BL
H
H
H
H
H
H
acac

3-200Y
Rh
0
3
Ph
H
BL
H
H
H
H
H
H
—
—

3-201
Rh
1
3
Ph
H
H
PL
H
H
H
H
H
pic

3-201X
Rh
1
3
Ph
H
H
PL
H
H
H
H
H
acac

3-201Y
Rh
0
3
Ph
H
H
PL
H
H
H
H
H
—
—

3-202
Rh
1
3
Ph
H
PL
H
H
H
H
H
H
pic

3-202X
Rh
1
3
Ph
H
PL
H
H
H
H
H
H
acac

3-202Y
Rh
0
3
Ph
H
PL
H
H
H
H
H
H
—
—

3-203
Rh
1
3
Ph
H
H
MEE1
H
H
H
H
H
pic

3-203X
Rh
1
3
Ph
H
H
MEE1
H
H
H
H
H
acac

3-203Y
Rh
0
3
Ph
H
H
MEE1
H
H
H
H
H
—
—

3-204
Rh
1
3
Ph
H
MEE1
H
H
H
H
H
H
pic

3-204X
Rh
1
3
Ph
H
MEE1
H
H
H
H
H
H
acac

3-204Y
Rh
0
3
Ph
H
MEE1
H
H
H
H
H
H
—
—

3-205
Rh
1
3
Ph
H
H
MEE2
H
H
H
H
H
pic

3-205X
Rh
1
3
Ph
H
H
MEE2
H
H
H
H
H
acac

3-205Y
Rh
0
3
Ph
H
H
MEE2
H
H
H
H
H
—
—

3-206
Rh
1
3
Ph
H
MEE2
H
H
H
H
H
H
pic

3-206X
Rh
1
3
Ph
H
MEE2
H
H
H
H
H
H
acac

3-206Y
Rh
0
3
Ph
H
MEE2
H
H
H
H
H
H
—
—

3-207
Rh
1
3
Ph
H
H
PA1
H
H
H
H
H
pic

3-207X
Rh
1
3
Ph
H
H
PA1
H
H
H
H
H
acac

3-207Y
Rh
0
3
Ph
H
H
PA1
H
H
H
H
H
—
—

3-208
Rh
1
3
Ph
H
PA1
H
H
H
H
H
H
pic

3-208X
Rh
1
3
Ph
H
PA1
H
H
H
H
H
H
acac

3-208Y
Rh
0
3
Ph
H
PA1
H
H
H
H
H
H
—
—

3-209
Rh
1
3
Ph
H
H
PA2
H
H
H
H
H
pic

3-209X
Rh
1
3
Ph
H
H
PA2
H
H
H
H
H
acac

3-209Y
Rh
0
3
Ph
H
H
PA2
H
H
H
H
H
—
—

3-210
Rh
1
3
Ph
H
PA2
H
H
H
H
H
H
pic

3-210X
Rh
1
3
Ph
H
PA2
H
H
H
H
H
H
acac

3-210Y
Rh
0
3
Ph
H
PA2
H
H
H
H
H
H
—
—

3-211
Rh
1
3
Ph
H
H
EA1
H
H
H
H
H
pic

3-211X
Rh
1
3
Ph
H
H
EA1
H
H
H
H
H
acac

3-211 Y
Rh
0
3
Ph
H
H
EA1
H
H
H
H
H
—
—

3-212
Rh
1
3
Ph
H
EA2
H
H
H
H
H
H
pic

3-212X
Rh
1
3
Ph
H
EA2
H
H
H
H
H
H
acac

3-212Y
Rh
0
3
Ph
H
EA2
H
H
H
H
H
H
—
—

3-213
Rh
1
3
Ph
H
H
ME
H
H
H
H
H
pic

3-213X
Rh
1
3
Ph
H
H
ME
H
H
H
H
H
acac

3-213Y
Rh
0
3
Ph
H
H
ME
H
H
H
H
H
—
—

3-214
Rh
1
3
Ph
H
ME
H
H
H
H
H
H
pic

3-214X
Rh
1
3
Ph
H
ME
H
H
H
H
H
H
acac

3-214Y
Rh
0
3
Ph
H
ME
H
H
H
H
H
H
—
—

3-215
Rh
1
3
Ph
H
H
AT
H
H
H
H
H
pic

3-215X
Rh
1
3
Ph
H
H
AT
H
H
H
H
H
acac

3-215Y
Rh
0
3
Ph
H
H
AT
H
H
H
H
H
—
—

3-216
Rh
1
3
Ph
H
AT
H
H
H
H
H
H
pic

3-216X
Rh
1
3
Ph
H
AT
H
H
H
H
H
H
acac

3-216Y
Rh
0
3
Ph
H
AT
H
H
H
H
H
H
—
—

3-217
Rh
1
3
Ph
H
H
MES1
H
H
H
H
H
pic

3-217X
Rh
1
3
Ph
H
H
MES1
H
H
H
H
H
acac

3-217Y
Rh
0
3
Ph
H
H
MES1
H
H
H
H
H
—
—

3-218
Rh
1
3
Ph
H
MES1
H
H
H
H
H
H
pic

3-218X
Rh
1
3
Ph
H
MES1
H
H
H
H
H
H
acac

3-218Y
Rh
0
3
Ph
H
MES1
H
H
H
H
H
H
—
—

3-219
Rh
1
3
Ph
H
H
MES2
H
H
H
H
H
pic

3-219X
Rh
1
3
Ph
H
H
MES2
H
H
H
H
H
acac

3-219Y
Rh
0
3
Ph
H
H
MES2
H
H
H
H
H
—
—

3-220
Rh
1
3
Ph
H
MES2
H
H
H
H
H
H
pic

3-220X
Rh
1
3
Ph
H
MES2
H
H
H
H
H
H
acac

3-220Y
Rh
0
3
Ph
H
MES2
H
H
H
H
H
H
—
—

3-221
Rh
1
3
Ph
H
H
PS1
H
H
H
H
H
pic

3-221X
Rh
1
3
Ph
H
H
PS1
H
H
H
H
H
acac

3-221Y
Rh
0
3
Ph
H
H
PS1
H
H
H
H
H
—
—

3-222
Rh
1
3
Ph
H
PS1
H
H
H
H
H
H
pic

3-222X
Rh
1
3
Ph
H
PS1
H
H
H
H
H
H
acac

3-222Y
Rh
0
3
Ph
H
PS1
H
H
H
H
H
H
—
—

3-223
Rh
1
3
Ph
H
H
PS2
H
H
H
H
H
pic

3-223X
Rh
1
3
Ph
H
H
PS2
H
H
H
H
H
acac

3-223Y
Rh
0
3
Ph
H
H
PS2
H
H
H
H
H
—
—

3-224
Rh
1
3
Ph
H
PS2
H
H
H
H
H
H
pic

3-224X
Rh
1
3
Ph
H
PS2
H
H
H
H
H
H
acac

3-224Y
Rh
0
3
Ph
H
PS2
H
H
H
H
H
H
—
—

3-225
Rh
1
3
Ph
H
H
BAL1
H
H
H
H
H
pic

3-225X
Rh
1
3
Ph
H
H
BAL1
H
H
H
H
H
acac

3-225Y
Rh
0
3
Ph
H
H
BAL1
H
H
H
H
H
—
—

3-226
Rh
1
3
Ph
H
BAL1
H
H
H
H
H
H
pic

3-226X
Rh
1
3
Ph
H
BAL1
H
H
H
H
H
H
acac

3-226Y
Rh
0
3
Ph
H
BAL1
H
H
H
H
H
H
—
—

3-227
Rh
1
3
Ph
H
H
BAL2
H
H
H
H
H
pic

3-227X
Rh
1
3
Ph
H
H
BAL2
H
H
H
H
H
acac

3-227Y
Rh
0
3
Ph
H
H
BAL2
H
H
H
H
H
—
—

3-228
Rh
1
3
Ph
H
BAL2
H
H
H
H
H
H
pic

3-228X
Rh
1
3
Ph
H
BAL2
H
H
H
H
H
H
acac

3-228Y
Rh
0
3
Ph
H
BAL2
H
H
H
H
H
H
—
—

3-229
Rh
1
3
Ph
H
H
MEK1
H
H
H
H
H
pic

3-229X
Rh
1
3
Ph
H
H
MEK1
H
H
H
H
H
acac

3-229Y
Rh
0
3
Ph
H
H
MEK1
H
H
H
H
H
—
—

3-230
Rh
1
3
Ph
H
MEK1
H
H
H
H
H
H
pic

3-230X
Rh
1
3
Ph
H
MEK1
H
H
H
H
H
H
acac

3-230Y
Rh
0
3
Ph
H
MEK1
H
H
H
H
H
H
—
—

3-231
Rh
1
3
Ph
H
H
MEK2
H
H
H
H
H
pic

3-231X
Rh
1
3
Ph
H
H
MEK2
H
H
H
H
H
acac

3-231Y
Rh
0
3
Ph
H
H
MEK2
H
H
H
H
H
—
—

3-232
Rh
1
3
Ph
H
MEK2
H
H
H
H
H
H
pic

3-232X
Rh
1
3
Ph
H
MEK2
H
H
H
H
H
H
acac

3-232Y
Rh
0
3
Ph
H
MEK2
H
H
H
H
H
H
—
—

3-233
Rh
1
3
Ph
H
H
PAL1
H
H
H
H
H
pic

3-233X
Rh
1
3
Ph
H
H
PAL1
H
H
H
H
H
acac

3-233Y
Rh
0
3
Ph
H
H
PAL1
H
H
H
H
H
—
—

3-234
Rh
1
3
Ph
H
PAL1
H
H
H
H
H
H
pic

3-234X
Rh
1
3
Ph
H
PAL1
H
H
H
H
H
H
acac

3-234Y
Rh
0
3
Ph
H
PAL1
H
H
H
H
H
H
—
—

3-235
Rh
1
3
Ph
H
H
PAL2
H
H
H
H
H
pic

3-235X
Rh
1
3
Ph
H
H
PAL2
H
H
H
H
H
acac

3-235Y
Rh
0
3
Ph
H
H
PAL2
H
H
H
H
H
—
—

3-236
Rh
1
3
Ph
H
PAL2
H
H
H
H
H
H
pic

3-236X
Rh
1
3
Ph
H
PAL2
H
H
H
H
H
H
acac

3-236Y
Rh
0
3
Ph
H
PAL2
H
H
H
H
H
H
—
—

3-237
Rh
1
3
Ph
H
H
MMK
H
H
H
H
H
pic

3-237X
Rh
1
3
Ph
H
H
MMK
H
H
H
H
H
acac

3-237Y
Rh
0
3
Ph
H
H
MMK
H
H
H
H
H
—
—

3-238
Rh
1
3
Ph
H
MMK
H
H
H
H
H
H
pic

3-238X
Rh
1
3
Ph
H
MMK
H
H
H
H
H
H
acac

3-238Y
Rh
0
3
Ph
H
MMK
H
H
H
H
H
H
—
—

3-239
Rh
1
3
Ph
H
H
EES1
H
H
H
H
H
pic

3-239X
Rh
1
3
Ph
H
H
EES1
H
H
H
H
H
acac

3-239Y
Rh
0
3
Ph
H
H
EES1
H
H
H
H
H
—
—

3-240
Rh
1
3
Ph
H
EES2
H
H
H
H
H
H
pic

3-240X
Rh
1
3
Ph
H
EES2
H
H
H
H
H
H
acac

3-240Y
Rh
0
3
Ph
H
EES2
H
H
H
H
H
H
—
—

3-241
Rh
1
3
Ph
H
H
PAE1
H
H
H
H
H
pic

3-241X
Rh
1
3
Ph
H
H
PAE1
H
H
H
H
H
acac

3-241Y
Rh
0
3
Ph
H
H
PAE1
H
H
H
H
H
—
—

3-242
Rh
1
3
Ph
H
PAE2
H
H
H
H
H
H
pic

3-242X
Rh
1
3
Ph
H
PAE2
H
H
H
H
H
H
acac

3-242Y
Rh
0
3
Ph
H
PAE2
H
H
H
H
H
H
—
—

3-243
Rh
1
3
Ph
H
H
AME1
H
H
H
H
H
pic

3-243X
Rh
1
3
Ph
H
H
AME1
H
H
H
H
H
acac

3-243Y
Rh
0
3
Ph
H
H
AME1
H
H
H
H
H
—
—

3-244
Rh
1
3
Ph
H
AME1
H
H
H
H
H
H
pic

3-244X
Rh
1
3
Ph
H
AME1
H
H
H
H
H
H
acac

3-244Y
Rh
0
3
Ph
H
AME1
H
H
H
H
H
H
—
—

3-245
Rh
1
3
Ph
H
H
AME2
H
H
H
H
H
pic

3-245X
Rh
1
3
Ph
H
H
AME2
H
H
H
H
H
acac

3-245Y
Rh
0
3
Ph
H
H
AME2
H
H
H
H
H
—
—

3-246
Rh
1
3
Ph
H
AME2
H
H
H
H
H
H
pic

3-246X
Rh
1
3
Ph
H
AME2
H
H
H
H
H
H
acac

3-246Y
Rh
0
3
Ph
H
AME2
H
H
H
H
H
H
—
—

3-247
Rh
1
3
Ph
H
H
EAE1
H
H
H
H
H
pic

3-247X
Rh
1
3
Ph
H
H
EAE1
H
H
H
H
H
acac

3-247Y
Rh
0
3
Ph
H
H
EAE1
H
H
H
H
H
—
—

3-248
Rh
1
3
Ph
H
EAE1
H
H
H
H
H
H
pic

3-248X
Rh
1
3
Ph
H
EAE1
H
H
H
H
H
H
acac

3-248Y
Rh
0
3
Ph
H
EAE1
H
H
H
H
H
H
—
—

3-249
Rh
1
3
Ph
H
H
EAE2
H
H
H
H
H
pic

3-249X
Rh
1
3
Ph
H
H
EAE2
H
H
H
H
H
acac

3-249Y
Rh
0
3
Ph
H
H
EAE2
H
H
H
H
H
—
—

3-250
Rh
1
3
Ph
H
EAE2
H
H
H
H
H
H
pic

3-250X
Rh
1
3
Ph
H
EAE2
H
H
H
H
H
H
acac

3-250Y
Rh
0
3
Ph
H
EAE2
H
H
H
H
H
H
—
—

3-251
Rh
1
3
Ph
H
H
AAE1
H
H
H
H
H
pic

3-251X
Rh
1
3
Ph
H
H
AAE1
H
H
H
H
H
acac

3-251Y
Rh
0
3
Ph
H
H
AAE1
H
H
H
H
H
—
—

3-252
Rh
1
3
Ph
H
AAE1
H
H
H
H
H
H
pic

3-252X
Rh
1
3
Ph
H
AAE1
H
H
H
H
H
H
acac

3-252Y
Rh
0
3
Ph
H
AAE1
H
H
H
H
H
H
—
—

3-253
Rh
1
3
Ph
H
H
AAE2
H
H
H
H
H
pic

3-253X
Rh
1
3
Ph
H
H
AAE2
H
H
H
H
H
acac

3-253Y
Rh
0
3
Ph
H
H
AAE2
H
H
H
H
H
—
—

3-254
Rh
1
3
Ph
H
AAE2
H
H
H
H
H
H
pic

3-254X
Rh
1
3
Ph
H
AAE2
H
H
H
H
H
H
acac

3-254Y
Rh
0
3
Ph
H
AAE2
H
H
H
H
H
H
—
—

3-255
Rh
1
3
Ph
H
H
PME1
H
H
H
H
H
pic

3-255X
Rh
1
3
Ph
H
H
PME1
H
H
H
H
H
acac

3-255Y
Rh
0
3
Ph
H
H
PME1
H
H
H
H
H
—
—

3-256
Rh
1
3
Ph
H
PME1
H
H
H
H
H
H
pic

3-256X
Rh
1
3
Ph
H
PME1
H
H
H
H
H
H
acac

3-256Y
Rh
0
3
Ph
H
PME1
H
H
H
H
H
H
—
—

3-257
Rh
1
3
Ph
H
H
PME2
H
H
H
H
H
pic

3-257X
Rh
1
3
Ph
H
H
PME2
H
H
H
H
H
acac

3-257Y
Rh
0
3
Ph
H
H
PME2
H
H
H
H
H
—
—

3-258
Rh
1
3
Ph
H
PME2
H
H
H
H
H
H
pic

3-258X
Rh
1
3
Ph
H
PME2
H
H
H
H
H
H
acac

3-258Y
Rh
0
3
Ph
H
PME2
H
H
H
H
H
H
—
—

3-259
Rh
1
3
Ph
H
H
MET1
H
H
H
H
H
pic

3-259X
Rh
1
3
Ph
H
H
MET1
H
H
H
H
H
acac

3-259Y
Rh
0
3
Ph
H
H
MET1
H
H
H
H
H
—
—

3-260
Rh
1
3
Ph
H
MET1
H
H
H
H
H
H
pic

3-260X
Rh
1
3
Ph
H
MET1
H
H
H
H
H
H
acac

3-260Y
Rh
0
3
Ph
H
MET1
H
H
H
H
H
H
—
—

3-261
Rh
1
3
Ph
H
H
MET2
H
H
H
H
H
pic

3-261X
Rh
1
3
Ph
H
H
MET2
H
H
H
H
H
acac

3-261Y
Rh
0
3
Ph
H
H
MET2
H
H
H
H
H
—
—

3-262
Rh
1
3
Ph
H
MET2
H
H
H
H
H
H
pic

3-262X
Rh
1
3
Ph
H
MET2
H
H
H
H
H
H
acac

3-262Y
Rh
0
3
Ph
H
MET2
H
H
H
H
H
H
—
—

3-263
Rh
1
3
Ph
H
H
EE1
H
H
H
H
H
pic

3-263X
Rh
1
3
Ph
H
H
EE1
H
H
H
H
H
acac

3-263Y
Rh
0
3
Ph
H
H
EE1
H
H
H
H
H
—
—

3-264
Rh
1
3
Ph
H
EE1
H
H
H
H
H
H
pic

3-264X
Rh
1
3
Ph
H
EE1
H
H
H
H
H
H
acac

3-264Y
Rh
0
3
Ph
H
EE1
H
H
H
H
H
H
—
—

3-265
Rh
1
3
Ph
H
H
EE2
H
H
H
H
H
pic

3-265X
Rh
1
3
Ph
H
H
EE2
H
H
H
H
H
acac

3-265Y
Rh
0
3
Ph
H
H
EE2
H
H
H
H
H
—
—

3-266
Rh
1
3
Ph
H
EE2
H
H
H
H
H
H
pic

3-266X
Rh
1
3
Ph
H
EE2
H
H
H
H
H
H
acac

3-266Y
Rh
0
3
Ph
H
EE2
H
H
H
H
H
H
—
—

3-267
Rh
1
3
Ph
H
H
MS1
H
H
H
H
H
pic

3-267X
Rh
1
3
Ph
H
H
MS1
H
H
H
H
H
acac

3-267Y
Rh
0
3
Ph
H
H
MS1
H
H
H
H
H
—
—

3-268
Rh
1
3
Ph
H
MS1
H
H
H
H
H
H
pic

3-268X
Rh
1
3
Ph
H
MS1
H
H
H
H
H
H
acac

3-268Y
Rh
0
3
Ph
H
MS1
H
H
H
H
H
H
—
—

3-269
Rh
1
3
Ph
H
H
MS2
H
H
H
H
H
pic

3-269X
Rh
1
3
Ph
H
H
MS2
H
H
H
H
H
acac

3-269Y
Rh
0
3
Ph
H
H
MS2
H
H
H
H
H
—
—

3-270
Rh
1
3
Ph
H
MS2
H
H
H
H
H
H
pic

3-270X
Rh
1
3
Ph
H
MS2
H
H
H
H
H
H
acac

3-270Y
Rh
0
3
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 18

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4-167
Rh
1
4
Ph
H
H
H
H
CH₃
H
H
H
H
pic

4-167X
Rh
1
4
Ph
H
H
H
H
CH₃
H
H
H
H
acac

4-167Y
Rh
0
4
Ph
H
H
H
H
CH₃
H
H
H
H
—
—

4-168
Rh
1
4
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

4-168X
Rh
1
4
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

4-168Y
Rh
0
4
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

4-169
Rh
1
4
Ph
H
F
H
F
CH₃
H
H
H
H
pic

4-169X
Rh
1
4
Ph
H
F
H
F
CH₃
H
H
H
H
acac

4-169Y
Rh
0
4
Ph
H
F
H
F
CH₃
H
H
H
H
—
—

4-170
Rh
1
4
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

4-170X
Rh
1
4
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

4-170Y
Rh
0
4
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

4-171
Rh
1
4
Ph
F
H
H
F
CH₃
H
H
H
H
pic

4-171X
Rh
1
4
Ph
F
H
H
F
CH₃
H
H
H
H
acac

4-171Y
Rh
0
4
Ph
F
H
H
F
CH₃
H
H
H
H
—
—

4-172
Rh
1
4
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
pic

4-172X
Rh
1
4
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
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4-172Y
Rh
0
4
Ph
F
H
H
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^tC₄H₉
H
H
H
H
—
—

4-173
Rh
1
4
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
pic

4-173X
Rh
1
4
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
acac

4-173Y
Rh
0
4
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
—
—

4-174
Rh
1
4
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

4-174X
Rh
1
4
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
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4-174Y
Rh
0
4
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4-175
Rh
1
4
Ph
H
F
CF₃
H
CH₃
H
H
H
H
pic

4-175X
Rh
1
4
Ph
H
F
CF₃
H
CH₃
H
H
H
H
acac

4-175Y
Rh
0
4
Ph
H
F
CF₃
H
CH₃
H
H
H
H
—
—

4-176
Rh
1
4
Ph
F
H
CF₃
H
CH₃
H
H
H
H
pic

4-176X
Rh
1
4
Ph
F
H
CF₃
H
CH₃
H
H
H
H
acac

4-176Y
Rh
0
4
Ph
F
H
CF₃
H
CH₃
H
H
H
H
—
—

4-177
Rh
1
4
Ph
F
F
F
F
CH₃
H
H
H
H
pic

4-177X
Rh
1
4
Ph
F
F
F
F
CH₃
H
H
H
H
acac

4-177Y
Rh
0
4
Ph
F
F
F
F
CH₃
H
H
H
H
—
—

4-178
Rh
1
4
Ph
H
F
H
CH₃
CH₃
H
H
H
H
pic

4-178X
Rh
1
4
Ph
H
F
H
CH₃
CH₃
H
H
H
H
acac

4-178Y
Rh
0
4
Ph
H
F
H
CH₃
CH₃
H
H
H
H
—
—

4-179
Rh
1
4
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
pic

4-179X
Rh
1
4
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
acac

4-179Y
Rh
0
4
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
—
—

4-180
Rh
1
4
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-180X
Rh
1
4
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-180Y
Rh
0
4
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-181
Rh
1
4
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-181X
Rh
1
4
Ph
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^tC₄H₉
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H
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4-181Y
Rh
0
4
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4-182
Rh
1
4
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
pic

4-182X
Rh
1
4
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
acac

4-182Y
Rh
0
4
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
—
—

4-183
Rh
1
4
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

4-183X
Rh
1
4
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

4-183Y
Rh
0
4
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

4-184
Rh
1
4
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-184X
Rh
1
4
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-184Y
Rh
0
4
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-185
Rh
1
4
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-185X
Rh
1
4
Ph
CF₃
H
H

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^tC₄H₉
H
H
H
H
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4-185Y
Rh
0
4
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4-186
Rh
1
4
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-186X
Rh
1
4
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-186Y
Rh
0
4
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-187
Rh
1
4
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-187X
Rh
1
4
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
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4-187Y
Rh
0
4
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4-188
Rh
1
4
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
pic

4-188X
Rh
1
4
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
acac

4-188Y
Rh
0
4
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
—
—

4-189
Rh
1
4
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
pic

4-189X
Rh
1
4
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
acac

4-189Y
Rh
0
4
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
—
—

4-190
Rh
1
4
Ph
H
H
NO₂
H
CH₃
H
H
H
H
pic

4-190X
Rh
1
4
Ph
H
H
NO₂
H
CH₃
H
H
H
H
acac

4-190Y
Rh
0
4
Ph
H
H
NO₂
H
CH₃
H
H
H
H
—
—

4-191
Rh
1
4
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
pic

4-191X
Rh
1
4
Ph
H
H
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H
H
H
H
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4-191Y
Rh
0
4
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
—
—

4-192
Rh
1
4
Ph
F
H
NO₂
H
CH₃
H
H
H
H
pic

4-192X
Rh
1
4
Ph
F
H
NO₂
H
CH₃
H
H
H
H
acac

4-192Y
Rh
0
4
Ph
F
H
NO₂
H
CH₃
H
H
H
H
—
—

4-193
Rh
1
4
Ph
F
H
NO₂
F
CH₃
H
H
H
H
pic

4-193X
Rh
1
4
Ph
F
H
NO₂
F
CH₃
H
H
H
H
acac

4-193Y
Rh
0
4
Ph
F
H
NO₂
F
CH₃
H
H
H
H
—
—

4-194
Rh
1
4
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
pic

4-194X
Rh
1
4
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
acac

4-194Y
Rh
0
4
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
—
—

4-195
Rh
1
4
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
pic

4-195X
Rh
1
4
Ph
H
NO₂
H
NO₂

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H
H
H
H
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4-195Y
Rh
0
4
Ph
H
NO₂
H
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^tC₄H₉
H
H
H
H
—
—

4-196
Rh
1
4
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
pic

4-196X
Rh
1
4
Ph
NO₂
H
H
NO₂
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H
H
H
H
acac

4-196Y
Rh
0
4
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
—
—

4-197
Rh
1
4
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
pic

4-197X
Rh
1
4
Ph
NO₂
H
H
NO₂

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H
H
H
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4-197Y
Rh
0
4
Ph
NO₂
H
H
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^tC₄H₉
H
H
H
H
—
—

4-198
Rh
1
4
Ph
H
H
CF₃
H
CH₃
H
H
H
H
pic

4-198X
Rh
1
4
Ph
H
H
CF₃
H
CH₃
H
H
H
H
acac

4-198Y
Rh
0
4
Ph
H
H
CF₃
H
CH₃
H
H
H
H
—
—

4-199
Rh
1
4
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

4-199X
Rh
1
4
Ph
H
H
CF₃
H

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H
H
H
H
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4-199Y
Rh
0
4
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4-200
Rh
1
4
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
pic

4-200X
Rh
1
4
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
acac

4-200Y
Rh
0
4
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
—
—

4-201
Rh
1
4
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
pic

4-201X
Rh
1
4
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
acac

4-201Y
Rh
0
4
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4-202
Rh
1
4
Ph
H
NO₂
H
H
CH₃
H
H
H
H
pic

4-202X
Rh
1
4
Ph
H
NO₂
H
H
CH₃
H
H
H
H
acac

4-202Y
Rh
0
4
Ph
H
NO₂
H
H
CH₃
H
H
H
H
—
—

4-203
Rh
1
4
Ph
H
CF₃
H
H
CH₃
H
H
H
H
pic

4-203X
Rh
1
4
Ph
H
CF₃
H
H
CH₃
H
H
H
H
acac

4-203Y
Rh
0
4
Ph
H
CF₃
H
H
CH₃
H
H
H
H
—
—

4-204
Rh
1
4
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
pic

4-204X
Rh
1
4
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
acac

4-204Y
Rh
0
4
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
—
—

4-205
Rh
1
4
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
pic

4-205X
Rh
1
4
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
acac

4-205Y
Rh
0
4
Ph
H
NO₂
H
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^tC₄H₉
H
H
H
H
—
—

4-206
Rh
1
4
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-206X
Rh
1
4
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-206Y
Rh
0
4
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-207
Rh
1
4
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-207X
Rh
1
4
Ph
H
NO₂
H

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^tC₄H₉
H
H
H
H
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4-207Y
Rh
0
4
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4-208
Rh
1
4
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
pic

4-208X
Rh
1
4
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
acac

4-208Y
Rh
0
4
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
—
—

4-209
Rh
1
4
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
pic

4-209X
Rh
1
4
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
acac

4-209Y
Rh
0
4
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
—
—

4-210
Rh
1
4
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
pic

4-210X
Rh
1
4
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
acac

4-210Y
Rh
0
4
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
—
—

4-211
Rh
1
4
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-211X
Rh
1
4
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-211Y
Rh
0
4
Ph
H
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H

^tC₄H₉
CH₃
H
H
H
H
—
—

4-212
Rh
1
4
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
pic

4-212X
Rh
1
4
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
acac

4-212Y
Rh
0
4
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
—
—

4-213
Rh
1
4
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
pic

4-213X
Rh
1
4
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
acac

4-213Y
Rh
0
4
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
—
—

4-214
Rh
1
4
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4-214X
Rh
1
4
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4-214Y
Rh
0
4
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4-215
Rh
1
4
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4-215X
Rh
1
4
Ph
H
H
H
Si(CH₃₎₃
CH₃
H
H
H
H
acac

4-215Y
Rh
0
4
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4-216
Rh
1
4
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4-216X
Rh
1
4
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4-216Y
Rh
0
4
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4-217
Rh
1
4
Ph
H
CF₃
H
Si(CH₃₎₃
CH₃
H
H
H
H
pic

4-217X
Rh
1
4
Ph
H
CF₃
H
Si(CH₃₎₃
CH₃
H
H
H
H
acac

4-217Y
Rh
0
4
Ph
H
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H
Si(CH₃)₃
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H
H
H
H
—
—

4-218
Rh
1
4
Ph
H
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H
Si(CH₃₎₃

^tC₄H₉
H
H
H
H
pic

4-218X
Rh
1
4
Ph
H
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H
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^tC₄H₉
H
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H
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4-218Y
Rh
0
4
Ph
H
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H
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^tC₄H₉
H
H
H
H
—
—

4-219
Rh
1
4
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
pic

4-219X
Rh
1
4
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
acac

4-219Y
Rh
0
4
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
—
—

4-220
Rh
1
4
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
pic

4-220X
Rh
1
4
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
acac

4-220Y
Rh
0
4
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
—
—

4-221
Rh
1
4
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
pic

4-221X
Rh
1
4
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
acac

4-221Y
Rh
0
4
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
—
—

4-222
Rh
1
4
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

4-222X
Rh
1
4
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

4-222Y
Rh
0
4
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

4-223
Rh
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4-223X
Rh
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4-223Y
Rh
0
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4-224
Rh
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
pic

4-224X
Rh
1
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
acac

4-224Y
Rh
0
4
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
—
—

4-225
Rh
1
4
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
pic

4-225X
Rh
1
4
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
acac

4-225Y
Rh
0
4
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
—
—

4-226
Rh
1
4
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
pic

4-226X
Rh
1
4
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
acac

4-226Y
Rh
0
4
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
—
—

4-227
Rh
1
4
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
pic

4-227X
Rh
1
4
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
acac

4-227Y
Rh
0
4
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
—
—

4-228
Rh
1
4
Ph
H
H
BL
CH₃
H
H
H
H
pic

4-228X
Rh
1
4
Ph
H
H
BL
CH₃
H
H
H
H
acac

4-228Y
Rh
0
4
Ph
H
H
BL
CH₃
H
H
H
H
—
—

4-229
Rh
1
4
Ph
H
H
BL

^tC₄H₉
H
H
H
H
pic

4-229X
Rh
1
4
Ph
H
H
BL

^tC₄H₉
H
H
H
H
acac

4-229Y
Rh
0
4
Ph
H
H
BL

^tC₄H₉
H
H
H
H
—
—

4-230
Rh
1
4
Ph
H
BL
H
CH₃
H
H
H
H
pic

4-230X
Rh
1
4
Ph
H
BL
H
CH₃
H
H
H
H
acac

4-230Y
Rh
0
4
Ph
H
BL
H
CH₃
H
H
H
H
—
—

4-231
Rh
1
4
Ph
H
BL
H

^tC₄H₉
H
H
H
H
pic

4-231X
Rh
1
4
Ph
H
BL
H

^tC₄H₉
H
H
H
H
acac

4-231Y
Rh
0
4
Ph
H
BL
H

^tC₄H₉
H
H
H
H
—
—

4-232
Rh
1
4
Ph
H
H
PL
CH₃
H
H
H
H
pic

4-232X
Rh
1
4
Ph
H
H
PL
CH₃
H
H
H
H
acac

4-232Y
Rh
0
4
Ph
H
H
PL
CH₃
H
H
H
H
—
—

4-233
Rh
1
4
Ph
H
H
PL

^tC₄H₉
H
H
H
H
pic

4-233X
Rh
1
4
Ph
H
H
PL

^tC₄H₉
H
H
H
H
acac

4-233Y
Rh
0
4
Ph
H
H
PL

^tC₄H₉
H
H
H
H
—
—

4-234
Rh
1
4
Ph
H
PL
H
CH₃
H
H
H
H
pic

4-234X
Rh
1
4
Ph
H
PL
H
CH₃
H
H
H
H
acac

4-234Y
Rh
0
4
Ph
H
PL
H
CH₃
H
H
H
H
—
—

4-235
Rh
1
4
Ph
H
PL
H

^tC₄H₉
H
H
H
H
pic

4-235X
Rh
1
4
Ph
H
PL
H

^tC₄H₉
H
H
H
H
acac

4-235Y
Rh
0
4
Ph
H
PL
H

^tC₄H₉
H
H
H
H
—
—

4-236
Rh
1
4
Ph
H
H
MEE1
CH₃
H
H
H
H
pic

4-236X
Rh
1
4
Ph
H
H
MEE1
CH₃
H
H
H
H
acac

4-236Y
Rh
0
4
Ph
H
H
MEE1
CH₃
H
H
H
H
—
—

4-237
Rh
1
4
Ph
H
MEE1
H
CH₃
H
H
H
H
pic

4-237X
Rh
1
4
Ph
H
MEE1
H
CH₃
H
H
H
H
acac

4-237Y
Rh
0
4
Ph
H
MEE1
H
CH₃
H
H
H
H
—
—

4-238
Rh
1
4
Ph
H
H
MEE2
CH₃
H
H
H
H
pic

4-238X
Rh
1
4
Ph
H
H
MEE2
CH₃
H
H
H
H
acac

4-238Y
Rh
0
4
Ph
H
H
MEE2
CH₃
H
H
H
H
—
—

4-239
Rh
1
4
Ph
H
MEE2
H
CH₃
H
H
H
H
pic

4-239X
Rh
1
4
Ph
H
MEE2
H
CH₃
H
H
H
H
acac

4-239Y
Rh
0
4
Ph
H
MEE2
H
CH₃
H
H
H
H
—
—

4-240
Rh
1
4
Ph
H
H
PA1
CH₃
H
H
H
H
pic

4-240X
Rh
1
4
Ph
H
H
PA1
CH₃
H
H
H
H
acac

4-240Y
Rh
0
4
Ph
H
H
PA1
CH₃
H
H
H
H
—
—

4-241
Rh
1
4
Ph
H
PA1
H
CH₃
H
H
H
H
pic

4-241X
Rh
1
4
Ph
H
PA1
H
CH₃
H
H
H
H
acac

4-241Y
Rh
0
4
Ph
H
PA1
H
CH₃
H
H
H
H
—
—

4-242
Rh
1
4
Ph
H
H
PA2
CH₃
H
H
H
H
pic

4-242X
Rh
1
4
Ph
H
H
PA2
CH₃
H
H
H
H
acac

4-242Y
Rh
0
4
Ph
H
H
PA2
CH₃
H
H
H
H
—
—

4-243
Rh
1
4
Ph
H
PA2
H
CH₃
H
H
H
H
pic

4-243X
Rh
1
4
Ph
H
PA2
H
CH₃
H
H
H
H
acac

4-243Y
Rh
0
4
Ph
H
PA2
H
CH₃
H
H
H
H
—
—

4-244
Rh
1
4
Ph
H
H
EA1
CH₃
H
H
H
H
pic

4-244X
Rh
1
4
Ph
H
H
EA1
CH₃
H
H
H
H
acac

4-244Y
Rh
0
4
Ph
H
H
EA1
CH₃
H
H
H
H
—
—

4-245
Rh
1
4
Ph
H
EA2
H
CH₃
H
H
H
H
pic

4-245X
Rh
1
4
Ph
H
EA2
H
CH₃
H
H
H
H
acac

4-245Y
Rh
0
4
Ph
H
EA2
H
CH₃
H
H
H
H
—
—

4-246
Rh
1
4
Ph
H
H
ME
CH₃
H
H
H
H
pic

4-246X
Rh
1
4
Ph
H
H
ME
CH₃
H
H
H
H
acac

4-246Y
Rh
0
4
Ph
H
H
ME
CH₃
H
H
H
H
—
—

4-247
Rh
1
4
Ph
H
ME
H
CH₃
H
H
H
H
pic

4-247X
Rh
1
4
Ph
H
ME
H
CH₃
H
H
H
H
acac

4-247Y
Rh
0
4
Ph
H
ME
H
CH₃
H
H
H
H
—
—

4-248
Rh
1
4
Ph
H
H
AT
CH₃
H
H
H
H
pic

4-248X
Rh
1
4
Ph
H
H
AT
CH₃
H
H
H
H
acac

4-248Y
Rh
0
4
Ph
H
H
AT
CH₃
H
H
H
H
—
—

4-249
Rh
1
4
Ph
H
AT
H
CH₃
H
H
H
H
pic

4-249X
Rh
1
4
Ph
H
AT
H
CH₃
H
H
H
H
acac

4-249Y
Rh
0
4
Ph
H
AT
H
CH₃
H
H
H
H
—
—

4-250
Rh
1
4
Ph
H
H
MES1
CH₃
H
H
H
H
pic

4-250X
Rh
1
4
Ph
H
H
MES1
CH₃
H
H
H
H
acac

4-250Y
Rh
0
4
Ph
H
H
MES1
CH₃
H
H
H
H
—
—

4-251
Rh
1
4
Ph
H
MES1
H
CH₃
H
H
H
H
pic

4-251X
Rh
1
4
Ph
H
MES1
H
CH₃
H
H
H
H
acac

4-251Y
Rh
0
4
Ph
H
MES1
H
CH₃
H
H
H
H
—
—

4-252
Rh
1
4
Ph
H
H
MES2
CH₃
H
H
H
H
pic

4-252X
Rh
1
4
Ph
H
H
MES2
CH₃
H
H
H
H
acac

4-252Y
Rh
0
4
Ph
H
H
MES2
CH₃
H
H
H
H
—
—

4-253
Rh
1
4
Ph
H
MES2
H
CH₃
H
H
H
H
pic

4-253X
Rh
1
4
Ph
H
MES2
H
CH₃
H
H
H
H
acac

4-253Y
Rh
0
4
Ph
H
MES2
H
CH₃
H
H
H
H
—
—

4-254
Rh
1
4
Ph
H
H
PS1
CH₃
H
H
H
H
pic

4-254X
Rh
1
4
Ph
H
H
PS1
CH₃
H
H
H
H
acac

4-254Y
Rh
0
4
Ph
H
H
PS1
CH₃
H
H
H
H
—
—

4-255
Rh
1
4
Ph
H
PS1
H
CH₃
H
H
H
H
pic

4-255X
Rh
1
4
Ph
H
PS1
H
CH₃
H
H
H
H
acac

4-255Y
Rh
0
4
Ph
H
PS1
H
CH₃
H
H
H
H
—
—

4-256
Rh
1
4
Ph
H
H
PS2
CH₃
H
H
H
H
pic

4-256X
Rh
1
4
Ph
H
H
PS2
CH₃
H
H
H
H
acac

4-256Y
Rh
0
4
Ph
H
H
PS2
CH₃
H
H
H
H
—
—

4-257
Rh
1
4
Ph
H
PS2
H
CH₃
H
H
H
H
pic

4-257X
Rh
1
4
Ph
H
PS2
H
CH₃
H
H
H
H
acac

4-257Y
Rh
0
4
Ph
H
PS2
H
CH₃
H
H
H
H
—
—

4-258
Rh
1
4
Ph
H
H
BAL1
CH₃
H
H
H
H
pic

4-258X
Rh
1
4
Ph
H
H
BAL1
CH₃
H
H
H
H
acac

4-258Y
Rh
0
4
Ph
H
H
BAL1
CH₃
H
H
H
H
—
—

4-259
Rh
1
4
Ph
H
BAL1
H
CH₃
H
H
H
H
pic

4-259X
Rh
1
4
Ph
H
BAL1
H
CH₃
H
H
H
H
acac

4-259Y
Rh
0
4
Ph
H
BAL1
H
CH₃
H
H
H
H
—
—

4-260
Rh
1
4
Ph
H
H
BAL2
CH₃
H
H
H
H
pic

4-260X
Rh
1
4
Ph
H
H
BAL2
CH₃
H
H
H
H
acac

4-260Y
Rh
0
4
Ph
H
H
BAL2
CH₃
H
H
H
H
—
—

4-261
Rh
1
4
Ph
H
BAL2
H
CH₃
H
H
H
H
pic

4-261X
Rh
1
4
Ph
H
BAL2
H
CH₃
H
H
H
H
acac

4-261Y
Rh
0
4
Ph
H
BAL2
H
CH₃
H
H
H
H
—
—

4-262
Rh
1
4
Ph
H
H
MEK1
CH₃
H
H
H
H
pic

4-262X
Rh
1
4
Ph
H
H
MEK1
CH₃
H
H
H
H
acac

4-262Y
Rh
0
4
Ph
H
H
MEK1
CH₃
H
H
H
H
—
—

4-263
Rh
1
4
Ph
H
MEK1
H
CH₃
H
H
H
H
pic

4-263X
Rh
1
4
Ph
H
MEK1
H
CH₃
H
H
H
H
acac

4-263Y
Rh
0
4
Ph
H
MEK1
H
CH₃
H
H
H
H
—
—

4-264
Rh
1
4
Ph
H
H
MEK2
CH₃
H
H
H
H
pic

4-264X
Rh
1
4
Ph
H
H
MEK2
CH₃
H
H
H
H
acac

4-264Y
Rh
0
4
Ph
H
H
MEK2
CH₃
H
H
H
H
—
—

4-265
Rh
1
4
Ph
H
MEK2
H
CH₃
H
H
H
H
pic

4-265X
Rh
1
4
Ph
H
MEK2
H
CH₃
H
H
H
H
acac

4-265Y
Rh
0
4
Ph
H
MEK2
H
CH₃
H
H
H
H
—
—

4-266
Rh
1
4
Ph
H
H
PAL1
CH₃
H
H
H
H
pic

4-266X
Rh
1
4
Ph
H
H
PAL1
CH₃
H
H
H
H
acac

4-266Y
Rh
0
4
Ph
H
H
PAL1
CH₃
H
H
H
H
—
—

4-267
Rh
1
4
Ph
H
PAL1
H
CH₃
H
H
H
H
pic

4-267X
Rh
1
4
Ph
H
PAL1
H
CH₃
H
H
H
H
acac

4-267Y
Rh
0
4
Ph
H
PAL1
H
CH₃
H
H
H
H
—
—

4-268
Rh
1
4
Ph
H
H
PA L2
CH₃
H
H
H
H
pic

4-268X
Rh
1
4
Ph
H
H
PAL2
CH₃
H
H
H
H
acac

4-268Y
Rh
0
4
Ph
H
H
PAL2
CH₃
H
H
H
H
—
—

4-269
Rh
1
4
Ph
H
PA L2
H
CH₃
H
H
H
H
pic

4-269X
Rh
1
4
Ph
H
PAL2
H
CH₃
H
H
H
H
acac

4-269Y
Rh
0
4
Ph
H
PA L2
H
CH₃
H
H
H
H
—
—

4-270
Rh
1
4
Ph
H
H
MMK
CH₃
H
H
H
H
pic

4-270X
Rh
1
4
Ph
H
H
MMK
CH₃
H
H
H
H
acac

4-270Y
Rh
0
4
Ph
H
H
MMK
CH₃
H
H
H
H
—
—

4-271
Rh
1
4
Ph
H
MMK
H
CH₃
H
H
H
H
pic

4-271X
Rh
1
4
Ph
H
MMK
H
CH₃
H
H
H
H
acac

4-271Y
Rh
0
4
Ph
H
MMK
H
CH₃
H
H
H
H
—
—

4-272
Rh
1
4
Ph
H
H
EES1
CH₃
H
H
H
H
pic

4-272X
Rh
1
4
Ph
H
H
EES1
CH₃
H
H
H
H
acac

4-272Y
Rh
0
4
Ph
H
H
EES1
CH₃
H
H
H
H
—
—

4-273
Rh
1
4
Ph
H
EES2
H
CH₃
H
H
H
H
pic

4-273X
Rh
1
4
Ph
H
EES2
H
CH₃
H
H
H
H
acac

4-273Y
Rh
0
4
Ph
H
EES2
H
CH₃
H
H
H
H
—
—

4-274
Rh
1
4
Ph
H
H
PAE1
CH₃
H
H
H
H
pic

4-274X
Rh
1
4
Ph
H
H
PAE1
CH₃
H
H
H
H
acac

4-274Y
Rh
0
4
Ph
H
H
PAE1
CH₃
H
H
H
H
—
—

4-275
Rh
1
4
Ph
H
PAE2
H
CH₃
H
H
H
H
pic

4-275X
Rh
1
4
Ph
H
PAE2
H
CH₃
H
H
H
H
acac

4-275Y
Rh
0
4
Ph
H
PAE2
H
CH₃
H
H
H
H
—
—

4-276
Rh
1
4
Ph
H
H
AME1
CH₃
H
H
H
H
pic

4-276X
Rh
1
4
Ph
H
H
AME1
CH₃
H
H
H
H
acac

4-276Y
Rh
0
4
Ph
H
H
AME1
CH₃
H
H
H
H
—
—

4-277
Rh
1
4
Ph
H
AME1
H
CH₃
H
H
H
H
pic

4-277X
Rh
1
4
Ph
H
AME1
H
CH₃
H
H
H
H
acac

4-277Y
Rh
0
4
Ph
H
AME1
H
CH₃
H
H
H
H
—
—

4-278
Rh
1
4
Ph
H
H
AME2
CH₃
H
H
H
H
pic

4-278X
Rh
1
4
Ph
H
H
AME2
CH₃
H
H
H
H
acac

4-278Y
Rh
0
4
Ph
H
H
AME2
CH₃
H
H
H
H
—
—

4-279
Rh
1
4
Ph
H
AME2
H
CH₃
H
H
H
H
pic

4-278X
Rh
1
4
Ph
H
AME2
H
CH₃
H
H
H
H
acac

4-279Y
Rh
0
4
Ph
H
AME2
H
CH₃
H
H
H
H
—
—

4-280
Rh
1
4
Ph
H
H
EAE1
CH₃
H
H
H
H
pic

4-280X
Rh
1
4
Ph
H
H
EAE1
CH₃
H
H
H
H
acac

4-280Y
Rh
0
4
Ph
H
H
EAE1
CH₃
H
H
H
H
—
—

4-281
Rh
1
4
Ph
H
EAE1
H
CH₃
H
H
H
H
pic

4-281X
Rh
1
4
Ph
H
EAE1
H
CH₃
H
H
H
H
acac

4-281Y
Rh
0
4
Ph
H
EAE1
H
CH₃
H
H
H
H
—
—

4-282
Rh
1
4
Ph
H
H
EAE2
CH₃
H
H
H
H
pic

4-282X
Rh
1
4
Ph
H
H
EAE2
CH₃
H
H
H
H
acac

4-282Y
Rh
0
4
Ph
H
H
EAE2
CH₃
H
H
H
H
—
—

4-283
Rh
1
4
Ph
H
EAE2
H
CH₃
H
H
H
H
pic

4-283X
Rh
1
4
Ph
H
EAE2
H
CH₃
H
H
H
H
acac

4-283Y
Rh
0
4
Ph
H
EAE2
H
CH₃
H
H
H
H
—
—

4-284
Rh
1
4
Ph
H
H
AAE1
CH₃
H
H
H
H
pic

4-284X
Rh
1
4
Ph
H
H
AAE1
CH₃
H
H
H
H
acac

4-284Y
Rh
0
4
Ph
H
H
AAE1
CH₃
H
H
H
H
—
—

4-285
Rh
1
4
Ph
H
AAE1
H
CH₃
H
H
H
H
pic

4-285X
Rh
1
4
Ph
H
AAE1
H
CH₃
H
H
H
H
acac

4-285Y
Rh
0
4
Ph
H
AAE1
H
CH₃
H
H
H
H
—
—

4-286
Rh
1
4
Ph
H
H
AAE2
CH₃
H
H
H
H
pic

4-286X
Rh
1
4
Ph
H
H
AAE2
CH₃
H
H
H
H
acac

4-286Y
Rh
0
4
Ph
H
H
AAE2
CH₃
H
H
H
H
—
—

4-287
Rh
1
4
Ph
H
AAE2
H
CH₃
H
H
H
H
pic

4-287X
Rh
1
4
Ph
H
AAE2
H
CH₃
H
H
H
H
acac

4-287Y
Rh
0
4
Ph
H
AAE2
H
CH₃
H
H
H
H
—
—

4-288
Rh
1
4
Ph
H
H
PME1
CH₃
H
H
H
H
pic

4-288X
Rh
1
4
Ph
H
H
PME1
CH₃
H
H
H
H
acac

4-288Y
Rh
0
4
Ph
H
H
PME1
CH₃
H
H
H
H
—
—

4-289
Rh
1
4
Ph
H
PME1
H
CH₃
H
H
H
H
pic

4-289X
Rh
1
4
Ph
H
PME1
H
CH₃
H
H
H
H
acac

4-289Y
Rh
0
4
Ph
H
PME1
H
CH₃
H
H
H
H
—
—

4-290
Rh
1
4
Ph
H
H
PME2
CH₃
H
H
H
H
pic

4-290X
Rh
1
4
Ph
H
H
PME2
CH₃
H
H
H
H
acac

4-290Y
Rh
0
4
Ph
H
H
PME2
CH₃
H
H
H
H
—
—

4-291
Rh
1
4
Ph
H
PME2
H
CH₃
H
H
H
H
pic

4-291X
Rh
1
4
Ph
H
PME2
H
CH₃
H
H
H
H
acac

4-291Y
Rh
0
4
Ph
H
PME2
H
CH₃
H
H
H
H
—
—

4-292
Rh
1
4
Ph
H
H
MET1
CH₃
H
H
H
H
pic

4-292X
Rh
1
4
Ph
H
H
MET1
CH₃
H
H
H
H
acac

4-292Y
Rh
0
4
Ph
H
H
MET1
CH₃
H
H
H
H
—
—

4-293
Rh
1
4
Ph
H
MET1
H
CH₃
H
H
H
H
pic

4-293X
Rh
1
4
Ph
H
MET1
H
CH₃
H
H
H
H
acac

4-293Y
Rh
0
4
Ph
H
MET1
H
CH₃
H
H
H
H
—
—

4-294
Rh
1
4
Ph
H
H
MET2
CH₃
H
H
H
H
pic

4-294X
Rh
1
4
Ph
H
H
MET2
CH₃
H
H
H
H
acac

4-294Y
Rh
0
4
Ph
H
H
MET2
CH₃
H
H
H
H
—
—

4-295
Rh
1
4
Ph
H
MET2
H
CH₃
H
H
H
H
pic

4-295X
Rh
1
4
Ph
H
MET2
H
CH₃
H
H
H
H
acac

4-295Y
Rh
0
4
Ph
H
MET2
H
CH₃
H
H
H
H
—
—

4-296
Rh
1
4
Ph
H
H
EE1
CH₃
H
H
H
H
pic

4-296X
Rh
1
4
Ph
H
H
EE1
CH₃
H
H
H
H
acac

4-296Y
Rh
0
4
Ph
H
H
EE1
CH₃
H
H
H
H
—
—

4-297
Rh
1
4
Ph
H
EE1
H
CH₃
H
H
H
H
pic

4-297X
Rh
1
4
Ph
H
EE1
H
CH₃
H
H
H
H
acac

4-297Y
Rh
0
4
Ph
H
EE1
H
CH₃
H
H
H
H
—
—

4-298
Rh
1
4
Ph
H
H
EE2
CH₃
H
H
H
H
pic

4-298X
Rh
1
4
Ph
H
H
EE2
CH₃
H
H
H
H
acac

4-298Y
Rh
0
4
Ph
H
H
EE2
CH₃
H
H
H
H
—
—

4-299
Rh
1
4
Ph
H
EE2
H
CH₃
H
H
H
H
pic

4-299X
Rh
1
4
Ph
H
EE2
H
CH₃
H
H
H
H
acac

4-299Y
Rh
0
4
Ph
H
EE2
H
CH₃
H
H
H
H
—
—

4-300
Rh
1
4
Ph
H
H
MS1
CH₃
H
H
H
H
pic

4-300X
Rh
1
4
Ph
H
H
MS1
CH₃
H
H
H
H
acac

4-300Y
Rh
0
4
Ph
H
H
MS1
CH₃
H
H
H
H
—
—

4-301
Rh
1
4
Ph
H
MS1
H
CH₃
H
H
H
H
pic

4-301X
Rh
1
4
Ph
H
MS1
H
CH₃
H
H
H
H
acac

4-301Y
Rh
0
4
Ph
H
MS1
H
CH₃
H
H
H
H
—
—

4-302
Rh
1
4
Ph
H
H
MS2
CH₃
H
H
H
H
pic

4-302X
Rh
1
4
Ph
H
H
MS2
CH₃
H
H
H
H
acac

4-302Y
Rh
0
4
Ph
H
H
MS2
CH₃
H
H
H
H
—
—

4-303
Rh
1
4
Ph
H
MS2
H
CH₃
H
H
H
H
pic

4-303X
Rh
1
4
Ph
H
MS2
H
CH₃
H
H
H
H
acac

4-303Y
Rh
0
4
Ph
H
MS2
H
CH₃
H
H
H
H
—
—

TABLE 19

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

5-211
Rh
1
5
Ph
H
H
H
H
H
CH₃
H
pic

5-211X
Rh
1
5
Ph
H
H
H
H
H
CH₃
H
acac

5-211Y
Rh
0
5
Ph
H
H
H
H
H
CH₃
H
—
—

5-212
Rh
1
5
Ph
H
H
H
H
H

^tC₄H₉
H
pic

5-212X
Rh
1
5
Ph
H
H
H
H
H

^tC₄H₉
H
acac

5-212Y
Rh
0
5
Ph
H
H
H
H
H

^tC₄H₉
H
—
—

5-213
Rh
1
5
Ph
H
F
H
F
H
CH₃
H
pic

5-213X
Rh
0
5
Ph
H
F
H
F
H
CH₃
H
acac

5-213Y
Rh
0
5
Ph
H
F
H
F
H
CH₃
H
—
—

5-214
Rh
1
5
Ph
H
F
H
F
H

^tC₄H₉
H
pic

5-214X
Rh
1
5
Ph
H
F
H
F
H

^tC₄H₉
H
acac

5-214Y
Rh
0
5
Ph
H
F
H
F
H

^tC₄H₉
H
—
—

5-215
Rh
1
5
Ph
CF₃
H
CF₃
H
H
CH₃
H
pic

5-215X
Rh
1
5
Ph
CF₃
H
CF₃
H
H
CH₃
H
acac

5-215Y
Rh
0
5
Ph
CF₃
H
CF₃
H
H
CH₃
H
—
—

5-216
Rh
1
5
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
pic

5-216X
Rh
1
5
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
acac

5-216Y
Rh
0
5
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
—
—

5-217
Rh
1
5
Ph
H
F
CF₃
H
H
CH₃
H
pic

5-217X
Rh
1
5
Ph
H
F
CF₃
H
H
CH₃
H
acac

5-217Y
Rh
0
5
Ph
H
F
CF₃
H
H
CH₃
H
—
—

5-218
Rh
1
5
Ph
F
H
CF₃
H
H
CH₃
H
pic

5-218X
Rh
1
5
Ph
F
H
CF₃
H
H
CH₃
H
acac

5-218Y
Rh
0
5
Ph
F
H
CF₃
H
H
CH₃
H
—
—

5-219
Rh
1
5
Ph
F
F
F
F
H
CH₃
H
pic

5-219X
Rh
1
5
Ph
F
F
F
F
H
CH₃
H
acac

5-219Y
Rh
0
5
Ph
F
F
F
F
H
CH₃
H
—
—

5-220
Rh
1
5
Ph
H
F
H
CH₃
H
CH₃
H
pic

5-220X
Rh
1
5
Ph
H
F
H
CH₃
H
CH₃
H
acac

5-220Y
Rh
0
5
Ph
H
F
H
CH₃
H
CH₃
H
—
—

5-221
Rh
1
5
Ph
H
F
H
CH₃
H

^tC₄H₉
H
pic

5-221X
Rh
1
5
Ph
H
F
H
CH₃
H

^tC₄H₉
H
acac

5-221Y
Rh
0
5
Ph
H
F
H
CH₃
H

^tC₄H₉
H
—
—

5-222
Rh
1
5
Ph
H
F
H

^tC₄H₉
H
CH₃
H
pic

5-222X
Rh
1
5
Ph
H
F
H

^tC₄H₉
H
CH₃
H
acac

5-222Y
Rh
0
5
Ph
H
F
H

^tC₄H₉
H
CH₃
H
—
—

5-223
Rh
1
5
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
pic

5-223X
Rh
1
5
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
acac

5-223Y
Rh
0
5
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5-224
Rh
1
5
Ph
H
CF₃
H
CF₃
H
CH₃
H
pic

5-224X
Rh
1
5
Ph
H
CF₃
H
CF₃
H
CH₃
H
acac

5-224Y
Rh
0
5
Ph
H
CF₃
H
CF₃
H
CH₃
H
—
—

5-225
Rh
1
5
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
pic

5-225X
Rh
1
5
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
acac

5-225Y
Rh
0
5
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
—
—

5-226
Rh
1
5
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
pic

5-226X
Rh
1
5
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
acac

5-226Y
Rh
0
5
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
—
—

5-227
Rh
1
5
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
pic

5-227X
Rh
1
5
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
acac

5-227Y
Rh
0
5
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5-228
Rh
1
5
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
pic

5-228X
Rh
1
5
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
acac

5-228Y
Rh
0
5
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
—
—

5-229
Rh
1
5
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
pic

5-229X
Rh
1
5
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
acac

5-229Y
Rh
0
5
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5-230
Rh
1
5
Ph
H
CF₃
H
CH₃
H
CH₃
H
pic

5-230X
Rh
1
5
Ph
H
CF₃
H
CH₃
H
CH₃
H
acac

5-230Y
Rh
0
5
Ph
H
CF₃
H
CH₃
H
CH₃
H
—
—

5-231
Rh
1
5
Ph
H
CF₃
CF₃
H
H
CH₃
H
pic

5-231X
Rh
1
5
Ph
H
CF₃
CF₃
H
H
CH₃
H
acac

5-231Y
Rh
0
5
Ph
H
CF₃
CF₃
H
H
CH₃
H
—
—

5-232
Rh
1
5
Ph
H
H
No₂
H
H
CH₃
H
pic

5-232X
Rh
1
5
Ph
H
H
No₂
H
H
CH₃
H
acac

5-232Y
Rh
0
5
Ph
H
H
No₂
H
H
CH₃
H
—
—

5-233
Rh
1
5
Ph
H
H
No₂
H
H

^tC₄H₉
H
pic

5-233X
Rh
1
5
Ph
H
H
No₂
H
H

^tC₄H₉
H
acac

5-233Y
Rh
0
5
Ph
H
H
No₂
H
H

^tC₄H₉
H
—
—

5-234
Rh
1
5
Ph
F
H
No₂
H
H
CH₃
H
pic

5-234X
Rh
1
5
Ph
F
H
No₂
H
H
CH₃
H
acac

5-234Y
Rh
0
5
Ph
F
H
No₂
H
H
CH₃
H
—
—

5-235
Rh
1
5
Ph
F
H
No₂
H
H

^tC₄H₉
H
pic

5-235X
Rh
1
5
Ph
F
H
No₂
H
H

^tC₄H₉
H
acac

5-235Y
Rh
0
5
Ph
F
H
No₂
H
H

^tC₄H₉
H
—
—

5-236
Rh
1
5
Ph
F
H
No₂
F
H
CH₃
H
pic

5-236X
Rh
1
5
Ph
F
H
No₂
F
H
CH₃
H
acac

5-236Y
Rh
0
5
Ph
F
H
No₂
F
H
CH₃
H
—
—

5-237
Rh
1
5
Ph
F
H
No₂
F
H

^tC₄H₉
H
pic

5-237X
Rh
1
5
Ph
F
H
No₂
F
H

^tC₄H₉
H
acac

5-237Y
Rh
0
5
Ph
F
H
No₂
F
H

^tC₄H₉
H
—
—

5-238
Rh
1
5
Ph
H
No₂
H
No₂
H
CH₃
H
pic

5-238X
Rh
1
5
Ph
H
No₂
H
No₂
H
CH₃
H
acac

5-238Y
Rh
0
5
Ph
H
No₂
H
No₂
H
CH₃
H
—
—

5-239
Rh
1
5
Ph
H
No₂
H
No₂
H

^tC₄H₉
H
pic

5-239X
Rh
1
5
Ph
H
No₂
H
No₂
H

^tC₄H₉
H
acac

5-239Y
Rh
0
5
Ph
H
No₂
H
No₂
H

^tC₄H₉
H
—
—

5-240
Rh
1
5
Ph
No₂
H
H
No₂
H
CH₃
H
pic

5-240X
Rh
1
5
Ph
No₂
H
H
No₂
H
CH₃
H
acac

5-240Y
Rh
0
5
Ph
No₂
H
H
No₂
H
CH₃
H
—
—

5-241
Rh
1
5
Ph
H
H
CF₃
H
H
CH₃
H
pic

5-241X
Rh
1
5
Ph
H
H
CF₃
H
H
CH₃
H
acac

5-241Y
Rh
0
5
Ph
H
H
CF₃
H
H
CH₃
H
—
—

5-242
Rh
1
5
Ph
H
CI
CF₃
H
H
CH₃
H
pic

5-242X
Rh
1
5
Ph
H
CI
CF₃
H
H
CH₃
H
acac

5-242Y
Rh
0
5
Ph
H
CI
CF₃
H
H
CH₃
H
—
—

5-243
Rh
1
5
Ph
H
CI
CF₃
H
H

^tC₄H₉
H
pic

5-243X
Rh
1
5
Ph
H
CI
CF₃
H
H

^tC₄H₉
H
acac

5-243Y
Rh
0
5
Ph
H
CI
CF₃
H
H

^tC₄H₉
H
—
—

5-244
Rh
1
5
Ph
H
No₂
H
H
H
CH₃
H
pic

5-244X
Rh
1
5
Ph
H
No₂
H
H
H
CH₃
H
acac

5-244Y
Rh
0
5
Ph
H
No₂
H
H
H
CH₃
H
—
—

5-245
Rh
1
5
Ph
H
CF₃
H
H
H
CH₃
H
pic

5-245X
Rh
1
5
Ph
H
CF₃
H
H
H
CH₃
H
acac

5-245Y
Rh
0
5
Ph
H
CF₃
H
H
H
CH₃
H
—
—

5-246
Rh
1
5
Ph
H
No₂
H
CH₃
H
CH₃
H
pic

5-246X
Rh
1
5
Ph
H
No₂
H
CH₃
H
CH₃
H
acac

5-246Y
Rh
0
5
Ph
H
No₂
H
CH₃
H
CH₃
H
—
—

5-247
Rh
1
5
Ph
H
No₂
H
CH₃
H

^tC₄H₉
H
pic

5-247X
Rh
1
5
Ph
H
No₂
H
CH₃
H

^tC₄H₉
H
acac

5-247Y
Rh
0
5
Ph
H
No₂
H
CH₃
H

^tC₄H₉
H
—
—

5-248
Rh
1
5
Ph
H
No₂
H

^tC₄H₉
H
CH₃
H
pic

5-248X
Rh
1
5
Ph
H
No₂
H

^tC₄H₉
H
CH₃
H
acac

5-248Y
Rh
0
5
Ph
H
No₂
H

^tC₄H₉
H
CH₃
H
—
—

5-249
Rh
1
5
Ph
H
H
CH₃O
H
H
CH₃
H
pic

5-249X
Rh
1
5
Ph
H
H
CH₃O
H
H
CH₃
H
acac

5-249Y
Rh
0
5
Ph
H
H
CH₃O
H
H
CH₃
H
—
—

5-250
Rh
1
5
Ph
H
CH₃O
H
H
H
CH₃
H
pic

5-250X
Rh
1
5
Ph
H
CH₃O
H
H
H
CH₃
H
acac

5-250Y
Rh
0
5
Ph
H
CH₃O
H
H
H
CH₃
H
—
—

5-251
Rh
1
5
Ph
H
CH₃O
H
CH₃
H
CH₃
H
pic

5-251X
Rh
1
5
Ph
H
CH₃O
H
CH₃
H
CH₃
H
acac

5-251Y
Rh
0
5
Ph
H
CH₃O
H
CH₃
H
CH₃
H
—
—

5-252
Rh
1
5
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
pic

5-252X
Rh
1
5
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
acac

5-252Y
Rh
0
5
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
—
—

5-253
Rh
1
5
Ph
H
H
H
H

^tC₄H₉
CH₃
H
pic

5-253X
Rh
1
5
Ph
H
H
H
H

^tC₄H₉
CH₃
H
acac

5-253Y
Rh
0
5
Ph
H
H
H
H

^tC₄H₉
CH₃
H
—
—

5-254
Rh
1
5
Ph
H
F
H
F

^tC₄H₉
CH₃
H
pic

5-254X
Rh
1
5
Ph
H
F
H
F

^tC₄H₉
CH₃
H
acac

5-254Y
Rh
0
5
Ph
H
F
H
F

^tC₄H₉
CH₃
H
—
—

5-255
Rh
1
5
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
pic

5-255X
Rh
1
5
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
acac

5-255Y
Rh
0
5
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
—
—

5-256
Rh
1
5
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
pic

5-256X
Rh
1
5
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
acac

5-256Y
Rh
0
5
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
—
—

5-257
Rh
1
5
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
pic

5-257X
Rh
1
5
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
acac

5-257Y
Rh
0
5
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
—
—

5-258
Rh
1
5
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
pic

5-258X
Rh
1
5
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
acac

5-258Y
Rh
0
5
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
—
—

5-259
Rh
1
5
Ph
H
Si (CH₃)₃
H
H
H
CH₃
H
pic

5-259X
Rh
1
5
Ph
H
Si (CH₃)₃
H
H
H
CH₃
H
acac

5-259Y
Rh
0
5
Ph
H
Si (CH₃)₃
H
H
H
CH₃
H
—
—

5-260
Rh
1
5
Ph
H
Si (CH₃)₃
H
H
H

^tC₄H₉
H
pic

5-260X
Rh
1
5
Ph
H
Si (CH₃)₃
H
H
H

^tC₄H₉
H
acac

5-260Y
Rh
0
5
Ph
H
Si (CH₃)₃
H
H
H

^tC₄H₉
H
—
—

5-261
Rh
1
5
Ph
H
H
Si (CH₃)₃
H
H
CH₃
H
pic

5-261X
Rh
1
5
Ph
H
H
Si (CH₃)₃
H
H
CH₃
H
acac

5-261Y
Rh
0
5
Ph
H
H
Si (CH₃)₃
H
H
CH₃
H
—
—

5-262
Rh
1
5
Ph
H
H
H
Si (CH₃)₃
H
CH₃
H
pic

5-262X
Rh
1
5
Ph
H
H
H
Si (CH₃)₃
H
CH₃
H
acac

5-262Y
Rh
0
5
Ph
H
H
H
Si (CH₃)₃
H
CH₃
H
—
—

5-263
Rh
1
5
Ph
H
F
H
Si (CH₃)₃
H
CH₃
H
pic

5-263X
Rh
1
5
Ph
H
F
H
Si (CH₃)₃
H
CH₃
H
acac

5-263Y
Rh
0
5
Ph
H
F
H
Si (CH₃)₃
H
CH₃
H
—
—

5-264
Rh
1
5
Ph
H
CF₃
H
Si (CH₃)₃
H
CH₃
H
pic

5-264X
Rh
1
5
Ph
H
CF₃
H
Si (CH₃)₃
H
CH₃
H
acac

5-264Y
Rh
0
5
Ph
H
CF₃
H
Si (CH₃)₃
H
CH₃
H
—
—

5-265
Rh
1
5
Ph
H
Si (CH₃)₃
H
F
H
CH₃
H
pic

5-265X
Rh
1
5
Ph
H
Si (CH₃)₃
H
F
H
CH₃
H
acac

5-265Y
Rh
0
5
Ph
H
Si (CH₃)₃
H
F
H
CH₃
H
—
—

5-266
Rh
1
5
Ph
H
Si (CH₃)₃
H
F
H

^tC₄H₉
H
pic

5-266X
Rh
1
5
Ph
H
Si (CH₃)₃
H
F
H

^tC₄H₉
H
acac

5-266Y
Rh
0
5
Ph
H
Si (CH₃)₃
H
F
H

^tC₄H₉
H
—
—

5-267
Rh
1
5
Ph
H
Si (CH₃)₃
H
CF₃
H
CH₃
H
pic

5-267X
Rh
1
5
Ph
H
Si (CH₃)₃
H
CF₃
H
CH₃
H
acac

5-267Y
Rh
0
5
Ph
H
Si (CH₃)₃
H
CF₃
H
CH₃
H
—
—

5-268
Rh
1
5
Ph
H
Si (CH₃)₃
H
CF₃
H

^tC₄H₉
H
pic

5-268X
Rh
1
5
Ph
H
Si (CH₃)₃
H
CF₃
H

^tC₄H₉
H
acac

5-268Y
Rh
0
5
Ph
H
Si (CH₃)₃
H
CF₃
H

^tC₄H₉
H
—
—

5-269
Rh
1
5
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
H
CH₃
H
pic

5-269X
Rh
1
5
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
H
CH₃
H
acac

5-269Y
Rh
0
5
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
H
CH₃
H
—
—

5-270
Rh
1
5
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
H

^tC₄H₉
H
pic

5-270X
Rh
1
5
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
H

^tC₄H₉
H
acac

5-270Y
Rh
0
5
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
H

^tC₄H₉
H
—
—

5-271
Rh
1
5
Ph
H
H
H
COCH₃
H
CH₃
H
pic

5-271X
Rh
1
5
Ph
H
H
H
COCH₃
H
CH₃
H
acac

5-271Y
Rh
0
5
Ph
H
H
H
COCH₃
H
CH₃
H
—
—

5-272
Rh
1
5
Ph
H
H
COCH₃
H
H
CH₃
H
pic

5-272X
Rh
1
5
Ph
H
H
COCH₃
H
H
CH₃
H
acac

5-272Y
Rh
0
5
Ph
H
H
COCH₃
H
H
CH₃
H
—
—

5-273
Rh
1
5
Ph
H
COCH₃
H
H
H
CH₃
H
pic

5-273X
Rh
1
5
Ph
H
COCH₃
H
H
H
CH₃
H
acac

5-273Y
Rh
0
5
Ph
H
COCH₃
H
H
H
CH₃
H
—
—

6-274
Rh
1
5
Ph
H
H
BL
H
CH₃
H
pic

5-274X
Rh
1
5
Ph
H
H
BL
H
CH₃
H
acac

5-274Y
Rh
0
5
Ph
H
H
BL
H
CH₃
H
—
—

5-275
Rh
1
5
Ph
H
H
BL
H

^tC₄H₉
H
pic

5-275X
Rh
1
5
Ph
H
H
BL
H

^tC₄H₉
H
acac

5-275Y
Rh
0
5
Ph
H
H
BL
H

^tC₄H₉
H
—
—

5-276
Rh
1
5
Ph
H
BL
H
H
CH₃
H
pic

5-276X
Rh
1
5
Ph
H
BL
H
H
CH₃
H
acac

5-276Y
Rh
0
5
Ph
H
BL
H
H
CH₃
H
—
—

5-277
Rh
1
5
Ph
H
BL
H
H

^tC₄H₉
H
pic

5-277X
Rh
1
5
Ph
H
BL
H
H

^tC₄H₉
H
acac

5-277Y
Rh
0
5
Ph
H
BL
H
H

^tC₄H₉
H
—
—

5-278
Rh
1
5
Ph
H
H
PL
H
CH₃
H
pic

5-278X
Rh
1
5
Ph
H
H
PL
H
CH₃
H
acac

5-278Y
Rh
0
5
Ph
H
H
PL
H
CH₃
H
—
—

5-279
Rh
1
5
Ph
H
H
PL
H

^tC₄H₉
H
pic

5-279X
Rh
1
5
Ph
H
H
PL
H

^tC₄H₉
H
acac

5-279Y
Rh
0
5
Ph
H
H
PL
H

^tC₄H₉
H
—
—

5-280
Rh
1
5
Ph
H
PL
H
H
CH₃
H
pic

5-280X
Rh
1
5
Ph
H
PL
H
H
CH₃
H
acac

5-280Y
Rh
0
5
Ph
H
PL
H
H
CH₃
H
—
—

5-281
Rh
1
5
Ph
H
PL
H
H

^tC₄H₉
H
pic

5-281X
Rh
1
5
Ph
H
PL
H
H

^tC₄H₉
H
acac

5-281Y
Rh
0
5
Ph
H
PL
H
H

^tC₄H₉
H
—
—

5-282
Rh
1
5
Ph
H
H
MEE1
H
CH₃
H
pic

5-282X
Rh
1
5
Ph
H
H
MEE1
H
CH₃
H
acac

5-282Y
Rh
0
5
Ph
H
H
MEE1
H
CH₃
H
—
—

5-283
Rh
1
5
Ph
H
MEE1
H
H
CH₃
H
pic

5-283X
Rh
1
5
Ph
H
MEE1
H
H
CH₃
H
acac

5-283Y
Rh
0
5
Ph
H
MEE1
H
H
CH₃
H
—
—

5-284
Rh
1
5
Ph
H
H
MEE2
H
CH₃
H
pic

5-284X
Rh
1
5
Ph
H
H
MEE2
H
CH₃
H
acac

5-284Y
Rh
0
5
Ph
H
H
MEE2
H
CH₃
H
—
—

5-285
Rh
1
5
Ph
H
MEE2
H
H
CH₃
H
pic

5-285X
Rh
1
5
Ph
H
MEE2
H
H
CH₃
H
acac

5-285Y
Rh
0
5
Ph
H
MEE2
H
H
CH₃
H
—
—

5-286
Rh
1
5
Ph
H
H
PA1
H
CH₃
H
pic

5-286X
Rh
1
5
Ph
H
H
PA1
H
CH₃
H
acac

5-286Y
Rh
0
5
Ph
H
H
PA1
H
CH₃
H
—
—

5-287
Rh
1
5
Ph
H
PA1
H
H
CH₃
H
pic

5-287X
Rh
1
5
Ph
H
PA1
H
H
CH₃
H
acac

5-287Y
Rh
0
5
Ph
H
PA1
H
H
CH₃
H
—
—

5-288
Rh
1
5
Ph
H
H
PA2
H
CH₃
H
pic

5-288X
Rh
1
5
Ph
H
H
PA2
H
CH₃
H
acac

5-288Y
Rh
0
5
Ph
H
H
PA2
H
CH₃
H
—
—

5-289
Rh
1
5
Ph
H
PA2
H
H
CH₃
H
pic

5-289X
Rh
1
5
Ph
H
PA2
H
H
CH₃
H
acac

5-289Y
Rh
0
5
Ph
H
PA2
H
H
CH₃
H
—
—

5-290
Rh
1
5
Ph
H
H
EA1
H
CH₃
H
pic

5-290X
Rh
1
5
Ph
H
H
EA1
H
CH₃
H
acac

5-290Y
Rh
0
5
Ph
H
H
EA1
H
CH₃
H
—
—

5-291
Rh
1
5
Ph
H
EA2
H
H
CH₃
H
pic

5-291X
Rh
1
5
Ph
H
EA2
H
H
CH₃
H
acac

5-291Y
Rh
0
5
Ph
H
EA2
H
H
CH₃
H
—
—

5-292
Rh
1
5
Ph
H
H
ME
H
CH₃
H
pic

5-292X
Rh
1
5
Ph
H
H
ME
H
CH₃
H
acac

5-292Y
Rh
0
5
Ph
H
H
ME
H
CH₃
H
—
—

5-293
Rh
1
5
Ph
H
ME
H
H
CH₃
H
pic

5-293X
Rh
1
5
Ph
H
ME
H
H
CH₃
H
acac

5-293Y
Rh
0
5
Ph
H
ME
H
H
CH₃
H
—
—

5-294
Rh
1
5
Ph
H
H
AT
H
CH₃
H
pic

5-294X
Rh
1
5
Ph
H
H
AT
H
CH₃
H
acac

5-294Y
Rh
0
5
Ph
H
H
AT
H
CH₃
H
—
—

5-295
Rh
1
5
Ph
H
AT
H
H
CH₃
H
pic

5-295X
Rh
1
5
Ph
H
AT
H
H
CH₃
H
acac

5-295Y
Rh
0
5
Ph
H
AT
H
H
CH₃
H
—
—

5-296
Rh
1
5
Ph
H
H
MES1
H
CH₃
H
pic

5-296X
Rh
1
5
Ph
H
H
MES1
H
CH₃
H
acac

5-296Y
Rh
0
5
Ph
H
H
MES1
H
CH₃
H
—
—

5-297
Rh
1
5
Ph
H
MES1
H
H
CH₃
H
pic

5-297X
Rh
1
5
Ph
H
MES1
H
H
CH₃
H
acac

5-297Y
Rh
0
5
Ph
H
MES1
H
H
CH₃
H
—
—

5-298
Rh
1
5
Ph
H
H
MES2
H
CH₃
H
pic

5-298X
Rh
1
5
Ph
H
H
MES2
H
CH₃
H
acac

5-298Y
Rh
0
5
Ph
H
H
MES2
H
CH₃
H
—
—

5-299
Rh
1
5
Ph
H
MES2
H
H
CH₃
H
pic

5-299X
Rh
1
5
Ph
H
MES2
H
H
CH₃
H
acac

5-299Y
Rh
0
5
Ph
H
MES2
H
H
CH₃
H
—
—

5-300
Rh
1
5
Ph
H
H
PS1
H
CH₃
H
pic

5-300X
Rh
1
5
Ph
H
H
PS1
H
CH₃
H
acac

5-300Y
Rh
0
5
Ph
H
H
PS1
H
CH₃
H
—
—

5-301
Rh
1
5
Ph
H
PS1
H
H
CH₃
H
pic

5-301X
Rh
1
5
Ph
H
PS1
H
H
CH₃
H
acac

5-301Y
Rh
0
5
Ph
H
PS1
H
H
CH₃
H
—
—

5-302
Rh
1
5
Ph
H
H
PS2
H
CH₃
H
pic

5-302X
Rh
1
5
Ph
H
H
PS2
H
CH₃
H
acac

5-302Y
Rh
0
5
Ph
H
H
PS2
H
CH₃
H
—
—

5-303
Rh
1
5
Ph
H
PS2
H
H
CH₃
H
pic

5-303X
Rh
1
5
Ph
H
PS2
H
H
CH₃
H
acac

5-303Y
Rh
0
5
Ph
H
PS2
H
H
CH₃
H
—
—

5-304
Rh
1
5
Ph
H
H
BAL1
H
CH₃
H
pic

5-304X
Rh
1
5
Ph
H
H
BAL1
H
CH₃
H
acac

5-304Y
Rh
0
5
Ph
H
H
BAL1
H
CH₃
H
—
—

5-305
Rh
1
5
Ph
H
BAL1
H
H
CH₃
H
pic

5-305X
Rh
1
5
Ph
H
BAL1
H
H
CH₃
H
acac

5-305Y
Rh
0
5
Ph
H
BAL1
H
H
CH₃
H
—
—

5-306
Rh
1
5
Ph
H
H
BAL2
H
CH₃
H
pic

5-306X
Rh
1
5
Ph
H
H
BAL2
H
CH₃
H
acac

5-306Y
Rh
0
5
Ph
H
H
BAL2
H
CH₃
H
—
—

5-307
Rh
1
5
Ph
H
BAL2
H
H
CH₃
H
pic

5-307X
Rh
1
5
Ph
H
BAL2
H
H
CH₃
H
acac

5-307Y
Rh
0
5
Ph
H
BAL2
H
H
CH₃
H
—
—

5-308
Rh
1
5
Ph
H
H
MEK1
H
CH₃
H
pic

5-308X
Rh
1
5
Ph
H
H
MEK1
H
CH₃
H
acac

5-308Y
Rh
0
5
Ph
H
H
MEK1
H
CH₃
H
—
—

5-309
Rh
1
5
Ph
H
MEK1
H
H
CH₃
H
pic

5-309X
Rh
1
5
Ph
H
MEK1
H
H
CH₃
H
acac

5-309Y
Rh
0
5
Ph
H
MEK1
H
H
CH₃
H
—
—

5-310
Rh
1
5
Ph
H
H
MEK2
H
CH₃
H
pic

5-310X
Rh
1
5
Ph
H
H
MEK2
H
CH₃
H
acac

5-310Y
Rh
0
5
Ph
H
H
MEK2
H
CH₃
H
—
—

5-311
Rh
1
5
Ph
H
MEK2
H
H
CH₃
H
pic

5-311X
Rh
1
5
Ph
H
MEK2
H
H
CH₃
H
acac

5-311Y
Rh
0
5
Ph
H
MEK2
H
H
CH₃
H
—
—

5-312
Rh
1
5
Ph
H
H
PAL1
H
CH₃
H
pic

5-312X
Rh
1
5
Ph
H
H
PAL1
H
CH₃
H
acac

5-312Y
Rh
0
5
Ph
H
H
PAL1
H
CH₃
H
—
—

5-313
Rh
1
5
Ph
H
PAL1
H
H
CH₃
H
pic

5-313X
Rh
1
5
Ph
H
PAL1
H
H
CH₃
H
acac

5-313Y
Rh
0
5
Ph
H
PAL1
H
H
CH₃
H
—
—

5-314
Rh
1
5
Ph
H
H
PAL2
H
CH₃
H
pic

5-314X
Rh
1
5
Ph
H
H
PAL2
H
CH₃
H
acac

5-314Y
Rh
0
5
Ph
H
H
PAL2
H
CH₃
H
—
—

5-315
Rh
1
5
Ph
H
PAL2
H
H
CH₃
H
pic

5-315X
Rh
1
5
Ph
H
PAL2
H
H
CH₃
H
acac

5-315Y
Rh
0
5
Ph
H
PAL2
H
H
CH₃
H
—
—

5-316
Rh
1
5
Ph
H
H
MMK
H
CH₃
H
pic

5-316X
Rh
1
5
Ph
H
H
MMK
H
CH₃
H
acac

5-316Y
Rh
0
5
Ph
H
H
MMK
H
CH₃
H
—
—

5-317
Rh
1
5
Ph
H
MMK
H
H
CH₃
H
pic

5-317X
Rh
1
5
Ph
H
MMK
H
H
CH₃
H
acac

5-317Y
Rh
0
5
Ph
H
MMK
H
H
CH₃
H
—
—

5-318
Rh
1
5
Ph
H
H
EES1
H
CH₃
H
pic

5-318X
Rh
1
5
Ph
H
H
EES1
H
CH₃
H
acac

5-318Y
Rh
0
5
Ph
H
H
EES1
H
CH₃
H
—
—

5-319
Rh
1
5
Ph
H
EES2
H
H
CH₃
H
pic

5-319X
Rh
1
5
Ph
H
EES2
H
H
CH₃
H
acac

5-319Y
Rh
0
5
Ph
H
EES2
H
H
CH₃
H
—
—

5-320
Rh
1
5
Ph
H
H
PAE1
H
CH₃
H
pic

5-320X
Rh
1
5
Ph
H
H
PAE1
H
CH₃
H
acac

5-320Y
Rh
0
5
Ph
H
H
PAE1
H
CH₃
H
—
—

5-321
Rh
1
5
Ph
H
PAE2
H
H
CH₃
H
pic

5-321X
Rh
1
5
Ph
H
PAE2
H
H
CH₃
H
acac

5-321Y
Rh
0
5
Ph
H
PAE2
H
H
CH₃
H
—
—

5-322
Rh
1
5
Ph
H
H
AME1
H
CH₃
H
pic

5-322X
Rh
1
5
Ph
H
H
AME1
H
CH₃
H
acac

5-322Y
Rh
0
5
Ph
H
H
AME1
H
CH₃
H
—
—

5-323
Rh
1
5
Ph
H
AME1
H
H
CH₃
H
pic

5-323X
Rh
1
5
Ph
H
AME1
H
H
CH₃
H
acac

5-323Y
Rh
0
5
Ph
H
AME1
H
H
CH₃
H
—
—

5-324
Rh
1
5
Ph
H
H
AME2
H
CH₃
H
pic

5-324X
Rh
1
5
Ph
H
H
AME2
H
CH₃
H
acac

5-324Y
Rh
0
5
Ph
H
H
AME2
H
CH₃
H
—
—

5-325
Rh
1
5
Ph
H
AME2
H
H
CH₃
H
pic

5-325X
Rh
1
5
Ph
H
AME2
H
H
CH₃
H
acac

5-325Y
Rh
0
5
Ph
H
AME2
H
H
CH₃
H
—
—

5-328
Rh
1
5
Ph
H
H
EAE1
H
CH₃
H
pic

5-326X
Rh
1
5
Ph
H
H
EAE1
H
CH₃
H
acac

5-326Y
Rh
0
5
Ph
H
H
EAE1
H
CH₃
H
—
—

5-327
Rh
1
5
Ph
H
EAE1
H
H
CH₃
H
pic

5-327X
Rh
1
5
Ph
H
EAE1
H
H
CH₃
H
acac

5-327Y
Rh
0
5
Ph
H
EAE1
H
H
CH₃
H
—
—

5-328
Rh
1
5
Ph
H
H
EAE2
H
CH₃
H
pic

5-328X
Rh
1
5
Ph
H
H
EAE2
H
CH₃
H
acac

5-328Y
Rh
0
5
Ph
H
H
EAE2
H
CH₃
H
—
—

5-329
Rh
1
5
Ph
H
EAE2
H
H
CH₃
H
pic

5-329X
Rh
1
5
Ph
H
EAE2
H
H
CH₃
H
acac

5-329Y
Rh
0
5
Ph
H
EAE2
H
H
CH₃
H
—
—

5-330
Rh
1
5
Ph
H
H
AAE1
H
CH₃
H
pic

5-330X
Rh
1
5
Ph
H
H
AAE1
H
CH₃
H
acac

5-330Y
Rh
0
5
Ph
H
H
AAE1
H
CH₃
H
—
—

5-331
Rh
1
5
Ph
H
AAE1
H
H
CH₃
H
pic

5-331X
Rh
1
5
Ph
H
AAE1
H
H
CH₃
H
acac

5-331Y
Rh
0
5
Ph
H
AAE1
H
H
CH₃
H
—
—

5-332
Rh
1
5
Ph
H
H
AAE2
H
CH₃
H
pic

5-332X
Rh
1
5
Ph
H
H
AAE2
H
CH₃
H
acac

5-332Y
Rh
0
5
Ph
H
H
AAE2
H
CH₃
H
—
—

5-333
Rh
1
5
Ph
H
AAE2
H
H
CH₃
H
pic

5-333X
Rh
1
5
Ph
H
AAE2
H
H
CH₃
H
acac

5-333Y
Rh
0
5
Ph
H
AAE2
H
H
CH₃
H
—
—

5-334
Rh
1
5
Ph
H
H
PME1
H
CH₃
H
pic

5-334X
Rh
1
5
Ph
H
H
PME1
H
CH₃
H
acac

5-334Y
Rh
0
5
Ph
H
H
PME1
H
CH₃
H
—
—

5-335
Rh
1
5
Ph
H
PME1
H
H
CH₃
H
pic

5-335X
Rh
1
5
Ph
H
PME1
H
H
CH₃
H
acac

5-335Y
Rh
0
5
Ph
H
PME1
H
H
CH₃
H
—
—

5-336
Rh
1
5
Ph
H
H
PME2
H
CH₃
H
pic

5-336X
Rh
1
5
Ph
H
H
PME2
H
CH₃
H
acac

5-336Y
Rh
0
5
Ph
H
H
PME2
H
CH₃
H
—
—

5-337
Rh
1
5
Ph
H
PME2
H
H
CH₃
H
pic

5-337X
Rh
1
5
Ph
H
PME2
H
H
CH₃
H
acac

5-337Y
Rh
0
5
Ph
H
PME2
H
H
CH₃
H
—
—

5-338
Rh
1
5
Ph
H
H
MET1
H
CH₃
H
pic

5-338X
Rh
1
5
Ph
H
H
MET1
H
CH₃
H
acac

5-338Y
Rh
0
5
Ph
H
H
MET1
H
CH₃
H
—
—

5-339
Rh
1
5
Ph
H
MET1
H
H
CH₃
H
pic

5-339X
Rh
1
5
Ph
H
MET1
H
H
CH₃
H
acac

5-339Y
Rh
0
5
Ph
H
MET1
H
H
CH₃
H
—
—

5-340
Rh
1
5
Ph
H
H
MET2
H
CH₃
H
pic

5-340X
Rh
1
5
Ph
H
H
MET2
H
CH₃
H
acac

5-340Y
Rh
0
5
Ph
H
H
MET2
H
CH₃
H
—
—

5-341
Rh
1
5
Ph
H
MET2
H
H
CH₃
H
pic

5-341X
Rh
1
5
Ph
H
MET2
H
H
CH₃
H
acac

5-341Y
Rh
0
5
Ph
H
MET2
H
H
CH₃
H
—
—

5-342
Rh
1
5
Ph
H
H
EE1
H
CH₃
H
pic

5-342X
Rh
1
5
Ph
H
H
EE1
H
CH₃
H
acac

5-342Y
Rh
0
5
Ph
H
H
EE1
H
CH₃
H
—
—

5-343
Rh
1
5
Ph
H
EE1
H
H
CH₃
H
pic

5-343X
Rh
1
5
Ph
H
EE1
H
H
CH₃
H
acac

5-343Y
Rh
0
5
Ph
H
EE1
H
H
CH₃
H
—
—

5-344
Rh
1
5
Ph
H
H
EE2
H
CH₃
H
pic

5-344X
Rh
1
5
Ph
H
H
EE2
H
CH₃
H
acac

5-344Y
Rh
0
5
Ph
H
H
EE2
H
CH₃
H
—
—

5-345
Rh
1
5
Ph
H
EE2
H
H
CH₃
H
pic

5-345X
Rh
1
5
Ph
H
EE2
H
H
CH₃
H
acac

5-345Y
Rh
0
5
Ph
H
EE2
H
H
CH₃
H
—
—

5-346
Rh
1
5
Ph
H
H
MS1
H
CH₃
H
pic

5-346X
Rh
1
5
Ph
H
H
MS1
H
CH₃
H
acac

5-346Y
Rh
0
5
Ph
H
H
MS1
H
CH₃
H
—
—

5-347
Rh
1
5
Ph
H
MS1
H
H
CH₃
H
pic

5-347X
Rh
1
5
Ph
H
MS1
H
H
CH₃
H
acac

5-347Y
Rh
0
5
Ph
H
MS1
H
H
CH₃
H
—
—

5-348
Rh
1
5
Ph
H
H
MS2
H
CH₃
H
pic

5-348X
Rh
1
5
Ph
H
H
MS2
H
CH₃
H
acac

5-348Y
Rh
0
5
Ph
H
H
MS2
H
CH₃
H
—
—

5-349
Rh
1
5
Ph
H
MS2
H
H
CH₃
H
pic

5-349X
Rh
1
5
Ph
H
MS2
H
H
CH₃
H
acac

5-349Y
Rh
0
5
Ph
H
MS2
H
H
CH₃
H
—
—

TABLE 20

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

6-167
Rh
1
6
Ph
H
H
H
H
CH₃
H
H
pic

6-167X
Rh
1
6
Ph
H
H
H
H
CH₃
H
H
acac

6-167Y
Rh
0
6
Ph
H
H
H
H
CH₃
H
H
—
—

6-168
Rh
1
6
Ph
H
H
H
H
CH₃
H
H
pic

6-168X
Rh
1
6
Ph
H
H
H
H
CH₃
H
H
acac

6-168Y
Rh
0
6
Ph
H
H
H
H
CH₃
H
H
—
—

6-169
Rh
1
6
Ph
H
F
H
F
CH₃
H
H
pic

6-169X
Rh
1
6
Ph
H
F
H
F
CH₃
H
H
acac

6-169Y
Rh
0
6
Ph
H
F
H
F
CH₃
H
H
—
—

6-170
Rh
1
6
Ph
H
F
H
F

^tC₄H₉
H
H
pic

6-170X
Rh
1
6
Ph
H
F
H
F

^tC₄H₉
H
H
acac

6-170Y
Rh
0
6
Ph
H
F
H
F

¹C₄H₉
H
H
—
—

6-171
Rh
1
6
Ph
F
H
H
F
CH₃
H
H
pic

6-171X
Rh
1
6
Ph
F
H
H
F
CH₃
H
H
acac

6-171Y
Rh
0
6
Ph
F
H
H
F
CH₃
H
H
—
—

6-172
Rh
1
6
Ph
F
H
H
F

^tC₄H₉
H
H
pic

6-172X
Rh
1
6
Ph
F
H
H
F

^tC₄H₉
H
H
acac

6-172Y
Rh
0
6
Ph
F
H
H
F

^tC₄H₉
H
H
—
—

6-173
Rh
1
6
Ph
CF₃
H
CF₃
H
CH₃
H
H
pic

6-173X
Rh
1
6
Ph
CF₃
H
CF₃
H
CH₃
H
H
acac

6-173
Rh
0
6
Ph
CF₃
H
CF₃
H
CH₃
H
H
—
—

6-174
Rh
1
6
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

6-174X
Rh
1
6
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

6-174Y
Rh
0
6
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
—
—

6-175
Rh
1
6
Ph
H
F
CF₃
H
CH₃
H
H
pic

6-175X
Rh
1
6
Ph
H
F
CF₃
H
CH₃
H
H
acac

6-175Y
Rh
0
6
Ph
H
F
CF₃
H
CH₃
H
H
—
—

6-176
Rh
1
6
Ph
F
H
CF₃
H
CH₃
H
H
pic

6-176X
Rh
1
6
Ph
F
H
CF₃
H
CH₃
H
H
acac

6-176Y
Rh
0
6
Ph
F
H
CF₃
H
CH₃
H
H
—
—

6-177
Rh
1
6
Ph
F
F
F
F
CH₃
H
H
pic

6-177X
Rh
1
6
Ph
F
F
F
F

^tC₄H₉
H
H
acac

6-177Y
Rh
0
6
Ph
F
F
F
F

^tC₄H₉
H
H
—
—

6-178
Rh
1
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

6-178X
Rh
1
6
Ph
H
F
H
CH₃
CH₃
H
H
acac

6-178Y
Rh
0
6
Ph
H
F
H
CH₃
CH₃
H
H
—
—

6-179
Rh
1
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

6-179X
Rh
1
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

6-179Y
Rh
0
6
Ph
H
F
H
CH₃

^tC₄H₉
H
H
—
—

6-180
Rh
1
6
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

6-180X
Rh
1
6
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

6-180Y
Rh
0
6
Ph
H
F
H

^tC₄H₉
CH₃
H
H
—
—

6-181
Rh
1
6
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-181X
Rh
1
6
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-181Y
Rh
0
6
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-182
Rh
1
6
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

6-182X
Rh
1
6
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

6-182Y
Rh
0
6
Ph
H
CF₃
H
CF₃
CH₃
H
H
—
—

6-183
Rh
1
6
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

6-183X
Rh
1
6
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

6-183Y
Rh
0
6
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
—
—

6-184
Rh
1
6
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

6-184X
Rh
1
6
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

6-184Y
Rh
0
6
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
—
—

6-185
Rh
1
6
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-185X
Rh
1
6
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-185Y
Rh
0
6
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-186
Rh
1
6
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
pic

6-186X
Rh
1
6
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

6-186Y
Rh
0
6
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
—
—

6-187
Rh
1
6
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-187X
Rh
1
6
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-187Y
Rh
0
6
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-188
Rh
1
6
Ph
H
CF₃
H
CH₃
CH₃
H
H
pic

6-188X
Rh
1
6
Ph
H
CF₃
H
CH₃
CH₃
H
H
acac

6-188Y
Rh
0
6
Ph
H
CF₃
H
CH₃
CH₃
H
H
—
—

6-189
Rh
1
6
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

6-189X
Rh
1
6
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

6-189Y
Rh
0
6
Ph
H
CF₃
CF₃
H
CH₃
H
H
—
—

6-190
Rh
1
6
Ph
H
H
No₂
H
CH₃
H
H
pic

6-190X
Rh
1
6
Ph
H
H
No₂
H
CH₃
H
H
acac

6-190Y
Rh
0
6
Ph
H
H
No₂
H
CH₃
H
H
—
—

6-191
Rh
1
6
Ph
H
H
No₂
H

^tC₄H₉
H
H
pic

6-191X
Rh
1
6
Ph
H
H
No₂
H

^tC₄H₉
H
H
acac

6-191Y
Rh
0
6
Ph
H
H
No₂
H

^tC₄H₉
H
H
—
—

6-192
Rh
1
6
Ph
F
H
No₂
H
CH₃
H
H
pic

6-192X
Rh
1
6
Ph
F
H
No₂
H
CH₃
H
H
acac

6-192Y
Rh
0
6
Ph
F
H
No₂
H
CH₃
H
H
—
—

6-193
Rh
1
6
Ph
F
H
No₂
F
CH₃
H
H
pic

6-193X
Rh
1
6
Ph
F
H
No₂
F
CH₃
H
H
acac

6-193Y
Rh
0
6
Ph
F
H
No₂
F
CH₃
H
H
—
—

6-194
Rh
1
6
Ph
H
No₂
H
No₂
CH₃
H
H
pic

6-194X
Rh
1
6
Ph
H
No₂
H
No₂
CH₃
H
H
acac

6-194Y
Rh
0
6
Ph
H
No₂
H
No₂
CH₃
H
H
—
—

6-195
Rh
1
6
Ph
H
No₂
H
No₂

^tC₄H₉
H
H
pic

6-195X
Rh
1
6
Ph
H
No₂
H
No₂

^tC₄H₉
H
H
acac

6-195Y
Rh
0
6
Ph
H
No₂
H
No₂

^tC₄H₉
H
H
—
—

6-196
Rh
1
6
Ph
No₂
H
H
No₂
CH₃
H
H
pic

6-196X
Rh
1
6
Ph
No₂
H
H
No₂
CH₃
H
H
acac

6-196Y
Rh
0
6
Ph
No₂
H
H
No₂
CH₃
H
H
—
—

6-197
Rh
1
6
Ph
No₂
H
H
No₂

^tC₄H₉
H
H
pic

6-197X
Rh
1
6
Ph
No₂
H
H
No₂

^tC₄H₉
H
H
acac

6-197Y
Rh
0
6
Ph
No₂
H
H
No₂

^tC₄H₉
H
H
—
—

6-198
Rh
1
6
Ph
H
H
CF₃
H
CH₃
H
H
pic

6-198X
Rh
1
6
Ph
H
H
CF₃
H
CH₃
H
H
acac

6-198Y
Rh
0
6
Ph
H
H
CF₃
H
CH₃
H
H
—
—

6-199
Rh
1
6
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

6-199X
Rh
1
6
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

6-199Y
Rh
0
6
Ph
H
H
CF₃
H

^tC₄H₉
H
H
—
—

6-200
Rh
1
6
Ph
H
CI
CF₃
H
CH₃
H
H
pic

6-200X
Rh
1
6
Ph
H
CI
CF₃
H
CH₃
H
H
acac

6-200Y
Rh
0
6
Ph
H
CI
CF₃
H
CH₃
H
H
—
—

6-201
Rh
1
6
Ph
H
CI
CF₃
H

^tC₄H₉
H
H
pic

6-201X
Rh
1
6
Ph
H
CI
CF₃
H

^tC₄H₉
H
H
acac

6-201Y
Rh
0
6
Ph
H
CI
CF₃
H

^tC₄H₉
H
H
—
—

6-202
Rh
1
6
Ph
H
No₂
H
H
CH₃
H
H
pic

6-202X
Rh
1
6
Ph
H
No₂
H
H
CH₃
H
H
acac

6-202Y
Rh
0
6
Ph
H
No₂
H
H
CH₃
H
H
—
—

6-203
Rh
1
6
Ph
H
CF₃
H
H
CH₃
H
H
pic

6-203X
Rh
1
6
Ph
H
CF₃
H
H
CH₃
H
H
acac

6-203Y
Rh
0
6
Ph
H
CF₃
H
H
CH₃
H
H
—
—

6-204
Rh
1
6
Ph
H
No₂
H
CH₃
CH₃
H
H
pic

6-204X
Rh
1
6
Ph
H
No₂
H
CH₃
CH₃
H
H
acac

6-204Y
Rh
0
6
Ph
H
No₂
H
CH₃
CH₃
H
H
—
—

6-205
Rh
1
6
Ph
H
No₂
H
CH₃

^tC₄H₉
H
H
pic

6-205X
Rh
1
6
Ph
H
No₂
H
CH₃

^tC₄H₉
H
H
acac

6-205Y
Rh
0
6
Ph
H
No₂
H
CH₃

^tC₄H₉
H
H
—
—

6-206
Rh
1
6
Ph
H
No₂
H

^tC₄H₉
CH₃
H
H
pic

6-206X
Rh
1
6
Ph
H
No₂
H

^tC₄H₉
CH₃
H
H
acac

6-206Y
Rh
0
6
Ph
H
No₂
H

^tC₄H₉
CH₃
H
H
—
—

6-207
Rh
1
6
Ph
H
No₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-207X
Rh
1
6
Ph
H
No₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-207Y
Rh
0
6
Ph
H
No₂
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6-208
Rh
1
6
Ph
H
H
CH₃O
H
CH₃
H
H
pic

6-208X
Rh
1
6
Ph
H
H
CH₃O
H
CH₃
H
H
acac

6-208Y
Rh
0
6
Ph
H
H
CH₃O
H
CH₃
H
H
—
—

6-209
Rh
1
6
Ph
H
CH₃O
H
H
CH₃
H
H
pic

6-209X
Rh
1
6
Ph
H
CH₃O
H
H
CH₃
H
H
acac

6-209Y
Rh
0
6
Ph
H
CH₃O
H
H
CH₃
H
H
—
—

6-210
Rh
1
6
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

6-210X
Rh
1
6
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

6-210Y
Rh
0
6
Ph
H
CH₃O
H
CH₃
CH₃
H
H
—
—

6-211
Rh
1
6
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

6-211X
Rh
1
6
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

6-211Y
Rh
0
6
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
—
—

6-212
Rh
1
6
Ph
H
Si (CH₃)₃
H
H
CH₃
H
H
pic

6-212X
Rh
1
6
Ph
H
Si (CH₃)₃
H
H
CH₃
H
H
acac

6-212Y
Rh
0
6
Ph
H
Si (CH₃)₃
H
H
CH₃
H
H
—
—

6-213
Rh
1
6
Ph
H
Si (CH₃)₃
H
H

^tC₄H₉
H
H
pic

6-213X
Rh
1
6
Ph
H
Si (CH₃)₃
H
H

^tC₄H₉
H
H
acac

6-213Y
Rh
0
6
Ph
H
Si (CH₃)₃
H
H

^tC₄H₉
H
H
—
—

6-214
Rh
1
6
Ph
H
H
Si (CH₃)₃
H
CH₃
H
H
pic

6-214X
Rh
1
6
Ph
H
H
Si (CH₃)₃
H
CM3
H
H
acac

6-214Y
Rh
0
6
Ph
H
H
Si (CH₃)₃
H
CH₃
H
H
—
—

6-215
Rh
1
6
Ph
H
H
H
Si (CH₃)₃
CH₃
H
H
pic

6-215X
Rh
1
6
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
acac

6-215Y
Rh
0
6
Ph
H
H
H
Si (CH₃)₃
CH₃
H
H
—
—

6-216
Rh
1
6
Ph
H
F
H
Si (CH₃)₃
CH₃
H
H
pic

6-216X
Rh
1
6
Ph
H
F
H
Si (CH₃)₃
CH₃
H
H
acac

6-216Y
Rh
0
6
Ph
H
F
H
Si (CH₃)₃
CH₃
H
H
—
—

6-217
Rh
1
6
Ph
H
CF₃
H
Si (CH₃)₃
CH₃
H
H
pic

6-217X
Rh
1
6
Ph
H
CF₃
H
Si (CH₃)₃
CH₃
H
H
acac

6-217Y
Rh
0
6
Ph
H
CF₃
H
Si (CH₃)₃
CH₃
H
H
—
—

6-218
Rh
1
6
Ph
H
CF₃
H
Si (CH₃)₃

^tC₄H₉
H
H
pic

6-218X
Rh
1
6
Ph
H
CF₃
H
Si (CH₃)₃

^tC₄H₉
H
H
acac

6-218Y
Rh
0
6
Ph
H
CF₃
H
Si (CH3)₃

^tC₄H₉
H
H
—
—

6-219
Rh
1
6
Ph
H
Si (CH₃)₃
H
F
CH₃
H
H
pic

6-219X
Rh
1
6
Ph
H
Si (CH₃)₃
H
F
CH₃
H
H
acac

6-219Y
Rh
0
6
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
—
—

6-220
Rh
1
6
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
pic

6-220X
Rh
1
6
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
acac

6-220Y
Rh
0
6
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
—
—

6-221
Rh
1
6
Ph
H
Si (CH₃)₃
H
CF₃
CH₃
H
H
pic

6-221X
Rh
1
6
Ph
H
Si (CH₃)₃
H
CF₃
CH₃
H
H
acac

6-221Y
Rh
0
6
Ph
H
Si (CH₃)₃
H
CF₃
CH₃
H
H
—
—

6-222
Rh
1
6
Ph
H
Si (CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

6-222X
Rh
1
6
Ph
H
Si (CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

6-222Y
Rh
0
6
Ph
H
Si (CH₃)₃
H
CF₃

^tC₄H₉
H
H
—
—

6-223
Rh
1
6
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
CH₃
H
H
pic

6-223X
Rh
1
6
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
CH₃
H
H
acac

6-223Y
Rh
0
6
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
CH₃
H
H
—
—

6-224
Rh
1
6
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H

^tC₄H₉
H
H
pic

6-224X
Rh
1
6
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H

^tC₄H₉
H
H
acac

6-224Y
Rh
0
6
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H

^tC₄H₉
H
H
—
—

6-225
Rh
1
6
Ph
H
H
H
COCH₃
CH₃
H
H
pic

6-225X
Rh
1
6
Ph
H
H
H
COCH₃
CH₃
H
H
acac

6-225Y
Rh
0
6
Ph
H
H
H
COCH₃
CH₃
H
H
—
—

6-226
Rh
1
6
Ph
H
H
COCH₃
H
CH₃
H
H
pic

6-226X
Rh
1
6
Ph
H
H
COCH₃
H
CH₃
H
H
acac

6-226Y
Rh
0
6
Ph
H
H
COCH₃
H
CH₃
H
H
—
—

6-227
Rh
1
6
Ph
H
COCH₃
H
H
CH₃
H
H
pic

6-227X
Rh
1
6
Ph
H
COCH₃
H
H

^tC₄H₉
H
H
acac

6-227Y
Rh
0
6
Ph
H
COCH₃
H
H
CH₃
H
H
—
—

6-228
Rh
1
6
Ph
H
H
BL
CH₃
H
H
pic

6-228X
Rh
1
6
Ph
H
H
BL
CH₃
H
H
acac

6-228Y
Rh
0
6
Ph
H
H
BL

^tC₄H₉
H
H
—
—

6-229
Rh
1
6
Ph
H
H
BL

^tC₄H₉
H
H
pic

6-229X
Rh
1
6
Ph
H
H
BL

^tC₄H₉
H
H
acac

6-229Y
Rh
0
6
Ph
H
H
BL

^tC₄H₉
H
H
—
—

6-230
Rh
1
6
Ph
H
BL
H
CH₃
H
H
pic

6-230X
Rh
1
6
Ph
H
BL
H
CH₃
H
H
acac

6-230Y
Rh
0
6
Ph
H
BL
H
CH₃
H
H
—
—

6-231
Rh
1
6
Ph
H
BL
H

^tC₄H₉
H
H
pic

6-231X
Rh
1
6
Ph
H
BL
H

^tC₄H₉
H
H
acac

6-231Y
Rh
0
6
Ph
H
BL
H

^tC₄H₉
H
H
—
—

6-232
Rh
1
6
Ph
H
H
PL
CH₃
H
H
pic

6-232X
Rh
1
6
Ph
H
H
PL
CH₃
H
H
acac

6-232Y
Rh
0
6
Ph
H
H
PL
CH₃
H
H
—
—

6-233
Rh
1
6
Ph
H
H
PL

^tC₄H₉
H
H
pic

6-233X
Rh
1
6
Ph
H
H
PL

^tC₄H₉
H
H
acac

6-233Y
Rh
0
6
Ph
H
H
PL

^tC₄H₉
H
H
—
—

6-234
Rh
1
6
Ph
H
PL
H
CH₃
H
H
pic

6-234X
Rh
1
6
Ph
H
PL
H
CH₃
H
H
acac

6-234Y
Rh
0
6
Ph
H
PL
H
CH₃
H
H
—
—

6-235
Rh
1
6
Ph
H
PL
H

^tC₄H₉
H
H
pic

6-235X
Rh
1
6
Ph
H
PL
H

^tC₄H₉
H
H
acac

6-235Y
Rh
0
6
Ph
H
PL
H

^tC₄H₉
H
H
—
—

6-236
Rh
1
6
Ph
H
H
MEE1
CH₃
H
H
pic

6-236X
Rh
1
6
Ph
H
H
MEE1
CH₃
H
H
acac

6-236Y
Rh
0
6
Ph
H
H
MEE1
CH₃
H
H
—
—

6-237
Rh
1
6
Ph
H
MEE1
H
CH₃
H
H
pic

6-237X
Rh
1
6
Ph
H
MEE1
H
CH₃
H
H
acac

6-237Y
Rh
0
6
Ph
H
MEE1
H
CH₃
H
H
—
—

6-238
Rh
1
6
Ph
H
H
MEE2
CH₃
H
H
pic

6-238X
Rh
1
6
Ph
H
H
MEE2
CH₃
H
H
acac

6-238Y
Rh
0
6
Ph
H
H
MEE2
CH₃
H
H
—
—

6-239
Rh
1
6
Ph
H
MEE2
H
CH₃
H
H
pic

6-239X
Rh
1
6
Ph
H
MEE2
H
CH₃
H
H
acac

6-239Y
Rh
0
6
Ph
H
MEE2
H
CH₃
H
H
—
—

6-240
Rh
1
6
Ph
H
H
PA1
CH₃
H
H
pic

6-240X
Rh
1
6
Ph
H
H
PA1
CH₃
H
H
acac

6-240Y
Rh
0
6
Ph
H
H
PA1
CH₃
H
H
—
—

6-241
Rh
1
6
Ph
H
PA1
H
CH₃
H
H
pic

6-241X
Rh
1
6
Ph
H
PA1
H
CH₃
H
H
acac

6-241Y
Rh
0
6
Ph
H
PA1
H
CH₃
H
H
—
—

6-242
Rh
1
6
Ph
H
H
PA2
CH₃
H
H
pic

6-242X
Rh
1
6
Ph
H
H
PA2
CH₃
H
H
acac

6-242Y
Rh
0
6
Ph
H
H
PA2
CH₃
H
H
—
—

6-243
Rh
1
6
Ph
H
PA2
H
CH₃
H
H
pic

6-243X
Rh
1
6
Ph
H
PA2
H
CH₃
H
H
acac

6-243Y
Rh
0
6
Ph
H
PA2
H
CH₃
H
H
—
—

6-244
Rh
1
6
Ph
H
H
EA1
CH₃
H
H
pic

6-244X
Rh
1
6
Ph
H
H
EA1
CH₃
H
H
acac

6-244Y
Rh
0
6
Ph
H
H
EA1
CH₃
H
H
—
—

6-245
Rh
1
6
Ph
H
EA2
H
CH₃
H
H
pic

6-245X
Rh
1
6
Ph
H
EA2
H
CH₃
H
H
acac

6-245Y
Rh
0
6
Ph
H
EA2
H
CH₃
H
H
—
—

6-246
Rh
1
6
Ph
H
H
ME
CH₃
H
H
pic

6-246X
Rh
1
6
Ph
H
H
ME
CH₃
H
H
acac

6-246Y
Rh
0
6
Ph
H
H
ME
CH₃
H
H
—
—

6-247
Rh
1
6
Ph
H
ME
H
CH₃
H
H
pic

6-247X
Rh
1
6
Ph
H
ME
H
CH₃
H
H
acac

6-247Y
Rh
0
6
Ph
H
ME
H
CH₃
H
H
—
—

6-248
Rh
1
6
Ph
H
H
AT
CH₃
H
H
pic

6-248X
Rh
1
6
Ph
H
H
AT
CH₃
H
H
acac

6-248Y
Rh
0
6
Ph
H
H
AT
CH₃
H
H
—
—

6-249
Rh
1
6
Ph
H
AT
H
CH₃
H
H
pic

6-249X
Rh
1
6
Ph
H
AT
H

^tC₄H₉
H
H
acac

6-249Y
Rh
0
6
Ph
H
AT
H
CH₃
H
H
—
—

6-250
Rh
1
6
Ph
H
H
MES1
CH₃
H
H
pic

6-250X
Rh
1
6
Ph
H
H
MES1
CH₃
H
H
acac

6-250Y
Rh
0
6
Ph
H
H
MES1
CH₃
H
H
—
—

6-251
Rh
1
6
Ph
H
MES1
H
CH₃
H
H
pic

6-251X
Rh
1
6
Ph
H
MES1
H
CH₃
H
H
acac

6-251Y
Rh
0
6
Ph
H
MES1
H
CH₃
H
H
—
—

6-252
Rh
1
6
Ph
H
H
MES2
CH₃
H
H
pic

6-252X
Rh
1
6
Ph
H
H
MES2
CH₃
H
H
acac

6-252Y
Rh
0
6
Ph
H
H
MES2
CH₃
H
H
—
—

6-253
Rh
1
6
Ph
H
MES2
H
CH₃
H
H
pic

6-253X
Rh
1
6
Ph
H
MES2
H
CH₃
H
H
acac

6-253Y
Rh
0
6
Ph
H
MES2
H
CH₃
H
H
—
—

6-254
Rh
1
6
Ph
H
H
PS1
CH₃
H
H
pic

6-254X
Rh
1
6
Ph
H
H
PS1
CH₃
H
H
acac

6-254Y
Rh
0
6
Ph
H
H
PS1
CH₃
H
H
—
—

6-255
Rh
1
6
Ph
H
PS1
H
CH₃
H
H
pic

6-255X
Rh
1
6
Ph
H
PS1
H
CH₃
H
H
acac

6-255Y
Rh
0
6
Ph
H
PS1
H
CH₃
H
H
—
—

6-256
Rh
1
6
Ph
H
H
PS2
CH₃
H
H
pic

6-256X
Rh
1
6
Ph
H
H
PS2
CH₃
H
H
acac

6-256Y
Rh
0
6
Ph
H
H
PS2
CH₃
H
H
—
—

6-257
Rh
1
6
Ph
H
PS2
H
CH₃
H
H
pic

6-257X
Rh
1
6
Ph
H
PS2
H
CH₃
H
H
acac

6-257Y
Rh
0
6
Ph
H
PS2
H
CH₃
H
H
—
—

6-258
Rh
1
6
Ph
H
H
BAL1
CH₃
H
H
pic

6-258X
Rh
1
6
Ph
H
H
BAL1
CH₃
H
H
acac

6-258Y
Rh
0
6
Ph
H
H
BAL1
CH₃
H
H
—
—

6-250
Rh
1
6
Ph
H
BAL1
H
CH₃
H
H
pic

6-259X
Rh
1
6
Ph
H
BAL1
H
CH₃
H
H
acac

6-259Y
Rh
0
6
Ph
H
BAL1
H
CH₃
H
H
—
—

6-260
Rh
1
6
Ph
H
H
BAL2
CH₃
H
H
pic

6-260X
Rh
1
6
Ph
H
H
BAL2
CH₃
H
H
acac

6-260Y
Rh
0
6
Ph
H
H
BAL2
CH₃
H
H
—
—

6-261
Rh
1
6
Ph
H
BAL2
H
CH₃
H
H
pic

6-261X
Rh
1
6
Ph
H
BAL2
H
CH₃
H
H
acac

6-261Y
Rh
0
6
Ph
H
BAL2
H
CH₃
H
H
—
—

6-262
Rh
1
6
Ph
H
H
MEK1
CH₃
H
H
pic

6-262X
Rh
1
6
Ph
H
H
MEK1
CH₃
H
H
acac

6-262Y
Rh
0
6
Ph
H
H
MEK1
CH₃
H
H
—
—

6-263
Rh
1
6
Ph
H
MEK1
H
CH₃
H
H
pic

6-263X
Rh
1
6
Ph
H
MEK1
H
CH₃
H
H
acac

6-263Y
Rh
0
6
Ph
H
MEK1
H
CH₃
H
H
—
—

6-264
Rh
1
6
Ph
H
H
MEK2
CH₃
H
H
pic

6-264X
Rh
1
6
Ph
H
H
MEK2
CH₃
H
H
acac

6-264Y
Rh
0
6
Ph
H
H
MEK2
CH₃
H
H
—
—

6-265
Rh
1
6
Ph
H
MEK2
H
CH₃
H
H
pic

6-265X
Rh
1
6
Ph
H
MEK2
H
CH₃
H
H
acac

6-265Y
Rh
0
6
Ph
H
MEK2
H
CH₃
H
H
—
—

6-266
Rh
1
6
Ph
H
H
PAL1
CH₃
H
H
pic

6-266X
Rh
1
6
Ph
H
H
PAL1
CH₃
H
H
acac

6-266Y
Rh
0
6
Ph
H
H
PAL1
CH₃
H
H
—
—

6-267
Rh
1
6
Ph
H
PAL1
H
CH₃
H
H
pic

6-267X
Rh
1
6
Ph
H
PAL1
H
CH₃
H
H
acac

6-267Y
Rh
0
6
Ph
H
PAL1
H
CH₃
H
H
—
—

6-268
Rh
1
6
Ph
H
H
PAL2
CH₃
H
H
pic

6-268X
Rh
1
6
Ph
H
H
PAL2
CH₃
H
H
acac

6-268Y
Rh
0
6
Ph
H
H
PAL2
CH₃
H
H
—
—

6-269
Rh
1
6
Ph
H
PAL2
H
CH₃
H
H
pic

6-269X
Rh
1
6
Ph
H
PAL2
H
CH₃
H
H
acac

6-269Y
Rh
0
6
Ph
H
PAL2
H
CH₃
H
H
—
—

6-270
Rh
1
6
Ph
H
H
MMK
CH₃
H
H
pic

6-270X
Rh
1
6
Ph
H
H
MMK
CH₃
H
H
acac

6-270Y
Rh
0
6
Ph
H
H
MMK
CH₃
H
H
—
—

6-271
Rh
1
6
Ph
H
MMK
H
CH₃
H
H
pic

6-271X
Rh
1
6
Ph
H
MMK
H
CH₃
H
H
acac

6-271Y
Rh
0
6
Ph
H
MMK
H
CH₃
H
H
—
—

6-272
Rh
1
6
Ph
H
H
EES1
CH₃
H
H
pic

6-272X
Rh
1
6
Ph
H
H
EES1
CH₃
H
H
acac

6-272Y
Rh
0
6
Ph
H
H
EES1
CH₃
H
H
—
—

6-273
Rh
1
6
Ph
H
EES2
H
CH₃
H
H
pic

6-273X
Rh
1
6
Ph
H
EES2
H
CH₃
H
H
acac

6-273Y
Rh
0
6
Ph
H
EES2
H
CH₃
H
H
—
—

6-274
Rh
1
6
Ph
H
H
PAE1
CH₃
H
H
pic

6-274X
Rh
1
6
Ph
H
H
PAE1
CH₃
H
H
acac

6-274Y
Rh
0
6
Ph
H
H
PAE1
CH₃
H
H
—
—

6-275
Rh
1
6
Ph
H
PAE2
H
CH₃
H
H
pic

6-275X
Rh
1
6
Ph
H
PAE2
H
CH₃
H
H
acac

6-275Y
Rh
0
6
Ph
H
PAE2
H
CH₃
H
H
—
—

6-276
Rh
1
6
Ph
H
H
AME1
CH₃
H
H
pic

6-276X
Rh
1
6
Ph
H
H
AME1
CH₃
H
H
acac

6-276Y
Rh
0
6
Ph
H
H
AME1
CH₃
H
H
—
—

6-277
Rh
1
6
Ph
H
AME1

H
CH₃
H
H
pic

6-277X
Rh
1
6
Ph
H
AME1

H
CH₃
H
H
acac

6-277Y
Rh
0
6
Ph
H
AME1

H
CH₃
H
H
—
—

6-278
Rh
1
6
Ph
H
H
AME2
CH₃
H
H
pic

6-278X
Rh
1
6
Ph
H
H
AME2
CH₃
H
H
acac

6-278Y
Rh
0
6
Ph
H
H
AME2
CH₃
H
H
—
—

6-279
Rh
1
6
Ph
H
AME2
H
CH₃
H
H
pic

6-279X
Rh
1
6
Ph
H
AME2
H
CH₃
H
H
acac

6-279Y
Rh
0
6
Ph
H
AME2
H
CH₃
H
H
—
—

6-280
Rh
1
6
Ph
H
H
EAE1
CH₃
H
H
pic

6-280X
Rh
1
6
Ph
H
H
EAE1
CH₃
H
H
acac

6-280Y
Rh
0
6
Ph
H
H
EAE1
CH₃
H
H
—
—

6-281
Rh
1
6
Ph
H
EAE1
H
CH₃
H
H
pic

6-281X
Rh
1
6
Ph
H
EAE1
H
CH₃
H
H
acac

6-281Y
Rh
0
6
Ph
H
EAE1
H
CH₃
H
H
—
—

6-282
Rh
1
6
Ph
H
H
EAE2
CH₃
H
H
pic

6-282X
Rh
1
6
Ph
H
H
EAE2
CH₃
H
H
acac

6-282Y
Rh
0
6
Ph
H
H
EAE2
CH₃
H
H
—
—

6-283
Rh
1
6
Ph
H
EAE2
H
CH₃
H
H
pic

6-283X
Rh
1
6
Ph
H
EAE2
H
CH₃
H
H
acac

6-283Y
Rh
0
6
Ph
H
EAE2
H
CH₃
H
H
—
—

6-284
Rh
1
6
Ph
H
H
AAE1
CH₃
H
H
pic

6-284X
Rh
1
6
Ph
H
H
AAE1
CH₃
H
H
acac

6-284Y
Rh
0
6
Ph
H
H
AAE1
CH₃
H
H
—
—

6-285
Rh
1
6
Ph
H
AAE1
H
CH₃
H
H
pic

6-285X
Rh
1
6
Ph
H
AAE1
H
CH₃
H
H
acac

6-285Y
Rh
0
6
Ph
H
AAE1
H
CH₃
H
H
—
—

6-286
Rh
1
6
Ph
H
H
AAE2
CH₃
H
H
pic

6-266X
Rh
1
6
Ph
H
H
AAE2
CH₃
H
H
acac

6-286Y
Rh
0
6
Ph
H
H
AAE2
CH₃
H
H
—
—

6-287
Rh
1
6
Ph
H
AAE2
H
CH₃
H
H
pic

6-287X
Rh
1
6
Ph
H
AAE2
H
CH₃
H
H
acac

6-287Y
Rh
0
6
Ph
H
AAE2
H
CH₃
H
H
—
—

6-288
Rh
1
6
Ph
H
H
PME1
CH₃
H
H
pic

6-288X
Rh
1
6
Ph
H
H
PME1
CH₃
H
H
acac

6-288Y
Rh
0
6
Ph
H
H
PME1
CH₃
H
H
—
—

6-289
Rh
1
6
Ph
H
PME1
H
CH₃
H
H
pic

6-289X
Rh
1
6
Ph
H
PME1
H
CH₃
H
H
acac

6-289Y
Rh
0
6
Ph
H
PME1
H
CH₃
H
H
—
—

6-290
Rh
1
6
Ph
H
H
PME2
CH₃
H
H
pic

6-290X
Rh
1
6
Ph
H
H
PME2
CH₃
H
H
acac

6-290Y
Rh
0
6
Ph
H
H
PME2
CH₃
H
H
—
—

6-291
Rh
1
6
Ph
H
PME2
H
CH₃
H
H
pic

6-291X
Rh
1
6
Ph
H
PME2
H
CH₃
H
H
acac

6-291Y
Rh
0
6
Ph
H
PME2
H
CH₃
H
H
—
—

6-292
Rh
1
6
Ph
H
H
MET1
CH₃
H
H
pic

6-292X
Rh
1
6
Ph
H
H
MET1
CH₃
H
H
acac

6-292Y
Rh
0
6
Ph
H
H
MET1
CH₃
H
H
—
—

6-293
Rh
1
6
Ph
H
MET1
H
CH₃
H
H
pic

6-293X
Rh
1
6
Ph
H
MET1
H
CH₃
H
H
acac

6-293Y
Rh
0
6
Ph
H
MET1
H
CH₃
H
H
—
—

6-294
Rh
1
6
Ph
H
H
MET2
CH₃
H
H
pic

6-294X
Rh
1
6
Ph
H
H
MET2
CH₃
H
H
acac

6-294Y
Rh
0
6
Ph
H
H
MET2
CH₃
H
H
—
—

6-295
Rh
1
6
Ph
H
MET2
H
CH₃
H
H
pic

6-295X
Rh
1
6
Ph
H
MET2
H
CH₃
H
H
acac

6-295Y
Rh
0
6
Ph
H
MET2
H
CH₃
H
H
—
—

6-296
Rh
1
6
Ph
H
H
EE1
CH₃
H
H
pic

6-296X
Rh
1
6
Ph
H
H
EE1
CH₃
H
H
acac

6-296Y
Rh
0
6
Ph
H
H
EE1
CH₃
H
H
—
—

6-297
Rh
1
6
Ph
H
EE1
H
CH₃
H
H
pic

6-297X
Rh
1
6
Ph
H
EE1
H
CH₃
H
H
acac

6-297Y
Rh
0
6
Ph
H
EE1
H
CH₃
H
H
—
—

6-298
Rh
1
6
Ph
H
H
EE2
CH₃
H
H
pic

6-298X
Rh
1
6
Ph
H
H
EE2
CH₃
H
H
acac

6-298Y
Rh
0
6
Ph
H
H
EE2
CH₃
H
H
—
—

6-299
Rh
1
6
Ph
H
EE2
H
CH₃
H
H
pic

6-299X
Rh
1
6
Ph
H
EE2
H
CH₃
H
H
acac

6-299Y
Rh
0
6
Ph
H
EE2
H
CH₃
H
H
—
—

6-300
Rh
1
6
Ph
H
H
MS1
CH₃
H
H
pic

6-300X
Rh
1
6
Ph
H
H
MS1
CH₃
H
H
acac

6-300Y
Rh
0
6
Ph
H
H
MS1
CH₃
H
H
—
—

6-301
Rh
1
6
Ph
H
MS1
H
CH₃
H
H
pic

6-301X
Rh
1
6
Ph
H
MS1
H
CH₃
H
H
acac

6-301Y
Rh
0
6
Ph
H
MS1
H
CH₃
H
H
—
—

6-302
Rh
1
6
Ph
H
H
MS2
CH₃
H
H
pic

6-302X
Rh
1
6
Ph
H
H
MS2
CH₃
H
H
acac

6-302Y
Rh
0
6
Ph
H
H
MS2
CH₃
H
H
—
—

6-303
Rh
1
6
Ph
H
MS2
H
CH₃
H
H
pic

6-303X
Rh
1
6
Ph
H
MS2
H
CH₃
H
H
acac

6-303Y
Rh
0
6
Ph
H
MS2
H
CH₃
H
H
—
—

TABLE 21

No.
M
n
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

7-167
Ir
1
7
Ph
H
H
H
H
CM3
H
H
pic

7-167X
Ir
1
7
Ph
H
H
H
H
CH₃
H
H
acac

7-167Y
Ir
0
7
Ph
H
H
H
H
CH₃
H
H
—
—

7-168
Ir
1
7
Ph
H
H
H
H

^tC₄H₉
H
H
pic

7-188X
Ir
1
7
Ph
H
H
H
H

^tC₄H₉
H
H
acac

7-168Y
Ir
0
7
Ph
H
H
H
H

^tC₄H₉
H
H
—
—

7-169
Ir
1
7
Ph
H
F
H
F
CH₃
H
H
pic

7-169X
Ir
1
7
Ph
H
F
H
F
CH₃
H
H
acac

7-169Y
Ir
0
7
Ph
H
F
H
F
CH₃
H
H
—
—

7-170
Ir
1
7
Ph
H
F
H
F

^tC₄H₉
H
H
pic

7-170X
Ir
1
7
Ph
H
F
H
F

^tC₄H₉
H
H
acac

7-170Y
Ir
0
7
Ph
H
F
H
F

^tC₄H₉
H
H
—
—

7-171
Ir
1
7
Ph
F
H
H
F
CH₃
H
H
pic

7-171X
Ir
1
7
Ph
F
H
H
F
CH₃
H
H
scat

7-171Y
Ir
0
7
Ph
F
H
H
F
CH₃
H
H
—
—

7-172
Ir
1
7
Ph
F
H
H
F

^tC₄H₉
H
H
pic

7-172X
Ir
1
7
Ph
F
H
H
F

^tC₄H₉
H
H
acac

7-172Y
Ir
0
7
Ph
F
H
H
F

^tC₄H₉
H
H
—
—

7-173
Ir
1
7
Ph
CF₃
H
CF₃
H
CH₃
H
H
pic

7-173X
Ir
1
7
Ph
CF₃
H
CF₃
H
CH₃
H
H
acac

7-173Y
Ir
0
7
Ph
CF₃
H
CF₃
H
CH₃
H
H
—
—

7-174
Ir
1
7
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

7-174X
Ir
1
7
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

7-174Y
Ir
0
7
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
—
—

7-175
Ir
1
7
Ph
H
F
CF₃
H
CH₃
H
H
pic

7-175X
Ir
1
7
Ph
H
F
CF₃
H
CH₃
H
H
acac

7-175Y
Ir
0
7
Ph
H
F
CF₃
H
CH₃
H
H
—
—

7-176
Ir
1
7
Ph
F
H
CF₃
H
CH₃
H
H
pic

7-176X
Ir
1
7
Ph
F
H
CF₃
H
CH₃
H
H
acac

7-176Y
Ir
0
7
Ph
F
H
CF₃
H
CH₃
H
H
—
—

7-177
Ir
1
7
Ph
F
F
F
F
CH₃
H
H
pic

7-177X
Ir
1
7
Ph
F
F
F
F
CH₃
H
H
acac

7-177Y
Ir
0
7
Ph
F
F
F
F
CH₃
H
H
—
—

7-178
Ir
1
7
Ph
H
F
H
CH₃
CH₃
H
H
pic

7-178X
Ir
1
7
Ph
H
F
H
CH₃
CH₃
H
H
acac

7-178Y
Ir
0
7
Ph
H
F
H
CH₃
CH₃
H
H
—
—

7-179
Ir
1
7
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

7-179X
Ir
1
7
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

7-179Y
Ir
0
7
Ph
H
F
H
CH₃

^tC₄H₉
H
H
—
—

7-180
Ir
1
7
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

7-180X
Ir
1
7
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

7-180Y
Ir
0
7
Ph
H
F
H

^tC₄H₉
CH₃
H
H
—
—

7-181
Ir
1
7
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-181X
Ir
1
7
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-181Y
Ir
0
7
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-182
Ir
1
7
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

7-182X
Ir
1
7
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

7-182Y
Ir
0
7
Ph
H
CF₃
H
CF₃
CH₃
H
H
—
—

7-183
Ir
1
7
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

7-183X
Ir
1
7
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

7-183Y
Ir
0
7
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
—
—

7-184
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

7-184X
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

7-184Y
Ir
0
7
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
—
—

7-185
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-185X
Ir
1
7
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-185Y
Ir
0
7
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-186
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
pic

7-186X
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

7-186Y
Ir
0
7
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
—
—

7-187
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-187X
Ir
1
7
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-187Y
Ir
0
7
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-188
Ir
1
7
Ph
H
CF₃
H
CH₃
CH₃
H
H
pic

7-188X
Ir
1
7
Ph
H
CF₃
H
CH₃
CH₃
H
H
acac

7-188Y
Ir
0
7
Ph
H
CF₃
H
CH₃
CH₃
H
H
—
—

7-189
Ir
1
7
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

7-189X
Ir
1
7
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

7-189Y
Ir
0
7
Ph
H
CF₃
CF₃
H
CH₃
H
H
—
—

7-190
Ir
1
7
Ph
H
H
No₂
H
CH₃
H
H
pic

7-190X
Ir
1
7
Ph
H
H
No₂
H
CH₃
H
H
acac

7-190Y
Ir
0
7
Ph
H
H
No₂
H
CH₃
H
H
—
—

7-191
Ir
1
7
Ph
H
H
No₂
H

^tC₄H₉
H
H
pic

7-191X
Ir
1
7
Ph
H
H
No₂
H

^tC₄H₉
H
H
acac

7-191Y
Ir
0
7
Ph
H
H
No₂
H

^tC₄H₉
H
H
—
—

7-192
Ir
1
7
Ph
F
H
No₂
H
CH₃
H
H
pic

7-192X
Ir
1
7
Ph
F
H
No₂
H
CH₃
H
H
acac

7-192Y
Ir
0
7
Ph
F
H
No₂
H
CH₃
H
H
—
—

7-193
Ir
1
7
Ph
F
H
No₂
F
CH₃
H
H
pic

7-193X
Ir
1
7
Ph
F
H
No₂
F
CH₃
H
H
acac

7-193Y
Ir
0
7
Ph
F
H
No₂
F
CH₃
H
H
—
—

7-194
Ir
1
7
Ph
H
No₂
H
No₂
CH₃
H
H
pic

7-194X
Ir
1
7
Ph
H
No₂
H
No₂
CH₃
H
H
acac

7-194Y
Ir
0
7
Ph
H
No₂
H
No₂
CH₃
H
H
—
—

7-195
Ir
1
7
Ph
H
No₂
H
No₂

^tC₄H₉
H
H
pic

7-195X
Ir
1
7
Ph
H
No₂
H
No₂

^tC₄H₉
H
H
acac

7-195Y
Ir
0
7
Ph
H
No₂
H
No₂

^tC₄H₉
H
H
—
—

7-196
Ir
1
7
Ph
No₂
H
H
No₂
CH₃
H
H
pic

7-196X
Ir
1
7
Ph
No₂
H
H
No₂
CH₃
H
H
acac

7-196Y
Ir
0
7
Ph
No₂
H
H
No₂
CH₃
H
H
—
—

7-197
Ir
1
7
Ph
No₂
H
H
No₂

^tC₄H₉
H
H
pic

7-197X
Ir
1
7
Ph
No₂
H
H
No₂

^tC₄H₉
H
H
acac

7-197Y
Ir
0
7
Ph
No₂
H
H
No₂

^tC₄H₉
H
H
—
—

7-198
Ir
1
7
Ph
H
H
CF₃
H
CH₃
H
H
pic

7-198X
Ir
1
7
Ph
H
H
CF₃
H
CH₃
H
H
acac

7-198Y
Ir
0
7
Ph
H
H
CF₃
H
CH₃
H
H
—
—

7-199
Ir
1
7
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

7-199X
Ir
1
7
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

7-199Y
Ir
0
7
Ph
H
H
CF₃
H

^tC₄H₉
H
H
—
—

7-200
Ir
1
7
Ph
H
CI
CF₃
H
CH₃
H
H
pic

7-200X
Ir
1
7
Ph
H
CI
CF₃
H
CH₃
H
H
acac

7-200Y
Ir
0
7
Ph
H
CI
CF₃
H
CH₃
H
H
—
—

7-201
Ir
1
7
Ph
H
CI
CF₃
H

^tC₄H₉
H
H
pic

7-201X
Ir
1
7
Ph
H
CI
CF₃
H

^tC₄H₉
H
H
acac

7-201Y
Ir
0
7
Ph
H
CI
CF₃
H

^tC₄H₉
H
H
—
—

7-202
Ir
1
7
Ph
H
No₂
H
H
CH₃
H
H
pic

7-202X
Ir
1
7
Ph
H
No₂
H
H
CH₃
H
H
acac

7-202Y
Ir
0
7
Ph
H
No₂
H
H
CH₃
H
H
—
—

7-203
Ir
1
7
Ph
H
CF₃
H
H
CH₃
H
H
pic

7-203X
Ir
1
7
Ph
H
CF₃
H
H
CH₃
H
H
acac

7-203Y
Ir
0
7
Ph
H
CF₃
H
H
CH₃
H
H
—
—

7-204
Ir
1
7
Ph
H
No₂
H
CH₃
CH₃
H
H
pic

7-204X
Ir
1
7
Ph
H
No₂
H
CH₃
CH₃
H
H
acac

7-204Y
Ir
0
7
Ph
H
No₂
H
CH₃
CH₃
H
H
—
—

7-205
Ir
1
7
Ph
H
No₂
H
CH₃

^tC₄H₉
H
H
pic

7-205X
Ir
1
7
Ph
H
No₂
H
CH₃

^tC₄H₉
H
H
acac

7-205Y
Ir
0
7
Ph
H
No₂
H
CH₃

^tC₄H₉
H
H
—
—

7-206
Ir
1
7
Ph
H
No₂
H

^tC₄H₉
CH₃
H
H
pic

7-206X
Ir
1
7
Ph
H
No₂
H

^tC₄H₉
CH₃
H
H
acac

7-206Y
Ir
0
7
Ph
H
No₂
H

^tC₄H₉
CH₃
H
H
—
—

7-207
Ir
1
7
Ph
H
No₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-207X
Ir
1
7
Ph
H
No₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-207Y
Ir
0
7
Ph
H
No₂
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-208
Ir
1
7
Ph
H
H
CH₃O
H
CH₃
H
H
pic

7-208X
Ir
1
7
Ph
H
H
CH₃O
H
CH₃
H
H
acac

7-208Y
Ir
0
7
Ph
H
H
CH₃O
H
CH₃
H
H
—
—

7-209
Ir
1
7
Ph
H
CH₃O
H
H
CH₃
H
H
pic

7-209X
Ir
1
7
Ph
H
CH₃O
H
H
CH₃
H
H
acac

7-209Y
Ir
0
7
Ph
H
CH₃O
H
H
CH₃
H
H
—
—

7-210
Ir
1
7
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

7-210X
Ir
1
7
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

7-210Y
Ir
0
7
Ph
H
CH₃O
H
CH₃
CH₃
H
H
—
—

7-211
Ir
1
7
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

7-211X
Ir
1
7
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

7-211Y
Ir
0
7
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
—
—

7-212
Ir
1
7
Ph
H
Si (CH₃)₃
H
H
CH₃
H
H
pic

7-212X
Ir
1
7
Ph
H
Si (CH₃)₃
H
H
CH₃
H
H
acac

7-212Y
Ir
0
7
Ph
H
Si (CH₃)₃
H
H
CH₃
H
H
—
—

7-213
Ir
1
7
Ph
H
Si (CH₃)₃
H
H

^tC₄H₉
H
H
pic

7-213X
Ir
1
7
Ph
H
Si (CH₃)₃
H
H

^tC₄H₉
H
H
acac

7-213Y
Ir
0
7
Ph
H
Si (CH₃)₃
H
H

^tC₄H₉
H
H
—
—

7-214
Ir
1
7
Ph
H
H
Si (CH₃)₃
H
CH₃
H
H
pic

7-214X
Ir
1
7
Ph
H
H
Si (CH₃)₃
H
CH₃
H
H
acac

7-214Y
Ir
0
7
Ph
H
H
Si (CH₃)₃
H
CH₃
H
H
—
—

7-215
Ir
1
7
Ph
H
H
H
Si (CH₃)₃
CH₃
H
H
pic

7-215X
Ir
1
7
Ph
H
H
H
Si (CH₃)₃
CH₃
H
H
acac

7-215Y
Ir
0
7
Ph
H
H
H
Si (CH₃)₃
CH₃
H
H
—
—

7-216
Ir
1
7
Ph
H
F
H
Si (CH₃)₃
CH₃
H
H
pic

7-216X
Ir
1
7
Ph
H
F
H
Si (CH₃)₃
CH₃
H
H
acac

7-216Y
Ir
0
7
Ph
H
F
H
Si (CH₃)₃
CH₃
H
H
—
—

7-217
Ir
1
7
Ph
H
CF₃
H
Si (CH₃)₃
CH₃
H
H
pic

7-217X
Ir
1
7
Ph
H
CF₃
H
Si (CH₃)₃
CH₃
H
H
acac

7-217Y
Ir
0
7
Ph
H
CF₃
H
Si (CH₃)₃
CH₃
H
H
—
—

7-218
Ir
1
7
Ph
H
CF₃
H
Si (CH₃)₃

^tC₄H₉
H
H
pic

7-218X
Ir
1
7
Ph
H
CF₃
H
Si (CH₃)₃

^tC₄H₉
H
H
acac

7-218Y
Ir
0
7
Ph
H
CF₃
H
Si (CH₃)₃

^tC₄H₉
H
H
—
—

7-219
Ir
1
7
Ph
H
Si (CH₃)₃
H
F
CH₃
H
H
pic

7-219X
Ir
1
7
Ph
H
Si (CH₃)₃
H
F
CH₃
H
H
acac

7-219Y
Ir
0
7
Ph
H
Si (CH₃)₃
H
F
CH₃
H
H
—
—

7-220
Ir
1
7
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
pic

7-220X
Ir
1
7
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
acac

7-220Y
Ir
0
7
Ph
H
Si (CH₃)₃
H
F

^tC₄H₉
H
H
—
—

7-221
Ir
1
7
Ph
H
Si (CH₃)₃
H
CF₃
CH₃
H
H
pic

7-221X
Ir
1
7
Ph
H
Si (CH₃)₃
H
CF₃
CH₃
H
H
acac

7-221Y
Ir
0
7
Ph
H
Si (CH₃)₃
H
CF₃
CH₃
H
H
—
—

7-222
Ir
1
7
Ph
H
Si (CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

7-222X
Ir
1
7
Ph
H
Si (CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

7-222Y
Ir
0
7
Ph
H
Si (CH₃)₃
H
CF₃

^tC₄H₉
H
H
—
—

7-223
Ir
1
7
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
CH₃
H
H
pic

7-223X
Ir
1
7
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
CH₃
H
H
acac

7-223Y
Ir
0
7
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H
CH₃
H
H
—
—

7-224
Ir
1
7
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H

^tC₄H₉
H
H
pic

7-224X
Ir
1
7
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H

^tC₄H₉
H
H
acac

7-224Y
Ir
0
7
Ph
Si (CH₃)₃
H
Si (CH₃)₃
H

^tC₄H₉
H
H
—
—

7-225
Ir
1
7
Ph
H
H
H
COCH₃
CH₃
H
H
pic

7-225X
Ir
1
7
Ph
H
H
H
COCH₃
CH₃
H
H
acac

7-225Y
Ir
0
7
Ph
H
H
H
COCH₃
CH₃
H
H
—
—

7-226
Ir
1
7
Ph
H
H
COCH₃
H
CH₃
H
H
pic

7-226X
Ir
1
7
Ph
H
H
COCH₃
H
CH₃
H
H
acac

7-226Y
Ir
0
7
Ph
H
H
COCH₃
H
CH₃
H
H
—
—

7-227
Ir
1
7
Ph
H
COCH₃
H
H
CH₃
H
H
pic

7-227X
Ir
1
7
Ph
H
COCH₃
H
H
CH₃
H
H
acac

7-227Y
Ir
0
7
Ph
H
COCH₃
H
H
CH₃
H
H
—
—

7-228
Ir
1
7
Ph
H
H
BL
CH₃
H
H
pic

7-228X
Ir
1
7
Ph
H
H
BL
CH₃
H
H
acac

7-228Y
Ir
0
7
Ph
H
H
BL
CH₃
H
H
—
—

7-229
Ir
1
7
Ph
H
H
BL

^tC₄H₉
H
H
pic

7-229X
Ir
1
7
Ph
H
H
BL

^tC₄H₉
H
H
acac

7-229Y
Ir
0
7
Ph
H
H
BL

^tC₄H₉
H
H
—
—

7-230
Ir
1
7
Ph
H
BL

H
CH₃
H
H
pic

7-230X
Ir
1
7
Ph
H
BL

H
CH₃
H
H
acac

7-230Y
Ir
0
7
Ph
H
BL

H
CH₃
H
H
—
—

7-231
Ir
1
7
Ph
H
BL

H

^tC₄H₉
H
H
pic

7-231X
Ir
1
7
Ph
H
BL

H

^tC₄H₉
H
H
acac

7-231Y
Ir
0
7
Ph
H
BL

H

^tC₄H₉
H
H
—
—

7-232
Ir
1
7
Ph
H
H
PL
CH₃
H
H
pic

7-232X
Ir
1
7
Ph
H
H
PL
CH₃
H
H
acac

7-232Y
Ir
0
7
Ph
H
H
PL
CH₃
H
H
—
—

7-233
Ir
1
7
Ph
H
H
PL

^tC₄H₉
H
H
pic

7-233X
Ir
1
7
Ph
H
H
PL

^tC₄H₉
H
H
acac

7-233Y
Ir
0
7
Ph
H
H
PL

^tC₄H₉
H
H
—
—

7-234
Ir
1
7
Ph
H
PL
H
CH₃
H
H
pic

7-234X
Ir
1
7
Ph
H
PL
H
CH₃
H
H
acac

7-234Y
Ir
0
7
Ph
H
PL
H
CH₃
H
H
—
—

7-235
Ir
1
7
Ph
H
PL
H

^tC₄H₉
H
H
pic

7-235X
Ir
1
7
Ph
H
PL
H

^tC₄H₉
H
H
acac

7-235Y
Ir
0
7
Ph
H
PL
H

^tC₄H₉
H
H
—
—

7-236
Ir
1
7
Ph
H
H
MEE1
CH₃
H
H
pic

7-236X
Ir
1
7
Ph
H
H
MEE1
CH₃
H
H
acac

7-236Y
Ir
0
7
Ph
H
H
MEE1
CH₃
H
H
—
—

7-237
Ir
1
7
Ph
H
MEE1
H
CH₃
H
H
pic

7-237X
Ir
1
7
Ph
H
MEE1
H
CH₃
H
H
acac

7-237Y
Ir
0
7
Ph
H
MEE1
H
CH₃
H
H
—
—

7-238
Ir
1
7
Ph
H
H
MEE2
CH₃
H
H
pic

7-238X
Ir
1
7
Ph
H
H
MEE2
CH₃
H
H
acac

7-238Y
Ir
0
7
Ph
H
H
MEE2
CH₃
H
H
—
—

7-239
Ir
1
7
Ph
H
MEE2
H
CH₃
H
H
pic

7-239X
Ir
1
7
Ph
H
MEE2
H
CH₃
H
H
acac

7-239Y
Ir
0
7
Ph
H
MEE2
H
CH₃
H
H
—
—

7-240
Ir
1
7
Ph
H
H
PA1
CH₃
H
H
pic

7-240X
Ir
1
7
Ph
H
H
PA1
CH₃
H
H
acac

7-240Y
Ir
0
7
Ph
H
H
PA1
CH₃
H
H
—
—

7-241
Ir
1
7
Ph
H
PA1
H
CH₃
H
H
pic

7-241X
Ir
1
7
Ph
H
PA1
H
CH₃
H
H
acac

7-241Y
Ir
0
7
Ph
H
PA1
H
CH₃
H
H
—
—

7-242
Ir
1
7
Ph
H
H
PA2
CH₃
H
H
pic

7-242X
Ir
1
7
Ph
H
H
PA2
CH₃
H
H
acac

7-242Y
Ir
0
7
Ph
H
H
PA2
CH₃
H
H
—
—

7-243
Ir
1
7
Ph
H
PA2
H
CH₃
H
H
pic

7-243X
Ir
1
7
Ph
H
PA2
H
CH₃
H
H
acac

7-243Y
Ir
0
7
Ph
H
PA2
H
CH₃
H
H
—
—

7-244
Ir
1
7
Ph
H
H
EA1
CH₃
H
H
pic

7-244X
Ir
1
7
Ph
H
H
EA1
CH₃
H
H
acac

7-244Y
Ir
0
7
Ph
H
H
EA1
CH₃
H
H
—
—

7-245
Ir
1
7
Ph
H
EA2
H
CH₃
H
H
pic

7-245X
Ir
1
7
Ph
H
EA2
H
CH₃
H
H
acac

7-245Y
Ir
0
7
Ph
H
EA2
H
CH₃
H
H
—
—

7-246
Ir
1
7
Ph
H
H
ME
CH₃
H
H
pic

7-248X
Ir
1
7
Ph
H
H
ME
CH₃
H
H
acac

7-246Y
Ir
0
7
Ph
H
H
ME
CH₃
H
H
—
—

7-247
Ir
1
7
Ph
H
ME
H
CH₃
H
H
pic

7-247X
Ir
1
7
Ph
H
ME
H
CH₃
H
H
acac

7-247Y
Ir
0
7
Ph
H
ME
H
CH₃
H
H
—
—

7-248
Ir
1
7
Ph
H
H
AT
CH₃
H
H
pic

7-248X
Ir
1
7
Ph
H
H
AT
CH₃
H
H
acac

7-248Y
Ir
0
7
Ph
H
H
AT
CH₃
H
H
—
—

7-249
Ir
1
7
Ph
H
AT
H
CH₃
H
H
pic

7-249X
Ir
1
7
Ph
H
AT
H
CH₃
H
H
acac

7-249Y
Ir
0
7
Ph
H
AT
H
CH₃
H
H
—
—

7-250
Ir
1
7
Ph
H
H
MES1
CH₃
H
H
pic

7-250X
Ir
1
7
Ph
H
H
MES1
CH₃
H
H
acac

7-250Y
Ir
0
7
Ph
H
H
MES1
CH₃
H
H
—
—

7-251
Ir
1
7
Ph
H
MES1
H
CH₃
H
H
pic

7-251X
Ir
1
7
Ph
H
MES1
H
CH₃
H
H
acac

7-251Y
Ir
0
7
Ph
H
MES1
H
CH₃
H
H
—
—

7-252
Ir
1
7
Ph
H
H
MES2
CH₃
H
H
pic

7-252X
Ir
1
7
Ph
H
H
MES2
CH₃
H
H
acac

7-252Y
Ir
0
7
Ph
H
H
MES2
CH₃
H
H
—
—

7-253
Ir
1
7
Ph
H
MES2
H
CH₃
H
H
pic

7-253X
Ir
1
7
Ph
H
MES2
H
CH₃
H
H
acac

7-253Y
Ir
0
7
Ph
H
MES2
H
CH₃
H
H
—
—

7-254
Ir
1
7
Ph
H
H
PS1
CH₃
H
H
pic

7-254X
Ir
1
7
Ph
H
H
PS1
CH₃
H
H
acac

7-254Y
Ir
0
7
Ph
H
H
PS1
CH₃
H
H
—
—

7-255
Ir
1
7
Ph
H
PS1
H
CH₃
H
H
pic

7-255X
Ir
1
7
Ph
H
PS1
H
CH₃
H
H
acac

7-255Y
Ir
0
7
Ph
H
PS1
H
CH₃
H
H
—
—

7-256
Ir
1
7
Ph
H
H
PS2
CH₃
H
H
pic

7-256X
Ir
1
7
Ph
H
H
PS2
CH₃
H
H
acac

7-256Y
Ir
0
7
Ph
H
H
PS2
CH₃
H
H
—
—

7-257
Ir
1
7
Ph
H
PS2
H
CH₃
H
H
pic

7-257X
Ir
1
7
Ph
H
PS2
H
CH₃
H
H
acac

7-257Y
Ir
0
7
Ph
H
PS2
H
CH₃
H
H
—
—

7-258
Ir
1
7
Ph
H
H
BAL1
CH₃
H
H
pic

7-258X
Ir
1
7
Ph
H
H
BAL1
CH₃
H
H
acac

7-258Y
Ir
0
7
Ph
H
H
BAL1
CH₃
H
H
—
—

7-259
Ir
1
7
Ph
H
BAL1
H
CH₃
H
H
pic

7-259X
Ir
1
7
Ph
H
BAL1
H
CH₃
H
H
acac

7-259Y
Ir
0
7
Ph
H
BAL1
H
CH₃
H
H
—
—

7-260
Ir
1
7
Ph
H
H
BAL2
CH₃
H
H
pic

7-260X
Ir
1
7
Ph
H
H
BAL2
CH₃
H
H
acac

7-260Y
Ir
0
7
Ph
H
H
BAL2
CH₃
H
H
—
—

7-261
Ir
1
7
Ph
H
BAL2
H
CH₃
H
H
pic

7-261X
Ir
1
7
Ph
H
BAL2
H
CH₃
H
H
acac

7-261Y
Ir
0
7
Ph
H
BAL2
H
CH₃
H
H
—
—

7-262
Ir
1
7
Ph
H
H
MEK1
CH₃
H
H
pic

7-262X
Ir
1
7
Ph
H
H
MEK1
CH₃
H
H
acac

7-262Y
Ir
0
7
Ph
H
H
MEK1
CH₃
H
H
—
—

7-263
Ir
1
7
Ph
H
MEK1
H
CH₃
H
H
pic

7-263X
Ir
1
7
Ph
H
MEK1
H
CH₃
H
H
acac

7-263Y
Ir
0
7
Ph
H
MEK1
H
CH₃
H
H
—
—

7-264
Ir
1
7
Ph
H
H
MEK2
CH₃
H
H
pic

7-264X
Ir
1
7
Ph
H
H
MEK2
CH₃
H
H
acac

7-264Y
Ir
0
7
Ph
H
H
MEK2
CH₃
H
H
—
—

7-265
Ir
1
7
Ph
H
MEK2
H
CH₃
H
H
pic

7-265X
Ir
1
7
Ph
H
MEK2
H
CH₃
H
H
acac

7-265Y
Ir
0
7
Ph
H
MEK2
H
CH₃
H
H
—
—

7-266
Ir
1
7
Ph
H
H
PAL1
CH₃
H
H
pic

7-266X
Ir
1
7
Ph
H
H
PAL1
CH₃
H
H
acac

7-266Y
Ir
0
7
Ph
H
H
PAL1
CH₃
H
H
—
—

7-267
Ir
1
7
Ph
H
PAL1
H
CH₃
H
H
pic

7-267X
Ir
1
7
Ph
H
PAL1
H
CH₃
H
H
acac

7-267Y
Ir
0
7
Ph
H
PAL1
H
CH₃
H
H
—
—

7-268
Ir
1
7
Ph
H
H
PAL2
CH₃
H
H
pic

7-268X
Ir
1
7
Ph
H
H
PAL2
CH₃
H
H
acac

7-268Y
Ir
0
7
Ph
H
H
PAL2
CH₃
H
H
—
—

7-289
Ir
1
7
Ph
H
PAL2
H
CH₃
H
H
pic

7-269X
Ir
1
7
Ph
H
PAL2
H
CH₃
H
H
acac

7-269Y
Ir
0
7
Ph
H
PAL2
H
CH₃
H
H
—
—

7-270
Ir
1
7
Ph
H
H
MMK
CH₃
H
H
pic

7-270X
Ir
1
7
Ph
H
H
MMK
CH₃
H
H
acac

7-270Y
Ir
0
7
Ph
H
H
MMK
CH₃
H
H
—
—

7-271
Ir
1
7
Ph
H
MMK
H
CH₃
H
H
pic

7-271X
Ir
1
7
Ph
H
MMK
H
CH₃
H
H
acac

7-271Y
Ir
0
7
Ph
H
MMK
H
CH₃
H
H
—
—

7-272
Ir
1
7
Ph
H
H
EES1
CH₃
H
H
pic

7-272X
Ir
1
7
Ph
H
H
EES1
CH₃
H
H
acac

7-272Y
Ir
0
7
Ph
H
H
EES1
CH₃
H
H
—
—

7-273
Ir
1
7
Ph
H
EES2

H
CH₃
H
H
pic

7-273X
Ir
1
7
Ph
H
EES2

H
CH₃
H
H
acac

7-273Y
Ir
0
7
Ph
H
EES2

H
CH₃
H
H
—
—

7-274
Ir
1
7
Ph
H
H
PAE1
CH₃
H
H
pic

7-274X
Ir
1
7
Ph
H
H
PAE1
CH₃
H
H
acac

7-274Y
Ir
0
7
Ph
H
H
PAE1
CH₃
H
H
—
—

7-275
Ir
1
7
Ph
H
PAE2
H
CH₃
H
H
pic

7-275X
Ir
1
7
Ph
H
PAE2
H
CH₃
H
H
acac

7-275Y
Ir
0
7
Ph
H
PAE2
H

^tC₄H₉
H
H
—
—

7-276
Ir
1
7
Ph
H
H
AME1

^tC₄H₉
H
H
pic

7-276X
Ir
1
7
Ph
H
H
AME1
CH₃
H
H
acac

7-276Y
Ir
0
7
Ph
H
H
AME1
CH₃
H
H
—
—

7-277
Ir
1
7
Ph
H
AME1
H

^tC₄H₉
H
H
pic

7-277X
Ir
1
7
Ph
H
AME1
H
CH₃
H
H
acac

7-277Y
Ir
0
7
Ph
H
AME1
H
CH₃
H
H
—
—

7-278
Ir
1
7
Ph
H
H
AME2
CH₃
H
H
pic

7-278X
Ir
1
7
Ph
H
H
AME2
CH₃
H
H
acac

7-278Y
Ir
0
7
Ph
H
H
AME2
CH₃
H
H
—
—

7-279
Ir
1
7
Ph
H
AME2
H
CH₃
H
H
pic

7-279X
Ir
1
7
Ph
H
AME2
H
CH₃
H
H
acac

7-279Y
Ir
0
7
Ph
H
AME2
H
CH₃
H
H
—
—

7-280
Ir
1
7
Ph
H
H
EAE1
CH₃
H
H
pic

7-280X
Ir
1
7
Ph
H
H
EAE1
CH₃
H
H
acac

7-280Y
Ir
0
7
Ph
H
H
EAE1
CH₃
H
H
—
—

7-281
Ir
1
7
Ph
H
EAE1
H
CH₃
H
H
pic

7-281X
Ir
1
7
Ph
H
EAE1
H
CH₃
H
H
acac

7-281Y
Ir
0
7
Ph
H
EAE1
H
CH₃
H
H
—
—

7-282
Ir
1
7
Ph
H
H
EAE2
CH₃
H
H
pic

7-282X
Ir
1
7
Ph
H
H
EAE2
CH₃
H
H
acac

7-282Y
Ir
0
7
Ph
11
H
EAE2
CH₃
H
H
—
—

7-283
Ir
1
7
Ph
H
EAE2
H
CH₃
H
H
pic

7-283X
Ir
1
7
Ph
H
EAE2
H
CH₃
H
H
acac

7-283Y
Ir
0
7
Ph
H
EAE2
H
CH₃
H
H
—
—

7-284
Ir
1
7
Ph
H
H
AAE1
CH₃
H
H
pic

7-284X
Ir
1
7
Ph
H
H
AAE1
CH₃
H
H
acac

7-284Y
Ir
0
7
Ph
H
H
AAE1
CH₃
H
H
—
—

7-285
Ir
1
7
Ph
H
AAE1
H
CH₃
H
H
pic

7-285X
Ir
1
7
Ph
H
AAE1
H
CH₃
H
H
acac

7-285Y
Ir
0
7
Ph
H
AAE1
H
CH₃
H
H
—
—

7-286
Ir
1
7
Ph
H
H
AAE2
CH₃
H
H
pic

7-286X
Ir
1
7
Ph
H
H
AAE2
CH₃
H
H
acac

7-286Y
Ir
0
7
Ph
H
H
AAE2
CH₃
H
H
—
—

7-287
Ir
1
7
Ph
H
AAE2
H
CH₃
H
H
pic

7-287X
Ir
1
7
Ph
H
AAE2
H
CH₃
H
H
acac

7-287Y
Ir
0
7
Ph
H
AAE2
H
CH₃
H
H
—
—

7-288
Ir
1
7
Ph
H
H
PME1
CH₃
H
H
pic

7-288X
Ir
1
7
Ph
H
H
PME1
CH₃
H
H
acac

7-288Y
Ir
0
7
Ph
H
H
PME1
CH₃
H
H
—
—

7-289
Ir
1
7
Ph
H
PME1
H
CH₃
H
H
pic

7-289X
Ir
1
7
Ph
H
PME1
H
CH₃
H
H
acac

7-289Y
Ir
0
7
Ph
H
PME1
H
CH₃
H
H
—
—

7-290
Ir
1
7
Ph
H
H
PME2
CH₃
H
H
pic

7-290X
Ir
1
7
Ph
H
H
PME2
CH₃
H
H
acac

7-290Y
Ir
0
7
Ph
H
H
PME2
CH₃
H
H
—
—

7-291
Ir
1
7
Ph
H
PME2
H
CH₃
H
H
pic

7-291X
Ir
1
7
Ph
H
PME2
H
CH₃
H
H
acac

7-291Y
Ir
0
7
Ph
H
PME2
H
CH₃
H
H
—
—

7-292
Ir
1
7
Ph
H
H
MET1
CH₃
H
H
pic

7-292X
Ir
1
7
Ph
H
H
MET1
CH₃
H
H
acac

7-292Y
Ir
0
7
Ph
H
H
MET1
CH₃
H
H
—
—

7-293
Ir
1
7
Ph
H
MET1
H
CH₃
H
H
pic

7-293X
Ir
1
7
Ph
H
MET1
H
CH₃
H
H
acac

7-293Y
Ir
0
7
Ph
H
MET1
H
CH₃
H
H
—
—

7-294
Ir
1
7
Ph
H
H
MET2
CH₃
H
H
pic

7-294X
Ir
1
7
Ph
H
H
MET2

^tC₄H₉
H
H
acac

7-294Y
Ir
0
7
Ph
H
H
MET2
CH₃
H
H
—
—

7-295
Ir
1
7
Ph
H
MET2
H
CH₃
H
H
pic

7-295X
Ir
1
7
Ph
H
MET2
H
CH₃
H
H
acac

7-295Y
Ir
0
7
Ph
H
MET2
H
CH₃
H
H
—
—

7-296
Ir
1
7
Ph
H
H
EE1
CH₃
H
H
pic

7-296X
Ir
1
7
Ph
H
H
EE1
CH₃
H
H
acac

7-296Y
Rh
0
7
Ph
H
H
EE1
CH₃
H
H
—
—

7-297
Rh
1
7
Ph
H
EE1
H
CH₃
H
H
pic

7-297X
Rh
1
7
Ph
H
EE1
H
CH₃
H
H
acac

7-297Y
Rh
0
7
Ph
H
EE1
H
CH₃
H
H
—
—

7-298
Rh
1
7
Ph
H
H
EE2
CH₃
H
H
pia

7-298X
Rh
1
7
Ph
H
H
EE2
CH₃
H
H
acac

7-298Y
Rh
0
7
Ph
H
H
EE2
CH₃
H
H
—
—

7-299
Rh
1
7
Ph
H
EE2
H
CH₃
H
H
pic

7-299X
Rh
1
7
Ph
H
EE2
H
CH₃
H
H
acac

7-299Y
Rh
0
7
Ph
H
EE2
H
CH₃
H
H
—
—

7-300
Rh
1
7
Ph
H
H
MS1
CH₃
H
H
pic

7-300X
Rh
1
7
Ph
H
H
MS1
CH₃
H
H
acac

7-300Y
Rh
0
7
Ph
H
H
MS1
CH₃
H
H
—
—

7-301
Rh
1
7
Ph
H
MS1
H
CH₃
H
H
pic

7-301X
Rh
1
7
Ph
H
MS1
H
CH₃
H
H
acac

7-301Y
Rh
0
7
Ph
H
MS1
H
CH₃
H
H
—
—

7-302
Rh
1
7
Ph
H
H
MS2
CH₃
H
H
pic

7-302X
Rh
1
7
Ph
H
H
MS2
CH₃
H
H
acac

7-302Y
Rh
0
7
Ph
H
H
MS2
CH₃
H
H
—
—

7-303
Rh
1
7
Ph
H
MS2
H
CH₃
H
H
pic

7-303X
Rh
1
7
Ph
H
MS2
H
CH₃
H
H
acac

7-303Y
Rh
0
7
Ph
H
MS2
H
CH₃
H
H
—
—

embedded image

TABLE 22

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹ L²

1-305
Rh
1
1
Nap1
—
—
H
H
H
H
H
pic

1-305X
Rh
1
1
Nap1
—
—
H
H
H
H
H
acac

1-305Y
Rh
0
1
Nap1
—
—
H
H
H
H
H
— —

1-306
Rh
1
1
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

1-306X
Rh
1
1
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

1-306Y
Rh
0
1
Nap1
—
—

^tC₄H₉
H
H
H
H
— —

1-307
Rh
1
1
Nap1
—
—
CH₃
H
H
H
H
pic

1-307X
Rh
1
1
Nap1
—
—
CH₃
H
H
H
H
acac

1-307Y
Rh
0
1
Nap1
—
—
CH₃
H
H
H
H
— —

1-308
Rh
1
1
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-308X
Rh
1
1
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-308Y
Rh
0
1
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-309
Rh
1
1
Nap1
—
—
CH₃
CH₃
H
H
H
pic

1-309X
Rh
1
1
Nap1
—
—
CH₃
CH₃
H
H
H
acac

1-309Y
Rh
0
1
Nap1
—
—
CH₃
CH₃
H
H
H
— —

1-310
Rh
1
1
Nap1
—
—
H
CH₃
H
H
H
pic

1-310X
Rh
1
1
Nap1
—
—
H
CH₃
H
H
H
acac

1-310Y
Rh
0
1
Nap1
—
—
H
CH₃
H
H
H
— —

1-311
Rh
1
1
Nap2
—
—
H
H
H
H
H
pic

1-311X
Rh
1
1
Nap2
—
—
H
H
H
H
H
acac

1-311Y
Rh
0
1
Nap2
—
—
H
H
H
H
H
— —

1-312
Rh
1
1
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

1-312X
Rh
1
1
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

1-312Y
Rh
0
1
Nap2
—
—

^tC₄H₉
H
H
H
H
— —

1-313
Rh
1
1
Nap2
—
—
CH₃
H
H
H
H
pic

1-313X
Rh
1
1
Nap2
—
—
CH₃
H
H
H
H
acac

1-313Y
Rh
0
1
Nap2
—
—
CH₃
H
H
H
H
— —

1-314
Rh
1
1
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-314X
Rh
1
1
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-314Y
Rh
0
1
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-315
Rh
1
1
Nap2
—
—
CH₃
CH₃
H
H
H
pic

1-315X
Rh
1
1
Nap2
—
—
CH₃
CH₃
H
H
H
acac

1-315Y
Rh
0
1
Nap2
—
—
CH₃
CH₃
H
H
H
— —

1-316
Rh
1
1
Nap2
—
—
H
CH₃
H
H
H
pic

1-316X
Rh
1
1
Nap2
—
—
H
CH₃
H
H
H
acac

1-316Y
Rh
0
1
Nap2
—
—
H
CH₃
H
H
H
— —

1-317
Rh
1
1
Nap3
—
—
H
H
H
H
H
pic

1-317X
Rh
1
1
Nap3
—
—
H
H
H
H
H
acac

1-317Y
Rh
0
1
Nap3
—
—
H
H
H
H
H
— —

1-318
Rh
1
1
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

1-318X
Rh
1
1
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

1-318Y
Rh
0
1
Nap3
—
—

^tC₄H₉
H
H
H
H
— —

1-319
Rh
1
1
Nap3
—
—
CH₃
H
H
H
H
pic

1-319X
Rh
1
1
Nap3
—
—
CH₃
H
H
H
H
acac

1-319Y
Rh
0
1
Nap3
—
—
CH₃
H
H
H
H
— —

1-320
Rh
1
1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-320X
Rh
1
1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-320Y
Rh
0
1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-321
Rh
1
1
Nap3
—
—
CH₃
CH₃
H
H
H
pic

1-321X
Rh
1
1
Nap3
—
—
CH₃
CH₃
H
H
H
acac

1-321Y
Rh
0
1
Nap3
—
—
CH₃
CH₃
H
H
H
— —

1-322
Rh
1
1
Nap3
—
—
H
CH₃
H
H
H
pic

1-322X
Rh
1
1
Nap3
—
—
H
CH₃
H
H
H
acac

1-322Y
Rh
0
1
Nap3
—
—
H
CH₃
H
H
H
— —

1-323
Rh
1
1
TB
—
—
H
H
H
H
H
pic

1-323X
Rh
1
1
TB
—
—
H
H
H
H
H
acac

1-323Y
Rh
0
1
TB
—
—
H
H
H
H
H
— —

1-324
Rh
1
1
TB
—
—

^tC₄H₉
H
H
H
H
pic

1-324X
Rh
1
1
TB
—
—

^tC₄H₉
H
H
H
H
acac

1-324Y
Rh
0
1
TB
—
—

^tC₄H₉
H
H
H
H
— —

1-325
Rh
1
1
TB
—
—
CH₃
H
H
H
H
pic

1-325X
Rh
1
1
TB
—
—
CH₃
H
H
H
H
acac

1-325Y
Rh
0
1
TB
—
—
CH₃
H
H
H
H
— —

1-326
Rh
1
1
TB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-326X
Rh
1
1
TB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-326Y
Rh
0
1
TB
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-327
Rh
1
1
TB
—
—
CH₃
CH₃
H
H
H
pic

1-327X
Rh
1
1
TB
—
—
CH₃
CH₃
H
H
H
acac

1-327Y
Rh
0
1
TB
—
—
CH₃
CH₃
H
H
H
— —

1-328
Rh
1
1
TB
—
—
H
CH₃
H
H
H
pic

1-328X
Rh
1
1
TB
—
—
H
CH₃
H
H
H
acac

1-328Y
Rh
0
1
TB
—
—
H
CH₃
H
H
H
— —

1-329
Rh
1
1
TF
—
—
H
H
H
H
H
pic

1-329X
Rh
1
1
TF
—
—
H
H
H
H
H
acac

1-329Y
Rh
0
1
TF
—
—
H
H
H
H
H
— —

1-330
Rh
1
1
TF
—
—

^tC₄H₉
H
H
H
H
pic

1-330X
Rh
1
1
TF
—
—

^tC₄H₉
H
H
H
H
acac

1-330Y
Rh
0
1
TF
—
—

^tC₄H₉
H
H
H
H
— —

1-331
Rh
1
1
TF
—
—
CH₃
H
H
H
H
pic

1-331X
Rh
1
1
TF
—
—
CH₃
H
H
H
H
acac

1-331Y
Rh
0
1
TF
—
—
CH₃
H
H
H
H
— —

1-332
Rh
1
1
TF
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-332X
Rh
1
1
TF
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-332Y
Rh
0
1
TF
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-333
Rh
1
1
TF
—
—
CH₃
CH₃
H
H
H
pic

1-333X
Rh
1
1
TF
—
—
CH₃
CH₃
H
H
H
acac

1-333Y
Rh
0
1
TF
—
—
CH₃
CH₃
H
H
H
— —

1-334
Rh
1
1
TF
—
—
H
CH₃
H
H
H
pic

1-334X
Rh
1
1
TF
—
—
H
CH₃
H
H
H
acac

1-334Y
Rh
0
1
TF
—
—
H
CH₃
H
H
H
— —

1-335
Rh
1
1
OB
—
—
H
H
H
H
H
pic

1-335X
Rh
1
1
OB
—
—
H
H
H
H
H
acac

1-335Y
Rh
0
1
OB
—
—
H
H
H
H
H
— —

1-336
Rh
1
1
OB
—
—

^tC₄H₉
H
H
H
H
pic

1-336X
Rh
1
1
OB
—
—

^tC₄H₉
H
H
H
H
acac

1-336Y
Rh
0
1
OB
—
—

^tC₄H₉
H
H
H
H
— —

1-337
Rh
1
1
OB
—
—
CH₃
H
H
H
H
pic

1-337X
Rh
1
1
OB
—
—
CH₃
H
H
H
H
acac

1-337Y
Rh
0
1
OB
—
—
CH₃
H
H
H
H
— —

1-338
Rh
1
1
OB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-338X
Rh
1
1
OB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-338Y
Rh
0
1
OB
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-339
Rh
1
1
OB
—
—
CH₃
CH₃
H
H
H
pic

1-339X
Rh
1
1
OB
—
—
CH₃
CH₃
H
H
H
acac

1-339Y
Rh
0
1
OB
—
—
CH₃
CH₃
H
H
H
— —

1-340
Rh
1
1
OB
—
—
H
CH₃
H
H
H
pic

1-340X
Rh
1
1
OB
—
—
H
CH₃
H
H
H
acac

1-340Y
Rh
0
1
OB
—
—
H
CH₃
H
H
H
— —

1-341
Rh
1
1
Fu
—
—
H
H
H
H
H
pic

1-341X
Rh
1
1
Fu
—
—
H
H
H
H
H
acac

1-341Y
Rh
0
1
Fu
—
—
H
H
H
H
H
— —

1-342
Rh
1
1
Fu
—
—

^tC₄H₉
H
H
H
H
pic

1-342X
Rh
1
1
Fu
—
—

^tC₄H₉
H
H
H
H
acac

1-342Y
Rh
0
1
Fu
—
—

^tC₄H₉
H
H
H
H
— —

1-343
Rh
1
1
Fu
—
—
CH₃
H
H
H
H
pic

1-343X
Rh
1
1
Fu
—
—
CH₃
H
H
H
H
acac

1-343Y
Rh
0
1
Fu
—
—
CH₃
H
H
H
H
— —

1-344
Rh
1
1
Fu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-344X
Rh
1
1
Fu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-344Y
Rh
0
1
Fu
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-345
Rh
1
1
Fu
—
—
CH₃
CH₃
H
H
H
pic

1-345X
Rh
1
1
Fu
—
—
CH₃
CH₃
H
H
H
acac

1-345Y
Rh
0
1
Fu
—
—
CH₃
CH₃
H
H
H
— —

1-346
Rh
1
1
Fu
—
—
H
CH₃
H
H
H
pic

1-346X
Rh
1
1
Fu
—
—
H
CH₃
H
H
H
acac

1-346Y
Rh
0
1
Fu
—
—
H
CH₃
H
H
H
— —

1-347
Rh
1
1
Fl
—
—
H
H
H
H
H
pic

1-347X
Rh
1
1
Fl
—
—
H
H
H
H
H
acac

1-347Y
Rh
0
1
Fl
—
—
H
H
H
H
H
— —

1-348
Rh
1
1
Fl
—
—

^tC₄H₉
H
H
H
H
pic

1-348X
Rh
1
1
Fl
—
—

^tC₄H₉
H
H
H
H
acac

1-348Y
Rh
0
1
Fl
—
—

^tC₄H₉
H
H
H
H
— —

1-349
Rh
1
1
Fl
—
—
CH₃
H
H
H
H
pic

1-349X
Rh
1
1
Fl
—
—
CH₃
H
H
H
H
acac

1-349Y
Rh
0
1
Fl
—
—
CH₃
H
H
H
H
— —

1-350
Rh
1
1
Fl
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-350X
Rh
1
1
Fl
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-350Y
Rh
0
1
Fl
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-351
Rh
1
1
Fl
—
—
CH₃
CH₃
H
H
H
pic

1-351X
Rh
1
1
Fl
—
—
CH₃
CH₃
H
H
H
acac

1-351Y
Rh
0
1
Fl
—
—
CH₃
CH₃
H
H
H
— —

1-352
Rh
1
1
Fl
—
—
H
CH₃
H
H
H
pic

1-352X
Rh
1
1
Fl
—
—
H
CH₃
H
H
H
acac

1-352Y
Rh
0
1
Fl
—
—
H
CH₃
H
H
H
— —

1-353
Rh
1
1
Bz
—
—
H
H
H
H
H
pic

1-353X
Rh
1
1
Bz
—
—
H
H
H
H
H
acac

1-353Y
Rh
0
1
Bz
—
—
H
H
H
H
H
— —

1-354
Rh
1
1
Bz
—
—

^tC₄H₉
H
H
H
H
pic

1-354X
Rh
1
1
Bz
—
—

^tC₄H₉
H
H
H
H
acac

1-354Y
Rh
0
1
Bz
—
—

^tC₄H₉
H
H
H
H
— —

1-355
Rh
1
1
Bz
—
—
CH₃
H
H
H
H
pic

1-355X
Rh
1
1
Bz
—
—
CH₃
H
H
H
H
acac

1-355Y
Rh
0
1
Bz
—
—
CH₃
H
H
H
H
— —

1-356
Rh
1
1
Bz
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-356X
Rh
1
1
Bz
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-356Y
Rh
0
1
Bz
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-357
Rh
1
1
Bz
—
—
CH₃
CH₃
H
H
H
pic

1-357X
Rh
1
1
Bz
—
—
CH₃
CH₃
H
H
H
acac

1-357Y
Rh
0
1
Bz
—
—
CH₃
CH₃
H
H
H
— —

1-358
Rh
1
1
Bz
—
—
H
CH₃
H
H
H
pic

1-358X
Rh
1
1
Bz
—
—
H
CH₃
H
H
H
acac

1-358Y
Rh
0
1
Bz
—
—
H
CH₃
H
H
H
— —

1-359
Rh
1
1
Qu
—
—
H
H
H
H
H
pic

1-359X
Rh
1
1
Qu
—
—
H
H
H
H
H
acac

1-359Y
Rh
0
1
Qu
—
—
H
H
H
H
H
— —

1-360
Rh
1
1
Qu
—
—

^tC₄H₉
H
H
H
H
pic

1-360X
Rh
1
1
Qu
—
—

^tC₄H₉
H
H
H
H
acac

1-360Y
Rh
0
1
Qu
—
—

^tC₄H₉
H
H
H
H
— —

1-361
Rh
1
1
Qu
—
—
CH₃
H
H
H
H
pic

1-361X
Rh
1
1
Qu
—
—
CH₃
H
H
H
H
acac

1-361Y
Rh
0
1
Qu
—
—
CH₃
H
H
H
H
— —

1-362
Rh
1
1
Qu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1-362X
Rh
1
1
Qu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1-362Y
Rh
0
1
Qu
—
—

^tC₄H₉
CH₃
H
H
H
— —

1-363
Rh
1
1
Qu
—
—
CH₃
CH₃
H
H
H
pic

1-363X
Rh
1
1
Qu
—
—
CH₃
CH₃
H
H
H
acac

1-363Y
Rh
0
1
Qu
—
—
CH₃
CH₃
H
H
H
— —

1-364
Rh
1
1
Qu
—
—
H
CH₃
H
H
H
pic

1-364X
Rh
1
1
Qu
—
—
H
CH₃
H
H
H
acac

1-364Y
Rh
0
1
Qu
—
—
H
CH₃
H
H
H
— —

1-365
Rh
1
1
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

1-365X
Rh
1
1
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

1-365Y
Rh
0
1
OL
H

ⁿC₄H₉
H
H
H
H
H
— —

1-366
Rh
1
1
OL
H

^tC₄H₉
H
H
H
H
H
pic

1-366X
Rh
1
1
OL
H

^tC₄H₉
H
H
H
H
H
acac

1-366Y
Rh
0
1
OL
H

^tC₄H₉
H
H
H
H
H
— —

1-367
Rh
1
1
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

1-367X
Rh
1
1
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

1-367Y
Rh
0
1
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
— —

1-368
Rh
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

1-368X
Rh
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

1-368Y
Rh
0
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
— —

1-369
Rh
1
1
OL
H
H
H
H
H
H
H
pic

1-369X
Rh
1
1
OL
H
H
H
H
H
H
H
acac

1-369Y
Rh
0
1
OL
H
H
H
H
H
H
H
— —

1-370
Rh
1
1
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

1-370X
Rh
1
1
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

1-370Y
Rh
0
1
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
— —

1-371
Rh
1
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

1-371X
Rh
1
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

1-371Y
Rh
0
1
OL
H

^tC₄H₉
CH₃
H
H
H
H
— —

1-372
Rh
1
1
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

1-372X
Rh
1
1
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

1-372Y
Rh
0
1
OL
—CH₂CH₂CH₂—
H
H
H
H
H
— —

embedded image

TABLE 23

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹ L²

2-305
Rh
1
2
Nap1
—
—
H
H
H
H
H
pic

2-305X
Rh
1
2
Nap1
—
—
H
H
H
H
H
acac

2-305Y
Rh
0
2
Nap1
—
—
H
H
H
H
H
— —

2-306
Rh
1
2
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

2-306X
Rh
1
2
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

2-306Y
Rh
0
2
Nap1
—
—

^tC₄H₉
H
H
H
H
— —

2-307
Rh
1
2
Nap1
—
—
CH₃
H
H
H
H
pic

2-307X
Rh
1
2
Nap1
—
—
CH₃
H
H
H
H
acac

2-307Y
Rh
0
2
Nap1
—
—
CH₃
H
H
H
H
— —

2-308
Rh
1
2
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-308X
Rh
1
2
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-308Y
Rh
0
2
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-309
Rh
1
2
Nap1
—
—
CH₃
H
H
CH₃
H
pic

2-309X
Rh
1
2
Nap1
—
—
CH₃
H
H
CH₃
H
acac

2-309Y
Rh
0
2
Nap1
—
—
CH₃
H
H
CH₃
H
— —

2-310
Rh
1
2
Nap1
—
—
H
H
H
CH₃
H
pic

2-310X
Rh
1
2
Nap1
—
—
H
H
H
CH₃
H
acac

2-310Y
Rh
0
2
Nap1
—
—
H
H
H
CH₃
H
— —

2-311
Rh
1
2
Nap2
—
—
H
H
H
H
H
pic

2-311X
Rh
1
2
Nap2
—
—
H
H
H
H
H
acac

2-311Y
Rh
0
2
Nap2
—
—
H
H
H
H
H
— —

2-312
Rh
1
2
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

2-312X
Rh
1
2
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

2-312Y
Rh
0
2
Nap2
—
—

^tC₄H₉
H
H
H
H
— —

2-313
Rh
1
2
Nap2
—
—
CH₃
H
H
H
H
pic

2-313X
Rh
1
2
Nap2
—
—
CH₃
H
H
H
H
acac

2-313Y
Rh
0
2
Nap2
—
—
CH₃
H
H
H
H
— —

2-314
Rh
1
2
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-314X
Rh
1
2
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
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2-314Y
Rh
0
2
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-315
Rh
1
2
Nap2
—
—
CH₃
H
H
CH₃
H
pic

2-315X
Rh
1
2
Nap2
—
—
CH₃
H
H
CH₃
H
acac

2-315Y
Rh
0
2
Nap2
—
—
CH₃
H
H
CH₃
H
— —

2-316
Rh
1
2
Nap2
—
—
H
H
H
CH₃
H
pic

2-316X
Rh
1
2
Nap2
—
—
H
H
H
CH₃
H
acac

2-316Y
Rh
0
2
Nap2
—
—
H
H
H
CH₃
H
— —

2-317
Rh
1
2
Nap3
—
—
H
H
H
H
H
pic

2-317X
Rh
1
2
Nap3
—
—
H
H
H
H
H
acac

2-317Y
Rh
0
2
Nap3
—
—
H
H
H
H
H
— —

2-318
Rh
1
2
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

2-318X
Rh
1
2
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

2-318Y
Rh
0
2
Nap3
—
—

^tC₄H₉
H
H
H
H
— —

2-319
Rh
1
2
Nap3
—
—
CH₃
H
H
H
H
pic

2-319X
Rh
1
2
Nap3
—
—
CH₃
H
H
H
H
acac

2-319Y
Rh
0
2
Nap3
—
—
CH₃
H
H
H
H
— —

2-320
Rh
1
2
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-320X
Rh
1
2
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
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2-320Y
Rh
0
2
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-321
Rh
1
2
Nap3
—
—
CH₃
H
H
CH₃
H
pic

2-321X
Rh
1
2
Nap3
—
—
CH₃
H
H
CH₃
H
acac

2-321Y
Rh
0
2
Nap3
—
—
CH₃
H
H
CH₃
H
— —

2-322
Rh
1
2
Nap3
—
—
H
H
H
CH₃
H
pic

2-322X
Rh
1
2
Nap3
—
—
H
H
H
CH₃
H
acac

2-322Y
Rh
0
2
Nap3
—
—
H
H
H
CH₃
H
— —

2-323
Rh
1
2
TB
—
—
H
H
H
H
H
pic

2-323X
Rh
1
2
TB
—
—
H
H
H
H
H
acac

2-323Y
Rh
0
2
TB
—
—
H
H
H
H
H
— —

2-324
Rh
1
2
TB
—
—

^tC₄H₉
H
H
H
H
pic

2-324X
Rh
1
2
TB
—
—

^tC₄H₉
H
H
H
H
acac

2-324Y
Rh
0
2
TB
—
—

^tC₄H₉
H
H
H
H
— —

2-325
Rh
1
2
TB
—
—
CH₃
H
H
H
H
pic

2-325X
Rh
1
2
TB
—
—
CH₃
H
H
H
H
acac

2-325Y
Rh
0
2
TB
—
—
CH₃
H
H
H
H
— —

2-326
Rh
1
2
TB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-326X
Rh
1
2
TB
—
—

^tC₄H₉
H
H
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H
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2-326Y
Rh
0
2
TB
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-327
Rh
1
2
TB
—
—
CH₃
H
H
CH₃
H
pic

2-327X
Rh
1
2
TB
—
—
CH₃
H
H
CH₃
H
acac

2-327Y
Rh
0
2
TB
—
—
CH₃
H
H
CH₃
H
— —

2-328
Rh
1
2
TB
—
—
H
H
H
CH₃
H
pic

2-328X
Rh
1
2
TB
—
—
H
H
H
CH₃
H
acac

2-328Y
Rh
0
2
TB
—
—
H
H
H
CH₃
H
— —

2-329
Rh
1
2
TF
—
—
H
H
H
H
H
pic

2-329X
Rh
1
2
TF
—
—
H
H
H
H
H
acac

2-329Y
Rh
0
2
TF
—
—
H
H
H
H
H
— —

2-330
Rh
1
2
TF
—
—

^tC₄H₉
H
H
H
H
pic

2-330X
Rh
1
2
TF
—
—

^tC₄H₉
H
H
H
H
acac

2-330Y
Rh
0
2
TF
—
—

^tC₄H₉
H
H
H
H
— —

2-331
Rh
1
2
TF
—
—
CH₃
H
H
H
H
pic

2-331X
Rh
1
2
TF
—
—
CH₃
H
H
H
H
acac

2-331Y
Rh
0
2
TF
—
—
CH₃
H
H
H
H
— —

2-332
Rh
1
2
TF
—
—

^tC₄H₉
H
H
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H
pic

2-332X
Rh
1
2
TF
—
—

^tC₄H₉
H
H
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H
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2-332Y
Rh
0
2
TF
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-333
Rh
1
2
TF
—
—
CH₃
H
H
CH₃
H
pic

2-333X
Rh
1
2
TF
—
—
CH₃
H
H
CH₃
H
acac

2-333Y
Rh
0
2
TF
—
—
CH₃
H
H
CH₃
H
— —

2-334
Rh
1
2
TF
—
—
H
H
H
CH₃
H
pic

2-334X
Rh
1
2
TF
—
—
H
H
H
CH₃
H
acac

2-334Y
Rh
0
2
TF
—
—
H
H
H
CH₃
H
— —

2-335
Rh
1
2
OB
—
—
H
H
H
H
H
pic

2-335X
Rh
1
2
OB
—
—
H
H
H
H
H
acac

2-335Y
Rh
0
2
OB
—
—
H
H
H
H
H
— —

2-336
Rh
1
2
OB
—
—

^tC₄H₉
H
H
H
H
pic

2-336X
Rh
1
2
OB
—
—

^tC₄H₉
H
H
H
H
acac

2-336Y
Rh
0
2
OB
—
—

^tC₄H₉
H
H
H
H
— —

2-337
Rh
1
2
OB
—
—
CH₃
H
H
H
H
pic

2-337X
Rh
1
2
OB
—
—
CH₃
H
H
H
H
acac

2-337Y
Rh
0
2
OB
—
—
CH₃
H
H
H
H
— —

2-338
Rh
1
2
OB
—
—

^tC₄H₉
H
H
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H
pic

2-338X
Rh
1
2
OB
—
—

^tC₄H₉
H
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H
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2-338Y
Rh
0
2
OB
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-339
Rh
1
2
OB
—
—
CH₃
H
H
CH₃
H
pic

2-339X
Rh
1
2
OB
—
—
CH₃
H
H
CH₃
H
acac

2-339Y
Rh
0
2
OB
—
—
CH₃
H
H
CH₃
H
— —

2-340
Rh
1
2
OB
—
—
H
H
H
CH₃
H
pic

2-340X
Rh
1
2
OB
—
—
H
H
H
CH₃
H
acac

2-340Y
Rh
0
2
OB
—
—
H
H
H
CH₃
H
— —

2-341
Rh
1
2
Fu
—
—
H
H
H
H
H
pic

2-341X
Rh
1
2
Fu
—
—
H
H
H
H
H
acac

2-341Y
Rh
0
2
Fu
—
—
H
H
H
H
H
— —

2-342
Rh
1
2
Fu
—
—

^tC₄H₉
H
H
H
H
pic

2-342X
Rh
1
2
Fu
—
—

^tC₄H₉
H
H
H
H
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2-342Y
Rh
0
2
Fu
—
—

^tC₄H₉
H
H
H
H
— —

2-343
Rh
1
2
Fu
—
—
CH₃
H
H
H
H
pic

2-343X
Rh
1
2
Fu
—
—
CH₃
H
H
H
H
acac

2-343Y
Rh
0
2
Fu
—
—
CH₃
H
H
H
H
— —

2-344
Rh
1
2
Fu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-344X
Rh
1
2
Fu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2-344Y
Rh
0
2
Fu
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-345
Rh
1
2
Fu
—
—
CH₃
H
H
CH₃
H
pic

2-345X
Rh
1
2
Fu
—
—
CH₃
H
H
CH₃
H
acac

2-345Y
Rh
0
2
Fu
—
—
CH₃
H
H
CH₃
H
— —

2-346
Rh
1
2
Fu
—
—
H
H
H
CH₃
H
pic

2-346X
Rh
1
2
Fu
—
—
H
H
H
CH₃
H
acac

2-346Y
Rh
0
2
Fu
—
—
H
H
H
CH₃
H
— —

2-347
Rh
1
2
Fl
—
—
H
H
H
H
H
pic

2-347X
Rh
1
2
Fl
—
—
H
H
H
H
H
acac

2-347Y
Rh
0
2
Fl
—
—
H
H
H
H
H
— —

2-348
Rh
1
2
Fl
—
—

^tC₄H₉
H
H
H
H
pic

2-348X
Rh
1
2
Fl
—
—

^tC₄H₉
H
H
H
H
acac

2-348Y
Rh
0
2
Fl
—
—

^tC₄H₉
H
H
H
H
— —

2-349
Rh
1
2
Fl
—
—
CH₃
H
H
H
H
pic

2-349X
Rh
1
2
Fl
—
—
CH₃
H
H
H
H
acac

2-349Y
Rh
0
2
Fl
—
—
CH₃
H
H
H
H
— —

2-350
Rh
1
2
Fl
—
—

^tC₄H₉
H
H
CH₃
H
pic

2-350X
Rh
1
2
Fl
—
—

^tC₄H₉
H
H
CH₃
H
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2-350Y
Rh
0
2
Fl
—
—

^tC₄H₉
H
H
CH₃
H
— —

2-351
Rh
1
2
Fl
—
—
CH₃
H
H
CH₃
H
pic

2-351X
Rh
1
2
Fl
—
—
CH₃
H
H
CH₃
H
acac

2-351Y
Rh
0
2
Fl
—
—
CH₃
H
H
CH₃
H
— —

2-352
Rh
1
2
Fl
—
—
H
H
H
CH₃
H
pic

2-352X
Rh
1
2
Fl
—
—
H
H
H
CH₃
H
acac

2-352Y
Rh
0
2
Fl
—
—
H
H
H
CH₃
H
— —

2-353
Rh
1
2
Bz
—
—
H
H
H
H
H
pic

2-353X
Rh
1
2
Bz
—
—
H
H
H
H
H
acac

2-353Y
Rh
0
2
Bz
—
—
H
H
H
H
H
— —

2-354
Rh
1
2
Bz
—
—

^tC₄H₉
H
H
H
H
pic

2-354X
Rh
1
2
Bz
—
—

^tC₄H₉
H
H
H
H
acac

2-354Y
Rh
0
2
Bz
—
—

^tC₄H₉
H
H
H
H
— —

2-355
Rh
1
2
Bz
—
—
CH₃
H
H
H
H
pic

2-355X
Rh
1
2
Bz
—
—
CH₃
H
H
H
H
acac

2-355Y
Rh
0
2
Bz
—
—
CH₃
H
H
H
H
— —

2-356
Rh
1
2
Bz
—
—

^tC₄H₉
H
H
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H
pic

2-356X
Rh
1
2
Bz
—
—

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H
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2-356Y
Rh
0
2
Bz
—
—

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H
H
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H
— —

2-357
Rh
1
2
Bz
—
—
CH₃
H
H
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H
pic

2-357X
Rh
1
2
Bz
—
—
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H
H
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H
acac

2-357Y
Rh
0
2
Bz
—
—
CH₃
H
H
CH₃
H
— —

2-358
Rh
1
2
Bz
—
—
H
H
H
CH₃
H
pic

2-358X
Rh
1
2
Bz
—
—
H
H
H
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H
acac

2-358Y
Rh
0
2
Bz
—
—
H
H
H
CH₃
H
— —

2-359
Rh
1
2
Qu
—
—
H
H
H
H
H
pic

2-359X
Rh
1
2
Qu
—
—
H
H
H
H
H
acac

2-359Y
Rh
0
2
Qu
—
—
H
H
H
H
H
— —

2-360
Rh
1
2
Qu
—
—

^tC₄H₉
H
H
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pic

2-360X
Rh
1
2
Qu
—
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H
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acac

2-360Y
Rh
0
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Qu
—
—

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H
H
H
H
— —

2-361
Rh
1
2
Qu
—
—
CH₃
H
H
H
H
pic

2-361X
Rh
1
2
Qu
—
—
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H
H
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acac

2-361Y
Rh
0
2
Qu
—
—
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H
H
H
H
— —

2-362
Rh
1
2
Qu
—
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^tC₄H₉
H
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pic

2-362X
Rh
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—
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2-362Y
Rh
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—
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H
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— —

2-363
Rh
1
2
Qu
—
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H
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pic

2-363X
Rh
1
2
Qu
—
—
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acac

2-363Y
Rh
0
2
Qu
—
—
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H
H
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— —

2-364
Rh
1
2
Qu
—
—
H
H
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pic

2-364X
Rh
1
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Qu
—
—
H
H
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acac

2-364Y
Rh
0
2
Qu
—
—
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H
H
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H
— —

2-365
Rh
1
2
OL
H

ⁿC₄H₉
H
H
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pic

2-365X
Rh
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2-365Y
Rh
0
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H
H
H
H
H
— —

2-366
Rh
1
2
OL
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H
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pic

2-366X
Rh
1
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2-366Y
Rh
0
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H
H
H
H
H
— —

2-367
Rh
1
2
OL
CH₃

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H
H
H
H
H
pic

2-367X
Rh
1
2
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H
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2-367Y
Rh
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OL
CH₃

ⁿC₄H₉
H
H
H
H
H
— —

2-368
Rh
1
2
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

2-368X
Rh
1
2
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

2-368Y
Rh
0
2
OL
CH₃

^tC₄H₉
H
H
H
H
H
— —

2-369
Rh
1
2
OL
H
H
H
H
H
H
H
pic

2-369X
Rh
1
2
OL
H
H
H
H
H
H
H
acac

2-369Y
Rh
0
2
OL
H
H
H
H
H
H
H
— —

2-370
Rh
1
2
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

2-370X
Rh
1
2
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

2-370Y
Rh
0
2
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
— —

2-371
Rh
1
2
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

2-371X
Rh
1
2
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

2-371Y
Rh
0
2
OL
H

^tC₄H₉
CH₃
H
H
H
H
— —

2-372
Rh
1
2
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

2-372X
Rh
1
2
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

2-372Y
Rh
0
2
OL
—CH₂CH₂CH₂—
H
H
H
H
H
— —

embedded image

TABLE 24

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹ L²

3-271
Rh
1
3
Nap1
—
—
H
H
H
H
H
pic

3-271X
Rh
1
3
Nap1
—
—
H
H
H
H
H
acac

3-271Y
Rh
0
3
Nap1
—
—
H
H
H
H
H
— —

3-272
Rh
1
3
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

3-272X
Rh
1
3
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

3-272Y
Rh
0
3
Nap1
—
—

^tC₄H₉
H
H
H
H
— —

3-273
Rh
1
3
Nap1
—
—
CH₃
H
H
H
H
pic

3-273X
Rh
1
3
Nap1
—
—
CH₃
H
H
H
H
acac

3-273Y
Rh
0
3
Nap1
—
—
CH₃
H
H
H
H
— —

3-274
Rh
1
3
Nap2
—
—
H
H
H
H
H
pic

3-274X
Rh
1
3
Nap2
—
—
H
H
H
H
H
acac

3-274Y
Rh
0
3
Nap2
—
—
H
H
H
H
H
— —

3-275
Rh
1
3
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

3-275X
Rh
1
3
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

3-275Y
Rh
0
3
Nap2
—
—

^tC₄H₉
H
H
H
H
— —

3-276
Rh
1
3
Nap2
—
—
CH₃
H
H
H
H
pic

3-276X
Rh
1
3
Nap2
—
—
CH₃
H
H
H
H
acac

3-276Y
Rh
0
3
Nap2
—
—
CH₃
H
H
H
H
— —

3-277
Rh
1
3
Nap3
—
—
H
H
H
H
H
pic

3-277X
Rh
1
3
Nap3
—
—
H
H
H
H
H
acac

3-277Y
Rh
0
3
Nap3
—
—
H
H
H
H
H
— —

3-278
Rh
1
3
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

3-278X
Rh
1
3
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

3-278Y
Rh
0
3
Nap3
—
—

^tC₄H₉
H
H
H
H
— —

3-279
Rh
1
3
Nap3
—
—
CH₃
H
H
H
H
pic

3-279X
Rh
1
3
Nap3
—
—
CH₃
H
H
H
H
acac

3-279Y
Rh
0
3
Nap3
—
—
CH₃
H
H
H
H
— —

3-280
Rh
1
3
TB
—
—
H
H
H
H
H
pic

3-280X
Rh
1
3
TB
—
—
H
H
H
H
H
acac

3-280Y
Rh
0
3
TB
—
—
H
H
H
H
H
— —

3-281
Rh
1
3
TB
—
—

^tC₄H₉
H
H
H
H
pic

3-281X
Rh
1
3
TB
—
—

^tC₄H₉
H
H
H
H
acac

3-281Y
Rh
0
3
TB
—
—

^tC₄H₉
H
H
H
H
— —

3-282
Rh
1
3
TB
—
—
CH₃
H
H
H
H
pic

3-282X
Rh
1
3
TB
—
—
CH₃
H
H
H
H
acac

3-282Y
Rh
0
3
TB
—
—
CH₃
H
H
H
H
— —

3-283
Rh
1
3
TF
—
—
H
H
H
H
H
pic

3-283X
Rh
1
3
TF
—
—
H
H
H
H
H
acac

3-283Y
Rh
0
3
TF
—
—
H
H
H
H
H
— —

3-284
Rh
1
3
TF
—
—

^tC₄H₉
H
H
H
H
pic

3-284X
Rh
1
3
TF
—
—

^tC₄H₉
H
H
H
H
acac

3-284Y
Rh
0
3
TF
—
—

^tC₄H₉
H
H
H
H
— —

3-285
Rh
1
3
TF
—
—
CH₃
H
H
H
H
pic

3-285X
Rh
1
3
TF
—
—
CH₃
H
H
H
H
acac

3-285Y
Rh
0
3
TF
—
—
CH₃
H
H
H
H
— —

3-286
Rh
1
3
OB
—
—
H
H
H
H
H
pic

3-286X
Rh
1
3
OB
—
—
H
H
H
H
H
acac

3-286Y
Rh
0
3
OB
—
—
H
H
H
H
H
— —

3-287
Rh
1
3
OB
—
—

^tC₄H₉
H
H
H
H
pic

3-287X
Rh
1
3
OB
—
—

^tC₄H₉
H
H
H
H
acac

3-287Y
Rh
0
3
OB
—
—

^tC₄H₉
H
H
H
H
— —

3-288
Rh
1
3
OB
—
—
CH₃
H
H
H
H
pic

3-288X
Rh
1
3
OB
—
—
CH₃
H
H
H
H
acac

3-288Y
Rh
0
3
OB
—
—
CH₃
H
H
H
H
— —

3-289
Rh
1
3
Fu
—
—
H
H
H
H
H
pic

3-289X
Rh
1
3
Fu
—
—
H
H
H
H
H
acac

3-289Y
Rh
0
3
Fu
—
—
H
H
H
H
H
— —

3-290
Rh
1
3
Fu
—
—

^tC₄H₉
H
H
H
H
pic

3-290X
Rh
1
3
Fu
—
—

^tC₄H₉
H
H
H
H
acac

3-290Y
Rh
0
3
Fu
—
—

^tC₄H₉
H
H
H
H
— —

3-291
Rh
1
3
Fu
—
—
CH₃
H
H
H
H
pic

3-291X
Rh
1
3
Fu
—
—
CH₃
H
H
H
H
acac

3-291Y
Rh
0
3
Fu
—
—
CH₃
H
H
H
H
— —

3-292
Rh
1
3
Fl
—
—
H
H
H
H
H
pic

3-292X
Rh
1
3
Fl
—
—
H
H
H
H
H
acac

3-292Y
Rh
0
3
Fl
—
—
H
H
H
H
H
— —

3-293
Rh
1
3
Fl
—
—

^tC₄H₉
H
H
H
H
pic

3-293X
Rh
1
3
Fl
—
—

^tC₄H₉
H
H
H
H
acac

3-293Y
Rh
0
3
Fl
—
—

^tC₄H₉
H
H
H
H
— —

3-294
Rh
1
3
Fl
—
—
CH₃
H
H
H
H
pic

3-294X
Rh
1
3
Fl
—
—
CH₃
H
H
H
H
acac

3-294Y
Rh
0
3
Fl
—
—
CH₃
H
H
H
H
— —

3-295
Rh
1
3
Bz
—
—
H
H
H
H
H
pic

3-295X
Rh
1
3
Bz
—
—
H
H
H
H
H
acac

3-295Y
Rh
0
3
Bz
—
—
H
H
H
H
H
— —

3-296
Rh
1
3
Bz
—
—

^tC₄H₉
H
H
H
H
pic

3-296X
Rh
1
3
Bz
—
—

^tC₄H₉
H
H
H
H
acac

3-296Y
Rh
0
3
Bz
—
—

^tC₄H₉
H
H
H
H
— —

3-297
Rh
1
3
Bz
—
—
CH₃
H
H
H
H
pic

3-297X
Rh
1
3
Bz
—
—
CH₃
H
H
H
H
acac

3-297Y
Rh
0
3
Bz
—
—
CH₃
H
H
H
H
— —

3-298
Rh
1
3
Qu
—
—
H
H
H
H
H
pic

3-298X
Rh
1
3
Qu
—
—
H
H
H
H
H
acac

3-298Y
Rh
0
3
Qu
—
—
H
H
H
H
H
— —

3-299
Rh
1
3
Qu
—
—

^tC₄H₉
H
H
H
H
pic

3-299X
Rh
1
3
Qu
—
—

^tC₄H₉
H
H
H
H
acac

3-299Y
Rh
0
3
Qu
—
—

^tC₄H₉
H
H
H
H
— —

3-300
Rh
1
3
Qu
—
—
CH₃
H
H
H
H
pic

3-300X
Rh
1
3
Qu
—
—
CH₃
H
H
H
H
acac

3-300Y
Rh
0
3
Qu
—
—
CH₃
H
H
H
H
— —

3-301
Rh
1
3
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

3-301X
Rh
1
3
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

3-301Y
Rh
0
3
OL
H

ⁿC₄H₉
H
H
H
H
H
— —

3-302
Rh
1
3
OL
H

^tC₄H₉
H
H
H
H
H
pic

3-302X
Rh
1
3
OL
H

^tC₄H₉
H
H
H
H
H
acac

3-302Y
Rh
0
3
OL
H

^tC₄H₉
H
H
H
H
H
— —

3-303
Rh
1
3
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

3-303X
Rh
1
3
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

3-303Y
Rh
0
3
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
— —

3-304
Rh
1
3
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

3-304X
Rh
1
3
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

3-304Y
Rh
0
3
OL
CH₃

^tC₄H₉
H
H
H
H
H
— —

3-305
Rh
1
3
OL
H
H
H
H
H
H
H
pic

3-305X
Rh
1
3
OL
H
H
H
H
H
H
H
acac

3-305Y
Rh
0
3
OL
H
H
H
H
H
H
H
— —

3-306
Rh
1
3
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

3-306X
Rh
1
3
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

3-306Y
Rh
0
3
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
— —

3-307
Rh
1
3
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

3-307X
Rh
1
3
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

3-307Y
Rh
0
3
OL
H

^tC₄H₉
CH₃
H
H
H
H
— —

3-308
Rh
1
3
OL
—CH₂CH₂CH₂—
H
H
H
H
H
H

3-308X
Rh
1
3
OL
—CH₂CH₂CH₂—
H
H
H
H
H
H

3-308Y
Rh
0
3
OL
—CH₂CH₂CH₂—
H
H
H
H
H
H

embedded image

TABLE 25

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹ L²

4-304
Rh
1
4
Nap1
—
—
CH₃
H
H
H
H
pic

4-304X
Rh
1
4
Nap1
—
—
CH₃
H
H
H
H
acac

4-304Y
Rh
0
4
Nap1
—
—
CH₃
H
H
H
H
— —

4-305
Rh
1
4
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

4-305X
Rh
1
4
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

4-305Y
Rh
0
4
Nap1
—
—

^tC₄H₉
H
H
H
H
— —

4-306
Rh
1
4
Nap2
—
—
CH₃
H
H
H
H
pic

4-306X
Rh
1
4
Nap2
—
—
CH₃
H
H
H
H
acac

4-306Y
Rh
0
4
Nap2
—
—
CH₃
H
H
H
H
— —

4-307
Rh
1
4
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

4-307X
Rh
1
4
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

4-307Y
Rh
0
4
Nap2
—
—

^tC₄H₉
H
H
H
H
— —

4-308
Rh
1
4
Nap3
—
—
CH₃
H
H
H
H
pic

4-308X
Rh
1
4
Nap3
—
—
CH₃
H
H
H
H
acac

4-308Y
Rh
0
4
Nap3
—
—
CH₃
H
H
H
H
— —

4-309
Rh
1
4
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

4-309X
Rh
1
4
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

4-309Y
Rh
0
4
Nap3
—
—

^tC₄H₉
H
H
H
H
— —

4-310
Rh
1
4
TB
—
—
CH₃
H
H
H
H
pic

4-310X
Rh
1
4
TB
—
—
CH₃
H
H
H
H
acac

4-310Y
Rh
0
4
TB
—
—
CH₃
H
H
H
H
— —

4-311
Rh
1
4
TB
—
—

^tC₄H₉
H
H
H
H
pic

4-311X
Rh
1
4
TB
—
—

^tC₄H₉
H
H
H
H
acac

4-311Y
Rh
0
4
TB
—
—

^tC₄H₉
H
H
H
H
— —

4-312
Rh
1
4
TF
—
—
CH₃
H
H
H
H
pic

4-312X
Rh
1
4
TF
—
—
CH₃
H
H
H
H
acac

4-312Y
Rh
0
4
TF
—
—
CH₃
H
H
H
H
— —

4-313
Rh
1
4
TF
—
—

^tC₄H₉
H
H
H
H
pic

4-313X
Rh
1
4
TF
—
—

^tC₄H₉
H
H
H
H
acac

4-313Y
Rh
0
4
TF
—
—

^tC₄H₉
H
H
H
H
— —

4-314
Rh
1
4
OB
—
—
CH₃
H
H
H
H
pic

4-314X
Rh
1
4
OB
—
—
CH₃
H
H
H
H
acac

4-314Y
Rh
0
4
OB
—
—
CH₃
H
H
H
H
— —

4-315
Rh
1
4
OB
—
—

^tC₄H₉
H
H
H
H
pic

4-315X
Rh
1
4
OB
—
—

^tC₄H₉
H
H
H
H
acac

4-315Y
Rh
0
4
OB
—
—

^tC₄H₉
H
H
H
H
— —

4-316
Rh
1
4
Fu
—
—
CH₃
H
H
H
H
pic

4-316X
Rh
1
4
Fu
—
—
CH₃
H
H
H
H
acac

4-316Y
Rh
0
4
Fu
—
—
CH₃
H
H
H
H
— —

4-317
Rh
1
4
Fu
—
—

^tC₄H₉
H
H
H
H
pic

4-317X
Rh
1
4
Fu
—
—

^tC₄H₉
H
H
H
H
acac

4-317Y
Rh
0
4
Fu
—
—

^tC₄H₉
H
H
H
H
— —

4-318
Rh
1
4
Fl
—
—
CH₃
H
H
H
H
pic

4-318X
Rh
1
4
Fl
—
—
CH₃
H
H
H
H
acac

4-318Y
Rh
0
4
Fl
—
—
CH₃
H
H
H
H
— —

4-319
Rh
1
4
Fl
—
—

^tC₄H₉
H
H
H
H
pic

4-319X
Rh
1
4
Fl
—
—

^tC₄H₉
H
H
H
H
acac

4-319Y
Rh
0
4
Fl
—
—

^tC₄H₉
H
H
H
H
— —

4-320
Rh
1
4
Bz
—
—
CH₃
H
H
H
H
pic

4-320X
Rh
1
4
Bz
—
—
CH₃
H
H
H
H
acac

4-320Y
Rh
0
4
Bz
—
—
CH₃
H
H
H
H
— —

4-321
Rh
1
4
Bz
—
—

^tC₄H₉
H
H
H
H
pic

4-321X
Rh
1
4
Bz
—
—

^tC₄H₉
H
H
H
H
acac

4-321Y
Rh
0
4
Bz
—
—

^tC₄H₉
H
H
H
H
— —

4-322
Rh
1
4
Qu
—
—
CH₃
H
H
H
H
pic

4-322X
Rh
1
4
Qu
—
—
CH₃
H
H
H
H
acac

4-322Y
Rh
0
4
Qu
—
—
CH₃
H
H
H
H
— —

4-323
Rh
1
4
Qu
—
—

^tC₄H₉
H
H
H
H
pic

4-323X
Rh
1
4
Qu
—
—

^tC₄H₉
H
H
H
H
acac

4-323Y
Rh
0
4
Qu
—
—

^tC₄H₉
H
H
H
H
— —

4-324
Rh
1
4
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

4-324X
Rh
1
4
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

4-324Y
Rh
0
4
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
— —

4-325
Rh
1
4
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
pic

4-325X
Rh
1
4
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
acac

4-325Y
Rh
0
4
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
— —

4-326
Rh
1
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

4-326X
Rh
1
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

4-326Y
Rh
0
4
OL
H

^tC₄H₉
CH₃
H
H
H
H
— —

4-327
Rh
1
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4-327X
Rh
1
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4-327Y
Rh
0
4
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
— —

4-328
Rh
1
4
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
pic

4-328X
Rh
1
4
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
acac

4-328Y
Rh
0
4
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
— —

4-329
Rh
1
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
pic

4-329X
Rh
1
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
acac

4-329Y
Rh
0
4
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
— —

4-330
Rh
1
4
OL
H
H
CH₃
H
H
H
H
pic

4-330X
Rh
1
4
OL
H
H
CH₃
H
H
H
H
acac

4-330Y
Rh
0
4
OL
H
H
CH₃
H
H
H
H
— —

4-331
Rh
1
4
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
pic

4-331X
Rh
1
4
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
acac

4-331Y
Rh
0
4
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
— —

4-332
Rh
1
4
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
pic

4-332X
Rh
1
4
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
acac

4-332Y
Rh
0
4
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
— —

embedded image

TABLE 26

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹ L²

5-350
Rh
1
5
Nap1
—
—
H
CH₃
H
pic

5-351X
Rh
1
5
Nap1
—
—
H
CH₃
H
acac

5-351Y
Rh
0
5
Nap1
—
—
H
CH₃
H
— —

5-351
Rh
1
5
Nap1
—
—
H

^tC₄H₉
H
pic

5-352X
Rh
1
5
Nap1
—
—
H

^tC₄H₉
H
acac

5-352Y
Rh
0
5
Nap1
—
—
H

^tC₄H₉
H
— —

5-352
Rh
1
5
Nap1
—
—

^tC₄H₉
CH₃
H
pic

5-353X
Rh
1
5
Nap1
—
—

^tC₄H₉
CH₃
H
acac

5-353Y
Rh
0
5
Nap1
—
—

^tC₄H₉
CH₃
H
— —

5-353
Rh
1
5
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-354X
Rh
1
5
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-354Y
Rh
0
5
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-354
Rh
1
5
Nap1
—
—
CH₃
CH₃
H
pic

5-355X
Rh
1
5
Nap1
—
—
CH₃
CH₃
H
acac

5-355Y
Rh
0
5
Nap1
—
—
CH₃
CH₃
H
— —

5-355
Rh
1
5
Nap1
—
—
CH₃

^tC₄H₉
H
pic

5-356X
Rh
1
5
Nap1
—
—
CH₃

^tC₄H₉
H
acac

5-356Y
Rh
0
5
Nap1
—
—
CH₃

^tC₄H₉
H
— —

5-356
Rh
1
5
Nap2
—
—
H
CH₃
H
pic

5-357X
Rh
1
5
Nap2
—
—
H
CH₃
H
acac

5-357Y
Rh
0
5
Nap2
—
—
H
CH₃
H
— —

5-357
Rh
1
5
Nap2
—
—
H

^tC₄H₉
H
pic

5-358X
Rh
1
5
Nap2
—
—
H

^tC₄H₉
H
acac

5-358Y
Rh
0
5
Nap2
—
—
H

^tC₄H₉
H
— —

5-358
Rh
1
5
Nap2
—
—

^tC₄H₉
CH₃
H
pic

5-359X
Rh
1
5
Nap2
—
—

^tC₄H₉
CH₃
H
acac

5-359Y
Rh
0
5
Nap2
—
—

^tC₄H₉
CH₃
H
— —

5-359
Rh
1
5
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-360X
Rh
1
5
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-360Y
Rh
0
5
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-360
Rh
1
5
Nap2
—
—
CH₃
CH₃
H
pic

5-361X
Rh
1
5
Nap2
—
—
CH₃
CH₃
H
acac

5-361Y
Rh
0
5
Nap2
—
—
CH₃
CH₃
H
— —

5-361
Rh
1
5
Nap2
—
—
CH₃

^tC₄H₉
H
pic

5-362X
Rh
1
5
Nap2
—
—
CH₃

^tC₄H₉
H
acac

5-362Y
Rh
0
5
Nap2
—
—
CH₃

^tC₄H₉
H
— —

5-362
Rh
1
5
Nap3
—
—
H
CH₃
H
pic

5-363X
Rh
1
5
Nap3
—
—
H
CH₃
H
acac

5-363Y
Rh
0
5
Nap3
—
—
H
CH₃
H
— —

5-363
Rh
1
5
Nap3
—
—
H

^tC₄H₉
H
pic

5-364X
Rh
1
5
Nap3
—
—
H

^tC₄H₉
H
acac

5-364Y
Rh
0
5
Nap3
—
—
H

^tC₄H₉
H
— —

5-364
Rh
1
5
Nap3
—
—

^tC₄H₉
CH₃
H
pic

5-365X
Rh
1
5
Nap3
—
—

^tC₄H₉
CH₃
H
acac

5-365Y
Rh
0
5
Nap3
—
—

^tC₄H₉
CH₃
H
— —

5-365
Rh
1
5
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-366X
Rh
1
5
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-366Y
Rh
0
5
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-366
Rh
1
5
Nap3
—
—
CH₃
CH₃
H
pic

5-367X
Rh
1
5
Nap3
—
—
CH₃
CH₃
H
acac

5-367Y
Rh
0
5
Nap3
—
—
CH₃
CH₃
H
— —

5-367
Rh
1
5
Nap3
—
—
CH₃

^tC₄H₉
H
pic

5-368X
Rh
1
5
Nap3
—
—
CH₃

^tC₄H₉
H
acac

5-368Y
Rh
0
5
Nap3
—
—
CH₃

^tC₄H₉
H
— —

5-368
Rh
1
5
TB
—
—
H
CH₃
H
pic

5-369X
Rh
1
5
TB
—
—
H
CH₃
H
acac

5-369Y
Rh
0
5
TB
—
—
H
CH₃
H
— —

5-369
Rh
1
5
TB
—
—
H

^tC₄H₉
H
pic

5-370X
Rh
1
5
TB
—
—
H

^tC₄H₉
H
acac

5-370Y
Rh
0
5
TB
—
—
H

^tC₄H₉
H
— —

5-370
Rh
1
5
TB
—
—

^tC₄H₉
CH₃
H
pic

5-371X
Rh
1
5
TB
—
—

^tC₄H₉
CH₃
H
acac

5-371Y
Rh
0
5
TB
—
—

^tC₄H₉
CH₃
H
— —

5-371
Rh
1
5
TB
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-372X
Rh
1
5
TB
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-372Y
Rh
0
5
TB
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-372
Rh
1
5
TB
—
—
CH₃
CH₃
H
pic

5-373X
Rh
1
5
TB
—
—
CH₃
CH₃
H
acac

5-373Y
Rh
0
5
TB
—
—
CH₃
CH₃
H
— —

5-373
Rh
1
5
TB
—
—
CH₃

^tC₄H₉
H
pic

5-374X
Rh
1
5
TB
—
—
CH₃

^tC₄H₉
H
acac

5-374Y
Rh
0
5
TB
—
—
CH₃

^tC₄H₉
H
— —

5-374
Rh
1
5
TF
—
—
H
CH₃
H
pic

5-375X
Rh
1
5
TF
—
—
H
CH₃
H
acac

5-375Y
Rh
0
5
TF
—
—
H
CH₃
H
— —

5-375
Rh
1
5
TF
—
—
H

^tC₄H₉
H
pic

5-376X
Rh
1
5
TF
—
—
H

^tC₄H₉
H
acac

5-376Y
Rh
0
5
TF
—
—
H

^tC₄H₉
H
— —

5-376
Rh
1
5
TF
—
—

^tC₄H₉
CH₃
H
pic

5-377X
Rh
1
5
TF
—
—

^tC₄H₉
CH₃
H
acac

5-377Y
Rh
0
5
TF
—
—

^tC₄H₉
CH₃
H
— —

5-377
Rh
1
5
TF
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-378X
Rh
1
5
TF
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-378Y
Rh
0
5
TF
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-378
Rh
1
5
TF
—
—
CH₃
CH₃
H
pic

5-379X
Rh
1
5
TF
—
—
CH₃
CH₃
H
acac

5-379Y
Rh
0
5
TF
—
—
CH₃
CH₃
H
— —

5-379
Rh
1
5
TF
—
—
CH₃

^tC₄H₉
H
pic

5-380X
Rh
1
5
TF
—
—
CH₃

^tC₄H₉
H
acac

5-380Y
Rh
0
5
TF
—
—
CH₃

^tC₄H₉
H
— —

5-380
Rh
1
5
OB
—
—
H
CH₃
H
pic

5-381X
Rh
1
5
OB
—
—
H
CH₃
H
acac

5-381Y
Rh
0
5
OB
—
—
H
CH₃
H
— —

5-381
Rh
1
5
OB
—
—
H

^tC₄H₉
H
pic

5-382X
Rh
1
5
OB
—
—
H

^tC₄H₉
H
acac

5-382Y
Rh
0
5
OB
—
—
H

^tC₄H₉
H
— —

5-382
Rh
1
5
OB
—
—

^tC₄H₉
CH₃
H
pic

5-383X
Rh
1
5
OB
—
—

^tC₄H₉
CH₃
H
acac

5-383Y
Rh
0
5
OB
—
—

^tC₄H₉
CH₃
H
— —

5-383
Rh
1
5
OB
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-384X
Rh
1
5
OB
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-384Y
Rh
0
5
OB
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-384
Rh
1
5
OB
—
—
CH₃
CH₃
H
pic

5-385X
Rh
1
5
OB
—
—
CH₃
CH₃
H
acac

5-385Y
Rh
0
5
OB
—
—
CH₃
CH₃
H
— —

5-385
Rh
1
5
OB
—
—
CH₃

^tC₄H₉
H
pic

5-386X
Rh
1
5
OB
—
—
CH₃

^tC₄H₉
H
acac

5-386Y
Rh
0
5
OB
—
—
CH₃

^tC₄H₉
H
— —

5-386
Rh
1
5
Fu
—
—
H
CH₃
H
pic

5-387X
Rh
1
5
Fu
—
—
H
CH₃
H
acac

5-387Y
Rh
0
5
Fu
—
—
H
CH₃
H
— —

5-387
Rh
1
5
Fu
—
—
H

^tC₄H₉
H
pic

5-388X
Rh
1
5
Fu
—
—
H

^tC₄H₉
H
acac

5-388Y
Rh
0
5
Fu
—
—
H

^tC₄H₉
H
— —

5-388
Rh
1
5
Fu
—
—

^tC₄H₉
CH₃
H
pic

5-389X
Rh
1
5
Fu
—
—

^tC₄H₉
CH₃
H
acac

5-389Y
Rh
0
5
Fu
—
—

^tC₄H₉
CH₃
H
— —

5-389
Rh
1
5
Fu
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-390X
Rh
1
5
Fu
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-390Y
Rh
0
5
Fu
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-390
Rh
1
5
Fu
—
—
CH₃
CH₃
H
pic

5-391X
Rh
1
5
Fu
—
—
CH₃
CH₃
H
acac

5-391Y
Rh
0
5
Fu
—
—
CH₃
CH₃
H
— —

5-391
Rh
1
5
Fu
—
—
CH₃

^tC₄H₉
H
pic

5-392X
Rh
1
5
Fu
—
—
CH₃

^tC₄H₉
H
acac

5-392Y
Rh
0
5
Fu
—
—
CH₃

^tC₄H₉
H
— —

5-392
Rh
1
5
Fl
—
—
H
CH₃
H
pic

5-393X
Rh
1
5
Fl
—
—
H
CH₃
H
acac

5-393Y
Rh
0
5
Fl
—
—
H
CH₃
H
— —

5-393
Rh
1
5
Fl
—
—
H

^tC₄H₉
H
pic

5-394X
Rh
1
5
Fl
—
—
H

^tC₄H₉
H
acac

5-394Y
Rh
0
5
Fl
—
—
H

^tC₄H₉
H
— —

5-394
Rh
1
5
Fl
—
—

^tC₄H₉
CH₃
H
pic

5-395X
Rh
1
5
Fl
—
—

^tC₄H₉
CH₃
H
acac

5-395Y
Rh
0
5
Fl
—
—

^tC₄H₉
CH₃
H
— —

5-395
Rh
1
5
Fl
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-396X
Rh
1
5
Fl
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-396Y
Rh
0
5
Fl
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-396
Rh
1
5
Fl
—
—
CH₃
CH₃
H
pic

5-397X
Rh
1
5
Fl
—
—
CH₃
CH₃
H
acac

5-397Y
Rh
0
5
Fl
—
—
CH₃
CH₃
H
— —

5-397
Rh
1
5
Fl
—
—
CH₃

^tC₄H₉
H
pic

5-398X
Rh
1
5
Fl
—
—
CH₃

^tC₄H₉
H
acac

5-398Y
Rh
0
5
Fl
—
—
CH₃

^tC₄H₉
H
— —

5-398
Rh
1
5
Bz
—
—
H
CH₃
H
pic

5-399X
Rh
1
5
Bz
—
—
H
CH₃
H
acac

5-399Y
Rh
0
5
Bz
—
—
H
CH₃
H
— —

5-399
Rh
1
5
Bz
—
—
H

^tC₄H₉
H
pic

5-400X
Rh
1
5
Bz
—
—
H

^tC₄H₉
H
acac

5-400Y
Rh
0
5
Bz
—
—
H

^tC₄H₉
H
— —

5-400
Rh
1
5
Bz
—
—

^tC₄H₉
CH₃
H
pic

5-401X
Rh
1
5
Bz
—
—

^tC₄H₉
CH₃
H
acac

5-401Y
Rh
0
5
Bz
—
—

^tC₄H₉
CH₃
H
— —

5-401
Rh
1
5
Bz
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-402X
Rh
1
5
Bz
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-402Y
Rh
0
5
Bz
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-402
Rh
1
5
Bz
—
—
CH₃
CH₃
H
pic

5-403X
Rh
1
5
Bz
—
—
CH₃
CH₃
H
acac

5-403Y
Rh
0
5
Bz
—
—
CH₃
CH₃
H
— —

5-403
Rh
1
5
Bz
—
—
CH₃

^tC₄H₉
H
pic

5-404X
Rh
1
5
Bz
—
—
CH₃

^tC₄H₉
H
acac

5-404Y
Rh
0
5
Bz
—
—
CH₃

^tC₄H₉
H
— —

5-404
Rh
1
5
Qu
—
—
H
CH₃
H
pic

5-405X
Rh
1
5
Bz
—
—
H
CH₃
H
acac

5-405Y
Rh
0
5
Bz
—
—
H
CH₃
H
— —

5-405
Rh
1
5
Bz
—
—
H

^tC₄H₉
H
pic

5-406X
Rh
1
5
Bz
—
—
H

^tC₄H₉
H
acac

5-406Y
Rh
0
5
Bz
—
—
H

^tC₄H₉
H
— —

5-406
Rh
1
5
Bz
—
—

^tC₄H₉
CH₃
H
pic

5-407X
Rh
1
5
Bz
—
—

^tC₄H₉
CH₃
H
acac

5-407Y
Rh
0
5
Bz
—
—

^tC₄H₉
CH₃
H
— —

5-407
Rh
1
5
Bz
—
—

^tC₄H₉

^tC₄H₉
H
pic

5-408X
Rh
1
5
Bz
—
—

^tC₄H₉

^tC₄H₉
H
acac

5-408Y
Rh
0
5
Bz
—
—

^tC₄H₉

^tC₄H₉
H
— —

5-408
Rh
1
5
Bz
—
—
CH₃
CH₃
H
pic

5-409X
Rh
1
5
Bz
—
—
CH₃
CH₃
H
acac

5-409Y
Rh
0
5
Bz
—
—
CH₃
CH₃
H
— —

5-409
Rh
1
5
Bz
—
—
CH₃

^tC₄H₉
H
pic

5-410X
Rh
1
5
Bz
—
—
CH₃

^tC₄H₉
H
acac

5-410Y
Rh
0
5
Bz
—
—
CH₃

^tC₄H₉
H
— —

5-410
Rh
1
5
OL
H

ⁿC₄H₉
H
CH₃
H
pic

5-411X
Rh
1
5
OL
H

ⁿC₄H₉
H
CH₃
H
acac

5-411Y
Rh
0
5
OL
H

ⁿC₄H₉
H
CH₃
H
— —

5-411
Rh
1
5
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
pic

5-412X
Rh
1
5
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
acac

5-412Y
Rh
0
5
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
— —

5-412
Rh
1
5
OL
H

^tC₄H₉
H
CH₃
H
pic

5-413X
Rh
1
5
OL
H

^tC₄H₉
H
CH₃
H
acac

5-413Y
Rh
0
5
OL
H

^tC₄H₉
H
CH₃
H
— —

5-413
Rh
1
5
OL
H

^tC₄H₉
H

^tC₄H₉
H
pic

5-414X
Rh
1
5
OL
H

^tC₄H₉
H

^tC₄H₉
H
acac

5-414Y
Rh
0
5
OL
H

^tC₄H₉
H

^tC₄H₉
H
— —

5-414
Rh
1
5
OL
CH₃

ⁿC₄H₉
H
CH₃
H
pic

5-415X
Rh
1
5
OL
CH₃

ⁿC₄H₉
H
CH₃
H
acac

5-415Y
Rh
0
5
OL
CH₃

ⁿC₄H₉
H
CH₃
H
— —

5-415
Rh
1
5
OL
CH₃

^tC₄H₉
H
CH₃
H
pic

5-416X
Rh
1
5
OL
CH₃

^tC₄H₉
H
CH₃
H
acac

5-416Y
Rh
0
5
OL
CH₃

^tC₄H₉
H
CH₃
H
— —

5-416
Rh
1
5
OL
H
H
H
CH₃
H
pic

5-417X
Rh
1
5
OL
H
H
H
CH₃
H
acac

5-417Y
Rh
0
5
OL
H
H
H
CH₃
H
— —

5-417
Rh
1
5
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
pic

5-418X
Rh
1
5
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
acac

5-418Y
Rh
0
5
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
— —

5-418
Rh
1
5
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
pic

5-419X
Rh
1
5
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
acac

5-419Y
Rh
0
5
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
— —

5-419
Rh
1
5
OL
—CH₂CH₂CH₂—
H
CH₃
H
pic

5-420X
Rh
1
5
OL
—CH₂CH₂CH₂—
H
CH₃
H
acac

5-420Y
Rh
0
5
OL
—CH₂CH₂CH₂—
H
CH₃
H
— —

5-420
Rh
1
5
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
pic

5-421X
Rh
1
5
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
acac

5-421Y
Rh
0
5
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
— —

embedded image

TABLE 27

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹ L²

6-304
Rh
1
6
Nap1
—
—
CH₃
H
H
pic

6-304X
Rh
1
6
Nap1
—
—
CH₃
H
H
acac

6-304Y
Rh
0
6
Nap1
—
—
CH₃
H
H
— —

6-305
Rh
1
6
Nap1
—
—

^tC₄H₉
H
H
pic

6-305X
Rh
1
6
Nap1
—
—

^tC₄H₉
H
H
acac

6-305Y
Rh
0
6
Nap1
—
—

^tC₄H₉
H
H
— —

6-306
Rh
1
6
Nap2
—
—
CH₃
H
H
pic

6-306X
Rh
1
6
Nap2
—
—
CH₃
H
H
acac

6-306Y
Rh
0
6
Nap2
—
—
CH₃
H
H
— —

6-307
Rh
1
6
Nap2
—
—

^tC₄H₉
H
H
pic

6-307X
Rh
1
6
Nap2
—
—

^tC₄H₉
H
H
acac

6-307Y
Rh
0
6
Nap2
—
—

^tC₄H₉
H
H
— —

6-308
Rh
1
6
Nap3
—
—
CH₃
H
H
pic

6-308X
Rh
1
6
Nap3
—
—
CH₃
H
H
acac

6-308Y
Rh
0
6
Nap3
—
—
CH₃
H
H
— —

6-309
Rh
1
6
Nap3
—
—

^tC₄H₉
H
H
pic

6-309X
Rh
1
6
Nap3
—
—

^tC₄H₉
H
H
acac

6-309Y
Rh
0
6
Nap3
—
—

^tC₄H₉
H
H
— —

6-310
Rh
1
6
TB
—
—
CH₃
H
H
pic

6-310X
Rh
1
6
TB
—
—
CH₃
H
H
acac

6-310Y
Rh
0
6
TB
—
—
CH₃
H
H
— —

6-311
Rh
1
6
TB
—
—

^tC₄H₉
H
H
pic

6-311X
Rh
1
6
TB
—
—

^tC₄H₉
H
H
acac

6-311Y
Rh
0
6
TB
—
—

^tC₄H₉
H
H
— —

6-312
Rh
1
6
TF
—
—
CH₃
H
H
pic

6-312X
Rh
1
6
TF
—
—
CH₃
H
H
acac

6-312Y
Rh
0
6
TF
—
—
CH₃
H
H
— —

6-313
Rh
1
6
TF
—
—

^tC₄H₉
H
H
pic

6-313X
Rh
1
6
TF
—
—

^tC₄H₉
H
H
acac

6-313Y
Rh
0
6
TF
—
—

^tC₄H₉
H
H
— —

6-314
Rh
1
6
OB
—
—
CH₃
H
H
pic

6-314X
Rh
1
6
OB
—
—
CH₃
H
H
acac

6-314Y
Rh
0
6
OB
—
—
CH₃
H
H
— —

6-315
Rh
1
6
OB
—
—

^tC₄H₉
H
H
pic

6-315X
Rh
1
6
OB
—
—

^tC₄H₉
H
H
acac

6-315Y
Rh
0
6
OB
—
—

^tC₄H₉
H
H
— —

6-316
Rh
1
6
Fu
—
—
CH₃
H
H
pic

6-316X
Rh
1
6
Fu
—
—
CH₃
H
H
acac

6-316Y
Rh
0
6
Fu
—
—
CH₃
H
H
— —

6-317
Rh
1
6
Fu
—
—

^tC₄H₉
H
H
pic

6-317X
Rh
1
6
Fu
—
—

^tC₄H₉
H
H
acac

6-317Y
Rh
0
6
Fu
—
—

^tC₄H₉
H
H
— —

6-318
Rh
1
6
Fl
—
—
CH₃
H
H
pic

6-318X
Rh
1
6
Fl
—
—
CH₃
H
H
acac

6-318Y
Rh
0
6
Fl
—
—
CH₃
H
H
— —

6-319
Rh
1
6
Fl
—
—

^tC₄H₉
H
H
pic

6-319X
Rh
1
6
Fl
—
—

^tC₄H₉
H
H
acac

6-319Y
Rh
0
6
Fl
—
—

^tC₄H₉
H
H
— —

6-320
Rh
1
6
Bz
—
—
CH₃
H
H
pic

6-320X
Rh
1
6
Bz
—
—
CH₃
H
H
acac

6-320Y
Rh
0
6
Bz
—
—
CH₃
H
H
— —

6-321
Rh
1
6
Bz
—
—

^tC₄H₉
H
H
pic

6-321X
Rh
1
6
Bz
—
—

^tC₄H₉
H
H
acac

6-321Y
Rh
0
6
Bz
—
—

^tC₄H₉
H
H
— —

6-322
Rh
1
6
Qu
—
—
CH₃
H
H
pic

6-322X
Rh
1
6
Qu
—
—
CH₃
H
H
acac

6-322Y
Rh
0
6
Qu
—
—
CH₃
H
H
— —

6-323
Rh
1
6
Qu
—
—

^tC₄H₉
H
H
pic

6-323X
Rh
1
6
Qu
—
—

^tC₄H₉
H
H
acac

6-323Y
Rh
0
6
Qu
—
—

^tC₄H₉
H
H
— —

6-324
Rh
1
6
OL
H

^pC₄H₉
CH₃
H
H
pic

6-324X
Rh
1
6
OL
H

ⁿC₄H₉
CH₃
H
H
acac

6-324Y
Rh
0
6
OL
H

ⁿC₄H₉
CH₃
H
H
— —

6-325
Rh
1
6
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
pic

6-325X
Rh
1
6
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
acac

6-325Y
Rh
0
6
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
— —

6-326
Rh
1
6
OL
H

^tC₄H₉
CH₃
H
H
pic

6-326X
Rh
1
6
OL
H

^tC₄H₉
CH₃
H
H
acac

6-326Y
Rh
0
6
OL
H

^tC₄H₉
CH₃
H
H
— —

6-327
Rh
1
6
OL
H

^tC₄H₉

^tC₄H₉
H
H
pic

6-327X
Rh
1
6
OL
H

^tC₄H₉

^tC₄H₉
H
H
acac

6-327Y
Rh
0
6
OL
H

^tC₄H₉

^tC₄H₉
H
H
— —

6-328
Rh
1
6
OL
CH₃

ⁿC₄H₉
CH₃
H
H
pic

6-328X
Rh
1
6
OL
CH₃

ⁿC₄H₉
CH₃
H
H
acac

6-328Y
Rh
0
6
OL
CH₃

ⁿC₄H₉
CH₃
H
H
— —

6-329
Rh
1
6
OL
CH₃

^tC₄H₉
CH₃
H
H
pic

6-329X
Rh
1
6
OL
CH₃

^tC₄H₉
CH₃
H
H
acac

6-329Y
Rh
0
6
OL
CH₃

^tC₄H₉
CH₃
H
H
— —

6-330
Rh
1
6
OL
H
H
CH₃
H
H
pic

6-330X
Rh
1
6
OL
H
H
CH₃
H
H
acac

6-330Y
Rh
0
6
OL
H
H
CH₃
H
H
— —

6-331
Rh
1
6
OL
—CH₂CH₂CH₂—
CH₃
H
H
pic

6-331X
Rh
1
6
OL
—CH₂CH₂CH₂—
CH₃
H
H
acac

6-331Y
Rh
0
6
OL
—CH₂CH₂CH₂—
CH₃
H
H
— —

6-332
Rh
1
6
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
pic

6-332X
Rh
1
6
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
acac

6-332Y
Rh
0
6
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
— —

embedded image

TABLE 28

No.
M
n
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹
L²

7-304
Rh
1
7
Nap1
—
—
CH₃
H
H
pic

7-304X
Rh
1
7
Nap1
—
—
CH₃
H
H
acac

7-304Y
Rh
0
7
Nap1
—
—
CH₃
H
H
—
—

7-305
Rh
1
7
Nap1
—
—

^tC₄H₉
H
H
pic

7-305X
Rh
1
7
Nap1
—
—

^tC₄H₉
H
H
acac

7-305Y
Rh
0
7
Nap1
—
—

^tC₄H₉
H
H
—
—

7-306
Rh
1
7
Nap2
—
—
CH₃
H
H
pic

7-306X
Rh
1
7
Nap2
—
—
CH₃
H
H
acac

7-306Y
Rh
0
7
Nap2
—
—
CH₃
H
H
—
—

7-307
Rh
1
7
Nap2
—
—

^tC₄H₉
H
H
pic

7-307X
Rh
1
7
Nap2
—
—

^tC₄H₉
H
H
acac

7-307Y
Rh
0
7
Nap2
—
—

^tC₄H₉
H
H
—
—

7-308
Rh
1
7
Nap3
—
—
CH₃
H
H
pic

7-308X
Rh
1
7
Nap3
—
—
CH₃
H
H
acac

7-308Y
Rh
0
7
Nap3
—
—
CH₃
H
H
—
—

7-309
Rh
1
7
Nap3
—
—

^tC₄H₉
H
H
pic

7-309X
Rh
1
7
Nap3
—
—

^tC₄H₉
H
H
acac

7-309Y
Rh
0
7
Nap3
—
—

^tC₄H₉
H
H
—
—

7-310
Rh
1
7
TB
—
—
CH₃
H
H
pic

7-310X
Rh
1
7
TB
—
—
CH₃
H
H
acac

7-310Y
Rh
0
7
TB
—
—
CH₃
H
H
—
—

7-311
Rh
1
7
TB
—
—

^tC₄H₉
H
H
pic

7-311X
Rh
1
7
TB
—
—

^tC₄H₉
H
H
acac

7-311Y
Rh
0
7
TB
—
—

^tC₄H₉
H
H
—
—

7-312
Rh
1
7
TF
—
—
CH₃
H
H
pic

7-312X
Rh
1
7
TF
—
—
CH₃
H
H
acac

7-312Y
Rh
0
7
TF
—
—
CH₃
H
H
—
—

7-313
Rh
1
7
TF
—
—

^tC₄H₉
H
H
pic

7-313X
Rh
1
7
TF
—
—

^tC₄H₉
H
H
acac

7-313Y
Rh
0
7
TF
—
—

^tC₄H₉
H
H
—
—

7-314
Rh
1
7
OB
—
—
CH₃
H
H
pic

7-314X
Rh
1
7
OB
—
—
CH₃
H
H
acac

7-314Y
Rh
0
7
OB
—
—
CH₃
H
H
—
—

7-315
Rh
1
7
OB
—
—

^tC₄H₉
H
H
pic

7-315X
Rh
1
7
OB
—
—

^tC₄H₉
H
H
acac

7-315Y
Rh
0
7
OB
—
—

^tC₄H₉
H
H
—
—

7-316
Rh
1
7
Fu
—
—
CH₃
H
H
pic

7-316X
Rh
1
7
Fu
—
—
CH₃
H
H
acac

7-316Y
Rh
0
7
Fu
—
—
CH₃
H
H
—
—

7-317
Rh
1
7
Fu
—
—

^tC₄H₉
H
H
pic

7-317X
Rh
1
7
Fu
—
—

^tC₄H₉
H
H
acac

7-317Y
Rh
0
7
Fu
—
—

^tC₄H₉
H
H
—
—

7-318
Rh
1
7
Fl
—
—
CH₃
H
H
pic

7-318X
Rh
1
7
Fl
—
—
CH₃
H
H
acac

7-318Y
Rh
0
7
Fl
—
—
CH₃
H
H
—
—

7-319
Rh
1
7
Fl
—
—

^tC₄H₉
H
H
pic

7-319X
Rh
1
7
Fl
—
—

^tC₄H₉
H
H
acac

7-319Y
Rh
0
7
Fl
—
—

^tC₄H₉
H
H
—
—

7-320
Rh
1
7
Bz
—
—
CH₃
H
H
pic

7-320X
Rh
1
7
Bz
—
—
CH₃
H
H
acac

7-320Y
Rh
0
7
Bz
—
—
CH₃
H
H
—
—

7-321
Rh
1
7
Bz
—
—

^tC₄H₉
H
H
pic

7-321X
Rh
1
7
Bz
—
—

^tC₄H₉
H
H
acac

7-321Y
Rh
0
7
Bz
—
—

^tC₄H₉
H
H
—
—

7-322
Rh
1
7
Qu
—
—
CH₃
H
H
pic

7-322X
Rh
1
7
Qu
—
—
CH₃
H
H
acac

7-322Y
Rh
0
7
Qu
—
—
CH₃
H
H
—
—

7-323
Rh
1
7
Qu
—
—

^tC₄H₉
H
H
pic

7-323X
Rh
1
7
Qu
—
—

^tC₄H₉
H
H
acac

7-323Y
Rh
0
7
Qu
—
—

^tC₄H₉
H
H
—
—

7-324
Rh
1
7
OL
H

ⁿC₄H₉
CH₃
H
H
pic

7-324X
Rh
1
7
OL
H

ⁿC₄H₉
CH₃
H
H
acac

7-324Y
Rh
0
7
OL
H

ⁿC₄H₉
CH₃
H
H
—
—

7-325
Rh
1
7
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
pic

7-325X
Rh
1
7
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
acac

7-325Y
Rh
0
7
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
—
—

7-326
Rh
1
7
OL
H

^tC₄H₉
CH₃
H
H
pic

7-326X
Rh
1
7
OL
H

^tC₄H₉
CH₃
H
H
acac

7-326Y
Rh
0
7
OL
H

^tC₄H₉
CH₃
H
H
—
—

7-327
Rh
1
7
OL
H

^tC₄H₉

^tC₄H₉
H
H
pic

7-327X
Rh
1
7
OL
H

^tC₄H₉

^tC₄H₉
H
H
acac

7-327Y
Rh
0
7
OL
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7-328
Rh
1
7
OL
CH₃

ⁿC₄H₉
CH₃
H
H
pic

7-328X
Rh
1
7
OL
CH₃

ⁿC₄H₉
CH₃
H
H
acac

7-328Y
Rh
0
7
OL
CH₃

ⁿC₄H₉
CH₃
H
H
—
—

7-329
Rh
1
7
OL
CH₃

^tC₄H₉
CH₃
H
H
pic

7-329X
Rh
1
7
OL
CH₃

^tC₄H₉
CH₃
H
H
acac

7-329Y
Rh
0
7
OL
CH₃

^tC₄H₉
CH₃
H
H
—
—

7-330
Rh
1
7
OL
H
H
CH₃
H
H
pic

7-330X
Rh
1
7
OL
H
H
CH₃
H
H
acac

7-330Y
Rh
0
7
OL
H
H
CH₃
H
H
—
—

7-331
Rh
1
7
OL
—CH₂CH₂CH₂—
CH₃
H
H
pic

7-331X
Rh
1
7
OL
—CH₂CH₂CH₂—
CH₃
H
H
acac

7-331Y
Rh
0
7
OL
—CH₂CH₂CH₂—
CH₃
H
H
—
—

7-332
Rh
1
7
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
pic

7-332X
Rh
1
7
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
acac

7-332Y
Rh
0
7
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
—
—

embedded image

TABLE 29

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1′-1
Pt
1
1′
Ph
H
H
H
H
H
H
H
H
H
pic

1′-1X
Pt
1
1′
Ph
H
H
H
H
H
H
H
H
H
acac

1′-1Y
Pt
0
1′
Ph
H
H
H
H
H
H
H
H
H
—
—

1′-2
Pt
1
1′
Ph
H
F
H
F
H
H
H
H
H
pic

1′-2X
Pt
1
1′
Ph
H
F
H
F
H
H
H
H
H
acac

1′-2Y
Pt
0
1′
Ph
H
F
H
F
H
H
H
H
H
—
—

1′-3
Pt
1
1′
Ph
F
H
H
F
H
H
H
H
H
pic

1′-3X
Pt
1
1′
Ph
F
H
H
F
H
H
H
H
H
acac

1′-3Y
Pt
0
1′
Ph
F
H
H
F
H
H
H
H
H
—
—

1′-4
Pt
1
1′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

1′-4X
Pt
1
1′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

1′-4Y
Pt
0
1′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

1′-5
Pt
1
1′
Ph
H
F
CF₃
H
H
H
H
H
H
pic

1′-5X
Pt
1
1′
Ph
H
F
CF₃
H
H
H
H
H
H
acac

1′-5Y
Pt
0
1′
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

1′-6
Pt
1
1′
Ph
F
H
CF₃
H
H
H
H
H
H
pic

1′-6X
Pt
1
1′
Ph
F
H
CF₃
H
H
H
H
H
H
acac

1′-6Y
Pt
0
1′
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

1′-7
Pt
1
1′
Ph
F
F
F
F
H
H
H
H
H
pic

1′-7X
Pt
1
1′
Ph
F
F
F
F
H
H
H
H
H
acac

1′-7Y
Pt
0
1′
Ph
F
F
F
F
H
H
H
H
H
—
—

1′-8
Pt
1
1′
Ph
H
F
H
CF₃
H
H
H
H
H
pic

1′-8X
Pt
1
1′
Ph
H
F
H
CF₃
H
H
H
H
H
acac

1′-8Y
Pt
0
1′
Ph
H
F
H
CF₃
H
H
H
H
H
—
—

1′-9
Pt
1
1′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

1′-9X
Pt
1
1′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

1′-9Y
Pt
0
1′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

1′-10
Pt
1
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

1′-10X
Pt
1
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

1′-10Y
Pt
0
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

1′-11
Pt
1
1′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

1′-11X
Pt
1
1′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

1′-11Y
Pt
0
1′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

1′-12
Pt
1
1′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

1′-12X
Pt
1
1′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

1′-12Y
Pt
0
1′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

1′-13
Pt
1
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

1′-13X
Pt
1
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

1′-13Y
Pt
0
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

1′-14
Pt
1
1′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

1′-14X
Pt
1
1′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

1′-14Y
Pt
0
1′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

1′-15
Pt
1
1′
Ph
H
H
NO₂
H
H
H
H
H
H
pic

1′-15X
Pt
1
1′
Ph
H
H
NO₂
H
H
H
H
H
H
acac

1′-15Y
Pt
0
1′
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

1′-16
Pt
1
1′
Ph
F
H
NO₂
H
H
H
H
H
H
pic

1′-16X
Pt
1
1′
Ph
F
H
NO₂
H
H
H
H
H
H
acac

1′-16Y
Pt
0
1′
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

1′-17
Pt
1
1′
Ph
F
H
NO₂
F
H
H
H
H
H
pic

1′-17X
Pt
1
1′
Ph
F
H
NO₂
F
H
H
H
H
H
acac

1′-17Y
Pt
0
1′
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

1′-18
Pt
1
1′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

1′-18X
Pt
1
1′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

1′-18Y
Pt
0
1′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

1′-19
Pt
1
1′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

1′-19X
Pt
1
1′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

1′-19Y
Pt
0
1′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

1′-20
Pt
1
1′
Ph
H
H
CF₃
H
H
H
H
H
H
pic

1′-20X
Pt
1
1′
Ph
H
H
CF₃
H
H
H
H
H
H
acac

1′-20Y
Pt
0
1′
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

1′-21
Pt
1
1′
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

1′-21X
Pt
1
1′
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

1′-21Y
Pt
0
1′
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

1′-22
Pt
1
1′
Ph
H
NO₂
H
H
H
H
H
H
H
pic

1′-22X
Pt
1
1′
Ph
H
NO₂
H
H
H
H
H
H
H
acac

1′-22Y
Pt
0
1′
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

1′-23
Pt
1
1′
Ph
H
CF₃
H
H
H
H
H
H
H
pic

1′-23X
Pt
1
1′
Ph
H
CF₃
H
H
H
H
H
H
H
acac

1′-23Y
Pt
0
1′
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

1′-24
Pt
1
1′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

1′-24X
Pt
1
1′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

1′-24Y
Pt
0
1′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

1′-25
Pt
1
1′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

1′-25X
Pt
1
1′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

1′-25Y
Pt
0
1′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

1′-26
Pt
1
1′
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

1′-26X
Pt
1
1′
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

1′-26Y
Pt
0
1′
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

1′-27
Pt
1
1′
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

1′-27X
Pt
1
1′
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

1′-27Y
Pt
0
1′
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

1′-28
Pt
1
1′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

1′-28X
Pt
1
1′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

1′-28Y
Pt
0
1′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

1′-29
Pt
1
1′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

1′-29X
Pt
1
1′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

1′-29Y
Pt
0
1′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

1′-30
Pt
1
1′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

1′-30X
Pt
1
1′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

1′-30Y
Pt
0
1′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

1′-31
Pt
1
1′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

1′-31X
Pt
1
1′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

1′-31Y
Pt
0
1′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

1′-32
Pt
1
1′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

1′-32X
Pt
1
1′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

1′-32Y
Pt
0
1′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

1′-33
Pt
1
1′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

1′-33X
Pt
1
1′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

1′-33Y
Pt
0
1′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

1′-34
Pt
1
1′
Ph
H
F
H
F
H
CH₃
H
H
H
pic

1′-34X
Pt
1
1′
Ph
H
F
H
F
H
CH₃
H
H
H
acac

1′-34Y
Pt
0
1′
Ph
H
F
H
F
H
CH₃
H
H
H
—
—

1′-35
Pt
1
1′
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
pic

1′-35X
Pt
1
1′
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
acac

1′-35Y
Pt
0
1′
Ph
CF₃
H
CF₃
H
H
CH₃
H
H
H
—
—

1′-36
Pt
1
1′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

1′-36X
Pt
1
1′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

1′-36Y
Pt
0
1′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

1′-37
Pt
1
1′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1′-37X
Pt
1
1′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1′-37Y
Pt
0
1′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1′-38
Pt
1
1′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

1′-38X
Pt
1
1′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

1′-38Y
Pt
0
1′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

1′-39
Pt
1
1′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

1′-39X
Pt
1
1′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

1′-39Y
Pt
0
1′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

1′-40
Pt
1
1′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

1′-40X
Pt
1
1′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

1′-40Y
Pt
0
1′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

1′-41
Pt
1
1′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

1′-41X
Pt
1
1′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

1′-41Y
Pt
0
1′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

1′-42
Pt
1
1′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

1′-42X
Pt
1
1′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

1′-42Y
Pt
0
1′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

1′-43
Pt
1
1′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1′-43X
Pt
1
1′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1′-43Y
Pt
0
1′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1′-44
Pt
1
1′
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

1′-44X
Pt
1
1′
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

1′-44Y
Pt
0
1′
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

1′-45
Pt
1
1′
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

1′-45X
Pt
1
1′
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

1′-45Y
Pt
0
1′
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

1′-46
Pt
1
1′
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

1′-46X
Pt
1
1′
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

1′-46Y
Pt
0
1′
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

1′-47
Pt
1
1′
Ph
H
H
BL
H
H
H
H
H
pic

1′-47X
Pt
1
1′
Ph
H
H
BL
H
H
H
H
H
acac

1′-47Y
Pt
0
1′
Ph
H
H
BL
H
H
H
H
H
—
—

1′-48
Pt
1
1′
Ph
H
BL
H
H
H
H
H
H
pic

1′-48X
Pt
1
1′
Ph
H
BL
H
H
H
H
H
H
acac

1′-48Y
Pt
0
1′
Ph
H
BL
H
H
H
H
H
H
—
—

1′-49
Pt
1
1′
Ph
H
H
PL
H
H
H
H
H
pic

1′-49X
Pt
1
1′
Ph
H
H
PL
H
H
H
H
H
acac

1′-49Y
Pt
0
1′
Ph
H
H
PL
H
H
H
H
H
—
—

1′-50
Pt
1
1′
Ph
H
PL
H
H
H
H
H
H
pic

1′-50X
Pt
1
1′
Ph
H
PL
H
H
H
H
H
H
acac

1′-50Y
Pt
0
1′
Ph
H
PL
H
H
H
H
H
H
—
—

1′-51
Pt
1
1′
Ph
H
H
MEE1
H
H
H
H
H
pic

1′-51X
Pt
1
1′
Ph
H
H
MEE1
H
H
H
H
H
acac

1′-51Y
Pt
0
1′
Ph
H
H
MEE1
H
H
H
H
H
—
—

1′-52
Pt
1
1′
Ph
H
MEE1
H
H
H
H
H
H
pic

1′-52X
Pt
1
1′
Ph
H
MEE1
H
H
H
H
H
H
acac

1′-52Y
Pt
0
1′
Ph
H
MEE1
H
H
H
H
H
H
—
—

1′-53
Pt
1
1′
Ph
H
H
MEE2
H
H
H
H
H
pic

1′-53X
Pt
1
1′
Ph
H
H
MEE2
H
H
H
H
H
acac

1′-53Y
Pt
0
1′
Ph
H
H
MEE2
H
H
H
H
H
—
—

1′-54
Pt
1
1′
Ph
H
MEE2
H
H
H
H
H
H
pic

1′-54X
Pt
1
1′
Ph
H
MEE2
H
H
H
H
H
H
acac

1′-54Y
Pt
0
1′
Ph
H
MEE2
H
H
H
H
H
H
—
—

1′-55
Pt
1
1′
Ph
H
H
PA1
H
H
H
H
H
pic

1′-55X
Pt
1
1′
Ph
H
H
PA1
H
H
H
H
H
acac

1′-55Y
Pt
0
1′
Ph
H
H
PA1
H
H
H
H
H
—
—

1′-56
Pt
1
1′
Ph
H
PA1
H
H
H
H
H
H
pic

1′-56X
Pt
1
1′
Ph
H
PA1
H
H
H
H
H
H
acac

1′-56Y
Pt
0
1′
Ph
H
PA1
H
H
H
H
H
H
—
—

1′-57
Pt
1
1′
Ph
H
H
PA2
H
H
H
H
H
pic

1′-57X
Pt
1
1′
Ph
H
H
PA2
H
H
H
H
H
acac

1′-57Y
Pt
0
1′
Ph
H
H
PA2
H
H
H
H
H
—
—

1′-58
Pt
1
1′
Ph
H
PA2
H
H
H
H
H
H
pic

1′-58X
Pt
1
1′
Ph
H
PA2
H
H
H
H
H
H
acac

1′-58Y
Pt
0
1′
Ph
H
PA2
H
H
H
H
H
H
—
—

1′-59
Pt
1
1′
Ph
H
H
EA1
H
H
H
H
H
pic

1′-59X
Pt
1
1′
Ph
H
H
EA1
H
H
H
H
H
acac

1′-59Y
Pt
0
1′
Ph
H
H
EA1
H
H
H
H
H
—
—

1′-60
Pt
1
1′
Ph
H
EA2
H
H
H
H
H
H
pic

1′-60X
Pt
1
1′
Ph
H
EA2
H
H
H
H
H
H
acac

1′-60Y
Pt
0
1′
Ph
H
EA2
H
H
H
H
H
H
—
—

1′-61
Pt
1
1′
Ph
H
H
ME
H
H
H
H
H
pic

1′-61X
Pt
1
1′
Ph
H
H
ME
H
H
H
H
H
acac

1′-61Y
Pt
0
1′
Ph
H
H
ME
H
H
H
H
H
—
—

1′-62
Pt
1
1′
Ph
H
ME
H
H
H
H
H
H
pic

1′-62X
Pt
1
1′
Ph
H
ME
H
H
H
H
H
H
acac

1′-62Y
Pt
0
1′
Ph
H
ME
H
H
H
H
H
H
—
—

1′-63
Pt
1
1′
Ph
H
H
AT
H
H
H
H
H
pic

1′-63X
Pt
1
1′
Ph
H
H
AT
H
H
H
H
H
acac

1′-63Y
Pt
0
1′
Ph
H
H
AT
H
H
H
H
H
—
—

1′-64
Pt
1
1′
Ph
H
AT
H
H
H
H
H
H
pic

1′-64X
Pt
1
1′
Ph
H
AT
H
H
H
H
H
H
acac

1′-64Y
Pt
0
1′
Ph
H
AT
H
H
H
H
H
H
—
—

1′-65
Pt
1
1′
Ph
H
H
MES1
H
H
H
H
H
pic

1′-65X
Pt
1
1′
Ph
H
H
MES1
H
H
H
H
H
acac

1′-65Y
Pt
0
1′
Ph
H
H
MES1
H
H
H
H
H
—
—

1′-66
Pt
1
1′
Ph
H
MES1
H
H
H
H
H
H
pic

1′-66X
Pt
1
1′
Ph
H
MES1
H
H
H
H
H
H
acac

1′-66Y
Pt
0
1′
Ph
H
MES1
H
H
H
H
H
H
—
—

1′-67
Pt
1
1′
Ph
H
H
MES2
H
H
H
H
H
pic

1′-67X
Pt
1
1′
Ph
H
H
MES2
H
H
H
H
H
acac

1′-67Y
Pt
0
1′
Ph
H
H
MES2
H
H
H
H
H
—
—

1′-68
Pt
1
1′
Ph
H
MES2
H
H
H
H
H
H
pic

1′-68X
Pt
1
1′
Ph
H
MES2
H
H
H
H
H
H
acac

1′-68Y
Pt
0
1′
Ph
H
MES2
H
H
H
H
H
H
—
—

1′-69
Pt
1
1′
Ph
H
H
PS1
H
H
H
H
H
pic

1′-69X
Pt
1
1′
Ph
H
H
PS1
H
H
H
H
H
acac

1′-69Y
Pt
0
1′
Ph
H
H
PS1
H
H
H
H
H
—
—

1′-70
Pt
1
1′
Ph
H
PS1
H
H
H
H
H
H
pic

1′-70X
Pt
1
1′
Ph
H
PS1
H
H
H
H
H
H
acac

1′-70Y
Pt
0
1′
Ph
H
PS1
H
H
H
H
H
H
—
—

1′-71
Pt
1
1′
Ph
H
H
PS2
H
H
H
H
H
pic

1′-71X
Pt
1
1′
Ph
H
H
PS2
H
H
H
H
H
acac

1′-71Y
Pt
0
1′
Ph
H
H
PS2
H
H
H
H
H
—
—

1′-72
Pt
1
1′
Ph
H
PS2
H
H
H
H
H
H
pic

1′-72X
Pt
1
1′
Ph
H
PS2
H
H
H
H
H
H
acac

1′-72Y
Pt
0
1′
Ph
H
PS2
H
H
H
H
H
H
—
—

1′-73
Pt
1
1′
Ph
H
H
BAL1
H
H
H
H
H
pic

1′-73X
Pt
1
1′
Ph
H
H
BAL1
H
H
H
H
H
acac

1′-73Y
Pt
0
1′
Ph
H
H
BAL1
H
H
H
H
H
—
—

1′-74
Pt
1
1′
Ph
H
BAL1
H
H
H
H
H
H
pic

1′-74X
Pt
1
1′
Ph
H
BAL1
H
H
H
H
H
H
acac

1′-74Y
Pt
0
1′
Ph
H
BAL1
H
H
H
H
H
H
—
—

1′-75
Pt
1
1′
Ph
H
H
BAL2
H
H
H
H
H
pic

1′-75X
Pt
1
1′
Ph
H
H
BAL2
H
H
H
H
H
acac

1′-75Y
Pt
0
1′
Ph
H
H
BAL2
H
H
H
H
H
—
—

1′-76
Pt
1
1′
Ph
H
BAL2
H
H
H
H
H
H
pic

1′-76X
Pt
1
1′
Ph
H
BAL2
H
H
H
H
H
H
acac

1′-76Y
Pt
0
1′
Ph
H
BAL2
H
H
H
H
H
H
—
—

1′-77
Pt
1
1′
Ph
H
H
MEK1
H
H
H
H
H
pic

1′-77X
Pt
1
1′
Ph
H
H
MEK1
H
H
H
H
H
acac

1′-77Y
Pt
0
1′
Ph
H
H
MEK1
H
H
H
H
H
—
—

1′-78
Pt
1
1′
Ph
H
MEK1
H
H
H
H
H
H
pic

1′-78X
Pt
1
1′
Ph
H
MEK1
H
H
H
H
H
H
acac

1′-78Y
Pt
0
1′
Ph
H
MEK1
H
H
H
H
H
H
—
—

1′-79
Pt
1
1′
Ph
H
H
MEK2
H
H
H
H
H
pic

1′-79X
Pt
1
1′
Ph
H
H
MEK2
H
H
H
H
H
acac

1′-79Y
Pt
0
1′
Ph
H
H
MEK2
H
H
H
H
H
—
—

1′-80
Pt
1
1′
Ph
H
MEK2
H
H
H
H
H
H
pic

1′-80X
Pt
1
1′
Ph
H
MEK2
H
H
H
H
H
H
acac

1′-80Y
Pt
0
1′
Ph
H
MEK2
H
H
H
H
H
H
—
—

1′-81
Pt
1
1′
Ph
H
H
PAL1
H
H
H
H
H
pic

1′-81X
Pt
1
1′
Ph
H
H
PAL1
H
H
H
H
H
acac

1′-81Y
Pt
0
1′
Ph
H
H
PAL1
H
H
H
H
H
—
—

1′-82
Pt
1
1′
Ph
H
PAL1
H
H
H
H
H
H
pic

1′-82X
Pt
1
1′
Ph
H
PAL1
H
H
H
H
H
H
acac

1′-82Y
Pt
0
1′
Ph
H
PAL1
H
H
H
H
H
H
—
—

1′-83
Pt
1
1′
Ph
H
H
PAL2
H
H
H
H
H
pic

1′-83X
Pt
1
1′
Ph
H
H
PAL2
H
H
H
H
H
acac

1′-83Y
Pt
0
1′
Ph
H
H
PAL2
H
H
H
H
H
—
—

1′-84
Pt
1
1′
Ph
H
PAL2
H
H
H
H
H
H
pic

1′-84X
Pt
1
1′
Ph
H
PAL2
H
H
H
H
H
H
acac

1′-84Y
Pt
0
1′
Ph
H
PAL2
H
H
H
H
H
H
—
—

1′-85
Pt
1
1′
Ph
H
H
MMK
H
H
H
H
H
pic

1′-85X
Pt
1
1′
Ph
H
H
MMK
H
H
H
H
H
acac

1′-85Y
Pt
0
1′
Ph
H
H
MMK
H
H
H
H
H
—
—

1′-86
Pt
1
1′
Ph
H
MMK
H
H
H
H
H
H
pic

1′-86X
Pt
1
1′
Ph
H
MMK
H
H
H
H
H
H
acac

1′-86Y
Pt
0
1′
Ph
H
MMK
H
H
H
H
H
H
—
—

1′-87
Pt
1
1′
Ph
H
H
EES1
H
H
H
H
H
pic

1′-87X
Pt
1
1′
Ph
H
H
EES1
H
H
H
H
H
acac

1′-87Y
Pt
0
1′
Ph
H
H
EES1
H
H
H
H
H
—
—

1′-88
Pt
1
1′
Ph
H
EES2
H
H
H
H
H
H
pic

1′-88X
Pt
1
1′
Ph
H
EES2
H
H
H
H
H
H
acac

1′-88Y
Pt
0
1′
Ph
H
EES2
H
H
H
H
H
H
—
—

1′-89
Pt
1
1′
Ph
H
H
PAE1
H
H
H
H
H
pic

1′-89X
Pt
1
1′
Ph
H
H
PAE1
H
H
H
H
H
acac

1′-89Y
Pt
0
1′
Ph
H
H
PAE1
H
H
H
H
H
—
—

1′-90
Pt
1
1′
Ph
H
PAE2
H
H
H
H
H
H
pic

1′-90X
Pt
1
1′
Ph
H
PAE2
H
H
H
H
H
H
acac

1′-90Y
Pt
0
1′
Ph
H
PAE2
H
H
H
H
H
H
—
—

1′-91
Pt
1
1′
Ph
H
H
AME1
H
H
H
H
H
pic

1′-91X
Pt
1
1′
Ph
H
H
AME1
H
H
H
H
H
acac

1′-91Y
Pt
0
1′
Ph
H
H
AME1
H
H
H
H
H
—
—

1′-92
Pt
1
1′
Ph
H
AME1
H
H
H
H
H
H
pic

1′-92X
Pt
1
1′
Ph
H
AME1
H
H
H
H
H
H
acac

1′-92Y
Pt
0
1′
Ph
H
AME1
H
H
H
H
H
H
—
—

1′-93
Pt
1
1′
Ph
H
H
AME2
H
H
H
H
H
pic

1′-93X
Pt
1
1′
Ph
H
H
AME2
H
H
H
H
H
acac

1′-93Y
Pt
0
1′
Ph
H
H
AME2
H
H
H
H
H
—
—

1′-94
Pt
1
1′
Ph
H
AME2
H
H
H
H
H
H
pic

1′-94X
Pt
1
1′
Ph
H
AME2
H
H
H
H
H
H
acac

1′-94Y
Pt
0
1′
Ph
H
AME2
H
H
H
H
H
H
—
—

1′-95
Pt
1
1′
Ph
H
H
EAE1
H
H
H
H
H
pic

1′-95X
Pt
1
1′
Ph
H
H
EAE1
H
H
H
H
H
acac

1′-95Y
Pt
0
1′
Ph
H
H
EAE1
H
H
H
H
H
—
—

1′-96
Pt
1
1′
Ph
H
EAE1
H
H
H
H
H
H
pic

1′-96X
Pt
1
1′
Ph
H
EAE1
H
H
H
H
H
H
acac

1′-96Y
Pt
0
1′
Ph
H
EAE1
H
H
H
H
H
H
—
—

1′-97
Pt
1
1′
Ph
H
H
EAE2
H
H
H
H
H
pic

1′-97X
Pt
1
1′
Ph
H
H
EAE2
H
H
H
H
H
acac

1′-97Y
Pt
0
1′
Ph
H
H
EAE2
H
H
H
H
H
—
—

1′-98
Pt
1
1′
Ph
H
EAE2
H
H
H
H
H
H
pic

1′-98X
Pt
1
1′
Ph
H
EAE2
H
H
H
H
H
H
acac

1′-98Y
Pt
0
1′
Ph
H
EAE2
H
H
H
H
H
H
—
—

1′-99
Pt
1
1′
Ph
H
H
AAE1
H
H
H
H
H
pic

1′-99X
Pt
1
1′
Ph
H
H
AAE1
H
H
H
H
H
acac

1′-99Y
Pt
0
1′
Ph
H
H
AAE1
H
H
H
H
H
—
—

1′-100
Pt
1
1′
Ph
H
AAE1
H
H
H
H
H
H
pic

1′-100X
Pt
1
1′
Ph
H
AAE1
H
H
H
H
H
H
acac

1′-100Y
Pt
0
1′
Ph
H
AAE1
H
H
H
H
H
H
—
—

1′-101
Pt
1
1′
Ph
H
H
AAE2
H
H
H
H
H
pic

1′-101X
Pt
1
1′
Ph
H
H
AAE2
H
H
H
H
H
acac

1′-101Y
Pt
0
1′
Ph
H
H
AAE2
H
H
H
H
H
—
—

1′-102
Pt
1
1′
Ph
H
AAE2
H
H
H
H
H
H
pic

1′-102X
Pt
1
1′
Ph
H
AAE2
H
H
H
H
H
H
acac

1′-102Y
Pt
0
1′
Ph
H
AAE2
H
H
H
H
H
H
—
—

1′-103
Pt
1
1′
Ph
H
H
PME1
H
H
H
H
H
pic

1′-103X
Pt
1
1′
Ph
H
H
PME1
H
H
H
H
H
acac

1′-103Y
Pt
0
1′
Ph
H
H
PME1
H
H
H
H
H
—
—

1′-104
Pt
1
1′
Ph
H
PME1
H
H
H
H
H
H
pic

1′-104X
Pt
1
1′
Ph
H
PME1
H
H
H
H
H
H
acac

1′-104Y
Pt
0
1′
Ph
H
PME1
H
H
H
H
H
H
—
—

1′-105
Pt
1
1′
Ph
H
H
PME2
H
H
H
H
H
pic

1′-105X
Pt
1
1′
Ph
H
H
PME2
H
H
H
H
H
acac

1′-105Y
Pt
0
1′
Ph
H
H
PME2
H
H
H
H
H
—
—

1′-106
Pt
1
1′
Ph
H
PME2
H
H
H
H
H
H
pic

1′-106X
Pt
1
1′
Ph
H
PME2
H
H
H
H
H
H
acac

1′-106Y
Pt
0
1′
Ph
H
PME2
H
H
H
H
H
H
—
—

1′-107
Pt
1
1′
Ph
H
H
MET1
H
H
H
H
H
pic

1′-107X
Pt
1
1′
Ph
H
H
MET1
H
H
H
H
H
acac

1′-107Y
Pt
0
1′
Ph
H
H
MET1
H
H
H
H
H
—
—

1′-108
Pt
1
1′
Ph
H
MET1
H
H
H
H
H
H
pic

1′-108X
Pt
1
1′
Ph
H
MET1
H
H
H
H
H
H
acac

1′-108Y
Pt
0
1′
Ph
H
MET1
H
H
H
H
H
H
—
—

1′-109
Pt
1
1′
Ph
H
H
MET2
H
H
H
H
H
pic

1′-109X
Pt
1
1′
Ph
H
H
MET2
H
H
H
H
H
acac

1′-109Y
Pt
0
1′
Ph
H
H
MET2
H
H
H
H
H
—
—

1′-110
Pt
1
1′
Ph
H
MET2
H
H
H
H
H
H
pic

1′-110X
Pt
1
1′
Ph
H
MET2
H
H
H
H
H
H
acac

1′-110Y
Pt
0
1′
Ph
H
MET2
H
H
H
H
H
H
—
—

1′-111
Pt
1
1′
Ph
H
H
EE1
H
H
H
H
H
pic

1′-111X
Pt
1
1′
Ph
H
H
EE1
H
H
H
H
H
acac

1′-111Y
Pt
0
1′
Ph
H
H
EE1
H
H
H
H
H
—
—

1′-112
Pt
1
1′
Ph
H
EE1
H
H
H
H
H
H
pic

1′-112X
Pt
1
1′
Ph
H
EE1
H
H
H
H
H
H
acac

1′-112Y
Pt
0
1′
Ph
H
EE1
H
H
H
H
H
H
—
—

1′-113
Pt
1
1′
Ph
H
H
EE2
H
H
H
H
H
pic

1′-113X
Pt
1
1′
Ph
H
H
EE2
H
H
H
H
H
acac

1′-113Y
Pt
0
1′
Ph
H
H
EE2
H
H
H
H
H
—
—

1′-114
Pt
1
1′
Ph
H
EE2
H
H
H
H
H
H
pic

1′-114X
Pt
1
1′
Ph
H
EE2
H
H
H
H
H
H
acac

1′-114Y
Pt
0
1′
Ph
H
EE2
H
H
H
H
H
H
—
—

1′-115
Pt
1
1′
Ph
H
H
MS1
H
H
H
H
H
pic

1′-115X
Pt
1
1′
Ph
H
H
MS1
H
H
H
H
H
acac

1′-115Y
Pt
0
1′
Ph
H
H
MS1
H
H
H
H
H
—
—

1′-116
Pt
1
1′
Ph
H
MS1
H
H
H
H
H
H
pic

1′-116X
Pt
1
1′
Ph
H
MS1
H
H
H
H
H
H
acac

1′-116Y
Pt
0
1′
Ph
H
MS1
H
H
H
H
H
H
—
—

1′-117
Pt
1
1′
Ph
H
H
MS2
H
H
H
H
H
pic

1′-117X
Pt
1
1′
Ph
H
H
MS2
H
H
H
H
H
acac

1′-117Y
Pt
0
1′
Ph
H
H
MS2
H
H
H
H
H
—
—

1′-118
Pt
1
1′
Ph
H
MS2
H
H
H
H
H
H
pic

1′-118X
Pt
1
1′
Ph
H
MS2
H
H
H
H
H
H
acac

1′-118Y
Pt
0
1′
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 30

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2′-1
Pt
1
2′
Ph
H
H
H
H
H
H
H
H
H
pic

2′-1X
Pt
1
2′
Ph
H
H
H
H
H
H
H
H
H
acac

2′-1Y
Pt
0
2′
Ph
H
H
H
H
H
H
H
H
H
—
—

2′-2
Pt
1
2′
Ph
H
F
H
F
H
H
H
H
H
pic

2′-2X
Pt
1
2′
Ph
H
F
H
F
H
H
H
H
H
acac

2′-2Y
Pt
0
2′
Ph
H
F
H
F
H
H
H
H
H
—
—

2′-3
Pt
1
2′
Ph
F
H
H
F
H
H
H
H
H
pic

2′-3X
Pt
1
2′
Ph
F
H
H
F
H
H
H
H
H
acac

2′-3Y
Pt
0
2′
Ph
F
H
H
F
H
H
H
H
H
—
—

2′-4
Pt
1
2′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

2′-4X
Pt
1
2′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

2′-4Y
Pt
0
2′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

2′-5
Pt
1
2′
Ph
H
F
CF₃
H
H
H
H
H
H
pic

2′-5X
Pt
1
2′
Ph
H
F
CF₃
H
H
H
H
H
H
acac

2′-5Y
Pt
0
2′
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

2′-6
Pt
1
2′
Ph
F
H
CF₃
H
H
H
H
H
H
pic

2′-6X
Pt
1
2′
Ph
F
H
CF₃
H
H
H
H
H
H
acac

2′-6Y
Pt
0
2′
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

2′-7
Pt
1
2′
Ph
F
F
F
F
H
H
H
H
H
pic

2′-7X
Pt
1
2′
Ph
F
F
F
F
H
H
H
H
H
acac

2′-7Y
Pt
0
2′
Ph
F
F
F
F
H
H
H
H
H
—
—

2′-8
Pt
1
2′
Ph
H
F
H
CH₃
H
H
H
H
H
pic

2′-8X
Pt
1
2′
Ph
H
F
H
CH₃
H
H
H
H
H
acac

2′-8Y
Pt
0
2′
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

2′-9
Pt
1
2′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

2′-9X
Pt
1
2′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

2′-9Y
Pt
0
2′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

2′-10
Pt
1
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

2′-10X
Pt
1
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

2′-10Y
Pt
0
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

2′-11
Pt
1
2′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

2′-11X
Pt
1
2′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

2′-11Y
Pt
0
2′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

2′-12
Pt
1
2′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

2′-12X
Pt
1
2′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

2′-12Y
Pt
0
2′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

2′-13
Pt
1
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

2′-13X
Pt
1
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

2′-13Y
Pt
0
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

2′-14
Pt
1
2′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

2′-14X
Pt
1
2′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

2′-14Y
Pt
0
2′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

2′-15
Pt
1
2′
Ph
H
H
NO₂
H
H
H
H
H
H
pic

2′-15X
Pt
1
2′
Ph
H
H
NO₂
H
H
H
H
H
H
acac

2′-15Y
Pt
0
2′
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

2′-16
Pt
1
2′
Ph
F
H
NO₂
H
H
H
H
H
H
pic

2′-16X
Pt
1
2′
Ph
F
H
NO₂
H
H
H
H
H
H
acac

2′-16Y
Pt
0
2′
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

2′-17
Pt
1
2′
Ph
F
H
NO₂
F
H
H
H
H
H
pic

2′-17X
Pt
1
2′
Ph
F
H
NO₂
F
H
H
H
H
H
acac

2′-17Y
Pt
0
2′
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

2′-18
Pt
1
2′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

2′-18X
Pt
1
2′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

2′-18Y
Pt
0
2′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

2′-19
Pt
1
2′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

2′-19X
Pt
1
2′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

2′-19Y
Pt
0
2′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

2′-20
Pt
1
2′
Ph
H
H
CF₃
H
H
H
H
H
H
pic

2′-20X
Pt
1
2′
Ph
H
H
CF₃
H
H
H
H
H
H
acac

2′-20Y
Pt
0
2′
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

2′-21
Pt
1
2′
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

2′-21X
Pt
1
2′
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

2′-21Y
Pt
0
2′
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

2′-22
Pt
1
2′
Ph
H
NO₂
H
H
H
H
H
H
H
pic

2′-22X
Pt
1
2′
Ph
H
NO₂
H
H
H
H
H
H
H
acac

2′-22Y
Pt
0
2′
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

2′-23
Pt
1
2′
Ph
H
CF₃
H
H
H
H
H
H
H
pic

2′-23X
Pt
1
2′
Ph
H
CF₃
H
H
H
H
H
H
H
acac

2′-23Y
Pt
0
2′
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

2′-24
Pt
1
2′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

2′-24X
Pt
1
2′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

2′-24Y
Pt
0
2′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

2′-25
Pt
1
2′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

2′-25X
Pt
1
2′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

2′-25Y
Pt
0
2′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

2′-26
Pt
1
2′
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

2′-26X
Pt
1
2′
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

2′-26Y
Pt
0
2′
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

2′-27
Pt
1
2′
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

2′-27X
Pt
1
2′
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

2′-27Y
Pt
0
2′
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

2′-28
Pt
1
2′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

2′-28X
Pt
1
2′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

2′-28Y
Pt
0
2′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

2′-29
Pt
1
2′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

2′-29X
Pt
1
2′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

2′-29Y
Pt
0
2′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

2′-30
Pt
1
2′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

2′-30X
Pt
1
2′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

2′-30Y
Pt
0
2′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

2′-31
Pt
1
2′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

2′-31X
Pt
1
2′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

2′-31Y
Pt
0
2′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

2′-32
Pt
1
2′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

2′-32X
Pt
1
2′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

2′-32Y
Pt
0
2′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

2′-33
Pt
1
2′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

2′-33X
Pt
1
2′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

2′-33Y
Pt
0
2′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

2′-34
Pt
1
2′
Ph
H
F
H
F
H
H
H
CH₃
H
pic

2′-34X
Pt
1
2′
Ph
H
F
H
F
H
H
H
CH₃
H
acac

2′-34Y
Pt
0
2′
Ph
H
F
H
F
H
H
H
CH₃
H
—
—

2′-35
Pt
1
2′
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
pic

2′-35X
Pt
1
2′
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
acac

2′-35Y
Pt
0
2′
Ph
CF₃
H
CF₃
H
H
H
H
CH₃
H
—
—

2′-36
Pt
1
2′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

2′-36X
Pt
1
2′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

2′-36Y
Pt
0
2′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

2′-37
Pt
1
2′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2′-37X
Pt
1
2′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

2′-37Y
Pt
0
2′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2′-38
Pt
1
2′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

2′-38X
Pt
1
2′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

2′-38Y
Pt
0
2′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

2′-39
Pt
1
2′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

2′-39X
Pt
1
2′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

2′-39Y
Pt
0
2′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

2′-40
Pt
1
2′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

2′-40X
Pt
1
2′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

2′-40Y
Pt
0
2′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

2′-41
Pt
1
2′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

2′-41X
Pt
1
2′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

2′-41Y
Pt
0
2′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

2′-42
Pt
1
2′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

2′-42X
Pt
1
2′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

2′-42Y
Pt
0
2′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

2′-43
Pt
1
2′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2′-43X
Pt
1
2′
Ph
Si(CH₃)₄
H
Si(CH₃)₄
H
H
H
H
H
H
acac

2′-43Y
Pt
0
2′
Ph
Si(CH₃)₅
H
Si(CH₃)₅
H
H
H
H
H
H
—
—

2′-44
Pt
1
2′
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

2′-44X
Pt
1
2′
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

2′-44Y
Pt
0
2′
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

2′-45
Pt
1
2′
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

2′-45X
Pt
1
2′
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

2′-45Y
Pt
0
2′
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

2′-46
Pt
1
2′
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

2′-46X
Pt
1
2′
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

2′-46Y
Pt
0
2′
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

2′-47
Pt
1
2′
Ph
H
H
BL
H
H
H
H
H
pic

2′-47X
Pt
1
2′
Ph
H
H
BL
H
H
H
H
H
acac

2′-47Y
Pt
0
2′
Ph
H
H
BL
H
H
H
H
H
—
—

2′-48
Pt
1
2′
Ph
H
BL
H
H
H
H
H
H
pic

2′-48X
Pt
1
2′
Ph
H
BL
H
H
H
H
H
H
acac

2′-48Y
Pt
0
2′
Ph
H
BL
H
H
H
H
H
H
—
—

2′-49
Pt
1
2′
Ph
H
H
PL
H
H
H
H
H
pic

2′-49X
Pt
1
2′
Ph
H
H
PL
H
H
H
H
H
acac

2′-49Y
Pt
0
2′
Ph
H
H
PL
H
H
H
H
H
—
—

2′-50
Pt
1
2′
Ph
H
PL
H
H
H
H
H
H
pic

2′-50X
Pt
1
2′
Ph
H
PL
H
H
H
H
H
H
acac

2′-50Y
Pt
0
2′
Ph
H
PL
H
H
H
H
H
H
—
—

2′-51
Pt
1
2′
Ph
H
H
MEE1
H
H
H
H
H
pic

2′-51X
Pt
1
2′
Ph
H
H
MEE1
H
H
H
H
H
acac

2′-51Y
Pt
0
2′
Ph
H
H
MEE1
H
H
H
H
H
—
—

2′-52
Pt
1
2′
Ph
H
MEE1
H
H
H
H
H
H
pic

2′-52X
Pt
1
2′
Ph
H
MEE1
H
H
H
H
H
H
acac

2′-52Y
Pt
0
2′
Ph
H
MEE1
H
H
H
H
H
H
—
—

2′-53
Pt
1
2′
Ph
H
H
MEE2
H
H
H
H
H
pic

2′-53X
Pt
1
2′
Ph
H
H
MEE2
H
H
H
H
H
acac

2′-53Y
Pt
0
2′
Ph
H
H
MEE2
H
H
H
H
H
—
—

2′-54
Pt
1
2′
Ph
H
MEE2
H
H
H
H
H
H
pic

2′-54X
Pt
1
2′
Ph
H
MEE2
H
H
H
H
H
H
acac

2′-54Y
Pt
0
2′
Ph
H
MEE2
H
H
H
H
H
H
—
—

2′-55
Pt
1
2′
Ph
H
H
PA1
H
H
H
H
H
pic

2′-55X
Pt
1
2′
Ph
H
H
PA1
H
H
H
H
H
acac

2′-55Y
Pt
0
2′
Ph
H
H
PA1
H
H
H
H
H
—
—

2′-56
Pt
1
2′
Ph
H
PA1
H
H
H
H
H
H
pic

2′-56X
Pt
1
2′
Ph
H
PA1
H
H
H
H
H
H
acac

2′-56Y
Pt
0
2′
Ph
H
PA1
H
H
H
H
H
H
—
—

2′-57
Pt
1
2′
Ph
H
H
PA2
H
H
H
H
H
pic

2′-57X
Pt
1
2′
Ph
H
H
PA2
H
H
H
H
H
acac

2′-57Y
Pt
0
2′
Ph
H
H
PA2
H
H
H
H
H
—
—

2′-58
Pt
1
2′
Ph
H
PA2
H
H
H
H
H
H
pic

2′-58X
Pt
1
2′
Ph
H
PA2
H
H
H
H
H
H
acac

2′-58Y
Pt
0
2′
Ph
H
PA2
H
H
H
H
H
H
—
—

2′-59
Pt
1
2′
Ph
H
H
EA1
H
H
H
H
H
pic

2′-59X
Pt
1
2′
Ph
H
H
EA1
H
H
H
H
H
acac

2′-59Y
Pt
0
2′
Ph
H
H
EA1
H
H
H
H
H
—
—

2′-60
Pt
1
2′
Ph
H
EA2
H
H
H
H
H
H
pic

2′-60X
Pt
1
2′
Ph
H
EA2
H
H
H
H
H
H
acac

2′-60Y
Pt
0
2′
Ph
H
EA2
H
H
H
H
H
H
—
—

2′-61
Pt
1
2′
Ph
H
H
ME
H
H
H
H
H
pic

2′-61X
Pt
1
2′
Ph
H
H
ME
H
H
H
H
H
acac

2′-61Y
Pt
0
2′
Ph
H
H
ME
H
H
H
H
H
—
—

2′-62
Pt
1
2′
Ph
H
ME
H
H
H
H
H
H
pic

2′-62X
Pt
1
2′
Ph
H
ME
H
H
H
H
H
H
acac

2′-62Y
Pt
0
2′
Ph
H
ME
H
H
H
H
H
H
—
—

2′-63
Pt
1
2′
Ph
H
H
AT
H
H
H
H
H
pic

2′-63X
Pt
1
2′
Ph
H
H
AT
H
H
H
H
H
acac

2′-63Y
Pt
0
2′
Ph
H
H
AT
H
H
H
H
H
—
—

2′-64
Pt
1
2′
Ph
H
AT
H
H
H
H
H
H
pic

2′-64X
Pt
1
2′
Ph
H
AT
H
H
H
H
H
H
acac

2′-64Y
Pt
0
2′
Ph
H
AT
H
H
H
H
H
H
—
—

2′-65
Pt
1
2′
Ph
H
H
MES1
H
H
H
H
H
pic

2′-65X
Pt
1
2′
Ph
H
H
MES1
H
H
H
H
H
acac

2′-65Y
Pt
0
2′
Ph
H
H
MES1
H
H
H
H
H
—
—

2′-66
Pt
1
2′
Ph
H
MES1
H
H
H
H
H
H
pic

2′-66X
Pt
1
2′
Ph
H
MES1
H
H
H
H
H
H
acac

2′-66Y
Pt
0
2′
Ph
H
MES1
H
H
H
H
H
H
—
—

2′-67
Pt
1
2′
Ph
H
H
MES2
H
H
H
H
H
pic

2′-67X
Pt
1
2′
Ph
H
H
MES2
H
H
H
H
H
acac

2′-67Y
Pt
0
2′
Ph
H
H
MES2
H
H
H
H
H
—
—

2′-68
Pt
1
2′
Ph
H
MES2
H
H
H
H
H
H
pic

2′-68X
Pt
1
2′
Ph
H
MES2
H
H
H
H
H
H
acac

2′-68Y
Pt
0
2′
Ph
H
MES2
H
H
H
H
H
H
—
—

2′-69
Pt
1
2′
Ph
H
H
PS1
H
H
H
H
H
pic

2′-69X
Pt
1
2′
Ph
H
H
PS1
H
H
H
H
H
acac

2′-69Y
Pt
0
2′
Ph
H
H
PS1
H
H
H
H
H
—
—

2′-70
Pt
1
2′
Ph
H
PS1
H
H
H
H
H
H
pic

2′-70X
Pt
1
2′
Ph
H
PS1
H
H
H
H
H
H
acac

2′-70Y
Pt
0
2′
Ph
H
PS1
H
H
H
H
H
H
—
—

2′-71
Pt
1
2′
Ph
H
H
PS2
H
H
H
H
H
pic

2′-71X
Pt
1
2′
Ph
H
H
PS2
H
H
H
H
H
acac

2′-71Y
Pt
0
2′
Ph
H
H
PS2
H
H
H
H
H
—
—

2′-72
Pt
1
2′
Ph
H
PS2
H
H
H
H
H
H
pic

2′-72X
Pt
1
2′
Ph
H
PS2
H
H
H
H
H
H
acac

2′-72Y
Pt
0
2′
Ph
H
PS2
H
H
H
H
H
H
—
—

2′-73
Pt
1
2′
Ph
H
H
BAL1
H
H
H
H
H
pic

2′-73X
Pt
1
2′
Ph
H
H
BAL1
H
H
H
H
H
acac

2′-73Y
Pt
0
2′
Ph
H
H
BAL1
H
H
H
H
H
—
—

2′-74
Pt
1
2′
Ph
H
BAL1
H
H
H
H
H
H
pic

2′-74X
Pt
1
2′
Ph
H
BAL1
H
H
H
H
H
H
acac

2′-74Y
Pt
0
2′
Ph
H
BAL1
H
H
H
H
H
H
—
—

2′-75
Pt
1
2′
Ph
H
H
BAL2
H
H
H
H
H
pic

2′-75X
Pt
1
2′
Ph
H
H
BAL2
H
H
H
H
H
acac

2′-75Y
Pt
0
2′
Ph
H
H
BAL2
H
H
H
H
H
—
—

2′-76
Pt
1
2′
Ph
H
BAL2
H
H
H
H
H
H
pic

2′-76X
Pt
1
2′
Ph
H
BAL2
H
H
H
H
H
H
acac

2′-76Y
Pt
0
2′
Ph
H
BAL2
H
H
H
H
H
H
—
—

2′-77
Pt
1
2′
Ph
H
H
MEK1
H
H
H
H
H
pic

2′-77X
Pt
1
2′
Ph
H
H
MEK1
H
H
H
H
H
acac

2′-77Y
Pt
0
2′
Ph
H
H
MEK1
H
H
H
H
H
—
—

2′-78
Pt
1
2′
Ph
H
MEK1
H
H
H
H
H
H
pic

2′-78X
Pt
1
2′
Ph
H
MEK1
H
H
H
H
H
H
acac

2′-78Y
Pt
0
2′
Ph
H
MEK1
H
H
H
H
H
H
—
—

2′-79
Pt
1
2′
Ph
H
H
MEK2
H
H
H
H
H
pic

2′-79X
Pt
1
2′
Ph
H
H
MEK2
H
H
H
H
H
acac

2′-79Y
Pt
0
2′
Ph
H
H
MEK2
H
H
H
H
H
—
—

2′-80
Pt
1
2′
Ph
H
MEK2
H
H
H
H
H
H
pic

2′-80X
Pt
1
2′
Ph
H
MEK2
H
H
H
H
H
H
acac

2′-80Y
Pt
0
2′
Ph
H
MEK2
H
H
H
H
H
H
—
—

2′-81
Pt
1
2′
Ph
H
H
PAL1
H
H
H
H
H
pic

2′-81X
Pt
1
2′
Ph
H
H
PAL1
H
H
H
H
H
acac

2′-81Y
Pt
0
2′
Ph
H
H
PAL1
H
H
H
H
H
—
—

2′-82
Pt
1
2′
Ph
H
PAL1
H
H
H
H
H
H
pic

2′-82X
Pt
1
2′
Ph
H
PAL1
H
H
H
H
H
H
acac

2′-82Y
Pt
0
2′
Ph
H
PAL1
H
H
H
H
H
H
—
—

2′-83
Pt
1
2′
Ph
H
H
PAL2
H
H
H
H
H
pic

2′-83X
Pt
1
2′
Ph
H
H
PAL2
H
H
H
H
H
acac

2′-83Y
Pt
0
2′
Ph
H
H
PAL2
H
H
H
H
H
—
—

2′-84
Pt
1
2′
Ph
H
PAL2
H
H
H
H
H
H
pic

2′-84X
Pt
1
2′
Ph
H
PAL2
H
H
H
H
H
H
acac

2′-84Y
Pt
0
2′
Ph
H
PAL2
H
H
H
H
H
H
—
—

2′-85
Pt
1
2′
Ph
H
H
MMK
H
H
H
H
H
pic

2′-85X
Pt
1
2′
Ph
H
H
MMK
H
H
H
H
H
acac

2′-85Y
Pt
0
2′
Ph
H
H
MMK
H
H
H
H
H
—
—

2′-86
Pt
1
2′
Ph
H
MMK
H
H
H
H
H
H
pic

2′-86X
Pt
1
2′
Ph
H
MMK
H
H
H
H
H
H
acac

2′-86Y
Pt
0
2′
Ph
H
MMK
H
H
H
H
H
H
—
—

2′-87
Pt
1
2′
Ph
H
H
EES1
H
H
H
H
H
pic

2′-87X
Pt
1
2′
Ph
H
H
EES1
H
H
H
H
H
acac

2′-87Y
Pt
0
2′
Ph
H
H
EES1
H
H
H
H
H
—
—

2′-88
Pt
1
2′
Ph
H
EES2
H
H
H
H
H
H
pic

2′-88X
Pt
1
2′
Ph
H
EES2
H
H
H
H
H
H
acac

2′-88Y
Pt
0
2′
Ph
H
EES2
H
H
H
H
H
H
—
—

2′-89
Pt
1
2′
Ph
H
H
PAE1
H
H
H
H
H
pic

2′-89X
Pt
1
2′
Ph
H
H
PAE1
H
H
H
H
H
acac

2′-89Y
Pt
0
2′
Ph
H
H
PAE1
H
H
H
H
H
—
—

2′-90
Pt
1
2′
Ph
H
PAE2
H
H
H
H
H
H
pic

2′-90X
Pt
1
2′
Ph
H
PAE2
H
H
H
H
H
H
acac

2′-90Y
Pt
0
2′
Ph
H
PAE2
H
H
H
H
H
H
—
—

2′-91
Pt
1
2′
Ph
H
H
AME1
H
H
H
H
H
pic

2′-91X
Pt
1
2′
Ph
H
H
AME1
H
H
H
H
H
acac

2′-91Y
Pt
0
2′
Ph
H
H
AME1
H
H
H
H
H
—
—

2′-92
Pt
1
2′
Ph
H
AME1
H
H
H
H
H
H
pic

2′-92X
Pt
1
2′
Ph
H
AME1
H
H
H
H
H
H
acac

2′-92Y
Pt
0
2′
Ph
H
AME1
H
H
H
H
H
H
—
—

2′-93
Pt
1
2′
Ph
H
H
AME2
H
H
H
H
H
pic

2′-93X
Pt
1
2′
Ph
H
H
AME2
H
H
H
H
H
acac

2′-93Y
Pt
0
2′
Ph
H
H
AME2
H
H
H
H
H
—
—

2′-94
Pt
1
2′
Ph
H
AME2
H
H
H
H
H
H
pic

2′-94X
Pt
1
2′
Ph
H
AME2
H
H
H
H
H
H
acac

2′-94Y
Pt
0
2′
Ph
H
AME2
H
H
H
H
H
H
—
—

2′-95
Pt
1
2′
Ph
H
H
EAE1
H
H
H
H
H
pic

2′-95X
Pt
1
2′
Ph
H
H
EAE1
H
H
H
H
H
acac

2′-95Y
Pt
0
2′
Ph
H
H
EAE1
H
H
H
H
H
—
—

2′-96
Pt
1
2′
Ph
H
EAE1
H
H
H
H
H
H
pic

2′-96X
Pt
1
2′
Ph
H
EAE1
H
H
H
H
H
H
acac

2′-96Y
Pt
0
2′
Ph
H
EAE1
H
H
H
H
H
H
—
—

2′-97
Pt
1
2′
Ph
H
H
EAE2
H
H
H
H
H
pic

2′-97X
Pt
1
2′
Ph
H
H
EAE2
H
H
H
H
H
acac

2′-97Y
Pt
0
2′
Ph
H
H
EAE2
H
H
H
H
H
—
—

2′-98
Pt
1
2′
Ph
H
EAE2
H
H
H
H
H
H
pic

2′-98X
Pt
1
2′
Ph
H
EAE2
H
H
H
H
H
H
acac

2′-98Y
Pt
0
2′
Ph
H
EAE2
H
H
H
H
H
H
—
—

2′-99
Pt
1
2′
Ph
H
H
AAE1
H
H
H
H
H
pic

2′-99X
Pt
1
2′
Ph
H
H
AAE1
H
H
H
H
H
acac

2′-99Y
Pt
0
2′
Ph
H
H
AAE1
H
H
H
H
H
—
—

2′-100
Pt
1
2′
Ph
H
AAE1
H
H
H
H
H
H
pic

2′-100X
Pt
1
2′
Ph
H
AAE1
H
H
H
H
H
H
acac

2′-100Y
Pt
0
2′
Ph
H
AAE1
H
H
H
H
H
H
—
—

2′-101
Pt
1
2′
Ph
H
H
AAE2
H
H
H
H
H
pic

2′-101X
Pt
1
2′
Ph
H
H
AAE2
H
H
H
H
H
acac

2′-101Y
Pt
0
2′
Ph
H
H
AAE2
H
H
H
H
H
—
—

2′-102
Pt
1
2′
Ph
H
AAE2
H
H
H
H
H
H
pic

2′-102X
Pt
1
2′
Ph
H
AAE2
H
H
H
H
H
H
acac

2′-102Y
Pt
0
2′
Ph
H
AAE2
H
H
H
H
H
H
—
—

2′-103
Pt
1
2′
Ph
H
H
PME1
H
H
H
H
H
pic

2′-103X
Pt
1
2′
Ph
H
H
PME1
H
H
H
H
H
acac

2′-103Y
Pt
0
2′
Ph
H
H
PME1
H
H
H
H
H
—
—

2′-104
Pt
1
2′
Ph
H
PME1
H
H
H
H
H
H
pic

2′-104X
Pt
1
2′
Ph
H
PME1
H
H
H
H
H
H
acac

2′-104Y
Pt
0
2′
Ph
H
PME1
H
H
H
H
H
H
—
—

2′-105
Pt
1
2′
Ph
H
H
PME2
H
H
H
H
H
pic

2′-105X
Pt
1
2′
Ph
H
H
PME2
H
H
H
H
H
acac

2′-105Y
Pt
0
2′
Ph
H
H
PME2
H
H
H
H
H
—
—

2′-106
Pt
1
2′
Ph
H
PME2
H
H
H
H
H
H
pic

2′-106X
Pt
1
2′
Ph
H
PME2
H
H
H
H
H
H
acac

2′-106Y
Pt
0
2′
Ph
H
PME2
H
H
H
H
H
H
—
—

2′-107
Pt
1
2′
Ph
H
H
MET1
H
H
H
H
H
pic

2′-107X
Pt
1
2′
Ph
H
H
MET1
H
H
H
H
H
acac

2′-107Y
Pt
0
2′
Ph
H
H
MET1
H
H
H
H
H
—
—

2′-108
Pt
1
2′
Ph
H
MET1
H
H
H
H
H
H
pic

2′-108X
Pt
1
2′
Ph
H
MET1
H
H
H
H
H
H
acac

2′-108Y
Pt
0
2′
Ph
H
MET1
H
H
H
H
H
H
—
—

2′-109
Pt
1
2′
Ph
H
H
MET2
H
H
H
H
H
pic

2′-109X
Pt
1
2′
Ph
H
H
MET2
H
H
H
H
H
acac

2′-109Y
Pt
0
2′
Ph
H
H
MET2
H
H
H
H
H
—
—

2′-110
Pt
1
2′
Ph
H
MET2
H
H
H
H
H
H
pic

2′-110X
Pt
1
2′
Ph
H
MET2
H
H
H
H
H
H
acac

2′-110Y
Pt
0
2′
Ph
H
MET2
H
H
H
H
H
H
—
—

2′-111
Pt
1
2′
Ph
H
H
EE1
H
H
H
H
H
pic

2′-111X
Pt
1
2′
Ph
H
H
EE1
H
H
H
H
H
acac

2′-111Y
Pt
0
2′
Ph
H
H
EE1
H
H
H
H
H
—
—

2′-112
Pt
1
2′
Ph
H
EE1
H
H
H
H
H
H
pic

2′-112X
Pt
1
2′
Ph
H
EE1
H
H
H
H
H
H
acac

2′-112Y
Pt
0
2′
Ph
H
EE1
H
H
H
H
H
H
—
—

2′-113
Pt
1
2′
Ph
H
H
EE2
H
H
H
H
H
pic

2′-113X
Pt
1
2′
Ph
H
H
EE2
H
H
H
H
H
acac

2′-113Y
Pt
0
2′
Ph
H
H
EE2
H
H
H
H
H
—
—

2′-114
Pt
1
2′
Ph
H
EE2
H
H
H
H
H
H
pic

2′-114X
Pt
1
2′
Ph
H
EE2
H
H
H
H
H
H
acac

2′-114Y
Pt
0
2′
Ph
H
EE2
H
H
H
H
H
H
—
—

2′-115
Pt
1
2′
Ph
H
H
MS1
H
H
H
H
H
pic

2′-115X
Pt
1
2′
Ph
H
H
MS1
H
H
H
H
H
acac

2′-115Y
Pt
0
2′
Ph
H
H
MS1
H
H
H
H
H
—
—

2′-116
Pt
1
2′
Ph
H
MS1
H
H
H
H
H
H
pic

2′-116X
Pt
1
2′
Ph
H
MS1
H
H
H
H
H
H
acac

2′-116Y
Pt
0
2′
Ph
H
MS1
H
H
H
H
H
H
—
—

2′-117
Pt
1
2′
Ph
H
H
MS2
H
H
H
H
H
pic

2′-117X
Pt
1
2′
Ph
H
H
MS2
H
H
H
H
H
acac

2′-117Y
Pt
0
2′
Ph
H
H
MS2
H
H
H
H
H
—
—

2′-118
Pt
1
2′
Ph
H
MS2
H
H
H
H
H
H
pic

2′-118X
Pt
1
2′
Ph
H
MS2
H
H
H
H
H
H
acac

2′-118Y
Pt
0
2′
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 31

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3′-1
Pt
1
3′
Ph
H
H
H
H
H
H
H
H
H
pic

3′-1X
Pt
1
3′
Ph
H
H
H
H
H
H
H
H
H
acac

3′-1Y
Pt
0
3′
Ph
H
H
H
H
H
H
H
H
H
—
—

3′-2
Pt
1
3′
Ph
H
F
H
F
H
H
H
H
H
pic

3′-2X
Pt
1
3′
Ph
H
F
H
F
H
H
H
H
H
acac

3′-2Y
Pt
0
3′
Ph
H
F
H
F
H
H
H
H
H
—
—

3′-3
Pt
1
3′
Ph
F
H
H
F
H
H
H
H
H
pic

3′-3X
Pt
1
3′
Ph
F
H
H
F
H
H
H
H
H
acac

3′-3Y
Pt
0
3′
Ph
F
H
H
F
H
H
H
H
H
—
—

3′-4
Pt
1
3′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

3′-4X
Pt
1
3′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

3′-4Y
Pt
0
3′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

3′-5
Pt
1
3′
Ph
H
F
CF₃
H
H
H
H
H
H
pic

3′-5X
Pt
1
3′
Ph
H
F
CF₃
H
H
H
H
H
H
acac

3′-5Y
Pt
0
3′
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

3′-6
Pt
1
3′
Ph
F
H
CF₃
H
H
H
H
H
H
pic

3′-6X
Pt
1
3′
Ph
F
H
CF₃
H
H
H
H
H
H
acac

3′-6Y
Pt
0
3′
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

3′-7
Pt
1
3′
Ph
F
F
F
F
H
H
H
H
H
pic

3′-7X
Pt
1
3′
Ph
F
F
F
F
H
H
H
H
H
acac

3′-7Y
Pt
0
3′
Ph
F
F
F
F
H
H
H
H
H
—
—

3′-8
Pt
1
3′
Ph
H
F
H
CH₃
H
H
H
H
H
pic

3′-8X
Pt
1
3′
Ph
H
F
H
CH₃
H
H
H
H
H
acac

3′-8Y
Pt
0
3′
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

3′-9
Pt
1
3′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

3′-9X
Pt
1
3′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

3′-9Y
Pt
0
3′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

3′-10
Pt
1
3′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

3′-10X
Pt
1
3′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

3′-10Y
Pt
0
3′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

3′-11
Pt
1
3′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

3′-11X
Pt
1
3′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

3′-11Y
Pt
0
3′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

3′-12
Pt
1
3′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

3′-12X
Pt
1
3′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

3′-12Y
Pt
0
3′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

3′-13
Pt
1
3′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

3′-13X
Pt
1
3′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

3′-13Y
Pt
0
3′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

3′-14
Pt
1
3′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

3′-14X
Pt
1
3′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

3′-14Y
Pt
0
3′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

3′-15
Pt
1
3′
Ph
H
H
NO₂
H
H
H
H
H
H
pic

3′-15X
Pt
1
3′
Ph
H
H
NO₂
H
H
H
H
H
H
acac

3′-15Y
Pt
0
3′
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

3′-16
Pt
1
3′
Ph
F
H
NO₂
H
H
H
H
H
H
pic

3′-16X
Pt
1
3′
Ph
F
H
NO₂
H
H
H
H
H
H
acac

3′-16Y
Pt
0
3′
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

3′-17
Pt
1
3′
Ph
F
H
NO₂
F
H
H
H
H
H
pic

3′-17X
Pt
1
3′
Ph
F
H
NO₂
F
H
H
H
H
H
acac

3′-17Y
Pt
0
3′
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

3′-18
Pt
1
3′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

3′-18X
Pt
1
3′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

3′-18Y
Pt
0
3′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

3′-19
Pt
1
3′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

3′-19X
Pt
1
3′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

3′-19Y
Pt
0
3′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

3′-20
Pt
1
3′
Ph
H
H
CF₃
H
H
H
H
H
H
pic

3′-20X
Pt
1
3′
Ph
H
H
CF₃
H
H
H
H
H
H
acac

3′-20Y
Pt
0
3′
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

3′-21
Pt
1
3′
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

3′-21X
Pt
1
3′
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

3′-21Y
Pt
0
3′
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

3′-22
Pt
1
3′
Ph
H
NO₂
H
H
H
H
H
H
H
pic

3′-22X
Pt
1
3′
Ph
H
NO₂
H
H
H
H
H
H
H
acac

3′-22Y
Pt
0
3′
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

3′-23
Pt
1
3′
Ph
H
CF₃
H
H
H
H
H
H
H
pic

3′-23X
Pt
1
3′
Ph
H
CF₃
H
H
H
H
H
H
H
acac

3′-23Y
Pt
0
3′
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

3′-24
Pt
1
3′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

3′-24X
Pt
1
3′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

3′-24Y
Pt
0
3′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

3′-25
Pt
1
3′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

3′-25X
Pt
1
3′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

3′-25Y
Pt
0
3′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

3′-26
Pt
1
3′
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

3′-26X
Pt
1
3′
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

3′-26Y
Pt
0
3′
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

3′-27
Pt
1
3′
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

3′-27X
Pt
1
3′
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

3′-27Y
Pt
0
3′
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

3′-28
Pt
1
3′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

3′-28X
Pt
1
3′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

3′-28Y
Pt
0
3′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

3′-29
Pt
1
3′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

3′-29X
Pt
1
3′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

3′-29Y
Pt
0
3′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

3′-30
Pt
1
3′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

3′-30X
Pt
1
3′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

3′-30Y
Pt
0
3′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

3′-31
Pt
1
3′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

3′-31X
Pt
1
3′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

3′-31Y
Pt
0
3′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

3′-32
Pt
1
3′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

3′-32X
Pt
1
3′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

3′-32Y
Pt
0
3′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

3′-33
Pt
1
3′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

3′-33X
Pt
1
3′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

3′-33Y
Pt
0
3′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

3′-34
Pt
1
3′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

3′-34X
Pt
1
3′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

3′-34Y
Pt
0
3′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

3′-35
Pt
1
3′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3′-35X
Pt
1
3′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3′-35Y
Pt
0
3′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3′-36
Pt
1
3′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

3′-36X
Pt
1
3′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

3′-36Y
Pt
0
3′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

3′-37
Pt
1
3′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

3′-37X
Pt
1
3′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

3′-37Y
Pt
0
3′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

3′-38
Pt
1
3′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

3′-38X
Pt
1
3′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

3′-38Y
Pt
0
3′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

3′-39
Pt
1
3′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

3′-39X
Pt
1
3′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

3′-39Y
Pt
0
3′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

3′-40
Pt
1
3′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

3′-40X
Pt
1
3′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

3′-40Y
Pt
0
3′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

3′-41
Pt
1
3′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3′-41X
Pt
1
3′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3′-41Y
Pt
0
3′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3′-42
Pt
1
3′
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

3′-42X
Pt
1
3′
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

3′-42Y
Pt
0
3′
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

3′-43
Pt
1
3′
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

3′-43X
Pt
1
3′
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

3′-43Y
Pt
0
3′
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

3′-44
Pt
1
3′
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

3′-44X
Pt
1
3′
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

3′-44Y
Pt
0
3′
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

3′-45
Pt
1
3′
Ph
H
H
BL
H
H
H
H
H
pic

3′-45X
Pt
1
3′
Ph
H
H
BL
H
H
H
H
H
acac

3′-45Y
Pt
0
3′
Ph
H
H
BL
H
H
H
H
H
—
—

3′-46
Pt
1
3′
Ph
H
BL
H
H
H
H
H
H
pic

3′-46X
Pt
1
3′
Ph
H
BL
H
H
H
H
H
H
acac

3′-46Y
Pt
0
3′
Ph
H
BL
H
H
H
H
H
H
—
—

3′-47
Pt
1
3′
Ph
H
H
PL
H
H
H
H
H
pic

3′-47X
Pt
1
3′
Ph
H
H
PL
H
H
H
H
H
acac

3′-47Y
Pt
0
3′
Ph
H
H
PL
H
H
H
H
H
—
—

3′-48
Pt
1
3′
Ph
H
PL
H
H
H
H
H
H
pic

3′-48X
Pt
1
3′
Ph
H
PL
H
H
H
H
H
H
acac

3′-48Y
Pt
0
3′
Ph
H
PL
H
H
H
H
H
H
—
—

3′-49
Pt
1
3′
Ph
H
H
MEE1
H
H
H
H
H
pic

3′-49X
Pt
1
3′
Ph
H
H
MEE1
H
H
H
H
H
acac

3′-49Y
Pt
0
3′
Ph
H
H
MEE1
H
H
H
H
H
—
—

3′-50
Pt
1
3′
Ph
H
MEE1
H
H
H
H
H
H
pic

3′-50X
Pt
1
3′
Ph
H
MEE1
H
H
H
H
H
H
acac

3′-50Y
Pt
0
3′
Ph
H
MEE1
H
H
H
H
H
H
—
—

3′-51
Pt
1
3′
Ph
H
H
MEE2
H
H
H
H
H
pic

3′-51X
Pt
1
3′
Ph
H
H
MEE2
H
H
H
H
H
acac

3′-51Y
Pt
0
3′
Ph
H
H
MEE2
H
H
H
H
H
—
—

3′-52
Pt
1
3′
Ph
H
MEE2
H
H
H
H
H
H
pic

3′-52X
Pt
1
3′
Ph
H
MEE2
H
H
H
H
H
H
acac

3′-52Y
Pt
0
3′
Ph
H
MEE2
H
H
H
H
H
H
—
—

3′-53
Pt
1
3′
Ph
H
H
PA1
H
H
H
H
H
pic

3′-53X
Pt
1
3′
Ph
H
H
PA1
H
H
H
H
H
acac

3′-53Y
Pt
0
3′
Ph
H
H
PA1
H
H
H
H
H
—
—

3′-54
Pt
1
3′
Ph
H
PA1
H
H
H
H
H
H
pic

3′-54X
Pt
1
3′
Ph
H
PA1
H
H
H
H
H
H
acac

3′-54Y
Pt
0
3′
Ph
H
PA1
H
H
H
H
H
H
—
—

3′-55
Pt
1
3′
Ph
H
H
PA2
H
H
H
H
H
pic

3′-55X
Pt
1
3′
Ph
H
H
PA2
H
H
H
H
H
acac

3′-55Y
Pt
0
3′
Ph
H
H
PA2
H
H
H
H
H
—
—

3′-56
Pt
1
3′
Ph
H
PA2
H
H
H
H
H
H
pic

3′-56X
Pt
1
3′
Ph
H
PA2
H
H
H
H
H
H
acac

3′-56Y
Pt
0
3′
Ph
H
PA2
H
H
H
H
H
H
—
—

3′-57
Pt
1
3′
Ph
H
H
EA1
H
H
H
H
H
pic

3′-57X
Pt
1
3′
Ph
H
H
EA1
H
H
H
H
H
acac

3′-57Y
Pt
0
3′
Ph
H
H
EA1
H
H
H
H
H
—
—

3′-58
Pt
1
3′
Ph
H
EA2
H
H
H
H
H
H
pic

3′-58X
Pt
1
3′
Ph
H
EA2
H
H
H
H
H
H
acac

3′-58Y
Pt
0
3′
Ph
H
EA2
H
H
H
H
H
H
—
—

3′-59
Pt
1
3′
Ph
H
H
ME
H
H
H
H
H
pic

3′-59X
Pt
1
3′
Ph
H
H
ME
H
H
H
H
H
acac

3′-59Y
Pt
0
3′
Ph
H
H
ME
H
H
H
H
H
—
—

3′-60
Pt
1
3′
Ph
H
ME
H
H
H
H
H
H
pic

3′-60X
Pt
1
3′
Ph
H
ME
H
H
H
H
H
H
acac

3′-60Y
Pt
0
3′
Ph
H
ME
H
H
H
H
H
H
—
—

3′-61
Pt
1
3′
Ph
H
H
AT
H
H
H
H
H
pic

3′-61X
Pt
1
3′
Ph
H
H
AT
H
H
H
H
H
acac

3′-61Y
Pt
0
3′
Ph
H
H
AT
H
H
H
H
H
—
—

3′-62
Pt
1
3′
Ph
H
AT
H
H
H
H
H
H
pic

3′-62X
Pt
1
3′
Ph
H
AT
H
H
H
H
H
H
acac

3′-62Y
Pt
0
3′
Ph
H
AT
H
H
H
H
H
H
—
—

3′-63
Pt
1
3′
Ph
H
H
MES1
H
H
H
H
H
pic

3′-63X
Pt
1
3′
Ph
H
H
MES1
H
H
H
H
H
acac

3′-63Y
Pt
0
3′
Ph
H
H
MES1
H
H
H
H
H
—
—

3′-64
Pt
1
3′
Ph
H
MES1
H
H
H
H
H
H
pic

3′-64X
Pt
1
3′
Ph
H
MES1
H
H
H
H
H
H
acac

3′-64Y
Pt
0
3′
Ph
H
MES1
H
H
H
H
H
H
—
—

3′-65
Pt
1
3′
Ph
H
H
MES2
H
H
H
H
H
pic

3′-65X
Pt
1
3′
Ph
H
H
MES2
H
H
H
H
H
acac

3′-65Y
Pt
0
3′
Ph
H
H
MES2
H
H
H
H
H
—
—

3′-66
Pt
1
3′
Ph
H
MES2
H
H
H
H
H
H
pic

3′-66X
Pt
1
3′
Ph
H
MES2
H
H
H
H
H
H
acac

3′-66Y
Pt
0
3′
Ph
H
MES2
H
H
H
H
H
H
—
—

3′-67
Pt
1
3′
Ph
H
H
PS1
H
H
H
H
H
pic

3′-67X
Pt
1
3′
Ph
H
H
PS1
H
H
H
H
H
acac

3′-67Y
Pt
0
3′
Ph
H
H
PS1
H
H
H
H
H
—
—

3′-68
Pt
1
3′
Ph
H
PS1
H
H
H
H
H
H
pic

3′-68X
Pt
1
3′
Ph
H
PS1
H
H
H
H
H
H
acac

3′-68Y
Pt
0
3′
Ph
H
PS1
H
H
H
H
H
H
—
—

3′-69
Pt
1
3′
Ph
H
H
PS2
H
H
H
H
H
pic

3′-69X
Pt
1
3′
Ph
H
H
PS2
H
H
H
H
H
acac

3′-69Y
Pt
0
3′
Ph
H
H
PS2
H
H
H
H
H
—
—

3′-70
Pt
1
3′
Ph
H
PS2
H
H
H
H
H
H
pic

3′-70X
Pt
1
3′
Ph
H
PS2
H
H
H
H
H
H
acac

3′-70Y
Pt
0
3′
Ph
H
PS2
H
H
H
H
H
H
—
—

3′-71
Pt
1
3′
Ph
H
H
BAL1
H
H
H
H
H
pic

3′-71X
Pt
1
3′
Ph
H
H
BAL1
H
H
H
H
H
acac

3′-71Y
Pt
0
3′
Ph
H
H
BAL1
H
H
H
H
H
—
—

3′-72
Pt
1
3′
Ph
H
BAL1
H
H
H
H
H
H
pic

3′-72X
Pt
1
3′
Ph
H
BAL1
H
H
H
H
H
H
acac

3′-72Y
Pt
0
3′
Ph
H
BAL1
H
H
H
H
H
H
—
—

3′-73
Pt
1
3′
Ph
H
H
BAL2
H
H
H
H
H
pic

3′-73X
Pt
1
3′
Ph
H
H
BAL2
H
H
H
H
H
acac

3′-73Y
Pt
0
3′
Ph
H
H
BAL2
H
H
H
H
H
—
—

3′-74
Pt
1
3′
Ph
H
BAL2
H
H
H
H
H
H
pic

3′-74X
Pt
1
3′
Ph
H
BAL2
H
H
H
H
H
H
acac

3′-74Y
Pt
0
3′
Ph
H
BAL2
H
H
H
H
H
H
—
—

3′-75
Pt
1
3′
Ph
H
H
MEK1
H
H
H
H
H
pic

3′-75X
Pt
1
3′
Ph
H
H
MEK1
H
H
H
H
H
acac

3′-75Y
Pt
0
3′
Ph
H
H
MEK1
H
H
H
H
H
—
—

3′-76
Pt
1
3′
Ph
H
MEK1
H
H
H
H
H
H
pic

3′-76X
Pt
1
3′
Ph
H
MEK1
H
H
H
H
H
H
acac

3′-76Y
Pt
0
3′
Ph
H
MEK1
H
H
H
H
H
H
—
—

3′-77
Pt
1
3′
Ph
H
H
MEK2
H
H
H
H
H
pic

3′-77X
Pt
1
3′
Ph
H
H
MEK2
H
H
H
H
H
acac

3′-77Y
Pt
0
3′
Ph
H
H
MEK2
H
H
H
H
H
—
—

3′-78
Pt
1
3′
Ph
H
MEK2
H
H
H
H
H
H
pic

3′-78X
Pt
1
3′
Ph
H
MEK2
H
H
H
H
H
H
acac

3′-78Y
Pt
0
3′
Ph
H
MEK2
H
H
H
H
H
H
—
—

3′-79
Pt
1
3′
Ph
H
H
PAL1
H
H
H
H
H
pic

3′-79X
Pt
1
3′
Ph
H
H
PAL1
H
H
H
H
H
acac

3′-79Y
Pt
0
3′
Ph
H
H
PAL1
H
H
H
H
H
—
—

3′-80
Pt
1
3′
Ph
H
PAL1
H
H
H
H
H
H
pic

3′-80X
Pt
1
3′
Ph
H
PAL1
H
H
H
H
H
H
acac

3′-80Y
Pt
0
3′
Ph
H
PAL1
H
H
H
H
H
H
—
—

3′-81
Pt
1
3′
Ph
H
H
PAL2
H
H
H
H
H
pic

3′-81X
Pt
1
3′
Ph
H
H
PAL2
H
H
H
H
H
acac

3′-81Y
Pt
0
3′
Ph
H
H
PAL2
H
H
H
H
H
—
—

3′-82
Pt
1
3′
Ph
H
PAL2
H
H
H
H
H
H
pic

3′-82X
Pt
1
3′
Ph
H
PAL2
H
H
H
H
H
H
acac

3′-82Y
Pt
0
3′
Ph
H
PAL2
H
H
H
H
H
H
—
—

3′-83
Pt
1
3′
Ph
H
H
MMK
H
H
H
H
H
pic

3′-83X
Pt
1
3′
Ph
H
H
MMK
H
H
H
H
H
acac

3′-83Y
Pt
0
3′
Ph
H
H
MMK
H
H
H
H
H
—
—

3′-84
Pt
1
3′
Ph
H
MMK
H
H
H
H
H
H
pic

3′-84X
Pt
1
3′
Ph
H
MMK
H
H
H
H
H
H
acac

3′-84Y
Pt
0
3′
Ph
H
MMK
H
H
H
H
H
H
—
—

3′-85
Pt
1
3′
Ph
H
H
EES1
H
H
H
H
H
pic

3′-85X
Pt
1
3′
Ph
H
H
EES1
H
H
H
H
H
acac

3′-85Y
Pt
0
3′
Ph
H
H
EES1
H
H
H
H
H
—
—

3′-86
Pt
1
3′
Ph
H
EES2
H
H
H
H
H
H
pic

3′-86X
Pt
1
3′
Ph
H
EES2
H
H
H
H
H
H
acac

3′-86Y
Pt
0
3′
Ph
H
EES2
H
H
H
H
H
H
—
—

3′-87
Pt
1
3′
Ph
H
H
PAE1
H
H
H
H
H
pic

3′-87X
Pt
1
3′
Ph
H
H
PAE1
H
H
H
H
H
acac

3′-87Y
Pt
0
3′
Ph
H
H
PAE1
H
H
H
H
H
—
—

3′-88
Pt
1
3′
Ph
H
PAE2
H
H
H
H
H
H
pic

3′-88X
Pt
1
3′
Ph
H
PAE2
H
H
H
H
H
H
acac

3′-88Y
Pt
0
3′
Ph
H
PAE2
H
H
H
H
H
H
—
—

3′-89
Pt
1
3′
Ph
H
H
AME1
H
H
H
H
H
pic

3′-89X
Pt
1
3′
Ph
H
H
AME1
H
H
H
H
H
acac

3′-89Y
Pt
0
3′
Ph
H
H
AME1
H
H
H
H
H
—
—

3′-90
Pt
1
3′
Ph
H
AME1
H
H
H
H
H
H
pic

3′-90X
Pt
1
3′
Ph
H
AME1
H
H
H
H
H
H
acac

3′-90Y
Pt
0
3′
Ph
H
AME1
H
H
H
H
H
H
—
—

3′-91
Pt
1
3′
Ph
H
H
AME2
H
H
H
H
H
pic

3′-91X
Pt
1
3′
Ph
H
H
AME2
H
H
H
H
H
acac

3′-91Y
Pt
0
3′
Ph
H
H
AME2
H
H
H
H
H
—
—

3′-92
Pt
1
3′
Ph
H
AME2
H
H
H
H
H
H
pic

3′-92X
Pt
1
3′
Ph
H
AME2
H
H
H
H
H
H
acac

3′-92Y
Pt
0
3′
Ph
H
AME2
H
H
H
H
H
H
—
—

3′-93
Pt
1
3′
Ph
H
H
EAE1
H
H
H
H
H
pic

3′-93X
Pt
1
3′
Ph
H
H
EAE1
H
H
H
H
H
acac

3′-93Y
Pt
0
3′
Ph
H
H
EAE1
H
H
H
H
H
—
—

3′-94
Pt
1
3′
Ph
H
EAE1
H
H
H
H
H
H
pic

3′-94X
Pt
1
3′
Ph
H
EAE1
H
H
H
H
H
H
acac

3′-94Y
Pt
0
3′
Ph
H
EAE1
H
H
H
H
H
H
—
—

3′-95
Pt
1
3′
Ph
H
H
EAE2
H
H
H
H
H
pic

3′-95X
Pt
1
3′
Ph
H
H
EAE2
H
H
H
H
H
acac

3′-95Y
Pt
0
3′
Ph
H
H
EAE2
H
H
H
H
H
—
—

3′-96
Pt
1
3′
Ph
H
EAE2
H
H
H
H
H
H
pic

3′-96X
Pt
1
3′
Ph
H
EAE2
H
H
H
H
H
H
acac

3′-96Y
Pt
0
3′
Ph
H
EAE2
H
H
H
H
H
H
—
—

3′-97
Pt
1
3′
Ph
H
H
AAE1
H
H
H
H
H
pic

3′-97X
Pt
1
3′
Ph
H
H
AAE1
H
H
H
H
H
acac

3′-97Y
Pt
0
3′
Ph
H
H
AAE1
H
H
H
H
H
—
—

3′-98
Pt
1
3′
Ph
H
AAE1
H
H
H
H
H
H
pic

3′-98X
Pt
1
3′
Ph
H
AAE1
H
H
H
H
H
H
acac

3′-98Y
Pt
0
3′
Ph
H
AAE1
H
H
H
H
H
H
—
—

3′-99
Pt
1
3′
Ph
H
H
AAE2
H
H
H
H
H
pic

3′-99X
Pt
1
3′
Ph
H
H
AAE2
H
H
H
H
H
acac

3′-99Y
Pt
0
3′
Ph
H
H
AAE2
H
H
H
H
H
—
—

3′-100
Pt
1
3′
Ph
H
AAE2
H
H
H
H
H
H
pic

3′-100X
Pt
1
3′
Ph
H
AAE2
H
H
H
H
H
H
acac

3′-100Y
Pt
0
3′
Ph
H
AAE2
H
H
H
H
H
H
—
—

3′-101
Pt
1
3′
Ph
H
H
PME1
H
H
H
H
H
pic

3′-101X
Pt
1
3′
Ph
H
H
PME1
H
H
H
H
H
acac

3′-101Y
Pt
0
3′
Ph
H
H
PME1
H
H
H
H
H
—
—

3′-102
Pt
1
3′
Ph
H
PME1
H
H
H
H
H
H
pic

3′-102X
Pt
1
3′
Ph
H
PME1
H
H
H
H
H
H
acac

3′-102Y
Pt
0
3′
Ph
H
PME1
H
H
H
H
H
H
—
—

3′-103
Pt
1
3′
Ph
H
H
PME2
H
H
H
H
H
pic

3′-103X
Pt
1
3′
Ph
H
H
PME2
H
H
H
H
H
acac

3′-103Y
Pt
0
3′
Ph
H
H
PME2
H
H
H
H
H
—
—

3′-104
Pt
1
3′
Ph
H
PME2
H
H
H
H
H
H
pic

3′-104X
Pt
1
3′
Ph
H
PME2
H
H
H
H
H
H
acac

3′-104Y
Pt
0
3′
Ph
H
PME2
H
H
H
H
H
H
—
—

3′-105
Pt
1
3′
Ph
H
H
MET1
H
H
H
H
H
pic

3′-105X
Pt
1
3′
Ph
H
H
MET1
H
H
H
H
H
acac

3′-105Y
Pt
0
3′
Ph
H
H
MET1
H
H
H
H
H
—
—

3′-106
Pt
1
3′
Ph
H
MET1
H
H
H
H
H
H
pic

3′-106X
Pt
1
3′
Ph
H
MET1
H
H
H
H
H
H
acac

3′-106Y
Pt
0
3′
Ph
H
MET1
H
H
H
H
H
H
—
—

3′-107
Pt
1
3′
Ph
H
H
MET2
H
H
H
H
H
pic

3′-107X
Pt
1
3′
Ph
H
H
MET2
H
H
H
H
H
acac

3′-107Y
Pt
0
3′
Ph
H
H
MET2
H
H
H
H
H
—
—

3′-108
Pt
1
3′
Ph
H
MET2
H
H
H
H
H
H
pic

3′-108X
Pt
1
3′
Ph
H
MET2
H
H
H
H
H
H
acac

3′-108Y
Pt
0
3′
Ph
H
MET2
H
H
H
H
H
H
—
—

3′-109
Pt
1
3′
Ph
H
H
EE1
H
H
H
H
H
pic

3′-109X
Pt
1
3′
Ph
H
H
EE1
H
H
H
H
H
acac

3′-109Y
Pt
0
3′
Ph
H
H
EE1
H
H
H
H
H
—
—

3′-110
Pt
1
3′
Ph
H
EE1
H
H
H
H
H
H
pic

3′-110X
Pt
1
3′
Ph
H
EE1
H
H
H
H
H
H
acac

3′-110Y
Pt
0
3′
Ph
H
EE1
H
H
H
H
H
H
—
—

3′-111
Pt
1
3′
Ph
H
H
EE2
H
H
H
H
H
pic

3′-111X
Pt
1
3′
Ph
H
H
EE2
H
H
H
H
H
acac

3′-111Y
Pt
0
3′
Ph
H
H
EE2
H
H
H
H
H
—
—

3′-112
Pt
1
3′
Ph
H
EE2
H
H
H
H
H
H
pic

3′-112X
Pt
1
3′
Ph
H
EE2
H
H
H
H
H
H
acac

3′-112Y
Pt
0
3′
Ph
H
EE2
H
H
H
H
H
H
—
—

3′-113
Pt
1
3′
Ph
H
H
MS1
H
H
H
H
H
pic

3′-113X
Pt
1
3′
Ph
H
H
MS1
H
H
H
H
H
acac

3′-113Y
Pt
0
3′
Ph
H
H
MS1
H
H
H
H
H
—
—

3′-114
Pt
1
3′
Ph
H
MS1
H
H
H
H
H
H
pic

3′-114X
Pt
1
3′
Ph
H
MS1
H
H
H
H
H
H
acac

3′-114Y
Pt
0
3′
Ph
H
MS1
H
H
H
H
H
H
—
—

3′-115
Pt
1
3′
Ph
H
H
MS2
H
H
H
H
H
pic

3′-115X
Pt
1
3′
Ph
H
H
MS2
H
H
H
H
H
acac

3′-115Y
Pt
0
3′
Ph
H
H
MS2
H
H
H
H
H
—
—

3′-116
Pt
1
3′
Ph
H
MS2
H
H
H
H
H
H
pic

3′-116X
Pt
1
3′
Ph
H
MS2
H
H
H
H
H
H
acac

3′-116Y
Pt
0
3′
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 32

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4′-1
Pt
1
4′
Ph
H
H
H
H
CH₃
H
H
H
H
pic

4′-1X
Pt
1
4′
Ph
H
H
H
H
CH₃
H
H
H
H
acac

4′-1Y
Pt
0
4′
Ph
H
H
H
H
CH₃
H
H
H
H
—
—

4′-2
Pt
1
4′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

4′-2X
Pt
1
4′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

4′-2Y
Pt
0
4′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

4′-3
Pt
1
4′
Ph
H
F
H
F
CH₃
H
H
H
H
pic

4′-3X
Pt
1
4′
Ph
H
F
H
F
CH₃
H
H
H
H
acac

4′-3Y
Pt
0
4′
Ph
H
F
H
F
CH₃
H
H
H
H
—
—

4′-4
Pt
1
4′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

4′-4X
Pt
1
4′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

4′-4Y
Pt
0
4′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

4′-5
Pt
1
4′
Ph
F
H
H
F
CH₃
H
H
H
H
pic

4′-5X
Pt
1
4′
Ph
F
H
H
F
CH₃
H
H
H
H
acac

4′-5Y
Pt
0
4′
Ph
F
H
H
F
CH₃
H
H
H
H
—
—

4′-6
Pt
1
4′
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
pic

4′-6X
Pt
1
4′
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
acac

4′-6Y
Pt
0
4′
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
—
—

4′-7
Pt
1
4′
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
pic

4′-7X
Pt
1
4′
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
acac

4′-7Y
Pt
0
4′
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
—
—

4′-8
Pt
1
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

4′-8X
Pt
1
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

4′-8Y
Pt
0
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4′-9
Pt
1
4′
Ph
F
F
CF₃
H
CH₃
H
H
H
H
pic

4′-9X
Pt
1
4′
Ph
F
F
CF₃
H
CH₃
H
H
H
H
acac

4′-9Y
Pt
0
4′
Ph
F
F
CF₃
H
CH₃
H
H
H
H
—
—

4′-10
Pt
1
4′
Ph
F
H
CF₃
H
CH₃
H
H
H
H
pic

4′-10X
Pt
1
4′
Ph
F
H
CF₃
H
CH₃
H
H
H
H
acac

4′-10Y
Pt
0
4′
Ph
F
H
CF₃
H
CH₃
H
H
H
H
—
—

4′-11
Pt
1
4′
Ph
H
F
F
F
CH₃
H
H
H
H
pic

4′-11X
Pt
1
4′
Ph
H
F
F
F
CH₃
H
H
H
H
acac

4′-11Y
Pt
0
4′
Ph
H
F
F
F
CH₃
H
H
H
H
—
—

4′-12
Pt
1
4′
Ph
H
F
H
CH₃
CH₃
H
H
H
H
pic

4′-12X
Pt
1
4′
Ph
H
F
H
CH₃
CH₃
H
H
H
H
acac

4′-12Y
Pt
0
4′
Ph
H
F
H
CH₃
CH₃
H
H
H
H
—
—

4′-13
Pt
1
4′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
pic

4′-13X
Pt
1
4′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
acac

4′-13Y
Pt
0
4′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
—
—

4′-14
Pt
1
4′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-14X
Pt
1
4′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-14Y
Pt
0
4′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-15
Pt
1
4′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-15X
Pt
1
4′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-15Y
Pt
0
4′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-16
Pt
1
4′
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
pic

4′-16X
Pt
1
4′
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
acac

4′-16Y
Pt
0
4′
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
—
—

4′-17
Pt
1
4′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

4′-17X
Pt
1
4′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

4′-17Y
Pt
0
4′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

4′-18
Pt
1
4′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-18X
Pt
1
4′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-18Y
Pt
0
4′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-19
Pt
1
4′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-19X
Pt
1
4′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-19Y
Pt
0
4′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-20
Pt
1
4′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-20X
Pt
1
4′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-20Y
Pt
0
4′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-21
Pt
1
4′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-21X
Pt
1
4′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-21Y
Pt
0
4′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-22
Pt
1
4′
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
pic

4′-22X
Pt
1
4′
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
acac

4′-22Y
Pt
0
4′
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
—
—

4′-23
Pt
1
4′
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
pic

4′-23X
Pt
1
4′
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
acac

4′-23Y
Pt
0
4′
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
—
—

4′-24
Pt
1
4′
Ph
H
H
NO₂
H
CH₃
H
H
H
H
pic

4′-24X
Pt
1
4′
Ph
H
H
NO₂
H
CH₃
H
H
H
H
acac

4′-24Y
Pt
0
4′
Ph
H
H
NO₂
H
CH₃
H
H
H
H
—
—

4′-25
Pt
1
4′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
pic

4′-25X
Pt
1
4′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
acac

4′-25Y
Pt
0
4′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
—
—

4′-26
Pt
1
4′
Ph
F
H
NO₂
H
CH₃
H
H
H
H
pic

4′-26X
Pt
1
4′
Ph
F
H
NO₂
H
CH₃
H
H
H
H
acac

4′-26Y
Pt
0
4′
Ph
F
H
NO₂
H
CH₃
H
H
H
H
—
—

4′-27
Pt
1
4′
Ph
F
H
NO₂
F
CH₃
H
H
H
H
pic

4′-27X
Pt
1
4′
Ph
F
H
NO₂
F
CH₃
H
H
H
H
acac

4′-27Y
Pt
0
4′
Ph
F
H
NO₂
F
CH₃
H
H
H
H
—
—

4′-28
Pt
1
4′
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
pic

4′-28X
Pt
1
4′
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
acac

4′-28Y
Pt
0
4′
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
—
—

4′-29
Pt
1
4′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
pic

4′-29X
Pt
1
4′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
acac

4′-29Y
Pt
0
4′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
—
—

4′-30
Pt
1
4′
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
pic

4′-30X
Pt
1
4′
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
acac

4′-30Y
Pt
0
4′
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
—
—

4′-31
Pt
1
4′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
pic

4′-31X
Pt
1
4′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
acac

4′-31Y
Pt
0
4′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
—
—

4′-32
Pt
1
4′
Ph
H
H
CF₃
H
CH₃
H
H
H
H
pic

4′-32X
Pt
1
4′
Ph
H
H
CF₃
H
CH₃
H
H
H
H
acac

4′-32Y
Pt
0
4′
Ph
H
H
CF₃
H
CH₃
H
H
H
H
—
—

4′-33
Pt
1
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

4′-33X
Pt
1
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

4′-33Y
Pt
0
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4′-34
Pt
1
4′
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
pic

4′-34X
Pt
1
4′
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
acac

4′-34Y
Pt
0
4′
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
—
—

4′-35
Pt
1
4′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
pic

4′-35X
Pt
1
4′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
acac

4′-35Y
Pt
0
4′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4′-36
Pt
1
4′
Ph
H
NO₂
H
H
CH₃
H
H
H
H
pic

4′-36X
Pt
1
4′
Ph
H
NO₂
H
H
CH₃
H
H
H
H
acac

4′-36Y
Pt
0
4′
Ph
H
NO₂
H
H
CH₃
H
H
H
H
—
—

4′-37
Pt
1
4′
Ph
H
CF₃
H
H
CH₃
H
H
H
H
pic

4′-37X
Pt
1
4′
Ph
H
CF₃
H
H
CH₃
H
H
H
H
acac

4′-37Y
Pt
0
4′
Ph
H
CF₃
H
H
CH₃
H
H
H
H
—
—

4′-38
Pt
1
4′
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
pic

4′-38X
Pt
1
4′
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
acac

4′-38Y
Pt
0
4′
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
—
—

4′-39
Pt
1
4′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
pic

4′-39X
Pt
1
4′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
acac

4′-39Y
Pt
0
4′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
—
—

4′-40
Pt
1
4′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-40X
Pt
1
4′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-40Y
Pt
0
4′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-41
Pt
1
4′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-41X
Pt
1
4′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-41Y
Pt
0
4′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-42
Pt
1
4′
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
pic

4′-42X
Pt
1
4′
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
acac

4′-42Y
Pt
0
4′
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
—
—

4′-43
Pt
1
4′
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
pic

4′-43X
Pt
1
4′
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
acac

4′-43Y
Pt
0
4′
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
—
—

4′-44
Pt
1
4′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
pic

4′-44X
Pt
1
4′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
acac

4′-44Y
Pt
0
4′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
—
—

4′-45
Pt
1
4′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-45X
Pt
1
4′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-45Y
Pt
0
4′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-46
Pt
1
4′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
pic

4′-46X
Pt
1
4′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
acac

4′-46Y
Pt
0
4′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
—
—

4′-47
Pt
1
4′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
pic

4′-47X
Pt
1
4′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
acac

4′-47Y
Pt
0
4′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
—
—

4′-48
Pt
1
4′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4′-48X
Pt
1
4′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4′-48Y
Pt
0
4′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4′-49
Pt
1
4′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4′-49X
Pt
1
4′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4′-49Y
Pt
0
4′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4′-50
Pt
1
4′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4′-50X
Pt
1
4′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4′-50Y
Pt
0
4′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4′-51
Pt
1
4′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4′-51X
Pt
1
4′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4′-51Y
Pt
0
4′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4′-52
Pt
1
4′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
H
H
pic

4′-52X
Pt
1
4′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
H
H
acac

4′-52Y
Pt
0
4′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
H
H
—
—

4′-53
Pt
1
4′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
pic

4′-53X
Pt
1
4′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
acac

4′-53Y
Pt
0
4′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
—
—

4′-54
Pt
1
4′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
pic

4′-54X
Pt
1
4′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
acac

4′-54Y
Pt
0
4′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
—
—

4′-55
Pt
1
4′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
pic

4′-55X
Pt
1
4′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
acac

4′-55Y
Pt
0
4′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
—
—

4′-56
Pt
1
4′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

4′-56X
Pt
1
4′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

4′-56Y
Pt
0
4′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

4′-57
Pt
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4′-57X
Pt
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4′-57Y
Pt
0
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4′-58
Pt
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
pic

4′-58X
Pt
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
acac

4′-58Y
Pt
0
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
—
—

4′-59
Pt
1
4′
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
pic

4′-59X
Pt
1
4′
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
acac

4′-59Y
Pt
0
4′
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
—
—

4′-60
Pt
1
4′
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
pic

4′-60X
Pt
1
4′
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
acac

4′-60Y
Pt
0
4′
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
—
—

4′-61
Pt
1
4′
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
pic

4′-61X
Pt
1
4′
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
acac

4′-61Y
Pt
0
4′
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
—
—

4′-62
Pt
1
4′
Ph
H
H
BL
CH₃
H
H
H
H
pic

4′-62X
Pt
1
4′
Ph
H
H
BL
CH₃
H
H
H
H
acac

4′-62Y
Pt
0
4′
Ph
H
H
BL
CH₃
H
H
H
H
—
—

4′-63
Pt
1
4′
Ph
H
H
BL

^tC₄H₉
H
H
H
H
pic

4′-63X
Pt
1
4′
Ph
H
H
BL

^tC₄H₉
H
H
H
H
acac

4′-63Y
Pt
0
4′
Ph
H
H
BL

^tC₄H₉
H
H
H
H
—
—

4′-64
Pt
1
4′
Ph
H
BL
H
CH₃
H
H
H
H
pic

4′-64X
Pt
1
4′
Ph
H
BL
H
CH₃
H
H
H
H
acac

4′-64Y
Pt
0
4′
Ph
H
BL
H
CH₃
H
H
H
H
—
—

4′-65
Pt
1
4′
Ph
H
BL
H

^tC₄H₉
H
H
H
H
pic

4′-65X
Pt
1
4′
Ph
H
BL
H

^tC₄H₉
H
H
H
H
acac

4′-65Y
Pt
0
4′
Ph
H
BL
H

^tC₄H₉
H
H
H
H
—
—

4′-66
Pt
1
4′
Ph
H
H
PL
CH₃
H
H
H
H
pic

4′-66X
Pt
1
4′
Ph
H
H
PL
CH₃
H
H
H
H
acac

4′-66Y
Pt
0
4′
Ph
H
H
PL
CH₃
H
H
H
H
—
—

4′-67
Pt
1
4′
Ph
H
H
PL

^tC₄H₉
H
H
H
H
pic

4′-67X
Pt
1
4′
Ph
H
H
PL

^tC₄H₉
H
H
H
H
acac

4′-67Y
Pt
0
4′
Ph
H
H
PL

^tC₄H₉
H
H
H
H
—
—

4′-68
Pt
1
4′
Ph
H
PL
H
CH₃
H
H
H
H
pic

4′-68X
Pt
1
4′
Ph
H
PL
H
CH₃
H
H
H
H
acac

4′-68Y
Pt
0
4′
Ph
H
PL
H
CH₃
H
H
H
H
—
—

4′-69
Pt
1
4′
Ph
H
PL
H

^tC₄H₉
H
H
H
H
pic

4′-69X
Pt
1
4′
Ph
H
PL
H

^tC₄H₉
H
H
H
H
acac

4′-69Y
Pt
0
4′
Ph
H
PL
H

^tC₄H₉
H
H
H
H
—
—

4′-70
Pt
1
4′
Ph
H
H
MEE1
CH₃
H
H
H
H
pic

4′-70X
Pt
1
4′
Ph
H
H
MEE1
CH₃
H
H
H
H
acac

4′-70Y
Pt
0
4′
Ph
H
H
MEE1
CH₃
H
H
H
H
—
—

4′-71
Pt
1
4′
Ph
H
MEE1
H
CH₃
H
H
H
H
pic

4′-71X
Pt
1
4′
Ph
H
MEE1
H
CH₃
H
H
H
H
acac

4′-71Y
Pt
0
4′
Ph
H
MEE1
H
CH₃
H
H
H
H
—
—

4′-72
Pt
1
4′
Ph
H
H
MEE2
CH₃
H
H
H
H
pic

4′-72X
Pt
1
4′
Ph
H
H
MEE2
CH₃
H
H
H
H
acac

4′-72Y
Pt
0
4′
Ph
H
H
MEE2
CH₃
H
H
H
H
—
—

4′-73
Pt
1
4′
Ph
H
MEE2
H
CH₃
H
H
H
H
pic

4′-73X
Pt
1
4′
Ph
H
MEE2
H
CH₃
H
H
H
H
acac

4′-73Y
Pt
0
4′
Ph
H
MEE2
H
CH₃
H
H
H
H
—
—

4′-74
Pt
1
4′
Ph
H
H
PA1
CH₃
H
H
H
H
pic

4′-74X
Pt
1
4′
Ph
H
H
PA1
CH₃
H
H
H
H
acac

4′-74Y
Pt
0
4′
Ph
H
H
PA1
CH₃
H
H
H
H
—
—

4′-75
Pt
1
4′
Ph
H
PA1
H
CH₃
H
H
H
H
pic

4′-75X
Pt
1
4′
Ph
H
PA1
H
CH₃
H
H
H
H
acac

4′-75Y
Pt
0
4′
Ph
H
PA1
H
CH₃
H
H
H
H
—
—

4′-76
Pt
1
4′
Ph
H
H
PA2
CH₃
H
H
H
H
pic

4′-76X
Pt
1
4′
Ph
H
H
PA2
CH₃
H
H
H
H
acac

4′-76Y
Pt
0
4′
Ph
H
H
PA2
CH₃
H
H
H
H
—
—

4′-77
Pt
1
4′
Ph
H
PA2
H
CH₃
H
H
H
H
pic

4′-77X
Pt
1
4′
Ph
H
PA2
H
CH₃
H
H
H
H
acac

4′-77Y
Pt
0
4′
Ph
H
PA2
H
CH₃
H
H
H
H
—
—

4′-78
Pt
1
4′
Ph
H
H
EA1
CH₃
H
H
H
H
pic

4′-78X
Pt
1
4′
Ph
H
H
EA1
CH₃
H
H
H
H
acac

4′-78Y
Pt
0
4′
Ph
H
H
EA1
CH₃
H
H
H
H
—
—

4′-79
Pt
1
4′
Ph
H
EA2
H
CH₃
H
H
H
H
pic

4′-79X
Pt
1
4′
Ph
H
EA2
H
CH₃
H
H
H
H
acac

4′-79Y
Pt
0
4′
Ph
H
EA2
H
CH₃
H
H
H
H
—
—

4′-80
Pt
1
4′
Ph
H
H
ME
CH₃
H
H
H
H
pic

4′-80X
Pt
1
4′
Ph
H
H
ME
CH₃
H
H
H
H
acac

4′-80Y
Pt
0
4′
Ph
H
H
ME
CH₃
H
H
H
H
—
—

4′-81
Pt
1
4′
Ph
H
ME
H
CH₃
H
H
H
H
pic

4′-81X
Pt
1
4′
Ph
H
ME
H
CH₃
H
H
H
H
acac

4′-81Y
Pt
0
4′
Ph
H
ME
H
CH₃
H
H
H
H
—
—

4′-82
Pt
1
4′
Ph
H
H
AT
CH₃
H
H
H
H
pic

4′-82X
Pt
1
4′
Ph
H
H
AT
CH₃
H
H
H
H
acac

4′-82Y
Pt
0
4′
Ph
H
H
AT
CH₃
H
H
H
H
—
—

4′-83
Pt
1
4′
Ph
H
AT
H
CH₃
H
H
H
H
pic

4′-83X
Pt
1
4′
Ph
H
AT
H
CH₃
H
H
H
H
acac

4′-83Y
Pt
0
4′
Ph
H
AT
H
CH₃
H
H
H
H
—
—

4′-84
Pt
1
4′
Ph
H
H
MES1
CH₃
H
H
H
H
pic

4′-84X
Pt
1
4′
Ph
H
H
MES1
CH₃
H
H
H
H
acac

4′-84Y
Pt
0
4′
Ph
H
H
MES1
CH₃
H
H
H
H
—
—

4′-85
Pt
1
4′
Ph
H
MES1
H
CH₃
H
H
H
H
pic

4′-85X
Pt
1
4′
Ph
H
MES1
H
CH₃
H
H
H
H
acac

4′-85Y
Pt
0
4′
Ph
H
MES1
H
CH₃
H
H
H
H
—
—

4′-86
Pt
1
4′
Ph
H
H
MES2
CH₃
H
H
H
H
pic

4′-86X
Pt
1
4′
Ph
H
H
MES2
CH₃
H
H
H
H
acac

4′-86Y
Pt
0
4′
Ph
H
H
MES2
CH₃
H
H
H
H
—
—

4′-87
Pt
1
4′
Ph
H
MES2
H
CH₃
H
H
H
H
pic

4′-87X
Pt
1
4′
Ph
H
MES2
H
CH₃
H
H
H
H
acac

4′-87Y
Pt
0
4′
Ph
H
MES2
H
CH₃
H
H
H
H
—
—

4′-88
Pt
1
4′
Ph
H
H
PS1
CH₃
H
H
H
H
pic

4′-88X
Pt
1
4′
Ph
H
H
PS1
CH₃
H
H
H
H
acac

4′-88Y
Pt
0
4′
Ph
H
H
PS1
CH₃
H
H
H
H
—
—

4′-89
Pt
1
4′
Ph
H
PS1
H
CH₃
H
H
H
H
pic

4′-89X
Pt
1
4′
Ph
H
PS1
H
CH₃
H
H
H
H
acac

4′-89Y
Pt
0
4′
Ph
H
PS1
H
CH₃
H
H
H
H
—
—

4′-90
Pt
1
4′
Ph
H
H
PS2
CH₃
H
H
H
H
pic

4′-90X
Pt
1
4′
Ph
H
H
PS2
CH₃
H
H
H
H
acac

4′-90Y
Pt
0
4′
Ph
H
H
PS2
CH₃
H
H
H
H
—
—

4′-91
Pt
1
4′
Ph
H
PS2
H
CH₃
H
H
H
H
pic

4′-91X
Pt
1
4′
Ph
H
PS2
H
CH₃
H
H
H
H
acac

4′-91Y
Pt
0
4′
Ph
H
PS2
H
CH₃
H
H
H
H
—
—

4′-92
Pt
1
4′
Ph
H
H
BAL1
CH₃
H
H
H
H
pic

4′-92X
Pt
1
4′
Ph
H
H
BAL1
CH₃
H
H
H
H
acac

4′-92Y
Pt
0
4′
Ph
H
H
BAL1
CH₃
H
H
H
H
—
—

4′-93
Pt
1
4′
Ph
H
BAL1
H
CH₃
H
H
H
H
pic

4′-93X
Pt
1
4′
Ph
H
BAL1
H
CH₃
H
H
H
H
acac

4′-93Y
Pt
0
4′
Ph
H
BAL1
H
CH₃
H
H
H
H
—
—

4′-94
Pt
1
4′
Ph
H
H
BAL2
CH₃
H
H
H
H
pic

4′-94X
Pt
1
4′
Ph
H
H
BAL2
CH₃
H
H
H
H
acac

4′-94Y
Pt
0
4′
Ph
H
H
BAL2
CH₃
H
H
H
H
—
—

4′-95
Pt
1
4′
Ph
H
BAL2
H
CH₃
H
H
H
H
pic

4′-95X
Pt
1
4′
Ph
H
BAL2
H
CH₃
H
H
H
H
acac

4′-95Y
Pt
0
4′
Ph
H
BAL2
H
CH₃
H
H
H
H
—
—

4′-96
Pt
1
4′
Ph
H
H
MEK1
CH₃
H
H
H
H
pic

4′-96X
Pt
1
4′
Ph
H
H
MEK1
CH₃
H
H
H
H
acac

4′-96Y
Pt
0
4′
Ph
H
H
MEK1
CH₃
H
H
H
H
—
—

4′-97
Pt
1
4′
Ph
H
MEK1
H
CH₃
H
H
H
H
pic

4′-97X
Pt
1
4′
Ph
H
MEK1
H
CH₃
H
H
H
H
acac

4′-97Y
Pt
0
4′
Ph
H
MEK1
H
CH₃
H
H
H
H
—
—

4′-98
Pt
1
4′
Ph
H
H
MEK2
CH₃
H
H
H
H
pic

4′-98X
Pt
1
4′
Ph
H
H
MEK2
CH₃
H
H
H
H
acac

4′-98Y
Pt
0
4′
Ph
H
H
MEK2
CH₃
H
H
H
H
—
—

4′-99
Pt
1
4′
Ph
H
MEK2
H
CH₃
H
H
H
H
pic

4′-99X
Pt
1
4′
Ph
H
MEK2
H
CH₃
H
H
H
H
acac

4′-99Y
Pt
0
4′
Ph
H
MEK2
H
CH₃
H
H
H
H
—
—

4′-100
Pt
1
4′
Ph
H
H
PAL1
CH₃
H
H
H
H
pic

4′-100X
Pt
1
4′
Ph
H
H
PAL1
CH₃
H
H
H
H
acac

4′-100Y
Pt
0
4′
Ph
H
H
PAL1
CH₃
H
H
H
H
—
—

4′-101
Pt
1
4′
Ph
H
PAL1
H
CH₃
H
H
H
H
pic

4′-101X
Pt
1
4′
Ph
H
PAL1
H
CH₃
H
H
H
H
acac

4′-101Y
Pt
0
4′
Ph
H
PAL1
H
CH₃
H
H
H
H
—
—

4′-102
Pt
1
4′
Ph
H
H
PAL2
CH₃
H
H
H
H
pic

4′-102X
Pt
1
4′
Ph
H
H
PAL2
CH₃
H
H
H
H
acac

4′-102Y
Pt
0
4′
Ph
H
H
PAL2
CH₃
H
H
H
H
—
—

4′-103
Pt
1
4′
Ph
H
PAL2
H
CH₃
H
H
H
H
pic

4′-103X
Pt
1
4′
Ph
H
PAL2
H
CH₃
H
H
H
H
acac

4′-103Y
Pt
0
4′
Ph
H
PAL2
H
CH₃
H
H
H
H
—
—

4′-104
Pt
1
4′
Ph
H
H
MMK
CH₃
H
H
H
H
pic

4′-104X
Pt
1
4′
Ph
H
H
MMK
CH₃
H
H
H
H
acac

4′-104Y
Pt
0
4′
Ph
H
H
MMK
CH₃
H
H
H
H
—
—

4′-105
Pt
1
4′
Ph
H
MMK
H
CH₃
H
H
H
H
pic

4′-105X
Pt
1
4′
Ph
H
MMK
H
CH₃
H
H
H
H
acac

4′-105Y
Pt
0
4′
Ph
H
MMK
H
CH₃
H
H
H
H
—
—

4′-106
Pt
1
4′
Ph
H
H
EES1
CH₃
H
H
H
H
pic

4′-106X
Pt
1
4′
Ph
H
H
EES1
CH₃
H
H
H
H
acac

4′-106Y
Pt
0
4′
Ph
H
H
EES1
CH₃
H
H
H
H
—
—

4′-107
Pt
1
4′
Ph
H
EES2
H
CH₃
H
H
H
H
pic

4′-107X
Pt
1
4′
Ph
H
EES2
H
CH₃
H
H
H
H
acac

4′-107Y
Pt
0
4′
Ph
H
EES2
H
CH₃
H
H
H
H
—
—

4′-108
Pt
1
4′
Ph
H
H
PAE1
CH₃
H
H
H
H
pic

4′-108X
Pt
1
4′
Ph
H
H
PAE1
CH₃
H
H
H
H
acac

4′-108Y
Pt
0
4′
Ph
H
H
PAE1
CH₃
H
H
H
H
—
—

4′-109
Pt
1
4′
Ph
H
PAE2
H
CH₃
H
H
H
H
pic

4′-109X
Pt
1
4′
Ph
H
PAE2
H
CH₃
H
H
H
H
acac

4′-109Y
Pt
0
4′
Ph
H
PAE2
H
CH₃
H
H
H
H
—
—

4′-110
Pt
1
4′
Ph
H
H
AME1
CH₃
H
H
H
H
pic

4′-110X
Pt
1
4′
Ph
H
H
AME1
CH₃
H
H
H
H
acac

4′-110Y
Pt
0
4′
Ph
H
H
AME1
CH₃
H
H
H
H
—
—

4′-111
Pt
1
4′
Ph
H
AME1
H
CH₃
H
H
H
H
pic

4′-111X
Pt
1
4′
Ph
H
AME1
H
CH₃
H
H
H
H
acac

4′-111Y
Pt
0
4′
Ph
H
AME1
H
CH₃
H
H
H
H
—
—

4′-112
Pt
1
4′
Ph
H
H
AME2
CH₃
H
H
H
H
pic

4′-112X
Pt
1
4′
Ph
H
H
AME2
CH₃
H
H
H
H
acac

4′-112Y
Pt
0
4′
Ph
H
H
AME2
CH₃
H
H
H
H
—
—

4′-113
Pt
1
4′
Ph
H
AME2
H
CH₃
H
H
H
H
pic

4′-113X
Pt
1
4′
Ph
H
AME2
H
CH₃
H
H
H
H
acac

4′-113Y
Pt
0
4′
Ph
H
AME2
H
CH₃
H
H
H
H
—
—

4′-114
Pt
1
4′
Ph
H
H
EAE1
CH₃
H
H
H
H
pic

4′-114X
Pt
1
4′
Ph
H
H
EAE1
CH₃
H
H
H
H
acac

4′-114Y
Pt
0
4′
Ph
H
H
EAE1
CH₃
H
H
H
H
—
—

4′-115
Pt
1
4′
Ph
H
EAE1
H
CH₃
H
H
H
H
pic

4′-115X
Pt
1
4′
Ph
H
EAE1
H
CH₃
H
H
H
H
acac

4′-115Y
Pt
0
4′
Ph
H
EAE1
H
CH₃
H
H
H
H
—
—

4′-116
Pt
1
4′
Ph
H
H
EAE2
CH₃
H
H
H
H
pic

4′-116X
Pt
1
4′
Ph
H
H
EAE2
CH₃
H
H
H
H
acac

4′-116Y
Pt
0
4′
Ph
H
H
EAE2
CH₃
H
H
H
H
—
—

4′-117
Pt
1
4′
Ph
H
EAE2
H
CH₃
H
H
H
H
pic

4′-117X
Pt
1
4′
Ph
H
EAE2
H
CH₃
H
H
H
H
acac

4′-117Y
Pt
0
4′
Ph
H
EAE2
H
CH₃
H
H
H
H
—
—

4′-118
Pt
1
4′
Ph
H
H
AAE1
CH₃
H
H
H
H
pic

4′-118X
Pt
1
4′
Ph
H
H
AAE1
CH₃
H
H
H
H
acac

4′-118Y
Pt
0
4′
Ph
H
H
AAE1
CH₃
H
H
H
H
—
—

4′-119
Pt
1
4′
Ph
H
AAE1
H
CH₃
H
H
H
H
pic

4′-119X
Pt
1
4′
Ph
H
AAE1
H
CH₃
H
H
H
H
acac

4′-119Y
Pt
0
4′
Ph
H
AAE1
H
CH₃
H
H
H
H
—
—

4′-120
Pt
1
4′
Ph
H
H
AAE2
CH₃
H
H
H
H
pic

4′-120X
Pt
1
4′
Ph
H
H
AAE2
CH₃
H
H
H
H
acac

4′-120Y
Pt
0
4′
Ph
H
H
AAE2
CH₃
H
H
H
H
—
—

4′-121
Pt
1
4′
Ph
H
AAE2
H
CH₃
H
H
H
H
pic

4′-121X
Pt
1
4′
Ph
H
AAE2
H
CH₃
H
H
H
H
acac

4′-121Y
Pt
0
4′
Ph
H
AAE2
H
CH₃
H
H
H
H
—
—

4′-122
Pt
1
4′
Ph
H
H
PME1
CH₃
H
H
H
H
pic

4′-122X
Pt
1
4′
Ph
H
H
PME1
CH₃
H
H
H
H
acac

4′-122Y
Pt
0
4′
Ph
H
H
PME1
CH₃
H
H
H
H
—
—

4′-123
Pt
1
4′
Ph
H
PME1
H
CH₃
H
H
H
H
pic

4′-123X
Pt
1
4′
Ph
H
PME1
H
CH₃
H
H
H
H
acac

4′-123Y
Pt
0
4′
Ph
H
PME1
H
CH₃
H
H
H
H
—
—

4′-124
Pt
1
4′
Ph
H
H
PME2
CH₃
H
H
H
H
pic

4′-124X
Pt
1
4′
Ph
H
H
PME2
CH₃
H
H
H
H
acac

4′-124Y
Pt
0
4′
Ph
H
H
PME2
CH₃
H
H
H
H
—
—

4′-125
Pt
1
4′
Ph
H
PME2
H
CH₃
H
H
H
H
pic

4′-125X
Pt
1
4′
Ph
H
PME2
H
CH₃
H
H
H
H
acac

4′-125Y
Pt
0
4′
Ph
H
PME2
H
CH₃
H
H
H
H
—
—

4′-126
Pt
1
4′
Ph
H
H
MET1
CH₃
H
H
H
H
pic

4′-126X
Pt
1
4′
Ph
H
H
MET1
CH₃
H
H
H
H
acac

4′-126Y
Pt
0
4′
Ph
H
H
MET1
CH₃
H
H
H
H
—
—

4′-127
Pt
1
4′
Ph
H
MET1
H
CH₃
H
H
H
H
pic

4′-127X
Pt
1
4′
Ph
H
MET1
H
CH₃
H
H
H
H
acac

4′-127Y
Pt
0
4′
Ph
H
MET1
H
CH₃
H
H
H
H
—
—

4′-128
Pt
1
4′
Ph
H
H
MET2
CH₃
H
H
H
H
pic

4′-128X
Pt
1
4′
Ph
H
H
MET2
CH₃
H
H
H
H
acac

4′-128Y
Pt
0
4′
Ph
H
H
MET2
CH₃
H
H
H
H
—
—

4′-129
Pt
1
4′
Ph
H
MET2
H
CH₃
H
H
H
H
pic

4′-129X
Pt
1
4′
Ph
H
MET2
H
CH₃
H
H
H
H
acac

4′-129Y
Pt
0
4′
Ph
H
MET2
H
CH₃
H
H
H
H
—
—

4′-130
Pt
1
4′
Ph
H
H
EE1
CH₃
H
H
H
H
pic

4′-130X
Pt
1
4′
Ph
H
H
EE1
CH₃
H
H
H
H
acac

4′-130Y
Pt
0
4′
Ph
H
H
EE1
CH₃
H
H
H
H
—
—

4′-131
Pt
1
4′
Ph
H
EE1
H
CH₃
H
H
H
H
pic

4′-131X
Pt
1
4′
Ph
H
EE1
H
CH₃
H
H
H
H
acac

4′-131Y
Pt
0
4′
Ph
H
EE1
H
CH₃
H
H
H
H
—
—

4′-132
Pt
1
4′
Ph
H
H
EE2
CH₃
H
H
H
H
pic

4′-132X
Pt
1
4′
Ph
H
H
EE2
CH₃
H
H
H
H
acac

4′-132Y
Pt
0
4′
Ph
H
H
EE2
CH₃
H
H
H
H
—
—

4′-133
Pt
1
4′
Ph
H
EE2
H
CH₃
H
H
H
H
pic

4′-133X
Pt
1
4′
Ph
H
EE2
H
CH₃
H
H
H
H
acac

4′-133Y
Pt
0
4′
Ph
H
EE2
H
CH₃
H
H
H
H
—
—

4′-134
Pt
1
4′
Ph
H
H
MS1
CH₃
H
H
H
H
pic

4′-134X
Pt
1
4′
Ph
H
H
MS1
CH₃
H
H
H
H
acac

4′-134Y
Pt
0
4′
Ph
H
H
MS1
CH₃
H
H
H
H
—
—

4′-135
Pt
1
4′
Ph
H
MS1
H
CH₃
H
H
H
H
pic

4′-135X
Pt
1
4′
Ph
H
MS1
H
CH₃
H
H
H
H
acac

4′-135Y
Pt
0
4′
Ph
H
MS1
H
CH₃
H
H
H
H
—
—

4′-136
Pt
1
4′
Ph
H
H
MS2
CH₃
H
H
H
H
pic

4′-136X
Pt
1
4′
Ph
H
H
MS2
CH₃
H
H
H
H
acac

4′-136Y
Pt
0
4′
Ph
H
H
MS2
CH₃
H
H
H
H
—
—

4′-137
Pt
1
4′
Ph
H
MS2
H
CH₃
H
H
H
H
pic

4′-137X
Pt
1
4′
Ph
H
MS2
H
CH₃
H
H
H
H
acac

4′-137Y
Pt
0
4′
Ph
H
MS2
H
CH₃
H
H
H
H
—
—

TABLE 33

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹ L²

5′-1
Pt
1
5′
Ph
H
H
H
H
H
CH₃
H
pic

5′-1X
Pt
1
5′
Ph
H
H
H
H
H
CH₃
H
acac

5′-1Y
Pt
0
5′
Ph
H
H
H
H
H
CH₃
H
— —

5′-2
Pt
1
5′
Ph
H
H
H
H
H

^tC₄H₉
H
pic

5′-2X
Pt
1
5′
Ph
H
H
H
H
H

^tC₄H₉
H
acac

5′-2Y
Pt
0
5′
Ph
H
H
H
H
H

^tC₄H₉
H
— —

5′-3
Pt
1
5′
Ph
H
F
H
F
H
CH₃
H
pic

5′-3X
Pt
1
5′
Ph
H
F
H
F
H
CH₃
H
acac

5′-3Y
Pt
0
5′
Ph
H
F
H
F
H
CH₃
H
— —

5′-4
Pt
1
5′
Ph
H
F
H
F
H

^tC₄H₉
H
pic

5′-4X
Pt
1
5′
Ph
H
F
H
F
H

^tC₄H₉
H
acac

5′-4Y
Pt
0
5′
Ph
H
F
H
F
H

^tC₄H₉
H
— —

5′-5
Pt
1
5′
Ph
CF₃
H
CF₃
H
H
CH₃
H
pic

5′-5X
Pt
1
5′
Ph
CF₃
H
CF₃
H
H
CH₃
H
acac

5′-5Y
Pt
0
5′
Ph
CF₃
H
CF₃
H
H
CH₃
H
— —

5′-6
Pt
1
5′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
pic

5′-6X
Pt
1
5′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
acac

5′-6Y
Pt
0
5′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
— —

5′-7
Pt
1
5′
Ph
H
F
CF₃
H
H
CH₃
H
pic

5′-7X
Pt
1
5′
Ph
H
F
CF₃
H
H
CH₃
H
acac

5′-7Y
Pt
0
5′
Ph
H
F
CF₃
H
H
CH₃
H
— —

5′-8
Pt
1
5′
Ph
F
H
CF₃
H
H
CH₃
H
pic

5′-8X
Pt
1
5′
Ph
F
H
CF₃
H
H
CH₃
H
acac

5′-8Y
Pt
0
5′
Ph
F
H
CF₃
H
H
CH₃
H
— —

5′-9
Pt
1
5′
Ph
F
F
F
F
H
CH₃
H
pic

5′-9X
Pt
1
5′
Ph
F
F
F
F
H
CH₃
H
acac

5′-9Y
Pt
0
5′
Ph
F
F
F
F
H
CH₃
H
— —

5′-10
Pt
1
5′
Ph
H
F
H
CH₃
H
CH₃
H
pic

5′-10X
Pt
1
5′
Ph
H
F
H
CH₃
H
CH₃
H
acac

5′-10Y
Pt
0
5′
Ph
H
F
H
CH₃
H
CH₃
H
— —

5′-11
Pt
1
5′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
pic

5′-11X
Pt
1
5′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
acac

5′-11Y
Pt
0
5′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
— —

5′-12
Pt
1
5′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
pic

5′-12X
Pt
1
5′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
acac

5′-12Y
Pt
0
5′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
— —

5′-13
Pt
1
5′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-13X
Pt
1
5′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-13Y
Pt
0
5′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
— —

5′-14
Pt
1
5′
Ph
H
CF₃
H
CF₃
H
CH₃
H
pic

5′-14X
Pt
1
5′
Ph
H
CF₃
H
CF₃
H
CH₃
H
acac

5′-14Y
Pt
0
5′
Ph
H
CF₃
H
CF₃
H
CH₃
H
— —

5′-15
Pt
1
5′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
pic

5′-15X
Pt
1
5′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
acac

5′-15Y
Pt
0
5′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
— —

5′-16
Pt
1
5′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
pic

5′-16X
Pt
1
5′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
acac

5′-16Y
Pt
0
5′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
— —

5′-17
Pt
1
5′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-17X
Pt
1
5′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-17Y
Pt
0
5′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
— —

5′-18
Pt
1
5′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
pic

5′-18X
Pt
1
5′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
acac

5′-18Y
Pt
0
5′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
— —

5′-19
Pt
1
5′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-19X
Pt
1
5′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-19Y
Pt
0
5′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
— —

5′-20
Pt
1
5′
Ph
H
CF₃
H
CH₃
H
CH₃
H
pic

5′-20X
Pt
1
5′
Ph
H
CF₃
H
CH₃
H
CH₃
H
acac

5′-20Y
Pt
0
5′
Ph
H
CF₃
H
CH₃
H
CH₃
H
— —

5′-21
Pt
1
5′
Ph
H
CF₃
CF₃
H
H
CH₃
H
pic

5′-21X
Pt
1
5′
Ph
H
CF₃
CF₃
H
H
CH₃
H
acac

5′-21Y
Pt
0
5′
Ph
H
CF₃
CF₃
H
H
CH₃
H
— —

5′-22
Pt
1
5′
Ph
H
H
NO₂
H
H
CH₃
H
pic

5′-22X
Pt
1
5′
Ph
H
H
NO₂
H
H
CH₃
H
acac

5′-22Y
Pt
0
5′
Ph
H
H
NO₂
H
H
CH₃
H
— —

5′-23
Pt
1
5′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
pic

5′-23X
Pt
1
5′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
acac

5′-23Y
Pt
0
5′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
— —

5′-24
Pt
1
5′
Ph
F
H
NO₂
H
H
CH₃
H
pic

5′-24X
Pt
1
5′
Ph
F
H
NO₂
H
H
CH₃
H
acac

5′-24Y
Pt
0
5′
Ph
F
H
NO₂
H
H
CH₃
H
— —

5′-25
Pt
1
5′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
pic

5′-25X
Pt
1
5′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
acac

5′-25Y
Pt
0
5′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
— —

5′-26
Pt
1
5′
Ph
F
H
NO₂
F
H
CH₃
H
pic

5′-26X
Pt
1
5′
Ph
F
H
NO₂
F
H
CH₃
H
acac

5′-26Y
Pt
0
5′
Ph
F
H
NO₂
F
H
CH₃
H
— —

5′-27
Pt
1
5′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
pic

5′-27X
Pt
1
5′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
acac

5′-27Y
Pt
0
5′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
— —

5′-28
Pt
1
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
pic

5′-28X
Pt
1
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
acac

5′-28Y
Pt
0
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
— —

5′-29
Pt
1
5′
Ph
H
NO₂
H
NO₂
H

^tC₄H₉
H
pic

5′-29X
Pt
1
5′
Ph
H
NO₂
H
NO₂
H

^tC₄H₉
H
acac

5′-29Y
Pt
0
5′
Ph
H
NO₂
H
NO₂
H

^tC₄H₉
H
— —

5′-30
Pt
1
5′
Ph
NO₂
H
H
NO₂
H
CH₃
H
pic

5′-30X
Pt
1
5′
Ph
NO₂
H
H
NO₂
H
CH₃
H
acac

5′-30Y
Pt
0
5′
Ph
NO₂
H
H
NO₂
H
CH₃
H
— —

5′-31
Pt
1
5′
Ph
H
H
CF₃
H
H
CH₃
H
pic

5′-31X
Pt
1
5′
Ph
H
H
CF₃
H
H
CH₃
H
acac

5′-31Y
Pt
0
5′
Ph
H
H
CF₃
H
H
CH₃
H
— —

5′-32
Pt
1
5′
Ph
H
Cl
CF₃
H
H
CH₃
H
pic

5′-32X
Pt
1
5′
Ph
H
Cl
CF₃
H
H
CH₃
H
acac

5′-32Y
Pt
0
5′
Ph
H
Cl
CF₃
H
H
CH₃
H
— —

5′-33
Pt
1
5′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
pic

5′-33X
Pt
1
5′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
acac

5′-33Y
Pt
0
5′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
— —

5′-34
Pt
1
5′
Ph
H
NO₂
H
H
H
CH₃
H
pic

5′-34X
Pt
1
5′
Ph
H
NO₂
H
H
H
CH₃
H
acac

5′-34Y
Pt
0
5′
Ph
H
NO₂
H
H
H
CH₃
H
— —

5′-35
Pt
1
5′
Ph
H
CF₃
H
H
H
CH₃
H
pic

5′-35X
Pt
1
5′
Ph
H
CF₃
H
H
H
CH₃
H
acac

5′-35Y
Pt
0
5′
Ph
H
CF₃
H
H
H
CH₃
H
— —

5′-36
Pt
1
5′
Ph
H
NO₂
H
CH₃
H
CH₃
H
pic

5′-36X
Pt
1
5′
Ph
H
NO₂
H
CH₃
H
CH₃
H
acac

5′-36Y
Pt
0
5′
Ph
H
NO₂
H
CH₃
H
CH₃
H
— —

5′-37
Pt
1
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
pic

5′-37X
Pt
1
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
acac

5′-37Y
Pt
0
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
— —

5′-38
Pt
1
5′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
pic

5′-38X
Pt
1
5′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
acac

5′-38Y
Pt
0
5′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
— —

5′-39
Pt
1
5′
Ph
H
H
CH₃O
H
H
CH₃
H
pic

5′-39X
Pt
1
5′
Ph
H
H
CH₃O
H
H
CH₃
H
acac

5′-39Y
Pt
0
5′
Ph
H
H
CH₃O
H
H
CH₃
H
— —

5′-40
Pt
1
5′
Ph
H
CH₃O
H
H
H
CH₃
H
pic

5′-40X
Pt
1
5′
Ph
H
CH₃O
H
H
H
CH₃
H
acac

5′-40Y
Pt
0
5′
Ph
H
CH₃O
H
H
H
CH₃
H
— —

5′-41
Pt
1
5′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
pic

5′-41X
Pt
1
5′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
acac

5′-41Y
Pt
0
5′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
— —

5′-42
Pt
1
5′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
pic

5′-42X
Pt
1
5′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
acac

5′-42Y
Pt
0
5′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
— —

5′-43
Pt
1
5′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
pic

5′-43X
Pt
1
5′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
acac

5′-43Y
Pt
0
5′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
— —

5′-44
Pt
1
5′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
pic

5′-44X
Pt
1
5′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
acac

5′-44Y
Pt
0
5′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
— —

5′-45
Pt
1
5′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
pic

5′-45X
Pt
1
5′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
acac

5′-45Y
Pt
0
5′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
— —

5′-46
Pt
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
pic

5′-46X
Pt
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
acac

5′-46Y
Pt
0
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
— —

5′-47
Pt
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
pic

5′-47X
Pt
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
acac

5′-47Y
Pt
0
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
— —

5′-48
Pt
1
5′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
pic

5′-48X
Pt
1
5′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
acac

5′-48Y
Pt
0
5′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
— —

5′-49
Pt
1
5′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
pic

5′-49X
Pt
1
5′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
acac

5′-49Y
Pt
0
5′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
— —

5′-50
Pt
1
5′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
pic

5′-50X
Pt
1
5′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
acac

5′-50Y
Pt
0
5′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
— —

5′-51
Pt
1
5′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
pic

5′-51X
Pt
1
5′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
acac

5′-51Y
Pt
0
5′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
— —

5′-52
Pt
1
5′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
pic

5′-52X
Pt
1
5′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
acac

5′-52Y
Pt
0
5′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
— —

5′-53
Pt
1
5′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
pic

5′-53X
Pt
1
5′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
acac

5′-53Y
Pt
0
5′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
— —

5′-54
Pt
1
5′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
pic

5′-54X
Pt
1
5′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
acac

5′-54Y
Pt
0
5′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
— —

5′-55
Pt
1
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
pic

5′-55X
Pt
1
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
acac

5′-55Y
Pt
0
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
— —

5′-56
Pt
1
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
pic

5′-56X
Pt
1
5′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
acac

5′-56Y
Pt
0
5′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
— —

5′-57
Pt
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
pic

5′-57X
Pt
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
acac

5′-57Y
Pt
0
5′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
— —

5′-58
Pt
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
pic

5′-58X
Pt
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
acac

5′-58Y
Pt
0
5′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
— —

5′-59
Pt
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
pic

5′-59X
Pt
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
acac

5′-59Y
Pt
0
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
— —

5′-60
Pt
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
pic

5′-60X
Pt
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
acac

5′-60Y
Pt
0
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
— —

5′-61
Pt
1
5′
Ph
H
H
H
COCH₃
H

^tC₄H₉
H
pic

5′-61X
Pt
1
5′
Ph
H
H
H
COCH₃
H
CH₃
H
acac

5′-61Y
Pt
0
5′
Ph
H
H
H
COCH₃
H
CH₃
H
— —

5′-62
Pt
1
5′
Ph
H
H
COCH₃
H
H
CH₃
H
pic

5′-62X
Pt
1
5′
Ph
H
H
COCH₃
H
H
CH₃
H
acac

5′-62Y
Pt
0
5′
Ph
H
H
COCH₃
H
H
CH₃
H
— —

5′-63
Pt
1
5′
Ph
H
COCH₃
H
H
H
CH₃
H
pic

5′-63X
Pt
1
5′
Ph
H
COCH₃
H
H
H
CH₃
H
acac

5′-63Y
Pt
0
5′
Ph
H
COCH₃
H
H
H
CH₃
H
— —

5′-64
Pt
1
5′
Ph
H
H
BL
H
CH₃
H
pic

5′-64X
Pt
1
5′
Ph
H
H
BL
H
CH₃
H
acac

5′-64Y
Pt
0
5′
Ph
H
H
BL
H
CH₃
H
— —

5′-65
Pt
1
5′
Ph
H
H
BL
H

^tC₄H₉
H
pic

5′-65X
Pt
1
5′
Ph
H
H
BL
H

^tC₄H₉
H
acac

5′-65Y
Pt
0
5′
Ph
H
H
BL
H

^tC₄H₉
H
— —

5′-66
Pt
1
5′
Ph
H
BL
H
H
CH₃
H
pic

5′-66X
Pt
1
5′
Ph
H
BL
H
H
CH₃
H
acac

5′-66Y
Pt
0
5′
Ph
H
BL
H
H
CH₃
H
— —

5′-67
Pt
1
5′
Ph
H
BL
H
H

^tC₄H₉
H
pic

5′-67X
Pt
1
5′
Ph
H
BL
H
H

^tC₄H₉
H
acac

5′-67Y
Pt
0
5′
Ph
H
BL
H
H

^tC₄H₉
H
— —

5′-68
Pt
1
5′
Ph
H
H
PL
H
CH₃
H
pic

5′-68X
Pt
1
5′
Ph
H
H
PL
H
CH₃
H
acac

5′-68Y
Pt
0
5′
Ph
H
H
PL
H
CH₃
H
— —

5′-69
Pt
1
5′
Ph
H
H
PL
H

^tC₄H₉
H
pic

5′-69X
Pt
1
5′
Ph
H
H
PL
H

^tC₄H₉
H
acac

5′-69Y
Pt
0
5′
Ph
H
H
PL
H

^tC₄H₉
H
— —

5′-70
Pt
1
5′
Ph
H
PL
H
H
CH₃
H
pic

5′-70X
Pt
1
5′
Ph
H
PL
H
H
CH₃
H
acac

5′-70Y
Pt
0
5′
Ph
H
PL
H
H
CH₃
H
— —

5′-71
Pt
1
5′
Ph
H
PL
H
H

^tC₄H₉
H
pic

5′-71X
Pt
1
5′
Ph
H
PL
H
H

^tC₄H₉
H
acac

5′-71Y
Pt
0
5′
Ph
H
PL
H
H

^tC₄H₉
H
— —

5′-72
Pt
1
5′
Ph
H
H
MEE1
H
CH₃
H
pic

5′-72X
Pt
1
5′
Ph
H
H
MEE1
H
CH₃
H
acac

5′-72Y
Pt
0
5′
Ph
H
H
MEE1
H
CH₃
H
— —

5′-73
Pt
1
5′
Ph
H
MEE1
H
H
CH₃
H
pic

5′-73X
Pt
1
5′
Ph
H
MEE1
H
H
CH₃
H
acac

5′-73Y
Pt
0
5′
Ph
H
MEE1
H
H
CH₃
H
— —

5′-74
Pt
1
5′
Ph
H
H
MEE2
H
CH₃
H
pic

5′-74X
Pt
1
5′
Ph
H
H
MEE2
H
CH₃
H
acac

5′-74Y
Pt
0
5′
Ph
H
H
MEE2
H
CH₃
H
— —

5′-75
Pt
1
5′
Ph
H
MEE2
H
H
CH₃
H
pic

5′-75X
Pt
1
5′
Ph
H
MEE2
H
H
CH₃
H
acac

5′-75Y
Pt
0
5′
Ph
H
MEE2
H
H
CH₃
H
— —

5′-76
Pt
1
5′
Ph
H
H
PA1
H
CH₃
H
pic

5′-76X
Pt
1
5′
Ph
H
H
PA1
H
CH₃
H
acac

5′-76Y
Pt
0
5′
Ph
H
H
PA1
H
CH₃
H
— —

5′-77
Pt
1
5′
Ph
H
PA1
H
H
CH₃
H
pic

5′-77X
Pt
1
5′
Ph
H
PA1
H
H
CH₃
H
acac

5′-77Y
Pt
0
5′
Ph
H
PA1
H
H
CH₃
H
— —

5′-78
Pt
1
5′
Ph
H
H
PA2
H
CH₃
H
pic

5′-78X
Pt
1
5′
Ph
H
H
PA2
H
CH₃
H
acac

5′-78Y
Pt
0
5′
Ph
H
H
PA2
H
CH₃
H
— —

5′-79
Pt
1
5′
Ph
H
PA2
H
H
CH₃
H
pic

5′-79X
Pt
1
5′
Ph
H
PA2
H
H
CH₃
H
acac

5′-79Y
Pt
0
5′
Ph
H
PA2
H
H
CH₃
H
— —

5′-80
Pt
1
5′
Ph
H
H
EA1
H
CH₃
H
pic

5′-80X
Pt
1
5′
Ph
H
H
EA1
H
CH₃
H
acac

5′-80Y
Pt
0
5′
Ph
H
H
EA1
H
CH₃
H
— —

5′-81
Pt
1
5′
Ph
H
EA2
H
H
CH₃
H
pic

5′-81X
Pt
1
5′
Ph
H
EA2
H
H
CH₃
H
acac

5′-81Y
Pt
0
5′
Ph
H
EA2
H
H
CH₃
H
— —

5′-82
Pt
1
5′
Ph
H
H
ME
H
CH₃
H
pic

5′-82X
Pt
1
5′
Ph
H
H
ME
H
CH₃
H
acac

5′-82Y
Pt
0
5′
Ph
H
H
ME
H
CH₃
H
— —

5′-83
Pt
1
5′
Ph
H
ME
H
H
CH₃
H
pic

5′-83X
Pt
1
5′
Ph
H
ME
H
H
CH₃
H
acac

5′-83Y
Pt
0
5′
Ph
H
ME
H
H
CH₃
H
— —

5′-84
Pt
1
5′
Ph
H
H
AT
H
CH₃
H
pic

5′-84X
Pt
1
5′
Ph
H
H
AT
H
CH₃
H
acac

5′-84Y
Pt
0
5′
Ph
H
H
AT
H
CH₃
H
— —

5′-85
Pt
1
5′
Ph
H
AT
H
H
CH₃
H
pic

5′-85X
Pt
1
5′
Ph
H
AT
H
H
CH₃
H
acac

5′-85Y
Pt
0
5′
Ph
H
AT
H
H
CH₃
H
— —

5′-86
Pt
1
5′
Ph
H
H
MES1
H
CH₃
H
pic

5′-86X
Pt
1
5′
Ph
H
H
MES1
H
CH₃
H
acac

5′-86Y
Pt
0
5′
Ph
H
H
MES1
H
CH₃
H
— —

5′-87
Pt
1
5′
Ph
H
MES1
H
H
CH₃
H
pic

5′-87X
Pt
1
5′
Ph
H
MES1
H
H
CH₃
H
acac

5′-87Y
Pt
0
5′
Ph
H
MES1
H
H
CH₃
H
— —

5′-88
Pt
1
5′
Ph
H
H
MES2
H
CH₃
H
pic

5′-88X
Pt
1
5′
Ph
H
H
MES2
H
CH₃
H
acac

5′-88Y
Pt
0
5′
Ph
H
H
MES2
H
CH₃
H
— —

5′-89
Pt
1
5′
Ph
H
MES2
H
H
CH₃
H
pic

5′-89X
Pt
1
5′
Ph
H
MES2
H
H
CH₃
H
acac

5′-89Y
Pt
0
5′
Ph
H
MES2
H
H
CH₃
H
— —

5′-90
Pt
1
5′
Ph
H
H
PS1
H
CH₃
H
pic

5′-90X
Pt
1
5′
Ph
H
H
PS1
H
CH₃
H
acac

5′-90Y
Pt
0
5′
Ph
H
H
PS1
H
CH₃
H
— —

5′-91
Pt
1
5′
Ph
H
PS1
H
H
CH₃
H
pic

5′-91X
Pt
1
5′
Ph
H
PS1
H
H
CH₃
H
acac

5′-91Y
Pt
0
5′
Ph
H
PS1
H
H
CH₃
H
— —

5′-92
Pt
1
5′
Ph
H
H
PS2
H
CH₃
H
pic

5′-92X
Pt
1
5′
Ph
H
H
PS2
H
CH₃
H
acac

5′-92Y
Pt
0
5′
Ph
H
H
PS2
H
CH₃
H
— —

5′-93
Pt
1
5′
Ph
H
PS2
H
H
CH₃
H
pic

5′-93X
Pt
1
5′
Ph
H
PS2
H
H
CH₃
H
acac

5′-93Y
Pt
0
5′
Ph
H
PS2
H
H
CH₃
H
— —

5′-94
Pt
1
5′
Ph
H
H
BAL1
H
CH₃
H
pic

5′-94X
Pt
1
5′
Ph
H
H
BAL1
H
CH₃
H
acac

5′-94Y
Pt
0
5′
Ph
H
H
BAL1
H
CH₃
H
— —

5′-95
Pt
1
5′
Ph
H
BAL1
H
H
CH₃
H
pic

5′-95X
Pt
1
5′
Ph
H
BAL1
H
H
CH₃
H
acac

5′-95Y
Pt
0
5′
Ph
H
BAL1
H
H
CH₃
H
— —

5′-96
Pt
1
5′
Ph
H
H
BAL2
H
CH₃
H
pic

5′-96X
Pt
1
5′
Ph
H
H
BAL2
H
CH₃
H
acac

5′-96Y
Pt
0
5′
Ph
H
H
BAL2
H
CH₃
H
— —

5′-97
Pt
1
5′
Ph
H
BAL2
H
H
CH₃
H
pic

5′-97X
Pt
1
5′
Ph
H
BAL2
H
H
CH₃
H
acac

5′-97Y
Pt
0
5′
Ph
H
BAL2
H
H
CH₃
H
— —

5′-98
Pt
1
5′
Ph
H
H
MEK1
H
CH₃
H
pic

5′-98X
Pt
1
5′
Ph
H
H
MEK1
H
CH₃
H
acac

5′-98Y
Pt
0
5′
Ph
H
H
MEK1
H
CH₃
H
— —

5′-99
Pt
1
5′
Ph
H
MEK1
H
H
CH₃
H
pic

5′-99X
Pt
1
5′
Ph
H
MEK1
H
H
CH₃
H
acac

5′-99Y
Pt
0
5′
Ph
H
MEK1
H
H
CH₃
H
— —

5′-100
Pt
1
5′
Ph
H
H
MEK2
H
CH₃
H
pic

5′-100X
Pt
1
5′
Ph
H
H
MEK2
H
CH₃
H
acac

5′-100Y
Pt
0
5′
Ph
H
H
MEK2
H
CH₃
H
— —

5′-101
Pt
1
5′
Ph
H
MEK2
H
H
CH₃
H
pic

5′-101X
Pt
1
5′
Ph
H
MEK2
H
H
CH₃
H
acac

5′-101Y
Pt
0
5′
Ph
H
MEK2
H
H
CH₃
H
— —

5′-102
Pt
1
5′
Ph
H
H
PAL1
H
CH₃
H
pic

5′-102X
Pt
1
5′
Ph
H
H
PAL1
H
CH₃
H
acac

5′-102Y
Pt
0
5′
Ph
H
H
PAL1
H
CH₃
H
— —

5′-103
Pt
1
5′
Ph
H
PAL1
H
H
CH₃
H
pic

5′-103X
Pt
1
5′
Ph
H
PAL1
H
H
CH₃
H
acac

5′-103Y
Pt
0
5′
Ph
H
PAL1
H
H
CH₃
H
— —

5′-104
Pt
1
5′
Ph
H
H
PAL2
H
CH₃
H
pic

5′-104X
Pt
1
5′
Ph
H
H
PAL2
H
CH₃
H
acac

5′-104Y
Pt
0
5′
Ph
H
H
PAL2
H
CH₃
H
— —

5′-105
Pt
1
5′
Ph
H
PAL2
H
H
CH₃
H
pic

5′-105X
Pt
1
5′
Ph
H
PAL2
H
H
CH₃
H
acac

5′-105Y
Pt
0
5′
Ph
H
PAL2
H
H
CH₃
H
— —

5′-106
Pt
1
5′
Ph
H
H
MMK
H
CH₃
H
pic

5′-106X
Pt
1
5′
Ph
H
H
MMK
H
CH₃
H
acac

5′-106Y
Pt
0
5′
Ph
H
H
MMK
H
CH₃
H
— —

5′-107
Pt
1
5′
Ph
H
MMK
H
H
CH₃
H
pic

5′-107X
Pt
1
5′
Ph
H
MMK
H
H
CH₃
H
acac

5′-107Y
Pt
0
5′
Ph
H
MMK
H
H
CH₃
H
— —

5′-108
Pt
1
5′
Ph
H
H
EES1
H
CH₃
H
pic

5′-108X
Pt
1
5′
Ph
H
H
EES1
H
CH₃
H
acac

5′-108Y
Pt
0
5′
Ph
H
H
EES1
H
CH₃
H
— —

5′-109
Pt
1
5′
Ph
H
EES2
H
H
CH₃
H
pic

5′-109X
Pt
1
5′
Ph
H
EES2
H
H
CH₃
H
acac

5′-109Y
Pt
0
5′
Ph
H
EES2
H
H
CH₃
H
— —

5′-110
Pt
1
5′
Ph
H
H
PAE1
H
CH₃
H
pic

5′-110X
Pt
1
5′
Ph
H
H
PAE1
H
CH₃
H
acac

5′-110Y
Pt
0
5′
Ph
H
H
PAE1
H
CH₃
H
— —

5′-111
Pt
1
5′
Ph
H
PAE2
H
H
CH₃
H
pic

5′-111X
Pt
1
5′
Ph
H
PAE2
H
H
CH₃
H
acac

5′-111Y
Pt
0
5′
Ph
H
PAE2
H
H
CH₃
H
— —

5′-112
Pt
1
5′
Ph
H
H
AME1
H
CH₃
H
pic

5′-112X
Pt
1
5′
Ph
H
H
AME1
H
CH₃
H
acac

5′-112Y
Pt
0
5′
Ph
H
H
AME1
H
CH₃
H
— —

5′-113
Pt
1
5′
Ph
H
AME1
H
H
CH₃
H
pic

5′-113X
Pt
1
5′
Ph
H
AME1
H
H
CH₃
H
acac

5′-113Y
Pt
0
5′
Ph
H
AME1
H
H
CH₃
H
— —

5′-114
Pt
1
5′
Ph
H
H
AME2
H
CH₃
H
pic

5′-114X
Pt
1
5′
Ph
H
H
AME2
H
CH₃
H
acac

5′-114Y
Pt
0
5′
Ph
H
H
AME2
H
CH₃
H
— —

5′-115
Pt
1
5′
Ph
H
AME2
H
H
CH₃
H
pic

5′-115X
Pt
1
5′
Ph
H
AME2
H
H
CH₃
H
acac

5′-115Y
Pt
0
5′
Ph
H
AME2
H
H
CH₃
H
— —

5′-116
Pt
1
5′
Ph
H
H
EAE1
H
CH₃
H
pic

5′-116X
Pt
1
5′
Ph
H
H
EAE1
H
CH₃
H
acac

5′-116Y
Pt
0
5′
Ph
H
H
EAE1
H
CH₃
H
— —

5′-117
Pt
1
5′
Ph
H
EAE1
H
H
CH₃
H
pic

5′-117X
Pt
1
5′
Ph
H
EAE1
H
H
CH₃
H
acac

5′-117Y
Pt
0
5′
Ph
H
EAE1
H
H
CH₃
H
— —

5′-118
Pt
1
5′
Ph
H
H
EAE2
H
CH₃
H
pic

5′-118X
Pt
1
5′
Ph
H
H
EAE2
H
CH₃
H
acac

5′-118Y
Pt
0
5′
Ph
H
H
EAE2
H
CH₃
H
— —

5′-119
Pt
1
5′
Ph
H
EAE2
H
H
CH₃
H
pic

5′-119X
Pt
1
5′
Ph
H
EAE2
H
H
CH₃
H
acac

5′-119Y
Pt
0
5′
Ph
H
EAE2
H
H
CH₃
H
— —

5′-120
Pt
1
5′
Ph
H
H
AAE1
H
CH₃
H
pic

5′-120X
Pt
1
5′
Ph
H
H
AAE1
H
CH₃
H
acac

5′-120Y
Pt
0
5′
Ph
H
H
AAE1
H
CH₃
H
— —

5′-121
Pt
1
5′
Ph
H
AAE1
H
H
CH₃
H
pic

5′-121X
Pt
1
5′
Ph
H
AAE1
H
H
CH₃
H
acac

5′-121Y
Pt
0
5′
Ph
H
AAE1
H
H
CH₃
H
— —

5′-122
Pt
1
5′
Ph
H
H
AAE2
H
CH₃
H
pic

5′-122X
Pt
1
5′
Ph
H
H
AAE2
H
CH₃
H
acac

5′-122Y
Pt
0
5′
Ph
H
H
AAE2
H
CH₃
H
— —

5′-123
Pt
1
5′
Ph
H
AAE2
H
H
CH₃
H
pic

5′-123X
Pt
1
5′
Ph
H
AAE2
H
H
CH₃
H
acac

5′-123Y
Pt
0
5′
Ph
H
AAE2
H
H
CH₃
H
— —

5′-124
Pt
1
5′
Ph
H
H
PME1
H
CH₃
H
pic

5′-124X
Pt
1
5′
Ph
H
H
PME1
H
CH₃
H
acac

5′-124Y
Pt
0
5′
Ph
H
H
PME1
H
CH₃
H
— —

5′-125
Pt
1
5′
Ph
H
PME1
H
H
CH₃
H
pic

5′-125X
Pt
1
5′
Ph
H
PME1
H
H
CH₃
H
acac

5′-125Y
Pt
0
5′
Ph
H
PME1
H
H
CH₃
H
— —

5′-126
Pt
1
5′
Ph
H
H
PME2
H
CH₃
H
pic

5′-126X
Pt
1
5′
Ph
H
H
PME2
H
CH₃
H
acac

5′-126Y
Pt
0
5′
Ph
H
H
PME2
H
CH₃
H
— —

5′-127
Pt
1
5′
Ph
H
PME2
H
H
CH₃
H
pic

5′-127X
Pt
1
5′
Ph
H
PME2
H
H
CH₃
H
acac

5′-127Y
Pt
0
5′
Ph
H
PME2
H
H
CH₃
H
— —

5′-128
Pt
1
5′
Ph
H
H
MET1
H
CH₃
H
pic

5′-128X
Pt
1
5′
Ph
H
H
MET1
H
CH₃
H
acac

5′-128Y
Pt
0
5′
Ph
H
H
MET1
H
CH₃
H
— —

5′-129
Pt
1
5′
Ph
H
MET1
H
H
CH₃
H
pic

5′-129X
Pt
1
5′
Ph
H
MET1
H
H
CH₃
H
acac

5′-129Y
Pt
0
5′
Ph
H
MET1
H
H
CH₃
H
— —

5′-130
Pt
1
5′
Ph
H
H
MET2
H
CH₃
H
pic

5′-130X
Pt
1
5′
Ph
H
H
MET2
H
CH₃
H
acac

5′-130Y
Pt
0
5′
Ph
H
H
MET2
H
CH₃
H
— —

5′-131
Pt
1
5′
Ph
H
MET2
H
H
CH₃
H
pic

5′-131X
Pt
1
5′
Ph
H
MET2
H
H
CH₃
H
acac

5′-131Y
Pt
0
5′
Ph
H
MET2
H
H
CH₃
H
— —

5′-132
Pt
1
5′
Ph
H
H
EE1
H
CH₃
H
pic

5′-132X
Pt
1
5′
Ph
H
H
EE1
H
CH₃
H
acac

5′-132Y
Pt
0
5′
Ph
H
H
EE1
H
CH₃
H
— —

5′-133
Pt
1
5′
Ph
H
EE1
H
H
CH₃
H
pic

5′-133X
Pt
1
5′
Ph
H
EE1
H
H
CH₃
H
acac

5′-133Y
Pt
0
5′
Ph
H
EE1
H
H
CH₃
H
— —

5′-134
Pt
1
5′
Ph
H
H
EE2
H
CH₃
H
pic

5′-134X
Pt
1
5′
Ph
H
H
EE2
H
CH₃
H
acac

5′-134Y
Pt
0
5′
Ph
H
H
EE2
H
CH₃
H
— —

5′-135
Pt
1
5′
Ph
H
EE2
H
H
CH₃
H
pic

5′-135X
Pt
1
5′
Ph
H
EE2
H
H
CH₃
H
acac

5′-135Y
Pt
0
5′
Ph
H
EE2
H
H
CH₃
H
— —

5′-136
Pt
1
5′
Ph
H
H
MS1
H
CH₃
H
pic

5′-136X
Pt
1
5′
Ph
H
H
MS1
H
CH₃
H
acac

5′-136Y
Pt
0
5′
Ph
H
H
MS1
H
CH₃
H
— —

5′-137
Pt
1
5′
Ph
H
MS1
H
H
CH₃
H
pic

5′-137X
Pt
1
5′
Ph
H
MS1
H
H
CH₃
H
acac

5′-137Y
Pt
0
5′
Ph
H
MS1
H
H
CH₃
H
— —

5′-138
Pt
1
5′
Ph
H
H
MS2
H
CH₃
H
pic

5′-138X
Pt
1
5′
Ph
H
H
MS2
H
CH₃
H
acac

5′-138Y
Pt
0
5′
Ph
H
H
MS2
H
CH₃
H
— —

5′-139
Pt
1
5′
Ph
H
MS2
H
H
CH₃
H
pic

5′-139X
Pt
1
5′
Ph
H
MS2
H
H
CH₃
H
acac

5′-139Y
Pt
0
5′
Ph
H
MS2
H
H
CH₃
H
— —

TABLE 34

No.
M
m
BMS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹ L²

6′-1
Pt
1
6′
Ph
H
H
H
H
CH₃
H
H
pic

6′-1X
Pt
1
6′
Ph
H
H
H
H
CH₃
H
H
acac

6′-1Y
Pt
0
6′
Ph
H
H
H
H
CH₃
H
H
— —

6′-2
Pt
1
6′
Ph
H
H
H
H

^tC₄H₉
H
H
pic

6′-2X
Pt
1
6′
Ph
H
H
H
H

^tC₄H₉
H
H
acac

6′-2Y
Pt
0
6′
Ph
H
H
H
H

^tC₄H₉
H
H
— —

6′-3
Pt
1
6′
Ph
H
F
H
F
CH₃
H
H
pic

6′-3X
Pt
1
6′
Ph
H
F
H
F
CH₃
H
H
acac

6′-3Y
Pt
0
6′
Ph
H
F
H
F
CH₃
H
H
— —

6′-4
Pt
1
6′
Ph
H
F
H
F

^tC₄H₉
H
H
pic

6′-4X
Pt
1
6′
Ph
H
F
H
F

^tC₄H₉
H
H
acac

6′-4Y
Pt
0
6′
Ph
H
F
H
F

^tC₄H₉
H
H
— —

6′-5
Pt
1
6′
Ph
F
H
H
F
CH₃
H
H
pic

6′-5X
Pt
1
6′
Ph
F
H
H
F
CH₃
H
H
acac

6′-5Y
Pt
0
6′
Ph
F
H
H
F
CH₃
H
H
— —

6′-6
Pt
1
6′
Ph
F
H
H
F

^tC₄H₉
H
H
pic

6′-6X
Pt
1
6′
Ph
F
H
H
F

^tC₄H₉
H
H
acac

6′-6Y
Pt
0
6′
Ph
F
H
H
F

^tC₄H₉
H
H
— —

6′-7
Pt
1
6′
Ph
CF₃
H
CF₃
H
CH₃
H
H
pic

6′-7X
Pt
1
6′
Ph
CF₃
H
CF₃
H
CH₃
H
H
acac

6′-7Y
Pt
0
6′
Ph
CF₃
H
CF₃
H
CH₃
H
H
— —

6′-8
Pt
1
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

6′-8X
Pt
1
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

6′-8Y
Pt
0
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
— —

6′-9
Pt
1
6′
Ph
H
F
CF₃
H
CH₃
H
H
pic

6′-9X
Pt
1
6′
Ph
H
F
CF₃
H
CH₃
H
H
acac

6′-9Y
Pt
0
6′
Ph
H
F
CF₃
H
CH₃
H
H
— —

6′-10
Pt
1
6′
Ph
F
H
CF₃
H
CH₃
H
H
pic

6′-10X
Pt
1
6′
Ph
F
H
CF₃
H
CH₃
H
H
acac

6′-10Y
Pt
0
6′
Ph
F
H
CF₃
H
CH₃
H
H
— —

6′-11
Pt
1
6′
Ph
F
F
F
F
CH₃
H
H
pic

6′-11X
Pt
1
6′
Ph
F
F
F
F
CH₃
H
H
acac

6′-11Y
Pt
0
6′
Ph
F
F
F
F
CH₃
H
H
— —

6′-12
Pt
1
6′
Ph
H
F
H
CH₃
CH₃
H
H
pic

6′-12X
Pt
1
6′
Ph
H
F
H
CH₃
CH₃
H
H
acac

6′-12Y
Pt
0
6′
Ph
H
F
H
CH₃
CH₃
H
H
— —

6′-13
Pt
1
6′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

6′-13X
Pt
1
6′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

6′-13Y
Pt
0
6′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
— —

6′-14
Pt
1
6′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

6′-14X
Pt
1
6′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

6′-14Y
Pt
0
6′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
— —

6′-15
Pt
1
6′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

6′-15X
Pt
1
6′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

6′-15Y
Pt
0
6′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
— —

6′-16
Pt
1
6′
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

6′-16X
Pt
1
6′
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

6′-16Y
Pt
0
6′
Ph
H
CF₃
H
CF₃
CH₃
H
H
— —

6′-17
Pt
1
6′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

6′-17X
Pt
1
6′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

6′-17Y
Pt
0
6′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
— —

6′-18
Pt
1
6′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

6′-18X
Pt
1
6′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

6′-18Y
Pt
0
6′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
— —

6′-19
Pt
1
6′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

6′-19X
Pt
1
6′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

6′-19Y
Pt
0
6′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
— —

6′-20
Pt
1
6′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
pic

6′-20X
Pt
1
6′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

6′-20Y
Pt
0
6′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
— —

6′-21
Pt
1
6′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

6′-21X
Pt
1
6′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

6′-21Y
Pt
0
6′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
— —

6′-22
Pt
1
6′
Ph
H
CF₃
H
CH₃
CH₃
H
H
pic

6′-22X
Pt
1
6′
Ph
H
CF₃
H
CH₃
CH₃
H
H
acac

6′-22Y
Pt
0
6′
Ph
H
CF₃
H
CH₃
CH₃
H
H
— —

6′-23
Pt
1
6′
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

6′-23X
Pt
1
6′
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

6′-23Y
Pt
0
6′
Ph
H
CF₃
CF₃
H
CH₃
H
H
— —

6′-24
Pt
1
6′
Ph
H
H
NO₂
H
CH₃
H
H
pic

6′-24X
Pt
1
6′
Ph
H
H
NO₂
H
CH₃
H
H
acac

6′-24Y
Pt
0
6′
Ph
H
H
NO₂
H
CH₃
H
H
— —

6′-25
Pt
1
6′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
pic

6′-25X
Pt
1
6′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
acac

6′-25Y
Pt
0
6′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
— —

6′-26
Pt
1
6′
Ph
F
H
NO₂
H
CH₃
H
H
pic

6′-26X
Pt
1
6′
Ph
F
H
NO₂
H
CH₃
H
H
acac

6′-26Y
Pt
0
6′
Ph
F
H
NO₂
H
CH₃
H
H
— —

6′-27
Pt
1
6′
Ph
F
H
NO₂
F
CH₃
H
H
pic

6′-27X
Pt
1
6′
Ph
F
H
NO₂
F
CH₃
H
H
acac

6′-27Y
Pt
0
6′
Ph
F
H
NO₂
F
CH₃
H
H
— —

6′-28
Pt
1
6′
Ph
H
NO₂
H
NO₂
CH₃
H
H
pic

6′-28X
Pt
1
6′
Ph
H
NO₂
H
NO₂
CH₃
H
H
acac

6′-28Y
Pt
0
6′
Ph
H
NO₂
H
NO₂
CH₃
H
H
— —

6′-29
Pt
1
6′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
pic

6′-29X
Pt
1
6′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
acac

6′-29Y
Pt
0
6′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
— —

6′-30
Pt
1
6′
Ph
NO₂
H
H
NO₂
CH₃
H
H
pic

6′-30X
Pt
1
6′
Ph
NO₂
H
H
NO₂
CH₃
H
H
acac

6′-30Y
Pt
0
6′
Ph
NO₂
H
H
NO₂
CH₃
H
H
— —

6′-31
Pt
1
6′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
pic

6′-31X
Pt
1
6′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
acac

6′-31Y
Pt
0
6′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
— —

6′-32
Pt
1
6′
Ph
H
H
CF₃
H
CH₃
H
H
pic

6′-32X
Pt
1
6′
Ph
H
H
CF₃
H
CH₃
H
H
acac

6′-32Y
Pt
0
6′
Ph
H
H
CF₃
H
CH₃
H
H
— —

6′-33
Pt
1
6′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

6′-33X
Pt
1
6′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

6′-33Y
Pt
0
6′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
— —

6′-34
Pt
1
6′
Ph
H
Cl
CF₃
H
CH₃
H
H
pic

6′-34X
Pt
1
6′
Ph
H
Cl
CF₃
H
CH₃
H
H
acac

6′-34Y
Pt
0
6′
Ph
H
Cl
CF₃
H
CH₃
H
H
— —

6′-35
Pt
1
6′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
pic

6′-35X
Pt
1
6′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
acac

6′-35Y
Pt
0
6′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
— —

6′-36
Pt
1
6′
Ph
H
NO₂
H
H
CH₃
H
H
pic

6′-36X
Pt
1
6′
Ph
H
NO₂
H
H
CH₃
H
H
acac

6′-36Y
Pt
0
6′
Ph
H
NO₂
H
H
CH₃
H
H
— —

6′-37
Pt
1
6′
Ph
H
CF₃
H
H
CH₃
H
H
pic

6′-37X
Pt
1
6′
Ph
H
CF₃
H
H
CH₃
H
H
acac

6′-37Y
Pt
0
6′
Ph
H
CF₃
H
H
CH₃
H
H
— —

6′-38
Pt
1
6′
Ph
H
NO₂
H
CH₃
CH₃
H
H
pic

6′-38X
Pt
1
6′
Ph
H
NO₂
H
CH₃
CH₃
H
H
acac

6′-38Y
Pt
0
6′
Ph
H
NO₂
H
CH₃
CH₃
H
H
— —

6′-39
Pt
1
6′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
pic

6′-39X
Pt
1
6′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
acac

6′-39Y
Pt
0
6′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
— —

6′-40
Pt
1
6′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
pic

6′-40X
Pt
1
6′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
acac

6′-40Y
Pt
0
6′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
— —

6′-41
Pt
1
6′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

6′-41X
Pt
1
6′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

6′-41Y
Pt
0
6′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
— —

6′-42
Pt
1
6′
Ph
H
H
CH₃O
H
CH₃
H
H
pic

6′-42X
Pt
1
6′
Ph
H
H
CH₃O
H
CH₃
H
H
acac

6′-42Y
Pt
0
6′
Ph
H
H
CH₃O
H
CH₃
H
H
— —

6′-43
Pt
1
6′
Ph
H
CH₃O
H
H
CH₃
H
H
pic

6′-43X
Pt
1
6′
Ph
H
CH₃O
H
H
CH₃
H
H
acac

6′-43Y
Pt
0
6′
Ph
H
CH₃O
H
H
CH₃
H
H
— —

6′-44
Pt
1
6′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

6′-44X
Pt
1
6′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

6′-44Y
Pt
0
6′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
— —

6′-45
Pt
1
6′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

6′-45X
Pt
1
6′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

6′-45Y
Pt
0
6′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
— —

6′-46
Pt
1
6′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
pic

6′-46X
Pt
1
6′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
acac

6′-46Y
Pt
0
6′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
— —

6′-47
Pt
1
6′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
pic

6′-47X
Pt
1
6′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
acac

6′-47Y
Pt
0
6′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
— —

6′-48
Pt
1
6′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
pic

6′-48X
Pt
1
6′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
acac

6′-48Y
Pt
0
6′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
— —

6′-49
Pt
1
6′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
pic

6′-49X
Pt
1
6′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
acac

6′-49Y
Pt
0
6′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
— —

6′-50
Pt
1
6′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
pic

6′-50X
Pt
1
6′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
acac

6′-50Y
Pt
0
6′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
— —

6′-51
Pt
1
6′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
pic

6′-51X
Pt
1
6′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
acac

6′-51Y
Pt
0
6′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
— —

6′-52
Pt
1
6′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
pic

6′-52X
Pt
1
6′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
acac

6′-52Y
Pt
0
6′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
— —

6′-53
Pt
1
6′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
pic

6′-53X
Pt
1
6′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
acac

6′-53Y
Pt
0
6′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
— —

6′-54
Pt
1
6′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
pic

6′-54X
Pt
1
6′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
acac

6′-54Y
Pt
0
6′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
— —

6′-55
Pt
1
6′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
pic

6′-55X
Pt
1
6′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
acac

6′-55Y
Pt
0
6′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
— —

6′-56
Pt
1
6′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

6′-56X
Pt
1
6′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

6′-56Y
Pt
0
6′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
— —

6′-57
Pt
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
pic

6′-57X
Pt
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
acac

6′-57Y
Pt
0
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
— —

6′-58
Pt
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
pic

6′-58X
Pt
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
acac

6′-58Y
Pt
0
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
— —

6′-59
Pt
1
6′
Ph
H
H
H
COCH₃
CH₃
H
H
pic

6′-59X
Pt
1
6′
Ph
H
H
H
COCH₃
CH₃
H
H
acac

6′-59Y
Pt
0
6′
Ph
H
H
H
COCH₃
CH₃
H
H
— —

6′-60
Pt
1
6′
Ph
H
H
COCH₃
H
CH₃
H
H
pic

6′-60X
Pt
1
6′
Ph
H
H
COCH₃
H
CH₃
H
H
acac

6′-60Y
Pt
0
6′
Ph
H
H
COCH₃
H
CH₃
H
H
— —

6′-61
Pt
1
6′
Ph
H
COCH₃
H
H
CH₃
H
H
pic

6′-61X
Pt
1
6′
Ph
H
COCH₃
H
H
CH₃
H
H
acac

6′-61Y
Pt
0
6′
Ph
H
COCH₃
H
H
CH₃
H
H
— —

6′-62
Pt
1
6′
Ph
H
H
BL
CH₃
H
H
pic

6′-62X
Pt
1
6′
Ph
H
H
BL
CH₃
H
H
acac

6′-62Y
Pt
0
6′
Ph
H
H
BL
CH₃
H
H
— —

6′-63
Pt
1
6′
Ph
H
H
BL

^tC₄H₉
H
H
pic

6′-63X
Pt
1
6′
Ph
H
H
BL

^tC₄H₉
H
H
acac

6′-63Y
Pt
0
6′
Ph
H
H
BL

^tC₄H₉
H
H
— —

6′-64
Pt
1
6′
Ph
H
BL
H
CH₃
H
H
pic

6′-64X
Pt
1
6′
Ph
H
BL
H
CH₃
H
H
acac

6′-64Y
Pt
0
6′
Ph
H
BL
H
CH₃
H
H
— —

6′-65
Pt
1
6′
Ph
H
BL
H

^tC₄H₉
H
H
pic

6′-65X
Pt
1
6′
Ph
H
BL
H

^tC₄H₉
H
H
acac

6′-65Y
Pt
0
6′
Ph
H
BL
H

^tC₄H₉
H
H
— —

6′-66
Pt
1
6′
Ph
H
H
PL
CH₃
H
H
pic

6′-66X
Pt
1
6′
Ph
H
H
PL
CH₃
H
H
acac

6′-66Y
Pt
0
6′
Ph
H
H
PL
CH₃
H
H
— —

6′-67
Pt
1
6′
Ph
H
H
PL

^tC₄H₉
H
H
pic

6′-67X
Pt
1
6′
Ph
H
H
PL

^tC₄H₉
H
H
acac

6′-67Y
Pt
0
6′
Ph
H
H
PL

^tC₄H₉
H
H
— —

6′-68
Pt
1
6′
Ph
H
PL
H
CH₃
H
H
pic

6′-68X
Pt
1
6′
Ph
H
PL
H
CH₃
H
H
acac

6′-68Y
Pt
0
6′
Ph
H
PL
H
CH₃
H
H
— —

6′-69
Pt
1
6′
Ph
H
PL
H

^tC₄H₉
H
H
pic

6′-69X
Pt
1
6′
Ph
H
PL
H

^tC₄H₉
H
H
acac

6′-69Y
Pt
0
6′
Ph
H
PL
H

^tC₄H₉
H
H
— —

6′-70
Pt
1
6′
Ph
H
H
MEE1
CH₃
H
H
pic

6′-70X
Pt
1
6′
Ph
H
H
MEE1
CH₃
H
H
acac

6′-70Y
Pt
0
6′
Ph
H
H
MEE1
CH₃
H
H
— —

6′-71
Pt
1
6′
Ph
H
MEE1
H
CH₃
H
H
pic

6′-71X
Pt
1
6′
Ph
H
MEE1
H
CH₃
H
H
acac

6′-71Y
Pt
0
6′
Ph
H
MEE1
H
CH₃
H
H
— —

6′-72
Pt
1
6′
Ph
H
H
MEE2
CH₃
H
H
pic

6′-72X
Pt
1
6′
Ph
H
H
MEE2
CH₃
H
H
acac

6′-72Y
Pt
0
6′
Ph
H
H
MEE2
CH₃
H
H
— —

6′-73
Pt
1
6′
Ph
H
MEE2
H
CH₃
H
H
pic

6′-73X
Pt
1
6′
Ph
H
MEE2
H
CH₃
H
H
acac

6′-73Y
Pt
0
6′
Ph
H
MEE2
H
CH₃
H
H
— —

6′-74
Pt
1
6′
Ph
H
H
PA1
CH₃
H
H
pic

6′-74X
Pt
1
6′
Ph
H
H
PA1
CH₃
H
H
acac

6′-74Y
Pt
0
6′
Ph
H
H
PA1
CH₃
H
H
— —

6′-75
Pt
1
6′
Ph
H
PA1
H
CH₃
H
H
pic

6′-75X
Pt
1
6′
Ph
H
PA1
H
CH₃
H
H
acac

6′-75Y
Pt
0
6′
Ph
H
PA1
H
CH₃
H
H
— —

6′-76
Pt
1
6′
Ph
H
H
PA2
CH₃
H
H
pic

6′-76X
Pt
1
6′
Ph
H
H
PA2
CH₃
H
H
acac

6′-76Y
Pt
0
6′
Ph
H
H
PA2
CH₃
H
H
— —

6′-77
Pt
1
6′
Ph
H
PA2
H
CH₃
H
H
pic

6′-77X
Pt
1
6′
Ph
H
PA2
H
CH₃
H
H
acac

6′-77Y
Pt
0
6′
Ph
H
PA2
H
CH₃
H
H
— —

6′-78
Pt
1
6′
Ph
H
H
EA1
CH₃
H
H
pic

6′-78X
Pt
1
6′
Ph
H
H
EA1
CH₃
H
H
acac

6′-78Y
Pt
0
6′
Ph
H
H
EA1
CH₃
H
H
— —

6′-79
Pt
1
6′
Ph
H
EA2
H
CH₃
H
H
pic

6′-79X
Pt
1
6′
Ph
H
EA2
H
CH₃
H
H
acac

6′-79Y
Pt
0
6′
Ph
H
EA2
H
CH₃
H
H
— —

6′-80
Pt
1
6′
Ph
H
H
ME
CH₃
H
H
pic

6′-80X
Pt
1
6′
Ph
H
H
ME
CH₃
H
H
acac

6′-80Y
Pt
0
6′
Ph
H
H
ME
CH₃
H
H
— —

6′-81
Pt
1
6′
Ph
H
ME
H
CH₃
H
H
pic

6′-81X
Pt
1
6′
Ph
H
ME
H
CH₃
H
H
acac

6′-81Y
Pt
0
6′
Ph
H
ME
H
CH₃
H
H
— —

6′-82
Pt
1
6′
Ph
H
H
AT
CH₃
H
H
pic

6′-82X
Pt
1
6′
Ph
H
H
AT
CH₃
H
H
acac

6′-82Y
Pt
0
6′
Ph
H
H
AT
CH₃
H
H
— —

6′-83
Pt
1
6′
Ph
H
AT
H
CH₃
H
H
pic

6′-83X
Pt
1
6′
Ph
H
AT
H
CH₃
H
H
acac

6′-83Y
Pt
0
6′
Ph
H
AT
H
CH₃
H
H
— —

6′-84
Pt
1
6′
Ph
H
H
MES1
CH₃
H
H
pic

6′-84X
Pt
1
6′
Ph
H
H
MES1
CH₃
H
H
acac

6′-84Y
Pt
0
6′
Ph
H
H
MES1
CH₃
H
H
— —

6′-85
Pt
1
6′
Ph
H
MES1
H
CH₃
H
H
pic

6′-85X
Pt
1
6′
Ph
H
MES1
H
CH₃
H
H
acac

6′-85Y
Pt
0
6′
Ph
H
MES1
H
CH₃
H
H
— —

6′-86
Pt
1
6′
Ph
H
H
MES2
CH₃
H
H
pic

6′-86X
Pt
1
6′
Ph
H
H
MES2
CH₃
H
H
acac

6′-86Y
Pt
0
6′
Ph
H
H
MES2
CH₃
H
H
— —

6′-87
Pt
1
6′
Ph
H
MES2
H
CH₃
H
H
pic

6′-87X
Pt
1
6′
Ph
H
MES2
H
CH₃
H
H
acac

6′-87Y
Pt
0
6′
Ph
H
MES2
H
CH₃
H
H
— —

6′-88
Pt
1
6′
Ph
H
H
PS1
CH₃
H
H
pic

6′-88X
Pt
1
6′
Ph
H
H
PS1
CH₃
H
H
acac

6′-88Y
Pt
0
6′
Ph
H
H
PS1
CH₃
H
H
— —

6′-89
Pt
1
6′
Ph
H
PS1
H
CH₃
H
H
pic

6′-89X
Pt
1
6′
Ph
H
PS1
H
CH₃
H
H
acac

6′-89Y
Pt
0
6′
Ph
H
PS1
H
CH₃
H
H
— —

6′-90
Pt
1
6′
Ph
H
H
PS2
CH₃
H
H
pic

6′-90X
Pt
1
6′
Ph
H
H
PS2
CH₃
H
H
acac

6′-90Y
Pt
0
6′
Ph
H
H
PS2
CH₃
H
H
— —

6′-91
Pt
1
6′
Ph
H
PS2
H
CH₃
H
H
pic

6′-91X
Pt
1
6′
Ph
H
PS2
H
CH₃
H
H
acac

6′-91Y
Pt
0
6′
Ph
H
PS2
H
CH₃
H
H
— —

6′-92
Pt
1
6′
Ph
H
H
BAL1
CH₃
H
H
pic

6′-92X
Pt
1
6′
Ph
H
H
BAL1
CH₃
H
H
acac

6′-92Y
Pt
0
6′
Ph
H
H
BAL1
CH₃
H
H
— —

6′-93
Pt
1
6′
Ph
H
BAL1
H
CH₃
H
H
pic

6′-93X
Pt
1
6′
Ph
H
BAL1
H
CH₃
H
H
acac

6′-93Y
Pt
0
6′
Ph
H
BAL1
H
CH₃
H
H
— —

6′-94
Pt
1
6′
Ph
H
H
BAL2
CH₃
H
H
pic

6′-94X
Pt
1
6′
Ph
H
H
BAL2
CH₃
H
H
acac

6′-94Y
Pt
0
6′
Ph
H
H
BAL2
CH₃
H
H
— —

6′-95
Pt
1
6′
Ph
H
BAL2
H
CH₃
H
H
pic

6′-95X
Pt
1
6′
Ph
H
BAL2
H
CH₃
H
H
acac

6′-95Y
Pt
0
6′
Ph
H
BAL2
H
CH₃
H
H
— —

6′-96
Pt
1
6′
Ph
H
H
MEK1
CH₃
H
H
pic

6′-96X
Pt
1
6′
Ph
H
H
MEK1
CH₃
H
H
acac

6′-96Y
Pt
0
6′
Ph
H
H
MEK1
CH₃
H
H
— —

6′-97
Pt
1
6′
Ph
H
MEK1
H
CH₃
H
H
pic

6′-97X
Pt
1
6′
Ph
H
MEK1
H
CH₃
H
H
acac

6′-97Y
Pt
0
6′
Ph
H
MEK1
H
CH₃
H
H
— —

6′-98
Pt
1
6′
Ph
H
H
MEK2
CH₃
H
H
pic

6′-98X
Pt
1
6′
Ph
H
H
MEK2
CH₃
H
H
acac

6′-98Y
Pt
0
6′
Ph
H
H
MEK2
CH₃
H
H
— —

6′-99
Pt
1
6′
Ph
H
MEK2
H
CH₃
H
H
pic

6′-99X
Pt
1
6′
Ph
H
MEK2
H
CH₃
H
H
acac

6′-99Y
Pt
0
6′
Ph
H
MEK2
H
CH₃
H
H
— —

6′-100
Pt
1
6′
Ph
H
H
PAL1
CH₃
H
H
pic

6′-100X
Pt
1
6′
Ph
H
H
PAL1
CH₃
H
H
acac

6′-100Y
Pt
0
6′
Ph
H
H
PAL1
CH₃
H
H
— —

6′-101
Pt
1
6′
Ph
H
PAL1
H
CH₃
H
H
pic

6′-101X
Pt
1
6′
Ph
H
PAL1
H
CH₃
H
H
acac

6′-101Y
Pt
0
6′
Ph
H
PAL1
H
CH₃
H
H
— —

6′-102
Pt
1
6′
Ph
H
H
PAL2
CH₃
H
H
pic

6′-102X
Pt
1
6′
Ph
H
H
PAL2
CH₃
H
H
acac

6′-102Y
Pt
0
6′
Ph
H
H
PAL2
CH₃
H
H
— —

6′-103
Pt
1
6′
Ph
H
PAL2
H
CH₃
H
H
pic

6′-103X
Pt
1
6′
Ph
H
PAL2
H
CH₃
H
H
acac

6′-103Y
Pt
0
6′
Ph
H
PAL2
H
CH₃
H
H
— —

6′-104
Pt
1
6′
Ph
H
H
MMK
CH₃
H
H
pic

6′-104X
Pt
1
6′
Ph
H
H
MMK
CH₃
H
H
acac

6′-104Y
Pt
0
6′
Ph
H
H
MMK
CH₃
H
H
— —

6′-105
Pt
1
6′
Ph
H
MMK
H
CH₃
H
H
pic

6′-105X
Pt
1
6′
Ph
H
MMK
H
CH₃
H
H
acac

6′-105Y
Pt
0
6′
Ph
H
MMK
H
CH₃
H
H
— —

6′-106
Pt
1
6′
Ph
H
H
EES1
CH₃
H
H
pic

6′-106X
Pt
1
6′
Ph
H
H
EES1
CH₃
H
H
acac

6′-106Y
Pt
0
6′
Ph
H
H
EES1
CH₃
H
H
— —

6′-107
Pt
1
6′
Ph
H
EES2
H
CH₃
H
H
pic

6′-107X
Pt
1
6′
Ph
H
EES2
H
CH₃
H
H
acac

6′-107Y
Pt
0
6′
Ph
H
EES2
H
CH₃
H
H
— —

6′-108
Pt
1
6′
Ph
H
H
PAE1
CH₃
H
H
pic

6′-108X
Pt
1
6′
Ph
H
H
PAE1
CH₃
H
H
acac

6′-108Y
Pt
0
6′
Ph
H
H
PAE1
CH₃
H
H
— —

6′-109
Pt
1
6′
Ph
H
PAE2
H
CH₃
H
H
pic

6′-109X
Pt
1
6′
Ph
H
PAE2
H
CH₃
H
H
acac

6′-109Y
Pt
0
6′
Ph
H
PAE2
H
CH₃
H
H
— —

6′-110
Pt
1
6′
Ph
H
H
AME1
CH₃
H
H
pic

6′-110X
Pt
1
6′
Ph
H
H
AME1
CH₃
H
H
acac

6′-110Y
Pt
0
6′
Ph
H
H
AME1
CH₃
H
H
— —

6′-111
Pt
1
6′
Ph
H
AME1
H
CH₃
H
H
pic

6′-111X
Pt
1
6′
Ph
H
AME1
H
CH₃
H
H
acac

6′-111Y
Pt
0
6′
Ph
H
AME1
H
CH₃
H
H
— —

6′-112
Pt
1
6′
Ph
H
H
AME2
CH₃
H
H
pic

6′-112X
Pt
1
6′
Ph
H
H
AME2
CH₃
H
H
acac

6′-112Y
Pt
0
6′
Ph
H
H
AME2
CH₃
H
H
— —

6′-113
Pt
1
6′
Ph
H
AME2
H
CH₃
H
H
pic

6′-113X
Pt
1
6′
Ph
H
AME2
H
CH₃
H
H
acac

6′-113Y
Pt
0
6′
Ph
H
AME2
H
CH₃
H
H
— —

6′-114
Pt
1
6′
Ph
H
H
EAE1
CH₃
H
H
pic

6′-114X
Pt
1
6′
Ph
H
H
EAE1
CH₃
H
H
acac

6′-114Y
Pt
0
6′
Ph
H
H
EAE1
CH₃
H
H
— —

6′-115
Pt
1
6′
Ph
H
EAE1
H
CH₃
H
H
pic

6′-115X
Pt
1
6′
Ph
H
EAE1
H
CH₃
H
H
acac

6′-115Y
Pt
0
6′
Ph
H
EAE1
H
CH₃
H
H
— —

6′-116
Pt
1
6′
Ph
H
H
EAE2
CH₃
H
H
pic

6′-116X
Pt
1
6′
Ph
H
H
EAE2
CH₃
H
H
acac

6′-116Y
Pt
0
6′
Ph
H
H
EAE2
CH₃
H
H
— —

6′-117
Pt
1
6′
Ph
H
EAE2
H
CH₃
H
H
pic

6′-117X
Pt
1
6′
Ph
H
EAE2
H
CH₃
H
H
acac

6′-117Y
Pt
0
6′
Ph
H
EAE2
H
CH₃
H
H
— —

6′-118
Pt
1
6′
Ph
H
H
AAE1
CH₃
H
H
pic

6′-118X
Pt
1
6′
Ph
H
H
AAE1
CH₃
H
H
acac

6′-118Y
Pt
0
6′
Ph
H
H
AAE1
CH₃
H
H
— —

6′-119
Pt
1
6′
Ph
H
AAE1
H
CH₃
H
H
pic

6′-119X
Pt
1
6′
Ph
H
AAE1
H
CH₃
H
H
acac

6′-119Y
Pt
0
6′
Ph
H
AAE1
H
CH₃
H
H
— —

6′-120
Pt
1
6′
Ph
H
H
AAE2
CH₃
H
H
pic

6′-120X
Pt
1
6′
Ph
H
H
AAE2
CH₃
H
H
acac

6′-120Y
Pt
0
6′
Ph
H
H
AAE2
CH₃
H
H
— —

6′-121
Pt
1
6′
Ph
H
AAE2
H
CH₃
H
H
pic

6′-121X
Pt
1
6′
Ph
H
AAE2
H
CH₃
H
H
acac

6′-121Y
Pt
0
6′
Ph
H
AAE2
H
CH₃
H
H
— —

6′-122
Pt
1
6′
Ph
H
H
PME1
CH₃
H
H
pic

6′-122X
Pt
1
6′
Ph
H
H
PME1
CH₃
H
H
acac

6′-122Y
Pt
0
6′
Ph
H
H
PME1
CH₃
H
H
— —

6′-123
Pt
1
6′
Ph
H
PME1
H
CH₃
H
H
pic

6′-123X
Pt
1
6′
Ph
H
PME1
H
CH₃
H
H
acac

6′-123Y
Pt
0
6′
Ph
H
PME1
H
CH₃
H
H
— —

6′-124
Pt
1
6′
Ph
H
H
PME2
CH₃
H
H
pic

6′-124X
Pt
1
6′
Ph
H
H
PME2
CH₃
H
H
acac

6′-124Y
Pt
0
6′
Ph
H
H
PME2
CH₃
H
H
— —

6′-125
Pt
1
6′
Ph
H
PME2
H
CH₃
H
H
pic

6′-125X
Pt
1
6′
Ph
H
PME2
H
CH₃
H
H
acac

6′-125Y
Pt
0
6′
Ph
H
PME2
H
CH₃
H
H
— —

6′-126
Pt
1
6′
Ph
H
H
MET1
CH₃
H
H
pic

6′-126X
Pt
1
6′
Ph
H
H
MET1
CH₃
H
H
acac

6′-126Y
Pt
0
6′
Ph
H
H
MET1
CH₃
H
H
— —

6′-127
Pt
1
6′
Ph
H
MET1
H
CH₃
H
H
pic

6′-127X
Pt
1
6′
Ph
H
MET1
H
CH₃
H
H
acac

6′-127Y
Pt
0
6′
Ph
H
MET1
H
CH₃
H
H
— —

6′-128
Pt
1
6′
Ph
H
H
MET2
CH₃
H
H
pic

6′-128X
Pt
1
6′
Ph
H
H
MET2
CH₃
H
H
acac

6′-128Y
Pt
0
6′
Ph
H
H
MET2
CH₃
H
H
— —

6′-129
Pt
1
6′
Ph
H
MET2
H
CH₃
H
H
pic

6′-129X
Pt
1
6′
Ph
H
MET2
H
CH₃
H
H
acac

6′-129Y
Pt
0
6′
Ph
H
MET2
H
CH₃
H
H
— —

6′-130
Pt
1
6′
Ph
H
H
EE1
CH₃
H
H
pic

6′-130X
Pt
1
6′
Ph
H
H
EE1
CH₃
H
H
acac

6′-130Y
Pt
0
6′
Ph
H
H
EE1
CH₃
H
H
— —

6′-131
Pt
1
6′
Ph
H
EE1
H
CH₃
H
H
pic

6′-131X
Pt
1
6′
Ph
H
EE1
H
CH₃
H
H
acac

6′-131Y
Pt
0
6′
Ph
H
EE1
H
CH₃
H
H
— —

6′-132
Pt
1
6′
Ph
H
H
EE2
CH₃
H
H
pic

6′-132X
Pt
1
6′
Ph
H
H
EE2
CH₃
H
H
acac

6′-132Y
Pt
0
6′
Ph
H
H
EE2
CH₃
H
H
— —

6′-133
Pt
1
6′
Ph
H
EE2
H
CH₃
H
H
pic

6′-133X
Pt
1
6′
Ph
H
EE2
H
CH₃
H
H
acac

6′-133Y
Pt
0
6′
Ph
H
EE2
H
CH₃
H
H
— —

6′-134
Pt
1
6′
Ph
H
H
MS1
CH₃
H
H
pic

6′-134X
Pt
1
6′
Ph
H
H
MS1
CH₃
H
H
acac

6′-134Y
Pt
0
6′
Ph
H
H
MS1
CH₃
H
H
— —

6′-135
Pt
1
6′
Ph
H
MS1
H
CH₃
H
H
pic

6′-135X
Pt
1
6′
Ph
H
MS1
H
CH₃
H
H
acac

6′-135Y
Pt
0
6′
Ph
H
MS1
H
CH₃
H
H
— —

6′-136
Pt
1
6′
Ph
H
H
MS2
CH₃
H
H
pic

6′-136X
Pt
1
6′
Ph
H
H
MS2
CH₃
H
H
acac

6′-136Y
Pt
0
6′
Ph
H
H
MS2
CH₃
H
H
— —

6′-137
Pt
1
6′
Ph
H
MS2
H
CH₃
H
H
pic

6′-137X
Pt
1
6′
Ph
H
MS2
H
CH₃
H
H
acac

6′-137Y
Pt
0
6′
Ph
H
MS2
H
CH₃
H
H
— —

TABLE 35

No.
M
m
BMS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹ L²

7′-1
Pt
1
7′
Ph
H
H
H
H
CH₃
H
H
pic

7′-1X
Pt
1
7′
Ph
H
H
H
H
CH₃
H
H
acac

7′-1Y
Pt
0
7′
Ph
H
H
H
H
CH₃
H
H
— —

7′-2
Pt
1
7′
Ph
H
H
H
H

^tC₄H₉
H
H
pic

7′-2X
Pt
1
7′
Ph
H
H
H
H

^tC₄H₉
H
H
acac

7′-2Y
Pt
0
7′
Ph
H
H
H
H

^tC₄H₉
H
H
— —

7′-3
Pt
1
7′
Ph
H
F
H
F
CH₃
H
H
pic

7′-3X
Pt
1
7′
Ph
H
F
H
F
CH₃
H
H
acac

7′-3Y
Pt
0
7′
Ph
H
F
H
F
CH₃
H
H
— —

7′-4
Pt
1
7′
Ph
H
F
H
F

^tC₄H₉
H
H
pic

7′-4X
Pt
1
7′
Ph
H
F
H
F

^tC₄H₉
H
H
acac

7′-4Y
Pt
0
7′
Ph
H
F
H
F

^tC₄H₉
H
H
— —

7′-5
Pt
1
7′
Ph
F
H
H
F
CH₃
H
H
pic

7′-5X
Pt
1
7′
Ph
F
H
H
F
CH₃
H
H
acac

7′-5Y
Pt
0
7′
Ph
F
H
H
F
CH₃
H
H
— —

7′-6
Pt
1
7′
Ph
F
H
H
F

^tC₄H₉
H
H
pic

7′-6X
Pt
1
7′
Ph
F
H
H
F

^tC₄H₉
H
H
acac

7′-6Y
Pt
0
7′
Ph
F
H
H
F

^tC₄H₉
H
H
— —

7′-7
Pt
1
7′
Ph
CF₃
H
CF₃
H
CH₃
H
H
pic

7′-7X
Pt
1
7′
Ph
CF₃
H
CF₃
H
CH₃
H
H
acac

7′-7Y
Pt
0
7′
Ph
CF₃
H
CF₃
H
CH₃
H
H
— —

7′-8
Pt
1
7′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

7′-8X
Pt
1
7′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

7′-8Y
Pt
0
7′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
— —

7′-9
Pt
1
7′
Ph
H
F
CF₃
H
CH₃
H
H
pic

7′-9X
Pt
1
7′
Ph
H
F
CF₃
H
CH₃
H
H
acac

7′-9Y
Pt
0
7′
Ph
H
F
CF₃
H
CH₃
H
H
— —

7′-10
Pt
1
7′
Ph
F
H
CF₃
H
CH₃
H
H
pic

7′-10X
Pt
1
7′
Ph
F
H
CF₃
H
CH₃
H
H
acac

7′-10Y
Pt
0
7′
Ph
F
H
CF₃
H
CH₃
H
H
— —

7′-11
Pt
1
7′
Ph
F
F
F
F
CH₃
H
H
pic

7′-11X
Pt
1
7′
Ph
F
F
F
F
CH₃
H
H
acac

7′-11Y
Pt
0
7′
Ph
F
F
F
F
CH₃
H
H
— —

7′-12
Pt
1
7′
Ph
H
F
H
CH₃
CH₃
H
H
pic

7′-12X
Pt
1
7′
Ph
H
F
H
CH₃
CH₃
H
H
acac

7′-12Y
Pt
0
7′
Ph
H
F
H
CH₃
CH₃
H
H
— —

7′-13
Pt
1
7′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

7′-13X
Pt
1
7′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

7′-13Y
Pt
0
7′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
— —

7′-14
Pt
1
7′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

7′-14X
Pt
1
7′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

7′-14Y
Pt
0
7′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
— —

7′-15
Pt
1
7′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-15X
Pt
1
7′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-15Y
Pt
0
7′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
— —

7′-16
Pt
1
7′
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

7′-16X
Pt
1
7′
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

7′-16Y
Pt
0
7′
Ph
H
CF₃
H
CF₃
CH₃
H
H
— —

7′-17
Pt
1
7′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

7′-17X
Pt
1
7′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

7′-17Y
Pt
0
7′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
— —

7′-18
Pt
1
7′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

7′-18X
Pt
1
7′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

7′-18Y
Pt
0
7′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
— —

7′-19
Pt
1
7′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-19X
Pt
1
7′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-19Y
Pt
0
7′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
— —

7′-20
Pt
1
7′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
pic

7′-20X
Pt
1
7′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

7′-20Y
Pt
0
7′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
— —

7′-21
Pt
1
7′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-21X
Pt
1
7′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-21Y
Pt
0
7′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
— —

7′-22
Pt
1
7′
Ph
H
CF₃
H
CH₃
CH₃
H
H
pic

7′-22X
Pt
1
7′
Ph
H
CF₃
H
CH₃
CH₃
H
H
acac

7′-22Y
Pt
0
7′
Ph
H
CF₃
H
CH₃
CH₃
H
H
— —

7′-23
Pt
1
7′
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

7′-23X
Pt
1
7′
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

7′-23Y
Pt
0
7′
Ph
H
CF₃
CF₃
H
CH₃
H
H
— —

7′-24
Pt
1
7′
Ph
H
H
NO₂
H
CH₃
H
H
pic

7′-24X
Pt
1
7′
Ph
H
H
NO₂
H
CH₃
H
H
acac

7′-24Y
Pt
0
7′
Ph
H
H
NO₂
H
CH₃
H
H
— —

7′-25
Pt
1
7′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
pic

7′-25X
Pt
1
7′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
acac

7′-25Y
Pt
0
7′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
— —

7′-26
Pt
1
7′
Ph
F
H
NO₂
H
CH₃
H
H
pic

7′-26X
Pt
1
7′
Ph
F
H
NO₂
H
CH₃
H
H
acac

7′-26Y
Pt
0
7′
Ph
F
H
NO₂
H
CH₃
H
H
— —

7′-27
Pt
1
7′
Ph
F
H
NO₂
F
CH₃
H
H
pic

7′-27X
Pt
1
7′
Ph
F
H
NO₂
F
CH₃
H
H
acac

7′-27Y
Pt
0
7′
Ph
F
H
NO₂
F
CH₃
H
H
— —

7′-28
Pt
1
7′
Ph
H
NO₂
H
NO₂
CH₃
H
H
pic

7′-28X
Pt
1
7′
Ph
H
NO₂
H
NO₂
CH₃
H
H
acac

7′-28Y
Pt
0
7′
Ph
H
NO₂
H
NO₂
CH₃
H
H
— —

7′-29
Pt
1
7′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
pic

7′-29X
Pt
1
7′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
acac

7′-29Y
Pt
0
7′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
— —

7′-30
Pt
1
7′
Ph
NO₂
H
H
NO₂
CH₃
H
H
pic

7′-30X
Pt
1
7′
Ph
NO₂
H
H
NO₂
CH₃
H
H
acac

7′-30Y
Pt
0
7′
Ph
NO₂
H
H
NO₂
CH₃
H
H
— —

7′-31
Pt
1
7′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
pic

7′-31X
Pt
1
7′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
acac

7′-31Y
Pt
0
7′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
— —

7′-32
Pt
1
7′
Ph
H
H
CF₃
H
CH₃
H
H
pic

7′-32X
Pt
1
7′
Ph
H
H
CF₃
H
CH₃
H
H
acac

7′-32Y
Pt
0
7′
Ph
H
H
CF₃
H
CH₃
H
H
— —

7′-33
Pt
1
7′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

7′-33X
Pt
1
7′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

7′-33Y
Pt
0
7′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
— —

7′-34
Pt
1
7′
Ph
H
Cl
CF₃
H
CH₃
H
H
pic

7′-34X
Pt
1
7′
Ph
H
Cl
CF₃
H
CH₃
H
H
acac

7′-34Y
Pt
0
7′
Ph
H
Cl
CF₃
H
CH₃
H
H
— —

7′-35
Pt
1
7′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
pic

7′-35X
Pt
1
7′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
acac

7′-35Y
Pt
0
7′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
— —

7′-36
Pt
1
7′
Ph
H
NO₂
H
H
CH₃
H
H
pic

7′-36X
Pt
1
7′
Ph
H
NO₂
H
H
CH₃
H
H
acac

7′-36Y
Pt
0
7′
Ph
H
NO₂
H
H
CH₃
H
H
— —

7′-37
Pt
1
7′
Ph
H
CF₃
H
H
CH₃
H
H
pic

7′-37X
Pt
1
7′
Ph
H
CF₃
H
H
CH₃
H
H
acac

7′-37Y
Pt
0
7′
Ph
H
CF₃
H
H
CH₃
H
H
— —

7′-38
Pt
1
7′
Ph
H
NO₂
H
CH₃
CH₃
H
H
pic

7′-38X
Pt
1
7′
Ph
H
NO₂
H
CH₃
CH₃
H
H
acac

7′-38Y
Pt
0
7′
Ph
H
NO₂
H
CH₃
CH₃
H
H
— —

7′-39
Pt
1
7′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
pic

7′-39X
Pt
1
7′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
acac

7′-39Y
Pt
0
7′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
— —

7′-40
Pt
1
7′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
pic

7′-40X
Pt
1
7′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
acac

7′-40Y
Pt
0
7′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
— —

7′-41
Pt
1
7′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-41X
Pt
1
7′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-41Y
Pt
0
7′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
— —

7′-42
Pt
1
7′
Ph
H
H
CH₃O
H
CH₃
H
H
pic

7′-42X
Pt
1
7′
Ph
H
H
CH₃O
H
CH₃
H
H
acac

7′-42Y
Pt
0
7′
Ph
H
H
CH₃O
H
CH₃
H
H
— —

7′-43
Pt
1
7′
Ph
H
CH₃O
H
H
CH₃
H
H
pic

7′-43X
Pt
1
7′
Ph
H
CH₃O
H
H
CH₃
H
H
acac

7′-43Y
Pt
0
7′
Ph
H
CH₃O
H
H
CH₃
H
H
— —

7′-44
Pt
1
7′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

7′-44X
Pt
1
7′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

7′-44Y
Pt
0
7′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
— —

7′-45
Pt
1
7′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

7′-45X
Pt
1
7′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

7′-45Y
Pt
0
7′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
— —

7′-46
Pt
1
7′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
pic

7′-46X
Pt
1
7′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
acac

7′-46Y
Pt
0
7′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
— —

7′-47
Pt
1
7′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
pic

7′-47X
Pt
1
7′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
acac

7′-47Y
Pt
0
7′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
— —

7′-48
Pt
1
7′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
pic

7′-48X
Pt
1
7′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
acac

7′-48Y
Pt
0
7′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
— —

7′-49
Pt
1
7′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
pic

7′-49X
Pt
1
7′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
acac

7′-49Y
Pt
0
7′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
— —

7′-50
Pt
1
7′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
pic

7′-50X
Pt
1
7′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
acac

7′-50Y
Pt
0
7′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
— —

7′-51
Pt
1
7′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
pic

7′-51X
Pt
1
7′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
acac

7′-51Y
Pt
0
7′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
— —

7′-52
Pt
1
7′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
pic

7′-52X
Pt
1
7′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
acac

7′-52Y
Pt
0
7′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
— —

7′-53
Pt
1
7′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
pic

7′-53X
Pt
1
7′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
acac

7′-53Y
Pt
0
7′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
— —

7′-54
Pt
1
7′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
pic

7′-54X
Pt
1
7′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
acac

7′-54Y
Pt
0
7′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
— —

7′-55
Pt
1
7′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
pic

7′-55X
Pt
1
7′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
acac

7′-55Y
Pt
0
7′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
— —

7′-56
Pt
1
7′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

7′-56X
Pt
1
7′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

7′-56Y
Pt
0
7′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
— —

7′-57
Pt
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
pic

7′-57X
Pt
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
acac

7′-57Y
Pt
0
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
— —

7′-58
Pt
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
pic

7′-58X
Pt
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
acac

7′-58Y
Pt
0
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
— —

7′-59
Pt
1
7′
Ph
H
H
H
COCH₃
CH₃
H
H
pic

7′-59X
Pt
1
7′
Ph
H
H
H
COCH₃
CH₃
H
H
acac

7′-59Y
Pt
0
7′
Ph
H
H
H
COCH₃
CH₃
H
H
— —

7′-60
Pt
1
7′
Ph
H
H
COCH₃
H
CH₃
H
H
pic

7′-60X
Pt
1
7′
Ph
H
H
COCH₃
H
CH₃
H
H
acac

7′-60Y
Pt
0
7′
Ph
H
H
COCH₃
H
CH₃
H
H
— —

7′-61
Pt
1
7′
Ph
H
COCH₃
H
H
CH₃
H
H
pic

7′-61X
Pt
1
7′
Ph
H
COCH₃
H
H
CH₃
H
H
acac

7′-61Y
Pt
0
7′
Ph
H
COCH₃
H
H
CH₃
H
H
— —

7′-62
Pt
1
7′
Ph
H
H
BL
CH₃
H
H
pic

7′-62X
Pt
1
7′
Ph
H
H
BL
CH₃
H
H
acac

7′-62Y
Pt
0
7′
Ph
H
H
BL
CH₃
H
H
— —

7′-63
Pt
1
7′
Ph
H
H
BL

^tC₄H₉
H
H
pic

7′-63X
Pt
1
7′
Ph
H
H
BL

^tC₄H₉
H
H
acac

7′-63Y
Pt
0
7′
Ph
H
H
BL

^tC₄H₉
H
H
— —

7′-64
Pt
1
7′
Ph
H
BL
H
CH₃
H
H
pic

7′-64X
Pt
1
7′
Ph
H
BL
H
CH₃
H
H
acac

7′-64Y
Pt
0
7′
Ph
H
BL
H
CH₃
H
H
— —

7′-65
Pt
1
7′
Ph
H
BL
H

^tC₄H₉
H
H
pic

7′-65X
Pt
1
7′
Ph
H
BL
H

^tC₄H₉
H
H
acac

7′-65Y
Pt
0
7′
Ph
H
BL
H

^tC₄H₉
H
H
— —

7′-66
Pt
1
7′
Ph
H
H
PL
CH₃
H
H
pic

7′-66X
Pt
1
7′
Ph
H
H
PL
CH₃
H
H
acac

7′-66Y
Pt
0
7′
Ph
H
H
PL
CH₃
H
H
— —

7′-67
Pt
1
7′
Ph
H
H
PL

^tC₄H₉
H
H
pic

7′-67X
Pt
1
7′
Ph
H
H
PL

^tC₄H₉
H
H
acac

7′-67Y
Pt
0
7′
Ph
H
H
PL

^tC₄H₉
H
H
— —

7′-68
Pt
1
7′
Ph
H
PL
H
CH₃
H
H
pic

7′-68X
Pt
1
7′
Ph
H
PL
H
CH₃
H
H
acac

7′-68Y
Pt
0
7′
Ph
H
PL
H
CH₃
H
H
— —

7′-69
Pt
1
7′
Ph
H
PL
H

^tC₄H₉
H
H
pic

7′-69X
Pt
1
7′
Ph
H
PL
H

^tC₄H₉
H
H
acac

7′-69Y
Pt
0
7′
Ph
H
PL
H

^tC₄H₉
H
H
— —

7′-70
Pt
1
7′
Ph
H
H
MEE1
CH₃
H
H
pic

7′-70X
Pt
1
7′
Ph
H
H
MEE1
CH₃
H
H
acac

7′-70Y
Pt
0
7′
Ph
H
H
MEE1
CH₃
H
H
— —

7′-71
Pt
1
7′
Ph
H
MEE1
H
CH₃
H
H
pic

7′-71X
Pt
1
7′
Ph
H
MEE1
H
CH₃
H
H
acac

7′-71Y
Pt
0
7′
Ph
H
MEE1
H
CH₃
H
H
— —

7′-72
Pt
1
7′
Ph
H
H
MEE2
CH₃
H
H
pic

7′-72X
Pt
1
7′
Ph
H
H
MEE2
CH₃
H
H
acac

7′-72Y
Pt
0
7′
Ph
H
H
MEE2
CH₃
H
H
— —

7′-73
Pt
1
7′
Ph
H
MEE2
H
CH₃
H
H
pic

7′-73X
Pt
1
7′
Ph
H
MEE2
H
CH₃
H
H
acac

7′-73Y
Pt
0
7′
Ph
H
MEE2
H
CH₃
H
H
— —

7′-74
Pt
1
7′
Ph
H
H
PA1
CH₃
H
H
pic

7′-74X
Pt
1
7′
Ph
H
H
PA1
CH₃
H
H
acac

7′-74Y
Pt
0
7′
Ph
H
H
PA1
CH₃
H
H
— —

7′-75
Pt
1
7′
Ph
H
PA1
H
CH₃
H
H
pic

7′-75X
Pt
1
7′
Ph
H
PA1
H
CH₃
H
H
acac

7′-75Y
Pt
0
7′
Ph
H
PA1
H
CH₃
H
H
— —

7′-76
Pt
1
7′
Ph
H
H
PA2
CH₃
H
H
pic

7′-76X
Pt
1
7′
Ph
H
H
PA2
CH₃
H
H
acac

7′-76Y
Pt
0
7′
Ph
H
H
PA2
CH₃
H
H
— —

7′-77
Pt
1
7′
Ph
H
PA2
H
CH₃
H
H
pic

7′-77X
Pt
1
7′
Ph
H
PA2
H
CH₃
H
H
acac

7′-77Y
Pt
0
7′
Ph
H
PA2
H
CH₃
H
H
— —

7′-78
Pt
1
7′
Ph
H
H
EA1
CH₃
H
H
pic

7′-78X
Pt
1
7′
Ph
H
H
EA1
CH₃
H
H
acac

7′-78Y
Pt
0
7′
Ph
H
H
EA1
CH₃
H
H
— —

7′-79
Pt
1
7′
Ph
H
EA2
H
CH₃
H
H
pic

7′-79X
Pt
1
7′
Ph
H
EA2
H
CH₃
H
H
acac

7′-79Y
Pt
0
7′
Ph
H
EA2
H
CH₃
H
H
— —

7′-80
Pt
1
7′
Ph
H
H
ME
CH₃
H
H
pic

7′-80X
Pt
1
7′
Ph
H
H
ME
CH₃
H
H
acac

7′-80Y
Pt
0
7′
Ph
H
H
ME
CH₃
H
H
— —

7′-81
Pt
1
7′
Ph
H
ME
H
CH₃
H
H
pic

7′-81X
Pt
1
7′
Ph
H
ME
H
CH₃
H
H
acac

7′-81Y
Pt
0
7′
Ph
H
ME
H
CH₃
H
H
— —

7′-82
Pt
1
7′
Ph
H
H
AT
CH₃
H
H
pic

7′-82X
Pt
1
7′
Ph
H
H
AT
CH₃
H
H
acac

7′-82Y
Pt
0
7′
Ph
H
H
AT
CH₃
H
H
— —

7′-83
Pt
1
7′
Ph
H
AT
H
CH₃
H
H
pic

7′-83X
Pt
1
7′
Ph
H
AT
H
CH₃
H
H
acac

7′-83Y
Pt
0
7′
Ph
H
AT
H
CH₃
H
H
— —

7′-84
Pt
1
7′
Ph
H
H
MES1
CH₃
H
H
pic

7′-84X
Pt
1
7′
Ph
H
H
MES1
CH₃
H
H
acac

7′-84Y
Pt
0
7′
Ph
H
H
MES1
CH₃
H
H
— —

7′-85
Pt
1
7′
Ph
H
MES1
H
CH₃
H
H
pic

7′-85X
Pt
1
7′
Ph
H
MES1
H
CH₃
H
H
acac

7′-85Y
Pt
0
7′
Ph
H
MES1
H
CH₃
H
H
— —

7′-86
Pt
1
7′
Ph
H
H
MES2
CH₃
H
H
pic

7′-86X
Pt
1
7′
Ph
H
H
MES2
CH₃
H
H
acac

7′-86Y
Pt
0
7′
Ph
H
H
MES2
CH₃
H
H
— —

7′-87
Pt
1
7′
Ph
H
MES2
H
CH₃
H
H
pic

7′-87X
Pt
1
7′
Ph
H
MES2
H
CH₃
H
H
acac

7′-87Y
Pt
0
7′
Ph
H
MES2
H
CH₃
H
H
— —

7′-88
Pt
1
7′
Ph
H
H
PS1
CH₃
H
H
pic

7′-88X
Pt
1
7′
Ph
H
H
PS1
CH₃
H
H
acac

7′-88Y
Pt
0
7′
Ph
H
H
PS1
CH₃
H
H
— —

7′-89
Pt
1
7′
Ph
H
PS1
H
CH₃
H
H
pic

7′-89X
Pt
1
7′
Ph
H
PS1
H
CH₃
H
H
acac

7′-89Y
Pt
0
7′
Ph
H
PS1
H
CH₃
H
H
— —

7′-90
Pt
1
7′
Ph
H
H
PS2
CH₃
H
H
pic

7′-90X
Pt
1
7′
Ph
H
H
PS2
CH₃
H
H
acac

7′-90Y
Pt
0
7′
Ph
H
H
PS2
CH₃
H
H
— —

7′-91
Pt
1
7′
Ph
H
PS2
H
CH₃
H
H
pic

7′-91X
Pt
1
7′
Ph
H
PS2
H
CH₃
H
H
acac

7′-91Y
Pt
0
7′
Ph
H
PS2
H
CH₃
H
H
— —

7′-92
Pt
1
7′
Ph
H
H
BAL1
CH₃
H
H
pic

7′-92X
Pt
1
7′
Ph
H
H
BAL1
CH₃
H
H
acac

7′-92Y
Pt
0
7′
Ph
H
H
BAL1
CH₃
H
H
— —

7′-93
Pt
1
7′
Ph
H
BAL1
H
CH₃
H
H
pic

7′-93X
Pt
1
7′
Ph
H
BAL1
H
CH₃
H
H
acac

7′-93Y
Pt
0
7′
Ph
H
BAL1
H
CH₃
H
H
— —

7′-94
Pt
1
7′
Ph
H
H
BAL2
CH₃
H
H
pic

7′-94X
Pt
1
7′
Ph
H
H
BAL2
CH₃
H
H
acac

7′-94Y
Pt
0
7′
Ph
H
H
BAL2
CH₃
H
H
— —

7′-95
Pt
1
7′
Ph
H
BAL2
H
CH₃
H
H
pic

7′-95X
Pt
1
7′
Ph
H
BAL2
H
CH₃
H
H
acac

7′-95Y
Pt
0
7′
Ph
H
BAL2
H
CH₃
H
H
— —

7′-96
Pt
1
7′
Ph
H
H
MEK1
CH₃
H
H
pic

7′-96X
Pt
1
7′
Ph
H
H
MEK1
CH₃
H
H
acac

7′-96Y
Pt
0
7′
Ph
H
H
MEK1
CH₃
H
H
— —

7′-97
Pt
1
7′
Ph
H
MEK1
H
CH₃
H
H
pic

7′-97X
Pt
1
7′
Ph
H
MEK1
H
CH₃
H
H
acac

7′-97Y
Pt
0
7′
Ph
H
MEK1
H
CH₃
H
H
— —

7′-98
Pt
1
7′
Ph
H
H
MEK2
CH₃
H
H
pic

7′-98X
Pt
1
7′
Ph
H
H
MEK2
CH₃
H
H
acac

7′-98Y
Pt
0
7′
Ph
H
H
MEK2
CH₃
H
H
— —

7′-99
Pt
1
7′
Ph
H
MEK2
H
CH₃
H
H
pic

7′-99X
Pt
1
7′
Ph
H
MEK2
H
CH₃
H
H
acac

7′-99Y
Pt
0
7′
Ph
H
MEK2
H
CH₃
H
H
— —

7′-100
Pt
1
7′
Ph
H
H
PAL1
CH₃
H
H
pic

7′-100X
Pt
1
7′
Ph
H
H
PAL1
CH₃
H
H
acac

7′-100Y
Pt
0
7′
Ph
H
H
PAL1
CH₃
H
H
— —

7′-101
Pt
1
7′
Ph
H
PAL1
H
CH₃
H
H
pic

7′-101X
Pt
1
7′
Ph
H
PAL1
H
CH₃
H
H
acac

7′-101Y
Pt
0
7′
Ph
H
PAL1
H
CH₃
H
H
— —

7′-102
Pt
1
7′
Ph
H
H
PAL2
CH₃
H
H
pic

7′-102X
Pt
1
7′
Ph
H
H
PAL2
CH₃
H
H
acac

7′-102Y
Pt
0
7′
Ph
H
H
PAL2
CH₃
H
H
— —

7′-103
Pt
1
7′
Ph
H
PAL2
H
CH₃
H
H
pic

7′-103X
Pt
1
7′
Ph
H
PAL2
H
CH₃
H
H
acac

7′-103Y
Pt
0
7′
Ph
H
PAL2
H
CH₃
H
H
— —

7′-104
Pt
1
7′
Ph
H
H
MMK
CH₃
H
H
pic

7′-104X
Pt
1
7′
Ph
H
H
MMK
CH₃
H
H
acac

7′-104Y
Pt
0
7′
Ph
H
H
MMK
CH₃
H
H
— —

7′-105
Pt
1
7′
Ph
H
MMK
H
CH₃
H
H
pic

7′-105X
Pt
1
7′
Ph
H
MMK
H
CH₃
H
H
acac

7′-105Y
Pt
0
7′
Ph
H
MMK
H
CH₃
H
H
— —

7′-106
Pt
1
7′
Ph
H
H
EES1
CH₃
H
H
pic

7′-106X
Pt
1
7′
Ph
H
H
EES1
CH₃
H
H
acac

7′-106Y
Pt
0
7′
Ph
H
H
EES1
CH₃
H
H
— —

7′-107
Pt
1
7′
Ph
H
EES2
H
CH₃
H
H
pic

7′-107X
Pt
1
7′
Ph
H
EES2
H
CH₃
H
H
acac

7′-107Y
Pt
0
7′
Ph
H
EES2
H
CH₃
H
H
— —

7′-108
Pt
1
7′
Ph
H
H
PAE1
CH₃
H
H
pic

7′-108X
Pt
1
7′
Ph
H
H
PAE1
CH₃
H
H
acac

7′-108Y
Pt
0
7′
Ph
H
H
PAE1
CH₃
H
H
— —

7′-109
Pt
1
7′
Ph
H
PAE2
H
CH₃
H
H
pic

7′-109X
Pt
1
7′
Ph
H
PAE2
H
CH₃
H
H
acac

7′-109Y
Pt
0
7′
Ph
H
PAE2
H
CH₃
H
H
— —

7′-110
Pt
1
7′
Ph
H
H
AME1
CH₃
H
H
pic

7′-110X
Pt
1
7′
Ph
H
H
AME1
CH₃
H
H
acac

7′-110Y
Pt
0
7′
Ph
H
H
AME1
CH₃
H
H
— —

7′-111
Pt
1
7′
Ph
H
AME1
H
CH₃
H
H
pic

7′-111X
Pt
1
7′
Ph
H
AME1
H
CH₃
H
H
acac

7′-111Y
Pt
0
7′
Ph
H
AME1
H
CH₃
H
H
— —

7′-112
Pt
1
7′
Ph
H
H
AME2
CH₃
H
H
pic

7′-112X
Pt
1
7′
Ph
H
H
AME2
CH₃
H
H
acac

7′-112Y
Pt
0
7′
Ph
H
H
AME2
CH₃
H
H
— —

7′-113
Pt
1
7′
Ph
H
AME2
H
CH₃
H
H
pic

7′-113X
Pt
1
7′
Ph
H
AME2
H
CH₃
H
H
acac

7′-113Y
Pt
0
7′
Ph
H
AME2
H
CH₃
H
H
— —

7′-114
Pt
1
7′
Ph
H
H
EAE1
CH₃
H
H
pic

7′-114X
Pt
1
7′
Ph
H
H
EAE1
CH₃
H
H
acac

7′-114Y
Pt
0
7′
Ph
H
H
EAE1
CH₃
H
H
— —

7′-115
Pt
1
7′
Ph
H
EAE1
H
CH₃
H
H
pic

7′-115X
Pt
1
7′
Ph
H
EAE1
H
CH₃
H
H
acac

7′-115Y
Pt
0
7′
Ph
H
EAE1
H
CH₃
H
H
— —

7′-116
Pt
1
7′
Ph
H
H
EAE2
CH₃
H
H
pic

7′-116X
Pt
1
7′
Ph
H
H
EAE2
CH₃
H
H
acac

7′-116Y
Pt
0
7′
Ph
H
H
EAE2
CH₃
H
H
— —

7′-117
Pt
1
7′
Ph
H
EAE2
H
CH₃
H
H
pic

7′-117X
Pt
1
7′
Ph
H
EAE2
H
CH₃
H
H
acac

7′-117Y
Pt
0
7′
Ph
H
EAE2
H
CH₃
H
H
— —

7′-118
Pt
1
7′
Ph
H
H
AAE1
CH₃
H
H
pic

7′-118X
Pt
1
7′
Ph
H
H
AAE1
CH₃
H
H
acac

7′-118Y
Pt
0
7′
Ph
H
H
AAE1
CH₃
H
H
— —

7′-119
Pt
1
7′
Ph
H
AAE1
H
CH₃
H
H
pic

7′-119X
Pt
1
7′
Ph
H
AAE1
H
CH₃
H
H
acac

7′-119Y
Pt
0
7′
Ph
H
AAE1
H
CH₃
H
H
— —

7′-120
Pt
1
7′
Ph
H
H
AAE2
CH₃
H
H
pic

7′-120X
Pt
1
7′
Ph
H
H
AAE2
CH₃
H
H
acac

7′-120Y
Pt
0
7′
Ph
H
H
AAE2
CH₃
H
H
— —

7′-121
Pt
1
7′
Ph
H
AAE2
H
CH₃
H
H
pic

7′-121X
Pt
1
7′
Ph
H
AAE2
H
CH₃
H
H
acac

7′-121Y
Pt
0
7′
Ph
H
AAE2
H
CH₃
H
H
— —

7′-122
Pt
1
7′
Ph
H
H
PME1
CH₃
H
H
pic

7′-122X
Pt
1
7′
Ph
H
H
PME1
CH₃
H
H
acac

7′-122Y
Pt
0
7′
Ph
H
H
PME1
CH₃
H
H
— —

7′-123
Pt
1
7′
Ph
H
PME1
H
CH₃
H
H
pic

7′-123X
Pt
1
7′
Ph
H
PME1
H
CH₃
H
H
acac

7′-123Y
Pt
0
7′
Ph
H
PME1
H
CH₃
H
H
— —

7′-124
Pt
1
7′
Ph
H
H
PME2
CH₃
H
H
pic

7′-124X
Pt
1
7′
Ph
H
H
PME2
CH₃
H
H
acac

7′-124Y
Pt
0
7′
Ph
H
H
PME2
CH₃
H
H
— —

7′-125
Pt
1
7′
Ph
H
PME2
H
CH₃
H
H
pic

7′-125X
Pt
1
7′
Ph
H
PME2
H
CH₃
H
H
acac

7′-125Y
Pt
0
7′
Ph
H
PME2
H
CH₃
H
H
— —

7′-126
Pt
1
7′
Ph
H
H
MET1
CH₃
H
H
pic

7′-126X
Pt
1
7′
Ph
H
H
MET1
CH₃
H
H
acac

7′-126Y
Pt
0
7′
Ph
H
H
MET1
CH₃
H
H
— —

7′-127
Pt
1
7′
Ph
H
MET1
H
CH₃
H
H
pic

7′-127X
Pt
1
7′
Ph
H
MET1
H
CH₃
H
H
acac

7′-127Y
Pt
0
7′
Ph
H
MET1
H
CH₃
H
H
— —

7′-128
Pt
1
7′
Ph
H
H
MET2
CH₃
H
H
pic

7′-128X
Pt
1
7′
Ph
H
H
MET2
CH₃
H
H
acac

7′-128Y
Pt
0
7′
Ph
H
H
MET2
CH₃
H
H
— —

7′-129
Pt
1
7′
Ph
H
MET2
H
CH₃
H
H
pic

7′-129X
Pt
1
7′
Ph
H
MET2
H
CH₃
H
H
acac

7′-129Y
Pt
0
7′
Ph
H
MET2
H
CH₃
H
H
— —

7′-130
Pt
1
7′
Ph
H
H
EE1
CH₃
H
H
pic

7′-130X
Pt
1
7′
Ph
H
H
EE1
CH₃
H
H
acac

7′-130Y
Pt
0
7′
Ph
H
H
EE1
CH₃
H
H
— —

7′-131
Pt
1
7′
Ph
H
EE1
H
CH₃
H
H
pic

7′-131X
Pt
1
7′
Ph
H
EE1
H
CH₃
H
H
acac

7′-131Y
Pt
0
7′
Ph
H
EE1
H
CH₃
H
H
— —

7′-132
Pt
1
7′
Ph
H
H
EE2
CH₃
H
H
pic

7′-132X
Pt
1
7′
Ph
H
H
EE2
CH₃
H
H
acac

7′-132Y
Pt
0
7′
Ph
H
H
EE2
CH₃
H
H
— —

7′-133
Pt
1
7′
Ph
H
EE2
H
CH₃
H
H
pic

7′-133X
Pt
1
7′
Ph
H
EE2
H
CH₃
H
H
acac

7′-133Y
Pt
0
7′
Ph
H
EE2
H
CH₃
H
H
— —

7′-134
Pt
1
7′
Ph
H
H
MS1
CH₃
H
H
pic

7′-134X
Pt
1
7′
Ph
H
H
MS1
CH₃
H
H
acac

7′-134Y
Pt
0
7′
Ph
H
H
MS1
CH₃
H
H
— —

7′-135
Pt
1
7′
Ph
H
MS1
H
CH₃
H
H
pic

7′-135X
Pt
1
7′
Ph
H
MS1
H
CH₃
H
H
acac

7′-135Y
Pt
0
7′
Ph
H
MS1
H
CH₃
H
H
— —

7′-136
Pt
1
7′
Ph
H
H
MS2
CH₃
H
H
pic

7′-136X
Pt
1
7′
Ph
H
H
MS2
CH₃
H
H
acac

7′-136Y
Pt
0
7′
Ph
H
H
MS2
CH₃
H
H
— —

7′-137
Pt
1
7′
Ph
H
MS2
H
CH₃
H
H
pic

7′-137X
Pt
1
7′
Ph
H
MS2
H
CH₃
H
H
acac

7′-137Y
Pt
0
7′
Ph
H
MS2
H
CH₃
H
H
— —

embedded image

TABLE 36

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1′-119
Pt
1
1′
Nap1
—
—
H
H
H
H
H
pic

1′-119X
Pt
1
1′
Nap1
—
—
H
H
H
H
H
acac

1′-119Y
Pt
0
1′
Nap1
—
—
H
H
H
H
H
—
—

1′-120
Pt
1
1′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

1′-120X
Pt
1
1′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

1′-120Y
Pt
0
1′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

1′-121
Pt
1
1′
Nap1
—
—
CH₃
H
H
H
H
pic

1′-121X
Pt
1
1′
Nap1
—
—
CH₃
H
H
H
H
acac

1′-121Y
Pt
0
1′
Nap1
—
—
CH₃
H
H
H
H
—
—

1′-122
Pt
1
1′
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-122X
Pt
1
1′
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-122Y
Pt
0
1′
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-123
Pt
1
1′
Nap1
—
—
CH₃
CH₃
H
H
H
pic

1′-123X
Pt
1
1′
Nap1
—
—
CH₃
CH₃
H
H
H
acac

1′-123Y
Pt
0
1′
Nap1
—
—
CH₃
CH₃
H
H
H
—
—

1′-124
Pt
1
1′
Nap1
—
—
H
CH₃
H
H
H
pic

1′-124X
Pt
1
1′
Nap1
—
—
H
CH₃
H
H
H
acac

1′-124Y
Pt
0
1′
Nap1
—
—
H
CH₃
H
H
H
—
—

1′-125
Pt
1
1′
Nap2
—
—
H
H
H
H
H
pic

1′-125X
Pt
1
1′
Nap2
—
—
H
H
H
H
H
acac

1′-125Y
Pt
0
1′
Nap2
—
—
H
H
H
H
H
—
—

1′-126
Pt
1
1′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

1′-126X
Pt
1
1′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

1′-126Y
Pt
0
1′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

1′-127
Pt
1
1′
Nap2
—
—
CH₃
H
H
H
H
pic

1′-127X
Pt
1
1′
Nap2
—
—
CH₃
H
H
H
H
acac

1′-127Y
Pt
0
1′
Nap2
—
—
CH₃
H
H
H
H
—
—

1′-128
Pt
1
1′
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-128X
Pt
1
1′
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-128Y
Pt
0
1′
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-129
Pt
1
1′
Nap2
—
—
CH₃
CH₃
H
H
H
pic

1′-129X
Pt
1
1′
Nap2
—
—
CH₃
CH₃
H
H
H
acac

1′-129Y
Pt
0
1′
Nap2
—
—
CH₃
CH₃
H
H
H
—
—

1′-130
Pt
1
1′
Nap2
—
—
H
CH₃
H
H
H
pic

1′-130X
Pt
1
1′
Nap2
—
—
H
CH₃
H
H
H
acac

1′-130Y
Pt
0
1′
Nap2
—
—
H
CH₃
H
H
H
—
—

1′-131
Pt
1
1′
Nap3
—
—
H
H
H
H
H
pic

1′-131X
Pt
1
1′
Nap3
—
—
H
H
H
H
H
acac

1′-131Y
Pt
0
1′
Nap3
—
—
H
H
H
H
H
—
—

1′-132
Pt
1
1′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

1′-132X
Pt
1
1′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

1′-132Y
Pt
0
1′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

1′-133
Pt
1
1′
Nap3
—
—
CH₃
H
H
H
H
pic

1′-133X
Pt
1
1′
Nap3
—
—
CH₃
H
H
H
H
acac

1′-133Y
Pt
0
1′
Nap3
—
—
CH₃
H
H
H
H
—
—

1′-134
Pt
1
1′
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-134X
Pt
1
1′
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-134Y
Pt
0
1′
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-135
Pt
1
1′
Nap3
—
—
CH₃
CH₃
H
H
H
pic

1′-135X
Pt
1
1′
Nap3
—
—
CH₃
CH₃
H
H
H
acac

1′-135Y
Pt
0
1′
Nap3
—
—
CH₃
CH₃
H
H
H
—
—

1′-136
Pt
1
1′
Nap3
—
—
H
CH₃
H
H
H
pic

1′-136X
Pt
1
1′
Nap3
—
—
H
CH₃
H
H
H
acac

1′-136Y
Pt
0
1′
Nap3
—
—
H
CH₃
H
H
H
—
—

1′-137
Pt
1
1′
TB
—
—
H
H
H
H
H
pic

1′-137X
Pt
1
1′
TB
—
—
H
H
H
H
H
acac

1′-137Y
Pt
0
1′
TB
—
—
H
H
H
H
H
—
—

1′-138
Pt
1
1′
TB
—
—

^tC₄H₉
H
H
H
H
pic

1′-138X
Pt
1
1′
TB
—
—

^tC₄H₉
H
H
H
H
acac

1′-138Y
Pt
0
1′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

1′-139
Pt
1
1′
TB
—
—
CH₃
H
H′
H
H
pic

1′-139X
Pt
1
1′
TB
—
—
CH₃
H
H
H
H
acac

1′-139Y
Pt
0
1′
TB
—
—
CH₃
H
H
H
H
—
—

1′-140
Pt
1
1′
TB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-140X
Pt
1
1′
TB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-140Y
Pt
0
1′
TB
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-141
Pt
1
1′
TB
—
—
CH₃
CH₃
H
H
H
pic

1′-141X
Pt
1
1′
TB
—
—
CH₃
CH₃
H
H
H
acac

1′-141Y
Pt
0
1′
TB
—
—
CH₃
CH₃
H
H
H
—
—

1′-142
Pt
1
1′
TB
—
—
H
CH₃
H
H
H
pic

1′-142X
Pt
1
1′
TB
—
—
H
CH₃
H
H
H
acac

1′-142Y
Pt
0
1′
TB
—
—
H
CH₃
H
H
H
—
—

1′-143
Pt
1
1′
TF
—
—
H
H
H
H
H
pic

1′-143X
Pt
1
1′
TF
—
—
H
H
H
H
H
acac

1′-143Y
Pt
0
1′
TF
—
—
H
H
H
H
H
—
—

1′-144
Pt
1
1′
TF
—
—

^tC₄H₉
H
H
H
H
pic

1′-144X
Pt
1
1′
TF
—
—

^tC₄H₉
H
H
H
H
acac

1′-144Y
Pt
0
1′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

1′-145
Pt
1
1′
TF
—
—
CH₃
H
H
H
H
pic

1′-145X
Pt
1
1′
TF
—
—
CH₃
H
H
H
H
acac

1′-145Y
Pt
0
1′
TF
—
—
CH₃
H
H
H
H
—
—

1′-146
Pt
1
1′
TF
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-146X
Pt
1
1′
TF
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-146Y
Pt
0
1′
TF
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-147
Pt
1
1′
TF
—
—
CH₃
CH₃
H
H
H
pic

1′-147X
Pt
1
1′
TF
—
—
CH₃
CH₃
H
H
H
acac

1′-147Y
Pt
0
1′
TF
—
—
CH₃
CH₃
H
H
H
—
—

1′-148
Pt
1
1′
TF
—
—
H
CH₃
H
H
H
pic

1′-148X
Pt
1
1′
TF
—
—
H
CH₃
H
H
H
acac

1′-148Y
Pt
0
1′
TF
—
—
H
CH₃
H
H
H
—
—

1′-149
Pt
1
1′
OB
—
—
H
H
H
H
H
pic

1′-149X
Pt
1
1′
OB
—
—
H
H
H
H
H
acac

1′-149Y
Pt
1′
1′
OB
—
—
H
H
H
H
H
—
—

1′-150
Pt
1
1′
OB
—
—

^tC₄H₉
H
H
H
H
pic

1′-150X
Pt
1
1′
OB
—
—

^tC₄H₉
H
H
H
H
acac

1′-150Y
Pt
0
1′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

1′-151
Pt
1
1′
OB
—
—
CH₃
H
H
H
H
pic

1′-151X
Pt
1
1′
OB
—
—
CH₃
H
H
H
H
acac

1′-151Y
Pt
0
1′
OB
—
—
CH₃
H
H
H
H
—
—

1′-152
Pt
1
1′
OB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-152X
Pt
1
1′
OB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-152Y
Pt
0
1′
OB
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-153
Pt
1
1′
OB
—
—
CH₃
CH₃
H
H
H
pic

1′-153X
Pt
1
1′
OB
—
—
CH₃
CH₃
H
H
H
acac

1′-153Y
Pt
0
1′
OB
—
—
CH₃
CH₃
H
H
H
—
—

1′-154
Pt
1
1′
OB
—
—
H
CH₃
H
H
H
pic

1′-154X
Pt
1
1′
OB
—
—
H
CH₃
H
H
H
acac

1′-154Y
Pt
0
1′
OB
—
—
H
CH₃
H
H
H
—
—

1′-155
Pt
1
1′
Fu
—
—
H
H
H
H
H
pic

1′-155X
Pt
1
1′
Fu
—
—
H
H
H
H
H
acac

1′-155Y
Pt
0
1′
Fu
—
—
H
H
H
H
H
—
—

1′-156
Pt
1
1′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

1′-156X
Pt
1
1′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

1′-156Y
Pt
0
1′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

1′-157
Pt
1
1′
Fu
—
—
CH₃
H
H
H
H
pic

1′-157X
Pt
1
1′
Fu
—
—
CH₃
H
H
H
H
acac

1′-157Y
Pt
0
1′
Fu
—
—
CH₃
H
H
H
H
—
—

1′-158
Pt
1
1′
Fu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-158X
Pt
1
1′
Fu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-158Y
Pt
0
1′
Fu
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-159
Pt
1
1′
Fu
—
—
CH₃
CH₃
H
H
H
pic

1′-159X
Pt
1
1′
Fu
—
—
CH₃
CH₃
H
H
H
acac

1′-159Y
Pt
0
1′
Fu
—
—
CH₃
CH₃
H
H
H
—
—

1′-160
Pt
1
1′
Fu
—
—
H
CH₃
H
H
H
pic

1′-160X
Pt
1
1′
Fu
—
—
H
CH₃
H
H
H
acac

1′-160Y
Pt
0
1′
Fu
—
—
H
CH₃
H
H
H
—
—

1′-161
Pt
1
1′
Fl
—
—
H
H
H
H
H
pic

1′-161X
Pt
1
1′
Fl
—
—
H
H
H
H
H
acac

1′-161Y
Pt
0
1′
Fl
—
—
H
H
H
H
H
—
—

1′-162
Pt
1
1′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

1′-162X
Pt
1
1′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

1′-162Y
Pt
0
1′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

1′-163
Pt
1
1′
Fl
—
—
CH₃
H
H
H
H
pic

1′-163X
Pt
1
1′
Fl
—
—
CH₃
H
H
H
H
acac

1′-163Y
Pt
0
1′
Fl
—
—
CH₃
H
H
H
H
—
—

1′-164
Pt
1
1′
Fl
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-164X
Pt
1
1′
Fl
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-164Y
Pt
0
1′
Fl
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-165
Pt
1
1′
Fl
—
—
CH₃
CH₃
H
H
H
pic

1′-165X
Pt
1
1′
Fl
—
—
CH₃
CH₃
H
H
H
acac

1′-165Y
Pt
0
1′
Fl
—
—
CH₃
CH₃
H
H
H
—
—

1′-166
Pt
1
1′
Fl
—
—
H
CH₃
H
H
H
pic

1′-166X
Pt
1
1′
Fl
—
—
H
CH₃
H
H
H
acac

1′-166Y
Pt
0
1′
Fl
—
—
H
CH₃
H
H
H
—
—

1′-167
Pt
1
1′
Bz
—
—
H
H
H
H
H
pic

1′-167X
Pt
1
1′
Bz
—
—
H
H
H
H
H
acac

1′-167Y
Pt
0
1′
Bz
—
—
H
H
H
H
H
—
—

1′-168
Pt
1
1′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

1′-168X
Pt
1
1′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

1′-168Y
Pt
0
1′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

1′-169
Pt
1
1′
Bz
—
—
CH₃
H
H
H
H
pic

1′-169X
Pt
1
1′
Bz
—
—
CH₃
H
H
H
H
acac

1′-169Y
Pt
0
1′
Bz
—
—
CH₃
H
H
H
H
—
—

1′-170
Pt
1
1′
Bz
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-170X
Pt
1
1′
Bz
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-170Y
Pt
0
1′
Bz
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-171
Pt
1
1′
Bz
—
—
CH₃
CH₃
H
H
H
pic

1′-171X
Pt
1
1′
Bz
—
—
CH₃
CH₃
H
H
H
acac

1′-171Y
Pt
0
1′
Bz
—
—
CH₃
CH₃
H
H
H
—
—

1′-172
Pt
1
1′
Bz
—
—
H
CH₃
H
H
H
pic

1′-172X
Pt
1
1′
Bz
—
—
H
CH₃
H
H
H
acac

1′-172Y
Pt
0
1′
Bz
—
—
H
CH₃
H
H
H
—
—

1′-173
Pt
1
1′
Qu
—
—
H
H
H
H
H
pic

1′-173X
Pt
1
1′
Qu
—
—
H
H
H
H
H
acac

1′-173Y
Pt
0
1′
Qu
—
—
H
H
H
H
H
—
—

1′-174
Pt
1
1′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

1′-174X
Pt
1
1′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

1′-174Y
Pt
0
1′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

1′-175
Pt
1
1′
Qu
—
—
CH₃
H
H
H
H
pic

1′-175X
Pt
1
1′
Qu
—
—
CH₃
H
H
H
H
acac

1′-175Y
Pt
0
1′
Qu
—
—
CH₃
H
H
H
H
—
—

1′-176
Pt
1
1′
Qu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′-176X
Pt
1
1′
Qu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′-176Y
Pt
0
1′
Qu
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′-177
Pt
1
1′
Qu
—
—
CH₃
CH₃
H
H
H
pic

1′-177X
Pt
1
1′
Qu
—
—
CH₃
CH₃
H
H
H
acac

1′-177Y
Pt
0
1′
Qu
—
—
CH₃
CH₃
H
H
H
—
—

1′-178
Pt
1
1′
Qu
—
—
H
CH₃
H
H
H
pic

1′-178X
Pt
1
1′
Qu
—
—
H
CH₃
H
H
H
acac

1′-178Y
Pt
0
1′
Qu
—
—
H
CH₃
H
H
H
—
—

1′-179
Pt
1
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

1′-179X
Pt
1
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

1′-179Y
Pt
0
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

1′-180
Pt
1
1′
OL
H

^tC₄H₉
H
H
H
H
H
pic

1′-180X
Pt
1
1′
OL
H

^tC₄H₉
H
H
H
H
H
acac

1′-180Y
Pt
0
1′
OL
H

^tC₄H₉
H
H
H
H
H
—
—

1′-181
Pt
1
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

1′-181X
Pt
1
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

1′-181Y
Pt
0
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

1′-182
Pt
1
1′
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

1′-182X
Pt
1
1
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

1′-182Y
Pt
0
1′
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

′-183
Pt
1
1′
OL
H
H
H
H
H
H
H
pic

1′-183X
Pt
1
1′
OL
H
H
H
H
H
H
H
acac

1′-183Y
Pt
0
1′
OL
H
H
H
H
H
H
H
—
—

1′-184
Pt
1
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

1′-184X
Pt
1
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

1′-184Y
Pt
0
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

1′-185
Pt
1
1′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

1′-185X
Pt
1
1′
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

1′-185Y
Pt
0
1′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

1′-186
Pt
1
1′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

1′-186X
Pt
1
1′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

1′-186Y
Pt
0
1′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 37

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2′-119
Pt
1
2′
Nap1
—
—
H
H
H
H
H
pic

2′-119X
Pt
1
2′
Nap1
—
—
H
H
H
H
H
acac

2′-119Y
Pt
0
2′
Nap1
—
—
H
H
H
H
H
—
—

2′-120
Pt
1
2′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

2′-120X
Pt
1
2′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

2′-120Y
Pt
0
2′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

2′-121
Pt
1
2′
Nap1
—
—
CH₃
H
H
H
H
pic

2′-121X
Pt
1
2′
Nap1
—
—
CH₃
H
H
H
H
acac

2′-121Y
Pt
0
2′
Nap1
—
—
CH₃
H
H
H
H
—
—

2′-122
Pt
1
2′
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-122X
Pt
1
2′
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-122Y
Pt
0
2′
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-123
Pt
1
2′
Nap1
—
—
CH₃
H
H
CH₃
H
pic

2′-123X
Pt
1
2′
Nap1
—
—
CH₃
H
H
CH₃
H
acac

2′-123Y
Pt
0
2′
Nap1
—
—
CH₃
H
H
CH₃
H
—
—

2′-124
Pt
1
2′
Nap1
—
—
H
H
H
CH₃
H
pic

2′-124X
Pt
1
2′
Nap1
—
—
H
H
H
CH₃
H
acac

2′-124Y
Pt
0
2′
Nap1
—
—
H
H
H
CH₃
H
—
—

2′-125
Pt
1
2′
Nap2
—
—
H
H
H
H
H
pic

2′-125X
Pt
1
2′
Nap2
—
—
H
H
H
H
H
acac

2′-125Y
Pt
0
2′
Nap2
—
—
H
H
H
H
H
—
—

2′-126
Pt
1
2′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

2′-126X
Pt
1
2′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

2′-126Y
Pt
0
2′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

2′-127
Pt
1
2′
Nap2
—
—
CH₃
H
H
H
H
pic

2′-127X
Pt
1
2′
Nap2
—
—
CH₃
H
H
H
H
acac

2′-127Y
Pt
0
2′
Nap2
—
—
CH₃
H
H
H
H
—
—

2′-128
Pt
1
2′
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-128X
Pt
1
2′
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-128Y
Pt
0
2′
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-129
Pt
1
2′
Nap2
—
—
CH₃
H
H
CH₃
H
pic

2′-129X
Pt
1
2′
Nap2
—
—
CH₃
H
H
CH₃
H
acac

2′-129Y
Pt
0
2′
Nap2
—
—
CH₃
H
H
CH₃
H
—
—

2′-130
Pt
1
2′
Nap2
—
—
H
H
H
CH₃
H
pic

2′-130X
Pt
1
2′
Nap2
—
—
H
H
H
CH₃
H
acac

2′-130Y
Pt
0
2′
Nap2
—
—
H
H
H
CH₃
H
—
—

2′-131
Pt
1
2′
Nap3
—
—
H
H
H
H
H
pic

2′-131X
Pt
1
2′
Nap3
—
—
H
H
H
H
H
acac

2′-131Y
Pt
0
2′
Nap3
—
—
H
H
H
H
H
—
—

2′-132
Pt
1
2′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

2′-132X
Pt
1
2′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

2′-132Y
Pt
0
2′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

2′-133
Pt
1
2′
Nap3
—
—
CH₃
H
H
H
H
pic

2′-133X
Pt
1
2′
Nap3
—
—
CH₃
H
H
H
H
acac

2′-133Y
Pt
0
2′
Nap3
—
—
CH₃
H
H
H
H
—
—

2′-134
Pt
1
2′
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-134X
Pt
1
2′
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-134Y
Pt
0
2′
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-135
Pt
1
2′
Nap3
—
—
CH₃
H
H
CH₃
H
pic

2′-135X
Pt
1
2′
Nap3
—
—
CH₃
H
H
CH₃
H
acac

2′-135Y
Pt
0
2′
Nap3
—
—
CH₃
H
H
CH₃
H
—
—

2′-136
Pt
1
2′
Nap3
—
—
H
H
H
CH₃
H
pic

2′-136X
Pt
1
2′
Nap3
—
—
H
H
H
CH₃
H
acac

2′-136Y
Pt
0
2′
Nap3
—
—
H
H
H
CH₃
H
—
—

2′-137
Pt
1
2′
TB
—
—
H
H
H
H
H
pic

2′-137X
Pt
1
2′
TB
—
—
H
H
H
H
H
acac

2′-137Y
Pt
0
2′
TB
—
—
H
H
H
H
H
—
—

2′-138
Pt
1
2′
TB
—
—

^tC₄H₉
H
H
H
H
pic

2′-138X
Pt
1
2′
TB
—
—

^tC₄H₉
H
H
H
H
acac

2′-138Y
Pt
0
2′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

2′-139
Pt
1
2′
TB
—
—
CH₃
H
H
H
H
pic

2′-139X
Pt
1
2′
TB
—
—
CH₃
H
H
H
H
acac

2′-139Y
Pt
0
2′
TB
—
—
CH₃
H
H
H
H
—
—

2′-140
Pt
1
2′
TB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-140X
Pt
1
2′
TB
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-140Y
Pt
0
2′
TB
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-141
Pt
1
2′
TB
—
—
CH₃
H
H
CH₃
H
pic

2′-141X
Pt
1
2′
TB
—
—
CH₃
H
H
CH₃
H
acac

2′-141Y
Pt
0
2′
TB
—
—
CH₃
H
H
CH₃
H
—
—

2′-142
Pt
1
2′
TB
—
—
H
H
H
CH₃
H
pic

2′-142X
Pt
1
2′
TB
—
—
H
H
H
CH₃
H
acac

2′-142Y
Pt
0
2′
TB
—
—
H
H
H
CH₃
H
—
—

2′-143
Pt
1
2′
TF
—
—
H
H
H
H
H
pic

2′-143X
Pt
1
2′
TF
—
—
H
H
H
H
H
acac

2′-143Y
Pt
0
2′
TF
—
—
H
H
H
H
H
—
—

2′-144
Pt
1
2′
TF
—
—

^tC₄H₉
H
H
H
H
pic

2′-144X
Pt
1
2′
TF
—
—

^tC₄H₉
H
H
H
H
acac

2′-144Y
Pt
0
2′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

2′-145
Pt
1
2′
TF
—
—
CH₃
H
H
H
H
pic

2′-145X
Pt
1
2′
TF
—
—
CH₃
H
H
H
H
acac

2′-145Y
Pt
0
2′
TF
—
—
CH₃
H
H
H
H
—
—

2′-146
Pt
1
2′
TF
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-146X
Pt
1
2′
TF
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-146Y
Pt
0
2′
TF
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-147
Pt
1
2′
TF
—
—
CH₃
H
H
CH₃
H
pic

2′-147X
Pt
1
2′
TF
—
—
CH₃
H
H
CH₃
H
acac

2′-147Y
Pt
0
2′
TF
—
—
CH₃
H
H
CH₃
H
—
—

2′-148
Pt
1
2′
TF
—
—
H
H
H
CH₃
H
pic

2′-148X
Pt
1
2′
TF
—
—
H
H
H
CH₃
H
acac

2′-148Y
Pt
0
2′
TF
—
—
H
H
H
CH₃
H
—
—

2′-149
Pt
1
2′
OB
—
—
H
H
H
H
H
pic

2′-149X
Pt
1
2′
OB
—
—
H
H
H
H
H
acac

2′-149Y
Pt
0
2′
OB
—
—
H
H
H
H
H
—
—

2′-150
Pt
1
2′
OB
—
—

^tC₄H₉
H
H
H
H
pic

2′-150X
Pt
1
2′
OB
—
—

^tC₄H₉
H
H
H
H
acac

2′-150Y
Pt
0
2′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

2′-151
Pt
1
2′
OB
—
—
CH₃
H
H
H
H
pic

2′-151X
Pt
1
2′
OB
—
—
CH₃
H
H
H
H
acac

2′-151Y
Pt
0
2′
OB
—
—
CH₃
H
H
H
H
—
—

2′-152
Pt
1
2′
OB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-152X
Pt
1
2′
OB
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-152Y
Pt
0
2′
OB
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-153
Pt
1
2′
OB
—
—
CH₃
H
H
CH₃
H
pic

2′-153X
Pt
1
2′
OB
—
—
CH₃
H
H
CH₃
H
acac

2′-153Y
Pt
0
2′
OB
—
—
CH₃
H
H
CH₃
H
—
—

2′-154
Pt
1
2′
OB
—
—
H
H
H
CH₃
H
pic

2′-154X
Pt
1
2′
OB
—
—
H
H
H
CH₃
H
acac

2′-154Y
Pt
0
2′
OB
—
—
H
H
H
CH₃
H
—
—

2′-155
Pt
1
2′
Fu
—
—
H
H
H
H
H
pic

2′-155X
Pt
1
2′
Fu
—
—
H
H
H
H
H
acac

2′-155Y
Pt
0
2′
Fu
—
—
H
H
H
H
H
—
—

2′-156
Pt
1
2′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

2′-156X
Pt
1
2′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

2′-156Y
Pt
0
2′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

2′-157
Pt
1
2′
Fu
—
—
CH₃
H
H
H
H
pic

2′-157X
Pt
1
2′
Fu
—
—
CH₃
H
H
H
H
acac

2′-157Y
Pt
0
2′
Fu
—
—
CH₃
H
H
H
H
—
—

2′-158
Pt
1
2′
Fu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-158X
Pt
1
2′
Fu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-158Y
Pt
0
2′
Fu
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-159
Pt
1
2′
Fu
—
—
CH₃
H
H
CH₃
H
pic

2′-159X
Pt
1
2′
Fu
—
—
CH₃
H
H
CH₃
H
acac

2′-159Y
Pt
0
2′
Fu
—
—
CH₃
H
H
CH₃
H
—
—

2′-160
Pt
1
2′
Fu
—
—
H
H
H
CH₃
H
pic

2′-160X
Pt
1
2′
Fu
—
—
H
H
H
CH₃
H
acac

2′-160Y
Pt
0
2′
Fu
—
—
H
H
H
CH₃
H
—
—

2′-161
Pt
1
2′
Fl
—
—
H
H
H
H
H
pic

2′-161X
Pt
1
2′
Fl
—
—
H
H
H
H
H
acac

2′-161Y
Pt
0
2′
Fl
—
—
H
H
H
H
H
—
—

2′-162
Pt
1
2′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

2′-162X
Pt
1
2′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

2′-162Y
Pt
0
2′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

2′-163
Pt
1
2′
Fl
—
—
CH₃
H
H
H
H
pic

2′-163X
Pt
1
2′
Fl
—
—
CH₃
H
H
H
H
acac

2′-163Y
Pt
0
2′
Fl
—
—
CH₃
H
H
H
H
—
—

2′-164
Pt
1
2′
Fl
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-164X
Pt
1
2′
Fl
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-164Y
Pt
0
2′
Fl
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-165
Pt
1
2′
Fl
—
—
CH₃
H
H
CH₃
H
pic

2′-165X
Pt
1
2′
Fl
—
—
CH₃
H
H
CH₃
H
acac

2′-165Y
Pt
0
2′
Fl
—
—
CH₃
H
H
CH₃
H
—
—

2′-166
Pt
1
2′
Fl
—
—
H
H
H
CH₃
H
pic

2′-166X
Pt
1
2′
Fl
—
—
H
H
H
CH₃
H
acac

2′-166Y
Pt
0
2′
Fl
—
—
H
H
H
CH₃
H
—
—

2′-167
Pt
1
2′
Bz
—
—
H
H
H
H
H
pic

2′-167X
Pt
1
2′
Bz
—
—
H
H
H
H
H
acac

2′-167Y
Pt
0
2′
Bz
—
—
H
H
H
H
H
—
—

2′-168
Pt
1
2′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

2′-168X
Pt
1
2′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

2′-168Y
Pt
0
2′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

2′-169
Pt
1
2′
Bz
—
—
CH₃
H
H
H
H
pic

2′-169X
Pt
1
2′
Bz
—
—
CH₃
H
H
H
H
acac

2′-169Y
Pt
0
2′
Bz
—
—
CH₃
H
H
H
H
—
—

2′-170
Pt
1
2′
Bz
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-170X
Pt
1
2′
Bz
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-170Y
Pt
0
2′
Bz
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-171
Pt
1
2′
Bz
—
—
CH₃
H
H
CH₃
H
pic

2′-171X
Pt
1
2′
Bz
—
—
CH₃
H
H
CH₃
H
acac

2′-171Y
Pt
0
2′
Bz
—
—
CH₃
H
H
CH₃
H
—
—

2′-172
Pt
1
2′
Bz
—
—
H
H
H
CH₃
H
pic

2′-172X
Pt
1
2′
Bz
—
—
H
H
H
CH₃
H
acac

2′-172Y
Pt
0
2′
Bz
—
—
H
H
H
CH₃
H
—
—

2′-173
Pt
1
2′
Qu
—
—
H
H
H
H
H
pic

2′-173X
Pt
1
2′
Qu
—
—
H
H
H
H
H
acac

2′-173Y
Pt
0
2′
Qu
—
—
H
H
H
H
H
—
—

2′-174
Pt
1
2′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

2′-174X
Pt
1
2′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

2′-174Y
Pt
0
2′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

2′-175
Pt
1
2′
Qu
—
—
CH₃
H
H
H
H
pic

2′-175X
Pt
1
2′
Qu
—
—
CH₃
H
H
H
H
acac

2′-175Y
Pt
0
2′
Qu
—
—
CH₃
H
H
H
H
—
—

2′-176
Pt
1
2′
Qu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′-176X
Pt
1
2′
Qu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′-176Y
Pt
0
2′
Qu
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′-177
Pt
1
2′
Qu
—
—
CH₃
H
H
CH₃
H
pic

2′-177X
Pt
1
2′
Qu
—
—
CH₃
H
H
CH₃
H
acac

2′-177Y
Pt
0
2′
Qu
—
—
CH₃
H
H
CH₃
H
—
—

2′-178
Pt
1
2′
Qu
—
—
H
H
H
CH₃
H
pic

2′-178X
Pt
1
2′
Qu
—
—
H
H
H
CH₃
H
acac

2′-178Y
Pt
0
2′
Qu
—
—
H
H
H
CH₃
H
—
—

2′-179
Pt
1
2′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

2′-179X
Pt
1
2′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

2′-179Y
Pt
0
2′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

2′-180
Pt
1
2′
OL
H

^tC₄H₉
H
H
H
H
H
pic

2′-180X
Pt
1
2′
OL
H

^tC₄H₉
H
H
H
H
H
acac

2′-180Y
Pt
0
2′
OL
H

^tC₄H₉
H
H
H
H
H
—
—

2′-181
Pt
1
2′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

2′-181X
Pt
1
2′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

2′-181Y
Pt
0
2′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

2′-182
Pt
1
2′
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

2′-182X
Pt
1
2′
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

2′-182Y
Pt
0
2′
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

2′-183
Pt
1
2′
OL
H
H
H
H
H
H
H
pic

2′-183X
Pt
1
2′
OL
H
H
H
H
H
H
H
acac

2′-183Y
Pt
0
2′
OL
H
H
H
H
H
H
H
—
—

2′-184
Pt
1
2′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

2′-184X
Pt
1
2′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

2′-184Y
Pt
0
2′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

2′-185
Pt
1
2′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

2′-185X
Pt
1
2′
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

2′-185Y
Pt
0
2′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

2′-186
Pt
1
2′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

2′-186X
Pt
1
2′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

2′-186Y
Pt
0
2′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 38

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3′-117
Pt
1
3′
Nap1
—
—
H
H
H
H
H
pic

3′-117X
Pt
1
3′
Nap1
—
—
H
H
H
H
H
acac

3′-117Y
Pt
0
3′
Nap1
—
—
H
H
H
H
H
—
—

3′-118
Pt
1
3′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

3′-118X
Pt
1
3′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

3′-118Y
Pt
0
3′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

3′-119
Pt
1
3′
Nap1
—
—
CH₃
H
H
H
H
pic

3′-119X
Pt
1
3′
Nap1
—
—
CH₃
H
H
H
H
acac

3′-119Y
Pt
0
3′
Nap1
—
—
CH₃
H
H
H
H
—
—

3′-120
Pt
1
3′
Nap2
—
—
H
H
H
H
H
pic

3′-120X
Pt
1
3′
Nap2
—
—
H
H
H
H
H
acac

3′-120Y
Pt
0
3′
Nap2
—
—
H
H
H
H
H
—
—

3′-121
Pt
1
3′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

3′-121X
Pt
1
3′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

3′-121Y
Pt
0
3′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

3′-122
Pt
1
3′
Nap2
—
—
CH₃
H
H
H
H
pic

3′-122X
Pt
1
3′
Nap2
—
—
CH₃
H
H
H
H
acac

3′-122Y
Pt
0
3′
Nap2
—
—
CH₃
H
H
H
H
—
—

3′-123
Pt
1
3′
Nap3
—
—
H
H
H
H
H
pic

3′-123X
Pt
1
3′
Nap3
—
—
H
H
H
H
H
acac

3′-123Y
Pt
0
3′
Nap3
—
—
H
H
H
H
H
—
—

3′-124
Pt
1
3′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

3′-124X
Pt
1
3′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

3′-124Y
Pt
0
3′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

3′-125
Pt
1
3′
Nap3
—
—
CH₃
H
H
H
H
pic

3′-125X
Pt
1
3′
Nap3
—
—
CH₃
H
H
H
H
acac

3′-125Y
Pt
0
3′
Nap3
—
—
CH₃
H
H
H
H
—
—

3′-126
Pt
1
3′
TB
—
—
H
H
H
H
H
pic

3′-126X
Pt
1
3′
TB
—
—
H
H
H
H
H
acac

3′-126Y
Pt
0
3′
TB
—
—
H
H
H
H
H
—
—

3′-127
Pt
1
3′
TB
—
—

^tC₄H₉
H
H
H
H
pic

3′-127X
Pt
1
3′
TB
—
—

^tC₄H₉
H
H
H
H
acac

3′-127Y
Pt
0
3′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

3′-128
Pt
1
3′
TB
—
—
CH₃
H
H
H
H
pic

3′-128X
Pt
1
3′
TB
—
—
CH₃
H
H
H
H
acac

3′-128Y
Pt
0
3′
TB
—
—
CH₃
H
H
H
H
—
—

3′-129
Pt
1
3′
TF
—
—
H
H
H
H
H
pic

3′-129X
Pt
1
3′
TF
—
—
H
H
H
H
H
acac

3′-129Y
Pt
0
3′
TF
—
—
H
H
H
H
H
—
—

3′-130
Pt
1
3′
TF
—
—

^tC₄H₉
H
H
H
H
pic

3′-130X
Pt
1
3′
TF
—
—

^tC₄H₉
H
H
H
H
acac

3′-130Y
Pt
0
3′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

3′-131
Pt
1
3′
TF
—
—
CH₃
H
H
H
H
pic

3′-131X
Pt
1
3′
TF
—
—
CH₃
H
H
H
H
acac

3′-131Y
Pt
0
3′
TF
—
—
CH₃
H
H
H
H
—
—

3′-132
Pt
1
3′
OB
—
—
H
H
H
H
H
pic

3′-132X
Pt
1
3′
OB
—
—
H
H
H
H
H
acac

3′-132Y
Pt
0
3′
OB
—
—
H
H
H
H
H
—
—

3′-133
Pt
1
3′
OB
—
—

^tC₄H₉
H
H
H
H
pic

3′-133X
Pt
1
3′
OB
—
—

^tC₄H₉
H
H
H
H
acac

3′-133Y
Pt
0
3′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

3′-134
Pt
1
3′
OB
—
—
CH₃
H
H
H
H
pic

3′-134X
Pt
1
3′
OB
—
—
CH₃
H
H
H
H
acac

3′-134Y
Pt
0
3′
OB
—
—
CH₃
H
H
H
H
—
—

3′-135
Pt
1
3′
Fu
—
—
H
H
H
H
H
pic

3′-135X
Pt
1
3′
Fu
—
—
H
H
H
H
H
acac

3′-135Y
Pt
0
3′
Fu
—
—
H
H
H
H
H
—
—

3′-136
Pt
1
3′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

3′-136X
Pt
1
3′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

3′-136Y
Pt
0
3′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

3′-137
Pt
1
3′
Fu
—
—
CH₃
H
H
H
H
pic

3′-137X
Pt
1
3′
Fu
—
—
CH₃
H
H
H
H
acac

3′-137Y
Pt
0
3′
Fu
—
—
CH₃
H
H
H
H
—
—

3′-138
Pt
1
3′
Fl
—
—
H
H
H
H
H
pic

3′-138X
Pt
1
3′
Fl
—
—
H
H
H
H
H
acac

3′-138Y
Pt
0
3′
Fl
—
—
H
H
H
H
H
—
—

3′-139
Pt
1
3′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

3′-139X
Pt
1
3′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

3′-139Y
Pt
0
3′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

3′-140
Pt
1
3′
Fl
—
—
CH₃
H
H
H
H
pic

3′-140X
Pt
1
3′
Fl
—
—
CH₃
H
H
H
H
acac

3′-140Y
Pt
0
3′
Fl
—
—
CH₃
H
H
H
H
—
—

3′-141
Pt
1
3′
Bz
—
—
H
H
H
H
H
pic

3′-141X
Pt
1
3′
Bz
—
—
H
H
H
H
H
acac

3′-141Y
Pt
0
3′
Bz
—
—
H
H
H
H
H
—
—

3′-142
Pt
1
3′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

3′-142X
Pt
1
3′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

3′-142Y
Pt
0
3′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

3′-143
Pt
1
3′
Bz
—
—
CH₃
H
H
H
H
pic

3′-143X
Pt
1
3′
Bz
—
—
CH₃
H
H
H
H
acac

3′-143Y
Pt
0
3′
Bz
—
—
CH₃
H
H
H
H
—
—

3′-144
Pt
1
3′
Qu
—
—
H
H
H
H
H
pic

3′-144X
Pt
1
3′
Qu
—
—
H
H
H
H
H
acac

3′-144Y
Pt
0
3′
Qu
—
—
H
H
H
H
H
—
—

3′-145
Pt
1
3′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

3′-145X
Pt
1
3′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

3′-145Y
Pt
0
3′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

3′-146
Pt
1
3′
Qu
—
—
CH₃
H
H
H
H
pic

3′-146X
Pt
1
3′
Qu
—
—
CH₃
H
H
H
H
acac

3′-146Y
Pt
0
3′
Qu
—
—
CH₃
H
H
H
H
—
—

3′-147
Pt
1
3′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

3′-147X
Pt
1
3′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

3′-147Y
Pt
0
3′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

3′-148
Pt
1
3′
OL
H

^tC₄H₉
H
H
H
H
H
pic

3′-148X
Pt
1
3′
OL
H

^tC₄H₉
H
H
H
H
H
acac

3′-148Y
Pt
0
3′
OL
H

^tC₄H₉
H
H
H
H
H
—
—

3′-149
Pt
1
3′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

3′-149X
Pt
1
3′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

3′-149Y
Pt
0
3′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

3′-150
Pt
1
3′
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

3′-150X
Pt
1
3′
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

3′-150Y
Pt
0
3′
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

3′-151
Pt
1
3′
OL
H
H
H
H
H
H
H
pic

3′-151X
Pt
1
3′
OL
H
H
H
H
H
H
H
acac

3′-151Y
Pt
0
3′
OL
H
H
H
H
H
H
H
—
—

3′-152
Pt
1
3′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

3′-152X
Pt
1
3′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

3′-152Y
Pt
0
3′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

3′-153
Pt
1
3′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

3′-153X
Pt
1
3′
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

3′-153Y
Pt
0
3′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

3′-154
Pt
1
3′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

3′-154X
Pt
1
3′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

3′-154Y
Pt
0
3′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 39

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4′-138
Pt
1
4′
Nap1
—
—
CH₃
H
H
H
H
pic

4′-138X
Pt
1
4′
Nap1
—
—
CH₃
H
H
H
H
acac

4′-138Y
Pt
0
4′
Nap1
—
—
CH₃
H
H
H
H
—
—

4′-139
Pt
1
4′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

4′-139X
Pt
1
4′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

4′-139Y
Pt
0
4′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

4′-140
Pt
1
4′
Nap2
—
—
CH₃
H
H
H
H
pic

4′-140X
Pt
1
4′
Nap2
—
—
CH₃
H
H
H
H
acac

4′-140Y
Pt
0
4′
Nap2
—
—
CH₃
H
H
H
H
—
—

4′-141
Pt
1
4′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

4′-141X
Pt
1
4′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

4′-141Y
Pt
0
4′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

4′-142
Pt
1
4′
Nap3
—
—
CH₃
H
H
H
H
pic

4′-142X
Pt
1
4′
Nap3
—
—
CH₃
H
H
H
H
acac

4′-142Y
Pt
0
4′
Nap3
—
—
CH₃
H
H
H
H
—
—

4′-143
Pt
1
4′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

4′-143X
Pt
1
4′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

4′-143Y
Pt
0
4′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

4′-144
Pt
1
4′
TB
—
—
CH₃
H
H
H
H
pic

4′-144X
Pt
1
4′
TB
—
—
CH₃
H
H
H
H
acac

4′-144Y
Pt
0
4′
TB
—
—
CH₃
H
H
H
H
—
—

4′-145
Pt
1
4′
TB
—
—

^tC₄H₉
H
H
H
H
pic

4′-145X
Pt
1
4′
TB
—
—

^tC₄H₉
H
H
H
H
acac

4′-145Y
Pt
0
4′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

4′-146
Pt
1
4′
TF
—
—
CH₃
H
H
H
H
pic

4′-146X
Pt
1
4′
TF
—
—
CH₃
H
H
H
H
acac

4′-146Y
Pt
0
4′
TF
—
—
CH₃
H
H
H
H
—
—

4′-147
Pt
1
4′
TF
—
—

^tC₄H₉
H
H
H
H
pic

4′-147X
Pt
1
4′
TF
—
—

^tC₄H₉
H
H
H
H
acac

4′-147Y
Pt
0
4′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

4′-148
Pt
1
4′
OB
—
—
CH₃
H
H
H
H
pic

4′-148X
Pt
1
4′
OB
—
—
CH₃
H
H
H
H
acac

4′-148Y
Pt
0
4′
OB
—
—
CH₃
H
H
H
H
—
—

4′-149
Pt
1
4′
OB
—
—

^tC₄H₉
H
H
H
H
pic

4′-149X
Pt
1
4′
OB
—
—

^tC₄H₉
H
H
H
H
acac

4′-149Y
Pt
0
4′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

4′-150
Pt
1
4′
Fu
—
—
CH₃
H
H
H
H
pic

4′-150X
Pt
1
4′
Fu
—
—
CH₃
H
H
H
H
acac

4′-150Y
Pt
0
4′
Fu
—
—
CH₃
H
H
H
H
—
—

4′-151
Pt
1
4′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

4′-151X
Pt
1
4′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

4′-151Y
Pt
0
4′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

4′-152
Pt
1
4′
Fl
—
—
CH₃
H
H
H
H
pic

4′-152X
Pt
1
4′
Fl
—
—
CH₃
H
H
H
H
acac

4′-152Y
Pt
0
4′
Fl
—
—
CH₃
H
H
H
H
—
—

4′-153
Pt
1
4′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

4′-153X
Pt
1
4′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

4′-153Y
Pt
0
4′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

4′-154
Pt
1
4′
Bz
—
—
CH₃
H
H
H
H
pic

4′-154X
Pt
1
4′
Bz
—
—
CH₃
H
H
H
H
acac

4′-154Y
Pt
0
4′
Bz
—
—
CH₃
H
H
H
H
—
—

4′-155
Pt
1
4′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

4′-155X
Pt
1
4′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

4′-155Y
Pt
0
4′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

4′-156
Pt
1
4′
Qu
—
—
CH₃
H
H
H
H
pic

4′-156X
Pt
1
4′
Qu
—
—
CH₃
H
H
H
H
acac

4′-156Y
Pt
0
4′
Qu
—
—
CH₃
H
H
H
H
—
—

4′-157
Pt
1
4′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

4′-157X
Pt
1
4′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

4′-157Y
Pt
0
4′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

4′-158
Pt
1
4′
OL
—
—
CH₃
H
H
H
H
pic

4′-158X
Pt
1
4′
OL
—
—
CH₃
H
H
H
H
acac

4′-158Y
Pt
0
4′
OL
—
—
CH₃
H
H
H
H
—
—

4′-159
Pt
1
4′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-159X
Pt
1
4′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-159Y
Pt
0
4′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-160
Pt
1
4′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

4′-160X
Pt
1
4′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

4′-160Y
Pt
0
4′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

4′-161
Pt
1
4′
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-161X
Pt
1
4′
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-161Y
Pt
0
4′
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-162
Pt
1
4′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-162X
Pt
1
4′
0L
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-162Y
Pt
0
4′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-163
Pt
1
4′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
pic

4′-163X
Pt
1
4′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
acac

4′-163Y
Pt
0
4′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
—
—

4′-164
Pt
1
4′
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
pic

4′-164X
Pt
1
4′
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
acac

4′-164Y
Pt
0
4′
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-165
Pt
1
4′
OL
H
H
CH₃
H
H
H
H
pic

4′-165X
Pt
1
4′
OL
H
H
CH₃
H
H
H
H
acac

4′-165Y
Pt
0
4′
OL
H
H
CH₃
H
H
H
H
—
—

4′-166
Pt
1
4′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
pic

4′-166X
Pt
1
4′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
acac

4′-166Y
Pt
0
4′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
—
—

embedded image

TABLE 40

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹
L²

5′-140
Pt
1
5′
Nap1
—
—
H
CH₃
H
pic

5′-140X
Pt
1
5′
Nap1
—
—
H
CH₃
H
acac

5′-140Y
Pt
0
5′
Nap1
—
—
H
CH₃
H
—
—

5′-141
Pt
1
5′
Nap1
—
—
H

^tC₄H₉
H
pic

5′-141X
Pt
1
5′
Nap1
—
—
H

^tC₄H₉
H
acac

5′-141Y
Pt
0
5′
Nap1
—
—
H

^tC₄H₉
H
—
—

5′-142
Pt
1
5′
Nap1
—
—

^tC₄H₉
CH₃
H
pic

5′-142X
Pt
1
5′
Nap1
—
—

^tC₄H₉
CH₃
H
acac

5′-142Y
Pt
0
5′
Nap1
—
—

^tC₄H₉
CH₃
H
—
—

5′-143
Pt
1
5′
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-143X
Pt
1
5′
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-143Y
Pt
0
5′
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-144
Pt
1
5′
Nap1
—
—
CH₃
CH₃
H
pic

5′-144X
Pt
1
5′
Nap1
—
—
CH₃
CH₃
H
acac

5′-144Y
Pt
0
5′
Nap1
—
—
CH₃
CH₃
H
—
—

5′-145
Pt
1
5′
Nap1
—
—
CH₃

^tC₄H₉
H
pic

5′-145X
Pt
1
5′
Nap1
—
—
CH₃

^tC₄H₉
H
acac

5′-145Y
Pt
0
5′
Nap1
—
—
CH₃

^tC₄H₉
H
—
—

5′-146
Pt
1
5′
Nap1
—
—
H
CH₃
H
pic

5′-146X
Pt
1
5′
Nap2
—
—
H
CH₃
H
acac

5′-146Y
Pt
0
5′
Nap2
—
—
H
CH₃
H
—
—

5′-147
Pt
1
5′
Nap2
—
—
H

^tC₄H₉
H
pic

5′-147X
Pt
1
5′
Nap2
—
—
H

^tC₄H₉
H
acac

5′-147Y
Pt
0
5′
Nap2
—
—
H

^tC₄H₉
H
—
—

5′-148
Pt
1
5′
Nap2
—
—

^tC₄H₉
CH₃
H
pic

5′-148X
Pt
1
5′
Nap2
—
—

^tC₄H₉
CH₃
H
acac

5′-148Y
Pt
0
5′
Nap2
—
—

^tC₄H₉
CH₃
H
—
—

5′-149
Pt
1
5′
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-149X
Pt
1
5′
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-149Y
Pt
0
5′
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-150
Pt
1
5′
Nap2
—
—
CH₃
CH₃
H
pic

5′-150X
Pt
1
5′
Nap2
—
—
CH₃
CH₃
H
acac

5′-150Y
Pt
0
5′
Nap2
—
—
CH₃
CH₃
H
—
—

5′-151
Pt
1
5′
Nap2
—
—
CH₃

^tC₄H₉
H
pic

5′-151X
Pt
1
5′
Nap2
—
—
CH₃

^tC₄H₉
H
acac

5′-151Y
Pt
0
5′
Nap2
—
—
CH₃

^tC₄H₉
H
—
—

5′-152
Pt
1
5′
Nap3
—
—
H
CH₃
H
pic

5′-152X
Pt
1
5′
Nap3
—
—
H
CH₃
H
acac

5′-152Y
Pt
0
5′
Nap3
—
—
H
CH₃
H
—
—

5′-153
Pt
1
5′
Nap3
—
—
H

^tC₄H₉
H
pic

5′-153X
Pt
1
5′
Nap3
—
—
H

^tC₄H₉
H
acac

5′-153Y
Pt
0
5′
Nap3
—
—
H

^tC₄H₉
H
—
—

5′-154
Pt
1
5′
Nap3
—
—

^tC₄H₉
CH₃
H
pic

5′-154X
Pt
1
5′
Nap3
—
—

^tC₄H₉
CH₃
H
acac

5′-154Y
Pt
0
5′
Nap3
—
—

^tC₄H₉
CH₃
H
—
—

5′-155
Pt
1
5′
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-155X
Pt
1
5′
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-155Y
Pt
0
5′
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-156
Pt
1
5′
Nap3
—
—
CH₃
CH₃
H
pic

5′-156X
Pt
1
5′
Nap3
—
—
CH₃
CH₃
H
acac

5′-156Y
Pt
0
5′
Nap3
—
—
CH₃
CH₃
H
—
—

5′-157
Pt
1
5′
Nap3
—
—
CH₃

^tC₄H₉
H
pic

5′-157X
Pt
1
5′
Nap3
—
—
CH₃

^tC₄H₉
H
acac

5′-157Y
Pt
0
5′
Nap3
—
—
CH₃

^tC₄H₉
H
—
—

5′-158
Pt
1
5′
TB
—
—
H
CH₃
H
pic

5′-158X
Pt
1
5′
TB
—
—
H
CH₃
H
acac

5′-158Y
Pt
0
5′
TB
—
—
H
CH₃
H
—
—

5′-159
Pt
1
5′
TB
—
—
H

^tC₄H₉
H
pic

5′-159X
Pt
1
5′
TB
—
—
H

^tC₄H₉
H
acac

5′-159Y
Pt
0
5′
TB
—
—
H

^tC₄H₉
H
—
—

5′-160
Pt
1
5′
TB
—
—

^tC₄H₉
CH₃
H
pic

5′-160X
Pt
1
5′
TB
—
—

^tC₄H₉
CH₃
H
acac

5′-160Y
Pt
0
5′
TB
—
—

^tC₄H₉
CH₃
H
—
—

5′-161
Pt
1
5′
TB
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-161X
Pt
1
5′
TB
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-161Y
Pt
0
5′
TB
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-162
Pt
1
5′
TB
—
—
CH₃
CH₃
H
pic

5′-162X
Pt
1
5′
TB
—
—
CH₃
CH₃
H
acac

5′-162Y
Pt
0
5′
TB
—
—
CH₃
CH₃
H
—
—

5′-163
Pt
1
5′
TB
—
—
CH₃

^tC₄H₉
H
pic

5′-163X
Pt
1
5′
TB
—
—
CH₃

^tC₄H₉
H
acac

5′-163Y
Pt
0
5′
TB
—
—
CH₃

^tC₄H₉
H
—
—

5′-164
Pt
1
5′
TF
—
—
H
CH₃
H
pic

5′-164X
Pt
1
5′
TF
—
—
H
CH₃
H
acac

5′-164Y
Pt
0
5′
TF
—
—
H
CH₃
H
—
—

5′-165
Pt
1
5′
TF
—
—
H

^tC₄H₉
H
pic

5′-165X
Pt
1
5′
TF
—
—
H

^tC₄H₉
H
acac

5′-165Y
Pt
0
5′
TF
—
—
H

^tC₄H₉
H
—
—

5′-166
Pt
1
5′
TF
—
—

^tC₄H₉
CH₃
H
pic

5′-166X
Pt
1
5′
TF
—
—

^tC₄H₉
CH₃
H
acac

5′-166Y
Pt
0
5′
TF
—
—

^tC₄H₉
CH₃
H
—
—

5′-167
Pt
1
5′
TF
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-167X
Pt
1
5′
TF
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-167Y
Pt
0
5′
TF
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-168
Pt
1
5′
TF
—
—
CH₃
CH₃
H
pic

5′-168X
Pt
1
5′
TF
—
—
CH₃
CH₃
H
acac

5′-168Y
Pt
0
5′
TF
—
—
CH₃
CH₃
H
—
—

5′-169
Pt
1
5′
TF
—
—
CH₃

^tC₄H₉
H
pic

5′-169X
Pt
1
5′
TF
—
—
CH₃

^tC₄H₉
H
acac

5′-169Y
Pt
0
5′
TF
—
—
CH₃

^tC₄H₉
H
—
—

5′-170
Pt
1
5′
OB
—
—
H
CH₃
H
pic

5′-170X
Pt
1
5′
OB
—
—
H
CH₃
H
acac

5′-170Y
Pt
0
5′
OB
—
—
H
CH₃
H
—
—

5′-171
Pt
1
5′
OB
—
—
H

^tC₄H₉
H
pic

5′-171X
Pt
1
5′
OB
—
—
H

^tC₄H₉
H
acac

5′-171Y
Pt
0
5′
OB
—
—
H

^tC₄H₉
H
—
—

5′-172
Pt
1
5′
OB
—
—

^tC₄H₉
CH₃
H
pic

5′-172X
Pt
1
5′
OB
—
—

^tC₄H₉
CH₃
H
acac

5′-172Y
Pt
0
5′
OB
—
—

^tC₄H₉
CH₃
H
—
—

5′-173
Pt
1
5′
OB
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-173X
Pt
1
5′
OB
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-173Y
Pt
0
5′
OB
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-174
Pt
1
5′
OB
—
—
CH₃
CH₃
H
pic

5′-174X
Pt
1
5′
OB
—
—
CH₃
CH₃
H
acac

5′-174Y
Pt
0
5′
OB
—
—
CH₃
CH₃
H
—
—

5′-175
Pt
1
5′
OB
—
—
CH₃

^tC₄H₉
H
pic

5′-175X
Pt
1
5′
OB
—
—
CH₃

^tC₄H₉
H
acac

5′-175Y
Pt
0
5′
OB
—
—
CH₃

^tC₄H₉
H
—
—

5′-176
Pt
1
5′
Fu
—
—
H
CH₃
H
pic

5′-176X
Pt
1
5′
Fu
—
—
H
CH₃
H
acac

5′-176Y
Pt
0
5′
Fu
—
—
H
CH₃
H
—
—

5′-177
Pt
1
5′
Fu
—
—
H

^tC₄H₉
H
pic

5′-177X
Pt
1
5′
Fu
—
—
H

^tC₄H₉
H
acac

5′-177Y
Pt
0
5′
Fu
—
—
H

^tC₄H₉
H
—
—

5′-178
Pt
1
5′
Fu
—
—

^tC₄H₉
CH₃
H
pic

5′-178X
Pt
1
5′
Fu
—
—

^tC₄H₉
CH₃
H
acac

5′-178Y
Pt
0
5′
Fu
—
—

^tC₄H₉
CH₃
H
—
—

5′-179
Pt
1
5′
Fu
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-179X
Pt
1
5′
Fu
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-179Y
Pt
0
5′
Fu
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-180
Pt
1
5′
Fu
—
—
CH₃
CH₃
H
pic

5′-180X
Pt
1
5′
Fu
—
—
CH₃
CH₃
H
acac

5′-180Y
Pt
0
5′
Fu
—
—
CH₃
CH₃
H
—
—

5′-181
Pt
1
5′
Fu
—
—
CH₃

^tC₄H₉
H
pic

5′-181X
Pt
1
5′
Fu
—
—
CH₃

^tC₄H₉
H
acac

5′-181Y
Pt
0
5′
Fu
—
—
CH₃

^tC₄H₉
H
—
—

5′-182
Pt
1
5′
Fu
—
—
H
CH₃
H
pic

5′-182X
Pt
1
5′
Fu
—
—
H
CH₃
H
acac

5′-182Y
Pt
0
5′
Fu
—
—
H
CH₃
H
—
—

5′-183
Pt
1
5′
Fl
—
—
H

^tC₄H₉
H
pic

5′-183X
Pt
1
5′
Fl
—
—
H

^tC₄H₉
H
acac

5′-183Y
Pt
0
5′
Fl
—
—
H

^tC₄H₉
H
—
—

5′-184
Pt
1
5′
Fl
—
—

^tC₄H₉
CH₃
H
pic

5′-184X
Pt
1
5′
Fl
—
—

^tC₄H₉
CH₃
H
acac

5′-184Y
Pt
0
5′
Fl
—
—

^tC₄H₉
CH₃
H
—
—

5′-185
Pt
1
5′
Fl
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-185X
Pt
1
5′
Fl
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-185Y
Pt
0
5′
Fl
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-186
Pt
1
5′
Fl
—
—
CH₃
CH₃
H
pic

5′-186X
Pt
1
5′
Fl
—
—
CH₃
CH₃
H
acac

5′-186Y
Pt
0
5′
Fl
—
—
CH₃
CH₃
H
—
—

5′-187
Pt
1
5′
Fl
—
—
CH₃

^tC₄H₉
H
pic

5′-187X
Pt
1
5′
Fl
—
—
CH₃

^tC₄H₉
H
acac

5′-187Y
Pt
0
5′
Fl
—
—
CH₃

^tC₄H₉
H
—
—

5′-188
Pt
1
5′
Bz
—
—
H
CH₃
H
pic

5′-188X
Pt
1
5′
Bz
—
—
H
CH₃
H
acac

5′-188Y
Pt
0
5′
Bz
—
—
H
CH₃
H
—
—

5′-189
Pt
1
5′
Bz
—
—
H

^tC₄H₉
H
pic

5′-189X
Pt
1
5′
Bz
—
—
H

^tC₄H₉
H
acac

5′-189Y
Pt
0
5′
Bz
—
—
H

^tC₄H₉
H
—
—

5′-190
Pt
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
pic

5′-190X
Pt
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
acac

5′-190Y
Pt
0
5′
Bz
—
—

^tC₄H₉
CH₃
H
—
—

5′-191
Pt
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-191X
Pt
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-191Y
Pt
0
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-192
Pt
1
5′
Bz
—
—
CH₃
CH₃
H
pic

5′-192X
Pt
1
5′
Bz
—
—
CH₃
CH₃
H
acac

5′-192Y
Pt
0
5′
Bz
—
—
CH₃
CH₃
H
—
—

5′-193
Pt
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
pic

5′-193X
Pt
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
acac

5′-193Y
Pt
0
5′
Bz
—
—
CH₃

^tC₄H₉
H
—
—

5′-194
Pt
1
5′
Qu
—
—
H
CH₃
H
pic

5′-194X
Pt
1
5′
Bz
—
—
H
CH₃
H
acac

5′-194Y
Pt
0
5′
Bz
—
—
H
CH₃
H
—
—

5′-195
Pt
1
5′
Bz
—
—
H

^tC₄H₉
H
pic

5′-195X
Pt
1
5′
Bz
—
—
H

^tC₄H₉
H
acac

5′-195Y
Pt
0
5′
Bz
—
—
H

^tC₄H₉
H
—
—

5′-196
Pt
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
pic

5′-196X
Pt
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
acac

5′-196Y
Pt
0
5′
Bz
—
—

^tC₄H₉
CH₃
H
—
—

5′-197
Pt
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′-197X
Pt
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′-197Y
Pt
0
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′-198
Pt
1
5′
Bz
—
—
CH₃
CH₃
H
pic

5′-198X
Pt
1
5′
Bz
—
—
CH₃
CH₃
H
acac

5′-198Y
Pt
0
5′
Bz
—
—
CH₃
CH₃
H
—
—

5′-199
Pt
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
pic

5′-199X
Pt
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
acac

5′-199Y
Pt
0
5′
Bz
—
—
CH₃

^tC₄H₉
H
—
—

5′-200
Pt
1
5′
OL
H

ⁿC₄H₉
H
CH₃
H
pic

5′-200X
Pt
1
5′
OL
H

ⁿC₄H₉
H
CH₃
H
acac

5′-200Y
Pt
0
5′
OL
H

ⁿC₄H₉
H
CH₃
H
—
—

5′-201
Pt
1
5′
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
pic

5′-201X
Pt
1
5′
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
acac

5′-201Y
Pt
0
5′
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
—
—

5′-202
Pt
1
5′
OL
H

^tC₄H₉
H
CH₃
H
pic

5′-202X
Pt
1
5′
OL
H

^tC₄H₉
H
CH₃
H
acac

5′-202Y
Pt
0
5′
OL
H

^tC₄H₉
H
CH₃
H
—
—

5′-203
Pt
1
5′
OL
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-203X
Pt
1
5′
OL
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-203Y
Pt
0
5′
OL
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5′-204
Pt
1
5′
OL
CH₃

ⁿC₄H₉
H
CH₃
H
pic

5′-204X
Pt
1
5′
OL
CH₃

ⁿC₄H₉
H
CH₃
H
acac

5′-204Y
Pt
0
5′
OL
CH₃

ⁿC₄H₉
H
CH₃
H
—
—

5′-205
Pt
1
5′
OL
CH₃

^tC₄H₉
H
CH₃
H
pic

5′-205X
Pt
1
5′
OL
CH₃

^tC₄H₉
H
CH₃
H
acac

5′-205Y
Pt
0
5′
OL
CH₃

^tC₄H₉
H
CH₃
H
—
—

5′-206
Pt
1
5′
OL
H
H
H
CH₃
H
pic

5′-206X
Pt
1
5′
OL
H
H
H
CH₃
H
acac

5′-206Y
Pt
0
5′
OL
H
H
H
CH₃
H
—
—

5′-207
Pt
1
5′
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
pic

5′-207X
Pt
1
5′
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
acac

5′-207Y
Pt
0
5′
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
—
—

5′-208
Pt
1
5′
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
pic

5′-208X
Pt
1
5′
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
acac

5′-208Y
Pt
0
5′
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
—
—

5′-209
Pt
1
5′
OL
—CH₂CH₂CH₂—
H
CH₃
H
pic

5′-209X
Pt
1
5′
OL
—CH₂CH₂CH₂—
H
CH₃
H
acac

5′-209Y
Pt
0
5′
OL
—CH₂CH₂CH₂—
H
CH₃
H
—
—

5′-210
Pt
1
5′
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
pic

5′-210X
Pt
1
5′
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
acac

5′-210Y
Pt
0
5′
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
—
—

embedded image

TABLE 41

No.
M
m
BSS
SS G
T¹
T²
T⁶
T⁰
T⁷
L¹
L²

6′-138
Pt
1
6′
Nap1
—
—
CH₃
H
H
pic

6′-138X
Pt
1
6′
Nap1
—
—
CH₃
H
H
acac

6′-138Y
Pt
0
6′
Nap1
—
—
CH₃
H
H
—
—

6′-139
Pt
1
6′
Nap1
—
—

^tC₄H₉
H
H
pic

6′-139X
Pt
1
6′
Nap1
—
—

^tC₄H₉
H
H
acac

6′-139Y
Pt
0
6′
Nap1
—
—

^tC₄H₉
H
H
—
—

6′-140
Pt
1
6′
Nap2
—
—
CH₃
H
H
pic

6′-140X
Pt
1
6′
Nap2
—
—
CH₃
H
H
acac

6′-140Y
Pt
0
6′
Nap2
—
—
CH₃
H
H
—
—

6′-141
Pt
1
6′
Nap2
—
—

^tC₄H₉
H
H
pic

6′-141X
Pt
1
6′
Nap2
—
—

^tC₄H₉
H
H
acac

6′-141Y
Pt
0
6′
Nap2
—
—

^tC₄H₉
H
H
—
—

6′-142
Pt
1
6′
Nap3
—
—
CH₃
H
H
pic

6′-142X
Pt
1
6′
Nap3
—
—
CH₃
H
H
acac

6′-142Y
Pt
0
6′
Nap3
—
—
CH₃
H
H
—
—

6′-143
Pt
1
6′
Nap3
—
—

^tC₄H₉
H
H
pic

6′-143X
Pt
1
6′
Nap3
—
—

^tC₄H₉
H
H
acac

6′-143Y
Pt
0
6′
Nap3
—
—

^tC₄H₉
H
H
—
—

6′-144
Pt
1
6′
TB
—
—
CH₃
H
H
pic

6′-144X
Pt
1
6′
TB
—
—
CH₃
H
H
acac

6′-144Y
Pt
0
6′
TB
—
—
CH₃
H
H
—
—

6′-145
Pt
1
6′
TB
—
—

^tC₄H₉
H
H
pic

6′-145X
Pt
1
6′
TB
—
—

^tC₄H₉
H
H
acac

6′-145Y
Pt
0
6′
TB
—
—

^tC₄H₉
H
H
—
—

6′-146
Pt
1
6′
TF
—
—
CH₃
H
H
pic

6′-146X
Pt
1
6′
TF
—
—
CH₃
H
H
acac

6′-146Y
Pt
0
6′
TF
—
—
CH₃
H
H
—
—

6′-147
Pt
1
6′
TF
—
—

^tC₄H₉
H
H
pic

6′-147X
Pt
1
6′
TF
—
—

^tC₄H₉
H
H
acac

6′-147Y
Pt
0
6′
TF
—
—

^tC₄H₉
H
H
—
—

6′-148
Pt
1
6′
OB
—
—
CH₃
H
H
pic

6′-148X
Pt
1
6′
OB
—
—
CH₃
H
H
acac

6′-148Y
Pt
0
6′
OB
—
—
CH₃
H
H
—
—

6′-149
Pt
1
6′
OB
—
—

^tC₄H₉
H
H
pic

6′-149X
Pt
1
6′
OB
—
—

^tC₄H₉
H
H
acac

6′-149Y
Pt
0
6′
OB
—
—

^tC₄H₉
H
H
—
—

6′-150
Pt
1
6′
Fu
—
—
CH₃
H
H
pic

6′-150X
Pt
1
6′
Fu
—
—
CH₃
H
H
acac

6′-150Y
Pt
0
6′
Fu
—
—
CH₃
H
H
—
—

6′-151
Pt
1
6′
Fu
—
—

^tC₄H₉
H
H
pic

6′-151X
Pt
1
6′
Fu
—
—

^tC₄H₉
H
H
acac

6′-151Y
Pt
0
6′
Fu
—
—

^tC₄H₉
H
H
—
—

6′-152
Pt
1
6′
Fl
—
—
CH₃
H
H
pic

6′-152X
Pt
1
6′
Fl
—
—
CH₃
H
H
acac

6′-152Y
Pt
0
6′
Fl
—
—
CH₃
H
H
—
—

6′-153
Pt
1
6′
Fl
—
—

^tC₄H₉
H
H
pic

6′-153X
Pt
1
6′
Fl
—
—

^tC₄H₉
H
H
acac

6′-153Y
Pt
0
6′
Fl
—
—

^tC₄H₉
H
H
—
—

6′-154
Pt
1
6′
Bz
—
—
CH₃
H
H
pic

6′-154X
Pt
1
6′
Bz
—
—
CH₃
H
H
acac

6′-154Y
Pt
0
6′
Bz
—
—
CH₃
H
H
—
—

6′-155
Pt
1
6′
Bz
—
—

^tC₄H₉
H
H
pic

6′-155X
Pt
1
6′
Bz
—
—

^tC₄H₉
H
H
acac

6′-155Y
Pt
0
6′
Bz
—
—

^tC₄H₉
H
H
—
—

6′-156
Pt
1
6′
Qu
—
—
CH₃
H
H
pic

6′-156X
Pt
1
6′
Qu
—
—
CH₃
H
H
acac

6′-156Y
Pt
0
6′
Qu
—
—
CH₃
H
H
—
—

6′-157
Pt
1
6′
Qu
—
—

^tC₄H₉
H
H
pic

6′-157X
Pt
1
6′
Qu
—
—

^tC₄H₉
H
H
acac

6′-157Y
Pt
0
6′
Qu
—
—

^tC₄H₉
H
H
—
—

6′-158
Pt
1
6′
OL
H

ⁿC₄H₉
CH₃
H
H
pic

6′-158X
Pt
1
6′
OL
H

ⁿC₄H₉
CH₃
H
H
acac

6′-158Y
Pt
0
6′
OL
H

ⁿC₄H₉
CH₃
H
H
—
—

6′-159
Pt
1
6′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
pic

6′-159X
Pt
1
6′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
acac

6′-159Y
Pt
0
6′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
—
—

6′-160
Pt
1
6′
OL
H

^tC₄H₉
CH₃
H
H
pic

6′-160X
Pt
1
6′
OL
H

^tC₄H₉
CH₃
H
H
acac

6′-160Y
Pt
0
6′
OL
H

^tC₄H₉
CH₃
H
H
—
—

6′-161
Pt
1
6′
OL
H

^tC₄H₉

^tC₄H₉
H
H
pic

6′-161X
Pt
1
6′
OL
H

^tC₄H₉

^tC₄H₉
H
H
acac

6′-161Y
Pt
0
6′
OL
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6′-162
Pt
1
6′
OL
H

ⁿC₄H₉
CH₃
H
H
pic

6′-162X
Pt
1
6′
0L
H

ⁿC₄H₉
CH₃
H
H
acac

6′-162Y
Pt
0
6′
OL
H

ⁿC₄H₉
CH₃
H
H
—
—

6′-163
Pt
1
6′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
pic

6′-163X
Pt
1
6′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
acac

6′-163Y
Pt
0
6′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
—
—

6′-164
Pt
1
6′
OL
CH₃

^tC₄H₉
CH₃
H
H
pic

6′-164X
Pt
1
6′
OL
CH₃

^tC₄H₉
CH₃
H
H
acac

6′-164Y
Pt
0
6′
OL
CH₃

^tC₄H₉
CH₃
H
H
—
—

6′-165
Pt
1
6′
OL
H
H
CH₃
H
H
pic

6′-165X
Pt
1
6′
OL
H
H
CH₃
H
H
acac

6′-165Y
Pt
0
6′
OL
H
H
CH₃
H
H
—
—

6′-166
Pt
1
6′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
pic

6′-166X
Pt
1
6′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
acac

6′-166Y
Pt
0
6′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
—
—

embedded image

TABLE 42

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹
L²

7′-138
Pt
1
7′
Nap1
—
—
CH₃
H
H
pic

7′-138X
Pt
1
7′
Nap1
—
—
CH₃
H
H
acac

7′-138Y
Pt
0
7′
Nap1
—
—
CH₃
H
H
—
—

7′-139
Pt
1
7′
Nap1
—
—

^tC₄H₉
H
H
pic

7′-139X
Pt
1
7′
Nap1
—
—

^tC₄H₉
H
H
acac

7′-139Y
Pt
0
7′
Nap1
—
—

^tC₄H₉
H
H
—
—

7′-140
Pt
1
7′
Nap2
—
—
CH₃
H
H
pic

7′-140X
Pt
1
7′
Nap2
—
—
CH₃
H
H
acac

7′-140Y
Pt
0
7′
Nap2
—
—
CH₃
H
H
—
—

7′-141
Pt
1
7′
Nap2
—
—

^tC₄H₉
H
H
pic

7′-141X
Pt
1
7′
Nap2
—
—

^tC₄H₉
H
H
acac

7′-141Y
Pt
0
7′
Nap2
—
—

^tC₄H₉
H
H
—
—

7′-142
Pt
1
7′
Nap3
—
—
CH₃
H
H
pic

7′-142X
Pt
1
7′
Nap3
—
—
CH₃
H
H
acac

7′-142Y
Pt
0
7′
Nap3
—
—
CH₃
H
H
—
—

7′-143
Pt
1
7′
Nap3
—
—

^tC₄H₉
H
H
pic

7′-143X
Pt
1
7′
Nap3
—
—

^tC₄H₉
H
H
acac

7′-143Y
Pt
0
7′
Nap3
—
—

^tC₄H₉
H
H
—
—

7′-144
Pt
1
7′
TB
—
—
CH₃
H
H
pic

7′-144X
Pt
1
7′
TB
—
—
CH₃
H
H
acac

7′-144Y
Pt
0
7′
TB
—
—
CH₃
H
H
—
—

7′-145
Pt
1
7′
TB
—
—

^tC₄H₉
H
H
pic

7′-145X
Pt
1
7′
TB
—
—

^tC₄H₉
H
H
acac

7′-145Y
Pt
0
7′
TB
—
—

^tC₄H₉
H
H
—
—

7′-146
Pt
1
7′
TF
—
—
CH₃
H
H
pic

7′-146X
Pt
1
7′
TF
—
—
CH₃
H
H
acac

7′-146Y
Pt
0
7′
TF
—
—
CH₃
H
H
—
—

7′-147
Pt
1
7′
TF
—
—

^tC₄H₉
H
H
pic

7′-147X
Pt
1
7′
TF
—
—

^tC₄H₉
H
H
acac

7′-147Y
Pt
0
7′
TF
—
—

^tC₄H₉
H
H
—
—

7′-148
Pt
1
7′
OB
—
—
CH₃
H
H
pic

7′-148X
Pt
1
7′
OB
—
—
CH₃
H
H
acac

7′-148Y
Pt
0
7′
OB
—
—
CH₃
H
H
—
—

7′-149
Pt
1
7′
OB
—
—

^tC₄H₉
H
H
pic

7′-149X
Pt
1
7′
OB
—
—

^tC₄H₉
H
H
acac

7′-149Y
Pt
0
7′
OB
—
—

^tC₄H₉
H
H
—
—

7′-150
Pt
1
7′
Fu
—
—
CH₃
H
H
pic

7′-150X
Pt
1
7′
Fu
—
—
CH₃
H
H
acac

7′-150Y
Pt
0
7′
Fu
—
—
CH₃
H
H
—
—

7′-151
Pt
1
7′
Fu
—
—

^tC₄H₉
H
H
pic

7′-151X
Pt
1
7′
Fu
—
—

^tC₄H₉
H
H
acac

7′-151Y
Pt
0
7′
Fu
—
—

^tC₄H₉
H
H
—
—

7′-152
Pt
1
7′
Fl
—
—
CH₃
H
H
pic

7′-152X
Pt
1
7′
Fl
—
—
CH₃
H
H
acac

7′-152Y
Pt
0
7′
Fl
—
—
CH₃
H
H
—
—

7′-153
Pt
1
7′
Fl
—
—

^tC₄H₉
H
H
pic

7′-153X
Pt
1
7′
Fl
—
—

^tC₄H₉
H
H
acac

7′-153Y
Pt
0
7′
Fl
—
—

^tC₄H₉
H
H
—
—

7′-154
Pt
1
7′
Bz
—
—
CH₃
H
H
pic

7′-154X
Pt
1
7′
Bz
—
—
CH₃
H
H
acac

7′-154Y
Pt
0
7′
Bz
—
—
CH₃
H
H
—
—

7′-155
Pt
1
7′
Bz
—
—

^tC₄H₉
H
H
pic

7′-155X
Pt
1
7′
Bz
—
—

^tC₄H₉
H
H
acac

7′-155Y
Pt
0
7′
Bz
—
—

^tC₄H₉
H
H
—
—

7′-156
Pt
1
7′
Qu
—
—
CH₃
H
H
pic

7′-156X
Pt
1
7′
Qu
—
—
CH₃
H
H
acac

7′-156Y
Pt
0
7′
Qu
—
—
CH₃
H
H
—
—

7′-157
Pt
1
7′
Qu
—
—

^tC₄H₉
H
H
pic

7′-157X
Pt
1
7′
Qu
—
—

^tC₄H₉
H
H
acac

7′-157Y
Pt
0
7′
Qu
—
—

^tC₄H₉
H
H
—
—

7′-158
Pt
1
7′
OL
H

ⁿC₄H₉
CH₃
H
H
pic

7′-158X
Pt
1
7′
OL
H

ⁿC₄H₉
CH₃
H
H
acac

7′-158Y
Pt
0
7′
OL
H

ⁿC₄H₉
CH₃
H
H
—
—

7′-159
Pt
1
7′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
pic

7′-159X
Pt
1
7′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
acac

7′-159Y
Pt
0
7′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
—
—

7′-160
Pt
1
7′
OL
H

^tC₄H₉
CH₃
H
H
pic

7′-160X
Pt
1
7′
OL
H

^tC₄H₉
CH₃
H
H
acac

7′-160Y
Pt
0
7′
OL
H

^tC₄H₉
CH₃
H
H
—
—

7′-161
Pt
1
7′
OL
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-161X
Pt
1
7′
OL
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-161Y
Pt
0
7′
OL
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7′-162
Pt
1
7′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
pic

7′-162X
Pt
1
7′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
acac

7′-162Y
Pt
0
7′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
—
—

7′-163
Pt
1
7′
OL
CH₃

^tC₄H₉
CH₃
H
H
pic

7′-163X
Pt
1
7′
OL
CH₃

^tC₄H₉
CH₃
H
H
acac

7′-163Y
Pt
0
7′
OL
CH₃

^tC₄H₉
CH₃
H
H
—
—

7′-164
Pt
1
7′
OL
H
H
CH₃
H
H
pic

7′-164X
Pt
1
7′
OL
H
H
CH₃
H
H
acac

7′-164Y
Pt
0
7′
OL
H
H
CH₃
H
H
—
—

7′-165
Pt
1
7′
OL
—CH₂CH₂CH₂—
CH₃
H
H
pic

7′-165X
Pt
1
7′
OL
—CH₂CH₂CH₂—
CH₃
H
H
acac

7′-165Y
Pt
0
7′
OL
—CH₂CH₂CH₂—
CH₃
H
H
—
—

7′-166
Pt
1
7′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
pic

7′-166X
Pt
1
7′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
acac

7′-166Y
Pt
0
7′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
—
—

embedded image

TABLE 43

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1′-187
Pd
1
1′
Ph
H
H
H
H
H
H
H
H
H
pic

1′-187X
Pd
1
1′
Ph
H
H
H
H
H
H
H
H
H
acac

1′-187Y
Pd
0
1′
Ph
H
H
H
H
H
H
H
H
H
—
—

1′-188
Pd
1
1′
Ph
H
F
H
F
H
H
H
H
H
pic

1′-188X
Pd
1
1′
Ph
H
F
H
F
H
H
H
H
H
acac

1′-188Y
Pd
0
1′
Ph
H
F
H
F
H
H
H
H
H
—
—

1′-189
Pd
1
1′
Ph
F
H
H
F
H
H
H
H
H
pic

1′-189X
Pd
1
1′
Ph
F
H
H
F
H
H
H
H
H
acac

1′-189Y
Pd
0
1′
Ph
F
H
H
F
H
H
H
H
H
—
—

1′-190
Pd
1
1′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

1′-190X
Pd
1
1′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

1′-190Y
Pd
0
1′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

1′-191
Pd
1
1′
Ph
H
F
CF₃
H
H
H
H
H
H
pic

1′-191X
Pd
1
1′
Ph
H
F
CF₃
H
H
H
H
H
H
acac

1′-191Y
Pd
0
1′
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

1′-192
Pd
1
1′
Ph
F
H
CF₃
H
H
H
H
H
H
pic

1′-192X
Pd
1
1′
Ph
F
H
CF₃
H
H
H
H
H
H
acac

1′-192Y
Pd
0
1′
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

1′-193
Pd
1
1′
Ph
F
F
F
F
H
H
H
H
H
pic

1′-193X
Pd
1
1′
Ph
F
F
F
F
H
H
H
H
H
acac

1′-193Y
Pd
0
1′
Ph
F
F
F
F
H
H
H
H
H
—
—

1′-194
Pd
1
1′
Ph
H
F
H
CH₃
H
H
H
H
H
pic

1′-194X
Pd
1
1′
Ph
H
F
H
CH₃
H
H
H
H
H
acac

1′-194Y
Pd
0
1′
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

1′-195
Pd
1
1′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

1′-195X
Pd
1
1′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

1′-195Y
Pd
0
1′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

1′-196
Pd
1
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

1′-196X
Pd
1
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

1′-196Y
Pd
0
1′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

1′-197
Pd
1
1′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

1′-197X
Pd
1
1′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

1′-197Y
Pd
0
1′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

1′-198
Pd
1
1′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

1′-198X
Pd
1
1′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

1′-198Y
Pd
0
1′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

1′-199
Pd
1
1′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

1′-199X
Pd
1
1′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

1′-199Y
Pd
0
1′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

1′-200
Pd
1
1′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

1′-200X
Pd
1
1′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

1′-200Y
Pd
0
1′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

1′-201
Pd
1
1′
Ph
H
H
NO₂
H
H
H
H
H
H
pic

1′-201X
Pd
1
1′
Ph
H
H
NO₂
H
H
H
H
H
H
acac

1′-201Y
Pd
0
1′
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

1′-202
Pd
1
1′
Ph
F
H
NO₂
H
H
H
H
H
H
pic

1′-202X
Pd
1
1′
Ph
F
H
NO₂
H
H
H
H
H
H
acac

1′-202Y
Pd
0
1′
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

1′-203
Pd
1
1′
Ph
F
H
NO₂
F
H
H
H
H
H
pic

1′-203X
Pd
1
1′
Ph
F
H
NO₂
F
H
H
H
H
H
acac

1′-203Y
Pd
0
1′
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

1′-204
Pd
1
1′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

1′-204X
Pd
1
1′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

1′-204Y
Pd
0
1′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

1′-205
Pd
1
1′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

1′-205X
Pd
1
1′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

1′-205Y
Pd
0
1′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

1′-206
Pd
1
1′
Ph
H
H
CF₃
H
H
H
H
H
H
pic

1′-206X
Pd
1
1′
Ph
H
H
CF₃
H
H
H
H
H
H
acac

1′-206Y
Pd
0
1′
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

1′-207
Pd
1
1′
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

1′-207X
Pd
1
1′
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

1′-207Y
Pd
0
1′
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

1′-208
Pd
1
1′
Ph
H
NO₂
H
H
H
H
H
H
H
pic

1′-208X
Pd
1
1′
Ph
H
NO₂
H
H
H
H
H
H
H
acac

1′-208Y
Pd
0
1′
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

1′-209
Pd
1
1′
Ph
H
CF₃
H
H
H
H
H
H
H
pic

1′-209X
Pd
1
1′
Ph
H
CF₃
H
H
H
H
H
H
H
acac

1′-209Y
Pd
0
1′
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

1′-210
Pd
1
1′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

1′-210X
Pd
1
1′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

1′-210Y
Pd
0
1′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

1′-211
Pd
1
1′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

1′-211X
Pd
1
1′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

1′-211Y
Pd
0
1′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

1′-212
Pd
1
1′
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

1′-212X
Pd
1
1′
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

1′-212Y
Pd
0
1′
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

1′-213
Pd
1
1′
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

1′-213X
Pd
1
1′
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

1′-213Y
Pd
0
1′
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

1′-214
Pd
1
1′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

1′-214X
Pd
1
1′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

1′-214Y
Pd
0
1′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

1′-215
Pd
1
1′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

1′-215X
Pd
1
1′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

1′-215Y
Pd
0
1′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

1′-216
Pd
1
1′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

1′-216X
Pd
1
1′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

1′-216Y
Pd
0
1′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

1′-217
Pd
1
1′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

1′-217X
Pd
1
1′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

1′-217Y
Pd
0
1′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

1′-218
Pd
1
1′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

1′-218X
Pd
1
1′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

1′-218Y
Pd
0
1′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

1′-219
Pd
1
1′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

1′-219X
Pd
1
1′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

1′-219Y
Pd
0
1′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

1′-220
Pd
1
1′
Ph
H
F
H
F
H
CH₃
H
H
H
pic

1′-220X
Pd
1
1′
Ph
H
F
H
F
H
CH₃
H
H
H
acac

1′-220Y
Pd
0
1′
Ph
H
F
H
F
H
CH₃
H
H
H
—
—

1′-221
Pd
1
1′
Ph
CF₃
H
CF₃
H
H
CF₃
H
H
H
pic

1′-221X
Pd
1
1′
Ph
CF₃
H
CF₃
H
H
CF₃
H
H
H
acac

1′-221Y
Pd
0
1′
Ph
CF₃
H
CF₃
H
H
CF₃
H
H
H
—
—

1′-222
Pd
1
1′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

1′-222X
Pd
1
1′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

1′-222Y
Pd
0
1′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

1′-223
Pd
1
1′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1′-223X
Pd
1
1′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1′-223Y
Pd
0
1′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1′-224
Pd
1
1′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

1′-224X
Pd
1
1′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

1′-224Y
Pd
0
1′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

1′-225
Pd
1
1′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

1′-225X
Pd
1
1′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

1′-225Y
Pd
0
1′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

1′-226
Pd
1
1′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

1′-226X
Pd
1
1′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

1′-226Y
Pd
0
1′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

1′-227
Pd
1
1′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

1′-227X
Pd
1
1′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

1′-227Y
Pd
0
1′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

1′-228
Pd
1
1′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

1′-228X
Pd
1
1′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

1′-228Y
Pd
0
1′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

1′-229
Pd
1
1′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

1′-229X
Pd
1
1′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

1′-229Y
Pd
0
1′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

1′-230
Pd
1
1′
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

1′-230X
Pd
1
1′
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

1′-230Y
Pd
0
1′
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

1′-231
Pd
1
1′
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

1′-231X
Pd
1
1′
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

1′-231Y
Pd
0
1′
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

1′-232
Pd
1
1′
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

1′-232X
Pd
1
1′
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

1′-232Y
Pd
0
1′
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

1′-233
Pd
1
1′
Ph
H
H
BL
H
H
H
H
H
pic

1′-233X
Pd
1
1′
Ph
H
H
BL
H
H
H
H
H
acac

1′-233Y
Pd
0
1′
Ph
H
H
BL
H
H
H
H
H
—
—

1′-234
Pd
1
1′
Ph
H
BL
H
H
H
H
H
H
pic

1′-234X
Pd
1
1′
Ph
H
BL
H
H
H
H
H
H
acac

1′-234Y
Pd
0
1′
Ph
H
BL
H
H
H
H
H
H
—
—

1′-235
Pd
1
1′
Ph
H
H
PL
H
H
H
H
H
pic

1′-235X
Pd
1
1′
Ph
H
H
PL
H
H
H
H
H
acac

1′-235Y
Pd
0
1′
Ph
H
H
PL
H
H
H
H
H
—
—

1′-236
Pd
1
1′
Ph
H
PL
H
H
H
H
H
H
pic

1′-236X
Pd
1
1′
Ph
H
PL
H
H
H
H
H
H
acac

1′-236Y
Pd
0
1′
Ph
H
PL
H
H
H
H
H
H
—
—

1′-237
Pd
1
1′
Ph
H
H
MEE1
H
H
H
H
H
pic

1′-237X
Pd
1
1′
Ph
H
H
MEE1
H
H
H
H
H
acac

1′-237Y
Pd
0
1′
Ph
H
H
MEE1
H
H
H
H
H
—
—

1′-238
Pd
1
1′
Ph
H
MEE1
H
H
H
H
H
H
pic

1′-238X
Pd
1
1′
Ph
H
MEE1
H
H
H
H
H
H
acac

1′-238Y
Pd
0
1′
Ph
H
MEE1
H
H
H
H
H
H
—
—

1′-239
Pd
1
1′
Ph
H
H
MEE2
H
H
H
H
H
pic

1′-239X
Pd
1
1′
Ph
H
H
MEE2
H
H
H
H
H
acac

1′-239Y
Pd
0
1′
Ph
H
H
MEE2
H
H
H
H
H
—
—

1′-240
Pd
1
1′
Ph
H
MEE2
H
H
H
H
H
H
pic

1′-240X
Pd
1
1′
Ph
H
MEE2
H
H
H
H
H
H
acac

1′-240Y
Pd
0
1′
Ph
H
MEE2
H
H
H
H
H
H
—
—

1′-241
Pd
1
1′
Ph
H
H
PA1
H
H
H
H
H
pic

1′-241X
Pd
1
1′
Ph
H
H
PA1
H
H
H
H
H
acac

1′-241Y
Pd
0
1′
Ph
H
H
PA1
H
H
H
H
H
—
—

1′-242
Pd
1
1′
Ph
H
PA1
H
H
H
H
H
H
pic

1′-242X
Pd
1
1′
Ph
H
PA1
H
H
H
H
H
H
acac

1′-242Y
Pd
0
1′
Ph
H
PA1
H
H
H
H
H
H
—
—

1′-243
Pd
1
1′
Ph
H
H
PA2
H
H
H
H
H
pic

1′-243X
Pd
1
1′
Ph
H
H
PA2
H
H
H
H
H
acac

1′-243Y
Pd
0
1′
Ph
H
H
PA2
H
H
H
H
H
—
—

1′-244
Pd
1
1′
Ph
H
PA2
H
H
H
H
H
H
pic

1′-244X
Pd
1
1′
Ph
H
PA2
H
H
H
H
H
H
acac

1′-244Y
Pd
0
1′
Ph
H
PA2
H
H
H
H
H
H
—
—

1′-245
Pd
1
1′
Ph
H
H
EA1
H
H
H
H
H
pic

1′-245X
Pd
1
1′
Ph
H
H
EA1
H
H
H
H
H
acac

1′-245Y
Pd
0
1′
Ph
H
H
EA1
H
H
H
H
H
—
—

1′-246
Pd
1
1′
Ph
H
EA2
H
H
H
H
H
H
pic

1′-246X
Pd
1
1′
Ph
H
EA2
H
H
H
H
H
H
acac

1′-246Y
Pd
0
1′
Ph
H
EA2
H
H
H
H
H
H
—
—

1′-247
Pd
1
1′
Ph
H
H
ME
H
H
H
H
H
pic

1′-247X
Pd
1
1′
Ph
H
H
ME
H
H
H
H
H
acac

1′-247Y
Pd
0
1′
Ph
H
H
ME
H
H
H
H
H
—
—

1′-248
Pd
1
1′
Ph
H
ME
H
H
H
H
H
H
pic

1′-248X
Pd
1
1′
Ph
H
ME
H
H
H
H
H
H
acac

1′-248Y
Pd
0
1′
Ph
H
ME
H
H
H
H
H
H
—
—

1′-249
Pd
1
1′
Ph
H
H
AT
H
H
H
H
H
pic

1′-249X
Pd
1
1′
Ph
H
H
AT
H
H
H
H
H
acac

1′-249Y
Pd
0
1′
Ph
H
H
AT
H
H
H
H
H
—
—

1′-250
Pd
1
1′
Ph
H
AT
H
H
H
H
H
H
pic

1′-250X
Pd
1
1′
Ph
H
AT
H
H
H
H
H
H
acac

1′-250Y
Pd
0
1′
Ph
H
AT
H
H
H
H
H
H
—
—

1′-251
Pd
1
1′
Ph
H
H
MES1
H
H
H
H
H
pic

1′-251X
Pd
1
1′
Ph
H
H
MES1
H
H
H
H
H
acac

1′-251Y
Pd
0
1′
Ph
H
H
MES1
H
H
H
H
H
—
—

1′-252
Pd
1
1′
Ph
H
MES1
H
H
H
H
H
H
pic

1′-252X
Pd
1
1′
Ph
H
MES1
H
H
H
H
H
H
acac

1′-252Y
Pd
0
1′
Ph
H
MES1
H
H
H
H
H
H
—
—

1′-253
Pd
1
1′
Ph
H
H
MES2
H
H
H
H
H
pic

1′-253X
Pd
1
1′
Ph
H
H
MES2
H
H
H
H
H
acac

1′-253Y
Pd
0
1′
Ph
H
H
MES2
H
H
H
H
H
—
—

1′-254
Pd
1
1′
Ph
H
MES2
H
H
H
H
H
H
pic

1′-254X
Pd
1
1′
Ph
H
MES2
H
H
H
H
H
H
acac

1′-254Y
Pd
0
1′
Ph
H
MES2
H
H
H
H
H
H
—
—

1′-255
Pd
1
1′
Ph
H
H
PS1
H
H
H
H
H
pic

1′-255X
Pd
1
1′
Ph
H
H
PS1
H
H
H
H
H
acac

1′-255Y
Pd
0
1′
Ph
H
H
PS1
H
H
H
H
H
—
—

1′-256
Pd
1
1′
Ph
H
PS1
H
H
H
H
H
H
pic

1′-256X
Pd
1
1′
Ph
H
PS1
H
H
H
H
H
H
acac

1′-256Y
Pd
0
1′
Ph
H
PS1
H
H
H
H
H
H
—
—

1′-257
Pd
1
1′
Ph
H
H
PS2
H
H
H
H
H
pic

1′-257X
Pd
1
1′
Ph
H
H
PS2
H
H
H
H
H
acac

1′-257Y
Pd
0
1′
Ph
H
H
PS2
H
H
H
H
H
—
—

1′-258
Pd
1
1′
Ph
H
PS2
H
H
H
H
H
H
pic

1′-258X
Pd
1
1′
Ph
H
PS2
H
H
H
H
H
H
acac

1′-258Y
Pd
0
1′
Ph
H
PS2
H
H
H
H
H
H
—
—

1′-259
Pd
1
1′
Ph
H
H
BAL1
H
H
H
H
H
pic

1′-259X
Pd
1
1′
Ph
H
H
BAL1
H
H
H
H
H
acac

1′-259Y
Pd
0
1′
Ph
H
H
BAL1
H
H
H
H
H
—
—

1′-260
Pd
1
1′
Ph
H
BAL1
H
H
H
H
H
H
pic

1′-260X
Pd
1
1′
Ph
H
BAL1
H
H
H
H
H
H
acac

1′-260Y
Pd
0
1′
Ph
H
BAL1
H
H
H
H
H
H
—
—

1′-261
Pd
1
1′
Ph
H
H
BAL2
H
H
H
H
H
pic

1′-261X
Pd
1
1′
Ph
H
H
BAL2
H
H
H
H
H
acac

1′-261Y
Pd
0
1′
Ph
H
H
BAL2
H
H
H
H
H
—
—

1′-262
Pd
1
1′
Ph
H
BAL2
H
H
H
H
H
H
pic

1′-262X
Pd
1
1′
Ph
H
BAL2
H
H
H
H
H
H
acac

1′-262Y
Pd
0
1′
Ph
H
BAL2
H
H
H
H
H
H
—
—

1′-263
Pd
1
1′
Ph
H
H
MEK1
H
H
H
H
H
pic

1′-263X
Pd
1
1′
Ph
H
H
MEK1
H
H
H
H
H
acac

1′-263Y
Pd
0
1′
Ph
H
H
MEK1
H
H
H
H
H
—
—

1′-264
Pd
1
1′
Ph
H
MEK1
H
H
H
H
H
H
pic

1′-264X
Pd
1
1′
Ph
H
MEK1
H
H
H
H
H
H
acac

1′-264Y
Pd
0
1′
Ph
H
MEK1
H
H
H
H
H
H
—
—

1′-265
Pd
1
1′
Ph
H
H
MEK2
H
H
H
H
H
pic

1′-265X
Pd
1
1′
Ph
H
H
MEK2
H
H
H
H
H
acac

1′-265Y
Pd
0
1′
Ph
H
H
MEK2
H
H
H
H
H
—
—

1′-266
Pd
1
1′
Ph
H
MEK2
H
H
H
H
H
H
pic

1′-266X
Pd
1
1′
Ph
H
MEK2
H
H
H
H
H
H
acac

1′-266Y
Pd
0
1′
Ph
H
MEK2
H
H
H
H
H
H
—
—

1′-267
Pd
1
1′
Ph
H
H
PAL1
H
H
H
H
H
pic

1′-267X
Pd
1
1′
Ph
H
H
PAL1
H
H
H
H
H
acac

1′-267Y
Pd
0
1′
Ph
H
H
PAL1
H
H
H
H
H
—
—

1′-268
Pd
1
1′
Ph
H
PAL1
H
H
H
H
H
H
pic

1′-268X
Pd
1
1′
Ph
H
PAL1
H
H
H
H
H
H
acac

1′-268Y
Pd
0
1′
Ph
H
PAL1
H
H
H
H
H
H
—
—

1′-269
Pd
1
1′
Ph
H
H
PAL2
H
H
H
H
H
pic

1′-269X
Pd
1
1′
Ph
H
H
PAL2
H
H
H
H
H
acac

1′-269Y
Pd
0
1′
Ph
H
H
PAL2
H
H
H
H
H
—
—

1′-270
Pd
1
1′
Ph
H
PAL2
H
H
H
H
H
H
pic

1′-270X
Pd
1
1′
Ph
H
PAL2
H
H
H
H
H
H
acac

1′-270Y
Pd
0
1′
Ph
H
PAL2
H
H
H
H
H
H
—
—

1′-271
Pd
1
1′
Ph
H
H
MMK
H
H
H
H
H
pic

1′-271X
Pd
1
1′
Ph
H
H
MMK
H
H
H
H
H
acac

1′-271Y
Pd
0
1′
Ph
H
H
MMK
H
H
H
H
H
—
—

1′-272
Pd
1
1′
Ph
H
MMK
H
H
H
H
H
H
pic

1′-272X
Pd
1
1′
Ph
H
MMK
H
H
H
H
H
H
acac

1′-272Y
Pd
0
1′
Ph
H
MMK
H
H
H
H
H
H
—
—

1′-273
Pd
1
1′
Ph
H
H
EES1
H
H
H
H
H
pic

1′-273X
Pd
1
1′
Ph
H
H
EES1
H
H
H
H
H
acac

1′-273Y
Pd
0
1′
Ph
H
H
EES1
H
H
H
H
H
—
—

1′-274
Pd
1
1′
Ph
H
EES2
H
H
H
H
H
H
pic

1′-274X
Pd
1
1′
Ph
H
EES2
H
H
H
H
H
H
acac

1′-274Y
Pd
0
1′
Ph
H
EES2
H
H
H
H
H
H
—
—

1′-275
Pd
1
1′
Ph
H
H
PAE1
H
H
H
H
H
pic

1′-275X
Pd
1
1′
Ph
H
H
PAE1
H
H
H
H
H
acac

1′-275Y
Pd
0
1′
Ph
H
H
PAE1
H
H
H
H
H
—
—

1′-276
Pd
1
1′
Ph
H
PAE2
H
H
H
H
H
H
pic

1′-276X
Pd
1
1′
Ph
H
PAE2
H
H
H
H
H
H
acac

1′-276Y
Pd
0
1′
Ph
H
PAE2
H
H
H
H
H
H
—
—

1′-277
Pd
1
1′
Ph
H
H
AME1
H
H
H
H
H
pic

1′-277X
Pd
1
1′
Ph
H
H
AME1
H
H
H
H
H
acac

1′-277Y
Pd
0
1′
Ph
H
H
AME1
H
H
H
H
H
—
—

1′-278
Pd
1
1′
Ph
H
AME1
H
H
H
H
H
H
pic

1′-278X
Pd
1
1′
Ph
H
AME1
H
H
H
H
H
H
acac

1′-278Y
Pd
0
1′
Ph
H
AME1
H
H
H
H
H
H
—
—

1′-279
Pd
1
1′
Ph
H
H
AME2
H
H
H
H
H
pic

1′-279X
Pd
1
1′
Ph
H
H
AME2
H
H
H
H
H
acac

1′-279Y
Pd
0
1′
Ph
H
H
AME2
H
H
H
H
H
—
—

1′-280
Pd
1
1′
Ph
H
AME2
H
H
H
H
H
H
pic

1′-280X
Pd
1
1′
Ph
H
AME2
H
H
H
H
H
H
acac

1′-280Y
Pd
0
1′
Ph
H
AME2
H
H
H
H
H
H
—
—

1′-281
Pd
1
1′
Ph
H
H
EAE1
H
H
H
H
H
pic

1′-281X
Pd
1
1′
Ph
H
H
EAE1
H
H
H
H
H
acac

1′-281Y
Pd
0
1′
Ph
H
H
EAE1
H
H
H
H
H
—
—

1′-282
Pd
1
1′
Ph
H
EAE1
H
H
H
H
H
H
pic

1′-282X
Pd
1
1′
Ph
H
EAE1
H
H
H
H
H
H
acac

1′-282Y
Pd
0
1′
Ph
H
EAE1
H
H
H
H
H
H
—
—

1′-283
Pd
1
1′
Ph
H
H
EAE2
H
H
H
H
H
pic

1′-283X
Pd
1
1′
Ph
H
H
EAE2
H
H
H
H
H
acac

1′-283Y
Pd
0
1′
Ph
H
H
EAE2
H
H
H
H
H
—
—

1′-284
Pd
1
1′
Ph
H
EAE2
H
H
H
H
H
H
pic

1′-284X
Pd
1
1′
Ph
H
EAE2
H
H
H
H
H
H
acac

1′-284Y
Pd
0
1′
Ph
H
EAE2
H
H
H
H
H
H
—
—

1′-285
Pd
1
1′
Ph
H
H
AAE1
H
H
H
H
H
pic

1′-285X
Pd
1
1′
Ph
H
H
AAE1
H
H
H
H
H
acac

1′-285Y
Pd
0
1′
Ph
H
H
AAE1
H
H
H
H
H
—
—

1′-286
Pd
1
1′
Ph
H
AAE1
H
H
H
H
H
H
pic

1′-286X
Pd
1
1′
Ph
H
AAE1
H
H
H
H
H
H
acac

1′-286Y
Pd
0
1′
Ph
H
AAE1
H
H
H
H
H
H
—
—

1′-287
Pd
1
1′
Ph
H
H
AAE2
H
H
H
H
H
pic

1′-287X
Pd
1
1′
Ph
H
H
AAE2
H
H
H
H
H
acac

1′-287Y
Pd
0
1′
Ph
H
H
AAE2
H
H
H
H
H
—
—

1′-288
Pd
1
1′
Ph
H
AAE2
H
H
H
H
H
H
pic

1′-288X
Pd
1
1′
Ph
H
AAE2
H
H
H
H
H
H
acac

1′-288Y
Pd
0
1′
Ph
H
AAE2
H
H
H
H
H
H
—
—

1′-289
Pd
1
1′
Ph
H
H
PME1
H
H
H
H
H
pic

1′-289X
Pd
1
1′
Ph
H
H
PME1
H
H
H
H
H
acac

1′-289Y
Pd
0
1′
Ph
H
H
PME1
H
H
H
H
H
—
—

1′-290
Pd
1
1′
Ph
H
PME1
H
H
H
H
H
H
pic

1′-290X
Pd
1
1′
Ph
H
PME1
H
H
H
H
H
H
acac

1′-290Y
Pd
0
1′
Ph
H
PME1
H
H
H
H
H
H
—
—

1′-291
Pd
1
1′
Ph
H
H
PME2
H
H
H
H
H
pic

1′-291X
Pd
1
1′
Ph
H
H
PME2
H
H
H
H
H
acac

1′-291Y
Pd
0
1′
Ph
H
H
PME2
H
H
H
H
H
—
—

1′-292
Pd
1
1′
Ph
H
PME2
H
H
H
H
H
H
pic

1′-292X
Pd
1
1′
Ph
H
PME2
H
H
H
H
H
H
acac

1′-292Y
Pd
0
1′
Ph
H
PME2
H
H
H
H
H
H
—
—

1′-293
Pd
1
1′
Ph
H
H
MET1
H
H
H
H
H
pic

1′-293X
Pd
1
1′
Ph
H
H
MET1
H
H
H
H
H
acac

1′-293Y
Pd
0
1′
Ph
H
H
MET1
H
H
H
H
H
—
—

1′-294
Pd
1
1′
Ph
H
MET1
H
H
H
H
H
H
pic

1′-294X
Pd
1
1′
Ph
H
MET1
H
H
H
H
H
H
acac

1′-294Y
Pd
0
1′
Ph
H
MET1
H
H
H
H
H
H
—
—

1′-295
Pd
1
1′
Ph
H
H
MET2
H
H
H
H
H
pic

1′-295X
Pd
1
1′
Ph
H
H
MET2
H
H
H
H
H
acac

1′-295Y
Pd
0
1′
Ph
H
H
MET2
H
H
H
H
H
—
—

1′-296
Pd
1
1′
Ph
H
MET2
H
H
H
H
H
H
pic

1′-296X
Pd
1
1′
Ph
H
MET2
H
H
H
H
H
H
acac

1′-296Y
Pd
0
1′
Ph
H
MET2
H
H
H
H
H
H
—
—

1′-297
Pd
1
1′
Ph
H
H
EE1
H
H
H
H
H
pic

1′-297X
Pd
1
1′
Ph
H
H
EE1
H
H
H
H
H
acac

1′-297Y
Pd
0
1′
Ph
H
H
EE1
H
H
H
H
H
—
—

1′-298
Pd
1
1′
Ph
H
EE1
H
H
H
H
H
H
pic

1′-298X
Pd
1
1′
Ph
H
EE1
H
H
H
H
H
H
acac

1′-298Y
Pd
0
1′
Ph
H
EE1
H
H
H
H
H
H
—
—

1′-299
Pd
1
1′
Ph
H
H
EE2
H
H
H
H
H
pic

1′-299X
Pd
1
1′
Ph
H
H
EE2
H
H
H
H
H
acac

1′-299Y
Pd
0
1′
Ph
H
H
EE2
H
H
H
H
H
—
—

1′-300
Pd
1
1′
Ph
H
EE2
H
H
H
H
H
H
pic

1′-300X
Pd
1
1′
Ph
H
EE2
H
H
H
H
H
H
acac

1′-300Y
Pd
0
1′
Ph
H
EE2
H
H
H
H
H
H
—
—

1′-301
Pd
1
1′
Ph
H
H
MS1
H
H
H
H
H
pic

1′-301X
Pd
1
1′
Ph
H
H
MS1
H
H
H
H
H
acac

1′-301Y
Pd
0
1′
Ph
H
H
MS1
H
H
H
H
H
—
—

1′-302
Pd
1
1′
Ph
H
MS1
H
H
H
H
H
H
pic

1′-302X
Pd
1
1′
Ph
H
MS1
H
H
H
H
H
H
acac

1′-302Y
Pd
0
1′
Ph
H
MS1
H
H
H
H
H
H
—
—

1′-303
Pd
1
1′
Ph
H
H
MS2
H
H
H
H
H
pic

1′-303X
Pd
1
1′
Ph
H
H
MS2
H
H
H
H
H
acac

1′-303Y
Pd
0
1′
Ph
H
H
MS2
H
H
H
H
H
—
—

1′-304
Pd
1
1′
Ph
H
MS2
H
H
H
H
H
H
pic

1′-304X
Pd
1
1′
Ph
H
MS2
H
H
H
H
H
H
acac

1′-304Y
Pd
0
1′
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 44

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2′-187
Pd
1
2′
Ph
H
H
H
H
H
H
H
H
H
pic

2′-187X
Pd
1
2′
Ph
H
H
H
H
H
H
H
H
H
acac

2′-187Y
Pd
0
2′
Ph
H
H
H
H
H
H
H
H
H
—
—

2′-188
Pd
1
2′
Ph
H
F
H
F
H
H
H
H
H
pic

2′-188X
Pd
1
2′
Ph
H
F
H
F
H
H
H
H
H
acac

2′-188Y
Pd
0
2′
Ph
H
F
H
F
H
H
H
H
H
—
—

2′-189
Pd
1
2′
Ph
F
H
H
F
H
H
H
H
H
pic

2′-189X
Pd
1
2′
Ph
F
H
H
F
H
H
H
H
H
acac

2′-189Y
Pd
0
2′
Ph
F
H
H
F
H
H
H
H
H
—
—

2′-190
Pd
1
2′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

2′-190X
Pd
1
2′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

2′-190Y
Pd
0
2′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

2′-191
Pd
1
2′
Ph
H
F
CF₃
H
H
H
H
H
H
pic

2′-191X
Pd
1
2′
Ph
H
F
CF₃
H
H
H
H
H
H
acac

2′-191Y
Pd
0
2′
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

2′-192
Pd
1
2′
Ph
F
H
CF₃
H
H
H
H
H
H
pic

2′-192X
Pd
1
2′
Ph
F
H
CF₃
H
H
H
H
H
H
acac

2′-192Y
Pd
0
2′
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

2′-193
Pd
1
2′
Ph
F
F
F
F
H
H
H
H
H
pic

2′-193X
Pd
1
2′
Ph
F
F
F
F
H
H
H
H
H
acac

2′-193Y
Pd
0
2′
Ph
F
F
F
F
H
H
H
H
H
—
—

2′-194
Pd
1
2′
Ph
H
F
H
CH₃
H
H
H
H
H
pic

2′-194X
Pd
1
2′
Ph
H
F
H
CH₃
H
H
H
H
H
acac

2′-194Y
Pd
0
2′
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

2′-195
Pd
1
2′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

2′-195X
Pd
1
2′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

2′-195Y
Pd
0
2′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

2′-196
Pd
1
2′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

2′-196X
Pd
1
2′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

2′-196Y
Pd
0
2′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

2′-197
Pd
1
2′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

2′-197X
Pd
1
2′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

2′-197Y
Pd
0
2′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

2′-198
Pd
1
2′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

2′-198X
Pd
1
2′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

2′-198Y
Pd
0
2′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

2′-199
Pd
1
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

2′-199X
Pd
1
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

2′-199Y
Pd
0
2′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

2′-200
Pd
1
2′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

2′-200X
Pd
1
2′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

2′-200Y
Pd
0
2′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

2′-201
Pd
1
2′
Ph
H
H
NO₂
H
H
H
H
H
H
pic

2′-201X
Pd
1
2′
Ph
H
H
NO₂
H
H
H
H
H
H
acac

2′-201Y
Pd
0
2′
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

2′-202
Pd
1
2′
Ph
F
H
NO₂
H
H
H
H
H
H
pic

2′-202X
Pd
1
2′
Ph
F
H
NO₂
H
H
H
H
H
H
acac

2′-202Y
Pd
0
2′
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

2′-203
Pd
1
2′
Ph
F
H
NO₂
F
H
H
H
H
H
pic

2′-203X
Pd
1
2′
Ph
F
H
NO₂
F
H
H
H
H
H
acac

2′-203Y
Pd
0
2′
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

2′-204
Pd
1
2′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

2′-204X
Pd
1
2′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

2′-204Y
Pd
0
2′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

2′-205
Pd
1
2′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

2′-205X
Pd
1
2′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

2′-205Y
Pd
0
2′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

2′-206
Pd
1
2′
Ph
H
H
CF₃
H
H
H
H
H
H
pic

2′-206X
Pd
1
2′
Ph
H
H
CF₃
H
H
H
H
H
H
acac

2′-206Y
Pd
0
2′
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

2′-207
Pd
1
2′
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

2′-207X
Pd
1
2′
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

2′-207Y
Pd
0
2′
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

2′-208
Pd
1
2′
Ph
H
NO₂
H
H
H
H
H
H
H
pic

2′-208X
Pd
1
2′
Ph
H
NO₂
H
H
H
H
H
H
H
acac

2′-208Y
Pd
0
2′
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

2′-209
Pd
1
2′
Ph
H
CF₃
H
H
H
H
H
H
H
pic

2′-209X
Pd
1
2′
Ph
H
CF₃
H
H
H
H
H
H
H
acac

2′-209Y
Pd
0
2′
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

2′-210
Pd
1
2′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

2′-210X
Pd
1
2′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

2′-210Y
Pd
0
2′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

2′-211
Pd
1
2′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

2′-211X
Pd
1
2′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

2′-211Y
Pd
0
2′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

2′-212
Pd
1
2′
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

2′-212X
Pd
1
2′
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

2′-212Y
Pd
0
2′
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

2′-213
Pd
1
2′
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

2′-213X
Pd
1
2′
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

2′-213Y
Pd
0
2′
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

2′-214
Pd
1
2′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

2′-214X
Pd
1
2′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

2′-214Y
Pd
0
2′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

2′-215
Pd
1
2′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

2′-215X
Pd
1
2′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

2′-215Y
Pd
0
2′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

2′-216
Pd
1
2′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

2′-216X
Pd
1
2′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

2′-216Y
Pd
0
2′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

2′-217
Pd
1
2′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

2′-217X
Pd
1
2′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

2′-217Y
Pd
0
2′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

2′-218
Pd
1
2′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

2′-218X
Pd
1
2′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

2′-218Y
Pd
0
2′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

2′-219
Pd
1
2′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

2′-219X
Pd
1
2′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

2′-219Y
Pd
0
2′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

2′-220
Pd
1
2′
Ph
H
F
H
F
H
CH₃
H
H
H
pic

2′-220X
Pd
1
2′
Ph
H
F
H
F
H
CH₃
H
H
H
acac

2′-220Y
Pd
0
2′
Ph
H
F
H
F
H
CH₃
H
H
H
—
—

2′-221
Pd
1
2′
Ph
CF₃
H
CF₃
H
H
CF₃
H
H
H
pic

2′-221X
Pd
1
2′
Ph
CF₃
H
CF₃
H
H
CF₃
H
H
H
acac

2′-221Y
Pd
0
2′
Ph
CF₃
H
CF₃
H
H
CF₃
H
H
H
—
—

2′-222
Pd
1
2′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

2′-222X
Pd
1
2′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

2′-222Y
Pd
0
2′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

2′-223
Pd
1
2′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2′-223X
Pd
1
2′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

2′-223Y
Pd
0
2′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2′-224
Pd
1
2′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

2′-224X
Pd
1
2′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

2′-224Y
Pd
0
2′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

2′-225
Pd
1
2′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

2′-225X
Pd
1
2′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

2′-225Y
Pd
0
2′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

2′-226
Pd
1
2′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

2′-226X
Pd
1
2′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

2′-226Y
Pd
0
2′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

2′-227
Pd
1
2′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

2′-227X
Pd
1
2′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

2′-227Y
Pd
0
2′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

2′-228
Pd
1
2′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

2′-228X
Pd
1
2′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

2′-228Y
Pd
0
2′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

2′-229
Pd
1
2′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

2′-229X
Pd
1
2′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

2′-229Y
Pd
0
2′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

2′-230
Pd
1
2′
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

2′-230X
Pd
1
2′
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

2′-230Y
Pd
0
2′
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

2′-231
Pd
1
2′
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

2′-231X
Pd
1
2′
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

2′-231Y
Pd
0
2′
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

2′-232
Pd
1
2′
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

2′-232X
Pd
1
2′
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

2′-232Y
Pd
0
2′
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

2′-233
Pd
1
2′
Ph
H
H
BL
H
H
H
H
H
pic

2′-233X
Pd
1
2′
Ph
H
H
BL
H
H
H
H
H
acac

2′-233Y
Pd
0
2′
Ph
H
H
BL
H
H
H
H
H
—
—

2′-234
Pd
1
2′
Ph
H
BL
H
H
H
H
H
H
pic

2′-234X
Pd
1
2′
Ph
H
BL
H
H
H
H
H
H
acac

2′-234Y
Pd
0
2′
Ph
H
BL
H
H
H
H
H
H
—
—

2′-235
Pd
1
2′
Ph
H
H
PL
H
H
H
H
H
pic

2′-235X
Pd
1
2′
Ph
H
H
PL
H
H
H
H
H
acac

2′-235Y
Pd
0
2′
Ph
H
H
PL
H
H
H
H
H
—
—

2′-236
Pd
1
2′
Ph
H
PL
H
H
H
H
H
H
pic

2′-236X
Pd
1
2′
Ph
H
PL
H
H
H
H
H
H
acac

2′-236Y
Pd
0
2′
Ph
H
PL
H
H
H
H
H
H
—
—

2′-237
Pd
1
2′
Ph
H
H
MEE1
H
H
H
H
H
pic

2′-237X
Pd
1
2′
Ph
H
H
MEE1
H
H
H
H
H
acac

2′-237Y
Pd
0
2′
Ph
H
H
MEE1
H
H
H
H
H
—
—

2′-238
Pd
1
2′
Ph
H
MEE1
H
H
H
H
H
H
pic

2′-238X
Pd
1
2′
Ph
H
MEE1
H
H
H
H
H
H
acac

2′-238Y
Pd
0
2′
Ph
H
MEE1
H
H
H
H
H
H
—
—

2′-239
Pd
1
2′
Ph
H
H
MEE2
H
H
H
H
H
pic

2′-239X
Pd
1
2′
Ph
H
H
MEE2
H
H
H
H
H
acac

2′-239Y
Pd
0
2′
Ph
H
H
MEE2
H
H
H
H
H
—
—

2′-240
Pd
1
2′
Ph
H
MEE2
H
H
H
H
H
H
pic

2′-240X
Pd
1
2′
Ph
H
MEE2
H
H
H
H
H
H
acac

2′-240Y
Pd
0
2′
Ph
H
MEE2
H
H
H
H
H
H
—
—

2′-241
Pd
1
2′
Ph
H
H
PA1
H
H
H
H
H
pic

2′-241X
Pd
1
2′
Ph
H
H
PA1
H
H
H
H
H
acac

2′-241Y
Pd
0
2′
Ph
H
H
PA1
H
H
H
H
H
—
—

2′-242
Pd
1
2′
Ph
H
PA1
H
H
H
H
H
H
pic

2′-242X
Pd
1
2′
Ph
H
PA1
H
H
H
H
H
H
acac

2′-242Y
Pd
0
2′
Ph
H
PA1
H
H
H
H
H
H
—
—

2′-243
Pd
1
2′
Ph
H
H
PA2
H
H
H
H
H
pic

2′-243X
Pd
1
2′
Ph
H
H
PA2
H
H
H
H
H
acac

2′-243Y
Pd
0
2′
Ph
H
H
PA2
H
H
H
H
H
—
—

2′-244
Pd
1
2′
Ph
H
PA2
H
H
H
H
H
H
pic

2′-244X
Pd
1
2′
Ph
H
PA2
H
H
H
H
H
H
acac

2′-244Y
Pd
0
2′
Ph
H
PA2
H
H
H
H
H
H
—
—

2′-245
Pd
1
2′
Ph
H
H
EA1
H
H
H
H
H
pic

2′-245X
Pd
1
2′
Ph
H
H
EA1
H
H
H
H
H
acac

2′-245Y
Pd
0
2′
Ph
H
H
EA1
H
H
H
H
H
—
—

2′-246
Pd
1
2′
Ph
H
EA2
H
H
H
H
H
H
pic

2′-246X
Pd
1
2′
Ph
H
EA2
H
H
H
H
H
H
acac

2′-246Y
Pd
0
2′
Ph
H
EA2
H
H
H
H
H
H
—
—

2′-247
Pd
1
2′
Ph
H
H
ME
H
H
H
H
H
pic

2′-247X
Pd
1
2′
Ph
H
H
ME
H
H
H
H
H
acac

2′-247Y
Pd
0
2′
Ph
H
H
ME
H
H
H
H
H
—
—

2′-248
Pd
1
2′
Ph
H
ME
H
H
H
H
H
H
pic

2′-248X
Pd
1
2′
Ph
H
ME
H
H
H
H
H
H
acac

2′-248Y
Pd
0
2′
Ph
H
ME
H
H
H
H
H
H
—
—

2′-249
Pd
1
2′
Ph
H
H
AT
H
H
H
H
H
pic

2′-249X
Pd
1
2′
Ph
H
H
AT
H
H
H
H
H
acac

2′-249Y
Pd
0
2′
Ph
H
H
AT
H
H
H
H
H
—
—

2′-250
Pd
1
2′
Ph
H
AT
H
H
H
H
H
H
pic

2′-250X
Pd
1
2′
Ph
H
AT
H
H
H
H
H
H
acac

2′-250Y
Pd
0
2′
Ph
H
AT
H
H
H
H
H
H
—
—

2′-251
Pd
1
2′
Ph
H
H
MES1
H
H
H
H
H
pic

2′-251X
Pd
1
2′
Ph
H
H
MES1
H
H
H
H
H
acac

2′-251Y
Pd
0
2′
Ph
H
H
MES1
H
H
H
H
H
—
—

2′-252
Pd
1
2′
Ph
H
MES1
H
H
H
H
H
H
pic

2′-252X
Pd
1
2′
Ph
H
MES1
H
H
H
H
H
H
acac

2′-252Y
Pd
0
2′
Ph
H
MES1
H
H
H
H
H
H
—
—

2′-253
Pd
1
2′
Ph
H
H
MES2
H
H
H
H
H
pic

2′-253X
Pd
1
2′
Ph
H
H
MES2
H
H
H
H
H
acac

2′-253Y
Pd
0
2′
Ph
H
H
MES2
H
H
H
H
H
—
—

2′-254
Pd
1
2′
Ph
H
MES2
H
H
H
H
H
H
pic

2′-254X
Pd
1
2′
Ph
H
MES2
H
H
H
H
H
H
acac

2′-254Y
Pd
0
2′
Ph
H
MES2
H
H
H
H
H
H
—
—

2′-255
Pd
1
2′
Ph
H
H
PS1
H
H
H
H
H
pic

2′-255X
Pd
1
2′
Ph
H
H
PS1
H
H
H
H
H
acac

2′-255Y
Pd
0
2′
Ph
H
H
PS1
H
H
H
H
H
—
—

2′-256
Pd
1
2′
Ph
H
PS1
H
H
H
H
H
H
pic

2′-256X
Pd
1
2′
Ph
H
PS1
H
H
H
H
H
H
acac

2′-256Y
Pd
0
2′
Ph
H
PS1
H
H
H
H
H
H
—
—

2′-257
Pd
1
2′
Ph
H
H
PS2
H
H
H
H
H
pic

2′-257X
Pd
1
2′
Ph
H
H
PS2
H
H
H
H
H
acac

2′-257Y
Pd
0
2′
Ph
H
H
PS2
H
H
H
H
H
—
—

2′-258
Pd
1
2′
Ph
H
PS2
H
H
H
H
H
H
pic

2′-258X
Pd
1
2′
Ph
H
PS2
H
H
H
H
H
H
acac

2′-258Y
Pd
0
2′
Ph
H
PS2
H
H
H
H
H
H
—
—

2′-259
Pd
1
2′
Ph
H
H
BAL1
H
H
H
H
H
pic

2′-259X
Pd
1
2′
Ph
H
H
BAL1
H
H
H
H
H
acac

2′-259Y
Pd
0
2′
Ph
H
H
BAL1
H
H
H
H
H
—
—

2′-260
Pd
1
2′
Ph
H
BAL1
H
H
H
H
H
H
pic

2′-260X
Pd
1
2′
Ph
H
BAL1
H
H
H
H
H
H
acac

2′-260Y
Pd
0
2′
Ph
H
BAL1
H
H
H
H
H
H
—
—

2′-261
Pd
1
2′
Ph
H
H
BAL2
H
H
H
H
H
pic

2′-261X
Pd
1
2′
Ph
H
H
BAL2
H
H
H
H
H
acac

2′-261Y
Pd
0
2′
Ph
H
H
BAL2
H
H
H
H
H
—
—

2′-262
Pd
1
2′
Ph
H
BAL2
H
H
H
H
H
H
pic

2′-262X
Pd
1
2′
Ph
H
BAL2
H
H
H
H
H
H
acac

2′-262Y
Pd
0
2′
Ph
H
BAL2
H
H
H
H
H
H
—
—

2′-263
Pd
1
2′
Ph
H
H
MEK1
H
H
H
H
H
pic

2′-263X
Pd
1
2′
Ph
H
H
MEK1
H
H
H
H
H
acac

2′-263Y
Pd
0
2′
Ph
H
H
MEK1
H
H
H
H
H
—
—

2′-264
Pd
1
2′
Ph
H
MEK1
H
H
H
H
H
H
pic

2′-264X
Pd
1
2′
Ph
H
MEK1
H
H
H
H
H
H
acac

2′-264Y
Pd
0
2′
Ph
H
MEK1
H
H
H
H
H
H
—
—

2′-265
Pd
1
2′
Ph
H
H
MEK2
H
H
H
H
H
pic

2′-265X
Pd
1
2′
Ph
H
H
MEK2
H
H
H
H
H
acac

2′-265Y
Pd
0
2′
Ph
H
H
MEK2
H
H
H
H
H
—
—

2′-266
Pd
1
2′
Ph
H
MEK2
H
H
H
H
H
H
pic

2′-266X
Pd
1
2′
Ph
H
MEK2
H
H
H
H
H
H
acac

2′-266Y
Pd
0
2′
Ph
H
MEK2
H
H
H
H
H
H
—
—

2′-267
Pd
1
2′
Ph
H
H
PAL1
H
H
H
H
H
pic

2′-267X
Pd
1
2′
Ph
H
H
PAL1
H
H
H
H
H
acac

2′-267Y
Pd
0
2′
Ph
H
H
PAL1
H
H
H
H
H
—
—

2′-268
Pd
1
2′
Ph
H
PAL1
H
H
H
H
H
H
pic

2′-268X
Pd
1
2′
Ph
H
PAL1
H
H
H
H
H
H
acac

2′-268Y
Pd
0
2′
Ph
H
PAL1
H
H
H
H
H
H
—
—

2′-269
Pd
1
2′
Ph
H
H
PAL2
H
H
H
H
H
pic

2′-269X
Pd
1
2′
Ph
H
H
PAL2
H
H
H
H
H
acac

2′-269Y
Pd
0
2′
Ph
H
H
PAL2
H
H
H
H
H
—
—

2′-270
Pd
1
2′
Ph
H
PAL2
H
H
H
H
H
H
pic

2′-270X
Pd
1
2′
Ph
H
PAL2
H
H
H
H
H
H
acac

2′-270Y
Pd
0
2′
Ph
H
PAL2
H
H
H
H
H
H
—
—

2′-271
Pd
1
2′
Ph
H
H
MMK
H
H
H
H
H
pic

2′-271X
Pd
1
2′
Ph
H
H
MMK
H
H
H
H
H
acac

2′-271Y
Pd
0
2′
Ph
H
H
MMK
H
H
H
H
H
—
—

2′-272
Pd
1
2′
Ph
H
MMK
H
H
H
H
H
H
pic

2′-272X
Pd
1
2′
Ph
H
MMK
H
H
H
H
H
H
acac

2′-272Y
Pd
0
2′
Ph
H
MMK
H
H
H
H
H
H
—
—

2′-273
Pd
1
2′
Ph
H
H
EES1
H
H
H
H
H
pic

2′-273X
Pd
1
2′
Ph
H
H
EES1
H
H
H
H
H
acac

2′-273Y
Pd
0
2′
Ph
H
H
EES1
H
H
H
H
H
—
—

2′-274
Pd
1
2′
Ph
H
EES2
H
H
H
H
H
H
pic

2′-274X
Pd
1
2′
Ph
H
EES2
H
H
H
H
H
H
acac

2′-274Y
Pd
0
2′
Ph
H
EES2
H
H
H
H
H
H
—
—

2′-275
Pd
1
2′
Ph
H
H
PAE1
H
H
H
H
H
pic

2′-275X
Pd
1
2′
Ph
H
H
PAE1
H
H
H
H
H
acac

2′-275Y
Pd
0
2′
Ph
H
H
PAE1
H
H
H
H
H
—
—

2′-276
Pd
1
2′
Ph
H
PAE2
H
H
H
H
H
H
pic

2′-276X
Pd
1
2′
Ph
H
PAE2
H
H
H
H
H
H
acac

2′-276Y
Pd
0
2′
Ph
H
PAE2
H
H
H
H
H
H
—
—

2′-277
Pd
1
2′
Ph
H
H
AME1
H
H
H
H
H
pic

2′-277X
Pd
1
2′
Ph
H
H
AME1
H
H
H
H
H
acac

2′-277Y
Pd
0
2′
Ph
H
H
AME1
H
H
H
H
H
—
—

2′-278
Pd
1
2′
Ph
H
AME1
H
H
H
H
H
H
pic

2′-278X
Pd
1
2′
Ph
H
AME1
H
H
H
H
H
H
acac

2′-278Y
Pd
0
2′
Ph
H
AME1
H
H
H
H
H
H
—
—

2′-279
Pd
1
2′
Ph
H
H
AME2
H
H
H
H
H
pic

2′-279X
Pd
1
2′
Ph
H
H
AME2
H
H
H
H
H
acac

2′-279Y
Pd
0
2′
Ph
H
H
AME2
H
H
H
H
H
—
—

2′-280
Pd
1
2′
Ph
H
AME2
H
H
H
H
H
H
pic

2′-280X
Pd
1
2′
Ph
H
AME2
H
H
H
H
H
H
acac

2′-280Y
Pd
0
2′
Ph
H
AME2
H
H
H
H
H
H
—
—

2′-281
Pd
1
2′
Ph
H
H
EAE1
H
H
H
H
H
pic

2′-281X
Pd
1
2′
Ph
H
H
EAE1
H
H
H
H
H
acac

2′-281Y
Pd
0
2′
Ph
H
H
EAE1
H
H
H
H
H
—
—

2′-282
Pd
1
2′
Ph
H
EAE1
H
H
H
H
H
H
pic

2′-282X
Pd
1
2′
Ph
H
EAE1
H
H
H
H
H
H
acac

2′-282Y
Pd
0
2′
Ph
H
EAE1
H
H
H
H
H
H
—
—

2′-283
Pd
1
2′
Ph
H
H
EAE2
H
H
H
H
H
pic

2′-283X
Pd
1
2′
Ph
H
H
EAE2
H
H
H
H
H
acac

2′-283Y
Pd
0
2′
Ph
H
H
EAE2
H
H
H
H
H
—
—

2′-284
Pd
1
2′
Ph
H
EAE2
H
H
H
H
H
H
pic

2′-284X
Pd
1
2′
Ph
H
EAE2
H
H
H
H
H
H
acac

2′-284Y
Pd
0
2′
Ph
H
EAE2
H
H
H
H
H
H
—
—

2′-285
Pd
1
2′
Ph
H
H
AAE1
H
H
H
H
H
pic

2′-285X
Pd
1
2′
Ph
H
H
AAE1
H
H
H
H
H
acac

2′-285Y
Pd
0
2′
Ph
H
H
AAE1
H
H
H
H
H
—
—

2′-286
Pd
1
2′
Ph
H
AAE1
H
H
H
H
H
H
pic

2′-286X
Pd
1
2′
Ph
H
AAE1
H
H
H
H
H
H
acac

2′-286Y
Pd
0
2′
Ph
H
AAE1
H
H
H
H
H
H
—
—

2′-287
Pd
1
2′
Ph
H
H
AAE2
H
H
H
H
H
pic

2′-287X
Pd
1
2′
Ph
H
H
AAE2
H
H
H
H
H
acac

2′-287Y
Pd
0
2′
Ph
H
H
AAE2
H
H
H
H
H
—
—

2′-288
Pd
1
2′
Ph
H
AAE2
H
H
H
H
H
H
pic

2′-288X
Pd
1
2′
Ph
H
AAE2
H
H
H
H
H
H
acac

2′-288Y
Pd
0
2′
Ph
H
AAE2
H
H
H
H
H
H
—
—

2′-289
Pd
1
2′
Ph
H
H
PME1
H
H
H
H
H
pic

2′-289X
Pd
1
2′
Ph
H
H
PME1
H
H
H
H
H
acac

2′-289Y
Pd
0
2′
Ph
H
H
PME1
H
H
H
H
H
—
—

2′-290
Pd
1
2′
Ph
H
PME1
H
H
H
H
H
H
pic

2′-290X
Pd
1
2′
Ph
H
PME1
H
H
H
H
H
H
acac

2′-290Y
Pd
0
2′
Ph
H
PME1
H
H
H
H
H
H
—
—

2′-291
Pd
1
2′
Ph
H
H
PME2
H
H
H
H
H
pic

2′-291X
Pd
1
2′
Ph
H
H
PME2
H
H
H
H
H
acac

2′-291Y
Pd
0
2′
Ph
H
H
PME2
H
H
H
H
H
—
—

2′-292
Pd
1
2′
Ph
H
PME2
H
H
H
H
H
H
pic

2′-292X
Pd
1
2′
Ph
H
PME2
H
H
H
H
H
H
acac

2′-292Y
Pd
0
2′
Ph
H
PME2
H
H
H
H
H
H
—
—

2′-293
Pd
1
2′
Ph
H
H
MET1
H
H
H
H
H
pic

2′-293X
Pd
1
2′
Ph
H
H
MET1
H
H
H
H
H
acac

2′-293Y
Pd
0
2′
Ph
H
H
MET1
H
H
H
H
H
—
—

2′-294
Pd
1
2′
Ph
H
MET1
H
H
H
H
H
H
pic

2′-294X
Pd
1
2′
Ph
H
MET1
H
H
H
H
H
H
acac

2′-294Y
Pd
0
2′
Ph
H
MET1
H
H
H
H
H
H
—
—

2′-295
Pd
1
2′
Ph
H
H
MET2
H
H
H
H
H
pic

2′-295X
Pd
1
2′
Ph
H
H
MET2
H
H
H
H
H
acac

2′-295Y
Pd
0
2′
Ph
H
H
MET2
H
H
H
H
H
—
—

2′-296
Pd
1
2′
Ph
H
MET2
H
H
H
H
H
H
pic

2′-296X
Pd
1
2′
Ph
H
MET2
H
H
H
H
H
H
acac

2′-296Y
Pd
0
2′
Ph
H
MET2
H
H
H
H
H
H
—
—

2′-297
Pd
1
2′
Ph
H
H
EE1
H
H
H
H
H
pic

2′-297X
Pd
1
2′
Ph
H
H
EE1
H
H
H
H
H
acac

2′-297Y
Pd
0
2′
Ph
H
H
EE1
H
H
H
H
H
—
—

2′-298
Pd
1
2′
Ph
H
EE1
H
H
H
H
H
H
pic

2′-298X
Pd
1
2′
Ph
H
EE1
H
H
H
H
H
H
acac

2′-298Y
Pd
0
2′
Ph
H
EE1
H
H
H
H
H
H
—
—

2′-299
Pd
1
2′
Ph
H
H
EE2
H
H
H
H
H
pic

2′-299X
Pd
1
2′
Ph
H
H
EE2
H
H
H
H
H
acac

2′-299Y
Pd
0
2′
Ph
H
H
EE2
H
H
H
H
H
—
—

2′-300
Pd
1
2′
Ph
H
EE2
H
H
H
H
H
H
pic

2′-300X
Pd
1
2′
Ph
H
EE2
H
H
H
H
H
H
acac

2′-300Y
Pd
0
2′
Ph
H
EE2
H
H
H
H
H
H
—
—

2′-301
Pd
1
2′
Ph
H
H
MS1
H
H
H
H
H
pic

2′-301X
Pd
1
2′
Ph
H
H
MS1
H
H
H
H
H
acac

2′-301Y
Pd
0
2′
Ph
H
H
MS1
H
H
H
H
H
—
—

2′-302
Pd
1
2′
Ph
H
MS1
H
H
H
H
H
H
pic

2′-302X
Pd
1
2′
Ph
H
MS1
H
H
H
H
H
H
acac

2′-302Y
Pd
0
2′
Ph
H
MS1
H
H
H
H
H
H
—
—

2′-303
Pd
1
2′
Ph
H
H
MS2
H
H
H
H
H
pic

2′-303X
Pd
1
2′
Ph
H
H
MS2
H
H
H
H
H
acac

2′-303Y
Pd
0
2′
Ph
H
H
MS2
H
H
H
H
H
—
—

2′-304
Pd
1
2′
Ph
H
MS2
H
H
H
H
H
H
pic

2′-304X
Pd
1
2′
Ph
H
MS2
H
H
H
H
H
H
acac

2′-304Y
Pd
0
2′
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 45

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3′-155
Pd
1
3′
Ph
H
H
H
H
H
H
H
H
H
pic

3′-155X
Pd
1
3′
Ph
H
H
H
H
H
H
H
H
H
acac

3′-155Y
Pd
0
3′
Ph
H
H
H
H
H
H
H
H
H
—
—

3′-156
Pd
1
3′
Ph
H
F
H
F
H
H
H
H
H
pic

3′-156X
Pd
1
3′
Ph
H
F
H
F
H
H
H
H
H
acac

3′-156Y
Pd
0
3′
Ph
H
F
H
F
H
H
H
H
H
—
—

3′-157
Pd
1
3′
Ph
F
H
H
F
H
H
H
H
H
pic

3′-157X
Pd
1
3′
Ph
F
H
H
F
H
H
H
H
H
acac

3′-157Y
Pd
0
3′
Ph
F
H
H
F
H
H
H
H
H
—
—

3′-158
Pd
1
3′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
pic

3′-158X
Pd
1
3′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
acac

3′-158Y
Pd
0
3′
Ph
CF₃
H
CF₃
H
H
H
H
H
H
—
—

3′-159
Pd
1
3′
Ph
H
F
CF₃
H
H
H
H
H
H
pic

3′-159X
Pd
1
3′
Ph
H
F
CF₃
H
H
H
H
H
H
acac

3′-159Y
Pd
0
3′
Ph
H
F
CF₃
H
H
H
H
H
H
—
—

3′-160
Pd
1
3′
Ph
F
H
CF₃
H
H
H
H
H
H
pic

3′-160X
Pd
1
3′
Ph
F
H
CF₃
H
H
H
H
H
H
acac

3′-160Y
Pd
0
3′
Ph
F
H
CF₃
H
H
H
H
H
H
—
—

3′-161
Pd
1
3′
Ph
F
F
F
F
H
H
H
H
H
pic

3′-161X
Pd
1
3′
Ph
F
F
F
F
H
H
H
H
H
acac

3′-161Y
Pd
0
3′
Ph
F
F
F
F
H
H
H
H
H
—
—

3′-162
Pd
1
3′
Ph
H
F
H
CH₃
H
H
H
H
H
pic

3′-162X
Pd
1
3′
Ph
H
F
H
CH₃
H
H
H
H
H
acac

3′-162Y
Pd
0
3′
Ph
H
F
H
CH₃
H
H
H
H
H
—
—

3′-163
Pd
1
3′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
pic

3′-163X
Pd
1
3′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
acac

3′-163Y
Pd
0
3′
Ph
H
F
H

^tC₄H₉
H
H
H
H
H
—
—

3′-164
Pd
1
3′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
pic

3′-164X
Pd
1
3′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
acac

3′-164Y
Pd
0
3′
Ph
H
CF₃
H
CF₃
H
H
H
H
H
—
—

3′-165
Pd
1
3′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
pic

3′-165X
Pd
1
3′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
acac

3′-165Y
Pd
0
3′
Ph
CF₃
H
H

^tC₄H₉
H
H
H
H
H
—
—

3′-166
Pd
1
3′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
pic

3′-166X
Pd
1
3′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
acac

3′-166Y
Pd
0
3′
Ph
H
CF₃
H

^tC₄H₉
H
H
H
H
H
—
—

3′-167
Pd
1
3′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
pic

3′-167X
Pd
1
3′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
acac

3′-167Y
Pd
0
3′
Ph
H
CF₃
H
CH₃
H
H
H
H
H
—
—

3′-168
Pd
1
3′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
pic

3′-168X
Pd
1
3′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
acac

3′-168Y
Pd
0
3′
Ph
H
CF₃
CF₃
H
H
H
H
H
H
—
—

3′-169
Pd
1
3′
Ph
H
H
NO₂
H
H
H
H
H
H
pic

3′-169X
Pd
1
3′
Ph
H
H
NO₂
H
H
H
H
H
H
acac

3′-169Y
Pd
0
3′
Ph
H
H
NO₂
H
H
H
H
H
H
—
—

3′-170
Pd
1
3′
Ph
F
H
NO₂
H
H
H
H
H
H
pic

3′-170X
Pd
1
3′
Ph
F
H
NO₂
H
H
H
H
H
H
acac

3′-170Y
Pd
0
3′
Ph
F
H
NO₂
H
H
H
H
H
H
—
—

3′-171
Pd
1
3′
Ph
F
H
NO₂
F
H
H
H
H
H
pic

3′-171X
Pd
1
3′
Ph
F
H
NO₂
F
H
H
H
H
H
acac

3′-171Y
Pd
0
3′
Ph
F
H
NO₂
F
H
H
H
H
H
—
—

3′-172
Pd
1
3′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
pic

3′-172X
Pd
1
3′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
acac

3′-172Y
Pd
0
3′
Ph
H
NO₂
H
NO₂
H
H
H
H
H
—
—

3′-173
Pd
1
3′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
pic

3′-173X
Pd
1
3′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
acac

3′-173Y
Pd
0
3′
Ph
NO₂
H
H
NO₂
H
H
H
H
H
—
—

3′-174
Pd
1
3′
Ph
H
H
CF₃
H
H
H
H
H
H
pic

3′-174X
Pd
1
3′
Ph
H
H
CF₃
H
H
H
H
H
H
acac

3′-174Y
Pd
0
3′
Ph
H
H
CF₃
H
H
H
H
H
H
—
—

3′-175
Pd
1
3′
Ph
H
Cl
CF₃
H
H
H
H
H
H
pic

3′-175X
Pd
1
3′
Ph
H
Cl
CF₃
H
H
H
H
H
H
acac

3′-175Y
Pd
0
3′
Ph
H
Cl
CF₃
H
H
H
H
H
H
—
—

3′-176
Pd
1
3′
Ph
H
NO₂
H
H
H
H
H
H
H
pic

3′-176X
Pd
1
3′
Ph
H
NO₂
H
H
H
H
H
H
H
acac

3′-176Y
Pd
0
3′
Ph
H
NO₂
H
H
H
H
H
H
H
—
—

3′-177
Pd
1
3′
Ph
H
CF₃
H
H
H
H
H
H
H
pic

3′-177X
Pd
1
3′
Ph
H
CF₃
H
H
H
H
H
H
H
acac

3′-177Y
Pd
0
3′
Ph
H
CF₃
H
H
H
H
H
H
H
—
—

3′-178
Pd
1
3′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
pic

3′-178X
Pd
1
3′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
acac

3′-178Y
Pd
0
3′
Ph
H
NO₂
H
CH₃
H
H
H
H
H
—
—

3′-179
Pd
1
3′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
pic

3′-179X
Pd
1
3′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
acac

3′-179Y
Pd
0
3′
Ph
H
NO₂
H

^tC₄H₉
H
H
H
H
H
—
—

3′-180
Pd
1
3′
Ph
H
H
CH₃O
H
H
H
H
H
H
pic

3′-180X
Pd
1
3′
Ph
H
H
CH₃O
H
H
H
H
H
H
acac

3′-180Y
Pd
0
3′
Ph
H
H
CH₃O
H
H
H
H
H
H
—
—

3′-181
Pd
1
3′
Ph
H
CH₃O
H
H
H
H
H
H
H
pic

3′-181X
Pd
1
3′
Ph
H
CH₃O
H
H
H
H
H
H
H
acac

3′-181Y
Pd
0
3′
Ph
H
CH₃O
H
H
H
H
H
H
H
—
—

3′-182
Pd
1
3′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
pic

3′-182X
Pd
1
3′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
acac

3′-182Y
Pd
0
3′
Ph
H
CH₃O
H
CH₃
H
H
H
H
H
—
—

3′-183
Pd
1
3′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
pic

3′-183X
Pd
1
3′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
acac

3′-183Y
Pd
0
3′
Ph
H
CH₃O
H

^tC₄H₉
H
H
H
H
H
—
—

3′-184
Pd
1
3′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

3′-184X
Pd
1
3′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

3′-184Y
Pd
0
3′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

3′-185
Pd
1
3′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

3′-185X
Pd
1
3′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

3′-185Y
Pd
0
3′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

3′-186
Pd
1
3′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

3′-186X
Pd
1
3′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

3′-186Y
Pd
0
3′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

3′-187
Pd
1
3′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
pic

3′-187X
Pd
1
3′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
acac

3′-187Y
Pd
0
3′
Ph
H
CF₃
H
CH₃

^tC₄H₉
H
H
H
H
—
—

3′-188
Pd
1
3′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
pic

3′-188X
Pd
1
3′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
acac

3′-188Y
Pd
0
3′
Ph
H
Si(CH₃)₃
H
H
H
H
H
H
H
—
—

3′-189
Pd
1
3′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3′-189X
Pd
1
3′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3′-189Y
Pd
0
3′
Ph
H
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3′-190
Pd
1
3′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
pic

3′-190X
Pd
1
3′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
acac

3′-190Y
Pd
0
3′
Ph
H
H
H
Si(CH₃)₃
H
H
H
H
H
—
—

3′-191
Pd
1
3′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
pic

3′-191X
Pd
1
3′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
acac

3′-191Y
Pd
0
3′
Ph
H
F
H
Si(CH₃)₃
H
H
H
H
H
—
—

3′-192
Pd
1
3′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
pic

3′-192X
Pd
1
3′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
acac

3′-192Y
Pd
0
3′
Ph
H
CF₃
H
Si(CH₃)₃
H
H
H
H
H
—
—

3′-193
Pd
1
3′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
pic

3′-193X
Pd
1
3′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
acac

3′-193Y
Pd
0
3′
Ph
H
Si(CH₃)₃
H
F
H
H
H
H
H
—
—

3′-194
Pd
1
3′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
pic

3′-194X
Pd
1
3′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
acac

3′-194Y
Pd
0
3′
Ph
H
Si(CH₃)₃
H
CF₃
H
H
H
H
H
—
—

3′-195
Pd
1
3′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
pic

3′-195X
Pd
1
3′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
acac

3′-195Y
Pd
0
3′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
H
H
H
H
—
—

3′-196
Pd
1
3′
Ph
H
H
H
COCH₃
H
H
H
H
H
pic

3′-196X
Pd
1
3′
Ph
H
H
H
COCH₃
H
H
H
H
H
acac

3′-196Y
Pd
0
3′
Ph
H
H
H
COCH₃
H
H
H
H
H
—
—

3′-197
Pd
1
3′
Ph
H
H
COCH₃
H
H
H
H
H
H
pic

3′-197X
Pd
1
3′
Ph
H
H
COCH₃
H
H
H
H
H
H
acac

3′-197Y
Pd
0
3′
Ph
H
H
COCH₃
H
H
H
H
H
H
—
—

3′-198
Pd
1
3′
Ph
H
COCH₃
H
H
H
H
H
H
H
pic

3′-198X
Pd
1
3′
Ph
H
COCH₃
H
H
H
H
H
H
H
acac

3′-198Y
Pd
0
3′
Ph
H
COCH₃
H
H
H
H
H
H
H
—
—

3′-199
Pd
1
3′
Ph
H
H
BL
H
H
H
H
H
pic

3′-199X
Pd
1
3′
Ph
H
H
BL
H
H
H
H
H
acac

3′-199Y
Pd
0
3′
Ph
H
H
BL
H
H
H
H
H
—
—

3′-200
Pd
1
3′
Ph
H
BL
H
H
H
H
H
H
pic

3′-200X
Pd
1
3′
Ph
H
BL
H
H
H
H
H
H
acac

3′-200Y
Pd
0
3′
Ph
H
BL
H
H
H
H
H
H
—
—

3′-201
Pd
1
3′
Ph
H
H
PL
H
H
H
H
H
pic

3′-201X
Pd
1
3′
Ph
H
H
PL
H
H
H
H
H
acac

3′-201Y
Pd
0
3′
Ph
H
H
PL
H
H
H
H
H
—
—

3′-202
Pd
1
3′
Ph
H
PL
H
H
H
H
H
H
pic

3′-202X
Pd
1
3′
Ph
H
PL
H
H
H
H
H
H
acac

3′-202Y
Pd
0
3′
Ph
H
PL
H
H
H
H
H
H
—
—

3′-203
Pd
1
3′
Ph
H
H
MEE1
H
H
H
H
H
pic

3′-203X
Pd
1
3′
Ph
H
H
MEE1
H
H
H
H
H
acac

3′-203Y
Pd
0
3′
Ph
H
H
MEE1
H
H
H
H
H
—
—

3′-204
Pd
1
3′
Ph
H
MEE1
H
H
H
H
H
H
pic

3′-204X
Pd
1
3′
Ph
H
MEE1
H
H
H
H
H
H
acac

3′-204Y
Pd
0
3′
Ph
H
MEE1
H
H
H
H
H
H
—
—

3′-205
Pd
1
3′
Ph
H
H
MEE2
H
H
H
H
H
pic

3′-205X
Pd
1
3′
Ph
H
H
MEE2
H
H
H
H
H
acac

3′-205Y
Pd
0
3′
Ph
H
H
MEE2
H
H
H
H
H
—
—

3′-206
Pd
1
3′
Ph
H
MEE2
H
H
H
H
H
H
pic

3′-206X
Pd
1
3′
Ph
H
MEE2
H
H
H
H
H
H
acac

3′-206Y
Pd
0
3′
Ph
H
MEE2
H
H
H
H
H
H
—
—

3′-207
Pd
1
3′
Ph
H
H
PA1
H
H
H
H
H
pic

3′-207X
Pd
1
3′
Ph
H
H
PA1
H
H
H
H
H
acac

3′-207Y
Pd
0
3′
Ph
H
H
PA1
H
H
H
H
H
—
—

3′-208
Pd
1
3′
Ph
H
PA1
H
H
H
H
H
H
pic

3′-208X
Pd
1
3′
Ph
H
PA1
H
H
H
H
H
H
acac

3′-208Y
Pd
0
3′
Ph
H
PA1
H
H
H
H
H
H
—
—

3′-209
Pd
1
3′
Ph
H
H
PA2
H
H
H
H
H
pic

3′-209X
Pd
1
3′
Ph
H
H
PA2
H
H
H
H
H
acac

3′-209Y
Pd
0
3′
Ph
H
H
PA2
H
H
H
H
H
—
—

3′-210
Pd
1
3′
Ph
H
PA2
H
H
H
H
H
H
pic

3′-210X
Pd
1
3′
Ph
H
PA2
H
H
H
H
H
H
acac

3′-210Y
Pd
0
3′
Ph
H
PA2
H
H
H
H
H
H
—
—

3′-211
Pd
1
3′
Ph
H
H
EA1
H
H
H
H
H
pic

3′-211X
Pd
1
3′
Ph
H
H
EA1
H
H
H
H
H
acac

3′-211Y
Pd
0
3′
Ph
H
H
EA1
H
H
H
H
H
—
—

3′-212
Pd
1
3′
Ph
H
EA2
H
H
H
H
H
H
pic

3′-212X
Pd
1
3′
Ph
H
EA2
H
H
H
H
H
H
acac

3′-212Y
Pd
0
3′
Ph
H
EA2
H
H
H
H
H
H
—
—

3′-213
Pd
1
3′
Ph
H
H
ME
H
H
H
H
H
pic

3′-213X
Pd
1
3′
Ph
H
H
ME
H
H
H
H
H
acac

3′-213Y
Pd
0
3′
Ph
H
H
ME
H
H
H
H
H
—
—

3′-214
Pd
1
3′
Ph
H
ME
H
H
H
H
H
H
pic

3′-214X
Pd
1
3′
Ph
H
ME
H
H
H
H
H
H
acac

3′-214Y
Pd
0
3′
Ph
H
ME
H
H
H
H
H
H
—
—

3′-215
Pd
1
3′
Ph
H
H
AT
H
H
H
H
H
pic

3′-215X
Pd
1
3′
Ph
H
H
AT
H
H
H
H
H
acac

3′-215Y
Pd
0
3′
Ph
H
H
AT
H
H
H
H
H
—
—

3′-216
Pd
1
3′
Ph
H
AT
H
H
H
H
H
H
pic

3′-216X
Pd
1
3′
Ph
H
AT
H
H
H
H
H
H
acac

3′-216Y
Pd
0
3′
Ph
H
AT
H
H
H
H
H
H
—
—

3′-217
Pd
1
3′
Ph
H
H
MES1
H
H
H
H
H
pic

3′-217X
Pd
1
3′
Ph
H
H
MES1
H
H
H
H
H
acac

3′-217Y
Pd
0
3′
Ph
H
H
MES1
H
H
H
H
H
—
—

3′-218
Pd
1
3′
Ph
H
MES1
H
H
H
H
H
H
pic

3′-218X
Pd
1
3′
Ph
H
MES1
H
H
H
H
H
H
acac

3′-218Y
Pd
0
3′
Ph
H
MES1
H
H
H
H
H
H
—
—

3′-219
Pd
1
3′
Ph
H
H
MES2
H
H
H
H
H
pic

3′-219X
Pd
1
3′
Ph
H
H
MES2
H
H
H
H
H
acac

3′-219Y
Pd
0
3′
Ph
H
H
MES2
H
H
H
H
H
—
—

3′-220
Pd
1
3′
Ph
H
MES2
H
H
H
H
H
H
pic

3′-220X
Pd
1
3′
Ph
H
MES2
H
H
H
H
H
H
acac

3′-220Y
Pd
0
3′
Ph
H
MES2
H
H
H
H
H
H
—
—

3′-221
Pd
1
3′
Ph
H
H
PS1
H
H
H
H
H
pic

3′-221X
Pd
1
3′
Ph
H
H
PS1
H
H
H
H
H
acac

3′-221Y
Pd
0
3′
Ph
H
H
PS1
H
H
H
H
H
—
—

3′-222
Pd
1
3′
Ph
H
PS1
H
H
H
H
H
H
pic

3′-222X
Pd
1
3′
Ph
H
PS1
H
H
H
H
H
H
acac

3′-222Y
Pd
0
3′
Ph
H
PS1
H
H
H
H
H
H
—
—

3′-223
Pd
1
3′
Ph
H
H
PS2
H
H
H
H
H
pic

3′-223X
Pd
1
3′
Ph
H
H
PS2
H
H
H
H
H
acac

3′-223Y
Pd
0
3′
Ph
H
H
PS2
H
H
H
H
H
—
—

3′-224
Pd
1
3′
Ph
H
PS2
H
H
H
H
H
H
pic

3′-224X
Pd
1
3′
Ph
H
PS2
H
H
H
H
H
H
acac

3′-224Y
Pd
0
3′
Ph
H
PS2
H
H
H
H
H
H
—
—

3′-225
Pd
1
3′
Ph
H
H
BAL1
H
H
H
H
H
pic

3′-225X
Pd
1
3′
Ph
H
H
BAL1
H
H
H
H
H
acac

3′-225Y
Pd
0
3′
Ph
H
H
BAL1
H
H
H
H
H
—
—

3′-226
Pd
1
3′
Ph
H
BAL1
H
H
H
H
H
H
pic

3′-226X
Pd
1
3′
Ph
H
BAL1
H
H
H
H
H
H
acac

3′-226Y
Pd
0
3′
Ph
H
BAL1
H
H
H
H
H
H
—
—

3′-227
Pd
1
3′
Ph
H
H
BAL2
H
H
H
H
H
pic

3′-227X
Pd
1
3′
Ph
H
H
BAL2
H
H
H
H
H
acac

3′-227Y
Pd
0
3′
Ph
H
H
BAL2
H
H
H
H
H
—
—

3′-228
Pd
1
3′
Ph
H
BAL2
H
H
H
H
H
H
pic

3′-228X
Pd
1
3′
Ph
H
BAL2
H
H
H
H
H
H
acac

3′-228Y
Pd
0
3′
Ph
H
BAL2
H
H
H
H
H
H
—
—

3′-229
Pd
1
3′
Ph
H
H
MEK1
H
H
H
H
H
pic

3′-229X
Pd
1
3′
Ph
H
H
MEK1
H
H
H
H
H
acac

3′-229Y
Pd
0
3′
Ph
H
H
MEK1
H
H
H
H
H
—
—

3′-230
Pd
1
3′
Ph
H
MEK1
H
H
H
H
H
H
pic

3′-230X
Pd
1
3′
Ph
H
MEK1
H
H
H
H
H
H
acac

3′-230Y
Pd
0
3′
Ph
H
MEK1
H
H
H
H
H
H
—
—

3′-231
Pd
1
3′
Ph
H
H
MEK2
H
H
H
H
H
pic

3′-231X
Pd
1
3′
Ph
H
H
MEK2
H
H
H
H
H
acac

3′-231Y
Pd
0
3′
Ph
H
H
MEK2
H
H
H
H
H
—
—

3′-232
Pd
1
3′
Ph
H
MEK2
H
H
H
H
H
H
pic

3′-232X
Pd
1
3′
Ph
H
MEK2
H
H
H
H
H
H
acac

3′-232Y
Pd
0
3′
Ph
H
MEK2
H
H
H
H
H
H
—
—

3′-233
Pd
1
3′
Ph
H
H
PAL1
H
H
H
H
H
pic

3′-233X
Pd
1
3′
Ph
H
H
PAL1
H
H
H
H
H
acac

3′-233Y
Pd
0
3′
Ph
H
H
PAL1
H
H
H
H
H
—
—

3′-234
Pd
1
3′
Ph
H
PAL1
H
H
H
H
H
H
pic

3′-234X
Pd
1
3′
Ph
H
PAL1
H
H
H
H
H
H
acac

3′-234Y
Pd
0
3′
Ph
H
PAL1
H
H
H
H
H
H
—
—

3′-235
Pd
1
3′
Ph
H
H
PAL2
H
H
H
H
H
pic

3′-235X
Pd
1
3′
Ph
H
H
PAL2
H
H
H
H
H
acac

3′-235Y
Pd
0
3′
Ph
H
H
PAL2
H
H
H
H
H
—
—

3′-236
Pd
1
3′
Ph
H
PAL2
H
H
H
H
H
H
pic

3′-236X
Pd
1
3′
Ph
H
PAL2
H
H
H
H
H
H
acac

3′-236Y
Pd
0
3′
Ph
H
PAL2
H
H
H
H
H
H
—
—

3′-237
Pd
1
3′
Ph
H
H
MMK
H
H
H
H
H
pic

3′-237X
Pd
1
3′
Ph
H
H
MMK
H
H
H
H
H
acac

3′-237Y
Pd
0
3′
Ph
H
H
MMK
H
H
H
H
H
—
—

3′-238
Pd
1
3′
Ph
H
MMK
H
H
H
H
H
H
pic

3′-238X
Pd
1
3′
Ph
H
MMK
H
H
H
H
H
H
acac

3′-238Y
Pd
0
3′
Ph
H
MMK
H
H
H
H
H
H
—
—

3′-239
Pd
1
3′
Ph
H
H
EES1
H
H
H
H
H
pic

3′-239X
Pd
1
3′
Ph
H
H
EES1
H
H
H
H
H
acac

3′-239Y
Pd
0
3′
Ph
H
H
EES1
H
H
H
H
H
—
—

3′-240
Pd
1
3′
Ph
H
EES2
H
H
H
H
H
H
pic

3′-240X
Pd
1
3′
Ph
H
EES2
H
H
H
H
H
H
acac

3′-240Y
Pd
0
3′
Ph
H
EES2
H
H
H
H
H
H
—
—

3′-241
Pd
1
3′
Ph
H
H
PAE1
H
H
H
H
H
pic

3′-241X
Pd
1
3′
Ph
H
H
PAE1
H
H
H
H
H
acac

3′-241Y
Pd
0
3′
Ph
H
H
PAE1
H
H
H
H
H
—
—

3′-242
Pd
1
3′
Ph
H
PAE2
H
H
H
H
H
H
pic

3′-242X
Pd
1
3′
Ph
H
PAE2
H
H
H
H
H
H
acac

3′-242Y
Pd
0
3′
Ph
H
PAE2
H
H
H
H
H
H
—
—

3′-243
Pd
1
3′
Ph
H
H
AME1
H
H
H
H
H
pic

3′-243X
Pd
1
3′
Ph
H
H
AME1
H
H
H
H
H
acac

3′-243Y
Pd
0
3′
Ph
H
H
AME1
H
H
H
H
H
—
—

3′-244
Pd
1
3′
Ph
H
AME1
H
H
H
H
H
H
pic

3′-244X
Pd
1
3′
Ph
H
AME1
H
H
H
H
H
H
acac

3′-244Y
Pd
0
3′
Ph
H
AME1
H
H
H
H
H
H
—
—

3′-245
Pd
1
3′
Ph
H
H
AME2
H
H
H
H
H
pic

3′-245X
Pd
1
3′
Ph
H
H
AME2
H
H
H
H
H
acac

3′-245Y
Pd
0
3′
Ph
H
H
AME2
H
H
H
H
H
—
—

3′-246
Pd
1
3′
Ph
H
AME2
H
H
H
H
H
H
pic

3′-246X
Pd
1
3′
Ph
H
AME2
H
H
H
H
H
H
acac

3′-246Y
Pd
0
3′
Ph
H
AME2
H
H
H
H
H
H
—
—

3′-247
Pd
1
3′
Ph
H
H
EAE1
H
H
H
H
H
pic

3′-247X
Pd
1
3′
Ph
H
H
EAE1
H
H
H
H
H
acac

3′-247Y
Pd
0
3′
Ph
H
H
EAE1
H
H
H
H
H
—
—

3′-248
Pd
1
3′
Ph
H
EAE1
H
H
H
H
H
H
pic

3′-248X
Pd
1
3′
Ph
H
EAE1
H
H
H
H
H
H
acac

3′-248Y
Pd
0
3′
Ph
H
EAE1
H
H
H
H
H
H
—
—

3′-249
Pd
1
3′
Ph
H
H
EAE2
H
H
H
H
H
pic

3′-249X
Pd
1
3′
Ph
H
H
EAE2
H
H
H
H
H
acac

3′-249Y
Pd
0
3′
Ph
H
H
EAE2
H
H
H
H
H
—
—

3′-250
Pd
1
3′
Ph
H
EAE2
H
H
H
H
H
H
pic

3′-250X
Pd
1
3′
Ph
H
EAE2
H
H
H
H
H
H
acac

3′-250Y
Pd
0
3′
Ph
H
EAE2
H
H
H
H
H
H
—
—

3′-251
Pd
1
3′
Ph
H
H
AAE1
H
H
H
H
H
pic

3′-251X
Pd
1
3′
Ph
H
H
AAE1
H
H
H
H
H
acac

3′-251Y
Pd
0
3′
Ph
H
H
AAE1
H
H
H
H
H
—
—

3′-252
Pd
1
3′
Ph
H
AAE1
H
H
H
H
H
H
pic

3′-252X
Pd
1
3′
Ph
H
AAE1
H
H
H
H
H
H
acac

3′-252Y
Pd
0
3′
Ph
H
AAE1
H
H
H
H
H
H
—
—

3′-253
Pd
1
3′
Ph
H
H
AAE2
H
H
H
H
H
pic

3′-253X
Pd
1
3′
Ph
H
H
AAE2
H
H
H
H
H
acac

3′-253Y
Pd
0
3′
Ph
H
H
AAE2
H
H
H
H
H
—
—

3′-254
Pd
1
3′
Ph
H
AAE2
H
H
H
H
H
H
pic

3′-254X
Pd
1
3′
Ph
H
AAE2
H
H
H
H
H
H
acac

3′-254Y
Pd
0
3′
Ph
H
AAE2
H
H
H
H
H
H
—
—

3′-255
Pd
1
3′
Ph
H
H
PME1
H
H
H
H
H
pic

3′-255X
Pd
1
3′
Ph
H
H
PME1
H
H
H
H
H
acac

3′-255Y
Pd
0
3′
Ph
H
H
PME1
H
H
H
H
H
—
—

3′-256
Pd
1
3′
Ph
H
PME1
H
H
H
H
H
H
pic

3′-256X
Pd
1
3′
Ph
H
PME1
H
H
H
H
H
H
acac

3′-256Y
Pd
0
3′
Ph
H
PME1
H
H
H
H
H
H
—
—

3′-257
Pd
1
3′
Ph
H
H
PME2
H
H
H
H
H
pic

3′-257X
Pd
1
3′
Ph
H
H
PME2
H
H
H
H
H
acac

3′-257Y
Pd
0
3′
Ph
H
H
PME2
H
H
H
H
H
—
—

3′-258
Pd
1
3′
Ph
H
PME2
H
H
H
H
H
H
pic

3′-258X
Pd
1
3′
Ph
H
PME2
H
H
H
H
H
H
acac

3′-258Y
Pd
0
3′
Ph
H
PME2
H
H
H
H
H
H
—
—

3′-259
Pd
1
3′
Ph
H
H
MET1
H
H
H
H
H
pic

3′-259X
Pd
1
3′
Ph
H
H
MET1
H
H
H
H
H
acac

3′-259Y
Pd
0
3′
Ph
H
H
MET1
H
H
H
H
H
—
—

3′-260
Pd
1
3′
Ph
H
MET1
H
H
H
H
H
H
pic

3′-260X
Pd
1
3′
Ph
H
MET1
H
H
H
H
H
H
acac

3′-260Y
Pd
0
3′
Ph
H
MET1
H
H
H
H
H
H
—
—

3′-261
Pd
1
3′
Ph
H
H
MET2
H
H
H
H
H
pic

3′-261X
Pd
1
3′
Ph
H
H
MET2
H
H
H
H
H
acac

3′-261Y
Pd
0
3′
Ph
H
H
MET2
H
H
H
H
H
—
—

3′-262
Pd
1
3′
Ph
H
MET2
H
H
H
H
H
H
pic

3′-262X
Pd
1
3′
Ph
H
MET2
H
H
H
H
H
H
acac

3′-262Y
Pd
0
3′
Ph
H
MET2
H
H
H
H
H
H
—
—

3′-263
Pd
1
3′
Ph
H
H
EE1
H
H
H
H
H
pic

3′-263X
Pd
1
3′
Ph
H
H
EE1
H
H
H
H
H
acac

3′-263Y
Pd
0
3′
Ph
H
H
EE1
H
H
H
H
H
—
—

3′-264
Pd
1
3′
Ph
H
EE1
H
H
H
H
H
H
pic

3′-264X
Pd
1
3′
Ph
H
EE1
H
H
H
H
H
H
acac

3′-264Y
Pd
0
3′
Ph
H
EE1
H
H
H
H
H
H
—
—

3′-265
Pd
1
3′
Ph
H
H
EE2
H
H
H
H
H
pic

3′-265X
Pd
1
3′
Ph
H
H
EE2
H
H
H
H
H
acac

3′-265Y
Pd
0
3′
Ph
H
H
EE2
H
H
H
H
H
—
—

3′-266
Pd
1
3′
Ph
H
EE2
H
H
H
H
H
H
pic

3′-266X
Pd
1
3′
Ph
H
EE2
H
H
H
H
H
H
acac

3′-266Y
Pd
0
3′
Ph
H
EE2
H
H
H
H
H
H
—
—

3′-267
Pd
1
3′
Ph
H
H
MS1
H
H
H
H
H
pic

3′-267X
Pd
1
3′
Ph
H
H
MS1
H
H
H
H
H
acac

3′-267Y
Pd
0
3′
Ph
H
H
MS1
H
H
H
H
H
—
—

3′-268
Pd
1
3′
Ph
H
MS1
H
H
H
H
H
H
pic

3′-268X
Pd
1
3′
Ph
H
MS1
H
H
H
H
H
H
acac

3′-268Y
Pd
0
3′
Ph
H
MS1
H
H
H
H
H
H
—
—

3′-269
Pd
1
3′
Ph
H
H
MS2
H
H
H
H
H
pic

3′-269X
Pd
1
3′
Ph
H
H
MS2
H
H
H
H
H
acac

3′-269Y
Pd
0
3′
Ph
H
H
MS2
H
H
H
H
H
—
—

3′-270
Pd
1
3′
Ph
H
MS2
H
H
H
H
H
H
pic

3′-270X
Pd
1
3′
Ph
H
MS2
H
H
H
H
H
H
acac

3′-270Y
Pd
0
3′
Ph
H
MS2
H
H
H
H
H
H
—
—

TABLE 46

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4′-167
Pd
1
4′
Ph
H
H
H
H
CH₃
H
H
H
H
pic

4′-167X
Pd
1
4′
Ph
H
H
H
H
CH₃
H
H
H
H
acac

4′-167Y
Pd
0
4′
Ph
H
H
H
H
CH₃
H
H
H
H
—
—

4′-168
Pd
1
4′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
pic

4′-168X
Pd
1
4′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
acac

4′-168Y
Pd
0
4′
Ph
H
H
H
H

^tC₄H₉
H
H
H
H
—
—

4′-169
Pd
1
4′
Ph
H
F
H
F
CH₃
H
H
H
H
pic

4′-169X
Pd
1
4′
Ph
H
F
H
F
CH₃
H
H
H
H
acac

4′-169Y
Pd
0
4′
Ph
H
F
H
F
CH₃
H
H
H
H
—
—

4′-170
Pd
1
4′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
pic

4′-170X
Pd
1
4′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
acac

4′-170Y
Pd
0
4′
Ph
H
F
H
F

^tC₄H₉
H
H
H
H
—
—

4′-171
Pd
1
4′
Ph
F
H
H
F
CH₃
H
H
H
H
pic

4′-171X
Pd
1
4′
Ph
F
H
H
F
CH₃
H
H
H
H
acac

4′-171Y
Pd
0
4′
Ph
F
H
H
F
CH₃
H
H
H
H
—
—

4′-172
Pd
1
4′
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
pic

4′-172X
Pd
1
4′
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
acac

4′-172Y
Pd
0
4′
Ph
F
H
H
F

^tC₄H₉
H
H
H
H
—
—

4′-173
Pd
1
4′
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
pic

4′-173X
Pd
1
4′
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
acac

4′-173Y
Pd
0
4′
Ph
CF₃
H
CF₃
H
CH₃
H
H
H
H
—
—

4′-174
Pd
1
4′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

4′-174X
Pd
1
4′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

4′-174Y
Pd
0
4′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4′-175
Pd
1
4′
Ph
H
F
CF₃
H
CH₃
H
H
H
H
pic

4′-175X
Pd
1
4′
Ph
H
F
CF₃
H
CH₃
H
H
H
H
acac

4′-175Y
Pd
0
4′
Ph
H
F
CF₃
H
CH₃
H
H
H
H
—
—

4′-176
Pd
1
4′
Ph
F
H
CF₃
H
CH₃
H
H
H
H
pic

4′-176X
Pd
1
4′
Ph
F
H
CF₃
H
CH₃
H
H
H
H
acac

4′-176Y
Pd
0
4′
Ph
F
H
CF₃
H
CH₃
H
H
H
H
—
—

4′-177
Pd
1
4′
Ph
F
F
F
F
CH₃
H
H
H
H
pic

4′-177X
Pd
1
4′
Ph
F
F
F
F
CH₃
H
H
H
H
acac

4′-177Y
Pd
0
4′
Ph
F
F
F
F
CH₃
H
H
H
H
—
—

4′-178
Pd
1
4′
Ph
H
F
H
CH₃
CH₃
H
H
H
H
pic

4′-178X
Pd
1
4′
Ph
H
F
H
CH₃
CH₃
H
H
H
H
acac

4′-178Y
Pd
0
4′
Ph
H
F
H
CH₃
CH₃
H
H
H
H
—
—

4′-179
Pd
1
4′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
pic

4′-179X
Pd
1
4′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
acac

4′-179Y
Pd
0
4′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
H
H
—
—

4′-180
Pd
1
4′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-180X
Pd
1
4′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-180Y
Pd
0
4′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-181
Pd
1
4′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-181X
Pd
1
4′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-181Y
Pd
0
4′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-182
Pd
1
4′
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
pic

4′-182X
Pd
1
4′
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
acac

4′-182Y
Pd
0
4′
Ph
H
CF₃
H
CF₃
CH₃
H
H
H
H
—
—

4′-183
Pd
1
4′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

4′-183X
Pd
1
4′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

4′-183Y
Pd
0
4′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

4′-184
Pd
1
4′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-184X
Pd
1
4′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-184Y
Pd
0
4′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-185
Pd
1
4′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-185X
Pd
1
4′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-185Y
Pd
0
4′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-186
Pd
1
4′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-186X
Pd
1
4′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-186Y
Pd
0
4′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-187
Pd
1
4′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-187X
Pd
1
4′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-187Y
Pd
0
4′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-188
Pd
1
4′
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
pic

4′-188X
Pd
1
4′
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
acac

4′-188Y
Pd
0
4′
Ph
H
CF₃
H
CH₃
CH₃
H
H
H
H
—
—

4′-189
Pd
1
4′
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
pic

4′-189X
Pd
1
4′
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
acac

4′-189Y
Pd
0
4′
Ph
H
CF₃
CF₃
H
CH₃
H
H
H
H
—
—

4′-190
Pd
1
4′
Ph
H
H
NO₂
H
CH₃
H
H
H
H
pic

4′-190X
Pd
1
4′
Ph
H
H
NO₂
H
CH₃
H
H
H
H
acac

4′-190Y
Pd
0
4′
Ph
H
H
NO₂
H
CH₃
H
H
H
H
—
—

4′-191
Pd
1
4′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
pic

4′-191X
Pd
1
4′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
acac

4′-191Y
Pd
0
4′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
H
H
—
—

4′-192
Pd
1
4′
Ph
F
H
NO₂
H
CH₃
H
H
H
H
pic

4′-192X
Pd
1
4′
Ph
F
H
NO₂
H
CH₃
H
H
H
H
acac

4′-192Y
Pd
0
4′
Ph
F
H
NO₂
H
CH₃
H
H
H
H
—
—

4′-193
Pd
1
4′
Ph
F
H
NO₂
F
CH₃
H
H
H
H
pic

4′-193X
Pd
1
4′
Ph
F
H
NO₂
F
CH₃
H
H
H
H
acac

4′-193Y
Pd
0
4′
Ph
F
H
NO₂
F
CH₃
H
H
H
H
—
—

4′-194
Pd
1
4′
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
pic

4′-194X
Pd
1
4′
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
acac

4′-194Y
Pd
0
4′
Ph
H
NO₂
H
NO₂
CH₃
H
H
H
H
—
—

4′-195
Pd
1
4′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
pic

4′-195X
Pd
1
4′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
acac

4′-195Y
Pd
0
4′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
H
H
—
—

4′-196
Pd
1
4′
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
pic

4′-196X
Pd
1
4′
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
acac

4′-196Y
Pd
0
4′
Ph
NO₂
H
H
NO₂
CH₃
H
H
H
H
—
—

4′-197
Pd
1
4′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
pic

4′-197X
Pd
1
4′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
acac

4′-197Y
Pd
0
4′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
H
H
—
—

4′-198
Pd
1
4′
Ph
H
H
CF₃
H
CH₃
H
H
H
H
pic

4′-198X
Pd
1
4′
Ph
H
H
CF₃
H
CH₃
H
H
H
H
acac

4′-198Y
Pd
0
4′
Ph
H
H
CF₃
H
CH₃
H
H
H
H
—
—

4′-199
Pd
1
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
pic

4′-199X
Pd
1
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
acac

4′-199Y
Pd
0
4′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4′-200
Pd
1
4′
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
pic

4′-200X
Pd
1
4′
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
acac

4′-200Y
Pd
0
4′
Ph
H
Cl
CF₃
H
CH₃
H
H
H
H
—
—

4′-201
Pd
1
4′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
pic

4′-201X
Pd
1
4′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
acac

4′-201Y
Pd
0
4′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
H
H
—
—

4′-202
Pd
1
4′
Ph
H
NO₂
H
H
CH₃
H
H
H
H
pic

4′-202X
Pd
1
4′
Ph
H
NO₂
H
H
CH₃
H
H
H
H
acac

4′-202Y
Pd
0
4′
Ph
H
NO₂
H
H
CH₃
H
H
H
H
—
—

4′-203
Pd
1
4′
Ph
H
CF₃
H
H
CH₃
H
H
H
H
pic

4′-203X
Pd
1
4′
Ph
H
CF₃
H
H
CH₃
H
H
H
H
acac

4′-203Y
Pd
0
4′
Ph
H
CF₃
H
H
CH₃
H
H
H
H
—
—

4′-204
Pd
1
4′
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
pic

4′-204X
Pd
1
4′
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
acac

4′-204Y
Pd
0
4′
Ph
H
NO₂
H
CH₃
CH₃
H
H
H
H
—
—

4′-205
Pd
1
4′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
pic

4′-205X
Pd
1
4′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
acac

4′-205Y
Pd
0
4′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
H
H
—
—

4′-206
Pd
1
4′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-206X
Pd
1
4′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-206Y
Pd
0
4′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-207
Pd
1
4′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′-207X
Pd
1
4′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′-207Y
Pd
0
4′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′-208
Pd
1
4′
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
pic

4′-208X
Pd
1
4′
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
acac

4′-208Y
Pd
0
4′
Ph
H
H
CH₃O
H
CH₃
H
H
H
H
—
—

4′-209
Pd
1
4′
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
pic

4′-209X
Pd
1
4′
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
acac

4′-209Y
Pd
0
4′
Ph
H
CH₃O
H
H
CH₃
H
H
H
H
—
—

4′-210
Pd
1
4′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
pic

4′-210X
Pd
1
4′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
acac

4′-210Y
Pd
0
4′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
H
H
—
—

4′-211
Pd
1
4′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′-211X
Pd
1
4′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′-211Y
Pd
0
4′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′-212
Pd
1
4′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
pic

4′-212X
Pd
1
4′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
acac

4′-212Y
Pd
0
4′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
H
H
—
—

4′-213
Pd
1
4′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
pic

4′-213X
Pd
1
4′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
acac

4′-213Y
Pd
0
4′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
H
H
—
—

4′-214
Pd
1
4′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4′-214X
Pd
1
4′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4′-214Y
Pd
0
4′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4′-215
Pd
1
4′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4′-215X
Pd
1
4′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4′-215Y
Pd
0
4′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4′-216
Pd
1
4′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4′-216X
Pd
1
4′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4′-216Y
Pd
0
4′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4′-217
Pd
1
4′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
pic

4′-217X
Pd
1
4′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
acac

4′-217Y
Pd
0
4′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
H
H
—
—

4′-218
Pd
1
4′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
H
H
pic

4′-218X
Pd
1
4′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
H
H
acac

4′-218Y
Pd
0
4′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
H
H
—
—

4′-219
Pd
1
4′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
pic

4′-219X
Pd
1
4′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
acac

4′-219Y
Pd
0
4′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
H
H
—
—

4′-220
Pd
1
4′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
pic

4′-220X
Pd
1
4′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
acac

4′-220Y
Pd
0
4′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
H
H
—
—

4′-221
Pd
1
4′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
pic

4′-221X
Pd
1
4′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
acac

4′-221Y
Pd
0
4′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
H
H
—
—

4′-222
Pd
1
4′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
pic

4′-222X
Pd
1
4′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
acac

4′-222Y
Pd
0
4′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
H
H
—
—

4′-223
Pd
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
pic

4′-223X
Pd
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
acac

4′-223Y
Pd
0
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
H
H
—
—

4′-224
Pd
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
pic

4′-224X
Pd
1
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
acac

4′-224Y
Pd
0
4′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
H
H
—
—

4′-225
Pd
1
4′
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
pic

4′-225X
Pd
1
4′
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
acac

4′-225Y
Pd
0
4′
Ph
H
H
H
COCH₃
CH₃
H
H
H
H
—
—

4′-226
Pd
1
4′
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
pic

4′-226X
Pd
1
4′
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
acac

4′-226Y
Pd
0
4′
Ph
H
H
COCH₃
H
CH₃
H
H
H
H
—
—

4′-227
Pd
1
4′
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
pic

4′-227X
Pd
1
4′
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
acac

4′-227Y
Pd
0
4′
Ph
H
COCH₃
H
H
CH₃
H
H
H
H
—
—

4′-228
Pd
1
4′
Ph
H
H
BL
CH₃
H
H
H
H
pic

4′-228X
Pd
1
4′
Ph
H
H
BL
CH₃
H
H
H
H
acac

4′-228Y
Pd
0
4′
Ph
H
H
BL
CH₃
H
H
H
H
—
—

4′-229
Pd
1
4′
Ph
H
H
BL

^tC₄H₉
H
H
H
H
pic

4′-229X
Pd
1
4′
Ph
H
H
BL

^tC₄H₉
H
H
H
H
acac

4′-229Y
Pd
0
4′
Ph
H
H
BL

^tC₄H₉
H
H
H
H
—
—

4′-230
Pd
1
4′
Ph
H
BL
H
CH₃
H
H
H
H
pic

4′-230X
Pd
1
4′
Ph
H
BL
H
CH₃
H
H
H
H
acac

4′-230Y
Pd
0
4′
Ph
H
BL
H
CH₃
H
H
H
H
—
—

4′-231
Pd
1
4′
Ph
H
BL
H

^tC₄H₉
H
H
H
H
pic

4′-231X
Pd
1
4′
Ph
H
BL
H

^tC₄H₉
H
H
H
H
acac

4′-231Y
Pd
0
4′
Ph
H
BL
H

^tC₄H₉
H
H
H
H
—
—

4′-232
Pd
1
4′
Ph
H
H
PL
CH₃
H
H
H
H
pic

4′-232X
Pd
1
4′
Ph
H
H
PL
CH₃
H
H
H
H
acac

4′-232Y
Pd
0
4′
Ph
H
H
PL
CH₃
H
H
H
H
—
—

4′-233
Pd
1
4′
Ph
H
H
PL

^tC₄H₉
H
H
H
H
pic

4′-233X
Pd
1
4′
Ph
H
H
PL

^tC₄H₉
H
H
H
H
acac

4′-233Y
Pd
0
4′
Ph
H
H
PL

^tC₄H₉
H
H
H
H
—
—

4′-234
Pd
1
4′
Ph
H
PL
H
CH₃
H
H
H
H
pic

4′-234X
Pd
1
4′
Ph
H
PL
H
CH₃
H
H
H
H
acac

4′-234Y
Pd
0
4′
Ph
H
PL
H
CH₃
H
H
H
H
—
—

4′-235
Pd
1
4′
Ph
H
PL
H
CH₃
H
H
H
H
pic

4′-235X
Pd
1
4′
Ph
H
PL
H
CH₃
H
H
H
H
acac

4′-235Y
Pd
0
4′
Ph
H
PL
H
CH₃
H
H
H
H
—
—

4′-236
Pd
1
4′
Ph
H
H
MEE1
CH₃
H
H
H
H
pic

4′-236X
Pd
1
4′
Ph
H
H
MEE1
CH₃
H
H
H
H
acac

4′-236Y
Pd
0
4′
Ph
H
H
MEE1
CH₃
H
H
H
H
—
—

4′-237
Pd
1
4′
Ph
H
MEE1
H
CH₃
H
H
H
H
pic

4′-237X
Pd
1
4′
Ph
H
MEE1
H
CH₃
H
H
H
H
acac

4′-237Y
Pd
0
4′
Ph
H
MEE1
H
CH₃
H
H
H
H
—
—

4′-238
Pd
1
4′
Ph
H
H
MEE2
CH₃
H
H
H
H
pic

4′-238X
Pd
1
4′
Ph
H
H
MEE2
CH₃
H
H
H
H
acac

4′-238Y
Pd
0
4′
Ph
H
H
MEE2
CH₃
H
H
H
H
—
—

4′-239
Pd
1
4′
Ph
H
MEE2
H
CH₃
H
H
H
H
pic

4′-239X
Pd
1
4′
Ph
H
MEE2
H
CH₃
H
H
H
H
acac

4′-239Y
Pd
0
4′
Ph
H
MEE2
H
CH₃
H
H
H
H
—
—

4′-240
Pd
1
4′
Ph
H
H
PA1
CH₃
H
H
H
H
pic

4′-240X
Pd
1
4′
Ph
H
H
PA1
CH₃
H
H
H
H
acac

4′-240Y
Pd
0
4′
Ph
H
H
PA1
CH₃
H
H
H
H
—
—

4′-241
Pd
1
4′
Ph
H
PA1
H
CH₃
H
H
H
H
pic

4′-241X
Pd
1
4′
Ph
H
PA1
H
CH₃
H
H
H
H
acac

4′-241Y
Pd
0
4′
Ph
H
PA1
H
CH₃
H
H
H
H
—
—

4′-242
Pd
1
4′
Ph
H
H
PA2
CH₃
H
H
H
H
pic

4′-242X
Pd
1
4′
Ph
H
H
PA2
CH₃
H
H
H
H
acac

4′-242Y
Pd
0
4′
Ph
H
H
PA2
CH₃
H
H
H
H
—
—

4′-243
Pd
1
4′
Ph
H
PA2
H
CH₃
H
H
H
H
pic

4′-243X
Pd
1
4′
Ph
H
PA2
H
CH₃
H
H
H
H
acac

4′-243Y
Pd
0
4′
Ph
H
PA2
H
CH₃
H
H
H
H
—
—

4′-244
Pd
1
4′
Ph
H
H
EA1
CH₃
H
H
H
H
pic

4′-244X
Pd
1
4′
Ph
H
H
EA1
CH₃
H
H
H
H
acac

4′-244Y
Pd
0
4′
Ph
H
H
EA1
CH₃
H
H
H
H
—
—

4′-245
Pd
1
4′
Ph
H
EA2
H
CH₃
H
H
H
H
pic

4′-245X
Pd
1
4′
Ph
H
EA2
H
CH₃
H
H
H
H
acac

4′-245Y
Pd
0
4′
Ph
H
EA2
H
CH₃
H
H
H
H
—
—

4′-246
Pd
1
4′
Ph
H
H
ME
CH₃
H
H
H
H
pic

4′-246X
Pd
1
4′
Ph
H
H
ME
CH₃
H
H
H
H
acac

4′-246Y
Pd
0
4′
Ph
H
H
ME
CH₃
H
H
H
H
—
—

4′-247
Pd
1
4′
Ph
H
ME
H
CH₃
H
H
H
H
pic

4′-247X
Pd
1
4′
Ph
H
ME
H
CH₃
H
H
H
H
acac

4′-247Y
Pd
0
4′
Ph
H
ME
H
CH₃
H
H
H
H
—
—

4′-248
Pd
1
4′
Ph
H
H
AT
CH₃
H
H
H
H
pic

4′-248X
Pd
1
4′
Ph
H
H
AT
CH₃
H
H
H
H
acac

4′-248Y
Pd
0
4′
Ph
H
H
AT
CH₃
H
H
H
H
—
—

4′-249
Pd
1
4′
Ph
H
AT
H
CH₃
H
H
H
H
pic

4′-249X
Pd
1
4′
Ph
H
AT
H
CH₃
H
H
H
H
acac

4′-249Y
Pd
0
4′
Ph
H
AT
H
CH₃
H
H
H
H
—
—

4′-250
Pd
1
4′
Ph
H
H
MES1
CH₃
H
H
H
H
pic

4′-250X
Pd
1
4′
Ph
H
H
MES1
CH₃
H
H
H
H
acac

4′-250Y
Pd
0
4′
Ph
H
H
MES1
CH₃
H
H
H
H
—
—

4′-251
Pd
1
4′
Ph
H
MES1
H
CH₃
H
H
H
H
pic

4′-251X
Pd
1
4′
Ph
H
MES1
H
CH₃
H
H
H
H
acac

4′-251Y
Pd
0
4′
Ph
H
MES1
H
CH₃
H
H
H
H
—
—

4′-252
Pd
1
4′
Ph
H
H
MES2
CH₃
H
H
H
H
pic

4′-252X
Pd
1
4′
Ph
H
H
MES2
CH₃
H
H
H
H
acac

4′-252Y
Pd
0
4′
Ph
H
H
MES2
CH₃
H
H
H
H
—
—

4′-253
Pd
1
4′
Ph
H
MES2
H
CH₃
H
H
H
H
pic

4′-253X
Pd
1
4′
Ph
H
MES2
H
CH₃
H
H
H
H
acac

4′-253Y
Pd
0
4′
Ph
H
MES2
H
CH₃
H
H
H
H
—
—

4′-254
Pd
1
4′
Ph
H
H
PS1
CH₃
H
H
H
H
pic

4′-254X
Pd
1
4′
Ph
H
H
PS1
CH₃
H
H
H
H
acac

4′-254Y
Pd
0
4′
Ph
H
H
PS1
CH₃
H
H
H
H
—
—

4′-255
Pd
1
4′
Ph
H
PS1
H
CH₃
H
H
H
H
pic

4′-255X
Pd
1
4′
Ph
H
PS1
H
CH₃
H
H
H
H
acac

4′-255Y
Pd
0
4′
Ph
H
PS1
H
CH₃
H
H
H
H
—
—

4′-256
Pd
1
4′
Ph
H
H
PS2
CH₃
H
H
H
H
pic

4′-256X
Pd
1
4′
Ph
H
H
PS2
CH₃
H
H
H
H
acac

4′-256Y
Pd
0
4′
Ph
H
H
PS2
CH₃
H
H
H
H
—
—

4′-257
Pd
1
4′
Ph
H
PS2
H
CH₃
H
H
H
H
pic

4′-257X
Pd
1
4′
Ph
H
PS2
H
CH₃
H
H
H
H
acac

4′-257Y
Pd
0
4′
Ph
H
PS2
H
CH₃
H
H
H
H
—
—

4′-258
Pd
1
4′
Ph
H
H
BAL1
CH₃
H
H
H
H
pic

4′-258X
Pd
1
4′
Ph
H
H
BAL1
CH₃
H
H
H
H
acac

4′-258Y
Pd
0
4′
Ph
H
H
BAL1
CH₃
H
H
H
H
—
—

4′-259
Pd
1
4′
Ph
H
BAL1
H
CH₃
H
H
H
H
pic

4′-259X
Pd
1
4′
Ph
H
BAL1
H
CH₃
H
H
H
H
acac

4′-259Y
Pd
0
4′
Ph
H
BAL1
H
CH₃
H
H
H
H
—
—

4′-260
Pd
1
4′
Ph
H
H
BAL2
CH₃
H
H
H
H
pic

4′-260X
Pd
1
4′
Ph
H
H
BAL2
CH₃
H
H
H
H
acac

4′-260Y
Pd
0
4′
Ph
H
H
BAL2
CH₃
H
H
H
H
—
—

4′-261
Pd
1
4′
Ph
H
BAL2
H
CH₃
H
H
H
H
pic

4′-261X
Pd
1
4′
Ph
H
BAL2
H
CH₃
H
H
H
H
acac

4′-261Y
Pd
0
4′
Ph
H
BAL2
H
CH₃
H
H
H
H
—
—

4′-262
Pd
1
4′
Ph
H
H
MEK1
CH₃
H
H
H
H
pic

4′-262X
Pd
1
4′
Ph
H
H
MEK1
CH₃
H
H
H
H
acac

4′-262Y
Pd
0
4′
Ph
H
H
MEK1
CH₃
H
H
H
H
—
—

4′-263
Pd
1
4′
Ph
H
MEK1
H
CH₃
H
H
H
H
pic

4′-263X
Pd
1
4′
Ph
H
MEK1
H
CH₃
H
H
H
H
acac

4′-263Y
Pd
0
4′
Ph
H
MEK1
H
CH₃
H
H
H
H
—
—

4′-264
Pd
1
4′
Ph
H
H
MEK2
CH₃
H
H
H
H
pic

4′-264X
Pd
1
4′
Ph
H
H
MEK2
CH₃
H
H
H
H
acac

4′-264Y
Pd
0
4′
Ph
H
H
MEK2
CH₃
H
H
H
H
—
—

4′-265
Pd
1
4′
Ph
H
MEK2
H
CH₃
H
H
H
H
pic

4′-265X
Pd
1
4′
Ph
H
MEK2
H
CH₃
H
H
H
H
acac

4′-265Y
Pd
0
4′
Ph
H
MEK2
H
CH₃
H
H
H
H
—
—

4′-266
Pd
1
4′
Ph
H
H
PAL1
CH₃
H
H
H
H
pic

4′-266X
Pd
1
4′
Ph
H
H
PAL1
CH₃
H
H
H
H
acac

4′-266Y
Pd
0
4′
Ph
H
H
PAL1
CH₃
H
H
H
H
—
—

4′-267
Pd
1
4′
Ph
H
PAL1
H
CH₃
H
H
H
H
pic

4′-267X
Pd
1
4′
Ph
H
PAL1
H
CH₃
H
H
H
H
acac

4′-267Y
Pd
0
4′
Ph
H
PAL1
H
CH₃
H
H
H
H
—
—

4′-268
Pd
1
4′
Ph
H
H
PAL2
CH₃
H
H
H
H
pic

4′-268X
Pd
1
4′
Ph
H
H
PAL2
CH₃
H
H
H
H
acac

4′-268Y
Pd
0
4′
Ph
H
H
PAL2
CH₃
H
H
H
H
—
—

4′-269
Pd
1
4′
Ph
H
PAL2
H
CH₃
H
H
H
H
pic

4′-269X
Pd
1
4′
Ph
H
PAL2
H
CH₃
H
H
H
H
acac

4′-269Y
Pd
0
4′
Ph
H
PAL2
H
CH₃
H
H
H
H
—
—

4′-270
Pd
1
4′
Ph
H
H
MMK
CH₃
H
H
H
H
pic

4′-270X
Pd
1
4′
Ph
H
H
MMK
CH₃
H
H
H
H
acac

4′-270Y
Pd
0
4′
Ph
H
H
MMK
CH₃
H
H
H
H
—
—

4′-271
Pd
1
4′
Ph
H
MMK
H
CH₃
H
H
H
H
pic

4′-271X
Pd
1
4′
Ph
H
MMK
H
CH₃
H
H
H
H
acac

4′-271Y
Pd
0
4′
Ph
H
MMK
H
CH₃
H
H
H
H
—
—

4′-272
Pd
1
4′
Ph
H
H
EES1
CH₃
H
H
H
H
pic

4′-272X
Pd
1
4′
Ph
H
H
EES1
CH₃
H
H
H
H
acac

4′-272Y
Pd
0
4′
Ph
H
H
EES1
CH₃
H
H
H
H
—
—

4′-273
Pd
1
4′
Ph
H
EES2
H
CH₃
H
H
H
H
pic

4′-273X
Pd
1
4′
Ph
H
EES2
H
CH₃
H
H
H
H
acac

4′-273Y
Pd
0
4′
Ph
H
EES2
H
CH₃
H
H
H
H
—
—

4′-274
Pd
1
4′
Ph
H
H
PAE1
CH₃
H
H
H
H
pic

4′-274X
Pd
1
4′
Ph
H
H
PAE1
CH₃
H
H
H
H
acac

4′-274Y
Pd
0
4′
Ph
H
H
PAE1
CH₃
H
H
H
H
—
—

4′-275
Pd
1
4′
Ph
H
PAE2
H
CH₃
H
H
H
H
pic

4′-275X
Pd
1
4′
Ph
H
PAE2
H
CH₃
H
H
H
H
acac

4′-275Y
Pd
0
4′
Ph
H
PAE2
H
CH₃
H
H
H
H
—
—

4′-276
Pd
1
4′
Ph
H
H
AME1
CH₃
H
H
H
H
pic

4′-276X
Pd
1
4′
Ph
H
H
AME1
CH₃
H
H
H
H
acac

4′-276Y
Pd
0
4′
Ph
H
H
AME1
CH₃
H
H
H
H
—
—

4′-277
Pd
1
4′
Ph
H
AME1
H
CH₃
H
H
H
H
pic

4′-277X
Pd
1
4′
Ph
H
AME1
H
CH₃
H
H
H
H
acac

4′-277Y
Pd
0
4′
Ph
H
AME1
H
CH₃
H
H
H
H
—
—

4′-278
Pd
1
4′
Ph
H
H
AME2
CH₃
H
H
H
H
pic

4′-278X
Pd
1
4′
Ph
H
H
AME2
CH₃
H
H
H
H
acac

4′-278Y
Pd
0
4′
Ph
H
H
AME2
CH₃
H
H
H
H
—
—

4′-279
Pd
1
4′
Ph
H
AME2
H
CH₃
H
H
H
H
pic

4′-279X
Pd
1
4′
Ph
H
AME2
H
CH₃
H
H
H
H
acac

4′-279Y
Pd
0
4′
Ph
H
AME2
H
CH₃
H
H
H
H
—
—

4′-280
Pd
1
4′
Ph
H
H
EAE1
CH₃
H
H
H
H
pic

4′-280X
Pd
1
4′
Ph
H
H
EAE1
CH₃
H
H
H
H
acac

4′-280Y
Pd
0
4′
Ph
H
H
EAE1
CH₃
H
H
H
H
—
—

4′-281
Pd
1
4′
Ph
H
EAE1
H
CH₃
H
H
H
H
pic

4′-281X
Pd
1
4′
Ph
H
EAE1
H
CH₃
H
H
H
H
acac

4′-281Y
Pd
0
4′
Ph
H
EAE1
H
CH₃
H
H
H
H
—
—

4′-282
Pd
1
4′
Ph
H
H
EAE2
CH₃
H
H
H
H
pic

4′-282X
Pd
1
4′
Ph
H
H
EAE2
CH₃
H
H
H
H
acac

4′-282Y
Pd
0
4′
Ph
H
H
EAE2
CH₃
H
H
H
H
—
—

4′-283
Pd
1
4′
Ph
H
EAE2
H
CH₃
H
H
H
H
pic

4′-283X
Pd
1
4′
Ph
H
EAE2
H
CH₃
H
H
H
H
acac

4′-283Y
Pd
0
4′
Ph
H
EAE2
H
CH₃
H
H
H
H
—
—

4′-284
Pd
1
4′
Ph
H
H
AAE1
CH₃
H
H
H
H
pic

4′-284X
Pd
1
4′
Ph
H
H
AAE1
CH₃
H
H
H
H
acac

4′-284Y
Pd
0
4′
Ph
H
H
AAE1
CH₃
H
H
H
H
—
—

4′-285
Pd
1
4′
Ph
H
AAE1
H
CH₃
H
H
H
H
pic

4′-285X
Pd
1
4′
Ph
H
AAE1
H
CH₃
H
H
H
H
acac

4′-285Y
Pd
0
4′
Ph
H
AAE1
H
CH₃
H
H
H
H
—
—

4′-286
Pd
1
4′
Ph
H
H
AAE2
CH₃
H
H
H
H
pic

4′-286X
Pd
1
4′
Ph
H
H
AAE2
CH₃
H
H
H
H
acac

4′-286Y
Pd
0
4′
Ph
H
H
AAE2
CH₃
H
H
H
H
—
—

4′-287
Pd
1
4′
Ph
H
AAE2
H
CH₃
H
H
H
H
pic

4′-287X
Pd
1
4′
Ph
H
AAE2
H
CH₃
H
H
H
H
acac

4′-287Y
Pd
0
4′
Ph
H
AAE2
H
CH₃
H
H
H
H
—
—

4′-288
Pd
1
4′
Ph
H
H
PME1
CH₃
H
H
H
H
pic

4′-288X
Pd
1
4′
Ph
H
H
PME1
CH₃
H
H
H
H
acac

4′-288Y
Pd
0
4′
Ph
H
H
PME1
CH₃
H
H
H
H
—
—

4′-289
Pd
1
4′
Ph
H
PME1
H
CH₃
H
H
H
H
pic

4′-289X
Pd
1
4′
Ph
H
PME1
H
CH₃
H
H
H
H
acac

4′-289Y
Pd
0
4′
Ph
H
PME1
H
CH₃
H
H
H
H
—
—

4′-290
Pd
1
4′
Ph
H
H
PME2
CH₃
H
H
H
H
pic

4′-290X
Pd
1
4′
Ph
H
H
PME2
CH₃
H
H
H
H
acac

4′-290Y
Pd
0
4′
Ph
H
H
PME2
CH₃
H
H
H
H
—
—

4′-291
Pd
1
4′
Ph
H
PME2
H
CH₃
H
H
H
H
pic

4′-291X
Pd
1
4′
Ph
H
PME2
H
CH₃
H
H
H
H
acac

4′-291Y
Pd
0
4′
Ph
H
PME2
H
CH₃
H
H
H
H
—
—

4′-292
Pd
1
4′
Ph
H
H
MET1
CH₃
H
H
H
H
pic

4′-292X
Pd
1
4′
Ph
H
H
MET1
CH₃
H
H
H
H
acac

4′-292Y
Pd
0
4′
Ph
H
H
MET1
CH₃
H
H
H
H
—
—

4′-293
Pd
1
4′
Ph
H
MET1
H
CH₃
H
H
H
H
pic

4′-293X
Pd
1
4′
Ph
H
MET1
H
CH₃
H
H
H
H
acac

4′-293Y
Pd
0
4′
Ph
H
MET1
H
CH₃
H
H
H
H
—
—

4′-294
Pd
1
4′
Ph
H
H
MET2
CH₃
H
H
H
H
pic

4′-294X
Pd
1
4′
Ph
H
H
MET2
CH₃
H
H
H
H
acac

4′-294Y
Pd
0
4′
Ph
H
H
MET2
CH₃
H
H
H
H
—
—

4′-295
Pd
1
4′
Ph
H
MET2
H
CH₃
H
H
H
H
pic

4′-295X
Pd
1
4′
Ph
H
MET2
H
CH₃
H
H
H
H
acac

4′-295Y
Pd
0
4′
Ph
H
MET2
H
CH₃
H
H
H
H
—
—

4′-296
Pd
1
4′
Ph
H
H
EE1
CH₃
H
H
H
H
pic

4′-296X
Pd
1
4′
Ph
H
H
EE1
CH₃
H
H
H
H
acac

4′-296Y
Pd
0
4′
Ph
H
H
EE1
CH₃
H
H
H
H
—
—

4′-297
Pd
1
4′
Ph
H
EE1
H
CH₃
H
H
H
H
pic

4′-297X
Pd
1
4′
Ph
H
EE1
H
CH₃
H
H
H
H
acac

4′-297Y
Pd
0
4′
Ph
H
EE1
H
CH₃
H
H
H
H
—
—

4′-298
Pd
1
4′
Ph
H
H
EE2
CH₃
H
H
H
H
pic

4′-298X
Pd
1
4′
Ph
H
H
EE2
CH₃
H
H
H
H
acac

4′-298Y
Pd
0
4′
Ph
H
H
EE2
CH₃
H
H
H
H
—
—

4′-299
Pd
1
4′
Ph
H
EE2
H
CH₃
H
H
H
H
pic

4′-299X
Pd
1
4′
Ph
H
EE2
H
CH₃
H
H
H
H
acac

4′-299Y
Pd
0
4′
Ph
H
EE2
H
CH₃
H
H
H
H
—
—

4′-300
Pd
1
4′
Ph
H
H
MS1
CH₃
H
H
H
H
pic

4′-300X
Pd
1
4′
Ph
H
H
MS1
CH₃
H
H
H
H
acac

4′-300Y
Pd
0
4′
Ph
H
H
MS1
CH₃
H
H
H
H
—
—

4′-301
Pd
1
4′
Ph
H
MS1
H
CH₃
H
H
H
H
pic

4′-301X
Pd
1
4′
Ph
H
MS1
H
CH₃
H
H
H
H
acac

4′-301Y
Pd
0
4′
Ph
H
MS1
H
CH₃
H
H
H
H
—
—

4′-302
Pd
1
4′
Ph
H
H
MS2
CH₃
H
H
H
H
pic

4′-302X
Pd
1
4′
Ph
H
H
MS2
CH₃
H
H
H
H
acac

4′-302Y
Pd
0
4′
Ph
H
H
MS2
CH₃
H
H
H
H
—
—

4′-303
Pd
1
4′
Ph
H
MS2
H
CH₃
H
H
H
H
pic

4′-303X
Pd
1
4′
Ph
H
MS2
H
CH₃
H
H
H
H
acac

4′-303Y
Pd
0
4′
Ph
H
MS2
H
CH₃
H
H
H
H
—
—

TABLE 47

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

5′-211
Pd
1
5′
Ph
H
H
H
H
H
CH₃
H
pic

5′-211X
Pd
1
5′
Ph
H
H
H
H
H
CH₃
H
acac

5′-211Y
Pd
0
5′
Ph
H
H
H
H
H
CH₃
H
—
—

5′-212
Pd
1
5′
Ph
H
H
H
H
H

^tC₄H₉
H
pic

5′-212X
Pd
1
5′
Ph
H
H
H
H
H

^tC₄H₉
H
acac

5′-212Y
Pd
0
5′
Ph
H
H
H
H
H

^tC₄H₉
H
—
—

5′-213
Pd
1
5′
Ph
H
F
H
F
H
CH₃
H
pic

5′-213X
Pd
1
5′
Ph
H
F
H
F
H
CH₃
H
acac

5′-213Y
Pd
0
5′
Ph
H
F
H
F
H
CH₃
H
—
—

5′-214
Pd
1
5′
Ph
H
F
H
F
H

^tC₄H₉
H
pic

5′-214X
Pd
1
5′
Ph
H
F
H
F
H

^tC₄H₉
H
acac

5′-214Y
Pd
0
5′
Ph
H
F
H
F
H

^tC₄H₉
H
—
—

5′-215
Pd
1
5′
Ph
CF₃
H
CF₃
H
H
CH₃
H
pic

5′-215X
Pd
1
5′
Ph
CF₃
H
CF₃
H
H
CH₃
H
acac

5′-215Y
Pd
0
5′
Ph
CF₃
H
CF₃
H
H
CH₃
H
—
—

5′-216
Pd
1
5′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
pic

5′-216X
Pd
1
5′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
acac

5′-216Y
Pd
0
5′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
—
—

5′-217
Pd
1
5′
Ph
H
F
CF₃
H
H
CH₃
H
pic

5′-217X
Pd
1
5′
Ph
H
F
CF₃
H
H
CH₃
H
acac

5′-217Y
Pd
0
5′
Ph
H
F
CF₃
H
H
CH₃
H
—
—

5′-218
Pd
1
5′
Ph
F
H
CF₃
H
H
CH₃
H
pic

5′-218X
Pd
1
5′
Ph
F
H
CF₃
H
H
CH₃
H
acac

5′-218Y
Pd
0
5′
Ph
F
H
CF₃
H
H
CH₃
H
—
—

5′-219
Pd
1
5′
Ph
F
F
F
F
H
CH₃
H
pic

5′-219X
Pd
1
5′
Ph
F
F
F
F
H
CH₃
H
acac

5′-219Y
Pd
0
5′
Ph
F
F
F
F
H
CH₃
H
—
—

5′-220
Pd
1
5′
Ph
H
F
H
CH₃
H
CH₃
H
pic

5′-220X
Pd
1
5′
Ph
H
F
H
CH₃
H
CH₃
H
acac

5′-220Y
Pd
0
5′
Ph
H
F
H
CH₃
H
CH₃
H
—
—

5′-221
Pd
1
5′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
pic

5′-221X
Pd
1
5′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
acac

5′-221Y
Pd
0
5′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
—
—

5′-222
Pd
1
5′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
pic

5′-222X
Pd
1
5′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
acac

5′-222Y
Pd
0
5′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
—
—

5′-223
Pd
1
5′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-223X
Pd
1
5′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-223Y
Pd
0
5′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5′-224
Pd
1
5′
Ph
H
CF₃
H
CF₃
H
CH₃
H
pic

5′-224X
Pd
1
5′
Ph
H
CF₃
H
CF₃
H
CH₃
H
acac

5′-224Y
Pd
0
5′
Ph
H
CF₃
H
CF₃
H
CH₃
H
—
—

5′-225
Pd
1
5′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
pic

5′-225X
Pd
1
5′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
acac

5′-225Y
Pd
0
5′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
—
—

5′-226
Pd
1
5′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
pic

5′-226X
Pd
1
5′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
acac

5′-226Y
Pd
0
5′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
—
—

5′-227
Pd
1
5′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-227X
Pd
1
5′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-227Y
Pd
0
5′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5′-228
Pd
1
5′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
pic

5′-228X
Pd
1
5′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
acac

5′-228Y
Pd
0
5′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
—
—

5′-229
Pd
1
5′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′-229X
Pd
1
5′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′-229Y
Pd
0
5′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5′-230
Pd
1
5′
Ph
H
CF₃
H
CH₃
H
CH₃
H
pic

5′-230X
Pd
1
5′
Ph
H
CF₃
H
CH₃
H
CH₃
H
acac

5′-230Y
Pd
0
5′
Ph
H
CF₃
H
CH₃
H
CH₃
H
—
—

5′-231
Pd
1
5′
Ph
H
CF₃
CF₃
H
H
CH₃
H
pic

5′-231X
Pd
1
5′
Ph
H
CF₃
CF₃
H
H
CH₃
H
acac

5′-231Y
Pd
0
5′
Ph
H
CF₃
CF₃
H
H
CH₃
H
—
—

5′-232
Pd
1
5′
Ph
H
H
NO₂
H
H
CH₃
H
pic

5′-232X
Pd
1
5′
Ph
H
H
NO₂
H
H
CH₃
H
acac

5′-232Y
Pd
0
5′
Ph
H
H
NO₂
H
H
CH₃
H
—
—

5′-233
Pd
1
5′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
pic

5′-233X
Pd
1
5′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
acac

5′-233Y
Pd
0
5′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
—
—

5′-234
Pd
1
5′
Ph
F
H
NO₂
H
H
CH₃
H
pic

5′-234X
Pd
1
5′
Ph
F
H
NO₂
H
H
CH₃
H
acac

5′-234Y
Pd
0
5′
Ph
F
H
NO₂
H
H
CH₃
H
—
—

5′-235
Pd
1
5′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
pic

5′-235X
Pd
1
5′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
acac

5′-235Y
Pd
0
5′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
—
—

5′-236
Pd
1
5′
Ph
F
H
NO₂
F
H
CH₃
H
pic

5′-236X
Pd
1
5′
Ph
F
H
NO₂
F
H
CH₃
H
acac

5′-236Y
Pd
0
5′
Ph
F
H
NO₂
F
H
CH₃
H
—
—

5′-237
Pd
1
5′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
pic

5′-237X
Pd
1
5′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
acac

5′-237Y
Pd
0
5′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
—
—

5′-238
Pd
1
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
pic

5′-238X
Pd
1
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
acac

5′-238Y
Pd
0
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
—
—

5′-239
Pd
1
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
pic

5′-239X
Pd
1
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
acac

5′-239Y
Pd
0
5′
Ph
H
NO₂
H
NO₂
H
CH₃
H
—
—

5′-240
Pd
1
5′
Ph
NO₂
H
H
NO₂
H
CH₃
H
pic

5′-240X
Pd
1
5′
Ph
NO₂
H
H
NO₂
H
CH₃
H
acac

5′-240Y
Pd
0
5′
Ph
NO₂
H
H
NO₂
H
CH₃
H
—
—

5′-241
Pd
1
5′
Ph
H
H
CF₃
H
H
CH₃
H
pic

5′-241X
Pd
1
5′
Ph
H
H
CF₃
H
H
CH₃
H
acac

5′-241Y
Pd
0
5′
Ph
H
H
CF₃
H
H
CH₃
H
—
—

5′-242
Pd
1
5′
Ph
H
Cl
CF₃
H
H
CH₃
H
pic

5′-242X
Pd
1
5′
Ph
H
Cl
CF₃
H
H
CH₃
H
acac

5′-242Y
Pd
0
5′
Ph
H
Cl
CF₃
H
H
CH₃
H
—
—

5′-243
Pd
1
5′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
pic

5′-243X
Pd
1
5′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
acac

5′-243Y
Pd
0
5′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
—
—

5′-244
Pd
1
5′
Ph
H
NO₂
H
H
H
CH₃
H
pic

5′-244X
Pd
1
5′
Ph
H
NO₂
H
H
H
CH₃
H
acac

5′-244Y
Pd
0
5′
Ph
H
NO₂
H
H
H
CH₃
H
—
—

5′-245
Pd
1
5′
Ph
H
CF₃
H
H
H
CH₃
H
pic

5′-245X
Pd
1
5′
Ph
H
CF₃
H
H
H
CH₃
H
acac

5′-245Y
Pd
0
5′
Ph
H
CF₃
H
H
H
CH₃
H
—
—

5′-246
Pd
1
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
pic

5′-246X
Pd
1
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
acac

5′-246Y
Pd
0
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
—
—

5′-247
Pd
1
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
pic

5′-247X
Pd
1
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
acac

5′-247Y
Pd
0
5′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
—
—

5′-248
Pd
1
5′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
pic

5′-248X
Pd
1
5′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
acac

5′-248Y
Pd
0
5′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
—
—

5′-249
Pd
1
5′
Ph
H
H
CH₃O
H
H
CH₃
H
pic

5′-249X
Pd
1
5′
Ph
H
H
CH₃O
H
H
CH₃
H
acac

5′-249Y
Pd
0
5′
Ph
H
H
CH₃O
H
H
CH₃
H
—
—

5′-250
Pd
1
5′
Ph
H
CH₃O
H
H
H
CH₃
H
pic

5′-250X
Pd
1
5′
Ph
H
CH₃O
H
H
H
CH₃
H
acac

5′-250Y
Pd
0
5′
Ph
H
CH₃O
H
H
H
CH₃
H
—
—

5′-251
Pd
1
5′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
pic

5′-251X
Pd
1
5′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
acac

5′-251Y
Pd
0
5′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
—
—

5′-252
Pd
1
5′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
pic

5′-252X
Pd
1
5′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
acac

5′-252Y
Pd
0
5′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
—
—

5′-253
Pd
1
5′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
pic

5′-253X
Pd
1
5′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
acac

5′-253Y
Pd
0
5′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
—
—

5′-254
Pd
1
5′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
pic

5′-254X
Pd
1
5′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
acac

5′-254Y
Pd
0
5′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
—
—

5′-255
Pd
1
5′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
pic

5′-255X
Pd
1
5′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
acac

5′-255Y
Pd
0
5′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
—
—

5′-256
Pd
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
pic

5′-256X
Pd
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
acac

5′-256Y
Pd
0
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
—
—

5′-257
Pd
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
pic

5′-257X
Pd
1
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
acac

5′-257Y
Pd
0
5′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
—
—

5′-258
Pd
1
5′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
pic

5′-258X
Pd
1
5′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
acac

5′-258Y
Pd
0
5′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
—
—

5′-259
Pd
1
5′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
pic

5′-259X
Pd
1
5′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
acac

5′-259Y
Pd
0
5′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
—
—

5′-260
Pd
1
5′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
pic

5′-260X
Pd
1
5′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
acac

5′-260Y
Pd
0
5′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
—
—

5′-261
Pd
1
5′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
pic

5′-261X
Pd
1
5′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
acac

5′-261Y
Pd
0
5′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
—
—

5′-262
Pd
1
5′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
pic

5′-262X
Pd
1
5′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
acac

5′-262Y
Pd
0
5′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
—
—

5′-263
Pd
1
5′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
pic

5′-263X
Pd
1
5′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
acac

5′-263Y
Pd
0
5′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
—
—

5′-264
Pd
1
5′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
pic

5′-264X
Pd
1
5′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
acac

5′-264Y
Pd
0
5′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
—
—

5′-265
Pd
1
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
pic

5′-265X
Pd
1
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
acac

5′-265Y
Pd
0
5′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
—
—

5′-266
Pd
1
5′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
pic

5′-266X
Pd
1
5′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
acac

5′-266Y
Pd
0
5′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
—
—

5′-267
Pd
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
pic

5′-267X
Pd
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
acac

5′-267Y
Pd
0
5′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
—
—

5′-268
Pd
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
pic

5′-268X
Pd
1
5′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
acac

5′-268Y
Pd
0
5′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
—
—

5′-269
Pd
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
pic

5′-269X
Pd
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
acac

5′-269Y
Pd
0
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
—
—

5′-270
Pd
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
pic

5′-270X
Pd
1
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
acac

5′-270Y
Pd
0
5′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
—
—

5′-271
Pd
1
5′
Ph
H
H
H
COCH₃
H
CH₃
H
pic

5′-271X
Pd
1
5′
Ph
H
H
H
COCH₃
H
CH₃
H
acac

5′-271Y
Pd
0
5′
Ph
H
H
H
COCH₃
H
CH₃
H
—
—

5′-272
Pd
1
5′
Ph
H
H
COCH₃
H
H
CH₃
H
pic

5′-272X
Pd
1
5′
Ph
H
H
COCH₃
H
H
CH₃
H
acac

5′-272Y
Pd
0
5′
Ph
H
H
COCH₃
H
H
CH₃
H
—
—

5′-273
Pd
1
5′
Ph
H
COCH₃
H
H
H
CH₃
H
pic

5′-273X
Pd
1
5′
Ph
H
COCH₃
H
H
H
CH₃
H
acac

5′-273Y
Pd
0
5′
Ph
H
COCH₃
H
H
H
CH₃
H
—
—

5′-274
Pd
1
5′
Ph
H
H
BL
H
CH₃
H
pic

5′-274X
Pd
1
5′
Ph
H
H
BL
H
CH₃
H
acac

5′-274Y
Pd
0
5′
Ph
H
H
BL
H
CH₃
H
—
—

5′-275
Pd
1
5′
Ph
H
H
BL
H

^tC₄H₉
H
pic

5′-275X
Pd
1
5′
Ph
H
H
BL
H

^tC₄H₉
H
acac

5′-275Y
Pd
0
5′
Ph
H
H
BL
H

^tC₄H₉
H
—
—

5′-276
Pd
1
5′
Ph
H
BL
H
H
CH₃
H
pic

5′-276X
Pd
1
5′
Ph
H
BL
H
H
CH₃
H
acac

5′-276Y
Pd
0
5′
Ph
H
BL
H
H
CH₃
H
—
—

5′-277
Pd
1
5′
Ph
H
BL
H
H

^tC₄H₉
H
pic

5′-277X
Pd
1
5′
Ph
H
BL
H
H

^tC₄H₉
H
acac

5′-277Y
Pd
0
5′
Ph
H
BL
H
H

^tC₄H₉
H
—
—

5′-278
Pd
1
5′
Ph
H
H
PL
H
CH₃
H
pic

5′-278X
Pd
1
5′
Ph
H
H
PL
H
CH₃
H
acac

5′-278Y
Pd
0
5′
Ph
H
H
PL
H
CH₃
H
—
—

5′-279
Pd
1
5′
Ph
H
H
PL
H

^tC₄H₉
H
pic

5′-279X
Pd
1
5′
Ph
H
H
PL
H

^tC₄H₉
H
acac

5′-279Y
Pd
0
5′
Ph
H
H
PL
H

^tC₄H₉
H
—
—

5′-280
Pd
1
5′
Ph
H
PL
H
H
CH₃
H
pic

5′-280X
Pd
1
5′
Ph
H
PL
H
H
CH₃
H
acac

5′-280Y
Pd
0
5′
Ph
H
PL
H
H
CH₃
H
—
—

5′-281
Pd
1
5′
Ph
H
PL
H
H

^tC₄H₉
H
pic

5′-281X
Pd
1
5′
Ph
H
PL
H
H

^tC₄H₉
H
acac

5′-281Y
Pd
0
5′
Ph
H
PL
H
H

^tC₄H₉
H
—
—

5′-282
Pd
1
5′
Ph
H
H
MEE1
H
CH₃
H
pic

5′-282X
Pd
1
5′
Ph
H
H
MEE1
H
CH₃
H
acac

5′-282Y
Pd
0
5′
Ph
H
H
MEE1
H
CH₃
H
—
—

5′-283
Pd
1
5′
Ph
H
MEE1
H
H
CH₃
H
pic

5′-283X
Pd
1
5′
Ph
H
MEE1
H
H
CH₃
H
acac

5′-283Y
Pd
0
5′
Ph
H
MEE1
H
H
CH₃
H
—
—

5′-284
Pd
1
5′
Ph
H
H
MEE2
H
CH₃
H
pic

5′-284X
Pd
1
5′
Ph
H
H
MEE2
H
CH₃
H
acac

5′-284Y
Pd
0
5′
Ph
H
H
MEE2
H
CH₃
H
—
—

5′-285
Pd
1
5′
Ph
H
MEE2
H
H
CH₃
H
pic

5′-285X
Pd
1
5′
Ph
H
MEE2
H
H
CH₃
H
acac

5′-285Y
Pd
0
5′
Ph
H
MEE2
H
H
CH₃
H
—
—

5′-286
Pd
1
5′
Ph
H
H
PA1
H
CH₃
H
pic

5′-286X
Pd
1
5′
Ph
H
H
PA1
H
CH₃
H
acac

5′-286Y
Pd
0
5′
Ph
H
H
PA1
H
CH₃
H
—
—

5′-287
Pd
1
5′
Ph
H
PA1
H
H
CH₃
H
pic

5′-287X
Pd
1
5′
Ph
H
PA1
H
H
CH₃
H
acac

5′-287Y
Pd
0
5′
Ph
H
PA1
H
H
CH₃
H
—
—

5′-288
Pd
1
5′
Ph
H
H
PA2
H
CH₃
H
pic

5′-288X
Pd
1
5′
Ph
H
H
PA2
H
CH₃
H
acac

5′-288Y
Pd
0
5′
Ph
H
H
PA2
H
CH₃
H
—
—

5′-289
Pd
1
5′
Ph
H
PA2
H
H
CH₃
H
pic

5′-289X
Pd
1
5′
Ph
H
PA2
H
H
CH₃
H
acac

5′-289Y
Pd
0
5′
Ph
H
PA2
H
H
CH₃
H
—
—

5′-290
Pd
1
5′
Ph
H
H
EA1
H
CH₃
H
pic

5′-290X
Pd
1
5′
Ph
H
H
EA1
H
CH₃
H
acac

5′-290Y
Pd
0
5′
Ph
H
H
EA1
H
CH₃
H
—
—

5′-291
Pd
1
5′
Ph
H
EA2
H
H
CH₃
H
pic

5′-291X
Pd
1
5′
Ph
H
EA2
H
H
CH₃
H
acac

5′-291Y
Pd
0
5′
Ph
H
EA2
H
H
CH₃
H
—
—

5′-292
Pd
1
5′
Ph
H
H
ME
H
CH₃
H
pic

5′-292X
Pd
1
5′
Ph
H
H
ME
H
CH₃
H
acac

5′-292Y
Pd
0
5′
Ph
H
H
ME
H
CH₃
H
—
—

5′-293
Pd
1
5′
Ph
H
ME
H
H
CH₃
H
pic

5′-293X
Pd
1
5′
Ph
H
ME
H
H
CH₃
H
acac

5′-293Y
Pd
0
5′
Ph
H
ME
H
H
CH₃
H
—
—

5′-294
Pd
1
5′
Ph
H
H
AT
H
CH₃
H
pic

5′-294X
Pd
1
5′
Ph
H
H
AT
H
CH₃
H
acac

5′-294Y
Pd
0
5′
Ph
H
H
AT
H
CH₃
H
—
—

5′-295
Pd
1
5′
Ph
H
AT
H
H
CH₃
H
pic

5′-295X
Pd
1
5′
Ph
H
AT
H
H
CH₃
H
acac

5′-295Y
Pd
0
5′
Ph
H
AT
H
H
CH₃
H
—
—

5′-296
Pd
1
5′
Ph
H
H
MES1
H
CH₃
H
pic

5′-296X
Pd
1
5′
Ph
H
H
MES1
H
CH₃
H
acac

5′-296Y
Pd
0
5′
Ph
H
H
MES1
H
CH₃
H
—
—

5′-297
Pd
1
5′
Ph
H
MES1
H
H
CH₃
H
pic

5′-297X
Pd
1
5′
Ph
H
MES1
H
H
CH₃
H
acac

5′-297Y
Pd
0
5′
Ph
H
MES1
H
H
CH₃
H
—
—

5′-298
Pd
1
5′
Ph
H
H
MES2
H
CH₃
H
pic

5′-298X
Pd
1
5′
Ph
H
H
MES2
H
CH₃
H
acac

5′-298Y
Pd
0
5′
Ph
H
H
MES2
H
CH₃
H
—
—

5′-299
Pd
1
5′
Ph
H
MES2
H
H
CH₃
H
pic

5′-299X
Pd
1
5′
Ph
H
MES2
H
H
CH₃
H
acac

5′-299Y
Pd
0
5′
Ph
H
MES2
H
H
CH₃
H
—
—

5′-300
Pd
1
5′
Ph
H
H
PS1
H
CH₃
H
pic

5′-300X
Pd
1
5′
Ph
H
H
PS1
H
CH₃
H
acac

5′-300Y
Pd
0
5′
Ph
H
H
PS1
H
CH₃
H
—
—

5′-301
Pd
1
5′
Ph
H
PS1
H
H
CH₃
H
pic

5′-301X
Pd
1
5′
Ph
H
PS1
H
H
CH₃
H
acac

5′-301Y
Pd
0
5′
Ph
H
PS1
H
H
CH₃
H
—
—

5′-302
Pd
1
5′
Ph
H
H
PS2
H
CH₃
H
pic

5′-302X
Pd
1
5′
Ph
H
H
PS2
H
CH₃
H
acac

5′-302Y
Pd
0
5′
Ph
H
H
PS2
H
CH₃
H
—
—

5′-303
Pd
1
5′
Ph
H
PS2
H
H
CH₃
H
pic

5′-303X
Pd
1
5′
Ph
H
PS2
H
H
CH₃
H
acac

5′-303Y
Pd
0
5′
Ph
H
PS2
H
H
CH₃
H
—
—

5′-304
Pd
1
5′
Ph
H
H
BAL1
H
CH₃
H
pic

5′-304X
Pd
1
5′
Ph
H
H
BAL1
H
CH₃
H
acac

5′-304Y
Pd
0
5′
Ph
H
H
BAL1
H
CH₃
H
—
—

5′-305
Pd
1
5′
Ph
H
BAL1
H
H
CH₃
H
pic

5′-305X
Pd
1
5′
Ph
H
BAL1
H
H
CH₃
H
acac

5′-305Y
Pd
0
5′
Ph
H
BAL1
H
H
CH₃
H
—
—

5′-306
Pd
1
5′
Ph
H
H
BAL2
H
CH₃
H
pic

5′-306X
Pd
1
5′
Ph
H
H
BAL2
H
CH₃
H
acac

5′-306Y
Pd
0
5′
Ph
H
H
BAL2
H
CH₃
H
—
—

5′-307
Pd
1
5′
Ph
H
BAL2
H
H
CH₃
H
pic

5′-307X
Pd
1
5′
Ph
H
BAL2
H
H
CH₃
H
acac

5′-307Y
Pd
0
5′
Ph
H
BAL2
H
H
CH₃
H
—
—

5′-308
Pd
1
5′
Ph
H
H
MEK1
H
CH₃
H
pic

5′-308X
Pd
1
5′
Ph
H
H
MEK1
H
CH₃
H
acac

5′-308Y
Pd
0
5′
Ph
H
H
MEK1
H
CH₃
H
—
—

5′-309
Pd
1
5′
Ph
H
MEK1
H
H
CH₃
H
pic

5′-309X
Pd
1
5′
Ph
H
MEK1
H
H
CH₃
H
acac

5′-309Y
Pd
0
5′
Ph
H
MEK1
H
H
CH₃
H
—
—

5′-310
Pd
1
5′
Ph
H
H
MEK2
H
CH₃
H
pic

5′-310X
Pd
1
5′
Ph
H
H
MEK2
H
CH₃
H
acac

5′-310Y
Pd
0
5′
Ph
H
H
MEK2
H
CH₃
H
—
—

5′-311
Pd
1
5′
Ph
H
MEK2
H
H
CH₃
H
pic

5′-311X
Pd
1
5′
Ph
H
MEK2
H
H
CH₃
H
acac

5′-311Y
Pd
0
5′
Ph
H
MEK2
H
H
CH₃
H
—
—

5′-312
Pd
1
5′
Ph
H
H
PAL1
H
CH₃
H
pic

5′-312X
Pd
1
5′
Ph
H
H
PAL1
H
CH₃
H
acac

5′-312Y
Pd
0
5′
Ph
H
H
PAL1
H
CH₃
H
—
—

5′-313
Pd
1
5′
Ph
H
PAL1
H
H
CH₃
H
pic

5′-313X
Pd
1
5′
Ph
H
PAL1
H
H
CH₃
H
acac

5′-313Y
Pd
0
5′
Ph
H
PAL1
H
H
CH₃
H
—
—

5′-314
Pd
1
5′
Ph
H
H
PAL2
H
CH₃
H
pic

5′-314X
Pd
1
5′
Ph
H
H
PAL2
H
CH₃
H
acac

5′-314Y
Pd
0
5′
Ph
H
H
PAL2
H
CH₃
H
—
—

5′-315
Pd
1
5′
Ph
H
PAL2
H
H
CH₃
H
pic

5′-315X
Pd
1
5′
Ph
H
PAL2
H
H
CH₃
H
acac

5′-315Y
Pd
0
5′
Ph
H
PAL2
H
H
CH₃
H
—
—

5′-316
Pd
1
5′
Ph
H
H
MMK
H
CH₃
H
pic

5′-316X
Pd
1
5′
Ph
H
H
MMK
H
CH₃
H
acac

5′-316Y
Pd
0
5′
Ph
H
H
MMK
H
CH₃
H
—
—

5′-317
Pd
1
5′
Ph
H
MMK
H
H
CH₃
H
pic

5′-317X
Pd
1
5′
Ph
H
MMK
H
H
CH₃
H
acac

5′-317Y
Pd
0
5′
Ph
H
MMK
H
H
CH₃
H
—
—

5′-318
Pd
1
5′
Ph
H
H
EES1
H
CH₃
H
pic

5′-318X
Pd
1
5′
Ph
H
H
EES1
H
CH₃
H
acac

5′-318Y
Pd
0
5′
Ph
H
H
EES1
H
CH₃
H
—
—

5′-319
Pd
1
5′
Ph
H
EES2
H
H
CH₃
H
pic

5′-319X
Pd
1
5′
Ph
H
EES2
H
H
CH₃
H
acac

5′-319Y
Pd
0
5′
Ph
H
EES2
H
H
CH₃
H
—
—

5′-320
Pd
1
5′
Ph
H
H
PAE1
H
CH₃
H
pic

5′-320X
Pd
1
5′
Ph
H
H
PAE1
H
CH₃
H
acac

5′-320Y
Pd
0
5′
Ph
H
H
PAE1
H
CH₃
H
—
—

5′-321
Pd
1
5′
Ph
H
PAE2
H
H
CH₃
H
pic

5′-321X
Pd
1
5′
Ph
H
PAE2
H
H
CH₃
H
acac

5′-321Y
Pd
0
5′
Ph
H
PAE2
H
H
CH₃
H
—
—

5′-322
Pd
1
5′
Ph
H
H
AME1
H
CH₃
H
pic

5′-322X
Pd
1
5′
Ph
H
H
AME1
H
CH₃
H
acac

5′-322Y
Pd
0
5′
Ph
H
H
AME1
H
CH₃
H
—
—

5′-323
Pd
1
5′
Ph
H
AME1
H
H
CH₃
H
pic

5′-323X
Pd
1
5′
Ph
H
AME1
H
H
CH₃
H
acac

5′-323Y
Pd
0
5′
Ph
H
AME1
H
H
CH₃
H
—
—

5′-324
Pd
1
5′
Ph
H
H
AME2
H
CH₃
H
pic

5′-324X
Pd
1
5′
Ph
H
H
AME2
H
CH₃
H
acac

5′-324Y
Pd
0
5′
Ph
H
H
AME2
H
CH₃
H
—
—

5′-325
Pd
1
5′
Ph
H
AME2
H
H
CH₃
H
pic

5′-325X
Pd
1
5′
Ph
H
AME2
H
H
CH₃
H
acac

5′-325Y
Pd
0
5′
Ph
H
AME2
H
H
CH₃
H
—
—

5′-326
Pd
1
5′
Ph
H
H
EAE1
H
CH₃
H
pic

5′-326X
Pd
1
5′
Ph
H
H
EAE1
H
CH₃
H
acac

5′-326Y
Pd
0
5′
Ph
H
H
EAE1
H
CH₃
H
—
—

5′-327
Pd
1
5′
Ph
H
EAE1
H
H
CH₃
H
pic

5′-327X
Pd
1
5′
Ph
H
EAE1
H
H
CH₃
H
acac

5′-327Y
Pd
0
5′
Ph
H
EAE1
H
H
CH₃
H
—
—

5′-328
Pd
1
5′
Ph
H
H
EAE2
H
CH₃
H
pic

5′-328X
Pd
1
5′
Ph
H
H
EAE2
H
CH₃
H
acac

5′-328Y
Pd
0
5′
Ph
H
H
EAE2
H
CH₃
H
—
—

5′-329
Pd
1
5′
Ph
H
EAE2
H
H
CH₃
H
pic

5′-329X
Pd
1
5′
Ph
H
EAE2
H
H
CH₃
H
acac

5′-329Y
Pd
0
5′
Ph
H
EAE2
H
H
CH₃
H
—
—

5′-330
Pd
1
5′
Ph
H
H
AAE1
H
CH₃
H
pic

5′-330X
Pd
1
5′
Ph
H
H
AAE1
H
CH₃
H
acac

5′-330Y
Pd
0
5′
Ph
H
H
AAE1
H
CH₃
H
—
—

5′-331
Pd
1
5′
Ph
H
AAE1
H
H
CH₃
H
pic

5′-331X
Pd
1
5′
Ph
H
AAE1
H
H
CH₃
H
acac

5′-331Y
Pd
0
5′
Ph
H
AAE1
H
H
CH₃
H
—
—

5′-332
Pd
1
5′
Ph
H
H
AAE2
H
CH₃
H
pic

5′-332X
Pd
1
5′
Ph
H
H
AAE2
H
CH₃
H
acac

5′-332Y
Pd
0
5′
Ph
H
H
AAE2
H
CH₃
H
—
—

5′-333
Pd
1
5′
Ph
H
AAE2
H
H
CH₃
H
pic

5′-333X
Pd
1
5′
Ph
H
AAE2
H
H
CH₃
H
acac

5′-333Y
Pd
0
5′
Ph
H
AAE2
H
H
CH₃
H
—
—

5′-334
Pd
1
5′
Ph
H
H
PME1
H
CH₃
H
pic

5′-334X
Pd
1
5′
Ph
H
H
PME1
H
CH₃
H
acac

5′-334Y
Pd
0
5′
Ph
H
H
PME1
H
CH₃
H
—
—

5′-335
Pd
1
5′
Ph
H
PME1
H
H
CH₃
H
pic

5′-335X
Pd
1
5′
Ph
H
PME1
H
H
CH₃
H
acac

5′-335Y
Pd
0
5′
Ph
H
PME1
H
H
CH₃
H
—
—

5′-336
Pd
1
5′
Ph
H
H
PME2
H
CH₃
H
pic

5′-336X
Pd
1
5′
Ph
H
H
PME2
H
CH₃
H
acac

5′-336Y
Pd
0
5′
Ph
H
H
PME2
H
CH₃
H
—
—

5′-337
Pd
1
5′
Ph
H
PME2
H
H
CH₃
H
pic

5′-337X
Pd
1
5′
Ph
H
PME2
H
H
CH₃
H
acac

5′-337Y
Pd
0
5′
Ph
H
PME2
H
H
CH₃
H
—
—

5′-338
Pd
1
5′
Ph
H
H
MET1
H
CH₃
H
pic

5′-338X
Pd
1
5′
Ph
H
H
MET1
H
CH₃
H
acac

5′-338Y
Pd
0
5′
Ph
H
H
MET1
H
CH₃
H
—
—

5′-339
Pd
1
5′
Ph
H
MET1
H
H
CH₃
H
pic

5′-339X
Pd
1
5′
Ph
H
MET1
H
H
CH₃
H
acac

5′-339Y
Pd
0
5′
Ph
H
MET1
H
H
CH₃
H
—
—

5′-340
Pd
1
5′
Ph
H
H
MET2
H
CH₃
H
pic

5′-340X
Pd
1
5′
Ph
H
H
MET2
H
CH₃
H
acac

5′-340Y
Pd
0
5′
Ph
H
H
MET2
H
CH₃
H
—
—

5′-341
Pd
1
5′
Ph
H
MET2
H
H
CH₃
H
pic

5′-341X
Pd
1
5′
Ph
H
MET2
H
H
CH₃
H
acac

5′-341Y
Pd
0
5′
Ph
H
MET2
H
H
CH₃
H
—
—

5′-342
Pd
1
5′
Ph
H
H
EE1
H
CH₃
H
pic

5′-342X
Pd
1
5′
Ph
H
H
EE1
H
CH₃
H
acac

5′-342Y
Pd
0
5′
Ph
H
H
EE1
H
CH₃
H
—
—

5′-343
Pd
1
5′
Ph
H
EE1
H
H
CH₃
H
pic

5′-343X
Pd
1
5′
Ph
H
EE1
H
H
CH₃
H
acac

5′-343Y
Pd
0
5′
Ph
H
EE1
H
H
CH₃
H
—
—

5′-344
Pd
1
5′
Ph
H
H
EE2
H
CH₃
H
pic

5′-344X
Pd
1
5′
Ph
H
H
EE2
H
CH₃
H
acac

5′-344Y
Pd
0
5′
Ph
H
H
EE2
H
CH₃
H
—
—

5′-345
Pd
1
5′
Ph
H
EE2
H
H
CH₃
H
pic

5′-345X
Pd
1
5′
Ph
H
EE2
H
H
CH₃
H
acac

5′-345Y
Pd
0
5′
Ph
H
EE2
H
H
CH₃
H
—
—

5′-346
Pd
1
5′
Ph
H
H
MS1
H
CH₃
H
pic

5′-346X
Pd
1
5′
Ph
H
H
MS1
H
CH₃
H
acac

5′-346Y
Pd
0
5′
Ph
H
H
MS1
H
CH₃
H
—
—

5′-347
Pd
1
5′
Ph
H
MS1
H
H
CH₃
H
pic

5′-347X
Pd
1
5′
Ph
H
MS1
H
H
CH₃
H
acac

5′-347Y
Pd
0
5′
Ph
H
MS1
H
H
CH₃
H
—
—

5′-348
Pd
1
5′
Ph
H
H
MS2
H
CH₃
H
pic

5′-348X
Pd
1
5′
Ph
H
H
MS2
H
CH₃
H
acac

5′-348Y
Pd
0
5′
Ph
H
H
MS2
H
CH₃
H
—
—

5′-349
Pd
1
5′
Ph
H
MS2
H
H
CH₃
H
pic

5′-349X
Pd
1
5′
Ph
H
MS2
H
H
CH₃
H
acac

5′-349Y
Pd
0
5′
Ph
H
MS2
H
H
CH₃
H
—
—

TABLE 48

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

6′-167
Pd
1
6′
Ph
H
H
H
H
H
CH₃
H
pic

6′-167X
Pd
1
6′
Ph
H
H
H
H
H
CH₃
H
acac

6′-167Y
Pd
0
6′
Ph
H
H
H
H
H
CH₃
H
—
—

6′-168
Pd
1
6′
Ph
H
H
H
H
H

^tC₄H₉
H
pic

6′-168X
Pd
1
6′
Ph
H
H
H
H
H

^tC₄H₉
H
acac

6′-168Y
Pd
0
6′
Ph
H
H
H
H
H

^tC₄H₉
H
—
—

6′-169
Pd
1
6′
Ph
H
F
H
F
H
CH₃
H
pic

6′-169X
Pd
1
6′
Ph
H
F
H
F
H
CH₃
H
acac

6′-169Y
Pd
0
6′
Ph
H
F
H
F
H
CH₃
H
—
—

6′-170
Pd
1
6′
Ph
H
F
H
F
H

^tC₄H₉
H
pic

6′-170X
Pd
1
6′
Ph
H
F
H
F
H

^tC₄H₉
H
acac

6′-170Y
Pd
0
6′
Ph
H
F
H
F
H

^tC₄H₉
H
—
—

6′-171
Pd
1
6′
Ph
CF₃
H
CF₃
H
H
CH₃
H
pic

6′-171X
Pd
1
6′
Ph
CF₃
H
CF₃
H
H
CH₃
H
acac

6′-171Y
Pd
0
6′
Ph
CF₃
H
CF₃
H
H
CH₃
H
—
—

6′-172
Pd
1
6′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
pic

6′-172X
Pd
1
6′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
acac

6′-172Y
Pd
0
6′
Ph
CF₃
H
CF₃
H
H

^tC₄H₉
H
—
—

6′-173
Pd
1
6′
Ph
H
F
CF₃
H
H
CH₃
H
pic

6′-173X
Pd
1
6′
Ph
H
F
CF₃
H
H
CH₃
H
acac

6′-173Y
Pd
0
6′
Ph
H
F
CF₃
H
H
CH₃
H
—
—

6′-174
Pd
1
6′
Ph
F
H
CF₃
H
H
CH₃
H
pic

6′-174X
Pd
1
6′
Ph
F
H
CF₃
H
H
CH₃
H
acac

6′-174Y
Pd
0
6′
Ph
F
H
CF₃
H
H
CH₃
H
—
—

6′-175
Pd
1
6′
Ph
F
F
F
F
H
CH₃
H
pic

6′-175X
Pd
1
6′
Ph
F
F
F
F
H
CH₃
H
acac

6′-175Y
Pd
0
6′
Ph
F
F
F
F
H
CH₃
H
—
—

6′-176
Pd
1
6′
Ph
H
F
H
CH₃
H
CH₃
H
pic

6′-176X
Pd
1
6′
Ph
H
F
H
CH₃
H
CH₃
H
acac

6′-176Y
Pd
0
6′
Ph
H
F
H
CH₃
H
CH₃
H
—
—

6′-177
Pd
1
6′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
pic

6′-177X
Pd
1
6′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
acac

6′-177Y
Pd
0
6′
Ph
H
F
H
CH₃
H

^tC₄H₉
H
—
—

6′-178
Pd
1
6′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
pic

6′-178X
Pd
1
6′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
acac

6′-178Y
Pd
0
6′
Ph
H
F
H

^tC₄H₉
H
CH₃
H
—
—

6′-179
Pd
1
6′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
pic

6′-179X
Pd
1
6′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
acac

6′-179Y
Pd
0
6′
Ph
H
F
H

^tC₄H₉
H

^tC₄H₉
H
—
—

6′-180
Pd
1
6′
Ph
H
CF₃
H
CF₃
H
CH₃
H
pic

6′-180X
Pd
1
6′
Ph
H
CF₃
H
CF₃
H
CH₃
H
acac

6′-180Y
Pd
0
6′
Ph
H
CF₃
H
CF₃
H
CH₃
H
—
—

6′-181
Pd
1
6′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
pic

6′-181X
Pd
1
6′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
acac

6′-181Y
Pd
0
6′
Ph
H
CF₃
H
CF₃
H

^tC₄H₉
H
—
—

6′-182
Pd
1
6′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
pic

6′-182X
Pd
1
6′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
acac

6′-182Y
Pd
0
6′
Ph
CF₃
H
H

^tC₄H₉
H
CH₃
H
—
—

6′-183
Pd
1
6′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
pic

6′-183X
Pd
1
6′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
acac

6′-183Y
Pd
0
6′
Ph
CF₃
H
H

^tC₄H₉
H

^tC₄H₉
H
—
—

6′-184
Pd
1
6′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
pic

6′-184X
Pd
1
6′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
acac

6′-184Y
Pd
0
6′
Ph
H
CF₃
H

^tC₄H₉
H
CH₃
H
—
—

6′-185
Pd
1
6′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
pic

6′-185X
Pd
1
6′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
acac

6′-185Y
Pd
0
6′
Ph
H
CF₃
H

^tC₄H₉
H

^tC₄H₉
H
—
—

6′-186
Pd
1
6′
Ph
H
CF₃
H
CH₃
H
CH₃
H
pic

6′-186X
Pd
1
6′
Ph
H
CF₃
H
CH₃
H
CH₃
H
acac

6′-186Y
Pd
0
6′
Ph
H
CF₃
H
CH₃
H
CH₃
H
—
—

6′-170
Pd
1
6′
Ph
H
CF₃
CF₃
H
H
CH₃
H
pic

6′-170X
Pd
1
6′
Ph
H
CF₃
CF₃
H
H
CH₃
H
acac

6′-170Y
Pd
0
6′
Ph
H
CF₃
CF₃
H
H
CH₃
H
—
—

6′-171
Pd
1
6′
Ph
H
H
NO₂
H
H
CH₃
H
pic

6′-171X
Pd
1
6′
Ph
H
H
NO₂
H
H
CH₃
H
acac

6′-171Y
Pd
0
6′
Ph
H
H
NO₂
H
H
CH₃
H
—
—

6′-172
Pd
1
6′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
pic

6′-172X
Pd
1
6′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
acac

6′-172Y
Pd
0
6′
Ph
H
H
NO₂
H
H

^tC₄H₉
H
—
—

6′-173
Pd
1
6′
Ph
F
H
NO₂
H
H
CH₃
H
pic

6′-173X
Pd
1
6′
Ph
F
H
NO₂
H
H
CH₃
H
acac

6′-173Y
Pd
0
6′
Ph
F
H
NO₂
H
H
CH₃
H
—
—

6′-174
Pd
1
6′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
pic

6′-174X
Pd
1
6′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
acac

6′-174Y
Pd
0
6′
Ph
F
H
NO₂
H
H

^tC₄H₉
H
—
—

6′-175
Pd
1
6′
Ph
F
H
NO₂
F
H
CH₃
H
pic

6′-175X
Pd
1
6′
Ph
F
H
NO₂
F
H
CH₃
H
acac

6′-175Y
Pd
0
6′
Ph
F
H
NO₂
F
H
CH₃
H
—
—

6′-176
Pd
1
6′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
pic

6′-176X
Pd
1
6′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
acac

6′-176Y
Pd
0
6′
Ph
F
H
NO₂
F
H

^tC₄H₉
H
—
—

6′-177
Pd
1
6′
Ph
H
NO₂
H
NO₂
H
CH₃
H
pic

6′-177X
Pd
1
6′
Ph
H
NO₂
H
NO₂
H
CH₃
H
acac

6′-177Y
Pd
0
6′
Ph
H
NO₂
H
NO₂
H
CH₃
H
—
—

6′-178
Pd
1
6′
Ph
H
NO₂
H
NO₂
H
CH₃
H
pic

6′-178X
Pd
1
6′
Ph
H
NO₂
H
NO₂
H
CH₃
H
acac

6′-178Y
Pd
0
6′
Ph
H
NO₂
H
NO₂
H
CH₃
H
—
—

6′-179
Pd
1
6′
Ph
NO₂
H
H
NO₂
H
CH₃
H
pic

6′-179X
Pd
1
6′
Ph
NO₂
H
H
NO₂
H
CH₃
H
acac

6′-179Y
Pd
0
6′
Ph
NO₂
H
H
NO₂
H
CH₃
H
—
—

6′-180
Pd
1
6′
Ph
H
H
CF₃
H
H
CH₃
H
pic

6′-180X
Pd
1
6′
Ph
H
H
CF₃
H
H
CH₃
H
acac

6′-180Y
Pd
0
6′
Ph
H
H
CF₃
H
H
CH₃
H
—
—

6′-181
Pd
1
6′
Ph
H
Cl
CF₃
H
H
CH₃
H
pic

6′-181X
Pd
1
6′
Ph
H
Cl
CF₃
H
H
CH₃
H
acac

6′-181Y
Pd
0
6′
Ph
H
Cl
CF₃
H
H
CH₃
H
—
—

6′-182
Pd
1
6′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
pic

6′-182X
Pd
1
6′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
acac

6′-182Y
Pd
0
6′
Ph
H
Cl
CF₃
H
H

^tC₄H₉
H
—
—

6′-183
Pd
1
6′
Ph
H
NO₂
H
H
H
CH₃
H
pic

6′-183X
Pd
1
6′
Ph
H
NO₂
H
H
H
CH₃
H
acac

6′-183Y
Pd
0
6′
Ph
H
NO₂
H
H
H
CH₃
H
—
—

6′-184
Pd
1
6′
Ph
H
CF₃
H
H
H
CH₃
H
pic

6′-184X
Pd
1
6′
Ph
H
CF₃
H
H
H
CH₃
H
acac

6′-184Y
Pd
0
6′
Ph
H
CF₃
H
H
H
CH₃
H
—
—

6′-186
Pd
1
6′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
pic

6′-186X
Pd
1
6′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
acac

6′-186Y
Pd
0
6′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
—
—

6′-187
Pd
1
6′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
pic

6′-187X
Pd
1
6′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
acac

6′-187Y
Pd
0
6′
Ph
H
NO₂
H
CH₃
H

^tC₄H₉
H
—
—

6′-188
Pd
1
6′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
pic

6′-188X
Pd
1
6′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
acac

6′-188Y
Pd
0
6′
Ph
H
NO₂
H

^tC₄H₉
H
CH₃
H
—
—

6′-189
Pd
1
6′
Ph
H
H
CH₃O
H
H
CH₃
H
pic

6′-189X
Pd
1
6′
Ph
H
H
CH₃O
H
H
CH₃
H
acac

6′-189Y
Pd
0
6′
Ph
H
H
CH₃O
H
H
CH₃
H
—
—

6′-190
Pd
1
6′
Ph
H
CH₃O
H
H
H
CH₃
H
pic

6′-190X
Pd
1
6′
Ph
H
CH₃O
H
H
H
CH₃
H
acac

6′-190Y
Pd
0
6′
Ph
H
CH₃O
H
H
H
CH₃
H
—
—

6′-191
Pd
1
6′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
pic

6′-191X
Pd
1
6′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
acac

6′-191Y
Pd
0
6′
Ph
H
CH₃O
H
CH₃
H
CH₃
H
—
—

6′-192
Pd
1
6′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
pic

6′-192X
Pd
1
6′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
acac

6′-192Y
Pd
0
6′
Ph
H
CH₃O
H

^tC₄H₉
H
CH₃
H
—
—

6′-193
Pd
1
6′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
pic

6′-193X
Pd
1
6′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
acac

6′-193Y
Pd
0
6′
Ph
H
H
H
H

^tC₄H₉
CH₃
H
—
—

6′-194
Pd
1
6′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
pic

6′-194X
Pd
1
6′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
acac

6′-194Y
Pd
0
6′
Ph
H
F
H
F

^tC₄H₉
CH₃
H
—
—

6′-195
Pd
1
6′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
pic

6′-195X
Pd
1
6′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
acac

6′-195Y
Pd
0
6′
Ph
H
F
H
F

^tC₄H₉

^tC₄H₉
H
—
—

6′-196
Pd
1
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
pic

6′-196X
Pd
1
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
acac

6′-196Y
Pd
0
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉
CH₃
H
—
—

6′-197
Pd
1
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
pic

6′-197X
Pd
1
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
acac

6′-197Y
Pd
0
6′
Ph
CF₃
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
—
—

6′-198
Pd
1
6′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
pic

6′-198X
Pd
1
6′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
acac

6′-198Y
Pd
0
6′
Ph
H
CF₃
H
CH₃

^tC₄H₉
CH₃
H
—
—

6′-199
Pd
1
6′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
pic

6′-199X
Pd
1
6′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
acac

6′-199Y
Pd
0
6′
Ph
H
Si(CH₃)₃
H
H
H
CH₃
H
—
—

6′-200
Pd
1
6′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
pic

6′-200X
Pd
1
6′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
acac

6′-200Y
Pd
0
6′
Ph
H
Si(CH₃)₃
H
H
H

^tC₄H₉
H
—
—

6′-201
Pd
1
6′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
pic

6′-201X
Pd
1
6′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
acac

6′-201Y
Pd
0
6′
Ph
H
H
Si(CH₃)₃
H
H
CH₃
H
—
—

6′-202
Pd
1
6′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
pic

6′-202X
Pd
1
6′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
acac

6′-202Y
Pd
0
6′
Ph
H
H
H
Si(CH₃)₃
H
CH₃
H
—
—

6′-203
Pd
1
6′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
pic

6′-203X
Pd
1
6′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
acac

6′-203Y
Pd
0
6′
Ph
H
F
H
Si(CH₃)₃
H
CH₃
H
—
—

6′-204
Pd
1
6′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
pic

6′-204X
Pd
1
6′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
acac

6′-204Y
Pd
0
6′
Ph
H
CF₃
H
Si(CH₃)₃
H
CH₃
H
—
—

6′-205
Pd
1
6′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
pic

6′-205X
Pd
1
6′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
acac

6′-205Y
Pd
0
6′
Ph
H
Si(CH₃)₃
H
F
H
CH₃
H
—
—

6′-206
Pd
1
6′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
pic

6′-206X
Pd
1
6′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
acac

6′-206Y
Pd
0
6′
Ph
H
Si(CH₃)₃
H
F
H

^tC₄H₉
H
—
—

6′-207
Pd
1
6′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
pic

6′-207X
Pd
1
6′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
acac

6′-207Y
Pd
0
6′
Ph
H
Si(CH₃)₃
H
CF₃
H
CH₃
H
—
—

6′-208
Pd
1
6′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
pic

6′-208X
Pd
1
6′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
acac

6′-208Y
Pd
0
6′
Ph
H
Si(CH₃)₃
H
CF₃
H

^tC₄H₉
H
—
—

6′-209
Pd
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
pic

6′-209X
Pd
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
acac

6′-209Y
Pd
0
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H
CH₃
H
—
—

6′-210
Pd
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
pic

6′-210X
Pd
1
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
acac

6′-210Y
Pd
0
6′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
H

^tC₄H₉
H
—
—

6′-211
Pd
1
6′
Ph
H
H
H
COCH₃
H
CH₃
H
pic

6′-211X
Pd
1
6′
Ph
H
H
H
COCH₃
H
CH₃
H
acac

6′-211Y
Pd
0
6′
Ph
H
H
H
COCH₃
H
CH₃
H
—
—

6′-212
Pd
1
6′
Ph
H
H
COCH₃
H
H
CH₃
H
pic

6′-212X
Pd
1
6′
Ph
H
H
COCH₃
H
H
CH₃
H
acac

6′-212Y
Pd
0
6′
Ph
H
H
COCH₃
H
H
CH₃
H
—
—

6′-213
Pd
1
6′
Ph
H
COCH₃
H
H
H
CH₃
H
pic

6′-213X
Pd
1
6′
Ph
H
COCH₃
H
H
H
CH₃
H
acac

6′-213Y
Pd
0
6′
Ph
H
COCH₃
H
H
H
CH₃
H
—
—

6′-214
Pd
1
6′
Ph
H
H
BL
H
CH₃
H
pic

6′-214X
Pd
1
6′
Ph
H
H
BL
H
CH₃
H
acac

6′-214Y
Pd
0
6′
Ph
H
H
BL
H
CH₃
H
—
—

6′-215
Pd
1
6′
Ph
H
H
BL
H

^tC₄H₉
H
pic

6′-215X
Pd
1
6′
Ph
H
H
BL
H

^tC₄H₉
H
acac

6′-215Y
Pd
0
6′
Ph
H
H
BL
H

^tC₄H₉
H
—
—

6′-216
Pd
1
6′
Ph
H
BL
H
H
CH₃
H
pic

6′-216X
Pd
1
6′
Ph
H
BL
H
H
CH₃
H
acac

6′-216Y
Pd
0
6′
Ph
H
BL
H
H
CH₃
H
—
—

6′-217
Pd
1
6′
Ph
H
BL
H
H

^tC₄H₉
H
pic

6′-217X
Pd
1
6′
Ph
H
BL
H
H

^tC₄H₉
H
acac

6′-217Y
Pd
0
6′
Ph
H
BL
H
H

^tC₄H₉
H
—
—

6′-218
Pd
1
6′
Ph
H
H
PL
H
CH₃
H
pic

6′-218X
Pd
1
6′
Ph
H
H
PL
H
CH₃
H
acac

6′-218Y
Pd
0
6′
Ph
H
H
PL
H
CH₃
H
—
—

6′-219
Pd
1
6′
Ph
H
H
PL
H

^tC₄H₉
H
pic

6′-219X
Pd
1
6′
Ph
H
H
PL
H

^tC₄H₉
H
acac

6′-219Y
Pd
0
6′
Ph
H
H
PL
H

^tC₄H₉
H
—
—

6′-220
Pd
1
6′
Ph
H
PL
H
H
CH₃
H
pic

6′-220X
Pd
1
6′
Ph
H
PL
H
H
CH₃
H
acac

6′-220Y
Pd
0
6′
Ph
H
PL
H
H
CH₃
H
—
—

6′-221
Pd
1
6′
Ph
H
PL
H
H

^tC₄H₉
H
pic

6′-221X
Pd
1
6′
Ph
H
PL
H
H

^tC₄H₉
H
acac

6′-221Y
Pd
0
6′
Ph
H
PL
H
H

^tC₄H₉
H
—
—

6′-222
Pd
1
6′
Ph
H
H
MEE1
H
CH₃
H
pic

6′-222X
Pd
1
6′
Ph
H
H
MEE1
H
CH₃
H
acac

6′-222Y
Pd
0
6′
Ph
H
H
MEE1
H
CH₃
H
—
—

6′-223
Pd
1
6′
Ph
H
MEE1
H
H
CH₃
H
pic

6′-223X
Pd
1
6′
Ph
H
MEE1
H
H
CH₃
H
acac

6′-223Y
Pd
0
6′
Ph
H
MEE1
H
H
CH₃
H
—
—

6′-224
Pd
1
6′
Ph
H
H
MEE2
H
CH₃
H
pic

6′-224X
Pd
1
6′
Ph
H
H
MEE2
H
CH₃
H
acac

6′-224Y
Pd
0
6′
Ph
H
H
MEE2
H
CH₃
H
—
—

6′-225
Pd
1
6′
Ph
H
MEE2
H
H
CH₃
H
pic

6′-225X
Pd
1
6′
Ph
H
MEE2
H
H
CH₃
H
acac

6′-225Y
Pd
0
6′
Ph
H
MEE2
H
H
CH₃
H
—
—

6′-226
Pd
1
6′
Ph
H
H
PA1
H
CH₃
H
pic

6′-226X
Pd
1
6′
Ph
H
H
PA1
H
CH₃
H
acac

6′-226Y
Pd
0
6′
Ph
H
H
PA1
H
CH₃
H
—
—

6′-227
Pd
1
6′
Ph
H
PA1
H
H
CH₃
H
pic

6′-227X
Pd
1
6′
Ph
H
PA1
H
H
CH₃
H
acac

6′-227Y
Pd
0
6′
Ph
H
PA1
H
H
CH₃
H
—
—

6′-228
Pd
1
6′
Ph
H
H
PA2
H
CH₃
H
pic

6′-228X
Pd
1
6′
Ph
H
H
PA2
H
CH₃
H
acac

6′-228Y
Pd
0
6′
Ph
H
H
PA2
H
CH₃
H
—
—

6′-229
Pd
1
6′
Ph
H
PA2
H
H
CH₃
H
pic

6′-229X
Pd
1
6′
Ph
H
PA2
H
H
CH₃
H
acac

6′-229Y
Pd
0
6′
Ph
H
PA2
H
H
CH₃
H
—
—

6′-230
Pd
1
6′
Ph
H
H
EA1
H
CH₃
H
pic

6′-230X
Pd
1
6′
Ph
H
H
EA1
H
CH₃
H
acac

6′-230Y
Pd
0
6′
Ph
H
H
EA1
H
CH₃
H
—
—

6′-231
Pd
1
6′
Ph
H
EA2
H
H
CH₃
H
pic

6′-231X
Pd
1
6′
Ph
H
EA2
H
H
CH₃
H
acac

6′-231Y
Pd
0
6′
Ph
H
EA2
H
H
CH₃
H
—
—

6′-232
Pd
1
6′
Ph
H
H
ME
H
CH₃
H
pic

6′-232X
Pd
1
6′
Ph
H
H
ME
H
CH₃
H
acac

6′-232Y
Pd
0
6′
Ph
H
H
ME
H
CH₃
H
—
—

6′-233
Pd
1
6′
Ph
H
ME
H
H
CH₃
H
pic

6′-233X
Pd
1
6′
Ph
H
ME
H
H
CH₃
H
acac

6′-233Y
Pd
0
6′
Ph
H
ME
H
H
CH₃
H
—
—

6′-234
Pd
1
6′
Ph
H
H
AT
H
CH₃
H
pic

6′-234X
Pd
1
6′
Ph
H
H
AT
H
CH₃
H
acac

6′-234Y
Pd
0
6′
Ph
H
H
AT
H
CH₃
H
—
—

6′-235
Pd
1
6′
Ph
H
AT
H
H
CH₃
H
pic

6′-235X
Pd
1
6′
Ph
H
AT
H
H
CH₃
H
acac

6′-235Y
Pd
0
6′
Ph
H
AT
H
H
CH₃
H
—
—

6′-236
Pd
1
6′
Ph
H
H
MES1
H
CH₃
H
pic

6′-236X
Pd
1
6′
Ph
H
H
MES1
H
CH₃
H
acac

6′-236Y
Pd
0
6′
Ph
H
H
MES1
H
CH₃
H
—
—

6′-237
Pd
1
6′
Ph
H
MES1
H
H
CH₃
H
pic

6′-237X
Pd
1
6′
Ph
H
MES1
H
H
CH₃
H
acac

6′-237Y
Pd
0
6′
Ph
H
MES1
H
H
CH₃
H
—
—

6′-238
Pd
1
6′
Ph
H
H
MES2
H
CH₃
H
pic

6′-238X
Pd
1
6′
Ph
H
H
MES2
H
CH₃
H
acac

6′-238Y
Pd
0
6′
Ph
H
H
MES2
H
CH₃
H
—
—

6′-239
Pd
1
6′
Ph
H
MES2
H
H
CH₃
H
pic

6′-239X
Pd
1
6′
Ph
H
MES2
H
H
CH₃
H
acac

6′-239Y
Pd
0
6′
Ph
H
MES2
H
H
CH₃
H
—
—

6′-240
Pd
1
6′
Ph
H
H
PS1
H
CH₃
H
pic

6′-240X
Pd
1
6′
Ph
H
H
PS1
H
CH₃
H
acac

6′-240Y
Pd
0
6′
Ph
H
H
PS1
H
CH₃
H
—
—

6′-241
Pd
1
6′
Ph
H
PS1
H
H
CH₃
H
pic

6′-241X
Pd
1
6′
Ph
H
PS1
H
H
CH₃
H
acac

6′-241Y
Pd
0
6′
Ph
H
PS1
H
H
CH₃
H
—
—

6′-242
Pd
1
6′
Ph
H
H
PS2
H
CH₃
H
pic

6′-242X
Pd
1
6′
Ph
H
H
PS2
H
CH₃
H
acac

6′-242Y
Pd
0
6′
Ph
H
H
PS2
H
CH₃
H
—
—

6′-243
Pd
1
6′
Ph
H
PS2
H
H
CH₃
H
pic

6′-243X
Pd
1
6′
Ph
H
PS2
H
H
CH₃
H
acac

6′-243Y
Pd
0
6′
Ph
H
PS2
H
H
CH₃
H
—
—

6′-244
Pd
1
6′
Ph
H
H
BAL1
H
CH₃
H
pic

6′-244X
Pd
1
6′
Ph
H
H
BAL1
H
CH₃
H
acac

6′-244Y
Pd
0
6′
Ph
H
H
BAL1
H
CH₃
H
—
—

6′-245
Pd
1
6′
Ph
H
BAL1
H
H
CH₃
H
pic

6′-245X
Pd
1
6′
Ph
H
BAL1
H
H
CH₃
H
acac

6′-245Y
Pd
0
6′
Ph
H
BAL1
H
H
CH₃
H
—
—

6′-246
Pd
1
6′
Ph
H
H
BAL2
H
CH₃
H
pic

6′-246X
Pd
1
6′
Ph
H
H
BAL2
H
CH₃
H
acac

6′-246Y
Pd
0
6′
Ph
H
H
BAL2
H
CH₃
H
—
—

6′-247
Pd
1
6′
Ph
H
BAL2
H
H
CH₃
H
pic

6′-247X
Pd
1
6′
Ph
H
BAL2
H
H
CH₃
H
acac

6′-247Y
Pd
0
6′
Ph
H
BAL2
H
H
CH₃
H
—
—

6′-248
Pd
1
6′
Ph
H
H
MEK1
H
CH₃
H
pic

6′-248X
Pd
1
6′
Ph
H
H
MEK1
H
CH₃
H
acac

6′-248Y
Pd
0
6′
Ph
H
H
MEK1
H
CH₃
H
—
—

6′-249
Pd
1
6′
Ph
H
MEK1
H
H
CH₃
H
pic

6′-249X
Pd
1
6′
Ph
H
MEK1
H
H
CH₃
H
acac

6′-249Y
Pd
0
6′
Ph
H
MEK1
H
H
CH₃
H
—
—

6′-250
Pd
1
6′
Ph
H
H
MEK2
H
CH₃
H
pic

6′-250X
Pd
1
6′
Ph
H
H
MEK2
H
CH₃
H
acac

6′-250Y
Pd
0
6′
Ph
H
H
MEK2
H
CH₃
H
—
—

6′-251
Pd
1
6′
Ph
H
MEK2
H
H
CH₃
H
pic

6′-251X
Pd
1
6′
Ph
H
MEK2
H
H
CH₃
H
acac

6′-251Y
Pd
0
6′
Ph
H
MEK2
H
H
CH₃
H
—
—

6′-252
Pd
1
6′
Ph
H
H
PAL1
H
CH₃
H
pic

6′-252X
Pd
1
6′
Ph
H
H
PAL1
H
CH₃
H
acac

6′-252Y
Pd
0
6′
Ph
H
H
PAL1
H
CH₃
H
—
—

6′-253
Pd
1
6′
Ph
H
PAL1
H
H
CH₃
H
pic

6′-253X
Pd
1
6′
Ph
H
PAL1
H
H
CH₃
H
acac

6′-253Y
Pd
0
6′
Ph
H
PAL1
H
H
CH₃
H
—
—

6′-254
Pd
1
6′
Ph
H
H
PAL2
H
CH₃
H
pic

6′-254X
Pd
1
6′
Ph
H
H
PAL2
H
CH₃
H
acac

6′-254Y
Pd
0
6′
Ph
H
H
PAL2
H
CH₃
H
—
—

6′-256
Pd
1
6′
Ph
H
PAL2
H
H
CH₃
H
pic

6′-256X
Pd
1
6′
Ph
H
PAL2
H
H
CH₃
H
acac

6′-256Y
Pd
0
6′
Ph
H
PAL2
H
H
CH₃
H
—
—

6′-256
Pd
1
6′
Ph
H
H
MMK
H
CH₃
H
pic

6′-256X
Pd
1
6′
Ph
H
H
MMK
H
CH₃
H
acac

6′-256Y
Pd
0
6′
Ph
H
H
MMK
H
CH₃
H
—
—

6′-257
Pd
1
6′
Ph
H
MMK
H
H
CH₃
H
pic

6′-257X
Pd
1
6′
Ph
H
MMK
H
H
CH₃
H
acac

6′-257Y
Pd
0
6′
Ph
H
MMK
H
H
CH₃
H
—
—

6′-258
Pd
1
6′
Ph
H
H
EES1
H
CH₃
H
pic

6′-258X
Pd
1
6′
Ph
H
H
EES1
H
CH₃
H
acac

6′-258Y
Pd
0
6′
Ph
H
H
EES1
H
CH₃
H
—
—

6′-259
Pd
1
6′
Ph
H
EES2
H
H
CH₃
H
pic

6′-259X
Pd
1
6′
Ph
H
EES2
H
H
CH₃
H
acac

6′-259Y
Pd
0
6′
Ph
H
EES2
H
H
CH₃
H
—
—

6′-260
Pd
1
6′
Ph
H
H
PAE1
H
CH₃
H
pic

6′-260X
Pd
1
6′
Ph
H
H
PAE1
H
CH₃
H
acac

6′-260Y
Pd
0
6′
Ph
H
H
PAE1
H
CH₃
H
—
—

6′-261
Pd
1
6′
Ph
H
PAE2
H
H
CH₃
H
pic

6′-261X
Pd
1
6′
Ph
H
PAE2
H
H
CH₃
H
acac

6′-261Y
Pd
0
6′
Ph
H
PAE2
H
H
CH₃
H
—
—

6′-262
Pd
1
6′
Ph
H
H
AME1
H
CH₃
H
pic

6′-262X
Pd
1
6′
Ph
H
H
AME1
H
CH₃
H
acac

6′-262Y
Pd
0
6′
Ph
H
H
AME1
H
CH₃
H
—
—

6′-263
Pd
1
6′
Ph
H
AME1
H
H
CH₃
H
pic

6′-263X
Pd
1
6′
Ph
H
AME1
H
H
CH₃
H
acac

6′-263Y
Pd
0
6′
Ph
H
AME1
H
H
CH₃
H
—
—

6′-264
Pd
1
6′
Ph
H
H
AME2
H
CH₃
H
pic

6′-264X
Pd
1
6′
Ph
H
H
AME2
H
CH₃
H
acac

6′-264Y
Pd
0
6′
Ph
H
H
AME2
H
CH₃
H
—
—

6′-265
Pd
1
6′
Ph
H
AME2
H
H
CH₃
H
pic

6′-265X
Pd
1
6′
Ph
H
AME2
H
H
CH₃
H
acac

6′-265Y
Pd
0
6′
Ph
H
AME2
H
H
CH₃
H
—
—

6′-266
Pd
1
6′
Ph
H
H
EAE1
H
CH₃
H
pic

6′-266X
Pd
1
6′
Ph
H
H
EAE1
H
CH₃
H
acac

6′-266Y
Pd
0
6′
Ph
H
H
EAE1
H
CH₃
H
—
—

6′-267
Pd
1
6′
Ph
H
EAE1
H
H
CH₃
H
pic

6′-267X
Pd
1
6′
Ph
H
EAE1
H
H
CH₃
H
acac

6′-267Y
Pd
0
6′
Ph
H
EAE1
H
H
CH₃
H
—
—

6′-268
Pd
1
6′
Ph
H
H
EAE2
H
CH₃
H
pic

6′-268X
Pd
1
6′
Ph
H
H
EAE2
H
CH₃
H
acac

6′-268Y
Pd
0
6′
Ph
H
H
EAE2
H
CH₃
H
—
—

6′-269
Pd
1
6′
Ph
H
EAE2
H
H
CH₃
H
pic

6′-269X
Pd
1
6′
Ph
H
EAE2
H
H
CH₃
H
acac

6′-269Y
Pd
0
6′
Ph
H
EAE2
H
H
CH₃
H
—
—

6′-270
Pd
1
6′
Ph
H
H
AAE1
H
CH₃
H
pic

6′-270X
Pd
1
6′
Ph
H
H
AAE1
H
CH₃
H
acac

6′-270Y
Pd
0
6′
Ph
H
H
AAE1
H
CH₃
H
—
—

6′-271
Pd
1
6′
Ph
H
AAE1
H
H
CH₃
H
pic

6′-271X
Pd
1
6′
Ph
H
AAE1
H
H
CH₃
H
acac

6′-271Y
Pd
0
6′
Ph
H
AAE1
H
H
CH₃
H
—
—

6′-272
Pd
1
6′
Ph
H
H
AAE2
H
CH₃
H
pic

6′-272X
Pd
1
6′
Ph
H
H
AAE2
H
CH₃
H
acac

6′-272Y
Pd
0
6′
Ph
H
H
AAE2
H
CH₃
H
—
—

6′-273
Pd
1
6′
Ph
H
AAE2
H
H
CH₃
H
pic

6′-273X
Pd
1
6′
Ph
H
AAE2
H
H
CH₃
H
acac

6′-273Y
Pd
0
6′
Ph
H
AAE2
H
H
CH₃
H
—
—

6′-274
Pd
1
6′
Ph
H
H
PME1
H
CH₃
H
pic

6′-274X
Pd
1
6′
Ph
H
H
PME1
H
CH₃
H
acac

6′-274Y
Pd
0
6′
Ph
H
H
PME1
H
CH₃
H
—
—

6′-275
Pd
1
6′
Ph
H
PME1
H
H
CH₃
H
pic

6′-275X
Pd
1
6′
Ph
H
PME1
H
H
CH₃
H
acac

6′-275Y
Pd
0
6′
Ph
H
PME1
H
H
CH₃
H
—
—

6′-276
Pd
1
6′
Ph
H
H
PME2
H
CH₃
H
pic

6′-276X
Pd
1
6′
Ph
H
H
PME2
H
CH₃
H
acac

6′-276Y
Pd
0
6′
Ph
H
H
PME2
H
CH₃
H
—
—

6′-277
Pd
1
6′
Ph
H
PME2
H
H
CH₃
H
pic

6′-277X
Pd
1
6′
Ph
H
PME2
H
H
CH₃
H
acac

6′-277Y
Pd
0
6′
Ph
H
PME2
H
H
CH₃
H
—
—

6′-278
Pd
1
6′
Ph
H
H
MET1
H
CH₃
H
pic

6′-278X
Pd
1
6′
Ph
H
H
MET1
H
CH₃
H
acac

6′-278Y
Pd
0
6′
Ph
H
H
MET1
H
CH₃
H
—
—

6′-279
Pd
1
6′
Ph
H
MET1
H
H
CH₃
H
pic

6′-279X
Pd
1
6′
Ph
H
MET1
H
H
CH₃
H
acac

6′-279Y
Pd
0
6′
Ph
H
MET1
H
H
CH₃
H
—
—

6′-280
Pd
1
6′
Ph
H
H
MET2
H
CH₃
H
pic

6′-280X
Pd
1
6′
Ph
H
H
MET2
H
CH₃
H
acac

6′-280Y
Pd
0
6′
Ph
H
H
MET2
H
CH₃
H
—
—

6′-281
Pd
1
6′
Ph
H
MET2
H
H
CH₃
H
pic

6′-281X
Pd
1
6′
Ph
H
MET2
H
H
CH₃
H
acac

6′-281Y
Pd
0
6′
Ph
H
MET2
H
H
CH₃
H
—
—

6′-282
Pd
1
6′
Ph
H
H
EE1
H
CH₃
H
pic

6′-282X
Pd
1
6′
Ph
H
H
EE1
H
CH₃
H
acac

6′-282Y
Pd
0
6′
Ph
H
H
EE1
H
CH₃
H
—
—

6′-283
Pd
1
6′
Ph
H
EE1
H
H
CH₃
H
pic

6′-283X
Pd
1
6′
Ph
H
EE1
H
H
CH₃
H
acac

6′-283Y
Pd
0
6′
Ph
H
EE1
H
H
CH₃
H
—
—

6′-284
Pd
1
6′
Ph
H
H
EE2
H
CH₃
H
pic

6′-284X
Pd
1
6′
Ph
H
H
EE2
H
CH₃
H
acac

6′-284Y
Pd
0
6′
Ph
H
H
EE2
H
CH₃
H
—
—

6′-285
Pd
1
6′
Ph
H
EE2
H
H
CH₃
H
pic

6′-285X
Pd
1
6′
Ph
H
EE2
H
H
CH₃
H
acac

6′-285Y
Pd
0
6′
Ph
H
EE2
H
H
CH₃
H
—
—

6′-286
Pd
1
6′
Ph
H
H
MS1
H
CH₃
H
pic

6′-286X
Pd
1
6′
Ph
H
H
MS1
H
CH₃
H
acac

6′-286Y
Pd
0
6′
Ph
H
H
MS1
H
CH₃
H
—
—

6′-287
Pd
1
6′
Ph
H
MS1
H
H
CH₃
H
pic

6′-287X
Pd
1
6′
Ph
H
MS1
H
H
CH₃
H
acac

6′-287Y
Pd
0
6′
Ph
H
MS1
H
H
CH₃
H
—
—

6′-288
Pd
1
6′
Ph
H
H
MS2
H
CH₃
H
pic

6′-288X
Pd
1
6′
Ph
H
H
MS2
H
CH₃
H
acac

6′-288Y
Pd
0
6′
Ph
H
H
MS2
H
CH₃
H
—
—

6′-289
Pd
1
6′
Ph
H
MS2
H
H
CH₃
H
pic

6′-289X
Pd
1
6′
Ph
H
MS2
H
H
CH₃
H
acac

6′-289Y
Pd
0
6′
Ph
H
MS2
H
H
CH₃
H
—
—

6′-290
Pd
1
6′
Ph
H
PME2
H
H
CH₃
H
pic

6′-290X
Pd
1
6′
Ph
H
PME2
H
H
CH₃
H
acac

6′-290Y
Pd
0
6′
Ph
H
PME2
H
H
CH₃
H
—
—

6′-291
Pd
1
6′
Ph
H
H
MET1
H
CH₃
H
pic

6′-291X
Pd
1
6′
Ph
H
H
MET1
H
CH₃
H
acac

6′-291Y
Pd
0
6′
Ph
H
H
MET1
H
CH₃
H
—
—

6′-292
Pd
1
6′
Ph
H
MET1
H
H
CH₃
H
pic

6′-292X
Pd
1
6′
Ph
H
MET1
H
H
CH₃
H
acac

6′-292Y
Pd
0
6′
Ph
H
MET1
H
H
CH₃
H
—
—

6′-293
Pd
1
6′
Ph
H
H
MET2
H
CH₃
H
pic

6′-293X
Pd
1
6′
Ph
H
H
MET2
H
CH₃
H
acac

6′-293Y
Pd
0
6′
Ph
H
H
MET2
H
CH₃
H
—
—

6′-294
Pd
1
6′
Ph
H
MET2
H
H
CH₃
H
pic

6′-294X
Pd
1
6′
Ph
H
MET2
H
H
CH₃
H
acac

6′-294Y
Pd
0
6′
Ph
H
MET2
H
H
CH₃
H
—
—

6′-295
Pd
1
6′
Ph
H
H
EE1
H
CH₃
H
pic

6′-295X
Pd
1
6′
Ph
H
H
EE1
H
CH₃
H
acac

6′-295Y
Pd
0
6′
Ph
H
H
EE1
H
CH₃
H
—
—

6′-296
Pd
1
6′
Ph
H
EE1
H
H
CH₃
H
pic

6′-296X
Pd
1
6′
Ph
H
EE1
H
H
CH₃
H
acac

6′-296Y
Pd
0
6′
Ph
H
EE1
H
H
CH₃
H
—
—

6′-297
Pd
1
6′
Ph
H
H
EE2
H
CH₃
H
pic

6′-297X
Pd
1
6′
Ph
H
H
EE2
H
CH₃
H
acac

6′-297Y
Pd
0
6′
Ph
H
H
EE2
H
CH₃
H
—
—

6′-298
Pd
1
6′
Ph
H
EE2
H
H
CH₃
H
pic

6′-298X
Pd
1
6′
Ph
H
EE2
H
H
CH₃
H
acac

6′-298Y
Pd
0
6′
Ph
H
EE2
H
H
CH₃
H
—
—

6′-299
Pd
1
6′
Ph
H
H
MS1
H
CH₃
H
pic

6′-299X
Pd
1
6′
Ph
H
H
MS1
H
CH₃
H
acac

6′-299Y
Pd
0
6′
Ph
H
H
MS1
H
CH₃
H
—
—

6′-300
Pd
1
6′
Ph
H
MS1
H
H
CH₃
H
pic

6′-300X
Pd
1
6′
Ph
H
MS1
H
H
CH₃
H
acac

6′-300Y
Pd
0
6′
Ph
H
MS1
H
H
CH₃
H
—
—

6′-301
Pd
1
6′
Ph
H
H
MS2
H
CH₃
H
pic

6′-301X
Pd
1
6′
Ph
H
H
MS2
H
CH₃
H
acac

6′-301Y
Pd
0
6′
Ph
H
H
MS2
H
CH₃
H
—
—

6′-302
Pd
1
6′
Ph
H
MS2
H
H
CH₃
H
pic

6′-302X
Pd
1
6′
Ph
H
MS2
H
H
CH₃
H
acac

6′-302Y
Pd
0
6′
Ph
H
MS2
H
H
CH₃
H
—
—

6′-303
Pd
1
6′
Ph
H
MS2
H
H
CH₃
H
pic

6′-303X
Pd
1
6′
Ph
H
MS2
H
H
CH₃
H
acac

6′-303Y
Pd
0
6′
Ph
H
MS2
H
H
CH₃
H
—
—

TABLE 49

No.
M
m
BSS
SS G
T¹
T²
T³
T⁴
T⁵
T⁶
T⁷
L¹
L²

7′-167
Pd
1
7′
Ph
H
H
H
H
CH₃
H
H
pic

7′-167X
Pd
1
7′
Ph
H
H
H
H
CH₃
H
H
acac

7′-167Y
Pd
0
7′
Ph
H
H
H
H
CH₃
H
H
—
—

7′-168
Pd
1
7′
Ph
H
H
H
H

^tC₄H₉
H
H
pic

7′-168X
Pd
1
7′
Ph
H
H
H
H

^tC₄H₉
H
H
acac

7′-168Y
Pd
0
7′
Ph
H
H
H
H

^tC₄H₉
H
H
—
—

7′-169
Pd
1
7′
Ph
H
F
H
F
CH₃
H
H
pic

7′-169X
Pd
1
7′
Ph
H
F
H
F
CH₃
H
H
acac

7′-169Y
Pd
0
7′
Ph
H
F
H
F
CH₃
H
H
—
—

7′-170
Pd
1
7′
Ph
H
F
H
F

^tC₄H₉
H
H
pic

7′-170X
Pd
1
7′
Ph
H
F
H
F

^tC₄H₉
H
H
acac

7′-170Y
Pd
0
7′
Ph
H
F
H
F

^tC₄H₉
H
H
—
—

7′-171
Pd
1
7′
Ph
F
H
H
F
CH₃
H
H
pic

7′-171X
Pd
1
7′
Ph
F
H
H
F
CH₃
H
H
acac

7′-171Y
Pd
0
7′
Ph
F
H
H
F
CH₃
H
H
—
—

7′-172
Pd
1
7′
Ph
F
H
H
F

^tC₄H₉
H
H
pic

7′-172X
Pd
1
7′
Ph
F
H
H
F

^tC₄H₉
H
H
acac

7′-172Y
Pd
0
7′
Ph
F
H
H
F

^tC₄H₉
H
H
—
—

7′-173
Pd
1
7′
Ph
CF₃
H
CF₃
H
CF₃
H
H
pic

7′-173X
Pd
1
7′
Ph
CF₃
H
CF₃
H
CF₃
H
H
acac

7′-173Y
Pd
0
7′
Ph
CF₃
H
CF₃
H
CF₃
H
H
—
—

7′-174
Pd
1
7′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
pic

7′-174X
Pd
1
7′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
acac

7′-174Y
Pd
0
7′
Ph
CF₃
H
CF₃
H

^tC₄H₉
H
H
—
—

7′-175
Pd
1
7′
Ph
H
F
CF₃
H
CH₃
H
H
pic

7′-175X
Pd
1
7′
Ph
H
F
CF₃
H
CH₃
H
H
acac

7′-175Y
Pd
0
7′
Ph
H
F
CF₃
H
CH₃
H
H
—
—

7′-176
Pd
1
7′
Ph
F
H
CF₃
H
CH₃
H
H
pic

7′-176X
Pd
1
7′
Ph
F
H
CF₃
H
CH₃
H
H
acac

7′-176Y
Pd
0
7′
Ph
F
H
CF₃
H
CH₃
H
H
—
—

7′-177
Pd
1
7′
Ph
F
F
F
F
CH₃
H
H
pic

7′-177X
Pd
1
7′
Ph
F
F
F
F
CH₃
H
H
acac

7′-177Y
Pd
0
7′
Ph
F
F
F
F
CH₃
H
H
—
—

7′-178
Pd
1
7′
Ph
H
F
H
CH₃
CH₃
H
H
pic

7′-178X
Pd
1
7′
Ph
H
F
H
CH₃
CH₃
H
H
acac

7′-178Y
Pd
0
7′
Ph
H
F
H
CH₃
CH₃
H
H
—
—

7′-179
Pd
1
7′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
pic

7′-179X
Pd
1
7′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
acac

7′-179Y
Pd
0
7′
Ph
H
F
H
CH₃

^tC₄H₉
H
H
—
—

7′-180
Pd
1
7′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
pic

7′-180X
Pd
1
7′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
acac

7′-180Y
Pd
0
7′
Ph
H
F
H

^tC₄H₉
CH₃
H
H
—
—

7′-181
Pd
1
7′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-181X
Pd
1
7′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-181Y
Pd
0
7′
Ph
H
F
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7′-182
Pd
1
7′
Ph
H
CF₃
H
CF₃
CH₃
H
H
pic

7′-182X
Pd
1
7′
Ph
H
CF₃
H
CF₃
CH₃
H
H
acac

7′-182Y
Pd
0
7′
Ph
H
CF₃
H
CF₃
CH₃
H
H
—
—

7′-183
Pd
1
7′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
pic

7′-183X
Pd
1
7′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
acac

7′-183Y
Pd
0
7′
Ph
H
CF₃
H
CF₃

^tC₄H₉
H
H
—
—

7′-184
Pd
1
7′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
pic

7′-184X
Pd
1
7′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
acac

7′-184Y
Pd
0
7′
Ph
CF₃
H
H

^tC₄H₉
CH₃
H
H
—
—

7′-185
Pd
1
7′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-185X
Pd
1
7′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-185Y
Pd
0
7′
Ph
CF₃
H
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7′-186
Pd
1
7′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
pic

7′-186X
Pd
1
7′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
acac

7′-186Y
Pd
0
7′
Ph
H
CF₃
H

^tC₄H₉
CH₃
H
H
—
—

7′-187
Pd
1
7′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-187X
Pd
1
7′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-187Y
Pd
0
7′
Ph
H
CF₃
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7′-188
Pd
1
7′
Ph
H
CF₃
H
CH₃
CH₃
H
H
pic

7′-188X
Pd
1
7′
Ph
H
CF₃
H
CH₃
CH₃
H
H
acac

7′-188Y
Pd
0
7′
Ph
H
CF₃
H
CH₃
CH₃
H
H
—
—

7′-189
Pd
1
7′
Ph
H
CF₃
CF₃
H
CH₃
H
H
pic

7′-189X
Pd
1
7′
Ph
H
CF₃
CF₃
H
CH₃
H
H
acac

7′-189Y
Pd
0
7′
Ph
H
CF₃
CF₃
H
CH₃
H
H
—
—

7′-190
Pd
1
7′
Ph
H
H
NO₂
H
CH₃
H
H
pic

7′-190X
Pd
1
7′
Ph
H
H
NO₂
H
CH₃
H
H
acac

7′-190Y
Pd
0
7′
Ph
H
H
NO₂
H
CH₃
H
H
—
—

7′-191
Pd
1
7′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
pic

7′-191X
Pd
1
7′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
acac

7′-191Y
Pd
0
7′
Ph
H
H
NO₂
H

^tC₄H₉
H
H
—
—

7′-192
Pd
1
7′
Ph
F
H
NO₂
H
CH₃
H
H
pic

7′-192X
Pd
1
7′
Ph
F
H
NO₂
H
CH₃
H
H
acac

7′-192Y
Pd
0
7′
Ph
F
H
NO₂
H
CH₃
H
H
—
—

7′-193
Pd
1
7′
Ph
F
H
NO₂
F
CH₃
H
H
pic

7′-193X
Pd
1
7′
Ph
F
H
NO₂
F
CH₃
H
H
acac

7′-193Y
Pd
0
7′
Ph
F
H
NO₂
F
CH₃
H
H
—
—

7′-194
Pd
1
7′
Ph
H
NO₂
H
NO₂
CH₃
H
H
pic

7′-194X
Pd
1
7′
Ph
H
NO₂
H
NO₂
CH₃
H
H
acac

7′-194Y
Pd
0
7′
Ph
H
NO₂
H
NO₂
CH₃
H
H
—
—

7′-195
Pd
1
7′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
pic

7′-195X
Pd
1
7′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
acac

7′-195Y
Pd
0
7′
Ph
H
NO₂
H
NO₂

^tC₄H₉
H
H
—
—

7′-196
Pd
1
7′
Ph
NO₂
H
H
NO₂
CH₃
H
H
pic

7′-196X
Pd
1
7′
Ph
NO₂
H
H
NO₂
CH₃
H
H
acac

7′-196Y
Pd
0
7′
Ph
NO₂
H
H
NO₂
CH₃
H
H
—
—

7′-197
Pd
1
7′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
pic

7′-197X
Pd
1
7′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
acac

7′-197Y
Pd
0
7′
Ph
NO₂
H
H
NO₂

^tC₄H₉
H
H
—
—

7′-198
Pd
1
7′
Ph
H
H
CF₃
H
CH₃
H
H
pic

7′-198X
Pd
1
7′
Ph
H
H
CF₃
H
CH₃
H
H
acac

7′-198Y
Pd
0
7′
Ph
H
H
CF₃
H
CH₃
H
H
—
—

7′-199
Pd
1
7′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
pic

7′-199X
Pd
1
7′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
acac

7′-199Y
Pd
0
7′
Ph
H
H
CF₃
H

^tC₄H₉
H
H
—
—

7′-200
Pd
1
7′
Ph
H
Cl
CF₃
H
CH₃
H
H
pic

7′-200X
Pd
1
7′
Ph
H
Cl
CF₃
H
CH₃
H
H
acac

7′-200Y
Pd
0
7′
Ph
H
Cl
CF₃
H
CH₃
H
H
—
—

7′-201
Pd
1
7′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
pic

7′-201X
Pd
1
7′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
acac

7′-201Y
Pd
0
7′
Ph
H
Cl
CF₃
H

^tC₄H₉
H
H
—
—

7′-201
Pd
1
7′
Ph
H
NO₂
H
H
CH₃
H
H
pic

7′-202X
Pd
1
7′
Ph
H
NO₂
H
H
CH₃
H
H
acac

7′-202Y
Pd
0
7′
Ph
H
NO₂
H
H
CH₃
H
H
—
—

7′-203
Pd
1
7′
Ph
H
CF₃
H
H
CH₃
H
H
pic

7′-203X
Pd
1
7′
Ph
H
CF₃
H
H
CH₃
H
H
acac

7′-203Y
Pd
0
7′
Ph
H
CF₃
H
H
CH₃
H
H
—
—

7′-204
Pd
1
7′
Ph
H
NO₂
H
CH₃
CH₃
H
H
pic

7′-204X
Pd
1
7′
Ph
H
NO₂
H
CH₃
CH₃
H
H
acac

7′-204Y
Pd
0
7′
Ph
H
NO₂
H
CH₃
CH₃
H
H
—
—

7′-205
Pd
1
7′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
pic

7′-205X
Pd
1
7′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
acac

7′-205Y
Pd
0
7′
Ph
H
NO₂
H
CH₃

^tC₄H₉
H
H
—
—

7′-206
Pd
1
7′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
pic

7′-206X
Pd
1
7′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
acac

7′-206Y
Pd
0
7′
Ph
H
NO₂
H

^tC₄H₉
CH₃
H
H
—
—

7′-207
Pd
1
7′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′-207X
Pd
1
7′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′-207Y
Pd
0
7′
Ph
H
NO₂
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7′-208
Pd
1
7′
Ph
H
H
CH₃O
H
CH₃
H
H
pic

7′-208X
Pd
1
7′
Ph
H
H
CH₃O
H
CH₃
H
H
acac

7′-208Y
Pd
0
7′
Ph
H
H
CH₃O
H
CH₃
H
H
—
—

7′-209
Pd
1
7′
Ph
H
CH₃O
H
H
CH₃
H
H
pic

7′-209X
Pd
1
7′
Ph
H
CH₃O
H
H
CH₃
H
H
acac

7′-209Y
Pd
0
7′
Ph
H
CH₃O
H
H
CH₃
H
H
—
—

7′-210
Pd
1
7′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
pic

7′-210X
Pd
1
7′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
acac

7′-210Y
Pd
0
7′
Ph
H
CH₃O
H
CH₃
CH₃
H
H
—
—

7′-211
Pd
1
7′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
pic

7′-211X
Pd
1
7′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
acac

7′-211Y
Pd
0
7′
Ph
H
CH₃O
H

^tC₄H₉
CH₃
H
H
—
—

7′-212
Pd
1
7′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
pic

7′-212X
Pd
1
7′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
acac

7′-212Y
Pd
0
7′
Ph
H
Si(CH₃)₃
H
H
CH₃
H
H
—
—

7′-213
Pd
1
7′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
pic

7′-213X
Pd
1
7′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
acac

7′-213Y
Pd
0
7′
Ph
H
Si(CH₃)₃
H
H

^tC₄H₉
H
H
—
—

7′-214
Pd
1
7′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
pic

7′-214X
Pd
1
7′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
acac

7′-214Y
Pd
0
7′
Ph
H
H
Si(CH₃)₃
H
CH₃
H
H
—
—

7′-215
Pd
1
7′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
pic

7′-215X
Pd
1
7′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
acac

7′-215Y
Pd
0
7′
Ph
H
H
H
Si(CH₃)₃
CH₃
H
H
—
—

7′-216
Pd
1
7′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
pic

7′-216X
Pd
1
7′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
acac

7′-216Y
Pd
0
7′
Ph
H
F
H
Si(CH₃)₃
CH₃
H
H
—
—

7′-217
Pd
1
7′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
pic

7′-217X
Pd
1
7′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
acac

7′-217Y
Pd
0
7′
Ph
H
CF₃
H
Si(CH₃)₃
CH₃
H
H
—
—

7′-218
Pd
1
7′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
pic

7′-218X
Pd
1
7′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
acac

7′-218Y
Pd
0
7′
Ph
H
CF₃
H
Si(CH₃)₃

^tC₄H₉
H
H
—
—

7′-219
Pd
1
7′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
pic

7′-219X
Pd
1
7′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
acac

7′-219Y
Pd
0
7′
Ph
H
Si(CH₃)₃
H
F
CH₃
H
H
—
—

7′-220
Pd
1
7′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
pic

7′-220X
Pd
1
7′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
acac

7′-220Y
Pd
0
7′
Ph
H
Si(CH₃)₃
H
F

^tC₄H₉
H
H
—
—

7′-221
Pd
1
7′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
pic

7′-221X
Pd
1
7′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
acac

7′-221Y
Pd
0
7′
Ph
H
Si(CH₃)₃
H
CF₃
CH₃
H
H
—
—

7′-222
Pd
1
7′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
pic

7′-222X
Pd
1
7′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
acac

7′-222Y
Pd
0
7′
Ph
H
Si(CH₃)₃
H
CF₃

^tC₄H₉
H
H
—
—

7′-223
Pd
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
pic

7′-223X
Pd
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
acac

7′-223Y
Pd
0
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H
CH₃
H
H
—
—

7′-224
Pd
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
pic

7′-224X
Pd
1
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
acac

7′-224Y
Pd
0
7′
Ph
Si(CH₃)₃
H
Si(CH₃)₃
H

^tC₄H₉
H
H
—
—

7′-225
Pd
1
7′
Ph
H
H
H
COCH₃
CH₃
H
H
pic

7′-225X
Pd
1
7′
Ph
H
H
H
COCH₃
CH₃
H
H
acac

7′-225Y
Pd
0
7′
Ph
H
H
H
COCH₃
CH₃
H
H
—
—

7′-226
Pd
1
7′
Ph
H
H
COCH₃
H
CH₃
H
H
pic

7′-226X
Pd
1
7′
Ph
H
H
COCH₃
H
CH₃
H
H
acac

7′-226Y
Pd
0
7′
Ph
H
H
COCH₃
H
CH₃
H
H
—
—

7′-227
Pd
1
7′
Ph
H
COCH₃
H
H
CH₃
H
H
pic

7′-227X
Pd
1
7′
Ph
H
COCH₃
H
H
CH₃
H
H
acac

7′-227Y
Pd
0
7′
Ph
H
COCH₃
H
H
CH₃
H
H
—
—

7′-228
Pd
1
7′
Ph
H
H
BL
CH₃
H
H
pic

7′-228X
Pd
1
7′
Ph
H
H
BL
CH₃
H
H
acac

7′-228Y
Pd
0
7′
Ph
H
H
BL
CH₃
H
H
—
—

7′-229
Pd
1
7′
Ph
H
H
BL

^tC₄H₉
H
H
pic

7′-229X
Pd
1
7′
Ph
H
H
BL

^tC₄H₉
H
H
acac

7′-229Y
Pd
0
7′
Ph
H
H
BL

^tC₄H₉
H
H
—
—

7′-230
Pd
1
7′
Ph
H
BL
H
CH₃
H
H
pic

7′-230X
Pd
1
7′
Ph
H
BL
H
CH₃
H
H
acac

7′-230Y
Pd
0
7′
Ph
H
BL
H
CH₃
H
H
—
—

7′-231
Pd
1
7′
Ph
H
BL
H
H

^tC₄H₉
H
pic

7′-231X
Pd
1
7′
Ph
H
BL
H
H

^tC₄H₉
H
acac

7′-231Y
Pd
0
7′
Ph
H
BL
H
H

^tC₄H₉
H
—
—

7′-232
Pd
1
7′
Ph
H
H
PL
CH₃
H
H
pic

7′-232X
Pd
1
7′
Ph
H
H
PL
CH₃
H
H
acac

7′-232Y
Pd
0
7′
Ph
H
H
PL
CH₃
H
H
—
—

7′-233
Pd
1
7′
Ph
H
H
PL

^tC₄H₉
H
H
pic

7′-233X
Pd
1
7′
Ph
H
H
PL

^tC₄H₉
H
H
acac

7′-233Y
Pd
0
7′
Ph
H
H
PL

^tC₄H₉
H
H
—
—

7′-234
Pd
1
7′
Ph
H
PL
H
CH₃
H
H
pic

7′-234X
Pd
1
7′
Ph
H
PL
H
CH₃
H
H
acac

7′-234Y
Pd
0
7′
Ph
H
PL
H
CH₃
H
H
—
—

7′-235
Pd
1
7′
Ph
H
PL
H
H

^tC₄H₉
H
pic

7′-235X
Pd
1
7′
Ph
H
PL
H
H

^tC₄H₉
H
acac

7′-235Y
Pd
0
7′
Ph
H
PL
H
H

^tC₄H₉
H
—
—

7′-236
Pd
1
7′
Ph
H
H
MEE1
CH₃
H
H
pic

7′-236X
Pd
1
7′
Ph
H
H
MEE1
CH₃
H
H
acac

7′-236Y
Pd
0
7′
Ph
H
H
MEE1
CH₃
H
H
—
—

7′-237
Pd
1
7′
Ph
H
MEE1
H
CH₃
H
H
pic

7′-237X
Pd
1
7′
Ph
H
MEE1
H
CH₃
H
H
acac

7′-237Y
Pd
0
7′
Ph
H
MEE1
H
CH₃
H
H
—
—

7′-238
Pd
1
7′
Ph
H
H
MEE2
CH₃
H
H
pic

7′-238X
Pd
1
7′
Ph
H
H
MEE2
CH₃
H
H
acac

7′-238Y
Pd
0
7′
Ph
H
H
MEE2
CH₃
H
H
—
—

7′-239
Pd
1
7′
Ph
H
MEE2
H
CH₃
H
H
pic

7′-239X
Pd
1
7′
Ph
H
MEE2
H
CH₃
H
H
acac

7′-239Y
Pd
0
7′
Ph
H
MEE2
H
CH₃
H
H
—
—

7′-240
Pd
1
7′
Ph
H
H
PA1
CH₃
H
H
pic

7′-240X
Pd
1
7′
Ph
H
H
PA1
CH₃
H
H
acac

7′-240Y
Pd
0
7′
Ph
H
H
PA1
CH₃
H
H
—
—

7′-241
Pd
1
7′
Ph
H
PA1
H
CH₃
H
H
pic

7′-241X
Pd
1
7′
Ph
H
PA1
H
CH₃
H
H
acac

7′-241Y
Pd
0
7′
Ph
H
PA1
H
CH₃
H
H
—
—

7′-242
Pd
1
7′
Ph
H
H
PA2
CH₃
H
H
pic

7′-242X
Pd
1
7′
Ph
H
H
PA2
CH₃
H
H
acac

7′-242Y
Pd
0
7′
Ph
H
H
PA2
CH₃
H
H
—
—

7′-243
Pd
1
7′
Ph
H
PA2
H
CH₃
H
H
pic

7′-243X
Pd
1
7′
Ph
H
PA2
H
CH₃
H
H
acac

7′-243Y
Pd
0
7′
Ph
H
PA2
H
CH₃
H
H
—
—

7′-244
Pd
1
7′
Ph
H
H
EA1
CH₃
H
H
pic

7′-244X
Pd
1
7′
Ph
H
H
EA1
CH₃
H
H
acac

7′-244Y
Pd
0
7′
Ph
H
H
EA1
CH₃
H
H
—
—

7′-245
Pd
1
7′
Ph
H
EA2
H
CH₃
H
H
pic

7′-245X
Pd
1
7′
Ph
H
EA2
H
CH₃
H
H
acac

7′-245Y
Pd
0
7′
Ph
H
EA2
H
CH₃
H
H
—
—

7′-246
Pd
1
7′
Ph
H
H
ME
CH₃
H
H
pic

7′-246X
Pd
1
7′
Ph
H
H
ME
CH₃
H
H
acac

7′-246Y
Pd
0
7′
Ph
H
H
ME
CH₃
H
H
—
—

7′-247
Pd
1
7′
Ph
H
ME
H
CH₃
H
H
pic

7′-247X
Pd
1
7′
Ph
H
ME
H
CH₃
H
H
acac

7′-247Y
Pd
0
7′
Ph
H
ME
H
CH₃
H
H
—
—

7′-248
Pd
1
7′
Ph
H
H
AT
CH₃
H
H
pic

7′-248X
Pd
1
7′
Ph
H
H
AT
CH₃
H
H
acac

7′-248Y
Pd
0
7′
Ph
H
H
AT
CH₃
H
H
—
—

7′-249
Pd
1
7′
Ph
H
AT
H
CH₃
H
H
pic

7′-249X
Pd
1
7′
Ph
H
AT
H
CH₃
H
H
acac

7′-249Y
Pd
0
7′
Ph
H
AT
H
CH₃
H
H
—
—

7′-250
Pd
1
7′
Ph
H
H
MES1
CH₃
H
H
pic

7′-250X
Pd
1
7′
Ph
H
H
MES1
CH₃
H
H
acac

7′-250Y
Pd
0
7′
Ph
H
H
MES1
CH₃
H
H
—
—

7′-251
Pd
1
7′
Ph
H
MES1
H
CH₃
H
H
pic

7′-251X
Pd
1
7′
Ph
H
MES1
H
CH₃
H
H
acac

7′-251Y
Pd
0
7′
Ph
H
MES1
H
CH₃
H
H
—
—

7′-252
Pd
1
7′
Ph
H
H
MES2
CH₃
H
H
pic

7′-252X
Pd
1
7′
Ph
H
H
MES2
CH₃
H
H
acac

7′-252Y
Pd
0
7′
Ph
H
H
MES2
CH₃
H
H
—
—

7′-253
Pd
1
7′
Ph
H
MES2
H
CH₃
H
H
pic

7′-253X
Pd
1
7′
Ph
H
MES2
H
CH₃
H
H
acac

7′-253Y
Pd
0
7′
Ph
H
MES2
H
CH₃
H
H
—
—

7′-254
Pd
1
7′
Ph
H
H
PS1
CH₃
H
H
pic

7′-254X
Pd
1
7′
Ph
H
H
PS1
CH₃
H
H
acac

7′-254Y
Pd
0
7′
Ph
H
H
PS1
CH₃
H
H
—
—

7′-255
Pd
1
7′
Ph
H
PS1
H
CH₃
H
H
pic

7′-255X
Pd
1
7′
Ph
H
PS1
H
CH₃
H
H
acac

7′-255Y
Pd
0
7′
Ph
H
PS1
H
CH₃
H
H
—
—

7′-256
Pd
1
7′
Ph
H
H
PS2
CH₃
H
H
pic

7′-256X
Pd
1
7′
Ph
H
H
PS2
CH₃
H
H
acac

7′-256Y
Pd
0
7′
Ph
H
H
PS2
CH₃
H
H
—
—

7′-257
Pd
1
7′
Ph
H
PS2
H
CH₃
H
H
pic

7′-257X
Pd
1
7′
Ph
H
PS2
H
CH₃
H
H
acac

7′-257Y
Pd
0
7′
Ph
H
PS2
H
CH₃
H
H
—
—

7′-258
Pd
1
7′
Ph
H
H
BAL1
CH₃
H
H
pic

7′-258X
Pd
1
7′
Ph
H
H
BAL1
CH₃
H
H
acac

7′-258Y
Pd
0
7′
Ph
H
H
BAL1
CH₃
H
H
—
—

7′-259
Pd
1
7′
Ph
H
BAL1
H
CH₃
H
H
pic

7′-259X
Pd
1
7′
Ph
H
BAL1
H
CH₃
H
H
acac

7′-259Y
Pd
0
7′
Ph
H
BAL1
H
CH₃
H
H
—
—

7′-260
Pd
1
7′
Ph
H
H
BAL2
CH₃
H
H
pic

7′-260X
Pd
1
7′
Ph
H
H
BAL2
CH₃
H
H
acac

7′-260Y
Pd
0
7′
Ph
H
H
BAL2
CH₃
H
H
—
—

7′-261
Pd
1
7′
Ph
H
BAL2
H
CH₃
H
H
pic

7′-261X
Pd
1
7′
Ph
H
BAL2
H
CH₃
H
H
acac

7′-261Y
Pd
0
7′
Ph
H
BAL2
H
CH₃
H
H
—
—

7′-262
Pd
1
7′
Ph
H
H
MEK1
CH₃
H
H
pic

7′-262X
Pd
1
7′
Ph
H
H
MEK1
CH₃
H
H
acac

7′-262Y
Pd
0
7′
Ph
H
H
MEK1
CH₃
H
H
—
—

7′-263
Pd
1
7′
Ph
H
MEK1
H
CH₃
H
H
pic

7′-263X
Pd
1
7′
Ph
H
MEK1
H
CH₃
H
H
acac

7′-263Y
Pd
0
7′
Ph
H
MEK1
H
CH₃
H
H
—
—

7′-264
Pd
1
7′
Ph
H
H
MEK2
CH₃
H
H
pic

7′-264X
Pd
1
7′
Ph
H
H
MEK2
CH₃
H
H
acac

7′-264Y
Pd
0
7′
Ph
H
H
MEK2
CH₃
H
H
—
—

7′-265
Pd
1
7′
Ph
H
MEK2
H
CH₃
H
H
pic

7′-265X
Pd
1
7′
Ph
H
MEK2
H
CH₃
H
H
acac

7′-265Y
Pd
0
7′
Ph
H
MEK2
H
CH₃
H
H
—
—

7′-266
Pd
1
7′
Ph
H
H
PAL1
CH₃
H
H
pic

7′-266X
Pd
1
7′
Ph
H
H
PAL1
CH₃
H
H
acac

7′-266Y
Pd
0
7′
Ph
H
H
PAL1
CH₃
H
H
—
—

7′-267
Pd
1
7′
Ph
H
PAL1
H
CH₃
H
H
pic

7′-267X
Pd
1
7′
Ph
H
PAL1
H
CH₃
H
H
acac

7′-267Y
Pd
0
7′
Ph
H
PAL1
H
CH₃
H
H
—
—

7′-268
Pd
1
7′
Ph
H
H
PAL2
CH₃
H
H
pic

7′-268X
Pd
1
7′
Ph
H
H
PAL2
CH₃
H
H
acac

7′-268Y
Pd
0
7′
Ph
H
H
PAL2
CH₃
H
H
—
—

7′-269
Pd
1
7′
Ph
H
PAL2
H
CH₃
H
H
pic

7′-269X
Pd
1
7′
Ph
H
PAL2
H
CH₃
H
H
acac

7′-269Y
Pd
0
7′
Ph
H
PAL2
H
CH₃
H
H
—
—

7′-270
Pd
1
7′
Ph
H
H
MMK
CH₃
H
H
pic

7′-270X
Pd
1
7′
Ph
H
H
MMK
CH₃
H
H
acac

7′-270Y
Pd
0
7′
Ph
H
H
MMK
CH₃
H
H
—
—

7′-271
Pd
1
7′
Ph
H
MMK
H
CH₃
H
H
pic

7′-271X
Pd
1
7′
Ph
H
MMK
H
CH₃
H
H
acac

7′-271Y
Pd
0
7′
Ph
H
MMK
H
CH₃
H
H
—
—

7′-272
Pd
1
7′
Ph
H
H
EES1
CH₃
H
H
pic

7′-272X
Pd
1
7′
Ph
H
H
EES1
CH₃
H
H
acac

7′-272Y
Pd
0
7′
Ph
H
H
EES1
CH₃
H
H
—
—

7′-273
Pd
1
7′
Ph
H
EES2
H
CH₃
H
H
pic

7′-273X
Pd
1
7′
Ph
H
EES2
H
CH₃
H
H
acac

7′-273Y
Pd
0
7′
Ph
H
EES2
H
CH₃
H
H
—
—

7′-274
Pd
1
7′
Ph
H
H
PAE1
CH₃
H
H
pic

7′-274X
Pd
1
7′
Ph
H
H
PAE1
CH₃
H
H
acac

7′-274Y
Pd
0
7′
Ph
H
H
PAE1
CH₃
H
H
—
—

7′-275
Pd
1
7′
Ph
H
PAE2
H
CH₃
H
H
pic

7′-275X
Pd
1
7′
Ph
H
PAE2
H
CH₃
H
H
acac

7′-275Y
Pd
0
7′
Ph
H
PAE2
H
CH₃
H
H
—
—

7′-276
Pd
1
7′
Ph
H
H
AME1
CH₃
H
H
pic

7′-276X
Pd
1
7′
Ph
H
H
AME1
CH₃
H
H
acac

7′-276Y
Pd
0
7′
Ph
H
H
AME1
CH₃
H
H
—
—

7′-277
Pd
1
7′
Ph
H
AME1
H
CH₃
H
H
pic

7′-277X
Pd
1
7′
Ph
H
AME1
H
CH₃
H
H
acac

7′-277Y
Pd
0
7′
Ph
H
AME1
H
CH₃
H
H
—
—

7′-278
Pd
1
7′
Ph
H
H
AME2
CH₃
H
H
pic

7′-278X
Pd
1
7′
Ph
H
H
AME2
CH₃
H
H
acac

7′-278Y
Pd
0
7′
Ph
H
H
AME2
CH₃
H
H
—
—

7′-279
Pd
1
7′
Ph
H
AME2
H
CH₃
H
H
pic

7′-279X
Pd
1
7′
Ph
H
AME2
H
CH₃
H
H
acac

7′-279Y
Pd
0
7′
Ph
H
AME2
H
CH₃
H
H
—
—

7′-280
Pd
1
7′
Ph
H
H
EAE1
CH₃
H
H
pic

7′-280X
Pd
1
7′
Ph
H
H
EAE1
CH₃
H
H
acac

7′-280Y
Pd
0
7′
Ph
H
H
EAE1
CH₃
H
H
—
—

7′-281
Pd
1
7′
Ph
H
EAE1
H
CH₃
H
H
pic

7′-281X
Pd
1
7′
Ph
H
EAE1
H
CH₃
H
H
acac

7′-281Y
Pd
0
7′
Ph
H
EAE1
H
CH₃
H
H
—
—

7′-282
Pd
1
7′
Ph
H
H
EAE2
CH₃
H
H
pic

7′-282X
Pd
1
7′
Ph
H
H
EAE2
CH₃
H
H
acac

7′-282Y
Pd
0
7′
Ph
H
H
EAE2
CH₃
H
H
—
—

7′-283
Pd
1
7′
Ph
H
EAE2
H
CH₃
H
H
pic

7′-283X
Pd
1
7′
Ph
H
EAE2
H
CH₃
H
H
acac

7′-283Y
Pd
0
7′
Ph
H
EAE2
H
CH₃
H
H
—
—

7′-284
Pd
1
7′
Ph
H
H
AAE1
CH₃
H
H
pic

7′-284X
Pd
1
7′
Ph
H
H
AAE1
CH₃
H
H
acac

7′-284Y
Pd
0
7′
Ph
H
H
AAE1
CH₃
H
H
—
—

7′-285
Pd
1
7′
Ph
H
AAE1
H
CH₃
H
H
pic

7′-285X
Pd
1
7′
Ph
H
AAE1
H
CH₃
H
H
acac

7′-285Y
Pd
0
7′
Ph
H
AAE1
H
CH₃
H
H
—
—

7′-286
Pd
1
7′
Ph
H
H
AAE2
CH₃
H
H
pic

7′-286X
Pd
1
7′
Ph
H
H
AAE2
CH₃
H
H
acac

7′-286Y
Pd
0
7′
Ph
H
H
AAE2
CH₃
H
H
—
—

7′-287
Pd
1
7′
Ph
H
AAE2
H
CH₃
H
H
pic

7′-287X
Pd
1
7′
Ph
H
AAE2
H
CH₃
H
H
acac

7′-287Y
Pd
0
7′
Ph
H
AAE2
H
CH₃
H
H
—
—

7′-288
Pd
1
7′
Ph
H
H
PME1
CH₃
H
H
pic

7′-288X
Pd
1
7′
Ph
H
H
PME1
CH₃
H
H
acac

7′-288Y
Pd
0
7′
Ph
H
H
PME1
CH₃
H
H
—
—

7′-289
Pd
1
7′
Ph
H
PME1
H
CH₃
H
H
pic

7′-289X
Pd
1
7′
Ph
H
PME1
H
CH₃
H
H
acac

7′-289Y
Pd
0
7′
Ph
H
PME1
H
CH₃
H
H
—
—

7′-290
Pd
1
7′
Ph
H
H
PME2
CH₃
H
H
pic

7′-290X
Pd
1
7′
Ph
H
H
PME2
CH₃
H
H
acac

7′-290Y
Pd
0
7′
Ph
H
H
PME2
CH₃
H
H
—
—

7′-291
Pd
1
7′
Ph
H
PME2
H
CH₃
H
H
pic

7′-291X
Pd
1
7′
Ph
H
PME2
H
CH₃
H
H
acac

7′-291Y
Pd
0
7′
Ph
H
PME2
H
CH₃
H
H
—
—

7′-292
Pd
1
7′
Ph
H
H
MET1
CH₃
H
H
pic

7′-292X
Pd
1
7′
Ph
H
H
MET1
CH₃
H
H
acac

7′-292Y
Pd
0
7′
Ph
H
H
MET1
CH₃
H
H
—
—

7′-293
Pd
1
7′
Ph
H
MET1
H
CH₃
H
H
pic

7′-293X
Pd
1
7′
Ph
H
MET1
H
CH₃
H
H
acac

7′-293Y
Pd
0
7′
Ph
H
MET1
H
CH₃
H
H
—
—

7′-294
Pd
1
7′
Ph
H
H
MET2
CH₃
H
H
pic

7′-294X
Pd
1
7′
Ph
H
H
MET2
CH₃
H
H
acac

7′-294Y
Pd
0
7′
Ph
H
H
MET2
CH₃
H
H
—
—

7′-295
Pd
1
7′
Ph
H
MET2
H
CH₃
H
H
pic

7′-295X
Pd
1
7′
Ph
H
MET2
H
CH₃
H
H
acac

7′-295Y
Pd
0
7′
Ph
H
MET2
H
CH₃
H
H
—
—

7′-296
Pd
1
7′
Ph
H
H
EE1
CH₃
H
H
pic

7′-296X
Pd
1
7′
Ph
H
H
EE1
CH₃
H
H
acac

7′-296Y
Pd
0
7′
Ph
H
H
EE1
CH₃
H
H
—
—

7′-297
Pd
1
7′
Ph
H
EE1
H
CH₃
H
H
pic

7′-297X
Pd
1
7′
Ph
H
EE1
H
CH₃
H
H
acac

7′-297Y
Pd
0
7′
Ph
H
EE1
H
CH₃
H
H
—
—

7′-298
Pd
1
7′
Ph
H
H
EE2
CH₃
H
H
pic

7′-298X
Pd
1
7′
Ph
H
H
EE2
CH₃
H
H
acac

7′-298Y
Pd
0
7′
Ph
H
H
EE2
CH₃
H
H
—
—

7′-299
Pd
1
7′
Ph
H
EE2
H
CH₃
H
H
pic

7′-299X
Pd
1
7′
Ph
H
EE2
H
CH₃
H
H
acac

7′-299Y
Pd
0
7′
Ph
H
EE2
H
CH₃
H
H
—
—

7′-300
Pd
1
7′
Ph
H
H
MS1
CH₃
H
H
pic

7′-300X
Pd
1
7′
Ph
H
H
MS1
CH₃
H
H
acac

7′-300Y
Pd
0
7′
Ph
H
H
MS1
CH₃
H
H
—
—

7′-301
Pd
1
7′
Ph
H
MS1
H
CH₃
H
H
pic

7′-301X
Pd
1
7′
Ph
H
MS1
H
CH₃
H
H
acac

7′-301Y
Pd
0
7′
Ph
H
MS1
H
CH₃
H
H
—
—

7′-302
Pd
1
7′
Ph
H
H
MS2
CH₃
H
H
pic

7′-302X
Pd
1
7′
Ph
H
H
MS2
CH₃
H
H
acac

7′-302Y
Pd
0
7′
Ph
H
H
MS2
CH₃
H
H
—
—

7′-303
Pd
1
7′
Ph
H
MS2
H
CH₃
H
H
pic

7′-303X
Pd
1
7′
Ph
H
MS2
H
CH₃
H
H
acac

7′-303Y
Pd
0
7′
Ph
H
MS2
H
CH₃
H
H
—
—

embedded image

TABLE 50

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

1′ -305
Pd
1
1′
Nap1
—
—
H
H
H
H
H
pic

1′ -305X
Pd
1
1′
Nap1
—
—
H
H
H
H
H
acac

1′ -305Y
Pd
0
1′
Nap1
—
—
H
H
H
H
H
—
—

1′ -306
Pd
1
1′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

1′ -306X
Pd
1
1′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

1′ -306Y
Pd
0
1′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -307
Pd
1
1′
Nap1
—
—
CH₃
H
H
H
H
pic

1′ -307X
Pd
1
1′
Nap1
—
—
CH₃
H
H
H
H
acac

1′ -307Y
Pd
0
1′
Nap1
—
—
CH₃
H
H
H
H
—
—

1′ -308
Pd
1
1′
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -308X
Pd
1
1′
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -308Y
Pd
0
1′
Nap1
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -309
Pd
1
1′
Nap1
—
—
CH₃
CH₃
H
H
H
pic

1′ -309X
Pd
1
1′
Napl
—
—
CH₃
CH₃
H
H
H
acac

1′ -309Y
Pd
0
1′
Nap1
—
—
CH₃
CH₃
H
H
H
—
—

1′ -310
Pd
1
1′
Nap1
—
—
H
CH₃
H
H
H
pic

1′ -310X
Pd
1
1′
Nap1
—
—
H
CH₃
H
H
H
acac

1′ -310Y
Pd
0
1′
Nap1
—
—
H
CH₃
H
H
H
—
—

1′ -311
Pd
1
1′
Nap2
—
—
H
H
H
H
H
pic

1′ -311X
Pd
1
1′
Nap2
—
—
H
H
H
H
H
acac

1′ -311Y
Pd
0
1′
Nap2
—
—
H
H
H
H
H
—
—

1′ -312
Pd
1
1′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

1′ -312X
Pd
1
1′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

1′ -312Y
Pd
0
1′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -313
Pd
1
1′
Nap2
—
—
CH₃
H
H
H
H
pic

1′ -313X
Pd
1
1′
Nap2
—
—
CH₃
H
H
H
H
acac

1′ -313Y
Pd
0
1′
Nap2
—
—
CH₃
H
H
H
H
—
—

1′ -314
Pd
1
1′
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -314X
Pd
1
1′
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -314Y
Pd
0
1′
Nap2
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -315
Pd
1
1′
Nap2
—
—
CH₃
CH₃
H
H
H
pic

1′ -315X
Pd
1
1′
Nap2
—
—
CH₃
CH₃
H
H
H
acac

1′ -315Y
Pd
0
1′
Nap2
—
—
CH₃
CH₃
H
H
H
—
—

1′ -316
Pd
1
1′
Nap2
—
—
H
CH₃
H
H
H
pic

1′ -316X
Pd
1
1′
Nap2
—
—
H
CH₃
H
H
H
acac

1′ -316Y
Pd
0
1′
Nap2
—
—
H
CH₃
H
H
H
—
—

1′ -317
Pd
1
1′
Nap3
—
—
H
H
H
H
H
pic

1′ -317X
Pd
1
1′
Nap3
—
—
H
H
H
H
H
acac

1′ -317Y
Pd
0
1′
Nap3
—
—
H
H
H
H
H
—
—

1′ -318
Pd
1
1′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

1′ -318X
Pd
1
1′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

1′ -318Y
Pd
0
1′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -319
Pd
1
1′
Nap3
—
—
CH₃
H
H
H
H
pic

1′ -319X
Pd
1
1′
Nap3
—
—
CH₃
H
H
H
H
acac

1′ -319Y
Pd
0
1′
Nap3
—
—
CH₃
H
H
H
H
—
—

1′ -320
Pd
1
′1
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -320X
Pd
1
1′
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -320Y
Pd
0
1′
Nap3
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -321
Pd
1
1′
Nap3
—
—
CH₃
CH₃
H
H
H
pic

1′ -321X
Pd
1
1′
Nap3
—
—
CH₃
CH₃
H
H
H
acac

1′ -321Y
Pd
0
1′
Nap3
—
—
CH₃
CH₃
H
H
H
—
—

1′ -322
Pd
1
1′
Nap3
—
—
H
CH₃
H
H
H
pic

1′ -322X
Pd
1
1′
Nap3
—
—
H
CH₃
H
H
H
acac

1′ -322Y
Pd
0
1′
Nap3
—
—
H
CH₃
H
H
H
—
—

1′ -323
Pd
1
1′
TB
—
—
H
H
H
H
H
pic

1′ -323X
Pd
1
1′
TB
—
—
H
H
H
H
H
acac

1′ -323Y
Pd
0
1′
TB
—
—
H
H
H
H
H
—
—

1′ -324
Pd
1
1′
TB
—
—

^tC₄H₉
H
H
H
H
pic

1′ -324X
Pd
1
1′
TB
—
—

^tC₄H₉
H
H
H
H
acac

1′ -324Y
Pd
0
1′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -325
Pd
1
1′
TB
—
—
CH₃
H
H
H
H
pic

1′ -325X
Pd
1
1′
TB
—
—
CH₃
H
H
H
H
acac

1′ -325Y
Pd
0
1′
TB
—
—
CH₃
H
H
H
H
—
—

1′ -326
Pd
1
1′
TB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -326X
Pd
1
1′
TB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -326Y
Pd
0
1′
TB
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -327
Pd
1
1′
TB
—
—
CH₃
CH₃
H
H
H
pic

1′ -327X
Pd
1
1′
TB
—
—
CH₃
CH₃
H
H
H
acac

1′ -327Y
Pd
1
1′
TB
—
—
CH₃
CH₃
H
H
H
—
—

1′ -328
Pd
1
1′
TB
—
—
H
CH₃
H
H
H
pic

1′ -328X
Pd
1
1′
TB
—
—
H
CH₃
H
H
H
acac

1′ -328Y
Pd
0
1′
TB
—
—
H
CH₃
H
H
H
—
—

1′ -329
Pd
1
1′
TF
—
—
H
H
H
H
H
pic

1′ -329X
Pd
1
1′
TF
—
—
H
H
H
H
H
acac

1′ -329Y
Pd
0
1′
TF
—
—
H
H
H
H
H
—
—

1′ -330
Pd
1
1′
TF
—
—

^tC₄H₉
H
H
H
H
pic

1′ -330X
Pd
1
1′
TF
—
—

^tC₄H₉
H
H
H
H
acac

1′ -330Y
Pd
0
1′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -331
Pd
1
1′
TF
—
—
CH₃
H
H
H
H
pic

1′ -331X
Pd
1
1′
TF
—
—
CH₃
H
H
H
H
acac

1′ -331Y
Pd
0
1′
TF
—
—
CH₃
H
H
H
H
—
—

1′ -332
Pd
1
1′
TF
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -332X
Pd
1
1′
TF
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -332Y
Pd
0
1′
TF
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -333
Pd
1
1′
TF
—
—
CH₃
CH₃
H
H
H
pic

1′ -333X
Pd
1
1′
TF
—
—
CH₃
CH₃
H
H
H
acac

1′ -333Y
Pd
0
1′
TF
—
—
CH₃
CH₃
H
H
H
—
—

1′ -334
Pd
1
1′
TF
—
—
H
CH₃
H
H
H
pic

1′ -334X
Pd
1
1′
TF
—
—
H
CH₃
H
H
H
acac

1′ -334Y
Pd
0
1′
TF
—
—
H
CH₃
H
H
H
—
—

1′ -335
Pd
1
1′
OB
—
—
H
H
H
H
H
pic

1′ -335X
Pd
1
1′
OB
—
—
H
H
H
H
H
acac

1′ -335Y
Pd
0
1′
OB
—
—
H
H
H
H
H
—
—

1′ -336
Pd
1
1′
OB
—
—

^tC₄H₉
H
H
H
H
pic

1′ -336X
Pd
1
1′
OB
—
—

^tC₄H₉
H
H
H
H
acac

1′ -336Y
Pd
0
1′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -337
Pd
1
1′
OB
—
—
CH₃
H
H
H
H
pic

1′ -337X
Pd
1
1′
OB
—
—
CH₃
H
H
H
H
acac

1′ -337Y
Pd
0
1′
OB
—
—
CH₃
H
H
H
H
—
—

1′ -338
Pd
1
1′
OB
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -338X
Pd
1
1′
OB
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -338Y
Pd
0
1′
OB
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -339
Pd
1
1′
OB
—
—
CH₃
CH₃
H
H
H
pic

1′ -339X
Pd
1
1′
OB
—
—
CH₃
CH₃
H
H
H
acac

1′ -339Y
Pd
0
1′
OB
—
—
CH₃
CH₃
H
H
H
—
—

1′ -340
Pd
1
1′
OB
—
—
H
CH₃
H
H
H
pic

1′ -340X
Pd
1
1′
OB
—
—
H
CH₃
H
H
H
acac

1′ -340Y
Pd
0
1′
OB
—
—
H
CH₃
H
H
H
—
—

1′ -341
Pd
1
1′
Fu
—
—
H
H
H
H
H
pic

1′ -341X
Pd
1
1′
Fu
—
—
H
H
H
H
H
acac

1′ -341Y
Pd
0
1′
Fu
—
—
H
H
H
H
H
—
—

1′ -342
Pd
1
1′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

1′ -342X
Pd
1
1′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

1′ -342Y
Pd
0
1′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -343
Pd
1
1′
Fu
—
—
CH₃
H
H
H
H
pic

1′ -343X
Pd
1
1′
Fu
—
—
CH₃
H
H
H
H
acac

1′ -343Y
Pd
0
1′
Fu
—
—
CH₃
H
H
H
H
—
—

1′ -344
Pd
1
1′
Fu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -344X
Pd
1
1′
Fu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -344Y
Pd
0
1′
Fu
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -345
Pd
1
1′
Fu
—
—
CH₃
CH₃
H
H
H
pic

1′ -345X
Pd
1
1′
Fu
—
—
CH₃
CH₃
H
H
H
acac

1′ -345Y
Pd
0
1′
Fu
—
—
CH₃
CH₃
H
H
H
—
—

1′ -346
Pd
1
1′
Fu
—
—
H
CH₃
H
H
H
pic

1′ -346X
Pd
1
1′
Fu
—
—
H
CH₃
H
H
H
acac

1′ -346Y
Pd
0
1′
Fu
—
—
H
CH₃
H
H
H
—
—

1′ -347
Pd
1
1′
Fl
—
—
H
H
H
H
H
pic

1′ -347X
Pd
1
1′
Fl
—
—
H
H
H
H
H
acac

1′ -347Y
Pd
0
1′
Fl
—
—
H
H
H
H
H
—
—

1′ -348
Pd
1
1′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

1′ -348X
Pd
1
1′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

1′ -348Y
Pd
0
1′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -349
Pd
1
1′
Fl
—
—
CH₃
H
H
H
H
pic

1′ -349X
Pd
1
1′
Fl
—
—
CH₃
H
H
H
H
acac

1′ -349Y
Pd
0
1′
Fl
—
—
CH₃
H
H
H
H
—
—

1′ -350
Pd
1
1′
Fl
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -350X
Pd
1
1′
Fl
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -350Y
Pd
0
1′
Fl
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -351
Pd
1
1′
Fl
—
—
CH₃
CH₃
H
H
H
pic

1′ -351X
Pd
1
1′
Fl
—
—
CH₃
CH₃
H
H
H
acac

1′ -351Y
Pd
1′
1′
Fl
—
—
CH₃
CH₃
H
H
H
—
—

1′ -352
Pd
1
1′
Fl
—
—
H
CH₃
H
H
H
pic

1′ -352X
Pd
1
1′
Fl
—
—
H
CH₃
H
H
H
acac

1′ -352Y
Pd
0
1′
Fl
—
—
H
CH₃
H
H
H
—
—

1′ -353
Pd
1
1′
Bz
—
—
H
H
H
H
H
pic

1′ -353X
Pd
1
1′
Bz
—
—
H
H
H
H
H
acac

1′ -353Y
Pd
0
1′
Bz
—
—
H
H
H
H
H
—
—

1′ -354
Pd
1
1′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

1′ -354X
Pd
1
1′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

1′ -354Y
Pd
0
1′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -355
Pd
1
1′
Bz
—
—
CH₃
H
H
H
H
pic

1′ -355X
Pd
1
1′
Bz
—
—
CH₃
H
H
H
H
acac

1′ -355Y
Pd
0
1′
Bz
—
—
CH₃
H
H
H
H
—
—

1′ -356
Pd
1
1′
Bz
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -356X
Pd
1
1′
Bz
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -356Y
Pd
0
1′
Bz
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -357
Pd
1
1′
Bz
—
—
CH₃
CH₃
H
H
H
pic

1′ -357X
Pd
1
1′
Bz
—
—
CH₃
CH₃
H
H
H
acac

1′ -357Y
Pd
0
1′
Bz
—
—
CH₃
CH₃
H
H
H
—
—

1′ -358
Pd
1
1′
Bz
—
—
H
CH₃
H
H
H
pic

1′ -358X
Pd
1
1′
Bz
—
—
H
CH₃
H
H
H
acac

1′ -358Y
Pd
0
1′
Bz
—
—
H
CH₃
H
H
H
—
—

1′ -359
Pd
1
1′
Qu
—
—
H
H
H
H
H
pic

1′ -359X
Pd
1
1′
Qu
—
—
H
H
H
H
H
acac

1′ -359Y
Pd
0
1′
Qu
—
—
H
H
H
H
H
—
—

1′ -360
Pd
1
1′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

1′ -360X
Pd
1
1′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

1′ -360Y
Pd
0
1′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

1′ -361
Pd
1
1′
Qu
—
—
CH₃
H
H
H
H
pic

1′ -361X
Pd
1
1′
Qu
—
—
CH₃
H
H
H
H
acac

1′ -361Y
Pd
0
1′
Qu
—
—
CH₃
H
H
H
H
—
—

1′ -362
Pd
1
1′
Qu
—
—

^tC₄H₉
CH₃
H
H
H
pic

1′ -362X
Pd
1
1′
Qu
—
—

^tC₄H₉
CH₃
H
H
H
acac

1′ -362Y
Pd
0
1′
Qu
—
—

^tC₄H₉
CH₃
H
H
H
—
—

1′ -363
Pd
1
1′
Qu
—
—
CH₃
CH₃
H
H
H
pic

1′ -363X
Pd
1
1′
Qu
—
—
CH₃
CH₃
H
H
H
acac

1′ -363Y
Pd
0
1′
Qu
—
—
CH₃
CH₃
H
H
H
—
—

1′ -364
Pd
1
1′
Qu
—
—
H
CH₃
H
H
H
pic

1′ -364X
Pd
1
1′
Qu
—
—
H
CH₃
H
H
H
acac

1′ -364Y
Pd
0
1′
Qu
—
—
H
CH₃
H
H
H
—
—

1′ -365
Pd
1
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

1′ -365X
Pd
1
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

1′ -365Y
Pd
0
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

1′ -366
Pd
1
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

1′ -366X
Pd
1
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

1′ -366Y
Pd
0
1′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

1′ -367
Pd
1
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

1′ -367X
Pd
1
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

1′ -367Y
Pd
0
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

1′ -368
Pd
1
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

1′ -368X
Pd
1
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

1′ -368Y
Pd
0
1′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

1′ -369
Pd
1
1′
OL
H
H
H
H
H
H
H
pic

1′ -369X
Pd
1
1′
OL
H
H
H
H
H
H
H
acac

1′ -369Y
Pd
0
1′
OL
H
H
H
H
H
H
H
—
—

1′ -370
Pd
1
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

1′ -370X
Pd
1
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

1′ -370Y
Pd
0
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

1′ -371
Pd
1
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

1′ -371X
Pd
1
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

1′ -371Y
Pd
0
1′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

1′ -372
Pd
1
1′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

1′ -372X
Pd
1
1′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

1′ -372Y
Pd
0
1′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 51

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

2′ -305
Pd
1
2′
Nap1
—
—
H
H
H
H
H
pic

2′ -305X
Pd
1
2′
Nap1
—
—
H
H
H
H
H
acac

2′ -305Y
Pd
0
2′
Nap1
—
—
H
H
H
H
H
—
—

2′ -306
Pd
1
2′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

2′ -306X
Pd
1
2′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

2′ -306Y
Pd
0
2′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -307
Pd
1
2′
Nap1
—
—
CH₃
H
H
H
H
pic

2′ -307X
Pd
1
2′
Nap1
—
—
CH₃
H
H
H
H
acac

2′ -307Y
Pd
0
2′
Nap1
—
—
CH₃
H
H
H
H
—
—

2′ -308
Pd
1
2′
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -308X
Pd
1
2′
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -308Y
Pd
0
2′
Nap1
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -309
Pd
1
2′
Nap1
—
—
CH₃
H
H
CH₃
H
pic

2′ -309X
Pd
1
2′
Nap1
—
—
CH₃
H
H
CH₃
H
acac

2′ -309Y
Pd
0
2′
Nap1
—
—
CH₃
H
H
CH₃
H
—
—

2′ -310
Pd
1
2′
Nap1
—
—
H
H
H
CH₃
H
pic

2′ -310X
Pd
1
2′
Nap1
—
—
H
H
H
CH₃
H
acac

2′ -310Y
Pd
0
2′
Nap1
—
—
H
H
H
CH₃
H
—
—

2′ -311
Pd
1
2′
Nap2
—
—
H
H
H
H
H
pic

2′ -311X
Pd
1
2′
Nap2
—
—
H
H
H
H
H
acac

2′ -311Y
Pd
0
2′
Nap2
—
—
H
H
H
H
H
—
—

2′ -312
Pd
1
2′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

2′ -312X
Pd
1
2′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

2′ -312Y
Pd
0
2′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -313
Pd
1
2′
Nap2
—
—
CH₃
H
H
H
H
pic

2′ -313X
Pd
1
2′
Nap2
—
—
CH₃
H
H
H
H
acac

2′ -313Y
Pd
0
2′
Nap2
—
—
CH₃
H
H
H
H
—
—

2′ -314
Pd
1
2′
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -314X
Pd
1
2′
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -314Y
Pd
0
2′
Nap2
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -315
Pd
1
2′
Nap2
—
—
CH₃
H
H
CH₃
H
pic

2′ -315X
Pd
1
2′
Nap2
—
—
CH₃
H
H
CH₃
H
acac

2′ -315Y
Pd
0
2′
Nap2
—
—
CH₃
H
H
CH₃
H
—
—

2′ -316
Pd
1
2′
Nap2
—
—
H
H
H
CH₃
H
pic

2′ -316X
Pd
1
2′
Nap2
—
—
H
H
H
CH₃
H
acac

2′ -316Y
Pd
0
2′
Nap2
—
—
H
H
H
CH₃
H
—
—

2′ -317
Pd
1
2′
Nap3
—
—
H
H
H
H
H
pic

2′ -317X
Pd
1
2′
Nap3
—
—
H
H
H
H
H
acac

2′ -317Y
Pd
0
2′
Nap3
—
—
H
H
H
H
H
—
—

2′ -318
Pd
1
2′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

2′ -318X
Pd
1
2′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

2′ -318Y
Pd
0
2′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -319
Pd
1
2′
Nap3
—
—
CH₃
H
H
H
H
pic

2′ -319X
Pd
1
2′
Nap3
—
—
CH₃
H
H
H
H
acac

2′ -319Y
Pd
0
2′
Nap3
—
—
CH₃
H
H
H
H
—
—

2′ -320
Pd
1
2′
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -320X
Pd
1
2′
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -320Y
Pd
0
2′
Nap3
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -321
Pd
1
2′
Nap3
—
—
CH₃
H
H
CH₃
H
pic

2′ -321X
Pd
1
2′
Nap3
—
—
CH₃
H
H
CH₃
H
acac

2′ -321Y
Pd
0
2′
Nap3
—
—
CH₃
H
H
CH₃
H
—
—

2′ -322
Pd
1
2′
Nap3
—
—
H
H
H
CH₃
H
pic

2′ -322X
Pd
1
2′
Nap3
—
—
H
H
H
CH₃
H
acac

2′ -322Y
Pd
0
2′
Nap3
—
—
H
H
H
H
H
—
—

2′ -323
Pd
1
2′
TB
—
—
H
H
H
H
H
pic

2′ -323X
Pd
1
2′
TB
—
—
H
H
H
H
H
acac

2′ -323Y
Pd
0
2′
TB
—
—
H
H
H
H
H
—
—

2′ -324
Pd
1
2′
TB
—
—

^tC₄H₉
H
H
H
H
pic

2′ -324X
Pd
1
2′
TB
—
—

^tC₄H₉
H
H
H
H
acac

2′ -324Y
Pd
0
2′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -325
Pd
1
2′
TB
—
—
CH₃
H
H
H
H
pic

2′ -325X
Pd
1
2′
TB
—
—
CH₃
H
H
H
H
acac

2′ -325Y
Pd
0
2′
TB
—
—
CH₃
H
H
H
H
—
—

2′ -326
Pd
1
2′
TB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -326X
Pd
1
2′
TB
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -326Y
Pd
0
2′
TB
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -327
Pd
1
2′
TB
—
—
CH₃
H
H
CH₃
H
pic

2′ -327X
Pd
1
2′
TB
—
—
CH₃
H
H
CH₃
H
acac

2′ -327Y
Pd
0
2′
TB
—
—
CH₃
H
H
CH₃
H
—
—

2′ -328
Pd
1
2′
TB
—
—
H
H
H
CH₃
H
pic

2′ -328X
Pd
1
2′
TB
—
—
H
H
H
CH₃
H
acac

2′ -328Y
Pd
0
2′
TB
—
—
H
H
H
CH₃
H
—
—

2′ -329
Pd
1
2′
TF
—
—
H
H
H
H
H
pic

2′ -329X
Pd
1
2′
TF
—
—
H
H
H
H
H
acac

2′ -329Y
Pd
0
2′
TF
—
—
H
H
H
H
H
—
—

2′ -330
Pd
1
2′
TF
—
—

^tC₄H₉
H
H
H
H
pic

2′ -330X
Pd
1
2′
TF
—
—

^tC₄H₉
H
H
H
H
acac

2′ -330Y
Pd
0
2′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -331
Pd
1
2′
TF
—
—
CH₃
H
H
H
H
pic

2′ -331X
Pd
1
2′
TF
—
—
CH₃
H
H
H
H
acac

2′ -331Y
Pd
0
2′
TF
—
—
CH₃
H
H
H
H
—
—

2′ -332
Pd
1
2′
TF
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -332X
Pd
1
2′
TF
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -332Y
Pd
0
2′
TF
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -333
Pd
1
2′
TF
—
—
CH₃
H
H
CH₃
H
pic

2′ -333X
Pd
1
2′
TF
—
—
CH₃
H
H
CH₃
H
acac

2′ -333Y
Pd
0
2′
TF
—
—
CH₃
H
H
CH₃
H
—
—

2′ -334
Pd
1
2′
TF
—
—
H
H
H
CH₃
H
pic

2′ -334X
Pd
1
2′
TF
—
—
H
H
H
CH₃
H
acac

2′ -334Y
Pd
0
2′
TF
—
—
H
H
H
CH₃
H
—
—

2′ -335
Pd
1
2′
OB
—
—
H
H
H
H
H
pic

2′ -335X
Pd
1
2′
OB
—
—
H
H
H
H
H
acac

2′ -335Y
Pd
0
2′
OB
—
—
H
H
H
H
H
—
—

2′ -336
Pd
1
2′
OB
—
—

^tC₄H₉
H
H
H
H
pic

2′ -336X
Pd
1
2′
OB
—
—

^tC₄H₉
H
H
H
H
acac

2′ -336Y
Pd
0
2′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -337
Pd
1
2′
OB
—
—
CH₃
H
H
H
H
pic

2′ -337X
Pd
1
2′
OB
—
—
CH₃
H
H
H
H
acac

2′ -337Y
Pd
0
2′
OB
—
—
CH₃
H
H
H
H
—
—

2′ -338
Pd
1
2′
OB
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -338X
Pd
1
2′
OB
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -338Y
Pd
0
2′
OB
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -339
Pd
1
2′
OB
—
—
CH₃
H
H
CH3
H
pic

2′ -339X
Pd
1
2′
OB
—
—
CH₃
H
H
CH₃
H
acac

2′ -339Y
Pd
0
2′
OB
—
—
CH₃
H
H
CH₃
H
—
—

2′ -340
Pd
1
2′
OB
—
—
H
H
H
CH₃
H
pic

2′ -340X
Pd
1
2′
OB
—
—
H
H
H
CH₃
H
acac

2′ -340Y
Pd
0
2′
OB
—
—
H
H
H
CH₃
H
—
—

2′ -341
Pd
1
2′
Fu
—
—
H
H
H
H
H
pic

2′ -341X
Pd
1
2′
Fu
—
—
H
H
H
H
H
acac

2′ -341Y
Pd
0
2′
Fu
—
—
H
H
H
H
H
—
—

2′ -342
Pd
1
2′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

2′ -342X
Pd
1
2′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

2′ -342Y
Pd
0
2′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -343
Pd
1
2′
Fu
—
—
CH₃
H
H
H
H
pic

2′ -343X
Pd
1
2′
Fu
—
—
CH₃
H
H
H
H
acac

2′ -343Y
Pd
0
2′
Fu
—
—
CH₃
H
H
H
H
—
—

2′ -344
Pd
1
2′
Fu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -344X
Pd
1
2′
Fu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -344Y
Pd
0
2′
Fu
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -345
Pd
1
2′
Fu
—
—
CH₃
H
H
CH3
H
pic

2′ -345X
Pd
1
2′
Fu
—
—
CH₃
H
H
CH₃
H
acac

2′ -345Y
Pd
0
2′
Fu
—
—
CH₃
H
H
CH₃
H
—
—

2′ -346
Pd
1
2′
Fu
—
—
H
H
H
CH₃
H
pic

2′ -346X
Pd
1
2′
Fu
—
—
H
H
H
CH₃
H
acac

2′ -346Y
Pd
0
2′
Fu
—
—
H
H
H
CH₃
H
—
—

2′ -347
Pd
1
2′
Fl
—
—
H
H
H
H
H
pic

2′ -347X
Pd
1
2′
Fl
—
—
H
H
H
H
H
acac

2′ -347Y
Pd
0
2′
Fl
—
—
H
H
H
H
H
—
—

2′ -348
Pd
1
2′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

2′ -348X
Pd
1
2′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

2′ -348Y
Pd
0
2′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -349
Pd
1
2′
Fl
—
—
CH₃
H
H
H
H
pic

2′ -349X
Pd
1
2′
Fl
—
—
CH₃
H
H
H
H
acac

2′ -349Y
Pd
0
2′
Fl
—
—
CH₃
H
H
H
H
—
—

2′ -350
Pd
1
2′
Fl
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -350X
Pd
1
2′
Fl
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -350Y
Pd
0
2′
Fl
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -351
Pd
1
2′
Fl
—
—
CH₃
H
H
CH₃
H
pic

2′ -351X
Pd
1
2′
Fl
—
—
CH₃
H
H
CH₃
H
acac

2′ -351Y
Pd
0
2′
Fl
—
—
CH₃
H
H
CH₃
H
—
—

2′ -352
Pd
1
2′
Fl
—
—
H
H
H
CH₃
H
pic

2′ -352X
Pd
1
2′
Fl
—
—
H
H
H
CH₃
H
acac

2′ -352Y
Pd
0
2′
Fl
—
—
H
H
H
CH₃
H
—
—

2′ -353
Pd
1
2′
Bz
—
—
H
H
H
H
H
pic

2′ -353X
Pd
1
2′
Bz
—
—
H
H
H
H
H
acac

2′ -353Y
Pd
0
2′
Bz
—
—
H
H
H
H
H
—
—

2′ -354
Pd
1
2′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

2′ -354X
Pd
1
2′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

2′ -354Y
Pd
0
2′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -355
Pd
1
2′
Bz
—
—
CH₃
H
H
H
H
pic

2′ -355X
Pd
1
2′
Bz
—
—
CH₃
H
H
H
H
acac

2′ -355Y
Pd
0
2′
Bz
—
—
CH₃
H
H
H
H
—
—

2′ -356
Pd
1
2′
Bz
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -356X
Pd
1
2′
Bz
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -356Y
Pd
0
2′
Bz
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -357
Pd
1
2′
Bz
—
—
CH₃
H
H
CH₃
H
pic

2′ -357X
Pd
1
2′
Bz
—
—
CH₃
H
H
CH₃
H
acac

2′ -357Y
Pd
0
2′
Bz
—
—
CH₃
H
H
CH₃
H
—
—

2′ -358
Pd
1
2′
Bz
—
—
H
H
H
CH₃
H
pic

2′ -358X
Pd
1
2′
Bz
—
—
H
H
H
CH₃
H
acac

2′ -358Y
Pd
0
2′
Bz
—
—
H
H
H
CH₃
H
—
—

2′ -359
Pd
1
2′
Qu
—
—
H
H
H
H
H
pic

2′ -359X
Pd
1
2′
Qu
—
—
H
H
H
H
H
acac

2′ -359Y
Pd
0
2′
Qu
—
—
H
H
H
H
H
—
—

2′ -360
Pd
1
2′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

2′ -360X
Pd
1
2′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

2′ -360Y
Pd
0
2′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

2′ -361
Pd
1
2′
Qu
—
—
CH₃
H
H
H
H
pic

2′ -361X
Pd
1
2′
Qu
—
—
CH₃
H
H
H
H
acac

2′ -361Y
Pd
0
2′
Qu
—
—
CH₃
H
H
H
H
—
—

2′ -362
Pd
1
2′
Qu
—
—

^tC₄H₉
H
H
CH₃
H
pic

2′ -362X
Pd
1
2′
Qu
—
—

^tC₄H₉
H
H
CH₃
H
acac

2′ -362Y
Pd
0
2′
Qu
—
—

^tC₄H₉
H
H
CH₃
H
—
—

2′ -363
Pd
1
2′
Qu
—
—
CH₃
H
H
CH₃
H
pic

2′ -363X
Pd
1
2′
Qu
—
—
CH₃
H
H
CH₃
H
acac

2′ -363Y
Pd
0
2′
Qu
—
—
CH₃
H
H
CH₃
H
—
—

2′ -364
Pd
1
2′
Qu
—
—
H
H
H
CH₃
H
pic

2′ -364X
Pd
1
2′
Qu
—
—
H
H
H
CH₃
H
acac

2′ -364Y
Pd
0
2′
Qu
—
—
H
H
H
CH₃
H
—
—

2′ -365
Pd
1
2′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

2′ -365X
Pd
1
2′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

2′ -365Y
Pd
0
2′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

2′ -366
Pd
1
2′
OL
H

^tC₄H₉
H
H
H
H
H
pic

2′ -366X
Pd
1
2′
OL
H

^tC₄H₉
H
H
H
H
H
acac

2′ -366Y
Pd
0
2′
OL
H

^tC₄H₉
H
H
H
H
H
—
—

2′ -367
Pd
1
2′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

2′ -367X
Pd
1
2′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

2′ -367Y
Pd
0
2′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

2′ -368
Pd
1
2′
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

2′ -368X
Pd
1
2′
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

2′ -368Y
Pd
0
2′
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

2′ -369
Pd
1
2′
OL
H
H
H
H
H
H
H
pic

2′ -369X
Pd
1
2′
OL
H
H
H
H
H
H
H
acac

2′ -369Y
Pd
0
2′
OL
H
H
H
H
H
H
H
—
—

2′ -370
Pd
1
2′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

2′ -370X
Pd
1
2′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

2′ -370Y
Pd
0
2′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

2′ -371
Pd
1
2′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

2′ -371X
Pd
1
2′
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

2′ -371Y
Pd
0
2′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

2′ -372
Pd
1
2′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

2′ -372X
Pd
1
2′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

2′ -372Y
Pd
0
2′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 52

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

3′ -271
Pd
1
3′
Nap1
—
—
H
H
H
H
H
pic

3′ -271X
Pd
1
3′
Nap1
—
—
H
H
H
H
H
acac

3′ -271Y
Pd
0
3′
Nap1
—
—
H
H
H
H
H
—
—

3′ -272
Pd
1
3′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

3′ -272X
Pd
1
3′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

3′ -272Y
Pd
0
3′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -273
Pd
1
3′
Nap1
—
—
CH₃
H
H
H
H
pic

3′ -273X
Pd
1
3′
Nap1
—
—
CH₃
H
H
H
H
acac

3′ -273Y
Pd
0
3′
Nap1
—
—
CH₃
H
H
H
H
—
—

3′ -274
Pd
1
3′
Nap2
—
—
H
H
H
H
H
pic

3′ -274X
Pd
1
3′
Nap2
—
—
H
H
H
H
H
acac

3′ -274Y
Pd
0
3′
Nap2
—
—
H
H
H
H
H
—
—

3′ -275
Pd
1
3′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

3′ -275X
Pd
1
3′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

3′ -275Y
Pd
0
3′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -276
Pd
1
3′
Nap2
—
—
CH₃
H
H
H
H
pic

3′ -276X
Pd
1
3′
Nap2
—
—
CH₃
H
H
H
H
acac

3′ -276Y
Pd
0
3′
Nap2
—
—
CH₃
H
H
H
H
—
—

3′ -277
Pd
1
3′
Nap3
—
—
H
H
H
H
H
pic

3′ -277X
Pd
1
3′
Nap3
—
—
H
H
H
H
H
acac

3′ -277Y
Pd
0
3′
Nap3
—
—
H
H
H
H
H
—
—

3′ -278
Pd
1
3′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

3′ -278X
Pd
1
3′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

3′ -278Y
Pd
0
3′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -279
Pd
1
3′
Nap3
—
—
CH₃
H
H
H
H
pic

3′ -279X
Pd
1
3′
Nap3
—
—
CH₃
H
H
H
H
acac

3′ -279Y
Pd
0
3′
Nap3
—
—
CH₃
H
H
H
H
—
—

3′ -280
Pd
1
3′
TB
—
—
H
H
H
H
H
pic

3′ -280X
Pd
1
3′
TB
—
—
H
H
H
H
H
acac

3′ -280Y
Pd
0
3′
TB
—
—
H
H
H
H
H
—
—

3′ -281
Pd
1
3′
TB
—
—

^tC₄H₉
H
H
H
H
pic

3′ -281X
Pd
1
3′
TB
—
—

^tC₄H₉
H
H
H
H
acac

3′ -281Y
Pd
0
3′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -282
Pd
1
3′
TB
—
—
CH₃
H
H
H
H
pic

3′ -282X
Pd
1
3′
TB
—
—
CH₃
H
H
H
H
acac

3′ -282Y
Pd
0
3′
TB
—
—
CH₃
H
H
H
H
—
—

3′ -283
Pd
1
3′
TF
—
—
H
H
H
H
H
pic

3′ -283X
Pd
1
3′
TF
—
—
H
H
H
H
H
acac

3′ -283Y
Pd
0
3′
TF
—
—
H
H
H
H
H
—
—

3′ -284
Pd
1
3′
TF
—
—

^tC₄H₉
H
H
H
H
pic

3′ -284X
Pd
1
3′
TF
—
—

^tC₄H₉
H
H
H
H
acac

3′ -284Y
Pd
0
3′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -285
Pd
1
3′
TF
—
—
CH₃
H
H
H
H
pic

3′ -285X
Pd
1
3′
TF
—
—
CH₃
H
H
H
H
acac

3′ -285Y
Pd
0
3′
TF
—
—
CH₃
H
H
H
H
—
—

3′ -286
Pd
1
3′
OB
—
—
H
H
H
H
H
pic

3′ -286X
Pd
1
3′
OB
—
—
H
H
H
H
H
acac

3′ -286Y
Pd
0
3′
OB
—
—
H
H
H
H
H
—
—

3′ -287
Pd
1
3′
OB
—
—

^tC₄H₉
H
H
H
H
pic

3′ -287X
Pd
1
3′
OB
—
—

^tC₄H₉
H
H
H
H
acac

3′ -287Y
Pd
0
3′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -288
Pd
1
3′
OB
—
—
CH₃
H
H
H
H
pic

3′ -288X
Pd
1
3′
OB
—
—
CH₃
H
H
H
H
acac

3′ -288Y
Pd
0
3′
OB
—
—
CH₃
H
H
H
H
—
—

3′ -289
Pd
1
3′
Fu
—
—
H
H
H
H
H
pic

3′ -289X
Pd
1
3′
Fu
—
—
H
H
H
H
H
acac

3′ -289Y
Pd
0
3′
Fu
—
—
H
H
H
H
H
—
—

3′ -290
Pd
1
3′
Fu
—
—

^tC₄H₉
H
H
H
H
pic

3′ -290X
Pd
1
3′
Fu
—
—

^tC₄H₉
H
H
H
H
acac

3′ -290Y
Pd
0
3′
Fu
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -291
Pd
1
3′
Fu
—
—
CH₃
H
H
H
H
pic

3′ -291X
Pd
1
3′
Fu
—
—
CH₃
H
H
H
H
acac

3′ -291Y
Pd
0
3′
Fu
—
—
CH₃
H
H
H
H
—
—

3′ -292
Pd
1
3′
Fl
—
—
H
H
H
H
H
pic

3′ -292X
Pd
1
3′
Fl
—
—
H
H
H
H
H
acac

3′ -292Y
Pd
0
3′
Fl
—
—
H
H
H
H
H
—
—

3′ -293
Pd
1
3′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

3′ -293X
Pd
1
3′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

3′ -293Y
Pd
0
3′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -294
Pd
1
3′
Fl
—
—
CH₃
H
H
H
H
pic

3′ -294X
Pd
1
3′
Fl
—
—
CH₃
H
H
H
H
acac

3′ -294Y
Pd
0
3′
Fl
—
—
CH₃
H
H
H
H
—
—

3′ -295
Pd
1
3′
Bz
—
—
H
H
H
H
H
pic

3′ -295X
Pd
1
3′
Bz
—
—
H
H
H
H
H
acac

3′ -295Y
Pd
0
3′
Bz
—
—
H
H
H
H
H
—
—

3′ -296
Pd
1
3′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

3′ -296X
Pd
1
3′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

3′ -296Y
Pd
0
3′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -297
Pd
1
3′
Bz
—
—
CH₃
H
H
H
H
pic

3′ -297X
Pd
1
3′
Bz
—
—
CH₃
H
H
H
H
acac

3′ -297Y
Pd
0
3′
Bz
—
—
CH₃
H
H
H
H
—
—

3′ -298
Pd
1
3′
Qu
—
—
H
H
H
H
H
pic

3′ -298X
Pd
1
3′
Qu
—
—
H
H
H
H
H
acac

3′ -298Y
Pd
0
3′
Qu
—
—
H
H
H
H
H
—
—

3′ -299
Pd
1
3′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

3′ -299X
Pd
1
3′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

3′ -299Y
Pd
0
3′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

3′ -300
Pd
1
3′
Qu
—
—
CH₃
H
H
H
H
pic

3′ -300X
Pd
1
3′
Qu
—
—
CH₃
H
H
H
H
acac

3′ -300Y
Pd
0
3′
Qu
—
—
CH₃
H
H
H
H
—
—

3′ -301
Pd
1
3′
OL
H

ⁿC₄H₉
H
H
H
H
H
pic

3′ -301X
Pd
1
3′
OL
H

ⁿC₄H₉
H
H
H
H
H
acac

3′ -301Y
Pd
0
3′
OL
H

ⁿC₄H₉
H
H
H
H
H
—
—

3′ -302
Pd
1
3′
OL
H

^tC₄H₉
H
H
H
H
H
pic

3′ -302X
Pd
1
3′
OL
H

^tC₄H₉
H
H
H
H
H
acac

3′ -302Y
Pd
0
3′
OL
H

^tC₄H₉
H
H
H
H
H
—
—

3′ -303
Pd
1
3′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
pic

3′ -303X
Pd
1
3′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
acac

3′ -303Y
Pd
0
3′
OL
CH₃

ⁿC₄H₉
H
H
H
H
H
—
—

3′ -304
Pd
1
3′
OL
CH₃

^tC₄H₉
H
H
H
H
H
pic

3′ -304X
Pd
1
3′
OL
CH₃

^tC₄H₉
H
H
H
H
H
acac

3′ -304Y
Pd
0
3′
OL
CH₃

^tC₄H₉
H
H
H
H
H
—
—

3′ -305
Pd
1
3′
OL
H
H
H
H
H
H
H
pic

3′ -305X
Pd
1
3′
OL
H
H
H
H
H
H
H
acac

3′ -305Y
Pd
0
3′
OL
H
H
H
H
H
H
H
—
—

3′ -306
Pd
1
3′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

3′ -306X
Pd
1
3′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

3′ -306Y
Pd
0
3′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

3′ -307
Pd
1
3′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

3′ -307X
Pd
1
3′
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

3′ -307Y
Pd
0
3′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

3′ -308
Pd
1
3′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
pic

3′ -308X
Pd
1
3′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
acac

3′ -308Y
Pd
0
3′
OL
—CH₂CH₂CH₂—
H
H
H
H
H
—
—

embedded image

TABLE 53

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
T⁸
T⁹
L¹
L²

4′ -304
Pd
1
4′
Nap1
—
—
CH₃
H
H
H
H
pic

4′ -304X
Pd
1
4′
Nap1
—
—
CH₃
H
H
H
H
acac

4′ -304Y
Pd
0
4′
Nap1
—
—
CH₃
H
H
H
H
—
—

4′ -305
Pd
1
4′
Nap1
—
—

^tC₄H₉
H
H
H
H
pic

4′ -305X
Pd
1
4′
Nap1
—
—

^tC₄H₉
H
H
H
H
acac

4′ -305Y
Pd
0
4′
Nap1
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -306
Pd
1
4′
Nap2
—
—
CH₃
H
H
H
H
pic

4′ -306X
Pd
1
4′
Nap2
—
—
CH₃
H
H
H
H
acac

4′ -306Y
Pd
0
4′
Nap2
—
—
CH₃
H
H
H
H
—
—

4′ -307
Pd
1
4′
Nap2
—
—

^tC₄H₉
H
H
H
H
pic

4′ -307X
Pd
1
4′
Nap2
—
—

^tC₄H₉
H
H
H
H
acac

4′ -307Y
Pd
0
4′
Nap2
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -308
Pd
1
4′
Nap3
—
—
CH₃
H
H
H
H
pic

4′ -308X
Pd
1
4′
Nap3
—
—
CH₃
H
H
H
H
acac

4′ -308Y
Pd
0
4′
Nap3
—
—
CH₃
H
H
H
H
—
—

4′ -309
Pd
1
4′
Nap3
—
—

^tC₄H₉
H
H
H
H
pic

4′ -309X
Pd
1
4′
Nap3
—
—

^tC₄H₉
H
H
H
H
acac

4′ -309Y
Pd
0
4′
Nap3
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -310
Pd
1
4′
TB
—
—
CH₃
H
H
H
H
pic

4′ -310X
Pd
1
4′
TB
—
—
CH₃
H
H
H
H
acac

4′ -310Y
Pd
0
4′
TB
—
—
CH₃
H
H
H
H
—
—

4′ -311
Pd
1
4′
TB
—
—

^tC₄H₉
H
H
H
H
pic

4′ -311X
Pd
1
4′
TB
—
—

^tC₄H₉
H
H
H
H
acac

4′ -311Y
Pd
0
4′
TB
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -312
Pd
1
4′
TF
—
—
CH₃
H
H
H
H
pic

4′ -312X
Pd
1
4′
TF
—
—
CH₃
H
H
H
H
acac

4′ -312Y
Pd
0
4′
TF
—
—
CH₃
H
H
H
H
—
—

4′ -313
Pd
1
4′
TF
—
—

^tC₄H₉
H
H
H
H
pic

4′ -313X
Pd
1
4′
TF
—
—

^tC₄H₉
H
H
H
H
acac

4′ -313Y
Pd
0
4′
TF
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -314
Pd
1
4′
OB
—
—
CH₃
H
H
H
H
pic

4′ -314X
Pd
1
4′
OB
—
—
CH₃
H
H
H
H
acac

4′ -314Y
Pd
0
4′
OB
—
—
CH₃
H
H
H
H
—
—

4′ -315
Pd
1
4′
OB
—
—

^tC₄H₉
H
H
H
H
pic

4′ -315X
Pd
1
4′
OB
—
—

^tC₄H₉
H
H
H
H
acac

4′ -315Y
Pd
0
4′
OB
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -316
Pd
1
4′
Fu
—
—
H
H
H
H
H
pic

4′ -316X
Pd
1
4′
Fu
—
—
H
H
H
H
H
acac

4′ -316Y
Pd
0
4′
Fu
—
—
H
H
H
H
H
—
—

4′ -317
Pd
1
4′
Fu
—
—
H
H
H
H
H
pic

4′ -317X
Pd
1
4′
Fu
—
—
H
H
H
H
H
acac

4′ -317Y
Pd
0
4′
Fu
—
—
H
H
H
H
H
—
—

4′ -318
Pd
1
4′
Fl
—
—
H
H
H
H
H
pic

4′ -318X
Pd
1
4′
Fl
—
—
H
H
H
H
H
acac

4′ -318Y
Pd
0
4′
Fl
—
—
H
H
H
H
H
—
—

4′ -319
Pd
1
4′
Fl
—
—

^tC₄H₉
H
H
H
H
pic

4′ -319X
Pd
1
4′
Fl
—
—

^tC₄H₉
H
H
H
H
acac

4′ -319Y
Pd
0
4′
Fl
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -320
Pd
1
4′
Bz
—
—
CH₃
H
H
H
H
pic

4′ -320X
Pd
1
4′
Bz
—
—
CH₃
H
H
H
H
acac

4′ -320Y
Pd
0
4′
Bz
—
—
CH₃
H
H
H
H
—
—

4′ -321
Pd
1
4′
Bz
—
—

^tC₄H₉
H
H
H
H
pic

4′ -321X
Pd
1
4′
Bz
—
—

^tC₄H₉
H
H
H
H
acac

4′ -321Y
Pd
0
4′
Bz
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -322
Pd
1
4′
Qu
—
—
CH₃
H
H
H
H
pic

4′ -322X
Pd
1
4′
Qu
—
—
CH₃
H
H
H
H
acac

4′ -322Y
Pd
0
4′
Qu
—
—
CH₃
H
H
H
H
—
—

4′ -323
Pd
1
4′
Qu
—
—

^tC₄H₉
H
H
H
H
pic

4′ -323X
Pd
1
4′
Qu
—
—

^tC₄H₉
H
H
H
H
acac

4′ -323Y
Pd
0
4′
Qu
—
—

^tC₄H₉
H
H
H
H
—
—

4′ -324
Pd
1
4′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
pic

4′ -324X
Pd
1
4′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
acac

4′ -324Y
Pd
0
4′
OL
H

ⁿC₄H₉
CH₃
H
H
H
H
—
—

4′ -325
Pd
1
4′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
pic

4′ -325X
Pd
1
4′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
acac

4′ -325Y
Pd
0
4′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′ -326
Pd
1
4′
OL
H

^tC₄H₉
CH₃
H
H
H
H
pic

4′ -326X
Pd
1
4′
OL
H

^tC₄H₉
CH₃
H
H
H
H
acac

4′ -326Y
Pd
0
4′
OL
H

^tC₄H₉
CH₃
H
H
H
H
—
—

4′ -327
Pd
1
4′
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
pic

4′ -327X
Pd
1
4′
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
acac

4′ -327Y
Pd
0
4′
OL
H

^tC₄H₉

^tC₄H₉
H
H
H
H
—
—

4′ -328
Pd
1
4′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
pic

4′ -328X
Pd
1
4′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
acac

4′ -328Y
Pd
0
4′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
H
H
—
—

4′ -329
Pd
1
4′
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
pic

4′ -329X
Pd
1
4′
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
acac

4′ -329Y
Pd
0
4′
OL
CH₃

^tC₄H₉
CH₃
H
H
H
H
—
—

4′ -330
Pd
1
4′
OL
H
H
CH₃
H
H
H
H
pic

4′ -330X
Pd
1
4′
OL
H
H
CH₃
H
H
H
H
acac

4′ -330Y
Pd
0
4′
OL
H
H
CH₃
H
H
H
H
—
—

4′ -331
Pd
1
4′
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
pic

4′ -331X
Pd
1
4′
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
acac

4′ -331Y
Pd
0
4′
OL
—CH₂CH₂CH₂—
CH₃
H
H
H
H
—
—

4′ -332
Pd
1
4′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
pic

4′ -332X
Pd
1
4′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
acac

4′ -332Y
Pd
0
4′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
H
H
—
—

embedded image

TABLE 54

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹
L²

5′ -350
Pd
1
5′
Nap1
—
—
H
CH₃
H
pic

5′ -350X
Pd
1
5′
Nap1
—
—
H
CH₃
H
acac

5′ -350Y
Pd
0
5′
Nap1
—
—
H
CH₃
H
—
—

5′ -351
Pd
1
5′
Nap1
—
—
H

^tC₄H₉
H
pic

5′ -351X
Pd
1
5′
Nap1
—
—
H

^tC₄H₉
H
acac

5′ -351Y
Pd
0
5′
Nap1
—
—
H

^tC₄H₉
H
—
—

5′ -352
Pd
1
5′
Nap1
—
—

^tC₄H₉
CH₃
H
pic

5′ -352X
Pd
1
5′
Nap1
—
—

^tC₄H₉
CH₃
H
acac

5′ -352Y
Pd
0
5′
Nap1
—
—

^tC₄H₉
CH₃
H
—
—

5′ -353
Pd
1
5′
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -353X
Pd
1
5′
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -353Y
Pd
0
5′
Nap1
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -354
Pd
1
5′
Nap1
—
—
CH₃
CH₃
H
pic

5′ -354X
Pd
1
5′
Nap1
—
—
CH₃
CH₃
H
acac

5′ -354Y
Pd
0
5′
Nap1
—
—
CH₃
CH₃
H
—
—

5′ -355
Pd
1
5′
Nap1
—
—
CH₃

^tC₄H₉
H
pic

5′ -355X
Pd
1
5′
Nap1
—
—
CH₃

^tC₄H₉
H
acac

5′ -355Y
Pd
0
5′
Nap1
—
—
CH₃

^tC₄H₉
H
—
—

5′ -356
Pd
1
5′
Nap2
—
—
H
CH₃
H
pic

5′ -356X
Pd
1
5′
Nap2
—
—
H
CH₃
H
acac

5′ -356Y
Pd
0
5′
Nap2
—
—
H
CH₃
H
—
—

5′ -357
Pd
1
5′
Nap2
—
—
H

^tC₄H₉
H
pic

5′ -357X
Pd
1
5′
Nap2
—
—
H

^tC₄H₉
H
acac

5′ -357Y
Pd
0
5′
Nap2
—
—
H

^tC₄H₉
H
—
—

5′ -358
Pd
1
5′
Nap2
—
—

^tC₄H₉
CH₃
H
pic

5′ -358X
Pd
1
5′
Nap2
—
—

^tC₄H₉
CH₃
H
acac

5′ -358Y
Pd
0
5′
Nap2
—
—

^tC₄H₉
CH₃
H
—
—

5′ -359
Pd
1
5′
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -359X
Pd
1
5′
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -359Y
Pd
0
5′
Nap2
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -360
Pd
1
5′
Nap2
—
—
CH₃
CH₃
H
pic

5′ -360X
Pd
1
5′
Nap2
—
—
CH₃
CH₃
H
acac

5′ -360Y
Pd
0
5′
Nap2
—
—
CH₃
CH₃
H
—
—

5′ -361
Pd
1
5′
Nap2
—
—
CH₃

^tC₄H₉
H
pic

5′ -361X
Pd
1
5′
Nap2
—
—
CH₃

^tC₄H₉
H
acac

5′ -361Y
Pd
0
5′
Nap2
—
—
CH₃

^tC₄H₉
H
—
—

5′ -362
Pd
1
5′
Nap3
—
—
H
CH₃
H
pic

5′ -362X
Pd
1
5′
Nap3
—
—
H
CH₃
H
acac

5′ -362Y
Pd
0
5′
Nap3
—
—
H
CH₃
H
—
—

5′ -363
Pd
1
5′
Nap3
—
—
H

^tC₄H₉
H
pic

5′ -363X
Pd
1
5′
Nap3
—
—
H

^tC₄H₉
H
acac

5′ -363Y
Pd
0
5′
Nap3
—
—
H

^tC₄H₉
H
—
—

5′ -364
Pd
1
5′
Nap3
—
—

^tC₄H₉
CH₃
H
pic

5′ -364X
Pd
1
5′
Nap3
—
—

^tC₄H₉
CH₃
H
acac

5′ -364Y
Pd
0
5′
Nap3
—
—

^tC₄H₉
CH₃
H
—
—

5′ -365
Pd
1
5′
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -365X
Pd
1
5′
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -365Y
Pd
0
5′
Nap3
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -366
Pd
1
5′
Nap3
—
—
CH₃
CH₃
H
pic

5′ -366X
Pd
1
5′
Nap3
—
—
CH₃
CH₃
H
acac

5′ -366Y
Pd
0
5′
Nap3
—
—
CH₃
CH₃
H
—
—

5′ -367
Pd
1
5′
Nap3
—
—
CH₃

^tC₄H₉
H
pic

5′ -367X
Pd
1
5′
Nap3
—
—
CH₃

^tC₄H₉
H
acac

5′ -367Y
Pd
0
5′
Nap3
—
—
CH₃

^tC₄H₉
H
—
—

5′ -368
Pd
1
5′
TB
—
—
H
CH₃
H
pic

5′ -368X
Pd
1
5′
TB
—
—
H
CH₃
H
acac

5′ -368Y
Pd
0
5′
TB
—
—
H
CH₃
H
—
—

5′ -369
Pd
1
5′
TB
—
—
H

^tC₄H₉
H
pic

5′ -369X
Pd
1
5′
TB
—
—
H

^tC₄H₉
H
acac

5′ -369Y
Pd
0
5′
TB
—
—
H

^tC₄H₉
H
—
—

5′ -370
Pd
1
5′
TB
—
—

^tC₄H₉
CH₃
H
pic

5′ -370X
Pd
1
5′
TB
—
—

^tC₄H₉
CH₃
H
acac

5′ -370Y
Pd
0
5′
TB
—
—

^tC₄H₉
CH₃
H
—
—

5′ -371
Pd
1
5′
TB
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -371X
Pd
1
5′
TB
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -371Y
Pd
0
5′
TB
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -372
Pd
1
5′
TB
—
—
CH₃
CH₃
H
pic

5′ -372X
Pd
1
5′
TB
—
—
CH₃
CH₃
H
acac

5′ -372Y
Pd
0
5′
TB
—
—
CH₃
CH₃
H
—
—

5′ -373
Pd
1
5′
TB
—
—
CH₃

^tC₄H₉
H
pic

5′ -373X
Pd
1
5′
TB
—
—
CH₃

^tC₄H₉
H
acac

5′ -373Y
Pd
0
5′
TB
—
—
CH₃

^tC₄H₉
H
—
—

5′ -374
Pd
1
5′
TF
—
—
H
CH₃
H
pic

5′ -374X
Pd
1
5′
TF
—
—
H
CH₃
H
acac

5′ -374Y
Pd
0
5′
TF
—
—
H
CH₃
H
—
—

5′ -375
Pd
1
5′
TF
—
—
H

^tC₄H₉
H
pic

5′ -375X
Pd
1
5′
TF
—
—
H

^tC₄H₉
H
acac

5′ -375Y
Pd
0
5′
TF
—
—
H

^tC₄H₉
H
—
—

5′ -376
Pd
1
5′
TF
—
—

^tC₄H₉
CH₃
H
pic

5′ -376X
Pd
1
5′
TF
—
—

^tC₄H₉
CH₃
H
acac

5′ -376Y
Pd
0
5′
TF
—
—

^tC₄H₉
CH₃
H
—
—

5′ -377
Pd
1
5′
TF
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -377X
Pd
1
5′
TF
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -377Y
Pd
0
5′
TF
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -378
Pd
1
5′
TF
—
—
CH₃
CH₃
H
pic

5′ -378X
Pd
1
5′
TF
—
—
CH₃
CH₃
H
acac

5′ -378Y
Pd
0
5′
TF
—
—
CH₃
CH₃
H
—
—

5′ -379
Pd
1
5′
TF
—
—
CH₃

^tC₄H₉
H
pic

5′ -379X
Pd
1
5′
TF
—
—
CH₃

^tC₄H₉
H
acac

5′ -379Y
Pd
0
5′
TF
—
—
CH₃

^tC₄H₉
H
—
—

5′ -380
Pd
1
5′
OB
—
—
H
CH₃
H
pic

5′ -380X
Pd
1
5′
OB
—
—
H
CH₃
H
acac

5′ -380Y
Pd
0
5′
OB
—
—
H
CH₃
H
—
—

5′ -381
Pd
1
5′
OB
—
—
H

^tC₄H₉
H
pic

5′ -381X
Pd
1
5′
OB
—
—
H

^tC₄H₉
H
acac

5′ -381Y
Pd
0
5′
OB
—
—
H

^tC₄H₉
H
—
—

5′ -382
Pd
1
5′
OB
—
—

^tC₄H₉
CH₃
H
pic

5′ -382X
Pd
1
5′
OB
—
—

^tC₄H₉
CH₃
H
acac

5′ -382Y
Pd
0
5′
OB
—
—

^tC₄H₉
CH₃
H
—
—

5′ -383
Pd
1
5′
OB
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -383X
Pd
1
5′
OB
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -383Y
Pd
0
5′
OB
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -384
Pd
1
5′
OB
—
—
CH₃
CH₃
H
pic

5′ -384X
Pd
1
5′
OB
—
—
CH₃
CH₃
H
acac

5′ -384Y
Pd
0
5′
OB
—
—
CH₃
CH₃
H
—
—

5′ -385
Pd
1
5′
OB
—
—
CH₃

^tC₄H₉
H
pic

5′ -385X
Pd
1
5′
OB
—
—
CH₃

^tC₄H₉
H
acac

5′ -385Y
Pd
0
5′
OB
—
—
CH₃

^tC₄H₉
H
—
—

5′ -386
Pd
1
5′
Fu
—
—
H
CH₃
H
pic

5′ -386X
Pd
1
5′
Fu
—
—
H
CH₃
H
acac

5′ -386Y
Pd
0
5′
Fu
—
—
H
CH₃
H
—
—

5′ -387
Pd
1
5′
Fu
—
—
H

^tC₄H₉
H
pic

5′ -387X
Pd
1
5′
Fu
—
—
H

^tC₄H₉
H
acac

5′ -387Y
Pd
0
5′
Fu
—
—
H

^tC₄H₉
H
—
—

5′ -388
Pd
1
5′
Fu
—
—

^tC₄H₉
CH₃
H
pic

5′ -388X
Pd
1
5′
Fu
—
—

^tC₄H₉
CH₃
H
acac

5′ -388Y
Pd
0
5′
Fu
—
—

^tC₄H₉
CH₃
H
—
—

5′ -389
Pd
1
5′
Fu
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -389X
Pd
1
5′
Fu
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -389Y
Pd
0
5′
Fu
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -390
Pd
1
5′
Fu
—
—
CH₃
CH₃
H
pic

5′ -390X
Pd
1
5′
Fu
—
—
CH₃
CH₃
H
acac

5′ -390Y
Pd
0
5′
Fu
—
—
CH₃
CH₃
H
—
—

5′ -391
Pd
1
5′
Fu
—
—
CH₃

^tC₄H₉
H
pic

5′ -391X
Pd
1
5′
Fu
—
—
CH₃

^tC₄H₉
H
acac

5′ -391Y
Pd
0
5′
Fu
—
—
CH₃

^tC₄H₉
H
—
—

5′ -392
Pd
1
5′
Fl
—
—
H
CH₃
H
pic

5′ -392X
Pd
1
5′
Fl
—
—
H
CH₃
H
acac

5′ -392Y
Pd
0
5′
Fl
—
—
H
CH₃
H
—
—

5′ -393
Pd
1
5′
Fl
—
—
H

^tC₄H₉
H
pic

5′ -393X
Pd
1
5′
Fl
—
—
H

^tC₄H₉
H
acac

5′ -393Y
Pd
0
5′
Fl
—
—
H

^tC₄H₉
H
—
—

5′ -394
Pd
1
5′
Fl
—
—

^tC₄H₉
CH₃
H
pic

5′ -394X
Pd
1
5′
Fl
—
—

^tC₄H₉
CH₃
H
acac

5′ -394Y
Pd
0
5′
Fl
—
—

^tC₄H₉
CH₃
H
—
—

5′ -395
Pd
1
5′
Fl
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -395X
Pd
1
5′
Fl
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -395Y
Pd
0
5′
Fl
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -396
Pd
1
5′
Fl
—
—
CH₃
CH₃
H
pic

5′ -396X
Pd
1
5′
Fl
—
—
CH₃
CH₃
H
acac

5′ -396Y
Pd
0
5′
Fl
—
—
CH₃
CH₃
H
—
—

5′ -397
Pd
1
5′
Fl
—
—
CH₃

^tC₄H₉
H
pic

5′ -397X
Pd
1
5′
Fl
—
—
CH₃

^tC₄H₉
H
acac

5′ -397Y
Pd
0
5′
Fl
—
—
CH₃

^tC₄H₉
H
—
—

5′ -398
Pd
1
5′
Bz
—
—
H
CH₃
H
pic

5′ -398X
Pd
1
5′
Bz
—
—
H
CH₃
H
acac

5′ -398Y
Pd
0
5′
Bz
—
—
H
CH₃
H
—
—

5′ -399
Pd
1
5′
Bz
—
—
H

^tC₄H₉
H
pic

5′ -399X
Pd
1
5′
Bz
—
—
H

^tC₄H₉
H
acac

5′ -399Y
Pd
0
5′
Bz
—
—
H

^tC₄H₉
H
—
—

5′ -400
Pd
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
pic

5′ -400X
Pd
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
acac

5′ -400Y
Pd
0
5′
Bz
—
—

^tC₄H₉
CH₃
H
—
—

5′ -401
Pd
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -401X
Pd
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -401Y
Pd
0
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -402
Pd
1
5′
Bz
—
—
CH₃
CH₃
H
pic

5′ -402X
Pd
1
5′
Bz
—
—
CH₃
CH₃
H
acac

5′ -402Y
Pd
0
5′
Bz
—
—
CH₃
CH₃
H
—
—

5′ -403
Pd
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
pic

5′ -403X
Pd
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
acac

5′ -403Y
Pd
0
5′
Bz
—
—
CH₃

^tC₄H₉
H
—
—

5′ -404
Pd
1
5′
Qu
—
—
H
CH₃
H
pic

5′ -404X
Pd
1
5′
Bz
—
—
H
CH₃
H
acac

5′ -404Y
Pd
0
5′
Bz
—
—
H
CH₃
H
—
—

5′ -405
Pd
1
5′
Bz
—
—
H

^tC₄H₉
H
pic

5′ -405X
Pd
1
5′
Bz
—
—
H

^tC₄H₉
H
acac

5′ -405Y
Pd
0
5′
Bz
—
—
H

^tC₄H₉
H
—
—

5′ -406
Pd
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
pic

5′ -406X
Pd
1
5′
Bz
—
—

^tC₄H₉
CH₃
H
acac

5′ -406Y
Pd
0
5′
Bz
—
—

^tC₄H₉
CH₃
H
—
—

5′ -407
Pd
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
pic

5′ -407X
Pd
1
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
acac

5′ -407Y
Pd
0
5′
Bz
—
—

^tC₄H₉

^tC₄H₉
H
—
—

5′ -408
Pd
1
5′
Bz
—
—
CH₃
CH₃
H
pic

5′ -408X
Pd
1
5′
Bz
—
—
CH₃
CH₃
H
acac

5′ -408Y
Pd
0
5′
Bz
—
—
CH₃
CH₃
H
—
—

5′ -409
Pd
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
pic

5′ -409X
Pd
1
5′
Bz
—
—
CH₃

^tC₄H₉
H
acac

5′ -409Y
Pd
0
5′
Bz
—
—
CH₃

^tC₄H₉
H
—
—

5′ -410
Pd
1
5′
OL
H

ⁿC₄H₉
H
CH₃
H
pic

5′ -410X
Pd
1
5′
OL
H

ⁿC₄H₉
H
CH₃
H
acac

5′ -410Y
Pd
0
5′
OL
H

ⁿC₄H₉
H
CH₃
H
—
—

5′ -411
Pd
1
5′
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
pic

5′ -411X
Pd
1
5′
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
acac

5′ -411Y
Pd
0
5′
OL
H

ⁿC₄H₉
H

^tC₄H₉
H
—
—

5′ -412
Pd
1
5′
OL
H

^tC₄H₉
H
CH₃
H
pic

5′ -412X
Pd
1
5′
OL
H

^tC₄H₉
H
CH₃
H
acac

5′ -412Y
Pd
0
5′
OL
H

^tC₄H₉
H
CH₃
H
—
—

5′ -413
Pd
1
5′
OL
H

^tC₄H₉
H

^tC₄H₉
H
pic

5′ -413X
Pd
1
5′
OL
H

^tC₄H₉
H

^tC₄H₉
H
acac

5′ -413Y
Pd
0
5′
OL
H

^tC₄H₉
H

^tC₄H₉
H
—
—

5′ -414
Pd
1
5′
OL
CH₃

ⁿC₄H₉
H
CH₃
H
pic

5′ -414X
Pd
1
5′
OL
CH₃

ⁿC₄H₉
H
CH₃
H
acac

5′ -414Y
Pd
0
5′
OL
CH₃

ⁿC₄H₉
H
CH₃
H
—
—

5′ -415
Pd
1
5′
OL
CH₃

^tC₄H₉
H
CH₃
H
pic

5′ -415X
Pd
1
5′
OL
CH₃

^tC₄H₉
H
CH₃
H
acac

5′ -415Y
Pd
0
5′
OL
CH₃

^tC₄H₉
H
CH₃
H
—
—

5′ -416
Pd
1
5′
OL
H
H
H
CH₃
H
pic

5′ -416X
Pd
1
5′
OL
H
H
H
CH₃
H
acac

5′ -416Y
Pd
0
5′
OL
H
H
H
CH₃
H
—
—

5′ -417
Pd
1
5′
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
pic

5′ -417X
Pd
1
5′
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
acac

5′ -417Y
Pd
0
5′
OL
H

ⁿC₄H₉
CH₃

^tC₄H₉
H
—
—

5′ -418
Pd
1
5′
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
pic

5′ -418X
Pd
1
5′
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
acac

5′ -418Y
Pd
0
5′
OL
H

^tC₄H₉
CH₃

^tC₄H₉
H
—
—

5′ -419
Pd
1
5′
OL
—CH₂CH₂CH₂—
H
CH₃
H
pic

5′ -419X
Pd
1
5′
OL
—CH₂CH₂CH₂—
H
CH₃
H
acac

5′ -419Y
Pd
0
5′
OL
—CH₂CH₂CH₂—
H
CH₃
H
—
—

5′ -420
Pd
1
5′
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
pic

5′ -420X
Pd
1
5′
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
acac

5′ -420Y
Pd
0
5′
OL
—CH₂CH₂CH₂—
H

^tC₄H₉
H
—
—

embedded image

TABLE 55

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹
L²

6′ -304
Pd
1
6′
Nap1
—
—
CH₃
H
H
pic

6′ -304X
Pd
1
6′
Nap1
—
—
CH₃
H
H
acac

6′ -304Y
Pd
0
6′
Nap1
—
—
CH₃
H
H
—
—

6′ -305
Pd
1
6′
Nap1
—
—

^tC₄H₉
H
H
pic

6′ -305X
Pd
1
6′
Nap1
—
—

^tC₄H₉
H
H
acac

6′ -305Y
Pd
0
6′
Nap1
—
—

^tC₄H₉
H
H
—
—

6′ -306
Pd
1
6′
Nap2
—
—
CH₃
H
H
pic

6′ -306X
Pd
1
6′
Nap2
—
—
CH₃
H
H
acac

6′ -306Y
Pd
0
6′
Nap2
—
—
CH₃
H
H
—
—

6′ -307
Pd
1
6′
Nap2
—
—

^tC₄H₉
H
H
pic

6′ -307X
Pd
1
6′
Nap2
—
—

^tC₄H₉
H
H
acac

6′ -307Y
Pd
0
6′
Nap2
—
—

^tC₄H₉
H
H
—
—

6′ -308
Pd
1
6′
Nap3
—
—
CH₃
H
H
pic

6′ -308X
Pd
1
6′
Nap3
—
—
CH₃
H
H
acac

6′ -308Y
Pd
0
6′
Nap3
—
—
CH₃
H
H
—
—

6′ -309
Pd
1
6′
Nap3
—
—

^tC₄H₉
H
H
pic

6′ -309X
Pd
1
6′
Nap3
—
—

^tC₄H₉
H
H
acac

6′ -309Y
Pd
0
6′
Nap3
—
—

^tC₄H₉
H
H
—
—

6′ -310
Pd
1
6′
TB
—
—
CH₃
H
H
pic

6′ -310X
Pd
1
6′
TB
—
—
CH₃
H
H
acac

6′ -310Y
Pd
0
6′
TB
—
—
CH₃
H
H
—
—

6′ -311
Pd
1
6′
TB
—
—

^tC₄H₉
H
H
pic

6′ -311X
Pd
1
6′
TB
—
—

^tC₄H₉
H
H
acac

6′ -311Y
Pd
0
6′
TB
—
—

^tC₄H₉
H
H
—
—

6′ -312
Pd
1
6′
TF
—
—
CH₃
H
H
pic

6′ -312X
Pd
1
6′
TF
—
—
CH₃
H
H
acac

6′ -312Y
Pd
0
6′
TF
—
—
CH₃
H
H
—
—

6′ -313
Pd
1
6′
TF
—
—

^tC₄H₉
H
H
pic

6′ -313X
Pd
1
6′
TF
—
—

^tC₄H₉
H
H
acac

6′ -313Y
Pd
0
6′
TF
—
—

^tC₄H₉
H
H
—
—

6′ -314
Pd
1
6′
OB
—
—
CH₃
H
H
pic

6′ -314X
Pd
1
6′
OB
—
—
CH₃
H
H
acac

6′ -314Y
Pd
0
6′
OB
—
—
CH₃
H
H
—
—

6′ -315
Pd
1
6′
OB
—
—

^tC₄H₉
H
H
pic

6′ -315X
Pd
1
6′
OB
—
—

^tC₄H₉
H
H
acac

6′ -315Y
Pd
0
6′
OB
—
—

^tC₄H₉
H
H
—
—

6′ -316
Pd
1
6′
Fu
—
—
CH₃
H
H
pic

6′ -316X
Pd
1
6′
Fu
—
—
CH₃
H
H
acac

6′ -316Y
Pd
0
6′
Fu
—
—
CH₃
H
H
—
—

6′ -317
Pd
1
6′
Fu
—
—

^tC₄H₉
H
H
pic

6′ -317X
Pd
1
6′
Fu
—
—

^tC₄H₉
H
H
acac

6′ -317Y
Pd
0
6′
Fu
—
—

^tC₄H₉
H
H
—
—

6′ -318
Pd
1
6′
Fl
—
—
CH₃
H
H
pic

6′ -318X
Pd
1
6′
Fl
—
—
CH₃
H
H
acac

6′ -318Y
Pd
0
6′
Fl
—
—
CH₃
H
H
—
—

6′ -319
Pd
1
6′
Fl
—
—

^tC₄H₉
H
H
pic

6′ -319X
Pd
1
6′
Fl
—
—

^tC₄H₉
H
H
acac

6′ -319Y
Pd
0
6′
Fl
—
—

^tC₄H₉
H
H
—
—

6′ -320
Pd
1
6′
Bz
—
—
CH₃
H
H
pic

6′ -320X
Pd
1
6′
Bz
—
—
CH₃
H
H
acac

6′ -320Y
Pd
0
6′
Bz
—
—
CH₃
H
H
—
—

6′ -321
Pd
1
6′
Bz
—
—

^tC₄H₉
H
H
pic

6′ -321X
Pd
1
6′
Bz
—
—

^tC₄H₉
H
H
acac

6′ -321Y
Pd
0
6′
Bz
—
—

^tC₄H₉
H
H
—
—

6′ -322
Pd
1
6′
Qu
—
—
CH₃
H
H
pic

6′ -322X
Pd
1
6′
Qu
—
—
CH₃
H
H
acac

6′ -322Y
Pd
0
6′
Qu
—
—
CH₃
H
H
—
—

6′ -323
Pd
1
6′
Qu
—
—

^tC₄H₉
H
H
pic

6′ -323X
Pd
1
6′
Qu
—
—

^tC₄H₉
H
H
acac

6′ -323Y
Pd
0
6′
Qu
—
—

^tC₄H₉
H
H
—
—

6′ -324
Pd
1
6′
OL
H

ⁿC₄H₉
CH₃
H
H
pic

6′ -324X
Pd
1
6′
OL
H

ⁿC₄H₉
CH₃
H
H
acac

6′ -324Y
Pd
0
6′
OL
H

ⁿC₄H₉
CH₃
H
H
—
—

6′ -325
Pd
1
6′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
pic

6′ -325X
Pd
1
6′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
acac

6′ -325Y
Pd
0
6′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
—
—

6′ -326
Pd
1
6′
OL
H

^tC₄H₉
CH₃
H
H
pic

6′ -326X
Pd
1
6′
OL
H

^tC₄H₉
CH₃
H
H
acac

6′ -326Y
Pd
0
6′
OL
H

^tC₄H₉
CH₃
H
H
—
—

6′ -327
Pd
1
6′
OL
H

^tC₄H₉

^tC₄H₉
H
H
pic

6′ -327X
Pd
1
6′
OL
H

^tC₄H₉

^tC₄H₉
H
H
acac

6′ -327Y
Pd
0
6′
OL
H

^tC₄H₉

^tC₄H₉
H
H
—
—

6′ -328
Pd
1
6′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
pic

6′ -328X
Pd
1
6′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
acac

6′ -328Y
Pd
0
6′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
—
—

6′ -329
Pd
1
6′
OL
CH₃

^tC₄H₉
CH₃
H
H
pic

6′ -329X
Pd
1
6′
OL
CH₃

^tC₄H₉
CH₃
H
H
acac

6′ -329Y
Pd
0
6′
OL
CH₃

^tC₄H₉
CH₃
H
H
—
—

6′ -330
Pd
1
6′
OL
H
H
CH₃
H
H
pic

6′ -330X
Pd
1
6′
OL
H
H
CH₃
H
H
acac

6′ -330Y
Pd
0
6′
OL
H
H
CH₃
H
H
—
—

6′ -331
Pd
1
6′
OL
—CH₂CH₂CH₂—
CH₃
H
H
pic

6′ -331X
Pd
1
6′
OL
—CH₂CH₂CH₂—
CH₃
H
H
acac

6′ -331Y
Pd
0
6′
OL
—CH₂CH₂CH₂—
CH₃
H
H
—
—

6′ -332
Pd
1
6′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
pic

6′ -332X
Pd
1
6′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
acac

6′ -332Y
Pd
0
6′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
—
—

embedded image

TABLE 56

No.
M
m
BSS
SS G
T¹
T²
T⁵
T⁶
T⁷
L¹
L²

7′ -304
Pd
1
7′
Nap1
—
—
CH₃
H
H
pic

7′ -304X
Pd
1
7′
Nap1
—
—
CH₃
H
H
acac

7′ -304Y
Pd
0
7′
Nap1
—
—
CH₃
H
H
—
—

7′ -305
Pd
1
7′
Nap1
—
—

^tC₄H₉
H
H
pic

7′ -305X
Pd
1
7′
Nap1
—
—

^tC₄H₉
H
H
acac

7′ -305Y
Pd
0
7′
Nap1
—
—

^tC₄H₉
H
H
—
—

7′ -306
Pd
1
7′
Nap2
—
—
CH₃
H
H
pic

7′ -306X
Pd
1
7′
Nap2
—
—
CH₃
H
H
acac

7′ -306Y
Pd
0
7′
Nap2
—
—
CH₃
H
H
—
—

7′ -307
Pd
1
7′
Nap2
—
—

^tC₄H₉
H
H
pic

7′ -307X
Pd
1
7′
Nap2
—
—

^tC₄H₉
H
H
acac

7′ -307Y
Pd
0
7′
Nap2
—
—

^tC₄H₉
H
H
—
—

7′ -308
Pd
1
7′
Nap3
—
—
CH₃
H
H
pic

7′ -308X
Pd
1
7′
Nap3
—
—
CH₃
H
H
acac

7′ -308Y
Pd
0
7′
Nap3
—
—
CH₃
H
H
—
—

7′ -309
Pd
1
7′
Nap3
—
—

^tC₄H₉
H
H
pic

7′ -309X
Pd
1
7′
Nap3
—
—

^tC₄H₉
H
H
acac

7′ -309Y
Pd
0
7′
Nap3
—
—

^tC₄H₉
H
H
—
—

7′ -310
Pd
1
7′
TB
—
—
CH₃
H
H
pic

7′ -310X
Pd
1
7′
TB
—
—
CH₃
H
H
acac

7′ -310Y
Pd
0
7′
TB
—
—
CH₃
H
H
—
—

7′ -311
Pd
1
7′
TB
—
—

^tC₄H₉
H
H
pic

7′ -311X
Pd
1
7′
TB
—
—

^tC₄H₉
H
H
acac

7′ -311Y
Pd
0
7′
TB
—
—

^tC₄H₉
H
H
—
—

7′ -312
Pd
1
7′
TF
—
—
CH₃
H
H
pic

7′ -312X
Pd
1
7′
TF
—
—
CH₃
H
H
acac

7′ -312Y
Pd
0
7′
TF
—
—
CH₃
H
H
—
—

7′ -313
Pd
1
7′
TF
—
—

^tC₄H₉
H
H
pic

7′ -313X
Pd
1
7′
TF
—
—

^tC₄H₉
H
H
acac

7′ -313Y
Pd
0
7′
TF
—
—

^tC₄H₉
H
H
—
—

7′ -314
Pd
1
7′
OB
—
—
CH₃
H
H
pic

7′ -314X
Pd
1
7′
OB
—
—
CH₃
H
H
acac

7′ -314Y
Pd
0
7′
OB
—
—
CH₃
H
H
—
—

7′ -315
Pd
1
7′
OB
—
—

^tC₄H₉
H
H
pic

7′ -315X
Pd
1
7′
OB
—
—

^tC₄H₉
H
H
acac

7′ -315Y
Pd
0
7′
OB
—
—

^tC₄H₉
H
H
—
—

7′ -316
Pd
1
7′
Fu
—
—
CH₃
H
H
pic

7′ -316X
Pd
1
7′
Fu
—
—
CH₃
H
H
acac

7′ -316Y
Pd
0
7′
Fu
—
—
CH₃
H
H
—
—

7′ -317
Pd
1
7′
Fu
—
—

^tC₄H₉
H
H
pic

7′ -317X
Pd
1
7′
Fu
—
—

^tC₄H₉
H
H
acac

7′ -317Y
Pd
0
7′
Fu
—
—

^tC₄H₉
H
H
—
—

7′ -318
Pd
1
7′
Fl
—
—
CH₃
H
H
pic

7′ -318X
Pd
1
7′
Fl
—
—
CH₃
H
H
acac

7′ -318Y
Pd
0
7′
Fl
—
—
CH₃
H
H
—
—

7′ -319
Pd
1
7′
Fl
—
—

^tC₄H₉
H
H
pic

7′ -319X
Pd
1
7′
Fl
—
—

^tC₄H₉
H
H
acac

7′ -319Y
Pd
0
7′
Fl
—
—

^tC₄H₉
H
H
—
—

7′ -320
Pd
1
7′
Bz
—
—
CH₃
H
H
pic

7′ -320X
Pd
1
7′
Bz
—
—
CH₃
H
H
acac

7′ -320Y
Pd
0
7′
Bz
—
—
CH₃
H
H
—
—

7′ -321
Pd
1
7′
Bz
—
—

^tC₄H₉
H
H
pic

7′ -321X
Pd
1
7′
Bz
—
—

^tC₄H₉
H
H
acac

7′ -321Y
Pd
0
7′
Bz
—
—

^tC₄H₉
H
H
—
—

7′ -322
Pd
1
7′
Qu
—
—
CH₃
H
H
pic

7′ -322X
Pd
1
7′
Qu
—
—
CH₃
H
H
acac

7′ -322Y
Pd
0
7′
Qu
—
—
CH₃
H
H
—
—

7′ -323
Pd
1
7′
Qu
—
—

^tC₄H₉
H
H
pic

7′ -323X
Pd
1
7′
Qu
—
—

^tC₄H₉
H
H
acac

7′ -323Y
Pd
0
7′
Qu
—
—

^tC₄H₉
H
H
—
—

7′ -324
Pd
1
7′
OL
H

ⁿC₄H₉
CH₃
H
H
pic

7′ -324X
Pd
1
7′
OL
H

ⁿC₄H₉
CH₃
H
H
acac

7′ -324Y
Pd
0
7′
OL
H

ⁿC₄H₉
CH₃
H
H
—
—

7′ -325
Pd
1
7′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
pic

7′ -325X
Pd
1
7′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
acac

7′ -325Y
Pd
0
7′
OL
H

ⁿC₄H₉

^tC₄H₉
H
H
—
—

7′ -326
Pd
1
7′
OL
H

^tC₄H₉
CH₃
H
H
pic

7′ -326X
Pd
1
7′
OL
H

^tC₄H₉
CH₃
H
H
acac

7′ -326Y
Pd
0
7′
OL
H

^tC₄H₉
CH₃
H
H
—
—

7′ -327
Pd
1
7′
OL
H

^tC₄H₉

^tC₄H₉
H
H
pic

7′ -327X
Pd
1
7′
OL
H

^tC₄H₉

^tC₄H₉
H
H
acac

7′ -327Y
Pd
0
7′
OL
H

^tC₄H₉

^tC₄H₉
H
H
—
—

7′ -328
Pd
1
7′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
pic

7′ -328X
Pd
1
7′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
acac

7′ -328Y
Pd
0
7′
OL
CH₃

ⁿC₄H₉
CH₃
H
H
—
—

7′ -329
Pd
1
7′
OL
CH₃

^tC₄H₉
CH₃
H
H
pic

7′ -329X
Pd
1
7′
OL
CH₃

^tC₄H₉
CH₃
H
H
acac

7′ -329Y
Pd
0
7′
OL
CH₃

^tC₄H₉
CH₃
H
H
—
—

7′ -330
Pd
1
7′
OL
H
H
CH₃
H
H
pic

7′ -330X
Pd
1
7′
OL
H
H
CH₃
H
H
acac

7′ -330Y
Pd
0
7′
OL
H
H
CH₃
H
H
—
—

7′ -331
Pd
1
7′
OL
—CH₂CH₂CH₂—
CH₃
H
H
pic

7′ -331X
Pd
1
7′
OL
—CH₂CH₂CH₂—
CH₃
H
H
acac

7′ -331Y
Pd
0
7′
OL
—CH₂CH₂CH₂—
CH₃
H
H
—
—

7′ -332
Pd
1
7′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
pic

7′ -332X
Pd
1
7′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
acac

7′ -332Y
Pd
0
7′
OL
—CH₂CH₂CH₂—

^tC₄H₉
H
H
—
—

The metal complex compound of the present invention is preferably a material for a light emitting element and in particular, more preferably a material for the organic EL device.

The present invention also provides an organic EL device which comprises at least one organic thin film layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises the above metal complex compound of the present invention, which emits light by applying an electric voltage between the pair of electrode.

With regard to the amount of the metal complex compound of the present invention contained in the organic thin film layer, it is usually 0.1 to 100% by weight, preferably 1 to 30% by weight of total mass of the light emitting layer.

It is preferable for the organic EL device of the present invention that the light emitting layer comprises the metal complex compound of the present invention. Further, the light emitting layer is usually formed to a thin film by means of vapor deposition process or coating process, however, it is preferable that the layer comprising the metal complex compound of the present invention is formed into film by coating process because it simplifies the production process.

In the organic EL device of the present invention, a monolayer-type organic thin layer consists of a light emitting layer, which comprises the metal complex compound of the present invention. Typical examples of the construction of the organic EL device include (an anode/a hole injecting layer (a hole transporting layer)/a light emitting layer/a cathode); (an anode/a light emitting layer/an electron injecting layer (an electron transporting layer)/a cathode); and (an anode/a hole injecting layer (a hole transporting layer)/a light emitting layer/an electron injecting layer (an electron transporting layer)/a cathode).

The anode in the organic EL device covers a role of injecting holes into a hole injecting layer, a hole transporting layer or into a light emitting layer, and as the material for the anode, metals, alloys, metal oxides, electroconductive compounds, or these mixtures may be employable. Specific examples of the material for the anode include electroconductive metal oxides such as tin oxide, zinc oxide, indium oxide, indium tin oxide (ITO), etc.; metals such as gold, silver, chromium, nickel, etc.; mixtures or laminated materials of these electroconductive metal oxide and metals; inorganic electroconductive substance such as copper iodide, copper sulfide, etc.; organic electroconductive materials such as polyaniline, polythiophene, polypyrrole, etc.; and laminated materials of the above materials with ITO; preferably are the electroconductive metal oxides. Particularly, it is preferable to employ ITO from viewpoints such as productivity, enhanced electroconductivity, transparency, etc. Regarding with a film thickness of the anode, it is possible to be appropriately selected depending on the material.

With regard to the cathode, it covers a role of injecting electrons into an electron injecting layer, an electron transporting layer or into a light emitting layer. Specific examples of the material for the cathode include alkali metals (for example, Li, Na, K, etc.) and their fluoride or oxidate, alkaline earth metals (for example, Mg, Ca, etc.) and their fluoride or oxidate, gold, silver, lead, aluminum, sodium-potassium alloy or sodium-potassium mixed metals, lithium-aluminum alloy or lithium-aluminum mixed metals, magnesium-silver alloy or the magnesium-silver mixed metals, or rare earth metals such as indium, ytterbium, etc. Among those, preferable examples are aluminum, lithium-aluminum alloy or lithium-aluminum mixed metals, magnesium-silver alloy or magnesium-silver mixed metals, etc. The cathode may be a monolayer structure of the above material, and may be a laminated structure of the layer containing the above material. For example, the laminated structure such as aluminum/lithium fluoride, aluminum/lithium oxide or the like is preferable. Regarding with a film thickness of the cathode, it is possible to be appropriately selected depending on the material.

It may be appropriate that the hole injecting layer and the hole transporting layer of the organic EL device of the present invention have any function of injecting holes from the anode, transporting holes, or barriering the electrons injected from the cathode. Specific examples include carbazole derivatives, triazole derivatives, oxazole derivatives, oxadiazole derivatives, imidazole derivatives, polyarylalkane derivatives, pyrazoline derivatives, pyrazolone derivatives, phenylenediamine derivatives, arylamine derivatives, amino substituted chalcone derivatives, styryl anthracene derivatives, fluorenone derivatives, hydrazone derivatives, stilbene derivatives, silazane derivatives, aromatic tertiary amine compounds, styryl amine compound, aromaticdimethylidene-based compounds, porphyrin-based compounds, polysilane-based compounds, poly(N-vinyl carbazole) derivatives, aniline-based copolymer; electroconductive polymer oligomer such as thiophene oligomer, polythiophene, etc.; organosilane derivatives, metal complex compound of the present invention, etc. The hole injecting layer and the hole transporting layer may be composed of single layer comprising one or more kind of these hole injecting materials and those hole transporting materials or may be laminated with themselves or a layer comprising another kind of compound.

It may be appropriate that the electron injecting layer and the electron transporting layer of the organic EL device of the present invention have any function of injecting electrons from the cathode, transporting electrons, or barriering the holes injected from the anode. Specific examples include triazole derivatives, oxazole derivatives, oxadiazole derivatives, imidazole derivatives, fluorenone derivatives, anthraquinodimethane derivatives, anthrone derivatives, diphenylchinone derivatives, thiopyrandioxide derivatives, carbodiimide derivatives, fluorenylidene methane derivatives, distyrylpyrazine derivatives; aromatic ring tetracarboxylic acid anhydride such as naphthalene, perylene, etc.; phthalocyanine derivatives, various metal complexes represented by metal complexes of 8-quinolinol derivatives or metal complexes having benzoxazole or benzothiazole as ligand; organosilane derivatives, metal complex compound of the present invention, etc. The electron injecting layer may be composed of single layer comprising one or more kind of these electron injecting materials or may be laminated with an electron injecting layer comprising another kind of compound.

It is preferable that the light emitting layer in the organic EL device of the present invention has functions capable of injecting holes from the anode or the hole injecting layer when an electric field is applied, of injecting electrons from the cathode or the electron injecting layer, of mobilizing the injected electric charges (electrons and holes) by means of the electric field, and of providing a space for recombination of the electrons and holes thereby urging the light emission. It is preferable for the organic EL device of the present invention that the light emitting layer at least comprises the metal complex compound of the present invention, and it may comprise a host material which employs the metal complex compound as a guest material. Examples of the above host material include such as those having a carbazole skeleton, those having a diarylamine skeleton, those having a pyridine skeleton, those having a pyrazine skeleton, those having a triazine skeleton, those having an arylsilane skeleton, etc. It is preferable that T1 (energy level in the minimum triplet excitation state) of the host material is larger than T1 level of the guest material. The host material may be either a low molecular weight compound or a high molecular weight compound. Further, the light emitting layer in which the above light emitting materials are doped into the above host materials can be formed by co-deposition of the host materials and the light emitting materials such as the above metal complex compound, etc.

In the organic EL device of the present invention, although a process for forming each layers are not particularly specified, various kinds of process such as a vacuum deposition process, a LB process, a resistance heating deposition process, an electron beam process, a sputtering process, a molecular lamination process, a coating process (a spin coating process, a casting process, a dip coating process), an ink-jet process, a printing process are employable and the coating process of applying the materials over a substrate is preferable in the present invention.

In the above coating process, preparing a coating solution by dissolving the metal complex compound of the present invention into a solvent, and by applying the coating solution over the surface of a predetermined layer (or, electrode), followed by drying may form the organic thin film layer. In the coating solution, a resin may be contained either by dissolved in a solvent or by dispersing into the solvent. Regarding with the resin, both non-conjugate high polymer (for example, polyvinylcarbazole) and conjugate high polymer (for example, polyolefin-based high polymer) are employable. Specific examples include polyvinylchloride, polycarbonate, polystyrene, polymethyl methacrylate, poly butylmethacrylate, polyester, polysulfone, polyphenylene oxide, polybutadiene, poly(N-vinyl carbazole), hydrocarbon resin, ketone resin, phenoxy resin, polyamide, ethyl cellulose, vinyl acetate, ABS resin, polyurethane, melamine resin, unsaturated polyester resin, alkyd resin, epoxide resin, silicone resin, etc.

EXAMPLES

The present invention will be described in more detail by reference to the following examples. However, it should be noted that these examples are only illustrative and not intended to limit the invention thereto.

Example 1
Synthesis of Metal Complex Compound 1-1

The route for synthesis of Metal complex Compound 1-1 is illustrated as the following.

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In the above route, the structural formula of Intermediate 1-1a expresses a dimer configuration.

(1) Synthesis of Intermediate 1-1b

Placing 2-aminopyridine in an amount of 3.5 g (36 mmol), α-bromoacetophenone in an amount of 7.2 g (36 mmol) and sodium hydrogen carbonate in an amount of 3.6 g (43 mmol) into a flask, the resultant mixture reacted among 120 milliliter of ethanol for 4 hours at the room temperature and subsequently for 2 hours under refluxing. Separating insoluble by filtration, the resultant filtrate was concentrated. Extracting with the use of methylene chloride in an amount of 150 milliliter, the resultant extract was washed three times using 200 milliliter of water. After drying an organic layer with the use of magnesium sulfide and removing the solvent, brown crystals were obtained. Refining the crystals by means of silicagel column (hexane/methylene chloride), 6.3 g of 2-phenylimidazo[1,2-a]pyridine Intermediate 1-1b as white crystals was obtained (yield: 90%). The white crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 7.8-8.3 (m, 4H), δ 7.0-8.3 (m, 5H), δ 0.6-6.9 (m, 1H)

(2) Synthesis of Intermediate 1-1a

Placing Intermediate 1-1b in an amount of 5.0 g (25.7 mmol) and IrCl₃hydrate (available from Strem Chemicals, Inc.) in an amount of 1.9 g (6.4 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 2-ethoxyethanol in an amount of 40 milliliter, the resultant mixture was reacted for 15 hours under refluxing. A resultant yellow precipitation was separated by filtration, followed by washing twice with the use of ethanol in an amount of 5 milliliter. Further, it was dissolved in 150 milliliter of methylene chloride, and the resultant solution was washed with the use of HCl aqueous solution, followed by washing three times with the use of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and as a result, 1.39 g of Intermediate 1-1a as yellow crystals was obtained (yield: 35%).

(3) Synthesis of Metal Complex Compound 1-1

Placing Intermediate 1-1a in an amount of 1.39 g (1.13 mmol) and 2-pyridinecarboxylic acid in an amount of 0.55 g (4.52 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 1,2-dichloroethane in an amount of 20 milliliter, the resultant mixture was reacted for 17 hours under refluxing. Separating the resultant yellow precipitation, dissolving the precipitation into 400 milliliter of methylene chloride, it was washed three times using 150 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and then, washing the resultant mixture with using a small amount of methylene chloride, 0.85 g of Metal complex Compound 1-1 as yellow crystals was obtained (yield: 54%). The yellow crystals were confirmed as the aimed compound from ¹H-NMR spectrum and from the result in accordance with Field Desorption Mass Spectrum (FD-MS) analysis. The measurement result is shown as follows:

FD-MS: m/z=701

Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal complex Compound 1-1, it was found that λ max (wave length of peak light emission intensity) of phosphorus light was 580 nm.

Example 2
Synthesis of Metal Complex Compound 1-2

The route of synthesis of Metal complex Compound 1-2 is illustrated in the following.

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In the above route, the structural formula of Intermediate 1-1a expresses a dimer configuration.

(1) Synthesis of Intermediate 1-2c

While cooling acetic acid solution prepared by dissolving 25 g (160.1 mmol) of 2,4-difluorophenyl acetophenone in an amount of 50 milliliter down to 10° C. or cooler, 25.5 g (160.1 mmol) of bromine was dripped and the resultant solution reacted for 7 hours. Throwing the resultant solution into 300 milliliter of water, the solution was extracted with the use of methylene chloride. After drying an organic layer with the use of magnesium sulfide, the solvent was removed. Refining the resultant residues by means of silica column (hexane), 23.4 g of α-bromo-2,4-difluorophenyl acetophenone Intermediate 1-2c as brown oil was obtained (yield: 62%). The brown oil was confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 7.87-8.14 (m, 1H), δ 6.8-7.13 (m, 2H), δ 4.49 (d, 2H)

(2) Synthesis of Intermediate Product 1-2b

Placing 2-aminopyridine in an amount of 3.3 g (35.5 mmol), Intermediate 1-2c in an amount of 8.4 g (35.5 mmol) and sodium hydrogen carbonate in an amount of 3.6 g (43 mmol) into a flask, the resultant mixture reacted among 120 milliliter of ethanol for 4 hours at the room temperature and subsequently for 2 hours under refluxing. Separating insolubles by filtration, the resultant filtrate was concentrated. Extracting with the use of dichloromethane in an amount of 150 milliliter, the resultant extract was washed three times using 200 milliliter of water. After drying an organic layer with the use of magnesium sulfide and removing the solvent, brown crystals were obtained. Refining the crystals by means of silicagel column (hexane/methylene chloride), 7.3 g of 2-(2′,4′-difluorophenyl)imidazo[1,2-a]pyridine Intermediate 1-2b was obtained (yield: 89%). The brown crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 7.9-8.45 (m, 3H), δ 7.5-7.7 (m, 1H), δ 6.7-7.28 (m, 4H)

(3) Synthesis of Intermediate 1-2a

Placing Intermediate 1-2b in an amount of 4.7 g (20.6 mmol) and IrCl₃hydrate (available from Strem Chemicals, Inc.) in an amount of 1.53 g (5.1 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 2-ethoxyethanol in an amount of 25 milliliter, the resultant mixture was reacted for 15 hours under refluxing. A resultant pale yellow precipitation was separated by filtration, followed by washing twice with the use of ethanol in an amount of 5 milliliter. Further, it was dissolved in 150 milliliter of methylene chloride, and the resultant solution was washed three times with the use of HCl aqueous solution, followed by washing twice with the use of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and as a result, 1.39 g of Intermediate 1-2a as yellow crystals was obtained (yield: 35%).

(4) Synthesis of Metal Complex Compound 1-2

Placing Intermediate 1-2a in an amount of 1.39 g (1.13 mmol) and 2-picolinic acid in an amount of 0.55 g (4.52 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 20 milliliter of 1,2-dichloroethane into the resultant solution, it was reacted for 17 hours under refluxing. Separating the resultant yellow precipitation, dissolving the precipitation into 400 milliliter of methylene chloride, it was washed three times using 150 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and then, washing the resultant mixture using a small amount of methylene chloride, 0.85 g of Metal complex Compound 1-2 as yellow crystals was obtained (yield: 54%). The yellow crystals were confirmed as the aimed compound from ¹H-NMR spectrum and from the result in accordance with FD-MS analysis. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 7.84-8.30 (m, 7H), δ 7.2-7.47 (m, 2H), δ 6.7-7.0 (m, 3H), δ 6.2-6.6 (m, 2H), δ 5.44-5.88 (m, 4H)

FD-MS: m/z=773

Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal complex Compound 1-2, it was found that λ max of phosphorus light was 529 nm.

Example 3
Synthesis of Metal Complex Compound 6-1

The route for synthesis of Metal complex Compound 6-1 is illustrated in the following.

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In the above route, the structural formula of Intermediate 6-1a expresses a dimer configuration.

(1) Synthesis of Intermediate 6-1b

Placing 2-phenylimidazole in an amount of 8.6 g (60 mmol) into a flask having a dropping funnel, and after replacing the atmosphere with argon gas, 180 milliliter of tetrahydrofuran was added. Under cooling with ice, n-butyllithium of 1.56 mol/liter in an amount of 39.1 milliliter (61 mmol) was dripped down into the solution spending 30 minutes and subsequently, 8.6 g (61 mmol) of methyl iodide dissolved into 10 milliliter of tetrahydrofuran was dripped down. After termination of dripping down, the resultant solution was reacted at the room temperature for 3 hours. Concentrating the reacted solution and extracting the resultant solid using 150 milliliter of methylene chloride, it was washed three times using 150 milliliter of water. After drying an organic layer with the use of magnesium sulfate, the solvent was removed. Refining the crystals by means of silicagel column (hexane/methylene chloride), 6.1 g of 1-methyl-2-phenylimidazo Intermediate6-1b as white crystals was obtained (yield: 69%). The white crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 7.29-7.67 (m, 5H), δ 6.93-7.10 (m, 2H), δ 3.69 (s, 3H)

(2) Synthesis of Intermediate 6-1a

Placing Intermediate 6-1b in an amount of 4.1 g (26.2 mmol) and IrCl₃hydrate (available from Strem Chemicals, Inc.) in an amount of 1.95 g (6.5 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 2-ethoxyethanol in an amount of 30 milliliter, the resultant mixture was reacted for 11 hours under refluxing. A resultant yellow precipitation was separated by filtration, followed by washing twice with the use of ethanol in an amount of 5 milliliter. Further, it was dissolved in 600 milliliter of methylene chloride, and the resultant solution was washed three times using 200 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and as a result, 1.35 g of Intermediate 6-1a as pale yellow crystals was obtained (yield: 38%). The pale yellow crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CD₂Cl₂): δ 7.26-7.42 (m, 2H), δ 6.47-6.94 (m, 3H), δ 6.0-6.09 (m, 1H), δ 4.13 (s, 3H)

(3) Synthesis of Metal Complex Compound 6-1

Placing Intermediate 6-1a in an amount of 1.32 g (1.21 mmol) and 2-picolinic acid in an amount of 0.59 g (4.87 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 15 milliliter of 1,2-dichloroethane into the resultant solution, it was reacted for 8 hours under refluxing. Separating the resultant yellow precipitation, dissolving the precipitation into 200 milliliter of methylene chloride, it was washed 4 times using 150 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and further, re-crystallized from methylene chloride/hexane. As a result 1.17 g of Metal complex Compound 6-1 as yellow crystals was obtained (yield: 78%). The yellow crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 8.1-8.2 (m, 1H), δ 7.75-7.90 (m, 2H), δ 7.2-7.51 (m, 3H), δ 6.3-7.0 (m, 9H), δ 6.13 (d, 1H), δ 4.06 (s, 3H)

Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal complex Compound 6-1, it was found that λ max of phosphorus light was 562 nm:

Comparative Example 1

Placing 4-phenylimidazole in an amount of 3.8 g (26.3 mmol) and IrCl₃hydrate (available from Strem Chemicals, Inc.) in an amount of 1.96 g (6.6 mmol) into a flask, the atmosphere was replaced with argon gas. Adding 30 milliliter of 2-ethoxyethanol, the resultant solution reacted for 18 hours under refluxing and as a result, a homogeneous blackish brown solution was prepared without any precipitate. Distillating the solvent away, the resultant solution was processed and a black solid was obtained, however, it was not identified as an aimed Ir metal complex compound (Q below). Comparing with Example 3, when a hydrogen atom exists at N position of imidazole as illustrated below, it was understood that any substituent such as a methyl group is necessary because synthesizing Ir complex is difficult.

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Example 4
Synthesis of Metal Complex Compound 7-1

The route for synthesis of Metal complex Compound 7-1 is illustrated in the following.

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In the above route, the structural formula of Intermediate 7-1a expresses a dimer configuration.

(1) Synthesis of Intermediate 7-1b

Placing 2-phenylimidazole in an amount of 8.9 g (60.8 mmol) into a flask having a dropping funnel, and after replacing the atmosphere with argon gas, 210 milliliter of tetrahydrofuran was added. Under cooling with ice, n-butyllithium of 1.56 mol/liter in an amount of 39.3 milliliter (61.2 mmol) was dripped down into the solution spending 30 minutes and subsequently, 8.7 g (61.3 mmol) of methyl iodide dissolved into 10 milliliter of tetrahydrofuran was dripped down. After termination of dripping down, the resultant solution was reacted at the room temperature for 3 hours. Concentrating the reacted solution and extracting the resultant solid using 150 milliliter of methylene chloride, it was washed three times using 150 milliliter of water. After drying an organic layer with the use of magnesium sulfate, the solvent was removed. Refining the crystals by means of silicagel column (hexane/methylene chloride), 8.0 g of 1-methyl-2-phenylimidazo Intermediate 7-1b as white crystals was obtained (yield: 83%). The white crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (CDCl₃): δ 7.33-7.60 (m, 5H), δ 3.27-3.98 (m, 4H), δ 2.76 (s, 3H)

(2) Synthesis of Intermediate 7-1a

Placing Intermediate 7-1b in an amount of 4.4 g (27.5 mmol) and IrCl₃hydrate (available from Strem Chemicals, Inc.) in an amount of 2.1 g (6.9 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 30 milliliter of 2-ethoxyethanol into the resultant solution, it was reacted for 16 hours under refluxing. A resultant yellow precipitation was separated by filtration, followed by washing twice with the use of ethanol in an amount of 5 milliliter. Further, it was dissolved in 200 milliliter of methylene chloride, and the resultant solution was washed 4 times using 200 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and as a result, 2.1 g of Intermediate 7-1a as orange crystals was obtained (yield: 57%). The orange crystals were confirmed as the aimed compound from ¹H-NMR spectrum. The measurement result is shown as follows:

¹H-NMR (DMSO-d₆): δ 7.51-7.61 (m, 1H), δ 6.69-6.97 (m, 3H), δ 3.60-4.1 (m, 4H), δ 3.33 (s, 3H)

(3) Synthesis of Metal Complex Compound 7-1

Placing Intermediate 7-1a in an amount of 1.95 g (1.78 mmol) and 2-picolinic acid in an amount of 0.88 g (7.14 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 20 milliliter of 1,2-dichloroethane into the resultant solution, it was reacted for 17 hours under refluxing. Removing the solvent from the reacted solution and dissolving the resultant brown solid using 150 milliliter of methylene chloride, it was washed 5 times using 200 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and further, refined by means of silica column (methylene chloride/hexane). Intermediate 7-1 as brown crystals in an amount of 1.2 g was obtained (yield: 53%). It was confirmed in accordance with FD-MS that the brown crystals were the aimed compound. The measurement result is shown as follows:

FD-MS: m/z=632

Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal complex Compound 7-1, it was found that λ max of phosphorus light was 562 nm

Example 5
Synthesis of Metal Complex Compound 5-1

The route for synthesis of Metal complex Compound 5-1 is illustrated in the following.

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(1) Synthesis of Intermediate 5-1b

Placing 4-phenylimidazole in an amount of 9.6 g (67 mmol) into a flask having a dropping funnel, and after replacing the atmosphere with argon gas, 50 milliliter of dimethylsulfoxide was added. Adding 2.8 g (60% in oil, 70 mmol equivalent) of NaH little by little into the solution and after achieving the addition of entire amount, the resultant solution was heated for 2 hours at a temperature of 80° C. Subsequently, 9.6 g (68 mmol) of methyl iodide dissolved into 15 milliliter of methylsulfoxide was dripped down and the resultant solution was heated again for further 15 hours at the temperature of 80° C.

Throwing the resultant solution into 200 milliliter of water, the solution was extracted using 200 milliliter of ethylene chloride. After separating an organic layer, it was washed 5 times using 200 milliliter of water, and it was dried with the use of magnesium sulfate. After concentrating the solution, refining the resultant pale brown solids by means of silicagel column (methylene chloride), 5.5 g of 1-methyl-4-phenylimidazo Intermediate 5-1b as white crystals was obtained (yield: 52%).

(2) Synthesis of Intermediate 5-1a

Placing Intermediate 5-1b in an amount of 3.0 g (18.9 mmol) and IrCl₃hydrate (available from Strem Chemicals, Inc.) in an amount of 1.41 g (4.7 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 15 milliliter of 2-ethoxyethanol into the resultant solution, it was reacted for 13 hours under refluxing. A resultant white precipitation was separated by filtration, followed by washing twice with the use of ethanol in an amount of 5 milliliter. Further, it was dissolved in 500 milliliter of methylene chloride, and the resultant solution was washed 3 times using 150 milliliter of water. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and as a result, 1.77 g of Intermediate 5-1a as white crystals was obtained (yield: 69%).

(3) Synthesis of Metal Complex Compound 5-1

Placing Intermediate 5-1a in an amount of 1.38 g (1.27 mmol) and 2-picolinic acid in an amount of 0.62 g (5.1 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 20 milliliter of 1,2-dichloroethane into the resultant solution, it was reacted for 12 hours under refluxing. Separating the resultant yellow precipitation, dissolving the precipitation into 300 milliliter of methylene chloride, it was washed 4 times using 200 milliliter of water. After drying the solution with the use of magnesium sulfate, the solvent was distillated away. Resultant yellow crystals were refined with silicagel column (methylene chloride/methanol). Intermediate 5-1 as pale yellow crystals in an amount of 0.4 g was obtained (yield: 26%).

Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal complex Compound 5-1, it was found that λ max of phosphorus light was 453 nm.

Example 6
Fabrication of Organic EL Device

A glass substrate of 25 mm×75 mm×1.1 mm thickness having an ITO transparent electrode was cleaned by application of ultrasonic wave in isopropyl alcohol for 5 minutes and then by exposure to ozone generated by ultraviolet light for 30 minutes. The cleaned substrate having the transparent electrode lines was attached to a substrate holder, and on the surface of the cleaned substrate at the side having the transparent electrode, a film of 4,4′-bis[N-(4-biphenyl)-N-(4-biphenyl)amino]biphenyl below having a thickness of 40 nm was formed so that the formed film covered the transparent electrode. The formed film worked as the hole transporting layer. Further, a host material (CBP) below together with adding a photo luminescent Ir-Metal Complex Compound 1-1 as a dopant were vapor deposited obtaining a film thickness of 30 nm on the formed film. The formed film worked as a light emitting layer. A concentration of Compound 1-1 in the light emitting layer was 5% by weight. On the light emitting layer, a film of (1,1-bisphenyl)-4-olate)bis(2-methyl-8-quinolinolato) aluminum (BAlq) below having a thickness of 10 nm was formed. The formed film of BAlq worked as the hole barrier layer. On the film formed above, a film of aluminum complex of 8-hydroxyquinoline (Alq) having a thickness of 30 nm was formed. The film of Alq worked as the electron injecting layer. Subsequently, lithium fluoride (LiF) being alkali metal halide was vapor deposited up to 0.15 nm in thickness and then, aluminum was vapor deposited up to 150 nm in thickness. The Al/LiF worked as a cathode.

An organic EL device was fabricated in the manner described above. The device fabricated above was examined by feeding electric current. Yellowish green light was emitted at a luminance of 103 cd/m²under a voltage of 6.7 V and a current density of 2.79 mA/cm². The CIE chromaticity coordinates were (0.347, 0.494), and the current efficiency was 3.7 cd/A. Additionally, λ max of light emission was 533 nm.

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4,4′-bis[N-(4-biphenyl)-N-(4-biphenyl)amino]biphenyl

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INDUSTRIAL APPLICABILITY

As described above in detail, the organic EL device employing the novel metal complex compound of the present invention emits various phosphorous light including blue light having an enhanced current efficiency and prolonged lifetime. Accordingly, the present invention is applicable for a field such as various display devices, display panels, backlights, illuminating light sources, beacon lights, signboards, and interior designs, particularly suitable as display device for color displays.

Number	Name	Date	Kind
4923638	Ohno et al.	May 1990	A
5182186	Inagaki et al.	Jan 1993	A
6656612	Okada et al.	Dec 2003	B2
6687266	Ma et al.	Feb 2004	B1
6822118	Jalett et al.	Nov 2004	B1
6933673	Yamazaki	Aug 2005	B2
7667228	Okuda et al.	Feb 2010	B2
20020094453	Takiguchi et al.	Jul 2002	A1
20020100906	Takiguchi et al.	Aug 2002	A1
20040056244	Marcus et al.	Mar 2004	A1
20040131881	Zheng et al.	Jul 2004	A1
20060083947	Ikeda et al.	Apr 2006	A1

Number	Date	Country
1726606	Jan 2006	CN
1 486 552	Dec 2004	EP
2003-109758	Apr 2003	JP
WO 0215645	Feb 2002	WO
WO 0245466	Jun 2002	WO
WO 2004045002	May 2004	WO
WO 2006098120	Sep 2006	WO

	Number	Date	Country
Parent	10565274		US
Child	12656892		US

Metal complex compound and organic electroluminescent device using same

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