The present invention relates to a metal gasket interposed, e.g., between a cylinder block and a cylinder head of an internal combustion engine.
In an internal combustion engine, a metal gasket is interposed on a joint surface between a cylinder block and a cylinder head and fastened, thereby imparting a sealing function. In particular, sealing in an area surrounding a cylinder port is important, and insufficient sealing in this portion causes a pressure drop in a combustion chamber and overheat. Consequently, as a metal gasket enhanced in sealing performance, a metal gasket constituted so that a thin metal plate is arranged and laminated between a pair of elastic metal substrates having beads concentric with cylinder ports, the thin metal plate having an opening corresponding to the above-mentioned cylinder ports (for example, see reference 1).
In the metal gasket of the reference 1, the sealing function in a peripheral portion surrounding the cylinder port is enhanced by utilizing repulsion of the bead generated at the time when the metal gasket is fastened with a bolt. However, casting holes (i.e., minute cavities on a surface due to bubbles developed in casting, see
On the other hand, it is also carried out that a foamed rubber layer is formed on a metal gasket to enhance sealing performance (e.g., see references 2 and 3). Although the foamed rubber layer in the references generally exhibits excellent sealing properties in such a case that casting holes having a diameter of 1.5 mm or less exist on a surface to be sealed, or the surface roughness thereof is 12.5 Ra or less (10-point average roughness according to JIS B0601-1994), in such a case that the diameter of the casting holes exceed 1.5 mm or the surface roughness exceeds 12.5 Ra, the foamed rubber layer does not secure sufficient sealing properties in some cases. Further, it is generally difficult to achieve foaming (particularly with a foaming factor of 2 or more) when a thickness of a rubber layer before foaming is not lower than about 70 μm. Further, the rubber layer before foaming of the metal gasket with the foamed rubber layer is relatively thick, the foamed rubber layer deteriorates under the conditions of a high temperature and a high pressure to result in a reduction in axial force of a bolt. In order to obtain the foamed rubber layer, a micro-encapsulation and a heat decomposition method using a chemical foaming agent are generally employed. Since a foamed rubber layer obtained by the micro-encapsulation has a low foaming factor, such foamed rubber layer has a lower effect for sealing casting holes. Also, since many of cells of the foamed rubber layer are separately closed (hereinafter referred to as “closed cells”), shrinkage of each of the cells is caused at a low temperature (lower than 0° C.), thereby causing a reduction in axial force of a bolt. Further, when a sealing surface pressure is insufficient, the foamed rubber layer does not perfectly crush to cause the foamed rubber layer to deteriorate during use, thereby undesirably resulting in a stress relaxation of a bolt. In addition, the temperature around the cylinder port becomes considerably high, so that the foamed rubber layer is thermally deteriorated in a relatively early stage to cause deterioration of sealing performance in some cases.
Here, a “foaming factor” means a ratio of the thickness of a rubber layer after foaming to that before foaming.
The invention has been made in view of the above-mentioned problems, and an object of the invention is to provide a metal gasket whose foamed rubber layer is not deteriorate under high temperature and pressure and does not shrink at low temperature, and which can sufficiently seal even a cylinder block having large casting holes or high surface roughness.
The present inventors have made eager investigation to examine the problem. As a result, it has been found that the foregoing objects can be achieved with the following metal gaskets. With this finding, the present invention is accomplished.
The present invention is mainly directed to the following items:
(1) A metal gasket disposed between a cylinder head and a cylinder block, which comprises: a thin metal plate having first opening; first elastic metal substrate; second elastic metal substrate; and at least one foamed rubber layer, wherein each of the first and second elastic metal substrates have second opening and a bead formed on a peripheral portion of the second opening, wherein the thin metal plate is disposed between the beads of the first and second elastic metal substrates, wherein the at least one foamed rubber layer is provided by a process comprising foaming a pre-foamed layer comprising a pre-foamed composition, and wherein the pre-foamed layer has a thickness of 15 to 50 μm and a foaming factor of 2 to 4.
(2) The metal gasket according to item 1, wherein the pre-foamed composition comprises: 20 to 70% by weight of a polymer having a mooney value of 10 to 70; 20 to 60% by weight of a heat decomposable chemical foaming agent, based on the total weight of the composition, and wherein the foamed rubber layer has an open cell ratio of 80% or more.
(3) The metal gasket according to item 1, wherein the first elastic metal substrate, which is disposed so as to face the cylinder block, has the foamed rubber layers disposed on both sides thereof.
(4) The metal gasket according to item 1, which further comprises an unfoamed rubber layer, wherein the first elastic metal substrate, which is disposed so as to face the cylinder block, has first surface that faces to the cylinder block and second surface opposite to the first surface, wherein the first elastic metal substrate has the foamed rubber layer disposed on the first surface and the unfoamed rubber layer disposed on the second surface.
(5) The metal gasket according to item 1, which further comprises third elastic metal substrate and unfoamed rubber layers, wherein each of the first and second elastic metal substrates have the unfoamed rubber layers disposed on both sides thereof, wherein the third elastic metal substrate comprises: third opening capable of accommodating the first elastic metal substrate; a bead formed on a peripheral portion of the third opening; and the foamed lubber layers disposed on both sides thereof, wherein the first elastic metal substrate is fixed to the third elastic metal substrates with plural connecting members.
(6) The metal gasket according to item 1, wherein the bead has a flection comprising a curved portion having a curvature radius of 0.5 mm or more in a cross-sectional surface perpendicular to the circumferential direction of the bead, wherein the first elastic metal substrate, which is disposed so as to face the cylinder block, has first surface that faces to the cylinder block and second surface opposite to the first surface, wherein the first elastic metal substrate has the foamed rubber layer disposed on the first surface.
In the present invention, open cells mean cells that intercommunicate each other. Furthermore, an “open cell ratio” means a ratio of the volume of open cells to the volume of total cells in a foamed rubber layer.
The invention will be described in detail below.
A metal gasket of the present invention is a metal gasket disposed between a cylinder head and a cylinder block, which comprises: a thin metal plate having opening; a pair of elastic metal substrates; at least one foamed rubber layer, wherein each of the pair of elastic metal substrates have opening and a bead formed on a peripheral portion of the opening, wherein the thin metal plate was disposed between the beads of the pair of elastic metal substrate, and wherein the at least one foamed rubber layer is provided by a process comprising foaming a pre-foamed layer comprising a pre-foamed composition, wherein the pre-foamed layer has a thickness of 15 to 50 μm and a foaming factor of 2 to 4. Thereby, it is possible to provide a metal gasket whose foamed rubber layer is not deteriorate under high temperature and pressure and does not shrink at low temperature, and which can sufficiently seal even a cylinder block having large casting holes or high surface roughness.
A pre-foamed composition used for forming the foamed rubber layer preferably contains 20 to 70 wt %, based on the total weight of the pre-foamed composition, of a polymer having a mooney value of 10 to 70. More preferably, the mooney value is 20 to 60, and the content is 20 to 60 wt % based on the total weight of the pre-foamed composition. By using such polymer, it is possible to effectively prevent a deterioration of the foamed rubber layer.
The polymer is not limited in type as far as the mooney value is in the above-described range. Examples thereof include those that have heretofore been used for gaskets, such as an NBR, an HNBR, a fluororubber, an EPDM, and an acrylic rubber. It is preferable to use the NBR, HNBR, and the fluororubber. Also, in the case of using the NBR, it is preferable that a content of acrylonitrile group in NBR (hereinafter referred to as an “AN value”) is from 39 to 52, more preferably from 40 to 48, for the purpose of imparting an oil resistance.
Further, the pre-foamed composition preferably contains a heat decomposable chemical foaming agent. Although the heat decomposable foaming agent is not limited, it is preferable that a foaming temperature thereof is 120° C. or more, more preferably from 150 to 210° C. An amount of the foaming agent in the pre-foamed composition is preferably from 20 to 60 wt %, more preferably from 15 to 35 wt %, based on the total weight of the pre-foamed composition.
Further, a vulcanizing agent and a vulcanization accelerator is preferably added to the pre-foamed composition. The vulcanizing agent is preferably added in a large amount so as to achieve a high vulcanization density. In the case of sulfur vulcanization, the vulcanizing agent is preferably used at 1.5 to 4.5 phr. It is preferable to use the vulcanization accelerator which enables rapid vulcanization, i.e., which provides a time period required for reaching to T50 in Curast data at 150° C. of four minutes or less. A time period required for reaching to T50 in Curast data at 150° C. means a time period that a rubber requires to reach T50 when vulcanization is done at 150° C.
The above pre-foamed composition is dissolved into an organic solvent to obtain a coating liquid which is applied on the steel plate to obtain a pre-foamed layer. The organic solvent is not limited as far as it dissolves the pre-foamed composition. An example thereof is a mixed solvent of 10 to 90 wt % of an aromatic hydrocarbon-based (or ketone-based) solvent such as toluene and 10 to 90 wt % of an ester-based solvent. The pre-foamed composition is dissolved into the organic solvent in such a way that a solid concentration thereof is preferably 10 to 60 wt % based on the weight of the coating liquid.
Although a method of applying the coating liquid containing the pre-foamed composition is not particularly limited, it is preferable to employ a method that enables to control a thickness of the pre-foamed layer. Examples thereof include a coating method using a gap coater or a roll coater. The coating thickness is preferably from 15 to 50 μm, and the foaming agent is foamed by a heat treatment at preferably about 150 to 240° C. for 5 to 15 minutes to form the foamed rubber layer. The foaming conditions such as the vulcanizing agent, the foaming agent, and the heating time are suitably adjusted so that the pre-foamed layer has a foaming factor of from 2 to 4, and the foamed rubber layer to be obtained has an open cell ratio of 80% or more. It is possible to control the foaming factor by using the polymer having the above-described mooney value and adding the vulcanizing agent and the foaming agent to the polymer at the above-described proportion. Particularly, the foaming factor depends on the mooney value of the polymer and the vulcanization speed. When the mooney value of the polymer is too low, the polymer is expanded too much by a foaming gas. When the mooney value is too high, the expansion of the polymer by the foaming gas is suppressed. When the vulcanizing speed is too high, the vulcanization progresses before the polymer is expanded by the foaming gas to suppress the foaming factor. When the vulcanization speed is too low, the polymer is expanded by the foaming gas before the rubber is cured by the vulcanization to increase the foaming factor. For instance, when a polymer having a mooney value of 20 to 40 is used in combination with a vulcanization accelerator of a low vulcanizing speed (Curast data: a time period required for reaching to T50 at 150° C. is about 5 to 6 minutes) and a foaming agent of a low decomposition temperature, the foaming factor is increased. On the other hand, when a polymer having a mooney value of 40 to 60 is used in combination with a vulcanization accelerator of a high vulcanizing speed (Curast data: a time period required for reaching to T50 at 150° C. is about 1 to 3 minutes) and a foaming agent of a high decomposition temperature, the foaming factor is reduced. Thus, the foaming factor is controlled by changing the combination of the polymer, the vulcanization accelerator, and the foaming agent.
In the present invention, the thin metal plate preferably has a thickness of 0.05 to 0.15 mm. The thin metal plate is preferably made of a stainless steel.
Such a foamed rubber layer is inhibited in deterioration even under high temperature and pressure, and maintains good sealing properties for a long period of time. Further, the foamed rubber layer is inhibited in shrinkage at low temperature. Furthermore, even when a casting hole having a diameter exceeding 1.5 mm exists on the surface of the cylinder block or the surface roughness thereof exceeds 12.5 Ra, sufficient sealing properties can be maintained.
Examples of several embodiments of the present invention are now illustrated, but it should be understood that the present invention is not to be construed as being limited thereto.
A plane view showing one embodiment of a metal gasket of this embodiment is shown in
The thin metal plate B1 is constituted so as to be integrally connected at adjacent portions. In that case, the thin metal plate is fixed to one elastic metal substrate A12 at a plurality of metal sites (indicated by reference numeral 16, 4 portions in an example shown in
In this embodiment, the elastic metal substrate A12, which is located at a cylinder block side (i.e., an lower side in
Further, as described above, the foamed rubber layer 110 is particularly effective for sealing properties to the casting holes or roughened surface of the cylinder block or cylinder head. However, there is a fear that permanent set occurs by pressure contact with the thin metal plate B to gradually deteriorate the sealing performance. Consequently, as shown in
As another embodiment, a partially cutaway plane view showing one embodiment of a metal gasket of the invention is shown in
The thin metal plate B2 has a plane shape in which rings having openings corresponding to the cylinder ports 21 are connected. The first elastic metal substrate A21 has openings corresponding to the cylinder ports 21 of the thin metal plate B2, and beads 22 are formed on peripheral portions of the openings. Further, unfoamed rubber layers 211 are formed on both surfaces thereof. The second elastic metal substrate A22 has openings corresponding to the cylinder ports 21 of the thin metal plate B, and beads 22 are formed on peripheral portions of the openings. Further, unfoamed rubber layers 211 are formed on both surfaces thereof. The third elastic metal substrate A23 has openings capable of accommodating the first elastic metal substrate, and beads are formed on peripheral portions of the openings. Further, foamed rubber layers 210 are formed on both surfaces thereof.
The third elastic metal substrate A23 is in point contact with the first elastic metal substrate A21 through the connecting members 28, so that the amount of heat transfer from the cylinder ports 21 is small. Further, a hole for allowing cooling water to flow is opened in the third elastic metal substrate A23, which also contributes to a cooling effect. Accordingly, thermal deterioration of the foamed rubber layer 210 does not occur. Furthermore, the cylinder ports 21 are formed in the first elastic metal substrate A21 and the second first elastic metal substrate A22, and the unfoamed rubber layers 211 are foamed to high temperature. However, the unfoamed rubber layers 211 are high in heat resistance, so that practically, no problem arises at all. In the invention, there is no limitation on the unfoamed rubber layer 211, but for such a reason, one excellent in heat resistance is preferably used.
As shown in
When the flection C4 of the bead is bent so as to have a corner portion that does not have a curved portion, as shown in
The present invention is now illustrated in greater detail with reference to Examples and Comparative Examples, but it should be understood that the present invention is not to be construed as being limited thereto.
Each of compositions containing a polymer, a foaming agent, a vulcanizing agent and a vulcanization accelerator as shown in Table 1 was dissolved into an organic solvent containing toluene and ethyl acetate to prepare a coating liquid in such a way that the solid concentration of the composition in each of the coating liquids was 40 wt % based on the weight of the coating liquid. Each of the coating liquids was applied with a roll coater on a stainless steel that has been applied a non-chromate treatment and a primer treatment to obtain a pre-foamed layer (see Table 1 for thickness of the each pre-foamed layer), and then a heat treatment was performed at 210° C. for 10 minutes to obtain samples 1-10 each having a foamed rubber layer. Evaluations of the samples were conducted as follows.
Note 1:
Polymers (A) used in Samples 1-3 and 8-10 are manufactured by ZEON Corporation. Polymers (A) used in Samples 2, 4-7 are manufactured by JSR Corporation
Note 2:
Foaming agents (B) used in Samples 1-8 and 10 are manufactured by SANKO KASEI Co., Ltd. Foaming agents (B) used in Samples 5 and 9 are manufactured by Matsumoto Yushi-Seiyaku Co., Ltd.
Note 3:
Sulfurs used in Samples 1-10 are manufactured by Tsurumi Chemical Corporation.
Note 4:
Vulcanization accelerators used in Samples 1-10 are manufactured by Ouchishinko Chemical Industrial Co., Ltd.
The foaming factor was calculated from a thickness of a pre-foamed layer and a thickness of a foamed rubber layer using the following formula (the thicknesses thereof were measured by using a micrometer).
(Thickness of foamed rubber layer/Thickness of pre-foamed layer)=Foaming factor
Each of the samples was soaked into water and then subjected to a vacuum degassing to replace the air in cells in the foamed rubber layer with water. The test was conducted until a weight after the replacement with water became constant, and an open cell ratio was calculated by using the following formula.
Weight of replaced water/(Volume of foamed rubber layer−Volume of pre-foamed layer)×100=Open cell ratio
The samples were subjected to a test under the conditions of a surface pressure of 100 MPa at 150° C. for 22 hours, and appearances after the test were observed with a microscope to evaluate the appearance based on the following criteria.
A: without rubber flow
B: with rubber flow
Each of the samples was subjected to a test to measure a torque down rate as follows.
(1) Each of the samples was fastened to a flange with a bolt by a torque wrench to measure an initial torque.
(2) In the state of (1) mentioned above, the sample was cooled to −35° C., and a mark was appended to the flange and the bolt by appending the mark at a position of a contact surface thereof, and then the bolt was unfastened.
(3) Each of the samples was re-fastened to the marked flange with the marked bolt by a torque wrench, in such a manner that marks of the flange and the bolt was aligned, to measure a torque at −35° C.
The initial torque (at an ordinary temperature) of each of the samples was compared with the torque at −35° C., and torque down rate was calculated by using the following formula.
[Initial torque−(Torque at −35° C.)]/Initial torque×100=Torque down rate
Gaskets of Examples 1 to 3 and Comparative Examples 1 to 7, having a shape as shown in the following Tables 2 and 3, were prepared by using above-mentioned Samples 1 to 10. Then, each of the gaskets of Examples and Comparative Examples were set on the flange having a shape shown in Tables 2 and 3, and the gaskets were subjected to the following tests to evaluate the gaskets by the following criteria.
A: without leakage of air
B: with leakage of air
(1) As shown in
(2) In the state of (1), air (200 kPa) was supplied to the flange through a nozzle at the center of the flange to measure an amount of leaked air.
(1) Each of the samples was processed to obtain a gasket having a half bead shape of a height of 0.2 mm and a width of 1.5 mm and a half bead center diameter of 51.5 mm. The gasket was set on a flange having a surface roughness of 50 Ra so that a casting hole was located at a position of the half bead center and then fastened to the flange at a bead linear load of 10 N/mm.
(2) In the state of (1), air (200 kPa) was supplied to the flange through a nozzle at the center of the flange to measure an amount of leaked air.
Results of the foregoing measurements and experiments are shown in the following Table 4.
From Table 4, it is apparent that the gasket of Examples each having the foamed rubber layer according to the present invention are capable of achieving satisfactory results in terms of heat resistance flowability, torque down, and sealing test. In contrast, the gasket of Comparative Example 1 which has the excessive thickness of the pre-foamed layer has the bad heat resistance flowability and the inferior torque down. The gasket of Comparative Example 2 which was prepared by using the microcapsule type foaming agent has the small open cell ratio and the inferior torque down. The gasket of Comparative Example 4 of the excessive mooney value has the low foaming factor and the inferior sealing property. The gasket of Comparative Example 5 prepared by using the excessively small amount of foaming agent has the low foaming factor and the inferior sealing property. The gasket of Comparative Example 6 prepared by using the excessively small amount of polymer has the small amount of open cell ratio, the worst torque down, and the inferior heat resistance flowability. Since the gasket of Comparative Example 7 which was prepared by using the microcapsule type foaming agent has the excessively thickness of the pre-foamed layer, the gasket has the worst foaming factor, the smallest open cell ratio, and the inferior sealing property.
As shown above, according to the present invention, a metal gasket whose foamed rubber layer is not deteriorate under high temperature and pressure and does not shrink at low temperature, and which can sufficiently seal even a cylinder block having large casting holes or high surface roughness is obtained.
While the present invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing the spirit and scope thereof.
The present application is based on Japanese Patent Application No. 2004-100006 filed on Mar. 30, 2004, No. 2004-102172 filed on Mar. 31, 2004 and No. 2004-102178 filed on Mar. 31, 2004, and the contents thereof are incorporated herein by reference.
Number | Date | Country | Kind |
---|---|---|---|
P. 2004-100006 | Mar 2004 | JP | national |
P. 2004-102172 | Mar 2004 | JP | national |
P. 2004-102178 | Mar 2004 | JP | national |