The present invention relates to a system for containing liquid or semiliquid metal material, for example aluminum, zinc, magnesium or any metal alloy, during an operation of casting, preferably flat, metal products, for example strips, according to the technology commonly known as Twin Roll Casting, or according to other alternative casting technologies using two casting members to define the flat metal product.
The technology commonly known as Twin Roll Casting is a well-known technology, in use since the middle of the 20th century to manufacture solid metal semi-finished products starting from liquid material. This technology is used to mainly manufacture flat strips but can also be adapted to be used for long products such as billets, bars or the like, because it allows increased productivity for thin formats (thickness or diameter generally up to 10 mm) and because such shapes can be cast at a high speed with the Twin Roll Casting as compared to other casting technologies. Another advantage of Twin Roll Casting is that of allowing the size of thin and small formats of the semi-finished products to be similar to the shape of the final product, thus decreasing the shaping work (rolling, drawing) in the processes downstream and contributing to obtaining a final product which is cheap and manufactured in large quantities.
Various materials can be used for Twin Roll Casting, such as ferrous alloys and non-ferrous alloys, or pure metals.
In the conventional steel casting configuration, Twin Roll Casting is actuated by a two-high stand with cooled horizontal rolls arranged parallel and placed side-by-side, with the axes thereof lying on a common horizontal plane; whereas the two cooled horizontal rolls for casting aluminum, magnesium, zinc and/or the alloys thereof, are placed one above the other, for example with the axes thereof lying on a common vertical plane or on a common plane which is inclined with respect to the vertical. The space defined by the casting rolls is fed by means of a discharger which brings the liquid metal material in contact with the cooled rolls to start solidification. The discharger is assisted, in its operation of sending and containing the material, by side barriers or edge dams which prevent the lateral spreading of the liquid or semiliquid material prior to the complete solidification thereof and which can be part of the discharger itself or separate components. Generally, the discharger is fed by a system of channels and furnaces that are different according to the material to be cast and the features thereof. Generally, the liquid material is conveyed by gravity or by using pumping means, and the channels are to be made of a material which has both isolating properties—to prevent drops in temperature and undesired local solidification of the material—and an adequate mechanical resistance in order to ensure the structural integrity and chemical compatibility with the alloy in the liquid state.
One of the most critical problems in casting a metal strip is the lateral spreading of the liquid material, which is caused by the edge working conditions and by the solidification parameters.
Generally, with increased casting loads, flow conditions of the liquid and low casting speed can promote a privileged cooling in the edges of the strip so that the results are a partial lateral spreading of the strip, an improved dimensional control and decreased risk of leaks. However, this generates worse local quality of the strip and the need for the side part of the strip to be trimmed.
The working conditions can be changed in order to have more uniform casting conditions even on the sides, but this can result in the risk of increased side leaks of the liquid material, which sticks to the casting roll and damages the equipment, thus also inducing the process to stop. This could be avoided by improving—by means of mechanical barriers—the side containment of the strip prior to solidification, but there are certain limitations from a technical viewpoint to obtain these results.
Indeed, the mechanical side containment systems, or mechanical edge dams, are not to be made of materials capable of reacting with the liquid material coming out of the casting device and, if they are made of isolating materials, they are not capable of effectively containing the material. Moreover, such materials must not excessively resist the rolls to avoid sliding damage to the rolls due to accidental contact. Generally, in order to meet these requirements, such materials preferably are soft materials such as, for example, oxide refractory materials. Moreover, when the casting load decreases, there is a need to ensure an effective side containment also in points which are rather distant from the discharger outlet, in a position which is close to the outlet of the roll bite, i.e., the point of minimum distance between the casting rolls, and this requires using very long and very thin edge dams. The materials mentioned above do not allow achieving the required geometries of the edge dam or operating with the geometries required without incurring the yielding of the edge dam itself or damage to the surface of the casting roll. Instead, by using alternative materials such as steel or metals to construct the edge dams, a gluing effect of the liquid metal material, for example aluminum or alloys thereof, is obtained in addition to a quick wear caused by phenomena of chemical reactions, corrosion and/or abrasion, thus risking damaging the surface of the casting rolls.
Thus, the need is felt to provide a containment system capable of overcoming the stated drawbacks.
It is an object of the present invention to provide a system for laterally containing liquid metal material, in particular aluminum or magnesium or zinc or a metal alloy based on one of these metals, in a casting of, preferably flat, metal products, said system being capable of improving performance in terms of both containing the liquid metal material at any casting load and extending the side containment region, while simultaneously avoiding the direct contact of the side containment device with the liquid metal material.
The system of the invention can be applied to a casting carried out according to the technology commonly known as Twin Roll Casting, or according to alternative casting technologies which use two casting members to define the flat metal product.
It is another object of the present invention to provide a containment system which is flexible, thus allowing various widths of metal product to be cast without the need to replace the casting members.
The present invention achieves at least one of such objects, and other objects which will become apparent in light of the present description, by means of a containment system for laterally containing an at least partially liquid metal material at an open side end of a passage defined between two casting members, said system comprising a feeding device for feeding at least one compressed aeriform substance,
Another aspect of the invention relates to a casting machine for casting metal material products, comprising:
A further aspect of the invention relates to a casting process for casting metal material products, carried out by the aforesaid casting machine, the process comprising the following stages:
In this description, reference is made by way of example to Twin Roll Casting technology, which uses two counter-rotating rolls as casting members.
The solution of the invention consists in providing a barrier consisting of a compressed aeriform substance capable of containing the edge of the flat metal product, for example a strip, during the solidification process by applying a force on said edge so as to push the liquid metal material towards the middle of the strip and avoid side spreading or leaks of the molten material.
The principle of the invention is based on the use of a feeding device of at least one compressed aeriform substance, possibly partially shaped so as to be positioned very close to the casting machine rolls, on the side where the material enters into the rolls or on the side where the material exits from the rolls, or also on the side of the flanks of the rolls themselves. Such a feeding device is configured to blow the at least one compressed aeriform substance, for example air or inert gas, into the space between the rolls, from one side towards the middle. This compressed aeriform substance has the dual effect of cooling the liquid material on the edge of the strip, thus locally accelerating solidification, and of applying a mechanical containment action to prevent the liquid material from spreading.
There are many advantages to such a solution.
Firstly, the mechanical action is applied while avoiding contact between the liquid metal material and any other material, thus avoiding any chemical reaction, corrosion or wear.
More in detail, the solution of the invention does not provide any direct contact either between the hollow end element and any surface of the casting rolls, or between the hollow end element and the liquid metal material.
In particular, a distance other than zero is always provided between the hollow end element and any surface of the casting rolls both when the hollow end element is completely external to the casting rolls and when it is at least partially inserted between said casting rolls, for example with a wedge shape thereof.
The at least one blowing face of the hollow end element applies the containment action of the metal material exclusively by blowing the compressed aeriform substance, without providing any contact thereof with the material being solidified, in order to prevent the lateral escape of the material from the rolls.
Moreover, a further advantage is that the containment action can be applied to any point between the rolls which instead, in the prior art, cannot be achieved by any physical barrier due to the limited space. For example, the jets of air or inert gas can be oriented towards the middle of the roll bite, also for very low casting thicknesses. Indeed, in this case, a physical barrier cannot be interposed between the rolls very close to the roll bite due to the limited gap imposed by the final thickness of the cast product, for example a strip.
Finally, a considerable advantage of the blowing action is the possibility of sealing any gap between the rolls even if the roll position is changed, without any adjustment being required. For example, the solution of the invention continues to work in the case of software-controlled roll position and of an unexpected change in the load set due to casting conditions which could determine occasional roll movements.
The containment system of the invention can generate more concentrated or diffused jets according to the geometry thereof so as to distribute the containment action by adequately adjusting it to the operating conditions and minimizing the consumption of air or inert gas. Moreover, the pressure and mechanical thrust action of the insufflated gas can be regulated to compensate for the different metallostatic pressure of the molten material.
The pneumatic system or edge dam solution of the invention also allows meeting the following requirements:
Further features and advantages of the invention will become more apparent in light of the detailed description of exemplary but not exclusive embodiments.
The dependent claims describe particular embodiments of the invention.
In the description of the invention reference is made to the accompanying drawings, which are provided by way of non-limiting example, in which:
The same elements or components are indicated by the same reference numerals in the drawings.
The containment system of the invention can be applied to a casting carried out according to the technology commonly known as Twin Roll Casting, or according to alternative casting technologies which use two casting members to define the flat metal product.
For example, this alternative casting technology can be one of the following:
In this detailed description, reference is made by way of example to Twin Roll Casting technology, which uses two counter-rotating rolls as casting members.
In the version shown in
It is sufficient to use a single containment system if it is necessary to laterally contain the liquid metal material only at one of the two side ends of said passage.
The feeding means, which are known per se, comprise:
Moving means (not shown) for moving the first containment system 1 and/or the second containment system 1′ can be provided in order to adjust the distance from each other along a direction parallel to the plane containing the rotation axes of the two casting rolls 20, 21. Such moving means can, for example, be linear actuators, such as hydraulic, pneumatic, mechanical actuators, combinations thereof or the like.
This allows different widths of metal product to be cast, for example strips, without the need to replace the casting rolls. The passage from one size to the other of strip to be produced only requires laterally displacing at least one of the two side containment systems 1, 1′ with respect to the casting rolls 20, 21 along said direction. This also applies in case of a single containment system.
Therefore, width—which is fixed—of the casting rolls being equal, the side containment system can be moved so as to define different widths of the strip to be cast, and therefore there is no need to have dedicated roll sets as in the prior art, in which the containment system cannot be laterally moved and therefore, the casting rolls need to be changed each time strips of different widths are cast.
The containment systems 1, 1′ in
In another variant, one or two containment systems can be provided on both the metal material inlet side and the metal material outlet side.
In all the embodiments of the invention, each side containment system 1, 1′ of the material being cast, at the respective open side end of the passage defined between the two casting rolls 20, 21, comprises (
The hollow end element 3 can at least partially have a wedge shape so that it can be possibly inserted, at least partially, between the two casting rolls at an open side end of the passage.
As an alternative to the wedge shape, the hollow end element 3 can have the shape of a rectangular or pyramidal parallelepiped, or any other shape adapted to position said hollow element close to the passage defined between the two casting rolls, said hollow end element 3 being possibly at least partially inserted between the two casting rolls at an open side end of the passage.
In the example in the drawings, the hollow end element 3 is wedge-shaped.
Preferably, each feeding device 2, and therefore the respective hollow end element 3, is positioned laterally and in an outer position, for example an entirely outer position, with respect to the zone occupied by discharger 35.
The hollow end element 3 defines therein at least one chamber 4, for example a single chamber, as shown in the non-limiting variant in
The feeding device 2 is configured to feed at least one compressed aeriform substance, such as air or inert gas, inside the at least one chamber 4.
Advantageously, the hollow end element 3 is provided with at least one blowing face for blowing the compressed aeriform substance from said at least one chamber 4 towards a side containment zone for the metal material being cast between the casting rolls 20, 21.
As shown in the non-limiting example in
Moving means 40 for moving the hollow end element 3 of one or both the containment systems 1, 1′ can be provided in order to adjust the distance from each other along a direction parallel to the plane containing the rotation axes of the two casting rolls 20, 21.
For example, one moving means 40 is provided for each containment system 1, 1′.
In particular, the moving means 40 is configured to move the support arm 24 of the hollow end element 3 along a direction parallel to the plane containing the rotation axes of the two casting rolls 20, 21.
Such a moving means 40 can, for example be a linear actuator, such as a hydraulic, pneumatic or mechanical actuator. Preferably, the at least one blowing face is provided with a plurality of through holes communicating with the at least one chamber 4, or is made of a porous matrix material to ensure the release of jets of air or inert gas.
In all the embodiments of the invention, the hollow end element 3 comprises a first outer surface 10 adapted to face towards the side containment zone and comprising the at least one blowing face.
Preferably, the hollow end element 3 also comprises:
In a non-limiting example, the hollow end element 3 at least partially has a wedge shape which is suitable for possibly being inserted between the two casting rolls. Here, the third outer surface 8 and the fourth outer surface 9 define the wedge shape of the hollow end element 3 (
The third surface 8 and the fourth surface 9 can be flat or curvilinear, or partially flat and partially curvilinear, and converge towards a center plane Z of the hollow element 3 so as to define the wedge shape.
In case of curvilinear or partially curvilinear surfaces 8 and 9, the radius of curvature thereof substantially is equal to the outer radius of the corresponding casting roll.
By way of mere example, during the operation of the containment system of the invention, the minimum distance between the hollow end element 3 and the casting rolls 20, 21, that is the minimum distance between the surfaces 8, 9 and the corresponding casting roll, is about 0.5 to 2 mm, for example about 1 mm. Preferably, the distance between hollow end element 3 and the edge of the liquid metal material is about 8 to 12 mm, for example 10 mm.
In a variant of the hollow end element 3, the at least one inlet hole 5 can be provided in a fifth surface 16 (
In the example in
Preferably, the third surface 8 and the fourth surface 9 are symmetrically arranged with respect to a center plane Z of the hollow element 3.
Advantageously, in all the embodiments of the invention, the hollow end element 3 can be made in a single piece by means of a 3D printer, preferably of a material selected from the following: graphite, calcium silicate, copper, bronze.
Alternatively, the hollow end element 3 can be made of several pieces, also of different material from one another.
For example, the piece or component comprising the at least one blowing face, or the pieces or components comprising a respective blowing face, can be made of a porous matrix material, for example sintered bronze or a ceramic foam, or be defined by a woven metal filament, or in which said matrix is obtained with additive manufacturing technologies.
Preferably, but not necessarily, the feeding device 2 can be a pneumatic device or any device adapted to compress and feed an aeriform substance.
In a first embodiment of the hollow end element 3, the first surface 10 is provided with two or more blowing faces, that are non-coplanar to each other, for differently orienting the flow of the aeriform substance towards the containment zone. This configuration allows blowing jets of air or inert gas in at least two directions, and therefore towards at least two different zones of the space enclosed between the two casting rolls, for an improved side containment of the liquid metal material and/or an increased extension of the containment region.
For example, the through holes of each blowing face are mutually parallel and inclined by an angle other than zero with respect to the through holes of the other blowing faces.
Preferably, a number of chambers 4 inside the hollow end element 3 can be provided which is equal to the number of blowing faces, each chamber feeding a respective blowing face.
In the variants shown in
A first variant of said first embodiment, shown in
The blowing face 6 defines a plane X, and the blowing face 7, which preferably is adjacent to the blowing face 6, defines a plane Y incident to plane X.
The blowing face 6 is distal from the pointed end 25 of the hollow end element 3, while the blowing face 7 is proximal to said pointed end.
For example, the blowing face 6 is flat and rectangular-shaped, preferably elongated, while the blowing face 7 is flat and triangular-shaped, preferably shaped as an isosceles triangle, with the base of the isosceles triangle preferably adjacent to one of the two smaller sides of the rectangular shape of the blowing face 6.
The center plane Z divides the two blowing faces 6, 7 into two equal parts.
When the containment system is mounted at an open side end of the passage defined between the two counter-rotating casting rolls 20, 21, the blowing face 6 is arranged perpendicularly to a metal material feeding plane, and the blowing face 7 has a first end, which is proximal to both the blowing face 6 and the side containment zone, and a second end which is distal from both the blowing face 6 and said side containment zone.
In other words, as the blowing face 7 approaches the roll bite, it diverges with respect to a center plane of the casting rolls which is perpendicular to the plane containing both rotation axes of said casting rolls. Therefore, considering the feeding direction of the metal material, the blowing face 7 diverges with respect to the edge of the metal material entering between the casting rolls if the system is arranged on the side where the material enters between the rolls, or converges with respect to the edge of the metal material exiting from the casting rolls if the system is arranged on the side where the material exits from the rolls. Instead, the blowing face 6 is substantially parallel to said edge. This configuration allows blowing jets of air or inert gas directed towards the edge of the material, also towards an innermost zone which is proximal to the roll bite, in the space between the two casting rolls, for an increased side containment in a zone which is difficult for the mechanical barriers of the prior art to access.
In the example in
The through holes 14 can be mutually parallel and inclined with respect to the mutually parallel through holes 15, for example by an acute angle, preferably between 5° and 45°, more preferably between 100 and 35°. Arrows A and B in
As an alternative to the through holes, the blowing faces 6, 7 can be made of a porous matrix material.
A second variant of said first embodiment, shown in
In addition to the two blowing faces 6, 7 of the first variant, this second variant provides two side blowing faces 12 adjacent to the blowing face 6 and symmetrically arranged with respect to the center plane Z of the hollow end element 3 which divides both the blowing face 6 and the blowing face 7 into two equal parts.
When the containment system is mounted at an open side end of the passage defined between the two casting rolls, the two blowing faces 12 have a respective first end which is proximal to the blowing face 6 but distal from the side containment zone, with respect to a respective second end thereof which is distal from the blowing face 6 but proximal to the side containment zone.
In other words, each blowing face 12 defines a respective plane incident and adjacent to plane X of the blowing face 6 and, starting from plane X, diverges with respect to the center plane Z so as to allow blowing additional jets of air or inert gas converging, for example both from the top and from the bottom in case of a horizontal casting machine, towards the feeding plane of the metal material, in particular towards the edge of the metal material during the casting step for an increased side containment of liquid metal.
In particular, the side blowing faces 12 and the central blowing face 6 define a groove of the first surface 10.
By way of mere example, the blowing faces 12 are flat and rectangular or trapezoidal in shape, preferably in the shape of a rectangular trapeze, with the largest base of the rectangular trapeze preferably adjacent to one of the two larger sides of the rectangular shape of the blowing face 6.
In the example in
The through holes 14 can be mutually parallel and inclined with respect to the mutually parallel through holes 15, for example by an acute angle, preferably between 5° and 45°, more preferably between 100 and 35°.
The through holes 17 can also be mutually parallel and inclined with respect to the through holes 14, for example by an acute angle, preferably between 5° and 45°, more preferably between 100 and 35°. However, the axes of the through holes 17 of the blowing faces 12 are skewed with respect to the axes of the through holes 15 of the blowing face 7.
As an alternative to the through holes, the blowing faces 6, 7, 12 can be made of a porous matrix material.
A third variant of said first embodiment, shown in
In addition to the two blowing faces 6, 7 of the first variant, this third variant provides two side blowing faces 13 adjacent to the blowing face 7 and symmetrically arranged with respect to the center plane Z of the hollow end element 3 which divides both the blowing face 6 and the blowing face 7 into two equal parts.
When the containment system is mounted at an open side end of the passage defined between the two casting rolls, the two blowing faces 13 have a respective first end which is proximal both to the blowing face 7 and to the side containment zone, with respect to a respective second end thereof which is distal both from the blowing face 7 and from the side containment zone.
In other words, each blowing face 13 defines a respective plane incident and adjacent to plane Y of the blowing face 7 and, starting from plane Y, diverges with respect to the center plane Z so that the two blowing faces 13 face one towards the casting roll 20 and the other towards the casting roll 21, and therefore not facing towards the feeding plane of the metal material. This allows blowing additional jets of air or inert gas directed against the casting roll 20 and the casting roll 21 so that the same casting rolls confine the air in the space delimited therebetween, thus determining a zone with increased pressure in front of the edge of the product being cast, thus further decreasing the spreading of liquid metal in the proximity of the roll bite.
By way of mere example, the blowing faces 13 are flat and rectangular- or trapezoidal-shaped, preferably with the smallest base of the trapeze adjacent to one of the two equal sides of the isosceles triangle of the blowing face 7.
In the example in
The through holes 14 can be mutually parallel and inclined with respect to the mutually parallel through holes 15, for example by an acute angle, preferably between 5° and 45°, more preferably between 100 and 35°.
The through holes 18 can be mutually parallel and inclined with respect to the through holes 15, for example by an acute angle, preferably between 5° and 45°, more preferably between 100 and 35°.
Preferably, the axes of the through holes 18 of the blowing faces 13 are skewed with respect to the axes of the through holes 14 of the blowing face 6.
As an alternative to the through holes, the blowing faces 6, 7, 13 can be made of a porous matrix material.
A fourth variant of said first embodiment, shown in
In addition to the two blowing faces 6, 7 of the first variant, this fourth variant provides both the two additional blowing faces 13 provided in the third variant and the two additional blowing faces 12 provided in the second variant.
A fifth variant of said first embodiment, shown in
The central blowing face 6 defines a first plane X and the two side blowing faces 12′ are adjacent to the blowing face 6 and symmetrically arranged with respect to the center plane Z of the hollow end element 3 which divides the blowing face 6 into two equal parts.
When the containment system is mounted at an open side end of the passage defined between the two casting rolls, the two blowing faces 12′ have a respective first end which is proximal to the blowing face 6′ but distal from the side containment zone, with respect to a respective second end thereof which is distal from the first blowing face 6 but proximal to the side containment zone.
In other words, each blowing face 12′ defines a respective plane incident and adjacent to plane X of the blowing face 6′ and, starting from plane X, diverges with respect to the center plane Z so as to allow blowing additional jets of air or inert gas converging, for example both from the top and from the bottom in case of a horizontal casting machine, towards the feeding plane of the metal material, in particular towards the edge of the metal material during the casting step for an increased side containment of liquid metal.
In particular, the side blowing faces 12′ and the central blowing face 6′ define a groove of the first surface 10.
For example, the central blowing face 6′ is flat and triangular-shaped, preferably the shape of an isosceles triangle, and the blowing faces 12′ are flat and rectangular or trapezoidal in shape, with a side adjacent to one of the equal sides of the isosceles triangle shape of the blowing face 6′.
In the example in
The through holes 17′ of each side blowing face 12′ can be mutually parallel and inclined with respect to the through holes 14′, for example by an acute angle, preferably between 5° and 45°, more preferably between 100 and 35°.
As an alternative to the through holes, the blowing faces 6′, 12′ can be made of a porous matrix material.
In a second embodiment of the hollow end element 3, the first surface 10 is provided with a single blowing face in which two or more groups of through holes are provided, preferably of various sizes, each group being differently oriented from the other groups to differently orient the flow of the aeriform substance towards the containment zone. This configuration allows blowing jets of air or inert gas directed towards the edge of the material in at least two directions, and therefore towards at least two different zones of the space enclosed between the two casting rolls, for an improved side containment and an increased extension of the containment region.
For example, the through holes of each group are mutually parallel and inclined by an angle other than zero with respect to the through holes of the other groups.
Preferably, one, two or also more than two chambers 4 are provided inside the hollow end element 3.
In the variants shown in
A first variant of said second embodiment, shown in
The central blowing face 6 is a flat or curvilinear face.
When the containment system is mounted at an open side end of the passage defined between the two counter-rotating casting rolls, the blowing face 6, if it is flat, is arranged perpendicularly to a metal material feeding plane.
Instead, in the case of a curvilinear face, as it approaches the roll bite, said face diverges with respect to a center plane of the casting rolls which is perpendicular to the plane containing both rotation axes of said casting rolls. Therefore, considering the feeding direction of the metal material, the blowing face 6 diverges with respect to the edge of the metal material entering between the casting rolls if the system is arranged on the side where the material enters between the rolls, or converges with respect to the edge of the metal material exiting from the casting rolls if the system is arranged on the side where the material exits from the rolls. This configuration allows blowing jets of air or inert gas directed towards the edge of the material, also towards an innermost zone which is proximal to the roll bite, in the space between the two casting rolls, for an increased side containment in a zone which is difficult for the mechanical barriers of the prior art to access.
In the example in
The center plane Z divides the blowing face 6 into two equal parts.
In the example in
Two or more groups of through holes 14 can be provided, for example of various size, each group of holes having a different orientation or inclination from the other groups to differently orient the flow of the aeriform substance towards the containment zone. Thereby, differently oriented jets of air or inert gas can be obtained in a similar manner to the jets obtained with the various variants of the first embodiment which provides two or more blowing faces.
A second variant of said second embodiment, shown in
A third and fourth variant of said second embodiment, shown in
The surface 10 is provided with two or more groups of through holes, preferably of various sizes, each group being differently oriented from the other groups to differently orient the flow of the aeriform substance towards the containment zone.
For example, two or more groups of through holes can be provided, each group of holes having a different orientation or inclination with respect to the other groups to obtain differently oriented jets of air or inert gas in a similar manner to the jets obtained with the various variants of the first embodiment which provides two or more blowing faces.
In the example in
In the example in
In all the variants shown above (
A solidification process of a liquid metal material by means of a casting machine is shown in
The containment system of the invention in any one of the embodiments thereof can be used in particular to manipulate the liquid metal or liquid metal alloy by applying a pressure along the sump depth 39 (
The containment system of the invention can also be used downstream of the outlet passage 38 to contain liquid metal material still present at the outlet from the casting rolls.
Number | Date | Country | Kind |
---|---|---|---|
102021000003029 | Feb 2021 | IT | national |
This application claims priority to PCT International Application No. PCT/IB2022/051187 filed on Feb. 10, 2022, which applications claims priority to Italian Patent Application No. 102021000003029 filed on Feb. 11, 2021, the entire disclosures of which are expressly incorporated herein by reference. Not Applicable
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/IB2022/051187 | 2/10/2022 | WO |