The present invention is related to a metal oxide transistor having a channel region formed of a metal oxide semiconductor, and in particular, is related to a metal oxide transistor that can be used as a non-volatile storage element.
Currently, eFUSE type elements shown in Patent Document 1 and insulation breakdown type elements shown in Patent Document 2 are known as storage elements that can be used as ROM (read only memory).
The memory element described in Patent Document 1 has a layered structure that is the same as the wiring structure used in a typical logic LSI process including a polysilicon layer, a silicide layer, and a silicon nitride film layer. In addition, the memory element is formed as a resistor having two terminals: a cathode and an anode. This resistor is heated by applying a large electric current thereto, causing the atoms in the metal wiring material to migrate in the direction of the current flow or melting the resistor so as to cause a disconnection therein, thereby changing the resistance between the two terminals. Other examples include those in which the resistance is changed by disconnecting the wiring line by radiating laser or the like onto the resistor instead of applying a large current.
The memory element (antifuse) described in Patent document 2 includes a MOS transistor and writing is performed thereon by applying a strong electric field to the gate insulating film to cause a breakdown in the insulator.
As another example, Patent Document 3 discloses an element that is a transistor element having a drain electrode and a source electrode that are disposed on an insulating film with a gap therebetween, a physical property transformation layer formed on an insulating film in an area between the drain electrode and the source electrode, a high dielectric film that is stacked on the physical property transformation layer, and a gate electrode formed on the high dielectric film. If the voltage applied to the gate electrode is 0V and the voltage between the drain electrode and the source electrode exceeds the first threshold voltage, then the resistance of the physical property transformation layer is decreased and the physical property transformation layer becomes conductive. On the other hand, if a voltage that is greater than 0V is applied to the gate electrode, because a channel is formed in the lower layer of the physical property transformation layer, if the voltage between the drain electrode and the source electrode is greater than a second threshold voltage that is smaller than the first threshold voltage, the physical property transformation layer becomes conductive. Therefore, by setting the voltage between the drain electrode and the source electrode to be between the first threshold voltage and the second threshold voltage, the transistor element can be used as a switching element that switches between conductive and non-conductive states through the application of gate voltage.
Additionally, Patent Document 4 discloses a variable resistor that is a three terminal type variable resistor having first and second electrodes, a variable resistor that is electrically connected to both the first and second electrodes, and a control electrode facing the variable resistor through a dielectric layer (equivalent to a gate insulating film). If a read voltage is applied between the first and second electrodes while a voltage is applied to the control electrode, then the resistance between the first and second electrodes is temporarily lowered, and therefore, a large read current can be obtained with a small read voltage, thereby allowing the readout margin to be increased.
Patent Document 1: US Patent No. 7960809 Specification
Patent Document 2: US Patent No. 6775171 Specification
Patent Document 3: Japanese Patent Application Laid-Open Publication No. 2006-245589
Patent Document 4: Japanese Patent Application Laid-Open Publication No. 2010-153591
The eFUSE type memory element described in Patent Document 1 is configured to be disconnected by melting by applying a large current thereto, and thus, the resistance of the element disconnected by writing varies greatly. Furthermore, because the fuse material is melted and disconnected by heating to high temperatures, there is a risk that the melted material scatters to surrounding areas, and a risk that characteristics of adjacent materials change due to heating of the element. As a result, a high density circuit cannot be disposed in the vicinity of the memory element, and thus, high integration is inhibited in a case in which a semiconductor integrated circuit is configured using the memory element and , thereby causing an increase in chip size.
The memory element described in Patent Document 2 performs writing by breaking down the insulating film, and therefore needs a high voltage to be applied to the gate electrode. Due to this, the peripheral circuit for writing needs to be large in order to have a high withstand voltage, and if the memory element is used to form the semiconductor integrated circuit, high integration of a configuration is inhibited, thereby causing an increase in the chip size.
In the transistor element disclosed in Patent document 3, the current/voltage characteristics between the drain electrode and the source electrode change depending on the applied gate voltage, and therefore, in order to use the transistor element as a switching element that switches between conductive and non-conductive states between the drain electrode and the source electrode through the application of the gate voltage, it is necessary for the voltage between the drain electrode and source electrode be maintained between the first threshold voltage and the second threshold voltage regardless of the transistor element being conductive or non-conductive. Furthermore, the transistor element can be used as a switching element, but is not suitable for a non-volatile memory element.
The variable resistor described in Patent Document 4 is essentially a resistor that switches between a low resistance state and a high resistance state. Thus, the variable resistor does not function as a transistor element and cannot be used as a switching element.
The present invention was made in view of the above-mentioned problems, and an object thereof is to provide a transistor element that can change states to be a resistor, the state change occurring with a small power consumption, without physical changes such as migration and melting of the resistor due to a large current, and breakdown of an insulating film due to the application of a high electric field, and the state change can be used as a memory element.
In order to achieve the above-mentioned aim, the present invention provides a metal oxide transistor including: a semiconductor thin film formed of a metal oxide semiconductor; a source electrode in contact with a portion of the semiconductor thin film; a drain electrode in contact with another portion of the semiconductor thin film; and a gate electrode facing the semiconductor thin film through a gate insulating film, wherein the metal oxide transistor has, as an initial state, first characteristics, which are transistor element, in which a drain current flowing from the drain electrode to the source electrode changes depending on a gate voltage applied between the gate electrode and the source electrode and a drain voltage applied between the drain electrode and the source electrode, wherein when the drain current having a prescribed current density or greater that induces a change from the first characteristics is caused to flow through the semiconductor thin film for a prescribed period of time, the dependence of the drain current on the gate voltage is smaller in the second characteristics than in the first characteristics, whereby changes in the drain current primarily depends on the drain voltage and not on the gate voltage, exhibiting ohmic resistive characteristics, wherein, in the first characteristics, there exists a specific voltage range of the gate voltage at which enters a minute current state, the minute current state being such that an absolute value of a unit drain current that is the drain current for each unit channel width is confined to be less than or equal to 1×10−14 A/μm at least when an absolute value of the drain voltage is in a range of 0.1V to 10V, and wherein, in the second characteristics, the absolute value of the unit drain current is greater than or equal to 1×10−11 A/μm regardless of the gate voltage, when the drain voltage is at least within a range of 0.1V to 10V, even if the gate voltage is within the specific voltage range.
The ohmic resistive characteristics in the second characteristics refer to when the differential resistance for the unit channel width that is the differential change of the drain voltage is divided by the unit drain current has a prescribed value that is not 0. In other words, the current voltage characteristics line between the drain voltage and the unit drain current passes through the starting point (drain voltage=0V, unit drain current=0A/μm).
In addition, it is preferable that the metal oxide transistor be a thin film transistor in which the semiconductor thin film, the source electrode, the drain electrode, the gate electrode, and the gate insulating film are formed on an insulating substrate.
In addition, it is preferable that the metal oxide semiconductor include In, Ga, or Zn, and in particular, include InGaZnOx.
In addition, it is preferable that the metal oxide semiconductor have the current density of the drain current be greater in a portion of the semiconductor thin film than in another portion.
In addition, it is preferable that an area sandwiched by the drain electrode and the source electrode have a U shape.
In addition, it is preferable that the gate insulating film have a multilayer structure having at least a first insulating film and a second insulating film having higher permittivity than the first insulating film, wherein the first insulating film has a lower hydrogen concentration therein than the second insulating film after being formed, and wherein the first insulating film is formed between the semiconductor thin film and the second insulating film.
In addition, it is preferable that the metal oxide transistor have a second gate electrode facing the semiconductor thin film through an insulating film other than the gate insulating film, the second gate electrode being provided across from the gate electrode with the semiconductor thin film therebetween.
The metal oxide transistor having the above-mentioned characteristic, wherein the change from the first characteristics to the second characteristics occurs due to a change in composition ratio of elements forming the metal oxide semiconductor of the semiconductor thin film through joule heat generated by the drain current.
The present invention provides a semiconductor device including the metal oxide transistor.
In addition, the present invention provides a method of driving the metal oxide transistor, the method including: causing the drain current having the prescribed current density or greater to flow between the drain electrode and the source electrode for the prescribed period of time when the metal oxide transistor is exhibiting the first characteristics, so as to cause the metal oxide transistor to make the transition from the first characteristics to the second characteristics.
The metal oxide transistor with the above-mentioned characteristics, in the initial state under the first characteristics, can be used as a transistor element in which the drain current changes depending on the gate voltage and drain voltage. Furthermore, a specific voltage range exists in which the absolute value of the unit drain current, which is the drain current for each unit channel width, is in a minute current state or a virtually non-conductive state less than or equal to 1×10−14 A/μm at least when the absolute value of the drain voltage is 0.1V to 10V. Therefore, the metal oxide transistor can be used as a switching element that switches between conductive and non-conductive states between the drain electrode and the source electrode by shifting the gate voltage between the specific voltage range and another voltage range.
Furthermore, the metal oxide transistor with the above-mentioned characteristics can be used as a resistor. This is because when a drain current at or above a prescribed current density is made to flow in the semiconductor thin film for a prescribed time, the characteristics shift to the second characteristics in which the drain current exhibits ohmic resistive characteristics regardless of the gate voltage. As a result, the function of the metal oxide transistor as a transistor element or a switching element is lost and the metal oxide transistor acts as a resistor and therefore can be used as a resistor. If the gate voltage is set within the specific voltage range, under the first characteristics, the metal oxide transistor is in a non-conductive state, and under the second characteristics, the metal oxide transistor acts as a resistor. Therefore, the metal oxide transistor can be determined to be at the first characteristics or the second characteristics according to the conductive state between the drain electrode and the source electrode, and thus, the metal oxide transistor can be used as a memory element.
Furthermore, by forming a plurality of metal oxide transistors with the above-mentioned characteristics, some of the metal oxide transistors can be used only as transistor elements or switching elements, and have other metal oxide transistors be programmed to have either the first characteristics or the second characteristics. As a result, the metal oxide transistors can be used as memory elements that store information in a non-volatile manner. In other words, using the metal oxide transistors having the same characteristics, the memory element and the peripheral circuit thereof can be formed.
Furthermore, by including the memory element of other metal oxide transistors into the logic circuit, a programmable logic device can be configured. Also, other metal oxide transistors can be used not as memory elements but simply as resistors. Furthermore, a composite device having various functions can be configured by combining a transistor element, a switching element, a memory element, and a resistor.
If the metal oxide transistor with the above-mentioned characteristics is a thin-film transistor, the thin-film transistor can be formed on the insulating substrate where a liquid crystal display device or the like is formed on the periphery of this display device and be used as a component of the periphery circuit of the display device. Also, on the integrated circuit formed of bulk-type transistors, an integrated circuit of high density and high functionality can be formed and be provided by stacking circuits formed of metal oxide transistors that are thin film transistors.
Below, embodiments of the metal oxide transistor (hereinafter, also referred to as a “present transistor”) are described with reference to drawings.
On an insulating substrate 10 such as a glass substrate, the transistor 1 has a gate electrode 11, a first insulating film (gate insulating film) 12 that covers the gate electrode 11, a semiconductor thin film 13 formed of a metal oxide semiconductor, a source electrode 14, a drain electrode 15, and a second insulating film 16 on top of these. The transistor 1 has a similar structure to a thin film transistor (TFT) having a bottom gate structure and being formed on the insulating substrate.
Next, the manufacturing method of the transistor 1 and details of the respective constituting elements are described with reference to the cross-sectional views of
As shown in
As shown in
Next, as shown in
Next, as shown in
Next, as shown in
The transistor 1 is manufactured through the respective steps mentioned above. As shown in
In the present embodiment, the channel length L and the channel width W of the transistor 1 are defined by the length and width of the gap over the semiconductor thin film 13 between the source electrode 14 and the drain electrode 15, and the channel length L corresponds to the distance between the source electrode 14 and the drain electrode 15 over the semiconductor thin film 13. The channel width W is the length of the line through the mid-points on the semiconductor thin film 13 between the source electrode 14 and the drain electrode 15. In the example shown in
In the example shown in
Next, the electrical characteristics of the transistor 1 are described. If the above-mentioned IGZO is used as a metal oxide film semiconductor of the semiconductor thin film 13, then the transistor 1 becomes an n-channel transistor. In the initial state right after manufacturing, like a typical thin film transistor, the drain current Ids (current flowing from the drain electrode based on the source electrode) changes depending on the gate voltage Vgs (voltage applied to the gate electrode with reference to the source electrode) and the drain voltage Vds (voltage applied to the drain electrode with reference to the source electrode).
a) shows the Ids−Vgs characteristics of cases in which Vds=0.1V and Vds=10V during the initial state.
It is clear from
By applying to the transistor 1, in the initial state showing the transistor characteristics (first characteristics), a voltage greater than the specific voltage range for circuit operation of a normal transistor element so as to cause a large drain current to flow therethrough, the electrical characteristics of the transistor 1 are changed from the transistor characteristics of the initial state to ohmic resistive characteristics (corresponding to the second characteristics) to locally generate joule heat in the semiconductor thin film 13. In the description below, the operation of changing the electric characteristics of the transistor 1 from the transistor characteristics to the ohmic resistive characteristics is referred to as a writing operation for convenience.
a) shows the Ids−Vgs characteristics for when Vds=0.1V and Vds=10V after the writing operation.
Furthermore, in order to compare the first characteristics to the second characteristics, the Ids−Vds characteristics near the starting point in
It is clear from
It is clear from
It is clear from
Next, additional descriptions are provided regarding the writing operation of the transistor 1. The writing operation of the transistor 1 can be performed by causing the drain current Ids with high current density to flow through the semiconductor thin film 13 for a fixed writing time when the gate voltage Vgs applied to the transistor 1 under the first characteristics is in a higher bias state than the range of drain voltage Vds. By causing the drain current Ids with high current density to flow through the semiconductor thin film 13 for a fixed writing time, joule heat and electromigration occurs in the semiconductor thin film 13 due to the drain current Ids, and the composition of the metal oxide semiconductor that forms the semiconductor thin film 13 changes, which is thought to be the cause for the characteristics change mentioned above being induced. In the present embodiment, the thickness of the semiconductor thin film 13 is constant, and the unit drain current (unit: A/μm) is in a proportional relationship with the current density (unit: A/m2) of the drain current. By increasing the unit drain current (unit: A/μm), the current density of the drain current (unit: A/m2) becomes large. In the present embodiment, it is assumed that the unit drain current is approximately 1 μA/μm to 1 mA/μm and the writing time is approximately 10 μs to 100 s. The unit drain current and the writing time for the writing operation change depending on the metal oxide semiconductor used in the semiconductor thin film 13 and the element structure of the transistor 1, and thus, the unit drain current and the writing time are not limited to the numerical range mentioned above.
In
Furthermore, the writing characteristics also changes depending on the element structure of the transistor as mentioned above, and writing characteristics improve in an element structure in which joule heat is likely to occur or in an element structure in which the generated joule heat is difficult to diffuse.
If the high voltage gate voltage Vgs is applied to increase the drain current Ids for writing operation, there is a risk of breakdown of the gate insulating film 12. Thus, in the present embodiment, in order to increase the drain current Ids by keeping the gate voltage Vgs lower than the electric breakdown voltage of the gate insulating film 12, a material with high permittivity is used for the gate insulating film 12 to increase the electric capacitance. In the example above, the permittivity of the silicon nitride film (SiN) and the silicon nitride oxide film (SiNO) are higher than the permittivity of the silicon oxide film (SiO2). However, the silicon oxide film (SiO2) and the silicon oxide nitride film (SiON) include hydrogen in the film after being formed through the CVD method. Because the hydrogen reacts with the oxygen of the metal oxide semiconductor causing the semiconductor thin film 13 become closer to a conductor than a semiconductor, in order to make sure the semiconductor thin film 13 and the high permittivity film (silicon nitride film (SiN) or silicon nitride oxide film (SiNO)) do not come into direct contact, it is preferable that a silicon oxide film (SiO2) or a silicon oxide nitride film (SiON) having low hydrogen concentration in the film be inserted therebetween.
Furthermore, as shown in
Through the above-mentioned writing operation, the transistor 1 markedly shifts from the first characteristics to the second characteristics, and in particular, a large difference in the drain current Ids occurs when the gate voltage Vgs is within the specific voltage range (approximately 0.5V or less), and thus, by using the difference in current, the transistor 1 can be used as a non-volatile memory element. In other words, binary data of either 0 or 1 is assigned to the first characteristics before writing operation, and another of the binary data of 0 or 1 is assigned to the second characteristics after writing operation. Then, a prescribed voltage (0V, for example) within the specific voltage range is applied as the gate voltage Vgs, and by detecting the size of the drain current Ids, it is possible to tell whether the transistor 1 is in the first characteristic state or the second characteristic state.
Additionally, the transistor 1 can be used as a switching element under the first characteristics before the writing operation (initial state) because almost no drain current Ids flows and the transistor 1 is in an OFF state when the gate voltage Vgs is within the specific voltage range. Also, the transistor 1 under the first characteristics before the writing operation (initial state) can be used as an amplifying element because the drain current Ids respectively changes depending on the gate voltage Vgs and the drain voltage Vds if the gate voltage Vgs is higher than the specific voltage range. In addition, the transistor 1 can be used as a resistor, because the transistor 1 under the second characteristics after writing operation shows ohmic resistive characteristics.
During the manufacturing process of the transistor 1 shown in
Therefore, the transistor 1 can be used not only as a memory element, but also as a switching element, an amplifying element, and a resistor. Furthermore, as the capacitance element is formed with the same manufacturing process, various semiconductor devices using the transistor 1 can be configured. A semiconductor storage device having the transistor used as a memory circuit can be formed, a semiconductor device having a digital logic circuit using the transistor 1 as a switching element can be formed, a semiconductor device having an analog circuit using the transistor 1 as an amplifying element or a resistor can be formed, and a semiconductor device combining these elements can be formed, for example. The semiconductor device can be formed by combining other transistor elements that have a different element structure from the transistor 1.
Because the transistor 1 is formed as a thin film transistor, if the transistor 1 is used in a display device such as a liquid crystal display device that is formed on an insulating substrate, the various semiconductor devices mentioned above can be formed on the same insulating substrate as the display device.
In addition, if the transistor 1 is used as a memory element, because the transistor 1 can be manufactured in relatively low temperatures, data can be stored in IDs of IC tags and the like. The transistor 1 can also be used as a storage device with large capacitance for digital signage because the transistor 1 can be manufactured using a transparent material. Furthermore, by using the transistor 1 as a program element of a logic circuit instead of a storage device, a programmable logic circuit device such as ASIC (Application Specific Integrated Circuit) and FPGA (Field-Programmable Gate Array) can be realized.
As can be seen from comparing
Next, the manufacturing method of the transistor 2 and details of the respective components are described with reference to the cross-sectional views of
As shown in
Next, as shown in
The etching stopper layer 31 covers the exposed surface of the gate insulating film 12, and the etching stopper layer 31 is formed as the base layer on the semiconductor thin film 13 for portions of the second conductive film that are removed by etching to form the source electrode 14 and the drain electrode 15 in a later step.
Next, as shown in
Next, as shown in
The transistor 2 is manufactured by the respective steps mentioned above. A third insulating film (not shown) such as a photosensitive resin is formed as a planarizing film that planarizes the surface of the second insulating film 16 in a similar manner to Embodiment 1, and then this photosensitive resin film is exposed, developed, and baked. Additionally, etching is performed on the third insulating film and the second insulating film 16 that are formed, and contact holes (not shown) are formed to connect the gate electrode 11, the source electrode 14, the drain electrode 15, and the like to the metal wiring line layer (ITO or the like, for example) formed on the third insulating film. The third insulating film may be formed alone without forming the second insulating film 16.
Because the transistor 2 of Embodiment 2 has the etching stopper layer 31, damage to the semiconductor thin film 13 during the etching of the second conductive film can be avoided, and the fluctuation in electric characteristics due to the variation in electric characteristics and electric stress in the transistor 2 is decreased compared to the transistor of Embodiment 1. Furthermore, because the first and second conductive films can directly contact each other, the size of the circuit area can be reduced due to the size of the contact hole being reduced.
In Embodiment 2, during the manufacturing process of the transistor 2 shown in
The electric characteristics, the writing operation, and the applications of the transistor 2 of Embodiment 2 are essentially the same as those explained in Embodiment 1 and redundant descriptions thereof are omitted.
As can be seen from comparing
Next, the manufacturing method of the transistor 2 and details of the respective constituting elements are described with reference to the cross-sectional views of
As shown in
Next, as shown in
Next, as shown in
The transistor 3 is manufactured by the respective steps mentioned above. A third insulating film (not shown) such as a photosensitive resin is formed as a planarizing film that planarizes the surface of the second insulating film 16 in a similar manner to Embodiment 1, and then this photosensitive resin film is exposed, developed, and baked. Additionally, etching is performed on the third insulating film and the second insulating film 16 that are formed, and contact holes (not shown) are formed to connect the gate electrode 11, the source electrode 14, the drain electrode 15, and the like to the metal wiring line layer (ITO or the like, for example) formed on the third insulating film. The third insulating film may be formed alone without forming the second insulating film 16.
In the transistor 3 of Embodiment 3, the source electrode 14 and the drain electrode 15 are formed before the semiconductor thin film 13, and thus, no etching damage occurs on the semiconductor thin film 13 while etching is performed on the second conductive film. Therefore, fluctuation of electric characteristics is decreased compared to the transistor of Embodiment 1 due to the variation in electric characteristics and electric stress in the transistor 3. Furthermore, compared to Embodiment 2, Embodiment 3 is advantageous in terms of manufacturing cost and yield because the etching stopper layer 31 does not need to be formed, which simplifies the manufacturing process.
Also in Embodiment 3, during the manufacturing process of the transistor 3 shown in
The electric characteristics, the writing operation, and the applications of the transistor 3 of Embodiment 3 are essentially the same as those explained in Embodiment 1 and redundant descriptions are omitted.
(1) In the respective embodiments above, examples of the transistors 1 to 3 formed of bottom gate type thin film transistors were shown, but the transistors 1 to 3 are not limited to bottom gate type thin film transistors.
In
The transistor 4 has a semiconductor thin film 13 formed of a metal oxide semiconductor, a gate insulating film 12, and a gate electrode 11 formed in that order on an insulating substrate 10 such as a glass substrate, and an interlayer insulating film 41 formed on top of these. A source electrode 14 and a drain electrode 15 formed on the interlayer insulating film 41 are in contact with the semiconductor thin film 13 through the contact holes 42.
The transistors 1 to 4 of the respective embodiments and other embodiment show cases in which the transistors 1 to 4 are thin film transistors, but even if the transistor has a MOS type structure by forming the semiconductor thin film 13 of a metal oxide semiconductor on a silicon substrate instead of the insulating substrate 10, a metal oxide transistor that shifts from the first characteristics to the second characteristics can be realized.
(2) In the respective embodiments, an n-channel present transistor using IGZO as the n-channel type metal oxide semiconductor of the semiconductor thin film 13 is described as an example, but the conductivity type of the transistor is not limited to the n-channel type.
(3) The respective conductive films, the respective materials of the insulating films, the structure, the thicknesses, the electric characteristics, and writing characteristics of the transistors described in the respective embodiments are just examples and the present invention is not limited to the descriptions provided in the respective embodiments. Industrial Applicability
The present invention can be used for metal oxide transistors having channel regions formed of metal oxide semiconductors, and for semiconductor devices and electronic devices using such transistors.
Number | Date | Country | Kind |
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2012-137868 | Jun 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/060583 | 4/8/2013 | WO | 00 |