Claims
- 1. A compound having the structural formula: ##STR255## wherein: R' is selected from chlorine, bromine, fluorine, alkyl, alkoxy, phenyl, or phenoxy;
- n is 0, 1, or 2;
- R.sub.1 is selected from:
- C.sub.5 up to C.sub.7 cycloalkyl,
- phenyl,
- --R.sub.2 --Z--B'--CH.dbd.C(P.sup.a)Q, wherein R.sub.2, P.sup.a and Q are as defined below, Z is 0 and B' is arylene; or R.sub.1 is
- straight or branched alkenyl,
- straight or branched alkyl,
- straight or branched alkyl substituted with at least one of:
- phenylcarbamoyloxy,
- alkanoylamino,
- carboxy,
- acrylamido,
- alkoxycarbonylamino,
- N-alkylcarbamoyloxy,
- groups of the formula:
- --O--R.sub.6, wherein R.sub.6 is selected from:
- alkyl, or
- aryl,
- --CONR.sub.7 R.sub.7, wherein each R.sub.7 is independently selected from:
- H,
- alkyl,
- phenoxyalkyl,
- alkanoyloxyalkyl,
- aryl;
- --OXR.sub.8, --NHXR.sub.8 or --XR.sub.8, wherein X is --CO--, or --COO--; and each R.sub.8 is selected from:
- alkyl,
- cycloalkyl,
- phenoxyalkyl,
- alkanoyloxyalkyl; and, when X is --CO--, R.sub.8 can further be selected from:
- H,
- alkenyl,
- amino,
- alkylamino,
- dialkylamino,
- arylamino,
- aryl,
- alkoxy,
- alkanoyloxyalkoxy,
- phenoxy,
- alkylphenoxy,
- carboxyphenoxy,
- alkoxyphenoxy,
- carbalkoxyphenoxy, or
- halogenophenoxy;
- R.sub.2 is selected from:
- alkylene,
- alkylene substituted with --Z--B'--CH.dbd.C(P.sup.a)Q, wherein Z and B' are as defined above and P.sup.a and Q are as defined below,
- arylene,
- aralkylene,
- alkylene--O--alkylene,
- alkylene--O--arylene--O--alkylene,
- alkylene--arylene--alkylene,
- alkylene--cyclohexylene--alkylene, ##STR256## wherein R.sub.9 is selected from: alkyl,
- aryl,
- alkanoyl,
- aroyl, or
- P.sup.a, Q, P.sup.1 and Q.sup.1 are each independently selected from:
- carbalkoxy,
- carbocycloalkoxy,
- carbaryloxy,
- carbaralkyloxy,
- carbalkenyloxy,
- carbamyl,
- carboxy,
- alkanoyl,
- aroyl,
- N-alkylcarbamyl,
- N-alkyl-N-arylcarbamyl,
- N,N-dialkylcarbamyl,
- N-arylcarbamyl,
- N-cyclohexylcarbamyl, and
- aryl;
- with the proviso that at least one of R.sub.1, R.sub.2, P.sup.a, Q, P.sup.1 and Q.sup.1 is a group reactive under condensation polymerization conditions, or bears a group reactive under condensation polymerization conditions, so as to incorporate said compound into the resulting polymer, said group selected from:
- carboxy,
- carbalkoxy,
- carbaryloxy,
- N-alkylcarbamyloxy,
- alkanoyloxy,
- chlorocarbonyl,
- carbamyloxy,
- amino,
- alkylamino,
- hydroxyl,
- N-phenylcarbamyloxy,
- cyclohexanoyloxy, or
- carbocyclohexyloxy;
- wherein in each of the above definitions the alkyl or alkylene moieties or portions of the various groups contain up to 8 carbon atoms, straight or branched chain, aryl moieties or portions of the various groups are carbocyclic species and contain in the range of 6 up to 10 carbon atoms; and wherein each alkyl, alkylene, alkoxy, aryl, or cycloalkyl moiety or portion of a group or radical can be further substituted with hydroxy, acyloxy, alkyl, alkoxycarbonyl, halogen, carbonylhalide, alkoxy, aryl, aryloxy, cycloalkyl, amino, alkylamino, alkanoylamino, or carboxy group; and wherein at least one carboxylic acid ester is present.
- 2. A compound in accordance with claim 1 wherein R.sub.1 is selected from:
- alkyl,
- alkyl of 1 up to 6 carbon atoms,
- alkyl of 1 up to 6 carbon atoms substituted with:
- cyclohexyl,
- phenyl,
- phenyl substituted with:
- C.sub.1 up to C.sub.6 alkyl, C.sub.1 up to C.sub.6 alkoxy, halogen, carboxy or carbalkoxy,
- hydroxy,
- alkoxy,
- aryloxy,
- halogen,
- carbalkoxy,
- carbamyl,
- alkanoyloxy,
- aroyloxy, or
- succinimido;
- cyclopentyl,
- cyclohexyl,
- phenyl, or
- phenyl substituted with:
- C.sub.1 up to C.sub.6 alkyl, C.sub.1 up to C.sub.6 alkoxy, or halogen.
- 3. A compound in accordance with claim 1 wherein R.sub.2 is selected from C.sub.1 up to C.sub.6 alkylene group.
- 4. A compound in accordance with claim 3 wherein R.sub.2 is --CH.sub.2 CH.sub.2 --.
- 5. A compound in accordance with claim 1 wherein Q and Q.sup.1 are each carbalkoxy.
- 6. A compound having the formula ##STR257##
Parent Case Info
This is a divisional of copending application Ser. No. 07/182,633 filed on Apr. 18, 1988, now U.S. Pat. No. 4,958,043.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3634320 |
Metaner et al. |
Jan 1972 |
|
4338247 |
Zannucci et al. |
Jul 1982 |
|
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1568693 |
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DEX |
WO8604904 |
Aug 1986 |
WOX |
WO8701121 |
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Non-Patent Literature Citations (1)
Entry |
"Plastics Additives Handbook" (1985), edited by Gacher et al., pp. 128-134, Hanser Publishers-Minuch, Vienna, N.Y. |
Divisions (1)
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Number |
Date |
Country |
Parent |
182633 |
Apr 1988 |
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