This invention relates generally to a method and apparatus for accelerating or controlling the degassing of roasted coffee.
It is a well known fact that as a result of the roasting process coffee beans release carbon dioxide. It is also well known that one should preferably allow roasted coffee beans and ground coffee to degas prior to packaging in containers because the diffusion of carbon dioxide can cause the containers to expand or potentially rupture. It is further known to those in the coffee roasting industry that exposing roasted coffee to oxygen causes the coffee to oxidize, which can have a negative effect upon its taste. In addition, a substantial portion of the flavour and aromatics associated with roasted coffee can be stripped away from the coffee beans as the carbon dioxide evolves therefrom.
Recognizing that coffee should preferably be allowed to degas prior to packaging, while at the same time appreciating that efforts should be undertaken to prevent contact between the roasted coffee and atmospheric air and to help limit the stripping off of aromatics and exposing to oxygen, it is known to deposit the freshly roasted coffee into large totes, silos, bins or other storage containers (hereafter referred to as containers) where degassing can occur in an enclosed environment. The containers are either vented or have open tops to permit the carbon dioxide that diffuses from the roasted coffee to escape. The containers are also typically kept at atmospheric pressure while the coffee is allowed to degas, a process that can take anywhere from a few hours to a couple of days. Unfortunately, the inherent delay caused by waiting for the coffee to degas not only decreases the productivity of a roasting and packaging operation, but also necessitates the use of a number of containers to house the coffee during the degassing process. In a large roasting facility where multiple types and blends of coffee may be produced, the number of containers, their capital cost, and the floor space that they occupy can be significant.
The invention therefore provides an apparatus for accelerated or controlled degassing of roasted coffee, the apparatus comprising a container for receiving and retaining roasted coffee; a source of inert gas in fluid communication with said container; and a controller, said controller including a timer and a valve, said valve operatively associated with said source of inert gas and having an open and a closed position, when in said closed position said valve restricting the flow of said inert gas into said container, when in said open position said valve permitting the flow of said inert gas into said container such that said inert gas displaces at least a portion of the carbon dioxide in said container, said timer causing said valve to cycle between said open and said closed positions at predetermined time intervals.
In another aspect the invention provides an apparatus for accelerated or controlled degassing of roasted coffee, the apparatus comprising a container for receiving and retaining roasted coffee; a sensor for measuring one or more gases retained in said container; a source of inert gas in fluid communication with said container; and a controller, said controller operatively associated with said sensor and said source of inert gas such that when said sensor is exposed to a predetermined concentration of said one or more gases, said controller causes inert gas to be delivered to said container, said inert gas displacing at least a portion of the one or more gases within said container.
In a further aspect the invention provides a method for accelerated or controlled degassing of roasted coffee, the method comprising the steps of loading a volume of roasted coffee into a container; sealing said container to limit contact between the roasted coffee and atmospheric air; with a carbon dioxide sensor, sensing the concentration of carbon dioxide within the container; delivering a signal from said sensor to a controller, said signal indicative of the concentration of carbon dioxide within the container, the controller being operatively associated with a source of pressurized nitrogen gas; if upon the receipt of said signal said controller determines that the concentration of carbon dioxide within the container exceeds a pre-determined value, said controller causing pressurized nitrogen gas to be delivered to the container, said nitrogen gas causing carbon dioxide within the container to be displaced and to be exhausted through a gas outlet.
Additional aspects of the invention will become apparent from the following description taken together with the accompanying drawings.
For a better understanding of the present invention, and to show more clearly how it may be carried into effect, reference will now be made, by way of example, to the accompanying drawings which show exemplary embodiments of the present invention in which:
The present invention may be embodied in a number of different forms. The specification and drawings that follow describe and disclose some of the specific forms of the invention.
With reference to
Roasted coffee (which may be in the form of ground coffee or whole coffee beans) is first loaded into container 1 to a pre-determined level that leaves an unoccupied head space 7 at the top of the container between the coffee and the container's upper surface. The upper opening in the container may be then sealed with cover 4 to help keep out air and other contaminants. Once received within the container, the roasted and/or ground coffee will begin to immediately degas and the level of carbon dioxide within the container will rise. Since carbon dioxide is heavier than air, as carbon dioxide evolves from the coffee it will exhibit a tendency to settle toward the bottom of container 1. Entrapped air that may exist within the container will be diluted by the carbon dioxide released from the coffee and/or will be displaced outwardly through gas outlet 5.
A carbon dioxide sensor 8, located in either gas outlet 5 or at the upper end of the container in head space 7, monitors the concentration of carbon dioxide as it builds within the container. Sensor 8 can be configured to continuously provide a signal to a controller 9 and to thereby provide a continuous indication of the concentration of carbon dioxide within container 1. Alternatively, the sensor can be configured such that a signal is sent to the controller once the concentration of carbon dioxide within the container exceeds a predetermined value. In either case, once controller 9 either receives a signal from the sensor indicating that the carbon dioxide concentration in the container is beyond a predetermined level, or when the continuous signal sent by the sensor to the controller is such that the controller recognizes the carbon dioxide level to exceed the predetermined level, the controller causes inert gas (most commonly nitrogen gas) from a pressurized supply 10 to be introduced into the container through inert gas inlet 6. Typically the controller will cause a solenoid valve 14 within the inert gas supply line to open and close as needed to deliver inert gas to the container. As the inert gas is introduced, the level or concentration of carbon dioxide in the container will be reduced, with the inert gas displacing at least a portion of the carbon dioxide out through gas outlet 5. When sensor 8 detects a drop in the concentration of carbon dioxide below a predetermined level, controller 9 will cause the flow of inert gas into the container to cease.
It will be appreciated by those having knowledge of the coffee roasting and packaging industry that the most common inert gas that is used in coffee packaging is nitrogen. In the case of the current invention, inert is meant to refer to gas that does not negatively react with the roasted coffee and that does not exhibit a tendency to restrict the degassing of the coffee. It will also be appreciated that the inert gas should not be harmful for human consumption within the limits of that which could be expected when used in association with coffee roasting and packaging.
Controller 9 may include, or may have associated with it, one or more different components to control or regulate the amount of inert gas delivered through inert gas inlet 6. For example, the controller may include a timer 11 associated with solenoid valve 14 causing pressurized inert gas to be delivered to the container for a predetermined length of time (that time will largely be a function of the size of the container, the amount of coffee contained therein, the degree of roasting, the concentration of carbon dioxide within the container, the degree of degassing required, etc). Further, the controller may include a flow controller 12 to regulate the volume of inert gas that is delivered to container 1. The controller may also include a pressure regulator 13 to regulate the pressure of the inert gas that is delivered. In yet a further embodiment, the controller may include a combination of a timer and/or a flow controller and/or a pressure regulator. A central processing unit 15 receives the signal or signals from sensor 8 and controls the opening and closing of solenoid valve 14, either through direct connection to the solenoid or through the control of timer 11, which in turn controls the solenoid. In some instances the central processing unit may also control the flow controller and/or the pressure regulator (see dashed lines in
In an alternate embodiment of the invention there may be provided an oxygen sensor in fluid communication with container 1. The oxygen sensor will monitor the concentration of O2 within the container and provide a signal to controller 9. Should the controller receive a signal indicating that the concentration of oxygen gas within the container exceeds a pre-determined level (for example, 10%) the controller will cause inert gas from supply 10 to be introduced into the container through gas inlet 6. Once the O2 level in the container has dropped below a predetermined level (for example, 2%) the controller will cause the flow of inert gas into the container to cease. In this manner the level of oxygen gas within the container can be regulated to minimize oxidation of the coffee retained therein. The oxygen sensor could be a separate dedicated sensor, or could be combined with the carbon dioxide sensor into a single sensor or sensor pack.
It will be appreciated that the described apparatus and methodology allows for an accelerated or a controlled degassing of roasted coffee. That is, in the normal course where the described apparatus and methodology is not employed, carbon dioxide naturally evolves from the roasted coffee received within container 1. If left to its own state of evolution, the concentration of carbon dioxide within the container will increase, with carbon dioxide gas slowly seeping outwardly from the top of the container. However, it will be appreciated that with an increased carbon dioxide concentration in the environment that immediately surrounds the roasted coffee, the diffusion of carbon dioxide outwardly from the individual coffee beans or coffee grounds is diminished. A reduction in the rate of release of carbon dioxide from the coffee slows down the overall degassing process.
The applicant has found that by reducing the concentration of carbon dioxide within the container, the rate of diffusion of carbon dioxide from the roasted coffee will tend to increase, or to at least remain at a relatively steady state without the traditional decrease that is experienced through the use of current degassing equipment and methodologies. Through the employment of the described invention the injection of nitrogen gas into the container will thus result in a lowering of the concentration of carbon dioxide within the container and will help to “encourage” a release of carbon dioxide from the coffee. When the flow of inert gas is stopped, the carbon dioxide levels within the container will again slowly begin to rise, until such time as sensor 8 signals the controller that the carbon dioxide concentration is such that degassing is being hindered, in which case the controller will cause inert gas to once again be introduced into the container in order to reduce carbon dioxide levels. Through cycling the injection of inert gas, the carbon dioxide concentration can thus be controlled and maintained generally within a range that permits an enhanced or accelerated degassing, over and above what can be typically achieved through traditional means.
Through the utilization of the described structure and method the length of time required for the overall degassing process can be reduced. At the same time, controlling the injection of inert gas into the container so that the concentration of carbon dioxide is maintained within a predetermined range helps to ensure that too much carbon dioxide is not removed and that significant aromatics are not lost.
In an alternate embodiment, the apparatus does not include a sensor 8. Instead, controller 9 is equipped with a timer that operates solenoid valve 14. The timer will be pre-programmed to periodically cycle the solenoid to start and stop the flow of nitrogen gas into the container. In this embodiment, a calculation is first made to determine a general rate of evolution of carbon dioxide gas from the roasted coffee. Then, based upon that calculation, the timer (or a CPU that controls the timer) is programmed to cause the solenoid to deliver nitrogen gas (at a known or controlled rate of flow and pressure) to the container for a predetermined length of time. That length of time is calculated to allow for the removal of carbon dioxide and a reduction in the concentration of carbon dioxide within the container without a significant loss of aromatics. In this embodiment the flow of inert gas into the container would be automatically cycled on and off for a period of time which would correspond to the length of time necessary for the coffee to sufficiently degas to permit packaging.
It will thus be appreciated that the described apparatus and method permits roasted coffee to be degassed at an accelerated or a controlled rate without a significant loss of aromatics. The apparatus and method are adaptable for use in association with a wide variety of different containers, container sizes, for different coffee roasts, etc.
It is to be understood that what has been described are the preferred embodiments of the invention. The scope of the claims should not be limited by the preferred embodiments set forth above, but should be given the broadest interpretation consistent with the description as a whole.
Number | Name | Date | Kind |
---|---|---|---|
2110518 | Becker | Mar 1938 | A |
2113715 | Wilcox | Apr 1938 | A |
2291604 | Baselt | Aug 1942 | A |
2987221 | Milton | Jun 1961 | A |
3110121 | Corrinet | Nov 1963 | A |
3119695 | Kahan | Jan 1964 | A |
3282703 | Broadhurst | Nov 1966 | A |
3333963 | Moon | Aug 1967 | A |
3399806 | Lucas | Sep 1968 | A |
3506446 | Champion | Apr 1970 | A |
3613549 | Champion | Oct 1971 | A |
3713936 | Ramsay A | Jan 1973 | A |
3799049 | Smith, Jr. | Mar 1974 | A |
3821430 | Reeves et al. | Jun 1974 | A |
4101627 | Menier | Jul 1978 | A |
4131064 | Ryan | Dec 1978 | A |
4161549 | Ohno | Jul 1979 | A |
4220673 | Strobel | Sep 1980 | A |
4235160 | Olney | Nov 1980 | A |
4306367 | Otto | Dec 1981 | A |
4368100 | Pyves | Jan 1983 | A |
4440796 | Lunder | Apr 1984 | A |
4471689 | Piana | Sep 1984 | A |
4518639 | Phillips | May 1985 | A |
4559729 | White | Dec 1985 | A |
4619830 | Napier | Oct 1986 | A |
4701365 | Iwasaki | Oct 1987 | A |
4728425 | Sandvig | Mar 1988 | A |
4748030 | Illy | May 1988 | A |
4859337 | Woltermann | Aug 1989 | A |
4865737 | McMichael | Sep 1989 | A |
4867993 | Nordskog | Sep 1989 | A |
4890637 | Lamparter | Jan 1990 | A |
4966780 | Hargraves | Oct 1990 | A |
4981588 | Poulallion | Jan 1991 | A |
4983410 | Dinos | Jan 1991 | A |
4995310 | van der Lijn | Feb 1991 | A |
4996066 | Love | Feb 1991 | A |
5008013 | Favre | Apr 1991 | A |
5076433 | Howes | Dec 1991 | A |
5156009 | Woodruff | Oct 1992 | A |
5208058 | Kotani | May 1993 | A |
5238648 | Kremen | Aug 1993 | A |
5298267 | Gruenbacher | Mar 1994 | A |
5305688 | Kotani | Apr 1994 | A |
5331793 | Pophal | Jul 1994 | A |
5333394 | Herdeman | Aug 1994 | A |
5361560 | Sandolo | Nov 1994 | A |
5368875 | Hibi | Nov 1994 | A |
5390587 | Wu | Feb 1995 | A |
5447631 | Mahlich | Sep 1995 | A |
5456929 | Mifune | Oct 1995 | A |
5496573 | Tsuji | Mar 1996 | A |
5532011 | Goglio | Jul 1996 | A |
5536290 | Stark | Jul 1996 | A |
5575383 | Seeley | Nov 1996 | A |
5601716 | Heinrich | Feb 1997 | A |
5605710 | Pridonoff | Feb 1997 | A |
5658607 | Herdeman | Aug 1997 | A |
5738786 | Winnington-Ingram | Apr 1998 | A |
5768859 | Goglio | Jun 1998 | A |
5806582 | Santavuori | Sep 1998 | A |
5822951 | Rosik | Oct 1998 | A |
5840189 | Sylvan | Nov 1998 | A |
5858437 | Anson | Jan 1999 | A |
5866185 | Burkett | Feb 1999 | A |
5871096 | Yakich | Feb 1999 | A |
5871644 | Simon | Feb 1999 | A |
5882716 | Munz-Schaerer | Mar 1999 | A |
5885314 | Oussoren | Mar 1999 | A |
5895672 | Cooper | Apr 1999 | A |
5896686 | Howes | Apr 1999 | A |
5897899 | Fond | Apr 1999 | A |
5908652 | Sakano | Jun 1999 | A |
5923242 | Slagle | Jul 1999 | A |
5957279 | Howes | Sep 1999 | A |
5971195 | Reidinger | Oct 1999 | A |
6025000 | Fond | Feb 2000 | A |
6092430 | Liston | Jul 2000 | A |
6146270 | Huard | Nov 2000 | A |
6189438 | Bielfeldt | Feb 2001 | B1 |
6203837 | Kalenian | Mar 2001 | B1 |
6220147 | Priley | Apr 2001 | B1 |
6223937 | Schmidt | May 2001 | B1 |
6337098 | Spencer | Jan 2002 | B1 |
6342261 | Spencer | Jan 2002 | B1 |
6440256 | Gordon | Aug 2002 | B1 |
6514552 | Sivetz | Feb 2003 | B1 |
6514555 | Fayard | Feb 2003 | B1 |
6548433 | Gbur | Apr 2003 | B1 |
6557597 | Riesterer | May 2003 | B2 |
6561232 | Frutin | May 2003 | B1 |
6589577 | Lazaris | Jul 2003 | B2 |
6606938 | Taylor | Aug 2003 | B2 |
6607762 | Lazaris | Aug 2003 | B2 |
6622615 | Heczko | Sep 2003 | B2 |
6644173 | Lazaris | Nov 2003 | B2 |
6645537 | Sweeney | Nov 2003 | B2 |
6658989 | Sweeney | Dec 2003 | B2 |
6720070 | Hamaguchi | Apr 2004 | B2 |
6758130 | Sargent | Jul 2004 | B2 |
6810788 | Hale | Nov 2004 | B2 |
6841185 | Sargent | Jan 2005 | B2 |
6854378 | Jarisch | Feb 2005 | B2 |
6861086 | Buckingham | Mar 2005 | B2 |
6869627 | Perkovic | Mar 2005 | B2 |
6913777 | Rebhorn | Jul 2005 | B2 |
6959832 | Sawada | Nov 2005 | B1 |
6992586 | Rosenfeld | Jan 2006 | B2 |
7067038 | Trokhan | Jun 2006 | B2 |
7153530 | Masek | Dec 2006 | B2 |
7169418 | Dalton | Jan 2007 | B2 |
7169419 | Dalton | Jan 2007 | B2 |
7279188 | Arrick | Oct 2007 | B2 |
7311209 | Bentz | Dec 2007 | B2 |
7325479 | Laigneau | Feb 2008 | B2 |
7328651 | Halliday | Feb 2008 | B2 |
7387063 | Vu | Jun 2008 | B2 |
7412921 | Hu | Aug 2008 | B2 |
7419692 | Kalenian | Sep 2008 | B1 |
7444925 | Mahlich | Nov 2008 | B2 |
7490542 | Macchi | Feb 2009 | B2 |
7543527 | Schmed | Jun 2009 | B2 |
7552672 | Schmed | Jun 2009 | B2 |
7552673 | Levin | Jun 2009 | B2 |
7594470 | Scarchilli | Sep 2009 | B2 |
7624673 | Zanetti | Dec 2009 | B2 |
7640842 | Bardazzi | Jan 2010 | B2 |
7681492 | Suggi Liverani | Mar 2010 | B2 |
7685930 | Mandralis | Mar 2010 | B2 |
7698992 | Wei | Apr 2010 | B2 |
7763300 | Sargent | Jul 2010 | B2 |
7765733 | Liu | Aug 2010 | B1 |
7775019 | Haak | Aug 2010 | B2 |
7798055 | Mandralis | Sep 2010 | B2 |
7854192 | Denisart | Dec 2010 | B2 |
7856920 | Schmed | Dec 2010 | B2 |
7856921 | Arrick | Dec 2010 | B2 |
7910145 | Reati | Mar 2011 | B2 |
8062682 | Mandralis | Nov 2011 | B2 |
8067049 | Hibi | Nov 2011 | B2 |
8225771 | Aso | Jul 2012 | B2 |
8252351 | Ozanne | Aug 2012 | B2 |
8256190 | Bowden | Sep 2012 | B2 |
8286547 | Lassota | Oct 2012 | B1 |
8361527 | Winkler | Jan 2013 | B2 |
8409646 | Yoakim | Apr 2013 | B2 |
8425957 | Steenhof | Apr 2013 | B2 |
8431175 | Yoakim | Apr 2013 | B2 |
8474368 | Kilber | Jul 2013 | B2 |
8475854 | Skalski | Jul 2013 | B2 |
8481097 | Skalski | Jul 2013 | B2 |
8573114 | Huang | Nov 2013 | B2 |
8591978 | Skalski | Nov 2013 | B2 |
8673379 | Skalski | Mar 2014 | B2 |
8740020 | Marina | Jun 2014 | B2 |
8834948 | Estabrook | Sep 2014 | B2 |
8881948 | Lassota | Nov 2014 | B1 |
8960078 | Hristov | Feb 2015 | B2 |
20020020659 | Sweeney | Feb 2002 | A1 |
20020144603 | Taylor | Oct 2002 | A1 |
20030005826 | Sargent | Jan 2003 | A1 |
20030010787 | Dalton | Jan 2003 | A1 |
20030039731 | Dalton | Feb 2003 | A1 |
20030087005 | Baron | May 2003 | A1 |
20040137110 | Dalton | Jul 2004 | A1 |
20040178232 | Langlois | Sep 2004 | A1 |
20050016383 | Kirschner | Jan 2005 | A1 |
20050051478 | Karanikos | Mar 2005 | A1 |
20050287251 | Lazaris | Dec 2005 | A1 |
20060236871 | Ternite | Oct 2006 | A1 |
20060246187 | Egolf | Nov 2006 | A1 |
20070144356 | Rivera | Jun 2007 | A1 |
20070148290 | Ternite | Jun 2007 | A1 |
20070275125 | Catani | Nov 2007 | A1 |
20080015098 | Littlejohn | Jan 2008 | A1 |
20080142115 | Vogt | Jun 2008 | A1 |
20080156196 | Doglioni Majer | Jul 2008 | A1 |
20080202075 | Kronawittleithner | Aug 2008 | A1 |
20080233265 | Hibi | Sep 2008 | A1 |
20080245236 | Ternite | Oct 2008 | A1 |
20080302825 | Illy | Dec 2008 | A1 |
20090110775 | Rijskamp | Apr 2009 | A1 |
20090133584 | De Graaff | May 2009 | A1 |
20090165228 | Kilkenny | Jul 2009 | A1 |
20090175986 | Doglioni Majer | Jul 2009 | A1 |
20090183640 | Ozanne | Jul 2009 | A1 |
20090186141 | Almblad | Jul 2009 | A1 |
20090206084 | Woolf | Aug 2009 | A1 |
20090211458 | Denisart | Aug 2009 | A1 |
20090232947 | Buisson | Sep 2009 | A1 |
20090260690 | Bell | Oct 2009 | A1 |
20090311389 | Zoss | Dec 2009 | A1 |
20090324791 | Ohresser | Dec 2009 | A1 |
20100003379 | Zoss | Jan 2010 | A1 |
20100028495 | Novak | Feb 2010 | A1 |
20100116772 | Teys | May 2010 | A1 |
20100215808 | Versini | Aug 2010 | A1 |
20100239733 | Yoakim | Sep 2010 | A1 |
20100239734 | Yoakim | Sep 2010 | A1 |
20100303964 | Beaulieu | Dec 2010 | A1 |
20110003040 | Graf | Jan 2011 | A1 |
20110033580 | Biesheuvel | Feb 2011 | A1 |
20110041469 | Fischer | Feb 2011 | A1 |
20110045144 | Boussemart | Feb 2011 | A1 |
20110076361 | Peterson | Mar 2011 | A1 |
20110183048 | Noble | Jul 2011 | A1 |
20110185911 | Rapparini | Aug 2011 | A1 |
20110247975 | Rapparini | Oct 2011 | A1 |
20110250339 | Onishi | Oct 2011 | A1 |
20110256273 | de Graaff | Oct 2011 | A1 |
20120006205 | Vanni | Jan 2012 | A1 |
20120024160 | Van Os | Feb 2012 | A1 |
20120052163 | Doleac | Mar 2012 | A1 |
20120070542 | Camera | Mar 2012 | A1 |
20120097602 | Tedford | Apr 2012 | A1 |
20120121764 | Lai | May 2012 | A1 |
20120171334 | Yoakim | Jul 2012 | A1 |
20120174794 | Fraij | Jul 2012 | A1 |
20120180670 | Yoakim | Jul 2012 | A1 |
20120180671 | Baudet | Jul 2012 | A1 |
20120183649 | Burkhalter | Jul 2012 | A1 |
20120186457 | Ozanne | Jul 2012 | A1 |
20120196008 | York | Aug 2012 | A1 |
20120199007 | Larzul | Aug 2012 | A1 |
20120199010 | Mariller | Aug 2012 | A1 |
20120199011 | Cheng | Aug 2012 | A1 |
20120201933 | Dran | Aug 2012 | A1 |
20120207893 | Kruger | Aug 2012 | A1 |
20120207894 | Webster | Aug 2012 | A1 |
20120210876 | Glucksman | Aug 2012 | A1 |
20120210878 | Mariller | Aug 2012 | A1 |
20120210879 | Mariller | Aug 2012 | A1 |
20120231123 | Kamerbeek | Sep 2012 | A1 |
20120231124 | Kamerbeek | Sep 2012 | A1 |
20120231126 | Lo Faro | Sep 2012 | A1 |
20120231133 | Kamerbeek | Sep 2012 | A1 |
20120251668 | Wong | Oct 2012 | A1 |
20120251669 | Kamerbeek | Oct 2012 | A1 |
20120251670 | Kamerbeek | Oct 2012 | A1 |
20120251671 | Kamerbeek | Oct 2012 | A1 |
20120251692 | Kamerbeek | Oct 2012 | A1 |
20120251693 | Kamerbeek | Oct 2012 | A1 |
20120251694 | Kamerbeek | Oct 2012 | A1 |
20120258204 | Tsuji | Oct 2012 | A1 |
20120258210 | Wong | Oct 2012 | A1 |
20120258219 | Wong | Oct 2012 | A1 |
20120258221 | Wong | Oct 2012 | A1 |
20120260806 | Rolfes | Oct 2012 | A1 |
20120263829 | Kamerbeek | Oct 2012 | A1 |
20120263830 | Kamerbeek | Oct 2012 | A1 |
20120263833 | Wong | Oct 2012 | A1 |
20120266755 | Baudet | Oct 2012 | A1 |
20120269933 | Rapparini | Oct 2012 | A1 |
20120272830 | Gugerli | Nov 2012 | A1 |
20120276252 | Bunke | Nov 2012 | A1 |
20120276255 | Verbeek | Nov 2012 | A1 |
20120297987 | Lee | Nov 2012 | A1 |
20120301581 | Abegglen | Nov 2012 | A1 |
20120307024 | Howes | Dec 2012 | A1 |
20120308688 | Peterson | Dec 2012 | A1 |
20120312174 | Lambert | Dec 2012 | A1 |
20120321755 | Macaulay | Dec 2012 | A1 |
20120321756 | Estabrook | Dec 2012 | A1 |
20120328739 | Nocera | Dec 2012 | A1 |
20120328740 | Nocera | Dec 2012 | A1 |
20120328744 | Nocera | Dec 2012 | A1 |
20130004629 | Clark | Jan 2013 | A1 |
20130004637 | Gugerli | Jan 2013 | A1 |
20130008316 | Hoglauer | Jan 2013 | A1 |
20130011521 | Weijers | Jan 2013 | A1 |
20130017303 | Vu | Jan 2013 | A1 |
20130025466 | Fu | Jan 2013 | A1 |
20130032034 | Jarisch | Feb 2013 | A1 |
20130047863 | Larzul | Feb 2013 | A1 |
20130059039 | Trombetta | Mar 2013 | A1 |
20130059903 | Raman | Mar 2013 | A1 |
20130068109 | Pribus | Mar 2013 | A1 |
20130084368 | Linck | Apr 2013 | A1 |
20130095219 | de Graaff | Apr 2013 | A1 |
20130101717 | de Graaff | Apr 2013 | A1 |
20130115342 | Van Os | May 2013 | A1 |
20130122153 | Ferrier | May 2013 | A1 |
20130122167 | Winkler | May 2013 | A1 |
20130129870 | Novak | May 2013 | A1 |
20130142931 | Fin | Jun 2013 | A1 |
20130199378 | Yoakim | Aug 2013 | A1 |
20130259982 | Abegglen | Oct 2013 | A1 |
20130340626 | Oh | Dec 2013 | A1 |
20130344205 | Oh | Dec 2013 | A1 |
20140013958 | Krasne | Jan 2014 | A1 |
20140037802 | Cardoso | Feb 2014 | A1 |
20140099388 | Wang | Apr 2014 | A1 |
20140242239 | Boggavarapu | Aug 2014 | A1 |
20150050391 | Rapparini | Feb 2015 | A1 |
20160174590 | Boggavarapu | Jun 2016 | A1 |
Number | Date | Country |
---|---|---|
853634 | Oct 1970 | CA |
1233690 | Mar 1988 | CA |
2012891 | Sep 1991 | CA |
2276927 | Jan 2000 | CA |
2516417 | Sep 2004 | CA |
2689804 | Mar 2008 | CA |
2686347 | Dec 2008 | CA |
2807489 | Feb 2012 | CA |
2824199 | Aug 2012 | CA |
2759782 | Nov 2012 | CA |
2801236 | Mar 2013 | CA |
202537195 | Nov 2012 | CN |
202960136 | Jun 2013 | CN |
4234991 | Apr 1994 | DE |
0047169 | Mar 1982 | EP |
0145499 | Jun 1985 | EP |
0432126 | Jun 1991 | EP |
D678244 | Oct 1995 | EP |
1593329 | Nov 2005 | EP |
1859683 | Nov 2007 | EP |
2230195 | Sep 2010 | EP |
2345351 | Jul 2011 | EP |
2409608 | Jan 2012 | EP |
1208782 | Aug 2014 | EP |
2225095 | Nov 1974 | FR |
2930522 | Oct 2009 | FR |
803486 | Oct 1958 | GB |
962038 | Jun 1964 | GB |
1427949 | Mar 1976 | GB |
2074838 | Nov 1981 | GB |
2128068 | Apr 1984 | GB |
1480997 | Jul 1997 | GB |
2495642 | Apr 2013 | GB |
662737 | Mar 1994 | JP |
11171249 | Jun 1999 | JP |
20100127907 | Dec 2010 | KR |
20140031693 | Mar 2014 | KR |
0145616 | Jun 2001 | WO |
03082065 | Oct 2003 | WO |
2004083071 | Sep 2004 | WO |
2009114119 | Sep 2009 | WO |
2010013146 | Feb 2010 | WO |
2010066705 | Jun 2010 | WO |
2010085824 | Aug 2010 | WO |
2011095518 | Aug 2010 | WO |
201006516 | Sep 2010 | WO |
2010137956 | Dec 2010 | WO |
2012009605 | Jan 2012 | WO |
2012031106 | Mar 2012 | WO |
2012069505 | May 2012 | WO |
2014056862 | Apr 2014 | WO |
2014112556 | Dec 2014 | WO |
Entry |
---|
International Search Report and Written Opinion in PCT/CA2014/051107 dated Feb. 9, 2015. |
Esegroth, “Inert gas: safeguard of quality”, Vacuum, abstracts, vol. 2, Issue 1, p. 97, Dec. 31, 1952. |
Anderson et al., “The diffusion kinetics of carbon dioxide in fresh roasted ground coffee”, Journal of Food Engineering, vol. 59, Issue 1, pp. 71-78, Aug. 2003. |
Number | Date | Country | |
---|---|---|---|
20150140184 A1 | May 2015 | US |
Number | Date | Country | |
---|---|---|---|
61906513 | Nov 2013 | US |