a,
5
b and 5c, show details of scraper designs.
The present invention is in the technical field of removing fine particles from water. The fine particles can include metal precipitates, organic solids, inorganic solids, clays, silts, oil and grease and any other hard to remove fine solids. The invention is applicable to industrial wastewater, municipal wastewater, potable water, combined sewer overflow, storm water, process water, cooling water, ground water, and any other waters that require clarification to remove fine particles. The term “water” as used herein includes water and all forms of wastewater.
The invention relates to the use of magnetic seeding and separation technology where a fine magnetic seed material is added to the water along with an organic flocculating polymer. The organic flocculating polymer binds the non-magnetic pollutant particles to the magnetic seed material and then the composite particle, or magnetic floc. In some embodiments, a flocculating polymer may not be used but rather the sorption properties of the magnetic particles are employed to extract pollutants from the water and attachë the pollutants to the magnetic particles. In some cases, certain scalants may be removed by employing magnetic particles whose surfaces provide sites for sacrificial scaling thus preventing or reducing scaling on downstream equipment. In any case, the invention includes utilizing the magnetic properties of the magnetic particles, bound with pollutants—be they in the form of flocs, particles with pollutants sorbed therewith, or scaled magnetic particles—to magnetically remove the pollutants from the water.
Collectors employing magnetized surfaces are used to attract magnetic particles and their burden of pollutants. The magnetized surfaces are generally moving magnetized surfaces to facilitate continuous transport of collected particles out of the water. The surfaces are equipped with permanent magnets or electromagnets to provide the required magnetic strength to remove the magnetic particles. The magnetic strength of the magnets used ranges approximately 0.1 to 10 tesla. Permanent magnets may be more commonly 0.5 to 1.5 tesla while electromagnets may be configured with a strength up to about 10 tesla.
The magnetically collected magnetic floc are further processed to form separate streams of sludge to be ejected as a waste product and cleaned magnetic seed to be recycled and reused in the water treatment system.
The process of using magnetic seeding and separation technology for removing fine pollutant particles sometimes involves attaching the fine pollutant particles to the magnetic seed material with a flocculating polymer. In a traditional flocculation process, the aim is to produce a large floc that will settle rapidly by gravity. To assure this floc formation, it is important to have the proper mixing energy. The measure of this mixing energy is referred to as the root-mean-square velocity gradient G measured in negative seconds (sec−1). For optimum floc formation in a gravity separation situation, the G value should generally not exceed approximately 50 sec−1. Exceeding this level increases the speed of mixing and the formation of microfloc, but will shear the floc and prevent the development of large macroflocs that will settle rapidly.
Magnetic seeding and separation is different. Since the size of floc is not important because gravity settling is not employed, the G value can be greatly increased because all that is needed is for the magnetic and non-magnetic particles to collide quickly in the presence of the flocculating polymer. Therefore the G value can be increased to about 100 sec−1 and higher, which will speed the flocculation and therefore clarification process. The G value should generally be greater than about 50 sec−1 and less than about 1000 sec−1 but more preferably in the range of about 100 to about 500 sec−1 in magnetic seeding and separation.
Various forms of magnetic seed material may be used. Among the forms is magnetite, a ferromagnetic form of ferric oxide. Other forms include but are not limited to zero valent iron, ferrosilicon, maghemite, jacobsite, trevorite, magnesioferrite, magnetic sulfides like pyrrohotite and greigite, and any other ferromagnetic and ferremagnetic materials that show strong attraction to a magnetic field.
Magnetic seed particle sizes in the range of 30 to 50 microns, as would be characteristic of 90% of material passing a 355 mesh, may be commonly used as magnetic seed for binding or sorbing pollutant particles for removal. Further, for various sorption processes, those that for example may be useful for removing very fine or nano pollutant particles, magnetic seed sizes may range down to approximately 20 nanometers. Magnetic seeding in treatment vessels such as flocculation tanks is typically done at a concentration by weight of magnetic seed of about 0.5 to 1% and which in some cases may up to about 3-5%.
With reference to the drawings, a final magnetic collector 4 is configured to maximize the residence time in the flocculation chamber while maximizing the surface area of the final magnetic collector. One way to do this is to locate the floc chamber in the center and bottom of a cylindrical tank and then to extend the final collector around the perimeter of the upper regions of the tank, as illustrated in
The tank can be a circular cylindrical tank with a circular final magnetic collector 4 extending around the perimeter of an upper portion of a treatment tank 5, as illustrated in
Scaling up the tank design for high flow rate applications requires a larger final magnetic collector 4 which is most easily accommodated by placing it in proximity to the perimeter of the tank 5. The efficiency of final magnetic collector 4 is reported as the Surface Overflow Rate (SOR) which is measured in gallons per minute per square foot (gpm/ft2) of surface area. The SOR for a traditional gravity clarifier is 0.25 to 1.00 gpm/ft2. The SOR for the present invention ranges from 10 gpm/ft2 to 300 gpm/ft2 which makes magnetic separation technology more effective than gravity clarification.
Referring in particular to
A first magnetic drum collector is used to collect the composite magnetic particles, or magnetic floc, comprising the pollutants to be removed, the flocculant, and the magnetic seeds. The first magnetic drum collector or a second magnetic drum collector can be used clean the pollutant and flocculant from the magnetic seed material so the seeds can be reused. For example, a first magnetic drum rotating about a horizontal axis is submerged into the floc tank where the first magnetic drum collects the composite magnetic floc. Typically, the magnetic floc is scraped off the magnetic drum into a vertical shear tank where fine pollutant particles are detached from the magnetic seed by a vigorous mixing action. The clean magnetic seed is then collected on a second magnetic drum collector and scraped back into the floc tank.
Mounting the shear tank in a vertical position causes a surging in the tank, especially if the tank is square, when the magnetic floc is scraped into the tank. This surging action causes an uneven amount of magnetic seed to be deposited on the second magnetic drum collector. There are also some layout problems caused by use of a vertical shear tank; notably, if a relatively wide first magnetic drum collector is used for removing magnetic floc from the floc tank, it will not match up well to a much narrower vertical shear tank. A better configuration is to mount the shear tank in a horizontal position, parallel to the first magnetic drum collector, and to make the shear tank of similar width to the first and second magnetic drum collectors. Doing so also avoids the surging found in a vertically mounted shear tank.
The goal is to use only one magnetic collector to remove magnetic floc from the floc tank and return cleaned magnetic seed into the floc tank. Magnetic floc collected on the magnetic collector are scraped off by a first removal device, or scraper, and transferred into a shearing device. The shearing device shears the magnetic flocs to free the magnetic seed from the floc, producing a slurry of magnetic seeds, flocculant, and pollutants, the flocculant and pollutants essentially forming a sludge It is necessary to separate the magnetic seed from the sludge so the magnetic seed can go back into the floc tank for re-use, while the separated sludge is disposed. It was observed that a blade, or retainer, pressing against the magnetic drum will squeeze or compress the magnetic seed together, urging any remaining sludge away from the seed and leaving the seed substantially dry. The sludge will then overflow over the blade, or retainer, to be discharged, while the compressed and substantially dry magnetic seed will be removed by another scraper and returned to the floc tank for re-use. This approach employs the same magnetic collector to remove magnetic floc from the water and to separate the magnetic seed from the sludge after shearing. One magnetic drum is eliminated, which reduces cost, space requirements, and mechanical complexity of the system.
Magnetic separation systems have typically involved continuous flow applications. In the case of the magnetic batch system shown in FIGS. 4 and 6-11, all treatment functions are carried out in the same tank, using a single variable speed motor and a mixing and shearing assembly.
With reference to
As noted above, the batch treatment system shown in
To treat water with the batch treatment system shown in
After sufficient flocculation has occurred, the floc 60 are settled to the bottom of tank 42. Settlement can be achieved in various ways. In one embodiment, the motor 41 is turned off and the magnetic floc 60 is allowed to settle by gravity to the bottom of the tank 42. In another embodiment, the motor 41 is operated at a relatively slow speed, thereby providing gentle mixing, and the magnets 46 are positioned closely adjacent the bottom of the tank 42 and the magnetic attraction caused by the magnets 46 causes the magnetic floc 60 to settle to the bottom of the tank. In this embodiment, the magnetic field applied by the magnets 46 attract the magnetic floc to the lower collection surface of the tank 42.
Once the clarified water has been decanted from the tank 42, the magnets 46 are moved to their inoperative position shown in
Once the shearing phase of the batch process is completed, the magnets 46 are moved back to their operative position, a position relatively close to the bottom of the tank 42. This is illustrated in
Once the sludge has been discharged, the magnetic seed remains in the bottom of the tank 42. This is illustrated in
a shows a removal device or scraper 51 that includes a ferromagnetic material disposed such that the scraper is attracted to a magnetic drum 52 to remove collected magnetic floc from the drum. A magnetic attraction, or force, acts between drum 52 and scraper 51, and maintains a constant pressure between the drum and the scraper 51 over the entire length of the scraper, thus providing good scraping efficiency. This also provides a self adjusting feature to allow compensation for wear. The magnetic attraction, or force is independent of wear of the drum 52 or the scraper 51. Thus as either the drum 52 or the scraper 51 wears, the scraper is kept in contact with the drum with essentially the same force. Moreover, the magnetic force has an intensity that is generally constant over the area of contact or approach between the scraper 51 and the drum 52. This facilitates maintaining uniform contact over the area of contact or approach. This uniform contact is also therefore obtainable even in cases where the scraper 51 or drum 52 wears in a pattern that produces irregularities in the contact area. This design enhances the consistent and continuous cleaning of permanent magnet collectors.
It should be noted, that scraper 51 also functions to convey removed magnetic floc from the magnetic drum 52. That is, since scraper 51 is magnetically held adjacent to or in contact with the magnetic drum 52, magnetic floc scraped from the drum 52 tends to move down the upper surface of scraper 51. Thus, scraper 51 not only removes the magnetic floc from magnetic drum 52, but also directs or channels the removed magnetic floc away from the magnetic drum. As discussed elsewhere herein, the removed magnetic floc is typically directed to a shear device where the magnetic floc is sheared producing magnetic seed and sludge.
b and 5c show a removal device or scraper 55 that can be easily removed and which does not impede the flow of water between disks of a rotary magnetic collector that is disposed in a tank of water to collect magnetic floc. A plurality of scrapers 55 is preferably disposed between adjacent disks 53, so as to engage and scrape magnetic flocs from the opposed faces of the adjacent disks. Each scraper 55 has a hook end 55A by which it is suspended from a center shaft 54 holding the disks of the magnetic collector. An opening 55B formed by hook end 55A facilitates easy installation and removal of the scraper from above the magnetic collector for convenience. Preferably, the magnets are maintained stationary on disk (not shown) sandwiched between two plastic, or other non-magnetic material-based, rotating disks. Typically, magnets are omitted from a lower sector of the disks, forming a magnet-free sector 53A on each disk. This facilitates magnetic floc detaching at sector 53A of the disk surface where the scrapers 55 are be located. The scrapers 55 extend radially beyond the magnetic collection disks so that they can engage a stop or retaining bar 56 that prevents each scraper from moving out of the magnet-free sector 53A at the bottom of the magnetic collection disks. This scraper 55 is hung from the center shaft 54 of the disk collector and mounted in a vertical position so it does not impede the flow of water through the magnetic disk collector. In one embodiment, the general direction of flow is generally parallel to scrapers 55. Each space between disks includes one scraper, which can be arranged to scrape the opposed surfaces of adjacent disks.
The present invention may, of course, be carried out in other specific ways than those herein set forth without departing from the scope and the characteristics of the invention. The present embodiments are therefore to be construed in all aspects as illustrative and not restrictive and all changes coming within the meaning and equivalency range of the appended claims are intended to be embraced therein.
This application claims priority under 35 U.S.C. §119(e) from the following U.S. provisional application: Application Ser. No. 60/847,372 filed on Sep. 27, 2006. That application is incorporated in its entirety by reference herein.
Number | Date | Country | |
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60847372 | Sep 2006 | US |