This invention was supported in full or in part with an award from the Kentucky Science and Technology Corporation under the Kentucky Alternative Fuel and Renewable Energy Fund Program.
1. Field of the Invention
The present invention relates generally to gasifiers and, more particularly, with controlling operating efficiency of a gasifier.
2. Description of Related Art
Gasifier reactors are relatively simple in construction; however, the chemistry and physics involved in their operation can be quite complex and are still not well understood. Conventional thermal gasification processes oxidize a portion of a fuel feedstock (containing predominantly carbon, hydrogen, and in some cases oxygen) at an elevated temperature to provide heat energy in order to drive chemical reactions which convert carbon and hydrogen-containing compounds to carbon monoxide, hydrogen, carbon dioxide, and methane gas. Gasification takes place in two main steps. First, the fuel is partially combusted to form fuel gas and charcoal or char in a flaming pyrolysis zone. In the second step, a fraction of the carbon dioxide and water produced in the first step are chemically altered or reduced by the char, forming carbon monoxide and hydrogen. Gasification processes typically utilize temperatures above approximately 1400-1480° F. to minimize the formation of tars and high molecular weight hydrocarbons in the product gas. This gas, commonly called “producer gas” or “syngas”, contains hydrogen (18-30% by volume), carbon monoxide (18-25%), carbon dioxide (8-12%), methane (2-3%), water, nitrogen (if air is used as the oxidizing agent) and various contaminants such as small char particles, ash, tars and oils. The resulting producer gas is combustible with a low calorific value that can be used as a fuel for turbine and gas engines. Many gasification methods are available for producing fuel gas such as updraft, downdraft, and fluidized bed type processes.
The partial oxidation of the fuel feedstock can be carried out using air, oxygen, steam or a mixture there of. Air-blown gasification produces a low heating value gas (100-180 Btu/ft3 higher heating value) suitable for boiler, engine and turbine operation but not for pipeline transportation due to its low energy density. Oxygen gasification produces a medium heating value gas (250-500 Btu/ft3 higher heating value) suitable for limited pipeline distribution and as synthesis gas for conversion. Such a medium heating value gas can also be produced by pyrolytic or steam gasification.
The gasification of biomass, which includes crop residues, wood mulch, animal wastes, and manure, can be further complicated by the presence of sulfur, chlorine, and organic nitrogen. For example, poultry litter (PL), typically consists primarily of wood mulch, manure, and animal feed. Based on the ultimate analyses of PL, the simplified gasification reaction for can be summarized by the following stoichiometric equation:
C1H1.6O0.62N0.1S0.001Cl0.001+0.34O2+1.27N2→aCO2+(1−a)CO+bH2O+cH2+dNH3+0.001H2S+(1.27+g)N2
The yields and distribution of CO2, CO, H2O, and H2 depend on numerous reactor operational and design parameters. Calculating the concentrations of these compounds in order to measure the caloric value of the producer gas as an indicator of the processes' efficiency can require complex and expensive techniques such as gas chromatography or mass spectroscopy which is unfeasible for many smaller-scale gasifier operations.
Thus, there remains a need for a simple, economical and speedy method for measuring and controlling the thermal efficiency of a gasifier system.
Embodiments of the present invention relate to a method and apparatus that detects the thermal conductivity (TC) of a producer gas as a way to measure the thermal efficiency of a gasifier system and to control the efficiency of the gasifier system.
It is understood that other embodiments of the present invention will become readily apparent to those skilled in the art from the following detailed description, wherein it is shown and described only various embodiments of the invention by way of illustration. As will be realized, the invention is capable of other and different embodiments and its several details are capable of modification in various other respects, all without departing from the spirit and scope of the present invention. Accordingly, the drawings and detailed description are to be regarded as illustrative in nature and not as restrictive.
Various aspects of embodiments of the present invention are illustrated by way of example, and not by way of limitation, in the accompanying drawings, wherein:
The detailed description set forth below in connection with the appended drawings is intended as a description of various embodiments of the invention and is not intended to represent the only embodiments in which the invention may be practiced. The detailed description includes specific details for the purpose of providing a thorough understanding of the invention. However, it will be apparent to those skilled in the art that the invention may be practiced without these specific details. In some instances, well known structures and components are shown in block diagram form in order to avoid obscuring the concepts of the invention.
One useful parameter for characterizing a gasifier system is the quantity of air or other oxidizer supplied to the gasifier or the ratio of air rate to the fuel fed or consumed. Typically for air-blown gasification, the air-fuel ratio is expressed as a dimensionless number known as the air equivalence ratio, φ:
Where, msupplied is the mass rate of the air supplied to the gasifier and mstoich is the theoretical air mass rate required for complete combustion of the fuel. For gasification, φ is typically in the range of 0.25 to 0.5 depending on the fuel feedstock chemical composition and moisture content
Depending on the type of gasification plant, the overall gasification efficiency (i.e., the quality and quantity of the resulting fuel gas or producer gas) is a parameter that may beneficially be used by the gasifier control system. Gasification with air is the more widely used technology for small-scale applications since there is not the cost or hazard of oxygen production. Another quantity, the gasifier efficiency, describes the heating value of the gas stream in relation to that of the higher heating value of the fuel stream. With air gasification, the gasifier efficiency, is typically in the order of about 45 to 85%, typically about 70% for a relatively dry fuel.
The information beneficial for calculating the gasification efficiency includes: the energy content and volumetric rate of the resulting producer gas; the fuel consumption rate; and the fuel higher heating value. As mentioned earlier, quantifying the producer gas caloric value requires a relatively detailed chemical analysis of the gas. It is often assumed that the fuel consumption rate is equal to the fuel feed rate; however, this assumption is valid only for a gasifier operating at a steady-state condition. Additionally, the higher heating value of the fuel can vary substantially and requires off-line analytical tests.
The caloric value of the producer gas can be determined online by gas chromatography (GC) or by mass spectroscopy (MS) to quantify the concentrations of carbon monoxide, hydrogen, methane, and other hydrocarbons gases. Therefore, the considerable capital costs of this type of analytical equipment can make smaller-scale gasifier operations economically unfeasible. Therefore, embodiments of the present invention offer an alternative approach.
For example, embodiments of the present invention include a method for measuring the thermal efficiency of a gasifier system with a simple instrument that detects the thermal conductivity (TC) of the producer gas. One resulting benefit is that the lower heating value of the producer gas and fuel feedstock and the fuel consumption rate are not required for measuring gasification efficiency. The signal from a TC cell, relative to that of a reference gas such as air, is used to estimate the optimal operating conditions for maximizing gasification efficiency. Accordingly, the real-time signal from the TC cell can be used in conjunction with a process controller to modulate air or other oxidizer such that the efficiency of the gasifier may be optimized continuously. Additionally, the real-time signal from the TC could be used to shutdown the producer gas supply to heaters or generator engines if the quality of the gas is not to specification as a result of a process upset.
The thermal conductivities of the major gas compounds that make up a typical producer gas along with air are listed below in Table 1. Air is included in the table because it can be used as a reference gas. However, one of ordinary skill will recognize that other gases with known thermal conductivities may be used as reference gasses as well without departing from the scope of the present invention Embodiments of the present invention beneficially utilize the fact that the thermal conductivity of hydrogen is nearly an order of magnitude higher than that of any other of the producer gas constituents.
The total thermal conductivity of the gas produced will therefore vary in proportion to the hydrogen content. The art and science of thermal conductivity detectors (TCD) is known. For example, a TCD typically consists of a filament of platinum or tungsten wire situated in the effluent gas and heated by an electrical current. In the presence of the carrier gas alone the wire comes into thermal equilibrium at a given temperature. If placed in the arms of a Wheatstone bridge in which another arm contains a similar sensor situated in a reference stream of the same gas the bridge can be electrically balanced. When solute vapor is eluted from the column, the thermal conductivity and the specific heat of the gas surrounding the heated wire, changes. This change in thermal properties of the system results in a change in heat loss from the wire, a consequent change in wire temperature and wire resistance and the bridge becomes out of balance. The out-of-balance signal is amplified and fed to a recorder.
In the discussion that follows, a specific example of a biomass feedstock and other processing parameters are provided. This specific example is discussed so as to help illuminate embodiments of the present invention by way of a concrete example. However, embodiments of the present invention are not limited to only these specific values, parameters and materials discussed in the example.
The figures that follow relate to an example system that includes an air-blown adiabatic gasifier reactor using a wood biomass waste material containing 15 wt % moisture. The resulting producer gas can for example, be filtered and dried to a 120° F. dew point. One of ordinary skill, however, will recognize that other types of gasifiers, other biomasses, and producer gas handling techniques may be used without departing from the scope of the present invention.
Referring now to
In
For example, referring now to
Much like the earlier figures,
In the example displayed in
This type of control system can be shown schematically in
Where TC, is the most recent thermal conductivity signal and TCt-1 is the signal from the previous sample period. Likewise, Tgas t and Tgas t-1 are the most recent and previous temperature samples from the gasifier combustion zone, respectively. The sample timing interval may advantageously be between about 1 and about 10 seconds; although other time periods may be used without departing from the scope of the present invention.
The output signal 432 from the TCD device 430 measuring the producer or syngas gas 434 thermal conductivity is compared 436 to a set point constant that is predetermined to be the optimal for maximum hydrogen content and gasifier thermal efficiency. The control action (either direct or reverse acting) of the TC controller 438 depends on the sign of λ. If positive, the TC controller will proportionally increase the temperature set point 440 for the gasifier temperature controller. This control action would continue until the high temperature is obtained. If λ is negative, this would indicate that the controller is below the TC maximum; therefore, the set point signal is decreased proportionally until returning to the minimum temperature set point or until a TC maximum is found. For each case of λ, the amount of the temperature set point adjustment will depend on the error of the TCD signal with the optimum TC set point and the constants set in the proportional-integral-derivative (PID) TC controller.
The output of the TC controller 438 is a set point of temperature 440, within the bounds of the Tsp low and Tsp high, to a gasifier temperature controller 442. This secondary controller 442 outputs a control signal to a final control element such as an air control valve 446 or air fan speed controller in order to regulate the mass of air entering the gasifier reactor and thus changing the AER. Hence, the gasifier process is influenced and a change in both producer gas temperature 448 and thermal conductivity (due to a change in hydrogen content in the gas) is measured. The control loop is completed by recalculating a new λ for the TC controller.
Referring now to
Referring now to
Referring now to
The sampled producer 651 enters the TCD system via a pump 652 through a filter 654. The sample gas is modulated by a valve 656 and directed to a flow indication device 658 such as a rotameter. Simultaneously, a reference gas 671 such as air, is pumped through a similar network containing a pump 672, filter 672, metering valve 676, and reference flow measuring device 678. Beneficially, the flow rate of the sample and reference gas, should be equalized with their respective metering valves. The sample and reference gases may be heated within the analyzer enclosure and may be done so at a magnitude such that their temperatures are within one °F. as measured from temperature sensors 658 and 678. However, such heating is optional. The sample stream is piped via line 662 into a chamber 692 that contains an electrical resistive element such as a thermistor or a filament typically used in thermal conductivity detection devices. Likewise, the sample gas is piped via line 682 into a chamber 694 that contains a thermistor of substantially identical specifications to that of 692. For example, thermistors 682 and 692 may be designed to operate at temperatures between 120 and 212° F. The filaments or thermistors of the sample and reference cells can be connected in a Wheatstone bridge configuration 690 with substantially identical balance resistors 696 and 698. The thermistor or filaments are energized with a small electric direct current from a power supply 700 thereby heating the elements slightly above the temperature of the sample and reference gases.
The heat dissipated from the sample resistor 692 element will be proportional to the thermal conductivity of the fuel gas (compared to the air reference stream) with all other factors being substantially equal. Consequently, there will be a resistance difference between the reference and sample resistor elements in the respective conductivity cells. This resistance difference can be converted to a voltage signal via a voltage divider such as the Wheatstone bridge 690 which as understood by those skilled in electronics and thermal conductivity instrumentation. The resulting voltage imbalance is amplified via a difference operational amplifier circuit 710.
The signal output 712 has the advantage of providing relatively real-time (e.g., less than a 10 second response time) information regarding the producer gas quality and the gasifier efficiency. In comparison a state-of-the-art GC system that would have a sample response in the order of minutes and require expensive and difficult-to-operate equipment.
The previous description is provided to enable any person skilled in the art to practice the various embodiments described herein. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments. Thus, the claims are not intended to be limited to the embodiments shown herein, but are to be accorded the full scope consistent with each claim's language, wherein reference to an element in the singular is not intended to mean “one and only one” unless specifically so stated, but rather “one or more.” All structural and functional equivalents to the elements of the various embodiments described throughout this disclosure that are known or later come to be known to those of ordinary skill in the art are expressly incorporated herein by reference and are intended to be encompassed by the claims. Moreover, nothing disclosed herein is intended to be dedicated to the public regardless of whether such disclosure is explicitly recited in the claims. No claim element is to be construed under the provisions of 35 U.S.C. §112, sixth paragraph, unless the element is expressly recited using the phrase “means for” or, in the case of a method claim, the element is recited using the phrase “step for.”
The present application claims priority to provisional Patent Application Ser. No. 61/072,471 filed Mar. 31, 2008, the disclosure of which is incorporated by reference herein, in its entirety.
Number | Date | Country | |
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61072471 | Mar 2008 | US |