The present invention relates to a method and an apparatus for cooling a high-temperature reduced-iron agglomerate that is reduced in, and discharged continuously from, a reducing furnace, in reduced-iron production equipment, to produce a reduced-iron agglomerate from an iron oxide agglomerate.
Here, the above method and apparatus include, for example, a method and an apparatus for cooling a reduced-iron agglomerate produced in a rotary hearth furnace, for reduction, wherein a reduced iron is produced by processing dust and sludge containing metallic oxide generated in the metal refining industry and the metal processing industry.
As a method for cooling a reduced-iron agglomerate discharged from a reduced-iron production equipment, a method has heretofore been put into practical use wherein a reduced-iron agglomerate is immersed and cooled in a water bath, thereafter taken out from the water bath with a conveyer, discharged directly to an earth floor and stored in stacks, and then, according to circumstances, conveyed and charged into an electric arc furnace.
However, the reduced-iron agglomerate produced by this immersing and cooling method has a high water content and, when it is charged directly into molten metal, there is the danger of a water vapor explosion. Therefore, it has been used only for charging into an electric arc furnace. Moreover, the reduced-iron agglomerate has the problems of pulverization and reoxidation.
Japanese Patent No. 3145834 discloses a method for producing reduced-iron briquettes wherein reduced iron produced by a direct reduction ironmaking method is formed into briquettes by a briquette machine and the reduced-iron briquettes are cooled slowly, at a cooling rate of 150 to 250° C./min., with a water spray.
However, this method is a method wherein high-temperature reduced-iron briquettes are cooled slowly with a water spray in order to suppress cracking of the reduced-iron briquettes and not a method wherein a reduced-iron agglomerate discharged from a reduced-iron production equipment, such as a rotary hearth furnace, is cooled. Moreover, this method does not take an appropriate water content of the reduced-iron agglomerate into consideration.
Further, Japanese Patent No. 3009661 discloses a method wherein high-temperature reduced-iron briquettes having been heated and reduced are cooled with water so that an average cooling rate may be in the range from 1,500 to 500° C./min. during the time when the surface temperature decreases from 650° C. to 150° C.
However, this method is one that is related to the cooling of reduced-iron pellets that are different in size and features from an agglomerate such as briquettes as intended in the present invention. Therefore, this method cannot be applied as it is.
In addition, though the temperature of a reduced-iron agglomerate discharged from a rotary hearth furnace is about 1,000° C., the patent describes neither a cooling method and a cooling rate in the temperature above 650° C. nor a concrete cooling means even in the temperature below 650° C., and further pays no attention at all to the water content of agglomerate.
The object of the present invention is, by solving the aforementioned problems of prior art, to provide a cooling method and a cooling apparatus for regulating the temperature at the center, and the water content, of a reduced-iron agglomerate to appropriate ranges and also to provide the following concrete means for solving the technological problems: to suppress the reoxidatioin of a reduced-iron agglomerate caused by the atmospheric air by means of rapidly cooling the reduced-iron agglomerate, at about 1,000° C., discharged from a reduced-iron production equipment such as a rotary hearth furnace to a temperature below 300° C.; to make it possible to charge the reduced-iron agglomerate into molten metal, to decrease the water evaporation energy during melting by means of controlling the water content of the reduced-iron agglomerate after the cooling to 6% or less; and to suppress the pulverization and the reoxidation of the reduced-iron agglomerate by means of optimizing a cooling time.
The present invention solves the aforementioned problems and the gist of the present invention is as follows;
(1) A method for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
(2) A method for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
(3) A method for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
(4) An apparatus for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
(5) An apparatus for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
(6) An apparatus for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
(7) An apparatus for cooling a reduced-iron agglomerate according to the item (6), characterized in that said spread width of cooling water in the conveying direction B and said spread width thereof in the conveyer width direction w satisfy the following expression (3),
W≧2×B (3),
where, W is the spread width of cooling water in the conveyer width direction and B is the same in the conveying direction.
(8) An apparatus for cooling a reduced-iron agglomerate according to any one of the items (4) to (7), characterized in that said spread width of cooling water in the conveyer width direction W and the width of said conveyer CW satisfy the following expression (5),
CW≦W (5)
where, CW is the width of a conveyer and W is the spread width of cooling water in the conveyer width direction.
(9) An apparatus for cooling a reduced-iron agglomerate in a reduced-iron agglomerate production equipment wherein an iron oxide agglomerate is reduced in a reducing furnace and discharged as a reduced-iron agglomerate characterized by:
1) The present invention is explained on the basis of the cooling apparatus shown in
An iron oxide agglomerate is reduced in a rotary hearth furnace 13 used as a reducing furnace and the reduced-iron agglomerate thus produced is discharged continuously from an outlet 8 to discharge the reduced-iron agglomerate. The discharged high-temperature reduced-iron agglomerate 5 is cooled with water sprayed through a plurality of spray nozzles 1 while being conveyed on a conveyer 6 in a cooling apparatus 16 placed in connection with the outlet 8, then discharged from another outlet 7 to discharge the reduced-iron agglomerate, and conveyed to a storage installation, or the like, not shown in the figures.
Each of the spray nozzles 1 is attached at prescribed intervals to a nozzle header 2 installed in parallel with the conveying direction of, and above, the conveyer 6.
The spray nozzles 1, the spray header 2 and the conveyer 6 are covered by a casing 15 and, at the top end of the casing 15, the outlet 7 is placed to discharge the cooled reduced-iron agglomerate 5 and, at the bottom end thereof, the outlet 9 is placed to discharge sludge formed by spraying water on the reduced-iron agglomerate 5.
Water is supplied to the spray header 2 through a feed water pipe 3 as shown in
As explained above, a cooling apparatus according to the present invention is an apparatus that intermittently cools a reduced-iron agglomerate 5 on a conveyer 6 by installing a plurality of spray nozzles 1 above the conveyer 6 at intervals in the conveying direction of the reduced-iron agglomerate 5 and ejecting spray water continuously through each of the spray nozzles. The condition that assures intermittent cooling is “B<P” as it is understood from
By intermittent cooling, the surface temperature of a reduced-iron agglomerate 5 on a conveyer 6 lowers while changing for example as shown in
Then, next cooling is commenced from the balanced temperature with the next spray water. By repeating such steps, the reduced-iron agglomerate 5 is cooled to 100° C. to 300° C. in accordance with such a cooling pattern as shown in
The reason why cooling can be accomplished with a small unit consumption of water is presumably that the internal transfer of heat in a reduced-iron agglomerate is faster than that in the case of applying spray water unilaterally from outside.
Further, in the case of the intermittent cooling of the reduced-iron agglomerate, the water sprayed on the surface thereof evaporates and the surface dries due to the rise of the surface temperature between cooling and the subsequent cooling. By repeating such a pattern, the surface of the reduced-iron agglomerate is cooled to a target discharge temperature while water spraying and evaporation are repeated alternately. By so doing, the reduced-iron agglomerate 5 discharged from a cooling apparatus according to the present invention can have a water content of 6% or less.
It is preferable that the water content of a reduced-iron agglomerate is low in order to reduce the energy consumption during melting in an electric arc furnace or the like and a preferable water content is also 6% or less in order to prevent a water vapor explosion at the time when the reduced-iron agglomerate is charged into molten metal.
A preferable temperature of a reduced-iron agglomerate at the time of discharge after cooling is in the range from 100° C. to 300° C. in the present invention. A reduced-iron agglomerate discharged from a rotary hearth furnace at about 1,000° C. is cooled to a intermittent water spray.
In the general arrangement of cooling nozzles, as shown in
In this arrangement, the temperature difference between the interior and the surface of a reduced-iron agglomerate (a high temperature at the interior and a low temperature at the surface) increases due to the continuous water spray and a larger amount of water is required in comparison with the intermittent water cooling according to the present invention. When a water amount is increased in order to cool a reduced-iron agglomerate sufficiently in the interior, water remains on the surface that has already been cooled to a low temperature and the water content exceeds 6%.
Further, when cone spray nozzles are used as shown in
The first cooling apparatus according to the present invention is configured so that the relation between the spread width of spray water in the conveying direction “B” and the intervals of installed spray nozzles “P” may satisfy the aforementioned expression (2), namely 1.2×B≦P≦10×B.
The condition “1.2×B≦P” is determined as the condition that makes sure that a sprayed range 1-1 is firmly separated from the sprayed range of an adjacent spray nozzle 1 as shown in
The condition “P≦10×B” is determined as the condition that makes sure that the temperature rise caused by the internal heat of a reduced-iron agglomerate is not saturated during the time between cooling and the subsequent cooling and effective cooling is secured.
Next, the second cooling apparatus according to the present invention is configured so that the relation between the spread width of spray water in the conveying direction “B” and the spread width thereof in the conveyer width direction “W” may satisfy the aforementioned expression (3), namely W≧2×B.
Under this condition, by employing, for example, flat spray nozzles that make the sprayed ranges 1-1 flat, the spread width of spray water in the conveying direction “B” is nearly constant in the conveyer width direction, therefore the variation of the cooling state in the conveyer width direction decreases, and resultantly intermittent cooling can be carried out effectively.
Further, the first and second cooling apparatuses according to the present invention are configured so that the relation between the spread width of spray water in the conveyer width direction “W” and the width of the conveyer “CW” may satisfy the aforementioned expression (5), namely CW≦W.
That is, by building up the relation between “W” and “CW” as shown in
In
As a result, though water is sprayed continuously through each of the spray nozzles 1, the water is intermittently sprayed on the reduced-iron agglomerate 5 conveyed continuously on the conveyer 6. The cooling pattern of intermittent water spray as viewed from agglomerate is, for example, as shown in
In this way, a high-temperature reduced-iron agglomerate loaded on a conveyer 6 is cooled from top and bottom by a plurality of nozzles 1 and 1a installed above and below the conveyer 6. By so doing, it becomes possible to load a reduced-iron agglomerate in plural layers on a conveyer 6 and to improve productivity.
As a conveyer 6, a tabular type or a wire-gauze type conveyer is adopted and, in the case where a reduced-iron agglomerate is cooled with nozzles installed above and below a conveyer 6, a cooling efficiency further improves when a wire gauze type conveyer 6 is adopted. Further, with regard to the size of the openings of the wire gauze, any size may be acceptable, as long as a reduced-iron agglomerate does not fall through when it is loaded thereon, but a preferable size of the openings is about 10 mm.
Another present invention is explained on the basis of the cooling apparatus shown in
Likewise,
Water is supplied to a spray header 2 through a feed water pipe 3 as shown in
In the present invention, as explained above, a plurality of spray nozzles 1 are installed above a conveyer 6 at prescribed intervals in the conveying direction, of the reduced-iron agglomerate 5, the relation between an ejecting time “T1” and an ejection stopping time “T2” of each of the spray nozzles 1 is arranged to satisfy the expression “1.2×T1≦T1+T2≦10×T1” and the reduced-iron agglomerate 5 on the conveyer is cooled intermittently (on-off) as shown in
By employing intermittent cooling, the surface temperature of a reduced-iron agglomerate 5 on a conveyer 6 lowers while changing, for example, as shown in
Then, the next cooling commences, from the balanced temperature, with the next spray water. By repeating such steps, the reduced-iron agglomerate 5 is cooled to 100° C. to 300° C. in accordance with such a cooling pattern as shown in
The reason why cooling can be accomplished with a small unit consumption of water is presumably that the internal transfer of heat in the reduced-iron agglomerate is faster than that in the case of applying spray water unilaterally from outside.
Further, in the case of the intermittent cooling of the reduced-iron agglomerate, the water sprayed on the surface thereof evaporates and the surface dries due to the rise of the surface temperature between one cooling and the subsequent cooling. By repeating such a pattern, the surface of the reduced-iron agglomerate is cooled to a target discharge temperature while water spraying and evaporation are repeated alternately. By so doing, the reduced-iron agglomerate 5 discharged from a cooling apparatus according to the present invention can secure a water content of 6% or less.
It is preferable that the water content of a reduced-iron agglomerate is low in order to reduce the energy consumption during melting in an electric arc furnace, or the like, and a preferable water content is also 6% or less in order to prevent water vapor explosion at the time when the reduced-iron agglomerate is charged into molten metal.
As shown in
In this arrangement, the temperature difference between the interior and the surface of a reduced-iron agglomerate (a high temperature at the interior and a low temperature at the surface) increases due to the continuous water spray and a larger amount of water is required in comparison with the intermittent water cooling according to the present invention. When a water amount is increased in order to cool a reduced-iron agglomerate sufficiently up to the interior, water remains on the surface that has already been cooled to a low temperature and the water content exceeds 6%.
Further, when cone spray nozzles are used as shown in
Another cooling apparatus according to the present invention is configured so that the relation between an ejecting time “T1” and an ejection stopping time “T2” of spray water may satisfy the expression
1.2×T1≦T1+T2≦10×T1.
That is, the term “1.2×T1≦T1+T2” is the condition for securing intermittent cooling for a shortest time period in order to determine an ejecting time and an ejection stopping time of spray water.
The term “T1+T2≦10×T1” is the condition for securing effective cooling without the saturation of a temperature rise caused by the internal heat of a reduced-iron agglomerate after cooling.
The third cooling apparatus according to the present invention is configured so that the spread width of spray water in the conveying direction “B” and the intervals of spray nozzles in the conveying direction “P” may satisfy the expression “B≦P”. The condition determines the intervals of spray nozzles 1 so that the spread widths of spray water “B” ejected through the spray nozzles 1 may not overlap with each other and, under this condition, uniform cooling is realized.
The fourth cooling apparatus according to the present invention is configured so that the relation between the spread width of spray water in the conveyer width direction “W” and the spread width thereof in the conveying direction “B” may satisfy the expression “2B≦W”. Under the condition, a spray region 1a becomes flat as shown in
For example, when flat spray nozzles are adopted, as the spread width of spray water in the conveying direction “B” becomes nearly constant in the conveyer width direction, the variation of the cooling state in the conveyer width direction decreases and resultantly intermittent cooling can be carried out effectively.
Further, in the aforementioned third cooling apparatus according to the present invention, by configuring the cooling apparatus so that tile relation between the spread width of spray water in the conveyer width direction “W” and the conveyer width “CW” may satisfy the expression “CW≦W”, namely by building up the relation between “W” and “CW” as shown in
Next, the results obtained from the examples of the present invention are shown in FIGS. 6 to 8.
The intermittent cooling of the invention examples was performed under the condition prepared so that the relation between the spread width of spray water in the conveying direction “B” and the intervals of the installed spray nozzles “P” might satisfy the expression “2B=P” and under this condition prepared so that the relation between the spread width of spray water in the conveying direction “B” and the intervals of the installed spray nozzles “P” might satisfy the expression “B≦P” and the relation between the spraying time and the spray stopping time might satisfy the expression “1.2×T1≦T1+T2”. The continuous cooling of the comparative examples was performed under the condition of “B≦P”.
By the present invention, the temperature at the center of the reduced-iron agglomerate is lowered to preferably not higher than 300° C., as shown by the solid line, and still more preferably not higher than 200° C., as shown by the broken line.
Further, whereas, in the case of the intermittent cooling of the invention example, the temperature is 300° C. or lower when the relative spray water amount is 0.7 or more, in the case of the continuous cooling of the comparative example, the relative spray water amount of 2.0 is required.
In the case of the intermittent cooling of the invention example, the water content is 6% or less when the relative spray water amount is 1.3 or less and the temperature is 300° C. or lower and the water content is 6% or less when the relative spray water amount is in the range from 0.7 to 1.3. On the other hand, in the case of the continuous cooling of the comparative example, the water content exceeds 6% when the temperature is controlled to 300° C. or lower.
In contrast, in the case of the intermittent cooling of the invention example, as shown by the solid line, the temperature at the center and the water content can be regulated to 300° C. or lower and 6% or less respectively and a good reduced-iron agglomerate can be obtained.
2) Another present invention is further explained on the basis of the cooling apparatus shown in
The technological concept of the present invention is explained hereunder.
Spray nozzles are arranged above a cooling conveyer along the conveying direction and a reduced-iron agglomerate is cooled with water sprayed from above. However, the bottom surface and the center portion of the reduced-iron agglomerate are hardly cooled with only the cooling from above.
Therefore, the temperature difference appears between the top and bottom surfaces of the reduced-iron agglomerate and, when a spray water amount is insufficient, the heat at the bottom surface is transferred after cooling and the cooling becomes insufficient.
On the other hand, when a spray water amount is abundant, water penetrates the top surface of a low temperature and the water content increases.
In this light, with intent to achieve both “cooling to a temperature of 300° C. or lower at the center” and “a water content of 6% or less” at the same time, the method is used wherein a reduced-iron agglomerate is cooled from the top and bottom surfaces by raising both the side portions of a conveyer and accumulating cooling water so as to form a water layer 1 mm to less than 10 mm on the conveyer.
When water accumulates so as to form a water layer 1 to less than 10 mm (which corresponds to less than a half of the thickness of a reduced-iron agglomerate) at the bottom of a conveyer by raising both the side portions of the conveyer, the bottom surface of the reduced-iron agglomerate is cooled by the heat of the evaporation of water and the temperature difference between the top and bottom surfaces decreases. Therefore, both “cooling to a temperature of 300° C. or lower at the center” and “a water content of 6% or less” can be achieved at the same time.
When a water layer at the bottom of a conveyer is less than 1 mm in thickness, the ability to cool the reduced-iron agglomerate is insufficient. On the other hand, when it is 10 mm or more in thickness, a water content increases excessively. For that reason, the thickness of a water layer is determined to be in the range from 1 mm to less than 10 mm.
With regard to a method of spraying cooling water on a reduced-iron agglomerate through spray nozzles installed above a conveyer, the cooling water may be sprayed intermittently, instead of continuously, on the reduced-iron agglomerate. By this intermittent cooling, it becomes possible to cool a reduced-iron agglomerate to a uniform temperature from the surface to the center. The method of intermittent spraying is not particularly specified and it is preferable to repeat spraying and non-spraying during the course of cooling by adjusting the arrangement and the spread angle of spray nozzles.
The present invention is explained on the basis of
A high-temperature reduced-iron agglomerate is discharged from the outlet 8 of a rotary hearth of a reduced-iron production equipment and loaded on a cooling conveyer 6. The temperature of the reduced-iron agglomerate discharged from the outlet 8 of the rotary hearth is 1,000° C. Spray nozzles 1 are installed above the cooling conveyer 6 and cooling water is sprayed on the reduced-iron agglomerate on the cooling conveyer 6 through the spray nozzles 1.
In such a cooling apparatus, when the length of the cooling conveyer 6 is set at 6.5 m and the conveying speed at 6.5 m/min., the reduced-iron agglomerate is cooled for about 1 min. In the meantime, the reduced-iron agglomerate is cooled from about 1,000° C. to 300° C. or lower.
The cooled reduced-iron agglomerate is conveyed from the end of the cooling conveyer 6 as a product. Further, sludge formed during the course of cooling is separated from water at a shoot 18, thereafter recovered with a sludge recovery conveyer 17, and reused as an iron source. Here, vapor generated during the course of cooling is discharged outside through a vapor duct 4.
Such side walls as shown in
Further, the bottom plate 21 of the cooling conveyer 6 is made of a steel plate and the structure is configured so that the cooling water may not fall down from the bottom plate 21.
The results of the examples according to the present invention are shown in
As shown in
On the other hand, in the case of using wire gauze as the bottom plate of the cooling conveyer 6, the temperature at the center of a reduced-iron agglomerate can be lowered only to 470° C. even when the spray water amount is about 1.1 times the calculated required amount.
As shown in
On the other hand, in the case of using wire gauze as the bottom plate of the cooling conveyer 6, the water content exceeds 6% when the spray water amount exceeds the calculated required amount.
From the results shown in
By a method and an apparatus according to the present invention, it is possible to cool a high-temperature reduced-iron agglomerate intermittently, to cool it effectively to a temperature in the range from 100° C. to 300° C. at a breath and, as a result, to suppress the reoxidation caused by the atmospheric air.
Further, it is possible to regulate the water content of a cooled reduced-iron agglomerate to 6% or lower, to eliminate the danger of a water-vapor explosion at the time when the reduced-iron agglomerate is charged into molten metal, and also to suppress the energy required for melting.
Further, the present invention makes it possible to reduce a water content to 6% or less in comparison with an immersion cooling method and therefore to suppress the pulverization and the reoxidation. Furthermore, by the present invention, a conveyer itself is also cooled and, therefore, the durability of the conveyer is improved.
Number | Date | Country | Kind |
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2001-285978 | Sep 2001 | JP | national |
2001-295686 | Sep 2001 | JP | national |
2002-225233 | Aug 2002 | JP | national |
2001-295782 | Sep 2001 | JP | national |
Number | Date | Country | |
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Parent | 10489996 | Mar 2004 | US |
Child | 11890133 | Aug 2007 | US |