The present invention is directed to deformed web materials and apparatuses and methods for deforming a web to create such materials.
Various methods and apparatuses for deforming webs are disclosed in the patent literature. Patents disclosing such methods include: U.S. Pat. No. 4,189,344, Busker; U.S. Pat. No. 4,276,336, Sabee; U.S. Pat. No. 4,609,518, Curro; U.S. Pat. No. 5,143,679, Weber; U.S. Pat. No. 5,562,645, Tanzer; U.S. Pat. No. 5,743,999, Kamps; U.S. Pat. No. 5,779,965, Beuether, et al.; U.S. Pat. No. 5,998,696, Schone; U.S. Pat. No. 6,332,955, Meschenmoser; U.S. Pat. No. 6,739,024 B1, Wagner; U.S. Patent Application Publication 2004/0110442 A1, Rhim; EP 1 440 197 B1, Thordahl; U.S. Pat. No. 6,916,969, Helmfridsson; U.S. Patent Application Publication No. 2006/0151914 A1, Gerndt; U.S. Pat. No. 7,147,453 B2, Boegli; U.S. Pat. No. 7,423,003, Volpenhein; U.S. Pat. No. 7,323,072 B2, Engelhart, et al.; U.S. Patent Application Publication No. 2006/0063454, Chung; U.S. Patent Application Publication No. 2007/0029694 A1, Cree, et al.; U.S. Patent Application Publication No. 2008/0224351 A1, Curro, et al.; U.S. Patent Application Publication No. 2009/0026651 A1, Lee, et al.; U.S. Pat. No. 7,521,588 B2, Stone, et al.; and U.S. Patent Application Publication No. 2010/0201024 A1, Gibson, et al.
However, the search continues for methods and apparatuses that are capable of forming new structures in webs that provide the webs with additional properties. In the case of webs used in absorbent articles, such new structures may include those that provide a single portion of the web with dual, or more, properties (such as improved softness, fluid handling, or other properties) in a predetermined portion of the web. A need also exists for apparatuses that will allow a web to be deformed multiple times while maintaining control over the registration of the deformations in the web. A further need exists for apparatuses that are capable of deforming a web multiple times with an apparatus that has a small footprint on a manufacturing floor.
The present invention is directed to deformed web materials and apparatuses and methods for deforming a web to create such materials. Such materials can be provided as components of products such as absorbent articles (such as topsheets, backsheets, acquisition layers, liquid handling layers, absorbent cores), packaging (such as flow wrap, shrink wrap, and polybags), trash bags, food wrap, wipes, facial tissue, toilet tissue, paper towels, and the like. There are numerous non-limiting embodiments of the present invention.
In one non-limiting embodiment, the deformed web material comprises a web having discrete deformations formed therein. The deformations may be features in the form of portions of the web with apertures therein, protrusions, depressed areas, and combinations thereof. These features may extend out from the surface on one side of the web, or from both of the surfaces of the web. Different features may be intermixed with one another.
The apparatuses and methods can, in certain non-limiting embodiments, be configured for deforming a web in a single nip. In one embodiment, the method involves feeding a web into a nip that is formed between two intermeshing rolls. The two rolls are configured for deforming a web with at least two sets of deformations that are oriented in different directions relative to the surfaces of the web.
In other embodiments, the apparatuses and methods can be configured for deforming a web at least two times (that is, in at least two or more nips). In such embodiments, the apparatus may comprise nested, or other arrangements of, multiple rolls in which the web may be maintained substantially in contact with at least one of the rolls throughout the process, and at least two of the rolls define two or more nips thereon with other rolls. In some embodiments, rolls can be used to expose a different side of the web for a subsequent deformation step. In these or other embodiments, the rolls can be used to transfer the web between rolls in such a manner that it may offset the rolls and/or web so that subsequent deformations are formed at a different cross-machine direction alignment than prior deformations. In some cases, this may be used to achieve a tighter spacing between deformations than might otherwise be possible.
The following detailed description will be more fully understood in view of the drawings in which:
The embodiments shown in the drawings are illustrative in nature and are not intended to be limiting of the invention defined by the claims. Moreover, the features of the invention will be more fully apparent and understood in view of the detailed description.
The term “absorbent article” includes disposable articles such as sanitary napkins, panty liners, tampons, interlabial devices, wound dressings, diapers, adult incontinence articles, wipes, and the like. Still further, the absorbent members produced by the methods and apparatuses disclosed herein can find utility in other webs such as scouring pads, dry-mop pads (such as SWIFFER® pads), and the like. At least some of such absorbent articles are intended for the absorption of body liquids, such as menses or blood, vaginal discharges, urine, and feces. Wipes may be used to absorb body liquids, or may be used for other purposes, such as for cleaning surfaces. Various absorbent articles described above will typically comprise a liquid pervious topsheet, a liquid impervious backsheet joined to the topsheet, and an absorbent core between the topsheet and backsheet.
The term “absorbent core”, as used herein, refers to the component of the absorbent article that is primarily responsible for storing liquids. As such, the absorbent core typically does not include the topsheet or backsheet of the absorbent article.
The term “absorbent member”, as used herein, refers to the components of the absorbent article that typically provide one or more liquid handling functionality, e.g., liquid acquisition, liquid distribution, liquid transportation, liquid storage, etc. If the absorbent member comprises an absorbent core component, the absorbent member can comprise the entire absorbent core or only a portion of the absorbent core.
The term “absorbent structure”, as used herein, refers to an arrangement of more than one absorbent component of an absorbent article.
The term “adjacent”, as used herein, with reference to features or regions, means near or close to, and which need not be in contact with each other.
The term “aperture”, as used herein, refers to a hole. The apertures can either be punched cleanly through the web so that the material surrounding the aperture lies in the same plane as the web prior to the formation of the aperture (a “two dimensional” aperture), or holes formed in which at least some of the material surrounding the opening is pushed out of the plane of the web. In the latter case, the apertures may resemble a protrusion or depression with an aperture therein, and may be referred to herein as a “three dimensional” aperture, a subset of apertures.
The term “component” of an absorbent article, as used herein, refers to an individual constituent of an absorbent article, such as a topsheet, acquisition layer, liquid handling layer, absorbent core or layers of absorbent cores, backsheets, and barriers such as barrier layers and barrier cuffs.
The term “cross-machine direction” or “CD” means the path that is perpendicular to the machine direction in the plane of the web.
The term “deformable material”, as used herein, is a material which is capable of changing its shape or density in response to applied stresses or strains.
The term “discrete”, as used herein, means distinct or unconnected. When the term “discrete” is used relative to forming elements on a forming member, it is meant that the distal (or radially outwardmost) ends of the forming elements are distinct or unconnected in all directions, including in the machine and cross-machine directions (even though bases of the forming elements may be formed into the same surface of a roll, for example).
The term “disposable” is used herein to describe absorbent articles and other products which are not intended to be laundered or otherwise restored or reused as an absorbent article or product (i.e., they are intended to be discarded after use and, preferably, to be recycled, composted or otherwise disposed of in an environmentally compatible manner).
The term “forming elements”, as used herein, refers to any elements on the surface of a forming member that are capable of deforming a web. The term “forming elements” includes both continuous or non-discrete forming elements such as the ridges and grooves on ring rolls, and discrete forming elements.
The term “intermixed”, as used herein, refers to features that are distributed between other features over at least some portion of the surface of a component, in which the features differ from each other as described herein. The term “intermixed” comprises arrangements of features in which at least two of the closest features in any direction (including, but not limited to longitudinal, transverse, or diagonal) differ from each other as described herein, even though there may be a similar feature that is as close as, or closer to, a given feature in another direction.
The term “Interpenetrating SELF” and the acronym “IPS”, as used herein, refers to a process that uses The Procter & Gamble Company's SELF technology (described below) to combine at least two layers or materials together. Tufts may be formed in both materials; or, the tuft of one material may burst through the other material. Interpenetrating SELF is described in greater detail in U.S. Pat. No. 7,648,752.
The term “joined to” encompasses configurations in which an element is directly secured to another element by affixing the element directly to the other element; configurations in which the element is indirectly secured to the other element by affixing the element to intermediate member(s) which in turn are affixed to the other element; and configurations in which one element is integral with another element, i.e., one element is essentially part of the other element. The term “joined to” encompasses configurations in which an element is secured to another element at selected locations, as well as configurations in which an element is completely secured to another element across the entire surface of one of the elements. The term “joined to” includes any known manner in which elements can be secured including, but not limited to mechanical entanglement.
The term “layer” is used herein to refer to an absorbent member whose primary dimension is X-Y, i.e., along its length (or longitudinal direction) and width (or transverse direction). It should be understood that the term “layer” is not necessarily limited to single layers or sheets of material. Thus the layer can comprise laminates or combinations of several sheets or webs of the requisite type of materials. Accordingly, the term “layer” includes the terms “layers” and “layered”.
The term “machine direction” or “MD” means the path that material, such as a web, follows through a manufacturing process.
The term “male/female embossing” as used herein, refers to an embossing apparatus and process that involves the use of at least a pair of patterned rolls, wherein the first patterned roll comprises one or more projections or protrusions, and the second patterned roll comprises one or more recesses into which one or more of the projections of the first patterned roll mesh. The projections and recesses may be discrete embossing elements, and they may have matched or unmatched patterns. The term “male/female embossing”, thus, excludes embossing processes that utilize the combination of a patterned roll against a flat anvil roll or deformable roll.
The term “macroscopic”, as used herein, refers to structural features or elements that are readily visible and distinctly discernable to a human having 20/20 vision when the perpendicular distance between the viewer's eye and the web is about 12 inches (30 cm). Conversely, the term “microscopic” refers to such features that are not readily visible and distinctly discernable under such conditions.
The terms “mechanically impacting” or “mechanically deforming”, may be used interchangeably herein, to refer to processes in which a mechanical force is exerted upon a material.
The term “Micro-SELF” is a process that is similar in apparatus and method to that of the SELF process defined herein. Micro-SELF teeth have different dimensions such that they are more conducive to forming tufts with openings on the leading and trailing ends. A process using micro-SELF to form tufts in a web substrate is disclosed in U.S. Patent application Publication No. US 2006/0286343A1.
The term “permanently deformed”, as used herein, refers to the state of a deformable material whose shape or density has been permanently altered in response to applied stresses or strains.
The term “post-consumer recycled material” as used herein generally refers to material that can originate from post-consumer sources such as domestic, distribution, retail, industrial, and demolition. “Post-consumer fibers” means fibers obtained from consumer products that have been discarded for disposal or recovery after having completed their intended uses and is intended to be a subset of post consumer recycled materials. Post-consumer materials may be obtained from the sorting of materials from a consumer or manufacturer waste stream prior to disposal. This definition is intended to include materials which are used to transport product to a consumer, including, for example, corrugated cardboard containers.
The terms “ring roll” or “ring rolling” refer to a process using deformation members comprising counter rotating rolls, intermeshing belts or intermeshing plates containing continuous ridges and grooves where intermeshing ridges (or projections) and grooves (or recesses) of deformation members engage and stretch a web interposed therebetween. For ring rolling, the deformation members can be arranged to stretch the web in the cross machine direction or the machine direction depending on the orientation of the ridges and grooves.
The term “rotary knife aperturing” (RKA) refers to a process and apparatus using intermeshing deformation members similar to those described herein with respect to SELF or micro-SELF deformation members. The RKA process differs from SELF or micro-SELF in that the relatively flat, elongated teeth of a SELF or micro-SELF deformation member have been modified to be pyramid shaped, elongated with at least six sides, the sides being substantially triangular and tapered to a point at the distal end. The teeth can be sharpened to cut through as well as deform a web to produce an apertured web, or in some cases, a three-dimensionally apertured web, as disclosed in U.S. Patent Application Publication Nos. US 2005/0064136A1, US 2006/0087053A1, and US 2005/021753. In other respects such as tooth height, tooth spacing, pitch, depth of engagement, and other processing parameters, RKA and the RKA apparatus can be the same as described herein with respect to SELF or micro-SELF.
The terms “SELF” or “SELF'ing”, refer to Procter & Gamble technology in which SELF stands for Structural Elastic Like Film. While the process was originally developed for deforming polymer film to have beneficial structural characteristics, it has been found that the SELF'ing process can be used to produce beneficial structures in other materials. Processes, apparatuses, and patterns produced via SELF are illustrated and described in U.S. Pat. Nos. 5,518,801; 5,691,035; 5,723,087; 5,891,544; 5,916,663; 6,027,483; and 7,527,615 B2.
The term “tuft”, as used herein, refers to a particular type of protrusion that may be formed in a nonwoven web. Tufts typically have a tunnel-like configuration, and in some cases may be open at one or both of their ends.
The term “upper” refers to absorbent members, such as layers, that are nearer to the wearer of the absorbent article during use, i.e. towards the topsheet of an absorbent article; conversely, the term “lower” refers to absorbent members that are further away from the wearer of the absorbent article towards the backsheet. The term “laterally” corresponds to direction of the shorter dimension of the article, which generally during use corresponds to a left-to-right orientation of the wearer. “Longitudinally” then refers to the direction perpendicular to the lateral one, but not corresponding to the thickness direction.
The term “Z-dimension” refers to the dimension orthogonal to the length and width of the web or article. The Z-dimension usually corresponds to the thickness of the web or article. As used herein, the term “X-Y dimension” refers to the plane orthogonal to the thickness of the web or article. The X-Y dimension usually corresponds to the length and width, respectively, of the web or article.
I. Deformed Web Materials.
The present inventions are directed to deformed web materials and methods and apparatuses for deforming a web. Methods and apparatuses are disclosed that are capable of forming new structures in webs that provide the webs with additional properties. It should be understood that while the term “deformed web materials” is utilized herein, the object is to create components, such as absorbent members (or non-absorbent components), for absorbent articles from such deformed web materials. In such cases, the deformed web materials will be cut into individual components for absorbent articles. The deformed web materials can also be used in products other than absorbent articles including, but not limited to packaging materials and trash bags.
Structures can be provided in webs and the components formed therefrom which are not possible to produce with current methods and tooling (forming components). Such structures include features extending out of the plane of the web on both sides of the web, and/or features that are intermixed between other features. The web can, in some cases, also be provided with features that are more closely spaced than is possible with conventional tooling. In the case of webs used in absorbent articles, such new structures may include those that provide a single portion of the web with dual, or more, properties (such as improved softness, fluid handling, or other properties) in a predetermined portion of the web. The apparatuses and processes can allow a web to be deformed multiple times while maintaining control over the registration of the deformations in the web. That is, the location/registration of the web may be controlled in the machine direction and in the cross-machine direction from the time the web is fed into the first forming nip to the time it exits the last forming nip so deformations made in the downstream nips occur in a controlled location relative to deformations made in previous nips.
The web (or “precursor web”) that will be deformed can comprise any suitable deformable material, such as a woven, nonwoven, film, combination, or laminate of any of the foregoing materials. As used herein, the term “nonwoven web” refers to a web having a structure of individual fibers or threads which are interlaid, but not in a repeating pattern as in a woven or knitted fabric, which do not typically have randomly oriented fibers. Nonwoven webs or fabrics have been formed from many processes, such as, for example, meltblowing, spunbonding, hydroentangling, airlaid, wetlaid, through-air-dried paper making processes, and bonded carded web processes, including carded thermal bonding. The woven, nonwoven, film, combination, or laminate can be made of any suitable materials including, but not limited to natural materials, synthetic materials, and combinations thereof. Suitable natural materials include, but are not limited to cellulose, cotton linters, bagasse, wool fibers, silk fibers, etc. In some embodiments, the web materials may be substantially free of cellulose, and/or exclude paper materials. In other embodiments, the methods described herein may be performed on cellulose-containing precursor materials. Suitable synthetic materials include, but are not limited to rayon and polymeric materials. Suitable polymeric materials include, but are not limited to: polyethylene, polyester, polyethylene terephthalate (PET), and polypropylene. Any of the materials described above may comprise post-consumer recycled material.
In one non-limiting embodiment, the deformed web material comprises a web having discrete deformations formed therein. The web has a first surface and a second surface. The web comprises: a) substantially undeformed first regions, the undeformed regions having surfaces that correspond to the first and second surfaces of the web prior to the formation of deformations therein; b) a plurality of spaced apart first formed features (or “first features”) in first locations comprising features that can comprise: portions of the web material with apertures therein; protrusions; and depressed areas (or “depressions”); and c) a plurality of spaced apart second formed features (or “second features”) in second locations comprising features that can comprise: portions of the web material with apertures therein; protrusions; and depressed areas (or “depressions”). In some embodiments, the first features and/or the second features may be selected from the group consisting of one or more of the foregoing types of features. The second features may be of a different type and/or have different properties or characteristics than the first features, and the second features may be intermixed with the first features. In some embodiments, all of the adjacent features, or all of closest features, may be of a different type and/or have different properties. In some embodiments, at least four of the closest eight features in any direction to a given feature may be of a different type and/or have different properties. The web material may further comprise third, fourth or more formed features. The third, fourth, or more features may comprise any of the types of features or have any of the properties described herein, and may differ from the first and second features in any such aspects.
In certain embodiments, it may be possible to densely pack multiple features within a relatively small area. For example, the center-to-center spacing in any direction between a first feature and a second feature may be less than or equal to about 20 mm, alternatively 10 mm, 5 mm, 3 mm, 2 mm, or 1 mm, or lie in any range between two of these numbers. The total number of features in an area that measures 1 square inch (645 mm2) may be greater than or equal to 4, 25, 100, 250, 500, or 645, or lie in any range between two of these numbers. The number of first features in one square inch may be the same or different from the number of the second features in that same area. The number of features in a one inch square area can be determined by marking a square area on the material that measures 1 inch (25.4 mm) by 1 inch with a fine tip pen or marker and counting the number of first, second, third, etc. features that lie fully or partially within and on the boundary of the 1 inch square. A low power microscope or other magnifying aid can be used to aid visibility of the features in the material if needed. The ratio of the number of first features to the number of second features may be between 0.0016 and 155. When the number of first features is the same as the number of second features, the ratio will be 1. For embodiments related to a web comprising a film, the ratio of the number of first features to the number of second features may be between 0.125 and 8. Note, in cases where there are third, fourth or more different types of features, these ratios would apply to all paired combinations of features.
The first features and second features may be of any suitable size. Typically, either the first features or the second features will be macroscopic. In some embodiments, the first features and the second features will both be macroscopic. The plan view area of the individual features may, in some embodiments of the web, be greater than or equal to about 0.5 mm2, 1 mm2, 5 mm2, mm2, or 15 mm2, or lie in any range between two of these numbers The methods described herein can, however, be used to create first features and/or second features that are microscopic which have plan view areas less than 0.5 mm2.
The first features and second features may be of any suitable configuration. The features may be continuous and/or discrete. Suitable configurations for the features include, but are not limited to: ridges (continuous protrusions) and grooves (continuous depressions); tufts; columnar shapes; dome-shapes, tent-shapes, volcano-shapes; features having plan view configurations including circular, oval, hour-glass shaped, star shaped, polygonal, polygonal with rounded corners, and the like, and combinations thereof. Polygonal shapes include, but are not limited to rectangular (inclusive of square), triangular, hexagonal, or trapezoidal. In some embodiments, the first and/or second features may exclude one or more of the configurations listed above.
The first features and the second features may differ from each other in terms of one or more of the following properties: type, shape, size, aspect ratio, edge-to-edge spacing, height or depth, density, color, surface treatment (e.g., lotion, etc.), number of web layers within the features, and orientation (protruding from different sides of the web). The term “type”, as used herein, refers to whether the feature is an aperture (a two dimensional aperture, or a three dimensional aperture), a protrusion (a tuft, or other kind of protrusion), or a depression. Two features will be considered to be different in type if one feature comprises one of these features listed (for example, a two dimensional aperture), and the other feature comprises another one of the listed features (for example, a three dimensional aperture). When the features are described as differing from each other in one of more of the properties listed above, it is meant to include those differences other than minor differences that are the result of variations within manufacturing tolerances. It should also be understood that although the web material may have discrete thermal or adhesive bond sites therein, in some embodiments the features of interest imparted by this process herein do not include such bond sites.
The various types of deformed webs will be shown in conjunction with the descriptions of the apparatuses and methods used to form the same. These webs can be cut to form various components of products such as absorbent articles (such as topsheets, backsheets, acquisition layers, absorbent cores), packaging (such as flow wrap, shrink wrap, and polybags), trash bags, food wrap, wipes, facial tissue, toilet tissue, paper towels, and the like.
II. Apparatuses for Deforming Web Materials.
Prior art approaches are not suitable for creating well-defined inter-mixed features with controlled placement of the features. Therefore, it is desirable to design a process that enables better independent control over the formation of two or more sets of features. Two approaches for achieving better independent control over the formation of each set of features are provided here. One approach utilizes a single nip with two rolls comprising discrete male forming elements wherein at least one roll comprises two or more raised ridges. A second approach comprises a multi-hit (multi-nip) configuration that enables controlled placement and orientation of multiple sets of features. Each of these approaches may enable independent control over the formation of each set of features and better pattern conformation of the web to the roll such that the desired size and/or shape of the feature is achieved.
The mechanical deformation process can be carried out on any suitable apparatus that may comprise any suitable type(s) of forming structure. Suitable types of forming structures include, but are not limited to: a pair of rolls that define a nip therebetween; pairs of plates; belts, etc. Using an apparatus with rolls can be beneficial in the case of continuous processes, particularly those in which the speed of the process is of interest. Although the apparatuses will be described herein for convenience primarily in terms of rolls, it should be understood that the description will be applicable to forming structures that have any other suitable configurations.
To assist in understanding the present inventions, several prior art apparatuses are shown.
Applicants have also considered using a single nip comprising two rolls with discrete male forming elements to form multiple set of discrete deformations into the web. The disadvantage of this approach is that typically, one set of features will be preferentially formed over the other, and the second set of features may never be formed or will not result in the desired feature size and/or shape. Without wishing to be bound by any particular theory, it is believed that this is a result of the material following the path of least resistance, which is dependent upon the two mating roll patterns. In situations in which the mating rolls are identical, a conventional single nip apparatus will not produce the same structure that is created if the elements are formed independently in separate nips. Prior art approaches do not provide an apparatus that can create independent control of the deformation and placement of multiple sets of features. Because of the drawbacks associated with the above apparatuses, applicants have developed improved configurations for the arrangement of the rolls.
The nested roll arrangement may provide several advantages. A nested roll arrangement provides more nips per total number of rolls than some of the roll arrangements shown in
The rolls used in the apparatuses and methods described herein are typically generally cylindrical. The term “generally cylindrical”, as used herein, encompasses rolls that are not only perfectly cylindrical, but also cylindrical rolls that may have elements on their surface. The term “generally cylindrical” also includes rolls that may have a step-down in diameter, such as on the surface of the roll near the ends of the roll. The rolls are also typically rigid (that is, substantially non-deformable). The term “substantially non-deformable”, as used herein, refers to rolls having surfaces (and any elements thereon) that typically do not deform or compress under the conditions used in carrying out the processes described herein. The rolls can be made from any suitable materials including, but not limited to steel, aluminum or rigid plastic. The steel may be made of corrosion resistant and wear resistant steel, such as stainless steel. The rolls may or may not be heated. If heated, consideration of thermal expansion effects must be accommodated according to well known practices to one skilled in the art of thermo-mechanical processes.
The rolls used in the apparatuses and methods described herein are used to mechanically deform portions of the web material or materials. The mechanical deformation process may be used to permanently deform portions of the web and form the types of features in the web described above. The terms “mechanically deform” and “mechanical deformation”, as used herein, do not include hydroforming processes. The features formed by the processes described herein may be registered since the processes described herein maintain control of the web, which may be in substantially continuous contact with at least one of the rolls (which serves as a metering surface) between the first nip through which the web material passes until the material exits the last nip.
The rolls may have any suitable type of elements on their surface (or surface configuration). The surface of the individual rolls may, depending on the desired type of mechanical deformation, be provided with forming elements comprising: “male” elements such as discrete projections, or continuous projections such as ridges; “female” elements or recesses such as discrete or continuous voids in the surface of the rolls; or any suitable combination thereof. The female elements may have a bottom surface (which may be referred to as depressions, cavities, or grooves), or they may be in the form of apertures (through holes in the surface of the rolls). In some embodiments, the forming elements on the components (such as the rolls) of the forming structure may comprise the same general type (that is, the opposing components may both have male forming elements thereon, or combinations of male and female elements).
The forming elements may have any suitable shape or configuration. A given forming element can have the same plan view length and width dimensions (such as a forming element with a circular or square shaped plan view). Alternatively, the forming element may have a length that is greater than its width (such as a forming element with a rectangular plan view), in which case, the forming element may have any suitable aspect ratio of its length to its width. Suitable configurations for the forming elements include, but are not limited to: ridges and grooves, teeth having a triangular-shaped side view; columnar shapes; elements having plan view configurations including circular, oval, hour-glass shaped, star shaped, polygonal, and the like, and combinations thereof. Polygonal shapes include, but are not limited to rectangular, triangular, hexagonal, or trapezoidal. The forming elements can have tips that are flat, rounded or sharp. In certain embodiments, the shapes of the female elements may differ from the shapes of any mating male forming elements. In certain embodiments, the female forming elements can be configured to mate with one or more male forming elements.
The forming elements can be of any suitable size and have any suitable spacing. For instance, at least one forming element for forming micro-textured webs has a center-to-center spacing of less than about 800 microns with at least three, at least four, or at least five of its adjacent forming elements as described in U.S. patent application Ser. No. 13/094,477 entitled “Process for Making a Micro-Textured Web”, filed on the same date as the present application. In some embodiments, at least 25%, at least 50%, at least 75%, at least 95%, or all of the forming elements on a forming structure have center-to-center spacings of less than about 800 microns with at least three, at least four, or at least five of their adjacent forming elements 10. Other acceptable center-to-center spacings are from about 30 microns to about 700 microns, from about 50 microns to about 600 microns, from about 100 microns to about 500 microns, or from about 150 microns to about 400 microns. The center-to-center spacings among adjacent forming elements may be the same or different. The center-to-center spacing of the forming elements may range from the scale used for such micro-textured webs up to, or greater than, the examples of the size of the center-to-center spacing of the larger forming elements described herein. Suitable configurations for the forming components include, but are not limited to: ring rolls; SELFing rolls; Micro-SELFing rolls; and RKA rolls; male/female embossing rolls; and the forming structures for forming the micro-textured web in the patent application described above. Several such roll surface configurations are described below.
In the embodiment shown in
As shown in
In other embodiments, which are described in the SELF patents that are incorporated by reference herein, the SELF roll can comprise a machine direction, or “MD SELF” roll. Such a roll will have alternating ridges and grooves that are oriented parallel to the axis A of the roll. The ridges in such a roll have spaced apart channels formed therein that are oriented around the circumference of the roll. The channels form breaks in the ridges to form discrete forming elements or teeth on the MD SELF roll. In the case of MD SELF rolls, the teeth have their longer dimension oriented in the cross-machine direction (CD).
The roll 90 can be aligned with an opposing roll which has ridges and grooves therein so that the rows of teeth in one roll align with the grooved regions between the teeth in the opposing roll. The advantage of using CD SELF rolls in the methods described herein is that registration of multiple rolls to provide multiple hits (impacts within multiple nips) is much easier in that it is only necessary to register the toothed regions (that is, to align the toothed regions with the grooved regions on the opposing roll) in the cross-machine direction, and it is not necessary to phase or register the toothed regions in the MD. The staggered tooth pattern allows the web 10 to be mechanically impacted to form features in a staggered pattern.
The teeth can have any suitable dimensions. In certain embodiments of the SELF rolls, the teeth 100 can have a length TL ranging from about 0.5 mm (0.020 inches) to about 13 mm (0.512 inches) and a spacing TD from about 0.5 mm to about 13 mm, a tooth height TH ranging from about 0.5 mm to about 17 mm (0.669 inches), a tooth tip radius TR ranging from about 0.05 mm (0.002 inches) to about 0.5 mm (0.020 inches), and a pitch P between about 1 mm (0.040 inches) and 10 mm (0.400 inches). The depth of engagement E can be from about −1 mm to about 16 mm (up to a maximum approaching the tooth height TH). Of course, E, P, TH, TD, TL, and TR can each be varied independently of each other to achieve the desired properties in the web. Another property describing the teeth is their side wall angle. The side wall angle is the angle the longer sides of the teeth make relative to an imaginary vertical line extending outward from the central axis of the roll through the center of the teeth. Any radius at the tips of the teeth is ignored. Typically, the side wall angle of the teeth is defined such that when the rolls are inter-meshing, there is sufficient clearance for the web and the web is not sheared (where portions of the web forced to slip relative to other portions) or pinched by the tooling. However, for some materials, such as those comprising cellulose fibers, it can be advantageous to have smaller clearances and induce shear in the material. Typically, the side wall angle will range from between about 3 to about 15 degrees. The leading and trailing ends of the teeth are typically squared off and have a vertical side wall from the base to the tip of the tooth.
The various types of rolls described above (as well as other types of rolls having forming elements thereon) may be combined in any suitable combinations in the different apparatuses described herein to deform a web of material in a particular manner. The apparatuses may comprise several rolls comprising a single type of roll described above, or any suitable combinations of two or more different types of rolls. The web 10 can be fed through any suitable number of mechanical deformation processes. The number of mechanical deformation nips to which the precursor web is subjected can range from one to between 2 and 100, or more, nips.
There can also be variations of the arrangements of rolls in the different apparatuses of interest herein. In the embodiment shown in
III. Methods for Deforming Web Materials and Deformed Web Materials Formed Thereby.
The following figures show non-limiting examples of specific roll arrangements, and the deformed web materials that can be formed thereby.
The top roll 162 in the apparatus shown in
The bottom roll 170 in the apparatus shown in
The web 10, in its initial state, can be thought of as being comprised entirely of undeformed regions. When the web 10 is fed into the nip N between the rolls shown in
In the example of the web shown in
The configuration of the rolls shown in
Various alternative embodiments of the raised ridge rolls are possible. For example,
A variation of the apparatus shown in
In one non-limiting example of a case in which the secondary nip occurs before the primary nip, the first satellite roll 34 can comprise a ring roll and the second satellite roll 36 can comprise a SELF roll. In such an embodiment, at the secondary nip between the raised ridge central roll 32 and the ring roll 34, the raised ridge central roll 32 will form a first set of deformations into the web (for example, three dimensional apertures if the central roll 32 is a raised ridge RKA roll, or protrusions if the central roll 32 is a raised ridge SELF roll). In addition, the ring roll in the secondary nip can pre-strain the web in the same CD location that the SELF roll will impact the web downstream in the primary nip, pre-weakening the web and making it easier to form the second set of deformations. Then, downstream at the primary nip between the raised ridge central roll 32 and the second satellite SELF roll 36, a second set of deformations can be formed into the web by the SELF roll and the first set of deformations can be enlarged by the raised ridge central roll 32.
In one non-limiting example of a case in which the secondary nip occurs after the primary nip, the first satellite roll 34 can comprise a SELF roll and the second satellite roll 36 can comprise a ring roll. In such an embodiment, at the primary nip between the raised ridge central roll 32 and the first satellite SELF roll 34, these rolls will combine to form a first and a second set of deformations into the web (for example, the central roll 32 will form three dimensional apertures if the central roll 32 is a raised ridge RKA roll, or protrusions if the central roll 32 is a raised ridge SELF roll, and the SELF roll will form protrusions or tufts). Then, downstream at the secondary nip between the raised ridge central roll 32 and the second satellite ring roll 36, the first set of deformations formed by the raised ridge central roll 32 can be enlarged by the raised ridge central roll 32.
The variation of the apparatus of
The methods of interest herein may also utilize multiple deformation steps. Such multiple deformation steps can be carried out by any suitable apparatuses described in the foregoing section of this description. Although the methods that utilize multiple deformation steps are shown as being carried out on nested apparatuses having a relatively small number of rolls in a standard nested arrangement, it should be understood that this is done for simplicity of illustration, and any of the apparatuses described herein (such as the hybrid, closed loop, and shared bank apparatuses) could be used with any suitable number of rolls in order to carry out the desired deformation.
Apparatuses that utilize multiple deformation steps for forming inter-mixed features typically comprise a minimum of three nips formed by a minimum of four rolls. Two of the nips are deformation nips in which the web is permanently deformed to form a first-time deformed precursor web with a first set of features and a second-time deformed precursor web with a second set of features. The third nip may be a transfer nip disposed between the deformation nips in which the web is not permanently deformed. The transfer nip may be used to dispose a different side of the web for a subsequent deformation step such that different sets of features can be formed on opposite sides of the web. The transfer nip can also be used to off-set the rolls in subsequent deformation steps such that the different sets of features can be formed in different CD lanes, enabling tighter spacing of features. Depending on the configuration and arrangement of the rolls, the forming elements in the second deformation nip can contact the web in one of the following locations: 1) the same location as in the first deformation nip; 2) at least partially different locations wherein at least some of the locations at least partially coincide with the first location; and 3) in completely different locations.
The deformation nips comprise a first roll with discrete male elements thereon and a second roll that is capable of mating with the first roll to form discrete features. The first roll may comprise a SELF roll, RKA roll, or male embossing roll. The second roll preferably comprises a ring roll or a female emboss roll, depending on the type of roll that is chosen for the first roll. In some the cases, it may be desirable for the second roll to comprise discrete male elements, for example when it is desired to use the process to reduce the density of drylap or other wetlaid structures. The rolls that comprise the transfer nips may be capable of being arranged in either: i) a tip-tip configuration in which the outwardmost portions on the surface of the rolls substantially align to form a nip, or ii) an off-set configuration in which the outwardmost portions on the surface of the rolls are capable of meshing. Any of the rolls listed above (SELF roll, RKA roll, ring roll, male embossing roll, female embossing roll) can be used for the rolls in the transfer nip. Several specific embodiments are detailed below in which the rolls with the discrete male forming elements thereon that are used to form deformations into the web are the first and the last rolls in the apparatus.
The process carried out in the example on the apparatus shown in
The third roll 196 should also be capable of cooperating with the second roll 194 to maintain control of the web 10 and transfer the web, without permanently deforming the same, to a downstream deforming nip. The third roll 196 has a surface with projections 208 and/or recesses 210 thereon, wherein any projections 208 or the portions of the roll between any recesses 210 form the radially outwardmost portions 212 on the surface of the third roll 196. The third roll 196 can comprise any suitable type of roll having such properties including, but not limited to: a male or female embossing roll, a ring roll, or a SELF roll. In the embodiment shown in
The web 10 is then fed into a third nip N3 between the third roll 196 and a fourth roll 198. The nip N3 between the intermeshing third and fourth rolls is shown in cross-section in
The elements on the various rolls shown in
When the precursor web 10 is fed into the first nip N1 in the apparatus shown in
When the features are described as being substantially aligned, or lying in substantially the same rows, this refers to at least a majority of the specified features. Thus, if the second features are described as lying substantially in the same rows as the first features, at least a majority of the second features lie in the same rows as the first features. Of course, in any of the embodiments described herein, the first and second features may be offset relative to each other so that they do not lie in substantially the same rows. The second features also need not be spaced between the first features such that there in equal spacing between the features on each side.
The apparatus 220 shown in
When the precursor web 10 is fed into the apparatus shown in
Any suitable combinations of the apparatuses and processes described herein are also possible.
Numerous alternative embodiments of the deformed web materials and methods of making the same are possible.
The methods described herein need not always be used to produce intermixed sets of elements that are in different locations on a web. In alternative embodiments, the method can, for example, comprise feeding a web through a “nested roll” arrangement in which at least two of the rolls define two or more nips thereon with other rolls, and the apparatus can be configured to deform the web in the same location at each nip. Such an apparatus and method can be used to lower the strain rate on the areas of the web that are impacted to produce deformations. For example, it may be desirable to initially deform the web to a degree in an initial nip, and then deform the web to a greater degree in a subsequent nip.
In some alternative embodiments, the method can comprise feeding a web through an apparatus with multiple deformation nips, and the apparatus can be configured to deform the web in the same location, but on the opposite surface of the web. This could be useful for reducing the density of drylap or other wetlaid structures.
In other alternative embodiments, the method can comprise feeding a web through an apparatus with multiple deformation nips, and the apparatus can be configured to deform the web in the same location and on the same surface of the web, but the size and/or shape of the forming elements in the first deformation nip is different from that of the forming elements in the subsequent deformation nip. Such an apparatus could, for example, be used to initially form a formed element (such as a three-dimensional region with an aperture, a protrusion, or depression) at a first nip, and then, at a second nip, to make the formed element larger, or of a different shape.
In other embodiments, deformed web materials can be provided which have different regions across their surface with different features therein. For example, a deformed web material can be provided which has a first region with a first combination of features (such as tufts extending upward that are intermixed with downwardly extending tufts), and a second region with a second combination of features (such as upwardly-oriented tufts and downwardly-oriented apertures).
In any of the embodiments described herein, the web can comprise one or more layers. Additional webs may be introduced at any of the different nips. The additional layers may be used to add webs having different chemical compositions, formulations, aesthetics, conductive properties, aromatic properties, and mechanical properties. Such additional webs may be selected so that they may or may not span the entire width of the web or webs that were introduced upstream of such additional web(s). This may be used to create a laminate in which some regions of the laminate contain a different number of layers from other regions. In other laminate structures, the regions may contain the same number of layers, but some deformed features could have a different number of layers through their thickness. For example, tufts could be formed into a nonwoven web material 14 in a first nip, and then a film 16 could be introduced in a second nip downstream of the first nip. Such a method could be used to form film/nonwoven tufts in a second nip. As shown in
In another alternative embodiment, the method can comprise feeding a web through an apparatus that comprises multiple nips formed by SELF rolls in order to more gradually strain a web than is possible with ring rolling processes. SELF rolls are known to more gradually strain a web than ring rolls, since less material is locked on the tooth and constrained during the deformation step. The apparatus can be configured to deform the web in multiple discrete locations such as in a first location on the web, then immediately adjacent to the first location. The deformation steps are repeated until all the regions within a row are deformed and form a continuous band of deformations that resemble a ring rolled web. The SELF rolls in such an apparatus can comprise CD, MD, or staggered CD or MD SELF rolls. The rolls in such an apparatus will typically all be either CD or MD SELF rolls. The depth of engagement of the SELF teeth in such an embodiment may, but need not, be increased in downstream nips.
In one non-limiting example for making inter-mixed apertures and tufts oriented in opposite directions in a nonwoven web material, like that shown in
In a second non-limiting example for making inter-mixed apertures and tufts oriented in opposite directions in a nonwoven web material, like that shown in
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “90°” is intended to mean “about 90°”.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this written document conflicts with any meaning or definition of the term in a document incorporated by reference, the meaning or definition assigned to the term in this written document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
This application is a Division of application Ser. No. 13/094,195, filed on 26 Apr. 2011, now U.S. Pat. No. 8,657,596.
Number | Name | Date | Kind |
---|---|---|---|
2068456 | Hooper | Jan 1937 | A |
2275425 | Grabec | Mar 1942 | A |
2404758 | Teague et al. | Jul 1946 | A |
2633441 | Buttress | Mar 1953 | A |
2669208 | Schur | Jan 1955 | A |
2748863 | Benton | Jun 1956 | A |
2924863 | Chavannes | Feb 1960 | A |
3017304 | Burgeni | Jan 1962 | A |
3034180 | Greiner et al. | May 1962 | A |
3073304 | Schaar | Jan 1963 | A |
3081500 | Griswold et al. | Mar 1963 | A |
3081512 | Griswold | Mar 1963 | A |
3097787 | Schur | Jul 1963 | A |
3137893 | Gelpke | Jun 1964 | A |
3243488 | Hannauer, Jr. et al. | Mar 1966 | A |
3355974 | Carmichael | Dec 1967 | A |
3466358 | Muller | Sep 1969 | A |
3496259 | Guenther | Feb 1970 | A |
3509007 | Kalwaites | Apr 1970 | A |
3511740 | Sanders | May 1970 | A |
3539423 | Simison et al. | Nov 1970 | A |
3542634 | Such et al. | Nov 1970 | A |
3549742 | Benz | Dec 1970 | A |
3566726 | Politis | Mar 1971 | A |
3579763 | Sommer | May 1971 | A |
3681182 | Kalwaites | Aug 1972 | A |
3681183 | Kalwaites | Aug 1972 | A |
3684284 | Tranfield | Aug 1972 | A |
3695270 | Dostal | Oct 1972 | A |
3718059 | Clayton | Feb 1973 | A |
3760671 | Jenkins | Sep 1973 | A |
3881987 | Benz | May 1975 | A |
3949127 | Ostermeier et al. | Apr 1976 | A |
3965906 | Karami | Jun 1976 | A |
3994771 | Morgan, Jr. et al. | Nov 1976 | A |
4035881 | Zocher | Jul 1977 | A |
4042453 | Conway | Aug 1977 | A |
4135021 | Patchell et al. | Jan 1979 | A |
4189344 | Busker | Feb 1980 | A |
4211743 | Nauta et al. | Jul 1980 | A |
4244683 | Rowland | Jan 1981 | A |
4276336 | Sabee | Jun 1981 | A |
4300981 | Carstens | Nov 1981 | A |
4379799 | Holmes | Apr 1983 | A |
4397644 | Matthews et al. | Aug 1983 | A |
4422837 | Rasmussen | Dec 1983 | A |
4465726 | Holmes | Aug 1984 | A |
4469734 | Minto et al. | Sep 1984 | A |
4514345 | Johnson et al. | Apr 1985 | A |
4528239 | Trokhan | Jul 1985 | A |
4529480 | Trokhan | Jul 1985 | A |
4588630 | Shimalla | May 1986 | A |
4609518 | Curro et al. | Sep 1986 | A |
4741941 | Englebert et al. | May 1988 | A |
4758297 | Calligarich | Jul 1988 | A |
4781962 | Zamarripa et al. | Nov 1988 | A |
4798604 | Carter | Jan 1989 | A |
4820294 | Morris | Apr 1989 | A |
4840829 | Suzuki et al. | Jun 1989 | A |
4842794 | Hovis et al. | Jun 1989 | A |
4859519 | Cabe, Jr. et al. | Aug 1989 | A |
4886632 | Van Iten et al. | Dec 1989 | A |
4935087 | Gilman | Jun 1990 | A |
4953270 | Gilpatrick | Sep 1990 | A |
4992324 | Dube | Feb 1991 | A |
5019062 | Ryan et al. | May 1991 | A |
5062418 | Dyer | Nov 1991 | A |
5143679 | Weber et al. | Sep 1992 | A |
5144730 | Dilo | Sep 1992 | A |
5165979 | Watkins et al. | Nov 1992 | A |
5171238 | Kajander | Dec 1992 | A |
5180620 | Mende | Jan 1993 | A |
5188625 | Van Iten et al. | Feb 1993 | A |
5223319 | Cotton et al. | Jun 1993 | A |
5242435 | Murji et al. | Sep 1993 | A |
5242632 | Mende | Sep 1993 | A |
5328565 | Rasch et al. | Jul 1994 | A |
5382245 | Thompson | Jan 1995 | A |
5383870 | Takai et al. | Jan 1995 | A |
5387209 | Yamamoto et al. | Feb 1995 | A |
5387385 | Murji et al. | Feb 1995 | A |
5405675 | Sawka et al. | Apr 1995 | A |
5414914 | Suzuki et al. | May 1995 | A |
5415640 | Kirby et al. | May 1995 | A |
5429854 | Currie et al. | Jul 1995 | A |
5437653 | Gilman et al. | Aug 1995 | A |
5470326 | Dabi et al. | Nov 1995 | A |
5503715 | Trokhan et al. | Apr 1996 | A |
5508080 | Sorimachi et al. | Apr 1996 | A |
5518801 | Chappell et al. | May 1996 | A |
5533991 | Kirby et al. | Jul 1996 | A |
5534326 | Trokhan et al. | Jul 1996 | A |
5554145 | Roe | Sep 1996 | A |
5560794 | Currie et al. | Oct 1996 | A |
5562645 | Tanzer et al. | Oct 1996 | A |
5567501 | Srinivasan et al. | Oct 1996 | A |
D375844 | Edwards et al. | Nov 1996 | S |
5573719 | Fitting | Nov 1996 | A |
5575874 | Griesbach, III et al. | Nov 1996 | A |
5580418 | Alikhan | Dec 1996 | A |
5599420 | Yeo et al. | Feb 1997 | A |
5624427 | Dreier et al. | Apr 1997 | A |
5626571 | Young et al. | May 1997 | A |
5628097 | Benson et al. | May 1997 | A |
5634915 | Osterdahl | Jun 1997 | A |
5637194 | Ampulski et al. | Jun 1997 | A |
5648142 | Phillips | Jul 1997 | A |
5656119 | Srinivasan et al. | Aug 1997 | A |
5658639 | Curro et al. | Aug 1997 | A |
5667619 | Alikhan | Sep 1997 | A |
5667625 | Alikhan | Sep 1997 | A |
5691035 | Chappell et al. | Nov 1997 | A |
5700255 | Curro | Dec 1997 | A |
5704101 | Majors et al. | Jan 1998 | A |
5709829 | Giacometti | Jan 1998 | A |
5714041 | Ayers et al. | Feb 1998 | A |
5714107 | Levy et al. | Feb 1998 | A |
5723087 | Chappell et al. | Mar 1998 | A |
5743776 | Igaue | Apr 1998 | A |
5743999 | Kamps et al. | Apr 1998 | A |
5779965 | Beuther et al. | Jul 1998 | A |
5804021 | Abuto et al. | Sep 1998 | A |
5814389 | Giacometti | Sep 1998 | A |
5817394 | Alikhan et al. | Oct 1998 | A |
5841107 | Riva | Nov 1998 | A |
5846636 | Ruppel et al. | Dec 1998 | A |
5858504 | Fitting | Jan 1999 | A |
5879494 | Hoff et al. | Mar 1999 | A |
5891544 | Chappell et al. | Apr 1999 | A |
5895623 | Trokhan et al. | Apr 1999 | A |
5897930 | Calhoun et al. | Apr 1999 | A |
5900122 | Huston | May 1999 | A |
5906710 | Trokhan | May 1999 | A |
5914084 | Benson et al. | Jun 1999 | A |
5916507 | Dabi et al. | Jun 1999 | A |
5916661 | Benson et al. | Jun 1999 | A |
5916663 | Chappell et al. | Jun 1999 | A |
5919177 | Georger et al. | Jul 1999 | A |
5925026 | Arteman et al. | Jul 1999 | A |
5925299 | Dierckes et al. | Jul 1999 | A |
5935381 | Trokhan et al. | Aug 1999 | A |
5964742 | McCormack et al. | Oct 1999 | A |
5968029 | Chappell | Oct 1999 | A |
5986167 | Arteman et al. | Nov 1999 | A |
5993432 | Lodge et al. | Nov 1999 | A |
5998696 | Schone | Dec 1999 | A |
6007468 | Giacometti | Dec 1999 | A |
6025050 | Srinivasan et al. | Feb 2000 | A |
6027483 | Chappell et al. | Feb 2000 | A |
6039555 | Tsuji et al. | Mar 2000 | A |
6053232 | Biagotti | Apr 2000 | A |
6074524 | Wu et al. | Jun 2000 | A |
6080276 | Burgess | Jun 2000 | A |
6096016 | Tsuji et al. | Aug 2000 | A |
6106928 | Laurent et al. | Aug 2000 | A |
6109326 | Leakey et al. | Aug 2000 | A |
6114263 | Benson et al. | Sep 2000 | A |
6117524 | Hisanaka et al. | Sep 2000 | A |
6120718 | Kotek et al. | Sep 2000 | A |
6129801 | Benson et al. | Oct 2000 | A |
6136146 | Phan et al. | Oct 2000 | A |
6155083 | Goeser et al. | Dec 2000 | A |
6168849 | Braverman et al. | Jan 2001 | B1 |
6176954 | Tsuji et al. | Jan 2001 | B1 |
6247914 | Lindquist et al. | Jun 2001 | B1 |
D444631 | Woodbridge et al. | Jul 2001 | S |
6264872 | Majors et al. | Jul 2001 | B1 |
6287407 | Stein et al. | Sep 2001 | B1 |
6296737 | Wu et al. | Oct 2001 | B1 |
6332955 | Meschenmoser | Dec 2001 | B1 |
6344109 | Gross | Feb 2002 | B1 |
6344111 | Wilhelm | Feb 2002 | B1 |
6355200 | Schmidt et al. | Mar 2002 | B1 |
6383431 | Dobrin et al. | May 2002 | B1 |
6395122 | Hisanaka et al. | May 2002 | B1 |
6395211 | Dettmer et al. | May 2002 | B1 |
6398895 | Stein et al. | Jun 2002 | B1 |
6410823 | Daley et al. | Jun 2002 | B1 |
6420625 | Jones et al. | Jul 2002 | B1 |
6423884 | Oehmen | Jul 2002 | B1 |
6444089 | Hollmark et al. | Sep 2002 | B1 |
6451718 | Yamada et al. | Sep 2002 | B1 |
6452064 | Thoren et al. | Sep 2002 | B1 |
6454905 | Hollmark et al. | Sep 2002 | B1 |
6458447 | Cabell et al. | Oct 2002 | B1 |
6464831 | Trokhan et al. | Oct 2002 | B1 |
D466702 | Carlson et al. | Dec 2002 | S |
6503370 | Hollmark et al. | Jan 2003 | B2 |
6506329 | Curro et al. | Jan 2003 | B1 |
6533898 | Gross | Mar 2003 | B2 |
6537936 | Busam et al. | Mar 2003 | B1 |
6596127 | Hollmark et al. | Jul 2003 | B2 |
6620485 | Benson et al. | Sep 2003 | B1 |
6632504 | Gillespie et al. | Oct 2003 | B1 |
D481872 | Hennel et al. | Nov 2003 | S |
6647549 | McDevitt et al. | Nov 2003 | B2 |
6669878 | Yamada et al. | Dec 2003 | B2 |
6716498 | Curro et al. | Apr 2004 | B2 |
6726870 | Benson et al. | Apr 2004 | B1 |
6736916 | Steinke et al. | May 2004 | B2 |
6739024 | Wagner | May 2004 | B1 |
6787000 | Burazin et al. | Sep 2004 | B2 |
6808791 | Curro et al. | Oct 2004 | B2 |
6811652 | Hollmark | Nov 2004 | B2 |
6818101 | Vinson | Nov 2004 | B2 |
6818802 | Takai et al. | Nov 2004 | B2 |
6830800 | Curro et al. | Dec 2004 | B2 |
6837956 | Cowell et al. | Jan 2005 | B2 |
6855220 | Wildeman | Feb 2005 | B2 |
6863960 | Curro et al. | Mar 2005 | B2 |
6872274 | Kauschke et al. | Mar 2005 | B2 |
6884494 | Curro et al. | Apr 2005 | B1 |
6916438 | Berry | Jul 2005 | B2 |
6916969 | Helmfridsson et al. | Jul 2005 | B1 |
6989075 | Kao et al. | Jan 2006 | B1 |
6991706 | Lindsay et al. | Jan 2006 | B2 |
7005558 | Johansson et al. | Feb 2006 | B1 |
7037569 | Curro et al. | May 2006 | B2 |
7112257 | Baggot et al. | Sep 2006 | B2 |
7147453 | Boegli | Dec 2006 | B2 |
7175412 | Lin | Feb 2007 | B2 |
7229681 | Boegli | Jun 2007 | B2 |
7323072 | Engelhart et al. | Jan 2008 | B2 |
7364687 | Copat et al. | Apr 2008 | B2 |
7399378 | Edwards et al. | Jul 2008 | B2 |
7410683 | Curro et al. | Aug 2008 | B2 |
7413630 | Graff et al. | Aug 2008 | B2 |
7423003 | Volpenhein et al. | Sep 2008 | B2 |
7459180 | Hamdar et al. | Dec 2008 | B2 |
7497926 | Hermans et al. | Mar 2009 | B2 |
7521588 | Stone et al. | Apr 2009 | B2 |
7527615 | Roe et al. | May 2009 | B2 |
7553532 | Turner et al. | Jun 2009 | B2 |
7632979 | Fujii et al. | Dec 2009 | B2 |
7682686 | Curro et al. | Mar 2010 | B2 |
7732657 | Hammons | Jun 2010 | B2 |
7754312 | Nakajima et al. | Jul 2010 | B2 |
7811665 | Manifold | Oct 2010 | B2 |
7820874 | Manifold | Oct 2010 | B2 |
7939168 | Manifold | May 2011 | B2 |
7960020 | Manifold | Jun 2011 | B2 |
7967801 | Hammons | Jun 2011 | B2 |
7989058 | Manifold | Aug 2011 | B2 |
7993317 | Hammons | Aug 2011 | B2 |
8012309 | Pare et al. | Sep 2011 | B2 |
8021591 | Curro et al. | Sep 2011 | B2 |
8025966 | Manifold | Sep 2011 | B2 |
8058501 | Hammons | Nov 2011 | B2 |
8152957 | Edwards et al. | Apr 2012 | B2 |
8158043 | Gibson | Apr 2012 | B2 |
8241543 | O'Donnell et al. | Aug 2012 | B2 |
8557169 | Gross et al. | Oct 2013 | B2 |
20020016122 | Curro et al. | Feb 2002 | A1 |
20020039867 | Curro et al. | Apr 2002 | A1 |
20020055310 | Falk et al. | May 2002 | A1 |
20020103469 | Chen et al. | Aug 2002 | A1 |
20020105110 | Dobrin et al. | Aug 2002 | A1 |
20020107495 | Chen et al. | Aug 2002 | A1 |
20020119720 | Arora et al. | Aug 2002 | A1 |
20020132544 | Takagaki | Sep 2002 | A1 |
20030021951 | Desai et al. | Jan 2003 | A1 |
20030028165 | Curro et al. | Feb 2003 | A1 |
20030085213 | Burckhardt et al. | May 2003 | A1 |
20030121380 | Cowell et al. | Jul 2003 | A1 |
20030191442 | Bewick-Sonntag | Oct 2003 | A1 |
20030191443 | Taylor | Oct 2003 | A1 |
20030204178 | Febo et al. | Oct 2003 | A1 |
20040110442 | Rhim et al. | Jun 2004 | A1 |
20040121686 | Wong et al. | Jun 2004 | A1 |
20040122396 | Maldonado et al. | Jun 2004 | A1 |
20040126531 | Harvey et al. | Jul 2004 | A1 |
20040131820 | Turner et al. | Jul 2004 | A1 |
20040137200 | Chhabra et al. | Jul 2004 | A1 |
20040157036 | Provost et al. | Aug 2004 | A1 |
20040161586 | Cree et al. | Aug 2004 | A1 |
20040229008 | Hoying et al. | Nov 2004 | A1 |
20040242097 | Hasenoehrl et al. | Dec 2004 | A1 |
20040265533 | Hoying et al. | Dec 2004 | A1 |
20040265534 | Curro et al. | Dec 2004 | A1 |
20050021753 | Coleman | Jan 2005 | A1 |
20050051290 | Beasley, Jr. et al. | Mar 2005 | A1 |
20050064136 | Turner et al. | Mar 2005 | A1 |
20050096614 | Perez et al. | May 2005 | A1 |
20050123726 | Broering et al. | Jun 2005 | A1 |
20050153100 | Zoller et al. | Jul 2005 | A1 |
20050173085 | Schulz | Aug 2005 | A1 |
20060019056 | Turner et al. | Jan 2006 | A1 |
20060063454 | Chung et al. | Mar 2006 | A1 |
20060087053 | ODonnell et al. | Apr 2006 | A1 |
20060151914 | Gerndt et al. | Jul 2006 | A1 |
20060206072 | Malakouti et al. | Sep 2006 | A1 |
20060286343 | Curro et al. | Dec 2006 | A1 |
20070029694 | Cree et al. | Feb 2007 | A1 |
20070131368 | Xia | Jun 2007 | A1 |
20080217809 | Zhao et al. | Sep 2008 | A1 |
20080221538 | Zhao et al. | Sep 2008 | A1 |
20080221539 | Zhao et al. | Sep 2008 | A1 |
20080221541 | Lavash et al. | Sep 2008 | A1 |
20080221542 | Zhao et al. | Sep 2008 | A1 |
20080224351 | Curro et al. | Sep 2008 | A1 |
20090026651 | Lee et al. | Jan 2009 | A1 |
20090029106 | Mauler et al. | Jan 2009 | A1 |
20100001434 | Atkin | Jan 2010 | A1 |
20100032867 | Schmidt | Feb 2010 | A1 |
20100201024 | Gibson et al. | Aug 2010 | A1 |
20100318047 | Ducker et al. | Dec 2010 | A1 |
20110088859 | Hultcrantz et al. | Apr 2011 | A1 |
20120049404 | Gibson et al. | Mar 2012 | A1 |
20120064280 | Hammons et al. | Mar 2012 | A1 |
20120064298 | Orr et al. | Mar 2012 | A1 |
20120273146 | Curro et al. | Nov 2012 | A1 |
20120273148 | Orr et al. | Nov 2012 | A1 |
20120273990 | O'Donnell et al. | Nov 2012 | A1 |
20120273997 | Stone et al. | Nov 2012 | A1 |
20120276238 | Strube et al. | Nov 2012 | A1 |
20120276239 | Coe et al. | Nov 2012 | A1 |
20120276331 | Orr et al. | Nov 2012 | A1 |
20120276337 | Curro et al. | Nov 2012 | A1 |
20120276341 | Lake et al. | Nov 2012 | A1 |
20120277393 | Curro et al. | Nov 2012 | A1 |
20120277701 | Stone et al. | Nov 2012 | A1 |
20120277704 | Marinelli et al. | Nov 2012 | A1 |
20120277705 | Marinelli et al. | Nov 2012 | A1 |
20120277706 | Marinelli et al. | Nov 2012 | A1 |
20120277707 | Orr et al. | Nov 2012 | A1 |
20120277709 | Marinelli et al. | Nov 2012 | A1 |
20120277710 | Marinelli et al. | Nov 2012 | A1 |
20120282436 | Coe et al. | Nov 2012 | A1 |
20120295060 | Mullane | Nov 2012 | A1 |
20140120323 | Curro et al. | May 2014 | A1 |
Number | Date | Country |
---|---|---|
0494112 | Jul 1992 | EP |
0598970 | Jun 1994 | EP |
0 509 012 | Jul 1995 | EP |
0 955 159 | Nov 1999 | EP |
0 963 747 | Dec 1999 | EP |
1 004 412 | May 2000 | EP |
1440197 | Jan 2005 | EP |
1302937 | Sep 1962 | FR |
A 2006-175689 | Jul 2006 | JP |
WO 9515138 | Jun 1995 | WO |
WO 02100632 | Dec 2002 | WO |
WO-2004108037 | Mar 2004 | WO |
WO 2005011936 | Feb 2005 | WO |
WO-2007001270 | Jan 2007 | WO |
WO-2008107846 | Sep 2008 | WO |
WO-2010135503 | Nov 2010 | WO |
Entry |
---|
International Search Report dated Sep. 24, 2012, 11 pages. |
International Search Report dated Jul. 4, 2012, 12 pages. |
International Search Report dated Aug. 8, 2012, 10 pages. |
International Search Report dated Aug. 13, 2012, 10 pages. |
All Office Actions, U.S. Appl. No. 13/094,206. |
All Office Actions, U.S. Appl. No. 13/094,219. |
All Office Actions, U.S. Appl. No. 13/094,185. |
U.S. Appl. No. 13/546,015, filed Jul. 11, 2012, Hugh Joseph O'Donnell et al. |
U.S. Appl. No. 13/568,180, filed Aug. 7, 2012, Mullane. |
U.S. Appl. No. 13/094,265, filed Apr. 26, 2011, Luigi Marinelli et al. |
U.S. Appl. No. 13/455,185, filed Apr. 25, 2012, Luigi Marinelli et al. |
U.S. Appl. No. 13/094,279, filed Apr. 26, 2011, Luigi Marinelli et al. |
U.S. Appl. No. 13/455,190, filed Apr. 25, 2012, Luigi Marinelli et al. |
U.S. Appl. No. 13/094,295, filed Apr. 26, 2011, Luigi Marinelli et al. |
U.S. Appl. No. 13/455,194, filed Apr. 25, 2012, Luigi Marinelli et al. |
U.S. Appl. No. 13/094,310, filed Apr. 26, 2011, Jill Marlene Orr et al. |
U.S. Appl. No. 13/455,199, filed Apr. 25, 2012, Jill Marlene Orr et al. |
U.S. Appl. No. 13/094,185, filed Apr. 26, 2011, John Lee Hammons et al. |
U.S. Appl. No. 13/094,206, filed Apr. 26, 2011, Jill Marlene Orr et al. |
U.S. Appl. No. 13/094,219, filed Apr. 26, 2011, John Brian Strube et al. |
U.S. Appl. No. 13/094,477, filed Apr. 26, 2011, Keith Joseph Stone et al. |
U.S. Appl. No. 13/094,559, filed Apr. 26, 2011, Richard George Coe et al. |
U.S. Appl. No. 13/094,593, Apr. 26, 2011, Keith Joseph Stone et al. |
U.S. Appl. No. 13/455,508, filed Apr. 25, 2012, John Joseph Curro et al. |
U.S. Appl. No. 13/455,532, filed Apr. 25, 2012, John Joseph Curro et al. |
U.S. Appl. No. 13/455,698, filed Apr. 25, 2012, John Joseph Curro et al. |
U.S. Appl. No. 13/455,857, filed Apr. 25, 2012, Richard George Coe et al. |
U.S. Appl. No. 13/455,925, filed Apr. 25, 2012, Jill Marlene Orr et al. |
Number | Date | Country | |
---|---|---|---|
20140120323 A1 | May 2014 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 13094195 | Apr 2011 | US |
Child | 14147615 | US |