This invention relates to fire fighting and in particular to an apparatus and method for introducing a super absorbent polymer into a mobile fire fighting apparatus in an amount sufficient to extinguish and prevent conflagrations.
Water is well known for its fire extinguishing properties and remains the predominate material used to extinguish or prevent certain types of fires. Water has a high heat capacity and high heat of vaporization, such that when water is sprayed onto a fire, the water that reaches the flames absorbs the heat of the fire and cools the article to below its combustion temperature. Water also deprives the fire of oxygen. Often the heat of the fire turns a portion of water into vapor before it can reach the flames. Since water vapor is heavier than air it displaces the oxygen surrounding the fire, thereby suffocating the fire.
The use of water for fire prevention is none more prevalent than when used in firefighting rescue operations. In emergency situations in urban areas, a hose is attached to a fire hydrant, then the valve on the hydrant is opened to provide a low pressure source of water to a fire engine. The fire engine, which contains a pumping unit, boosts the water pressure where it can be split into multiple streams for eventual dispensing through a nozzle and unto combustible sources. In emergency situations in rural or forestry areas, a water tender, which is designed to carry loads of up to 1000 gallons or more is used as a source of water. Water tenders are useful in rural or forestry areas because fire hydrants generally not readily available in these areas. Alternatively in rural or forestry areas, an alternate water supply (e.g. lake, river, stream, swimming pool) may be used as a source of water. However, water tenders and/or alternate water supplies normally do not have sufficient water pressure to produce a steady stream of water to douse a fire; therefore a mobile fire fighting apparatus with a pumping unit is ultimately needed. Thus the mobile fire fighting apparatus with a more powerful pumping unit converts the water from a tender or alternative water supply into a high pressure stream to be used for spraying water from a nozzle towards combustible sources.
The firefighting systems, described above, comprise of a mobile fire fighting apparatus having a pumping unit within for pumping water from a source and dispensing the water at a higher pressure through a nozzle at combustible sources. However, water alone is ineffective for retarding and extinguishing fires. A significant disadvantage often encountered using water to extinguish a fire is that much of the water ends up being wasted. Most of the water applied directly to the fire is turned into steam and evaporates before it can reach the base of the fire, where the combustible fuel for the fire resides. As much as 90 to 95% of the water that does manage to reach the flames simply runs off into the ground without remaining on the structure that is burning. Moreover, considerable effort must be made to continuously soak objects with water near the fire that could ignite. The evaporated and runoff water must be constantly replaced.
To increase effectiveness in fire extinguishment and retardation the use of chemical or foam additives have been introduced into the water line exiting the pumping unit within the mobile fire fighting apparatus. Some firefighting systems use additive pumps for forced injection of the chemical into the water line, while other systems use eductor valves relying on the movement of the water through a plenum chamber to educe the chemical or foam to the water line. More importantly, these additives have been integrated into the water line after the water has passed through the pumping unit within the mobile fire fighting apparatus. Unfortunately, adding the additive after the water has passed through the pumping unit within the mobile fire fighting apparatus has several drawbacks. For instance, U.S. Pat. No. 7,367,361 B2 discloses an eductor assembly for use with firefighting equipment that comprises an eductor body defining a fluid inlet connectable to a source of a firefighting fluid, a fluid outlet for dispensing, and an additive inlet connectable to a source of additive. The additive is educed to mix with the high pressure water under venturi flow. The hose attachable to the inlet is coming from pumping unit in the fire engine; and the hose attachable to the outlet terminates at a nozzle. Thus the eductor assembly is installed after the fluid leaves the pumping unit. Assortments of drawbacks are associated with the use of this device. Firstly, the device requires time for coupling the eductor body the inlet and the outlet; and regrettably, in firefighting rescue operations wasted time spent installing an eductor assembly maybe the difference in saving several lives. Secondly, the additive may not be fully admixed with the water line in the short distance it travels from the point of addition at the additive inlet to the nozzle end, thus possibly creating a mixture with a high viscosity having a tendency to clog the lines and cause a weak stream rendering the additive ineffective. Thirdly, using chemical or foam additives requires a cleaning process after use so the additive does not harden or solidify within the hoses, eductor, or nozzle.
Some of the disadvantages associated with introducing additives to the water line maybe be resolved if the additive were to be introduced by some means before entering the pumping unit within a mobile fire fighting apparatus. However, if a chemical or foam additive were to be added before entering the pumping unit in the mobile fire fighting apparatus concerns arise. Specifically concerns regarding clogging of the water line, clogging of the pump, or left behind harden residue which may potentially destroy the pumping unit or hoses still exists.
For instance, U.S. Pat. No. 5,989,446 discloses a water additive for use in fire extinguishing and prevention. The additive comprises a cross-linked water-swellable polymer in a water/oil emulsion that is produced by an inverse phase polymerization reaction. The polymer particles are dispersed in an oil emulsion wherein the polymer particles are contained within discrete water “droplets” within the oil. With the help of an emulsifier, the water “droplets” are dispersed relatively evenly throughout the water/oil emulsion. This allows the additive to be introduced to the water supply in a liquid form, such that it can be easily educted with standard firefighting equipment. However, it has been observed that this additive takes approximately 3-4 hours to “cure” such that it is able to absorb a sufficient amount of water and attain the viscosity necessary to adhere to vertical and horizontal surfaces for firefight purposes. Also, if the additive/water mixture is not completely flushed from a hose or nozzle after use, it will harden upon drying out and render the hose or nozzle useless. While these prior arts may be suitable for the particular purpose to which they address, these prior arts would not be suitable for the purposes of the present invention as heretofore described.
What is lacking in the art is a need to increase the effectiveness of water for firefighting by integrating an apparatus and method for introducing fire retardant particles to a source of water before entering a pumping unit within a mobile fire fighting apparatus, whereby the fire retardant particles do not clog the hoses or pumping unit, do not require “curing”, do not harden or solidify, maintain a viscosity similar to water, and need not be cleaned after use.
The instant invention discloses an apparatus and method for introducing super absorbent polymers to a flow of water from an outside source thereby forming a mixture of water and super absorbent polymers before the flow of water enters the pumping unit within a mobile fire fighting apparatus.
The instant invention discloses an eductor assemblage device comprising at least one hopper and an eductor member. The eductor member is positioned between a pumping unit within a mobile fire fighting apparatus and an outside source of water. The eductor member has an inlet connectable to the outside source of water, an outlet in fluid communication with the inlet of the pumping unit, and at least one additive inlet integrated into the eductor. The hopper contains super absorbent polymer and is connected to the additive inlet. The additive inlet is in fluid communication with the eductor member wherein a flow of the outside source of water from the inlet to the outlet on the eductor member draws the super absorbent polymers through the additive inlet by venturi. The super absorbent polymers flow into the eductor member forming a mixture within for dispensing through the outlet. The mixture is dispensed through the outlet to a pumping unit in a mobile fire fighting apparatus and discharged onto a source of combustible material for fire extinguishment or retardation. The eductor assembly further includes a valve positioned between the additive inlet and the hopper wherein the valve is infinitely adjustable for regulating the flow of super absorbent polymers into the eductor member.
The super absorbent polymers are prepared from water-soluble polymers, but have cross-linking structures that render the polymers water-insoluble. By taking water-soluble ethylenically unsaturated monomers which readily undergo vinyl polymerization, such as acrylamide, with cross-linking agents, a polymer can be produced that is of uniform small size, has a high gel capacity, is highly insoluble, but highly water-swellable (i.e., super absorbent polymer). The gel capacity refers to the property of the water-swollen polymer to resist viscosity changes as a result of mechanical working or milling.
Accordingly, it is an objective of this invention to present an apparatus and method that uses super absorbent polymers to transform water into a gel-like substance effective for fire extinguishment or prevention. This super absorbent polymer gel will bring fires under control more quickly, offering substantially less water consumption and substantially more time saving. The super absorbent polymer gel may be applied to any source of combustible material in anticipation of a fire for fire retardation or directly at a source of combustible material already flaming for fire extinguishment.
Yet another objective of the present invention is to provide a device used in conjunction with an outside source of fluid and a mobile fire fighting apparatus' pumping unit to combat fires in an effective manner. More specifically, where the eductor member inlet is connectable to an outside source of fluid; and where the outlet is connectable to a hose leading to a pumping unit within a mobile fire fighting apparatus or an intake on a mobile fire fighting apparatus leading to a pumping unit. The outside source of fluid includes sources such as naturally occurring bodies of water, existing water supplies, and transportable water supplies. Examples include fire hydrants, water tender, lakes, rivers, water pools, drop tanks, swimming pools, etc.
Yet another objective of the present invention is to teach a hydrated super absorbent polymer having a viscosity that allows the polymers to be emptied through the additive inlet and the gel to be dispensed from the outlet of the eductor member without clogging or blocking. Furthermore the hydrated super absorbent polymer gel has a viscosity that allows the gel to travel within standard firefighting equipment (e.g., fire hoses, nozzles, pumping unit etc.).
Yet another objective of the present invention is to have an admix chamber within the eductor member defining a plenum. When the outside source of fluid comes through the inlet it educes the super absorbent polymers from the additive inlet into the eductor member, thus providing an admix chamber.
Another objective of the instant invention is to introduce super absorbent polymers to an outside source of fluid which will not leave behind a residue, will not harden or solidify, and will not require time to “cure” before entering a pumping unit within a mobile fire fighting apparatus therefore clearly highlighting the inventiveness of the invention.
Another objective of the instant invention is the use of an eductor assembly which provides continuous use of polymer when a flow of fluid is the primary source of water replenishment creating a venturi effect within the eductor member. Therefore as long a flow of water is running through the eductor member and the hopper retains an amount of super absorbent polymer there will be a continuous stream of the gel-like mixture dispensing from the eductor outlet. The only maintenance required is re-filling the hopper.
Another objective of the instant invention is to use super absorbent polymers which lubricates the pumping unit.
Other objectives and advantages of this invention will become apparent from the following description taken in conjunction with any accompanying drawings wherein are set forth, by way of illustration and example, certain embodiments of this invention. Any drawings contained herein constitute a part of this specification and include exemplary embodiments of the present invention and illustrate various objects and features thereof.
Detailed embodiments of the instant invention are disclosed herein, however, it is to be understood that the disclosed embodiments are merely exemplary of the invention, which may be embodied in various forms. Therefore, specific functional and structural details disclosed herein are not to be interpreted as limiting, but merely as a basis for the claims and as a representative basis for teaching one skilled in the art to various employ the present invention in virtually any appropriately detailed structure.
Referring now to
The instant invention teaches an apparatus and method of introducing polymeric material through a polymeric delivery device between an outside source of fluid and a mobile fire fighting apparatus for fire prevention and retardation. A mobile firefighting apparatus is defined as a pumping truck, ladder truck, hook and ladder truck, water tender, wildland fire engines, fireboat, or the like. The outside source of fluid includes naturally occurring sources, existing water supplies, alternative water supplies, and transportable water supplies. Naturally occurring sources include, but are not limited, rivers, lakes, ponds or the like. Existing water supplies include, but are not limited to fire hydrants, wells, or the like. Alternative water supplies include, but are not limited to, water pools, swimming pools, drop tanks, or the like. Transportable water supplies include, but are not limited to, water tender, tankers, wildland fire tenders, or the like. The polymeric delivery device is defined as a means for introducing polymeric material to a flow of fluid for admixing. The polymeric delivery device includes a positive displacement pump (shown in
The polymeric material is a dehydrated super absorbent polymer. Super absorbent polymers have properties distinct from other chemical or foam additives which are typically introduced to water hose lines in an attempt to extinguish fire. The present invention relates to a process of retarding or extinguishing conflagrations using super absorbent polymers in water in an amount sufficient to retard or extinguish the fire. The present invention utilizes biodegradable super absorbent aqueous based polymers, for example, cross-linked modified polyacrylamides, potassium acrylate, polyacrylamides, sodium acrylate commercially available from Stockhausen, Inc. (Greensboro, N.C.). Other suitable polymers include, albeit are not limited to, carboxy-methylcellulose, alginic acid, cross-linked starches, and cross-linked polyaminoacids. In the present invention, a solid form of the super absorbent polymer, such as powder, is introduced into a standard fire fighting system.
Super absorbent polymers are capable of absorbing water up to several thousand times its own weight. These super absorbent polymers are prepared from water-soluble polymers, but have cross-linking structures that render the polymers water-insoluble. By taking water-soluble ethylenically unsaturated monomers which readily undergo vinyl polymerization, such as acrylamide, with cross-linking agents, a polymer can be produced that is of uniform small size, has a high gel capacity, is highly insoluble, but highly water-swellable (i.e., super absorbent polymer). The gel capacity refers to the property of the water-swollen polymer to resist viscosity changes as a result of mechanical working or milling. Super absorbent polymer particles are capable of absorbing water in significant quantities relative to its own weight, the water-swollen gel provides a greater water laden surface area, with a higher heat capacity, than the unbound water molecule. Thus, more water actually reaches the fire without being evaporated and provides more cooling. Thus, the fire is extinguished using less water. Aside from its water soluble properties super absorbent polymers do not harden or solidify after use, they do not clog water hoses, and do not require time to “cure”; for all the reasons mentioned super absorbent polymers provide firefighting system with an opportunity to introduce an additive into the water line before the water line enters the fire engine. The use of additives like super absorbent polymers allows for a transition of placing the eductor system from after the mobile fire fighting apparatus to before the fire engine.
As shown in
The 2½″ opening on the inlet and outlet, 33 and 35, respectively, on the eductor member 32 shall comply with the standards set forth by the National Fire Protection Association (NFPA). Specifically the standards set forth in NFPA 1901: Standard for Automotive Fire Apparatus. As most mobile fire fighting apparatuses are equipped with an intake having a 2½″ internal National Hose threadings collar sized to adapt to a fire hose having a 2½″ National Hose threaded opening, the eductor assemblage in the instant invention is sized to fit both the intake on the mobile fire fighting apparatus and a standard fire hose. Should there be any changes or differences in sizing on an intake or fire hose, then the eductor member's inlet and outlet should be sized to adapt to the changes as set forth by NFPA 1901.
The intake 22 on the mobile fire fighting apparatus 20 is normally connected to a fire hose 12 coming from a source of fluid 10. However, the eductor assemblage 30, specifically the outlet 36 is adapted to connect to the intake 22 on the mobile fire fighting apparatus 30 and the inlet 34 is connected to a fire hose 12 coming from a source of fluid 10. The additive inlet 38 is positioned between the inlet 34 and the outlet 36. The additive inlet 38 comprises of an opening 37 (shown in
The super absorbent polymers 50 and the flow of outside source of fluid admix within the eductor member 32. When the super absorbent polymers 50 are introduced to the flow of fluid within the eductor member 32 through venturi the super absorbent polymers 50 admixes with the water creating an admix chamber within the eductor member 32. The turbulence created by the flow of water within the eductor member's interior walls admixes the super absorbent polymers 50 with the water creating a mixture. The mixture is a gel-like substance comprising of fluid and super absorbent polymers 50.
A valve 42 is positioned on the conduit 39 between the hopper 40 and the opening 37. In the preferred embodiment a ball valve is used, however, a butterfly valve, control valve, diaphragm valve, pinch valve, or the like is contemplated. The valve 42 is infinitely adjustable. The ball valve operates between an open position, a closed position, and an infinitely adjustable position thereinbetween.
Furthermore it is also contemplated that use of a check valve may be employed on the conduit between the valve and the additive inlet. The check valve allows fluid to flow through it in only one direction, without being manually operated. The check valve comprises of a valve seat and a valve body pushed onto the valve seat. Thus, the check valve allows the passage of only the fluid which forces the body away from the seat. Any fluid that flows in the opposite direction applies back pressure to the body, pressing the body onto the seat and not allowing the fluid to pass therethrough. In the instant invention the super absorbent polymers would force the body away from the seat allowing the super absorbent polymers to pass through conduit and opening and into the eductor member. The flow of outside source of fluid would apply back pressure on the body preventing the passage of fluid through the check valve and into the hopper.
Alternative embodiments of the eductor assemblage contemplate the use of two additive inlets placed opposite each other. Both additive inlets being in fluid communication with the eductor member and intersecting the inlet and outlet. The use of a double additive inlet requires a double hopper system. The use of a double hopper system allows firefighters to easily switch from one hopper to the other when the other is emptied. The switching of hoppers is made easy by closing the valve on the first hopper and then subsequently opening the valve on the second hopper to allow for super absorbent polymers to be drawn from the second hopper. However, the hoppers maybe positioned in a manner whereby they are not capable of using gravity to keep the super absorbent polymers near the exit of the hopper in order to be drawn out by suction thus not capable of being educed by the eductor. When this is the case, the pumping unit within the mobile fire fighting apparatus will have to be powerful enough to suction not only the stream of water through the eductor member but also super absorbent polymers from the hopper. Otherwise a piston, pump, or the like may be used to introduce the super absorbent polymers to the flow of fluid. Also, other alternative embodiments may have the additive inlets positioned adjacent each other, in this configuration; both hoppers will be placed vertically above the eductor member. By placing the hoppers vertically above the eductor member gravity is able to keep the super absorbent polymers near the exit in order to be drawn out by venturi.
A non-limiting illustrative example is presented herein; the following is only an example and not solely representative of the inventive concepts discussed herein. On a mobile fire fighting apparatus an eductor assemblage was installed. Approximately 50 pounds of a superabsorbent aqueous based polymer was placed within a hopper, introduced to a flow of 500 gallons of water at a rate between 30-100 psi through the eductor member by venturi, the water and super absorbent polymers are admixed together to form a mixture, and exited through the outlet on the eductor member. The viscosity did not cause the polymer to aggregate or prevent eduction through the 2½″ eductor member and a standard fire hose.
The super absorbent polymers can be dehydrated to a powder. When the powder is added to an aqueous solution and agitated, a super absorbent gel-like substance is formed. In a dry state the preferred polymer may be considered a particle having a diameter less than 4000 microns but greater than 50 microns. In a swollen state the particle may have a diameter greater than three hundred times its original diameter in a dry state (more surface area). In a totally water-swollen state, the particles contain up to 99.98 weight percent of water and as little as about 0.1 weight percent of polymer. Thus, such particles could hold an amount of water from ten to thousands of times their own weight.
Without wishing to be bound to any particular theory it is believed that the since the polymer particles are capable of absorbing water in significant quantities relative to its own weight, the water-swollen gel provides a greater water laden surface area, with a higher heat capacity, than the unbound water molecule. More water actually reaches the fire without being evaporated and provides more cooling. Thus, a fire can be extinguished using less water.
The reaction of the water with the polymer creates a gel-like substance with a viscosity that allows the mixture to be readily pumped through standard eduction equipment and pumping unit, yet viscous enough to cover and adhere to vertical and horizontal surfaces of structures to act as barrier to prevent fire from damaging such structures, minimizing the manpower and water supply needed to continuously soak these structures.
It should be noted that the super absorbent polymer and water of the instant invention may create a slippery surface; in such instances, a small amount of grit may be added to the super absorbent polymer if it is to be used in an area that will be traversed by individuals such as exit corridors or where fireman are expected to travel by foot or vehicle.
All patents and publications mentioned in this specification are indicative of the levels of those skilled in the art to which the invention pertains. All patents and publications are herein incorporated by reference to the same extent as if each individual publication was specifically and individually indicated to be incorporated by reference.
It is to be understood that while a certain form of the invention is illustrated, it is not to be limited to the specific form or arrangement herein described and shown. It will be apparent to those skilled in the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is shown and described in the specification and drawings/figures.
One skilled in the art will readily appreciate that the present invention is well adapted to carry out the objectives and obtain the ends and advantages mentioned, as well as those inherent therein. The embodiments, methods, procedures and techniques described herein are presently representative of the preferred embodiments, are intended to be exemplary and are not intended as limitations on the scope. Changes therein and other uses will occur to those skilled in the art which are encompassed within the spirit of the invention. Although the invention has been described in connection with specific preferred embodiments, it should be understood that the invention should not be unduly limited to such specific embodiments.
This application is a continuation-in-part of U.S. patent application Ser. No. 11/680,803, filed Mar. 1, 2007, the contents of which are herein incorporated by reference.
Number | Date | Country | |
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Parent | 11680803 | Mar 2007 | US |
Child | 12270485 | US |