Method and apparatus for making absorbent structures with absorbent material

Information

  • Patent Grant
  • 11000422
  • Patent Number
    11,000,422
  • Date Filed
    Monday, October 8, 2018
    5 years ago
  • Date Issued
    Tuesday, May 11, 2021
    3 years ago
Abstract
Apparatus and method for producing absorbent structures with absorbent layers with channel(s) without absorbent material, using a first moving endless surface with specific raised strip(s) and a second moving endless surface with specific mating strip(s).
Description
FIELD OF THE INVENTION

The present disclosure relates to a method for making an absorbent structure with strips that are free of absorbent material, by receiving absorbent material on a first surface with raised strips that do not receive absorbent material, and transferring it therewith to a second surface with mating strips, that meet with said raised strips, and that then do not receive absorbent material; and to apparatuses combining such first and second surfaces.


BACKGROUND OF THE INVENTION

Absorbent articles, such as diapers and sanitary napkins, absorb and contain body exudates. They also are intended to prevent body exudates from soiling, wetting, or otherwise contaminating clothing or other articles, such as bedding, that come in contact with the wearer. A disposable absorbent article, such as a disposable diaper, may be worn for several hours in a dry state or in a urine-loaded state. Accordingly, efforts have been made toward improving the fit and comfort of the absorbent article to the wearer, both when the article is dry and when the article is fully or partially loaded with liquid exudate, while maintaining or enhancing the absorbing and containing functions of the article.


Efforts have also been made to make absorbent article thinner when dry, to improve the comfort of such articles.


Some absorbent articles, like diapers, contain absorbent material such as super absorbent polymers that absorbs very high quantities of liquid and causes the absorbent article to swell significantly. Such articles will thus increase significantly in volume during use, and sometimes in particular in the crotch area between the wearer's legs, which may render the article uncomfortable.


There is thus still a need to further improve the fit of such articles and/or the liquid transportation away from the crotch. There is also a need to reduce the usage of absorbent material in such articles.


There is also still a need to further reduce the chance of leakage and to improve the efficiency of absorbency of an absorbent article, such as a diaper.


It has also been found that improved liquid transportation can be achieved by the provision of transportation channels for distributing liquid in the absorbent article, e.g. the absorbent structure thereof. Furthermore, it has surprisingly been found that the amount of absorbent material can be reduced hereby, whilst maintaining the performance. It has been found that improved fit can be obtained by providing absorbent articles with absorbent structures wherein the absorbent material is structured in machine direction, optionally with areas that comprise less or no absorbent material, for improved bending flexibility in use (in the direction corresponding to the machine direction).


The present disclosure provides an apparatus and method for providing such absorbent structures, having suitable transportation channels, which allow reduction of the usage of absorbent material and/or channels that improve fit/flexibility.


SUMMARY OF THE INVENTION

The present disclosure provides an apparatus (1) for making an absorbent structure comprising a supporting sheet (200) and thereon an absorbent layer with a longitudinal dimensional and transverse dimension and a height dimension, said absorbent layer comprising an absorbent material (100) with therein one or more channels that are substantially free of absorbent material, said apparatus (1) having:

    • a) a feeder (60) for feeding said absorbent material (100) to a first moving endless surface;
    • b) a transfer means for transferring a supporting sheet (200) to a second moving endless surface;
    • c) a first moving endless surface (20), having one or more absorbent layer-forming reservoirs (25) with a longitudinal dimension and averaged length, a perpendicular transverse dimension and average width, and, perpendicular to both, a depth dimension and average depth, and a void volume for receiving said absorbent material (100) therein, said reservoir(s) comprising one or more substantially longitudinally extending raised strips (21) (not having a void volume and hence not receiving said absorbent material (100) therein), each having an average width W of at least 5% of the average width of the reservoir (25) (in some embodiments optionally at least 5 mm), and an average length L of at least 5% and at the most 80% of the average longitudinal dimension of the reservoir; said reservoir(s) being for transferring said absorbent material (100) to said second moving endless surface (30) adjacent and in proximity thereto;
    • d) said second moving endless surface (30), having an outer shell that has one or more air permeable or partially air permeable receptacles (33) for receiving said supporting sheet (200) thereon or therein, and said receptacle (33) having one or more substantially longitudinally extending substantially mating strips (31), having each an average width W′ of from


      0.5×W to 1.2×W, optionally at least 2.5 mm, optionally having an average length L′ being from about 0.8×L to 1.2×L provided at the most 90% of the longitudinal dimension of the reservoir,


      wherein said outer shell is optionally connected to one or more secondary vacuum systems for facilitating retention of said supporting sheet (200) and/or said absorbent material (100) thereon, and


      wherein, in a meeting point, said first moving endless surface (20) and said outer shell and/or second moving endless surface (30) are adjacent to one another and in close proximity of one another during transfer of said absorbent material (100) and wherein each mating strip (31) is adjacent and in close proximity to a raised strip (21) during transfer of said absorbent material.


The invention also provides methods using said apparatus (1) of the invention, and/or for making an absorbent structure with a longitudinal dimensional and transverse dimension and height dimension, and comprising a supporting sheet (200) and thereon an absorbent layer of absorbent material (100) and therein one or more channels with substantially no absorbent material, said method comprising the steps of:

    • a) providing a feeder (60) for feeding said absorbent material (100) to a first moving endless surface;
    • b) providing a transfer means for transferring a supporting sheet (200) to a second moving endless surface;
    • c) providing a first moving endless surface (20), having one or more absorbent layer-forming reservoirs (25) with a longitudinal dimension and averaged length, a perpendicular transverse dimension and average width, and, perpendicular to both, a depth dimension and average depth, and a void volume for receiving said absorbent material (100) therein, said reservoir(s) comprising one or more substantially longitudinally extending raised strips (21), each having an average width W of at least 5% of the average width of the reservoir, and an average length L of at least 5% and at the most 80% of the average longitudinal dimension of the reservoir; said reservoir(s) being for transferring said absorbent material (100) to said second moving endless surface (30) adjacent and in proximity thereto;
    • d) providing a second moving endless surface (30), having an outer shell that has one or more air permeable or partially air permeable receptacles (33) with for receiving said supporting sheet (200) thereon or therein, with a receiving area and with one or more substantially longitudinally extending mating strips (31) that may be air impermeable, and having each an average width W′ of from 0.5×W to 1.2×W, an average length L′ being from about 0.8×L to 1.2×L provided at the most 90% of the longitudinal dimension of the reservoir,


      wherein said outer shell is optionally connected to one or more secondary vacuum systems for facilitating retention of supporting sheet (200) and/or said absorbent material (100) thereon, and wherein, in a meeting point, said first moving endless surface (20) and said second surface (30)/outer shell are at least partially adjacent to one another and in close proximity of one another during transfer of said absorbent material (100) and such that each mating strip (31) is substantially completely adjacent and in close proximity to a raised strip (21) during transfer of said absorbent material;
    • e) feeding with said feeder (60) an absorbent material (100) to said first moving endless surface, in at least said reservoir(s) (25) thereof;
    • f) optionally, removing any absorbent material (100) on said raised strips (21);
    • g) simultaneously, transferring said supporting sheet (200) to said second moving endless surface, onto or into said receptacle (33);
    • h) selectively transferring in said meeting point, said absorbent material (100) with said first moving endless surface (20) only to said part of the supporting sheet (200) that is on or in said receiving area of said receptacle (33).


Said reservoir(s) (25) may be formed by of a multitude of grooves and/or cavities (22) with a void volume, for receiving said absorbent material (100) therein. In some embodiments, the average width W of (each) strip is optionally at least 6 mm, or for example at least 7 mm, and/or at least at least 7%, or for example at least 10% of the average width of the respective reservoir.


Said grooves and/or cavities (22) may each for example have a maximum dimension in transverse direction which is at least 3 mm, and wherein the shortest distance between directly neighboring cavities (22) and/or grooves in substantially transverse dimension, is less than 5 mm. Cavities (22) and/or grooves that are directly adjacent a raised strip (21) may have a volume that is more than the volume of one or more, or all of their neighboring cavities (22) or grooves, that are not directly adjacent said strip or another strip (thus further removed from a strip).


Said first moving endless surface's reservoir (25) may be at least partially air permeable and said first moving endless surface (20) may have a cylindrical surface with said reservoirs, rotatably moving around a stator, comprising a vacuum chamber (28) (and optionally a blow of chamber (29) to blow pressurized air through the reservoir onto said absorbent material just before the meeting point); said second moving surface's outershell may be cylindrical, rotatably moving around a stator, comprising a secondary vacuum chamber (38) connected to said secondary vacuum system (and optionally a blow of chamber (39) to blow pressurized air through the receptacle onto said absorbent structure to facilitate removal from the second moving endless surface).


Said receptacle(s) (33) may further comprise a multitude of substantially longitudinally extending rods (36), spaced apart from one another in transverse direction, for example, each rod having a maximum cross-machine dimension of at least 0.3 mm and the minimum distance in transverse dimension between neighboring rods (36) being at least 1 mm, and said rods (36) each having an average height dimension of at least 1 mm, optionally said rods (36) and said mating strips (31) being in the same plane of the outershell.


The apparatus (1) may comprise one or more adhesive application unit(s) (50;51) as described herein. Said adhesive application can be beneficial to immobilize said absorbent material, to ensure said channels remain substantially permanent in use and/or to help the supporting material adhere to a further material placed over said absorbent layer in said channels. The method may comprise the addition a step i):

    • i) 1) applying an adhesive material (i.e. a first adhesive material) to said absorbent structure produced in step g); and/or
    • i) 2) applying an adhesive material (i.e. a second adhesive material) to said supporting sheet (200), prior or step f, or simultaneously therewith, but in any event prior to step h).
    • Step i) 1) may involve straying said first adhesive material in the form of fibers onto said absorbent layer, or part thereof, for example substantially continuously, so it is also present in said channels.
    • Step i) 2) may involve slot coating or spray-coating the supporting sheet (200), either continuously, or for example in a pattern corresponding to the channel pattern.


In some preferred embodiments herein, the apparatus (1) may have pressure roll (70) with a raised pressure pattern (71), substantially corresponding to the pattern of said mating strip(s) (31) and/or channels, for contacting selectively said absorbent structure's supporting sheet (200) and/or the further material, described herein after, in the areas corresponding to said channel (s) (only).


Said receptacle (33) of said second moving surface may have a first average width dimension and said supporting sheet (200), or said part thereof that is on said receptacle (33), has a second average width dimension, and the ratio of said first to said second average width dimension is at least 1:1.2.


By use of method and apparatus (1) herein, wherein the raised portions and mating strips (31) substantially mate during transfer of the absorbent material (100) to a supporting sheet (200) on said receptacle (33), e.g. on said mating strips (31), the absorbent structure may have said absorbent material (100) deposited on a layer with therein channels substantially without absorbent material; the absorbent layer may be in the form of strips of absorbent material (100) with therein, or therein between strips free of absorbent material (e.g. the crests of said supporting sheet (200)); in some embodiments herein, the supporting sheet (200) is formed into undulation(s) between neighboring matting strips, and/or between neighboring rods (36) that may be present, as described below, and the method and apparatus (1) herein is such that the absorbent material (100) is deposited in said undulations.


As described above, the supporting sheet (200) may be transferred to said second moving endless surface (30) such that it forms undulations and crests. Then, when the supporting sheet (200) is removed from said second moving endless surface, the supporting sheet (200) is pulled substantially flat, resulting in an absorbent structure with substantially longitudinally extending strips (that correspond to the crests of said material) that comprise substantially no absorbent material.


The invention also relates to absorbent structures, cores obtainable by the method herein or with the apparatus herein, and absorbent articles, such as pads or in particular diapers, comprising such a structure or core.


It should be understood that above and following description applies equally to the method and the apparatus (1) of the invention, and the absorbent structure obtained therewith, unless stated otherwise.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1A is a top view of a reservoir (25) of the first moving endless surface (20) herein.



FIG. 1B is a top view of an alternative reservoir (25) of the first moving endless surface (20) herein.



FIG. 2 is a side view of an apparatus (1) of the present disclosure, or used in the method of the invention.



FIG. 3 is a partial perspective view of an apparatus (1) of the present disclosure, or used in a method of the invention.



FIG. 4 is a partial perspective view of an alternative apparatus (1) of the present disclosure, or used in an alternative method of the invention.



FIG. 5 is a partial perspective view of an optional element of apparatus (1) of the present disclosure, or optionally used in a method of the invention.





DETAILED DESCRIPTION OF THE INVENTION

As summarized above, this invention encompasses a method and apparatus (1) for making an absorbent structure useful for absorbent article comprising absorbent material, optionally at least, or only, particulate superabsorbent polymer material, and preferred absorbent structure. Embodiments of such method and apparatus (1) and resulting absorbent structures and absorbent articles are further described herein after the following definitions.


Definitions

“Absorbent structure” refers to a three-dimension structure with a longitudinally dimension and perpendicular thereto a transverse dimension and perpendicular to both a height dimension, and that comprises at least an absorbent material (100) and a supporting sheet (200), and that is useful in an absorbent article.


“Absorbent layer” refers to a three dimensional layer of absorbent material, formed by deposition of absorbent material (100) onto the supporting sheet (200).


“Absorbent material” refers to a material or mixture of materials that can absorb and retain bodily fluids; it typically includes or consists of “superabsorbent polymer material”. “Superabsorbent polymer material” (also known as “absorbent gelling material,” or “AGM,” or “superabsorbent,”) refer to polymeric material that can absorb at least 10 times 9 and typically t least 15 times or at least 20 times) their weight of an aqueous 0.9% saline solution as measured using the Centrifuge Retention Capacity test (Edana 441.2-02), i.e. having a CRC of at least 10 g/g, and typically at least 15 g/g or at least 20 g/g.


“Particulate” is used herein to refer to a material which is in particulate form so as to be flowable in the dry state.


“Absorbent article” refers to a device that absorbs and contains body exudates, and, more specifically, refers to devices that are placed against or in proximity to the body of the wearer to absorb and contain the various exudates discharged from the body. Absorbent articles may include adult and infant diapers, including pants, such as infant training pants and adult incontinence undergarments, and feminine hygiene products, such as sanitary napkins and panty-liners and adult in continent pads, and breast pads, care mats, bibs, wound dressing products, and the like. Absorbent articles may further include floor cleaning articles, food industry articles, and the like. As used herein, the term “body fluids” or “body exudates” includes, but is not limited to, urine, blood, vaginal discharges, breast milk, sweat and fecal matter.


“Diaper” refers to an absorbent article generally worn by infants and incontinent persons about the lower torso so as to encircle the waist and legs of the wearer and that is specifically adapted to receive and contain urinary and fecal waste.


“Pant” or “training pant”, as used herein, refer to diaper having a waist opening and leg openings designed for infant or adult wearers. A pant may be placed in position on the wearer by inserting the wearer's legs into the leg openings and sliding the pant into position about a wearer's lower torso. A pant may be preformed by any suitable technique including, but not limited to, joining together portions of the article using refastenable and/or non-refastenable bonds (e.g., seam, weld, adhesive, cohesive bond, fastener, etc.). A pant may be preformed anywhere along the circumference of the article (e.g., side fastened, front waist fastened). While the terms “pant” or “pants” are used herein, pants are also commonly referred to as “closed diapers,” “prefastened diapers,” “pull-on diapers,” “training pants,” and “diaper-pants”. Suitable pants are disclosed in U.S. Pat. No. 5,246,433, issued to Hasse, et al. on Sep. 21, 1993; U.S. Pat. No. 5,569,234, issued to Buell et al. on Oct. 29, 1996; U.S. Pat. No. 6,120,487, issued to Ashton on Sep. 19, 2000; U.S. Pat. No. 6,120,489, issued to Johnson et al. on Sep. 19, 2000; U.S. Pat. No. 4,940,464, issued to Van Gompel et al. on Jul. 10, 1990; U.S. Pat. No. 5,092,861, issued to Nomura et al. on Mar. 3, 1992; U.S. Patent Publication No. 2003/0233082 A1, entitled “Highly Flexible And Low Deformation Fastening Device”, filed on Jun. 13, 2002; U.S. Pat. No. 5,897,545, issued to Kline et al. on Apr. 27, 1999; U.S. Pat. No. 5,957,908, issued to Kline et al on Sep. 28, 1999.


A “nonwoven” is a manufactured sheet, web or batt of directionally or randomly orientated fibers, bonded by friction, and/or cohesion and/or adhesion, excluding paper and products which are woven, knitted, tufted, stitch-bonded incorporating binding yarns or filaments, or felted by wet-milling, whether or not additionally needled. The fibers may be of natural or man-made origin and may be staple or continuous filaments or be formed in situ. Commercially available fibers have diameters ranging from less than about 0.001 mm to more than about 0.2 mm and they come in several different forms: short fibers (known as staple, or chopped), continuous single fibers (filaments or monofilaments), untwisted bundles of continuous filaments (tow), and twisted bundles of continuous filaments (yarn). Nonwoven fabrics can be formed by many processes such as meltblowing, spunbonding, solvent spinning, electrospinning, and carding. The basis weight of nonwoven fabrics is usually expressed in grams per square meter (gsm).


“Substantially cellulose free” is used herein to describe an article, such as an absorbent layer structure or core, that contains less than 5% by weight cellulosic fibers.


“Thickness” and “height” are used herein interchangeably.


A absorbent structure and absorbent layer thereof, and a receptacle (33) and a reservoir (25) herein each have a longitudinal dimension and average length, and this may be corresponding the machine direction (MD, and perpendicular thereto a transverse dimension, and average width, which may be corresponding to the cross-machine direction (CD); and a front region, back region and central region, each being ⅓ of the average length of the structure/layer, respectively, and having each the full width. Each has longitudinal edges and edge zones, extending the full length thereof—as further described below.


First Moving Endless Surface, e.g. Print Roll


The absorbent material (100) is delivered to the supporting sheet (200) by a first moving endless surface (20) placed adjacent and in close proximity to said second moving endless surface, for example substantially above said surface. The absorbent material (100) may be deposited substantially continuously. The point or area where the absorbent material (100) leaves the first moving endless surface (20) and transfers to said second moving endless surface (30) is herein referred to as meeting point; and in this point or area a raised strip (21), e.g. each raised strip, mates with a mating strip (31), e.g. without direct contact.


A feeder (60) may deliver the absorbent material (100) to said first moving endless surface. Such as feeder (60) is capable of containing the absorbent material (100) and letting it flow to the supporting sheet (200) on said second moving endless surface, for example continuously. The feeder (60) may be a (e.g. stationary) hopper with a container portion, to hold the material, e.g. having a volume of at least 1000 cm3, and it may have a guiding portion, e.g. a pipe-shapes portion, that guides the material from the container portion to the first moving endless surface.


The first moving endless surface (20) may be a rotating roll or drum, as for example shown in the FIGS. 2, 3 and 4. The radius of the first moving endless surface (20) may depend on what absorbent structure is produced, e.g. what size, and for example how many structures are produced per cycle of the first moving endless surface, e.g. print roll or drum. For example, the drum/print roll may have a radius of at least 40 mm, or of at least 50 mm; it may be for example up to 300 mm, or up to 200 mm. In some embodiments, the radius of the first moving surface is less than 50% of the radius of the second moving endless surface.


The first moving endless surface (20) may have any suitable width, but for example a width (for example in CD, hence perpendicular to MD) corresponding (substantially) to the width of the absorbent structure to be produced; this for example be at least 40 mm, or at least 60 mm, or for example up to 400 mm, or up to 200 mm.


Said first moving endless surface (20) may have one or more reservoirs with a certain volume for receiving said absorbent material (100) therein, and transporting it to and then depositing it on said supporting sheet (200) on a second moving endless surface.


Each reservoir (25) corresponds typically to an absorbent structure to be produced, as suitable for an absorbent article. The supporting sheet (200) may be a web material, so the method and apparatus (1) herein can thus serve to produce a web of such absorbent structures that are then subsequently separated into individual structures.


The reservoir (25) is at least partially air-permeable. It typically has an area that serves to receive said absorbent material, and this area is substantially in air-communication with a vacuum system, i.e. air permeable.


As for example shown in FIGS. 1A and 1B and FIG. 3, the reservoir (25) has one or more raised strips (21) (that have no void volume) and that, when the first moving endless surface (20) moves (rotates) adjacent said second moving endless surface (30) with said supporting sheet (200) on said mating strips (31), said raised strips (21) mate substantially coincide (herein referred to as: mate) with said mating strips (31). Then, the absorbent material (100) is deposited selectively on the substrate material on the portions thereof that are not on said mating strips (31), to form an absorbent layer on a supporting sheet (200), having channels (strips) that are substantially free of absorbent material. A reservoir (25) has typically the same number of raised strips (21) as the number of mating strips (31) of the second moving endless surface.


Said strip(s) (21) may not be in air communication with a vacuum system that is in air communication with said first moving endless surface, i.e. the raised strips (21) may be air impermeable. They may have thereto have surfaces that have no apertures. The remaining area of the reservoir (25) that has void volume for receiving the absorbent material, thus excluding the raised strips (21), may be in air-communication with a vacuum system, e.g. having apertures in air-communication with a vacuum system.


The reservoir (25) has peripheral edges, and peripheral edge zones, including opposing longitudinal edges and edge zones, and a transverse front edge and front edge zone, and a transverse back edge and back edge zone. Each of said front and back edge zones, extending the complete transverse dimension, may for example have a longitudinal dimension of from about 5% to about 20%, or to 15%, or to 10% of the average longitudinal dimension of the reservoir. Each of said longitudinal edge zone may extend the length of the reservoir (25) and may have an average transverse dimension of for example from about 5% to about 20%, or typically to about 15% or to about 10% of the total average transverse dimension of the reservoir. In some embodiments herein, said raised strip(s) are not present in any of said edge zones.


The reservoir (25) may in addition, or alternatively, comprise a front region, back region and central region, therein between, as further described below. The central region may be for example the central ⅓ of the reservoir, extending the full transverse dimension. In some embodiment, the raised strips (21) are present only in the front region; alternatively, in some embodiments, the raised strips (21) are present in the central region only or at least; alternatively, in some embodiments, the raised strips (21) are present in the central region and front region and optionally in the back region. It may alternatively or in addition be preferred that one or more raised strips (21) are present in the central region and front region. To provide improved liquid transportation and more efficient absorbency by the whole absorbent structure, it may be preferred to have said raised strip(s) at least in the central region and optionally extending also at least in the front region.


In any such case, it may be preferred that none of the edge zones described above comprises such raised strips (21).


As for example shown in FIGS. 3 and 4, a raised strip (21) meets (and hence mates with) a mating strip (31) during the transfer of the absorbent material (100) herein, i.e. during absorbent material (100) transfer to said second moving endless surface, said raised strip (21) substantially overlaps said mating strip. This typically applies to each mating raised strip (21) and mating strip. In other words, each raised strip (21) typically has a corresponding mating strip. It should be understood that the raised strip (21) and mating strip (31) do not directly touch during the absorbent material (100) transfer (the supporting sheet (200) material is in between them). The supporting sheet (200) may or may not touch the raised strip(s).


The following is described for a raised strip, in relation to its corresponding mating strip, but may be, applicable to each raised strip.


A raised strip (21) and the corresponding mating strip (31) may have the same size and shaped and surface area, and be hence completely mating. It may be that a raised strip (21) has a surface area that is slightly more than the surface area of a corresponding mating strip. Hereby, the mating strip (31) and the corresponding raised strip (21) then typically still have substantially the same overall shape. Preferred length ratios and dimensions are herein described above and below.


In some embodiments, it may be preferred (in addition or as alternative of the above) that a mating strip (31) may have an average width W′ that is less than the average width W of the raised strip, but in some embodiments, W′ is not more than W, as further described above and below.


W is at typically least 5 mm, or for example at least 6 mm. or for example at least 7 mm or for example at least 8 mm, and for example less than 40 mm or less, or less 30 mm or less, or for example 20 mm or less.


A raised strip (21) extends typically at the most 80% or at the most 70% of the longitudinal dimension of the reservoir.


Thus, the average length of a raised strip (21) may be 80% or less of the average length of the reservoir, or for example at the most 70%.


The raised strips (21) are substantially longitudinally extending. They may be straight or for example curved, with a radius of curvature as describe herein, or angled, as described herein below.


The reservoir (25) may have for example at least two raised strips (21) on either side of the longitudinal axis of the reservoir, and being mirror images of one another. This is for example shown in FIG. 1 A.


The reservoir (25) may also for example have 3 or 4, or for example 5 or for example 6 raised strips (21). Two or more thereof may be parallel to one another. The reservoir (25) may have for example 3, or 4, or 5, or 6 raised strips (21) that are at least present in the central region, and optionally extend in the front region and optionally in the back region; they may be parallel to one another and/or they may be such that those on one longitudinal side of the longitudinal axis of the reservoir (25) are mirror images of those that are on the opposite longitudinal side. This is for example shown in FIG. 1 B.


The reservoir (25) may have for example two raised strips (21) in the front region, on either side of the longitudinal axis, and mirror images of one another therein; and two raised strips (21), extending in at least the central region, on either side of the longitudinal axis, and mirror images of one another therein; and optionally two raised strips (21) in the back region, on either side of the longitudinal axis, and mirror images of one another therein.


In some embodiments, there may be no raised strip (21) coinciding with the longitudinal axis of the reservoir, but only on either side thereof. This may help to ensure an absorbent structure formation into a U-shape during use, rather than a V-shape, which may be better for fit and/or absorbency.


In some embodiments, at least two raised strips (21) extend, and hence have an average length of, at least 50% of the average length of said reservoir. In some embodiments, there are at least an additional two raised strips (21) that have an average length that is less than 50% of the average length of the reservoir.


The raised strip's cross-section in the X-Z plane (X being transverse dimension; Z being height dimension) may be any form. It may have a square, rectangular, or hexagonal cross-section, for example. However, the top surface is typically flat, i.e. in the X-Y plane of the reservoir.


(Each of) said raised strip(s) herein is typically substantial longitudinally extending, which means that its longitudinal extension is more than its transverse extension. This includes raised strip(s) that are completely longitudinally extending and straight; it includes raised strip(s) under an angle with the longitudinal axis of the reservoir, provided said angle is at the most 30°; this may include raised strip(s) that may be slightly curved (as described herein below); this includes raised strip(s) that may be wavy; this includes raised strip(s) that may comprise an angle(s), provided said angle is at least 120°; and provided that any such raised strip(s) extend more in longitudinal dimension than in transverse dimension, e.g. that any such raised strip(s) extend at least 50% or at least 100% more in longitudinal dimension than in transverse dimension.


In some embodiments, one or more of the raised strips (21) may be slightly curved, for example having a single curvature, as for example shown in the Figures, having a curvature with a radius that is at least equal to the average transverse dimension of the reservoir; and/or having a curvature following for example the contour of the closest longitudinal side edge. In some embodiments it may be preferred that the raised strips (21) are concave, wherein the longitudinal centre of the strip is closer to the longitudinal-axis of the reservoir (25) than the end point(s), and wherein the radius of curvature is at least 1 time, or optionally at least 1.5 times the average transverse dimension of the reservoir.


In some embodiments, the reservoir (25) is, in addition to said raised strip (21) or strips, composed of multitude of grooves, extending substantially in longitudinal dimension, or a multitude of rows of cavities, extending substantially in longitudinal dimension, for receiving the absorbent material (100) therein, with therein between said raised strip(s).


In some embodiments herein, said raised strips (21) have a contour, and adjacent either longitudinal side thereof, there is at least one such first row or groove, and adjacent thereto a second row and/or or groove, and said second row and/or groove may have a total volume less than the total volume of said first row or groove. Thereby, directly adjacent a channel (in the absorbent structure herein) the absorbent material (100) may have a higher basis weight than in a further adjacent zone.


In some embodiments herein, neighboring grooves or rows may be separated from one another but the spacing distance (in transverse dimension) between neighboring cavities (22) of neighboring rows or between neighboring grooves is less than 5 mm, and typically 4 mm or less, or 3.5 mm or less, or for example 3 mm or less.


Such grooves and/or rows may during the absorbent material (100) transfer mate with (coincide with) the portions of the substrate material that are between the neighboring rods (36), if present, and as described below, that extend substantially in longitudinal dimension; and hence, the areas between neighboring grooves and/or rows may mate (coincide) during absorbent material (100) transfer with the portions (strips) of the supporting sheet (200) that are on said rods (36), if present, as described below.


The cavities (22) may have any dimensions and shape, including cubical, rectangular, cylindrical, semi-spherical, conical, or any other shape. This may be any suitable number of cavities, but for example at least 20 or at least 50.


The cavities (22) may be present as identical cavities (22) or they may vary in dimension(s) or shape. The exact pattern, dimensions etc. will depend on the required structure to be formed, but may for example also depend on the particle size of the absorbent material, process speed etc.


In some embodiments at least 30% of the surface area of the reservoir (25) of the first moving endless surface (20) comprises said cavities, optionally at least 40%; and optionally up to 60% or up to 55%.


The distance in longitudinal dimension between the centre point of a cavity (22) (said centre point being in the plane of the outer surface of the first moving endless surface) and the centre point of a neighboring cavity (22) (in a row of cavities (22)) may for example be at least 3 mm, or at least 4 mm, or at least 6 mm, or for example up to 40 mm or up to 30 mm or up to 20 mm. This may apply to all such distances between neighboring cavities (22) in longitudinal dimension, or this may be an average over all such distances.


The distance in transverse dimension between the centre point of a cavity (22) or groove (said centre point being in the plane of the outer surface of the first moving endless surface) and the centre point of a neighboring cavity (22) or groove (in a transverse line of cavities) may for example also be as above. In some embodiments, the shortest distance in transverse dimension between two neighboring cavities (22) of a line of cavities (22) or between neighboring grooves is 4.0 mm or less.


In some embodiments, the longitudinal dimension of a cavity (22) may be (on average over all cavities (22) and/or for each cavity; measured over the outer surface of the first moving endless surface) at least 1 mm, or at least 2 mm, or at least 4 mm, and for example at the most 20 mm or at the most 15 mm. The transverse dimension may be within the same ranges as above, or it may even be the same as the longitudinal dimensions for one or more or each cavity.


Said rows or grooves may extend substantially parallel to, and equally spaced from, one another and/or said lines may extend substantially parallel to, and equally spaced from, one another.


In some embodiments, two or more of the rows or grooves, or part thereof, may be in the form of the longitudinal side edges of the raised strip, to which they are adjacent (and hence typically parallel), e.g. having the same curvature, angle etc as described herein.


The reservoir, cavities (22) or grooves may have any suitable dept dimension, and it may depend for example on the height of the first moving endless surface (20) (e.g. radius), the thickness of the desired structure to be produced, the particle size of the material, etc. The maximum depth of a reservoir, cavities (22) or grooves and/or the average maximum depth (average over all maximum depths of all cavities (22) and/or grooves) may for example be at least 1 mm, or at least 1.5 mm, or for example 2 mm or more, and for example up to 20 mm, or up to 15 mm, or in some embodiment herein, up to 10 mm, or to 5 mm, or to 4 mm.


According to some embodiments herein, the cavities (22) may have a an average dimension in longitudinal dimension and in transverse dimension of from 2 to 8 mm or from 3 mm to 7 mm; and the cavities (22) may have a maximum depth and/or average maximum depth of for example from 1.5 mm to 4 mm.


A scraper or doctor blade may be used to remove excess absorbent material. Excess material may be removed from the reservoir (25) and recycled back to e.g. the hopper


One possibility to hold the material in the reservoir (25) (or its grooves or cavities) may be a vacuum applied to the inner side of the first moving endless surface, e.g. print roll or drum, in combination with suction apertures in (the bottom) of the reservoir, or of the grooves, or of cavities (22) thereof, to thus apply the vacuum suction onto the absorbent material. The vacuum is for example released just before or at the meeting point. The vacuum may be any vacuum pressure such as for example at least 10 kPa, or at least 20 kPa.


The vacuum may be provided by providing one or a plurality of vacuum chambers (28) in said first moving endless surface (20) (e.g. in its interior), wherein said vacuum can be applied, reduced, increased, and released (disconnected), depending on the position thereof in the process/apparatus.


Additional air pressure may be applied to said absorbent material (100) close to or at the meeting point, by provision of an air chamber (29) to ensure that the material flows to the supporting sheet (200) on said second moving endless surface.


Second Moving Endless Surface (30)


The method and apparatus (1) herein deploy a second moving endless surface (30), moving, like the first moving endless surface, in a machine direction (MD). It has an outer shell with one or more forming receptacle (s) (33), for receiving thereon or therein the supporting sheet (200) (which may be a web material, as described herein below, or individual sheets that are placed on a receptacle (33)). The following is described for a single receptacle (33) but may apply to each receptacles (33) of the second moving endless surface's outer shell.


Each receptacle (33) corresponds typically to an absorbent structure to be produced, as suitable for an absorbent article. The supporting sheet (200) may be a web material, so the method and apparatus (1) herein can thus serve to produce a web of such absorbent structures that are then subsequently separated into individual structures.


The second moving endless surface (30) may have or be a rotating surface, such as a rotating, e.g. cylindrical, drum. It may be that the outer shell moves, e.g. rotates, around a stationary inner chamber, e.g. a so-called stator.


The outer shell and the receptacle (33) have an average transverse dimension, which may for example be the cross-machine (CD) dimension, and the receptacle (33) has an average longitudinal dimension perpendicular thereto, which may for example be the machine dimension.


The receptacle (33) is at least partially air-permeable. It typically has an area that serves to receive said absorbent material, and this area is substantially in air-communication with a vacuum system, i.e. air permeable.


The receptacle (33) has one or more, optionally at least 2, substantially mating strips (31), that substantially mate (coincide) with said raised portion (but without contacting these directly), herein referred to as mating strips (31). Said mating strip(s) may not be in air communication with said vacuum system, i.e. it may be air impermeable. They may have thereto e a surface in the plane of the receptacle (33) that has no apertures.


A receptacle (33) has typically the same number of mating strips (31) as the number of raised strips (21) of a reservoir (25) of the first moving endless surface.


A raised strip (21) coincides (and hence mates with) a mating strip (31) during the transfer of the absorbent material (100) herein, i.e. during absorbent material (100) transfer to said second moving endless surface, said raised strip (21) substantially overlaps said mating strip. This typically applies to each mating raised strip (21) and mating strip. In other words, each raised strip (21) typically has a corresponding mating strip. It should be understood that the raised strip (21) and mating strip (31) do not directly touch during the absorbent material (100) transfer (the supporting sheet (200) material is in between them). The supporting sheet (200) may or may not touch the raised strip(s) (21); typically it does not.


The receptacle (33) has peripheral edges, and peripheral edge zones, including opposing longitudinal edges and edge zones, and a transverse front edge and front edge zone, and a transverse back edge and back edge zone. Each of said front and back edge zones, extending the complete transverse dimension, may for example have a longitudinal dimension of from about 5% to about 20%, or to 15%, or to 10% of the average longitudinal dimension of the receptacle (33). Each of said longitudinal edge zone may extend the length and may have an average transverse dimension of for example from about 5% to about 20%, or typically to about 15% or to about 10% of the average transverse dimension of the receptacle (33). In some embodiments, the mating strips (31) is not present in any of the edge zones.


The receptacle (33) may in addition, or alternatively, comprise a front region, back region and central region, therein between, as further described below. The central region may be for example the central ⅓ of the receptacle (33), extending the full transverse dimension. In some embodiment, the mating strip(s) are present only in the front region; alternatively, in some embodiments, the mating strip(s) are present in the central region only or at least; alternatively, in some embodiments, the mating strip(s) are present in the central region and front region and optionally in the back region. It may alternatively or in addition be preferred that one or more mating strips (31) are present in the central region and front region. To provide improved liquid transportation and more efficient absorbency by the whole absorbent structure, it may be preferred to have said mating strip(s) at least in the central region and optionally extending also at least in the front region.


In any such case, it may be preferred that none of the edge zones described above comprises such mating strips (31).


The following is described for a mating strip, in relation to its corresponding raised strip, but may be, and optionally is, applicable to each mating strip (31) (and its corresponding raised strip).


A mating strip (31) and the corresponding raised strip (21) may have the same size and shaped and surface area, and be hence completely mating. It may be that a raised strip (21) has a surface area that is slightly more than the surface area of a corresponding mating strip. Hereby, the mating strip (31) and the corresponding raised strip (21) then typically still have substantially the same overall shape.


In some embodiments, it may be preferred that at least the average length of a mating strip (31) and the average length of a corresponding mating step are substantially the same, the difference for example being at the most 20%, or for example the raised strip (21) having an average length that is at the most 10% more than the average length of the corresponding mating strip. The average length L′ of a mating strip (31) is hence from about 0.8×L to 1.2×L, or for example from 0.9×L to 1.1×L, or to 1×L, (L being the average length or the corresponding raised strip).


In some embodiments, it may be preferred (in addition or as alternative of the above) that a mating strip (31) may have an average width W′ that is less than the average width W of the raised strip, but in some embodiments, W′ is not more than W. Hence, W′ is from 0.5×W to 1.2×W, or for example from 0.66×W, or for example from 0.8×W, to for example 1×W, or for example to 0.9×W.


W′ may for example be at least 2.5 mm, or for example at least 4 mm or for example at least 6 mm. W′ may be less 20 mm or less, or less 15 mm or less, or for example 10 mm or less.


Thus in some embodiments, a raised strip (21) is completely overlapping a corresponding mating strip (31) during the absorbent material (100) transfer, but a mating strip (31) is not substantially overlapping a corresponding raised strip. This may help spreading of the deposited absorbent material (100) slightly on said supporting sheet (200), to ensure a more homogeneous deposition thereof on said supporting sheet (200).


Each mating strip (31) extends typically at the most 90% of the longitudinal dimension of the receptacle (33), or for example at the most 80% or at the most 70%.


Thus, the average length of a mating strip (31) may be 90% or less of the average length of the receptacle (33), or for example at the most 80% or at the most 70%.


The receptacle (33) may have for example at least two mating strips (31) on either side of the longitudinal axis of the receptacle (33), and being mirror images of one another. They may be straight or for example curved, with a radius of curvature as describe herein.


The receptacle (33) may also for example have 3 or 4, or for example 5 or for example 6 mating strips (31). Two or more thereof may be parallel to one another.


The receptacle (33) may have for example 3, or 4, or 5, or 6 mating strips (31) that are at least present in the central region, and optionally extend in the front region and optionally in the back region; they may be parallel to one another and/or they may be such that those on one longitudinal side of the longitudinal axis of the receptacle (33) are mirror images of those that are on the opposite longitudinal side.


The receptacle (33) may have for example two mating strips (31) in the front region, on either side of the longitudinal axis, and mirror images of one another therein; and two mating strips (31), extending in at least the central region, on either side of the longitudinal axis, and mirror images of one another therein; and optionally two mating strips (31) in the back region, on either side of the longitudinal axis, and mirror images of one another therein.


In some embodiments, there may be no mating strip (31) coinciding with the longitudinal axis of the receptacle (33), but only on either side thereof. This may help to ensure an absorbent structure formation into a U-shape during sue, rather than a V-shape, which may be better for fit and/or absorbency.


In some embodiments, at least two mating strips (31) extend, and hence have an average length (longitudinal dimension) of are at least 50% of the average length of said receptacle (33). In some embodiments, there are at least an additional two mating strips (31) that have an average length that is less than 50% of the average length of the receptacle (33).


The mating strip (31) cross-section in the X-Z plane may be any form. It may have a square, rectangular, or hexagonal cross-section, for example. However, the tops surface that supports the supporting sheet (200) is typically flat, i.e. in the X-Y plane of the receptacle (33).


(Each of) said mating strip(s) (31) herein is typically substantial longitudinal extending, which means that its longitudinal extension is more than its transverse extension. This includes mating strip(s) (31) that are completely longitudinally extending and straight; it includes mating strip(s) under an angle with the longitudinal axis of the reservoir, provided said angle is at the most 30°; this may include mating strip(s) that may be slightly curved (as described herein below); this includes mating strip(s) that may be wavy; this includes mating strip(s) that may comprise an angle(s), provided said angle is at least 120°; and provided that any such mating strip(s) extend more in longitudinal dimension than in transverse dimension, e.g. that any such mating strip(s) extend at least 50% or at least 100% more in longitudinal dimension than in transverse dimension.


In some embodiments, one or more of the mating strips (31) may be slightly curved, for example having a single curvature, having a curvature with a radius that is at least equal to the average transverse dimension of the reservoir; and/or having a curvature following for example the contour of the closest longitudinal side edge. In some embodiments it may be preferred that the mating strips (31) are concave, wherein the longitudinal centre of the strip is closer to the longitudinal-axis of the reservoir (25) than the end point(s), and wherein the radius of curvature is at least 1 time, or optionally at least 1.5 times the average transverse dimension of the reservoir.


The receptacle (33) area other than said mating strips (31) may for example be a mesh material that hence has apertures and is in air communication with said vacuum system (38), e.g. being air permeable.


The surface area of the receptacle (33), other than the mating strips (31), may alternatively comprise thin supports substantially in transverse, for supporting the supporting sheet (200), as for example shown in FIG. 3, i.e. typically having a maximum dimension in longitudinal direction which may be less than the average width dimension of the adjacent mating strip; and/or for example at the most 4 mm, or for example at the most 3 mm.


As for example shown in FIG. 4, the receptacle (33) may further comprise a multitude of substantially longitudinally extending rods (36), spaced apart from one another, and typically from a neighboring mating strip, in transverse direction. Such rods (36) may then partially form the most outer surface of said receptacle (33), so that the supporting sheet (200) is received and carried by said rods (36) and said mating strips (31).


Between rods (36), or between rods (36) and a neighboring mating strip, there is then a spacing where the supporting sheet (200) may not be supported directly by the receptacle (33)'s mating strips (31) or rods (36).


The receptacle (33) may comprise said rods (36) over substantially the whole length (longitudinal dimension) of the receptacle (33); or for example over the whole length except the front edge zone and/or back edge zone; or, in some embodiments herein, the rods (36) may be present only in said central region; in some embodiments, the rods (36) may be present in the front region and optionally the central region, but not the back region; in some embodiments, the rods (36) may be present in the back region and optionally the central region, but not the front region.


The receptacle (33) may comprise such rods (36) over the whole width (longitudinal-dimension) of said receptacle (33); or for example over the whole width except in said longitudinal edge zones.


In any of these embodiments, the zone(s) or region(s) not comprising said rods (36) is herein referred to as rod-free zone or rod-free region; in said rod-free region or rod-free zone the supporting sheet (200) is then deposited onto said mating strips (31) and optionally said inner grid (e.g. a mesh material) directly.


Said receptacle (33) may have in said region(s) or zone(s) that not comprising said rods (36) a higher friction than said rods (36). This can aid to ensure the supporting sheet (200) is pulled in between the rods (36), or rods (36) and mating strips (31), in the low friction zone, and less or not at all in the high friction zone. For example, the receptacle (33) can be made of a higher friction material (e.g. a material with a less even surface), or may be treated with an friction-increasing agents, in those zones or regions not comprising said rods (36); or for example said zones or regions with rods (36), or only said rods (36), can be made of a lower friction material, or treated with friction-reducing agent.


A rod (36), if present, is substantial longitudinally-extending, which means for the purpose of the invention the same as defined above for the mating strip.


The rod (36) may be any shape or form. It may have a square, rectangular, round, oval or hexagonal cross-section in CD, for example. Each rod has a top portion (which may be the top surface for, for example, rods (36) that have a square or rectangular cross-section) and an opposing bottom portion or surface. Said top portion or surface is then in contact with the supporting sheet (200); said bottom surface may be adjacent (e.g.: on) an, at least partially, air-permeable inner grid.


In some embodiments, it may be preferred that the rod is generally rectangular with optionally a triangular-shaped top portion.


The minimum distance between neighboring rods (36) or neighboring rods (36) and a mating strip (31) is for example (in transverse dimension) at least 2 mm, or at least 3 mm, or at least 5 mm, or for example at least 10 mm.


Two or more rods (36) may be parallel to one another, so that the spacing distance between parallel neighboring rods (36), in transverse dimension, is at least said 2 mm along substantially the whole length.


Thus, there may be a void volume between neighboring rods (36), or between a rod and a neighboring mating strip, and said void volume extends substantially in machine direction. This void volume can serve to receive the supporting sheet (200) therein, as an undulation, and then optionally said absorbent material (100) therein.


Each rod may have a maximum cross-machine dimension which may be at least 0.1 mm, optionally at least 0.3 mm, or at least 0.5 mm, and for example less than 4 mm, or less than 2 mm.


The receptacle (33) may for example have at least 2 such rods (36), or for example at least 4 such rods (36), or for example at least 5 or at least 7 such rods (36).


Said rods (36) may be straight in longitudinal direction and/or they may for example be parallel to a neighboring mating strip.


In some preferred embodiments, the supporting sheet (200) is deposited onto said mating strips (31) and optional rods (36) and it bends in between neighboring mating strips (31) and/or rods (36), e.g. due to the vacuum suction, to form thereby in said sheet undulations between neighboring rods (36) and/or mating strips (31), and crests supported on said rods (36)/mating strips (31) (on said top surface or top portion). (The inner grid may control/determine the size (height) of said undulations.)


The supporting sheet (200) is transferred from a transfer means, such a transfer roll (210), to said second moving endless surface (30) and deposited onto said outershell/receptacle(s) (33). It may be transported to the outershell and receptacle (33) thereof as a web, or as individual sheets. The supporting sheet (200) may be a nonwoven material, as further described herein.


Subsequently, said absorbent material (100) may be deposited onto said supporting sheet (200), on said receptacle (33), such that substantially no material is deposited on the portions of the supporting sheet (200) that are on the mating strips (31).


The absorbent material (100) may be deposited such that it is only present on the portions of the supporting sheet (200) (e.g. strips of supporting sheet (200)) that is present between neighboring rods (36) and/or mating strips (31), e.g. in said undulations. Thereto, specific first moving surface may be used that has the specific grooves or cavities (22) that mate with said undulations, and not with said rods (36) as described below may be used.


Alternatively, or in addition, the vacuum may be such that it pulls the absorbent material (100) to or towards the portions of the supporting sheet (200) present between neighboring rods (36) and/or mating strips (31), e.g. into said undulations. Substantially no absorbent material (100) may for example be present on the supporting sheet (200) present on said rods (36), (not on said mating strips (31), as set out herein above already), e.g. on said crests of said supporting sheet (200).


Alternatively, or in addition, absorbent material (100) deposited onto the portions of the supporting sheet (200) on said rods (36) (e.g. said crests) may be removed by means known in the art, such as a scraper or doctor blade.


Alternatively, or in addition, the supporting sheet (200) may comprise adhesive. For example said adhesive may be present on said portions of said supporting sheet (200) that are between neighboring rod and/or mating strips (31), e.g. said undulations. This may help to adhere the absorbent material (100) in such portions, e.g. on said undulations. The supporting sheet (200) may then, prior to addition of the absorbent material, comprise no adhesive applied on said portions supported by said rods (36) and/or mating strips (31), e.g. said crests, so that less or no absorbent material (100) adheres in said portions, e.g. crests.


In some embodiments, the second moving endless surface (30) may for example have a speed of at least 1000 part per minute and/or a speed of at least 4.5 m/s, or at least 6 m/s, or at least 8 m/s.


Absorbent Material (100)


The absorbent material (100) herein is optionally a flowable material (in the dry state), such as a particulate material; it may be any material in particulate form, which includes particles, flakes, fibers, spheres, agglomerated particles and other forms known in the art.


The absorbent material (100) comprises superabsorbent polymer material (e.g. particles), optionally combined with cellulosic material (including for example cellulose, comminuted wood pulp in the form of fibers). In some embodiment, the absorbent material (100) may comprise at least 60%, or at least 70% by weight of superabsorbent polymer material, and at the most 40% or at the most 30% of cellulosic material. In some other embodiments, the absorbent layer comprises absorbent material (100) that consists substantially of absorbent polymer material, e.g. particles, e.g. less than 5% by weight (of the absorbent material) of cellulosic material is present; and said absorbent layer/absorbent structure, may be free of cellulosic material.


In some embodiments herein, the absorbent material, e.g. the particulate absorbent material, comprises at least, or consists essentially of or consists of, (particulate) superabsorbent polymer material, herein referred to as SAP, and also known as particulate absorbent gelling material, AGM. The particulate SAP herein may have a high sorption capacity, e.g. having a CRC of for example at least 20 g/g, or at 30 g/g. Upper limits may for example be up to 150 g/g, or up to 100 g/g.


The particulate SAP may have a good permeability for liquid, for example, having a SFC value of at least 10×10−7 cm3 s/g; or optionally at least 30×10−7 cm3·s/g, or at least 50×10−7 cm3s/g 10×10−7 cm3s/g, or possibly permeability SFC value of at least 100×10−7 cm3s/g, or at least a SFC of 120×10−7 cm3 sec/g. This SFC is a measure of permeability and an indication of porosity is provided by the saline flow conductivity of the gel bed as described in U.S. Pat. No. 5,562,646, (Goldman et al.) issued Oct. 8, 1996 (wherein however a 0.9% NaCl solution is used instead of Jayco solution). Upper limits may for example be up to 350 or up to 250 (×10−7 cm3·s/g).


In some embodiments herein the polymers of said SAP are internally cross-linked and/or surface crosslinked polymers.


In some embodiments herein, the absorbent material (100) comprising or consisting of particles of polyacrylic acids/polyacrylate polymers, for example having a neutralization degree of from 60% to 90%, or about 75%, having for example sodium counter ions, as known in the art; they may be surface crosslinked and/or internally crosslinked polyacrylic acid/polyacrylate polymers.


In some embodiments herein, the absorbent material (100) is in the form of particles with, a mass medium particle size up to 2 mm, or between 50 microns and 2 mm or to 1 mm, or optionally from 100 or 200 or 300 or 400 or 500 m, or to 1000 or to 800 or to 700 μm; as can for example be measured by the method set out in for example EP-A-0691133. In some embodiments of the invention, the material is in the form of particles whereof at least 80% by weight are particles of a size between 50 μm and 1200 μm and having a mass median particle size between any of the range combinations above. In addition, or in another embodiment of the invention, said particles are essentially spherical. In yet another or additional embodiment of the invention the absorbent material (100) has a relatively narrow range of particle sizes, e.g. with the majority (e.g. at least 80% or optionally at least 90% or even at least 95% by weight) of particles having a particle size between 50 μm and 1000 μm, optionally between 100 μm and 800 μm, and more optionally between 200 μm and 600 μm.


The absorbent material (100) herein may advantageously comprise less than 15% by weight of water, or less than 10%, or less than 8% or less than 5%. The water-content can be determined by the Edana test, number ERT 430.1-99 (February 1999) which involves drying the particulate material (100) at 105° Celsius for 3 hours and determining the moisture content by the weight loss of the particulate material (100) after drying.


The particulate SAP herein may be particles of SAP that are surface coated or surface treated (this not including surface-crosslinking, which may be an additional surface-treatment); such coatings and surface treatment steps are well known in the art, and include surface treatment with one or more inorganic powders, including silicates, phosphates, and coatings of polymeric material, including elastomeric polymeric materials, or film-forming polymeric materials.


Supporting Sheet (200)


The absorbent structure producible with the apparatus (1) and method of the invention comprises a supporting sheet (200), to receive the absorbent material. This supporting sheet (200) may be any individual sheet or web sheet material, in particular paper, films, wovens or nonwovens, or laminate of any of these.


In some embodiments herein, the supporting sheet (200) is a nonwoven, e.g. a nonwoven web, such as a carded nonwoven, spunbond nonwoven or meltblown nonwoven, and including nonwoven laminates of any of these.


The fibers may be of natural or man-made origin and may be staple or continuous filaments or be formed in situ. Commercially available fibers have diameters ranging typically from less than about 0.001 mm to more than about 0.2 mm and they come in several different forms: short fibers (known as staple, or chopped), continuous single fibers (filaments or monofilaments), untwisted bundles of continuous filaments (tow), and twisted bundles of continuous filaments (yarn). The fibers may be bicomponent fibers, for example having a sheet-core arrangement, e.g. with different polymers forming the sheet and the core. Nonwoven fabrics can be formed by many processes such as meltblowing, spunbonding, solvent spinning, electrospinning, and carding. The basis weight of nonwoven fabrics is usually expressed in grams per square meter (gsm).


The nonwoven herein may be made of hydrophilic fibers; “Hydrophilic” describes fibers or surfaces of fibers, which are wettable by aqueous fluids (e.g. aqueous body fluids) deposited on these fibers. Hydrophilicity and wettability are typically defined in terms of contact angle and the strike through time of the fluids, for example through a nonwoven fabric. This is discussed in detail in the American Chemical Society publication entitled “Contact angle, wettability and adhesion”, edited by Robert F. Gould (Copyright 1964). A fiber or surface of a fiber is said to be wetted by a fluid (i.e. hydrophilic) when either the contact angle between the fluid and the fiber, or its surface, is less than 90°, or when the fluid tends to spread spontaneously across the surface of the fiber, both conditions are normally co-existing. Conversely, a fiber or surface of the fiber is considered to be hydrophobic if the contact angle is greater than 90° and the fluid does not spread spontaneously across the surface of the fiber.


The supporting sheet (200) herein may be air-permeable. Films useful herein may therefore comprise micro pores. Nonwovens herein may for example be air permeable. The supporting sheet (200) may have for example an air-permeability of from 40 or from 50, to 300 or to 200 m3/(m2×min), as determined by EDANA method 140-1-99 (125 Pa, 38.3 cm2). The supporting sheet (200) may alternatively have a lower air-permeability, e.g. being non-air-permeable, to for example be better detained on a moving surface comprising vacuum.


In preferred executions, the supporting sheet (200) is a nonwoven laminate material, a nonwoven laminate web, for example of the SMS or SMMS type.


In order to form easily said undulations, the supporting sheet (200) may have a basis weight that is less than 60 gsm, or for example than 50 gsm, for example from 5 gsm to 40 gsm, or to 30 gsm.


The supporting sheet (200) may have a transverse-extensibility or a longitudinal-extensibility, for example of more the 20%, or for example more than 100%, but for example not more than 200%.


In one of the embodiment herein, the supporting sheet (200) has a transverse dimension that is more than the transverse dimension of the part of the receptacle (33), e.g. at least 10%, or for example at 20% or at least 30%, and for example up to about 120%.


Adhesive Application Units (50; 51) and Method Steps.


The supporting sheet (200) may comprise and adhesive prior to transfer to said second moving endless surface. Thus, the apparatus (1) herein may comprise a (second) adhesive application unit (51) upstream from said second moving endless surface, and for example downstream from said supporting material transfer means, e.g. roll. The method herein may thus comprise such an adhesive application step.


This adhesive may be applied uniformly and/or continuously, to aid absorbent material (100) immobilization and then it may help to adhere the supporting sheet (200) to a further material that may overlay the absorbent layer, as described below. Alternatively, it may be applied in a pattern. It may be applied by spraying, or for example by selectively slot-coating; the apparatus (1) may thus comprise a slot-coater, with a pattern.


The adhesive may be applied on those portions of the supporting sheet (200) that are to receive to receive the absorbent material; then, it helps to immobilize the absorbent material (100) thereon (e.g. to ensure the absorbent material (100) will stay substantially as applied, with said channels, optionally not only during manufacturing, but also during storage and in use (at least during part of the use). Or, alternatively, only on those portions of the supporting sheet (200) that are to be on said mating strips (31); then it may help to adhere the supporting sheet (200) to a further material that may overlay the absorbent layer, as described below. It may be applied as substantially longitudinal stripes, for example.


In some embodiments, the apparatus (1) may comprise a unit to apply an adhesive to said supporting sheet (200) in a pattern, for example the pattern of the mating strips (31), and optionally of the rods (36), if present.


Any suitable adhesive can be used for this, for example so-called hotmelt adhesives used. For example, a sprayable hot melt adhesives, such as H.B. Fuller Co. (St. Paul, Minn.) Product No. HL-1620-B, can be used.


Alternatively, or in addition, it may be beneficial to apply a further immobilization adhesive to said absorbent structure produced by the apparatus (1) or method herein, e.g. to ensure the absorbent material (100) will stay substantially as applied, with said channels, optionally not only during manufacturing, but also during storage and in use (at least during part of the use). This immobilization adhesive may then for example be applied onto said absorbent layer just after application of said absorbent material (100) onto said supporting sheet (200).


The apparatus (1) herein may thus have a further (first) adhesive application unit (50), e.g. downstream from said second moving endless surface' meeting point. The method may have a corresponding method step


This adhesive may be applied uniformly and/or homogeneously. This may be a thermoplastic adhesive material.


In accordance with certain embodiments, the thermoplastic adhesive material may comprise, in its entirety, a single thermoplastic polymer or a blend of thermoplastic polymers, having a softening point, as determined by the ASTM Method D-36-95 “Ring and Ball”, in the range between 50° C. and 300° C., or alternatively the thermoplastic adhesive material may be a hot melt adhesive comprising at least one thermoplastic polymer in combination with other thermoplastic diluents such as tackifying resins, plasticizers and additives such as antioxidants. In certain embodiments, the thermoplastic polymer has typically a molecular weight (Mw) of more than 10,000 and a glass transition temperature (Tg) usually below room temperature or −6° C.>Tg<16° C. In certain embodiments, typical concentrations of the polymer in a hot melt are in the range of about 20 to about 40% by weight. In certain embodiments, thermoplastic polymers may be water insensitive. Exemplary polymers are (styrenic) block copolymers including A-B-A triblock structures, A-B diblock structures and (A-B)n radial block copolymer structures wherein the A blocks are non-elastomeric polymer blocks, typically comprising polystyrene, and the B blocks are unsaturated conjugated diene or (partly) hydrogenated versions of such. The B block is typically isoprene, butadiene, ethylene/butylene (hydrogenated butadiene), ethylene/propylene (hydrogenated isoprene), and mixtures thereof. Other suitable thermoplastic polymers that may be employed are metallocene polyolefins, which are ethylene polymers prepared using single-site or metallocene catalysts. Therein, at least one comonomer can be polymerized with ethylene to make a copolymer, terpolymer or higher order polymer. Also applicable are amorphous polyolefins or amorphous polyalphaolefins (APAO) which are homopolymers, copolymers or terpolymers of C2 to C8 alpha olefins. In exemplary embodiments, the tackifying resin has typically a Mw below 5,000 and a Tg usually above room temperature, typical concentrations of the resin in a hot melt are in the range of about 30 to about 60%, and the plasticizer has a low Mw of typically less than 1,000 and a Tg below room temperature, with a typical concentration of about 0 to about 15%. In certain embodiments, the thermoplastic adhesive material is present in the form of fibers. In some embodiments, the fibers will have an average thickness of about 1 to about 50 micrometers or about 1 to about 35 micrometers and an average length of about 5 mm to about 50 mm or about 5 mm to about 30 mm.


Further Method Steps/Apparatus Units


The apparatus (1) and method herein may comprise the further step/unit, of applying a further supporting sheet (300) onto said absorbent structure, to enclose said absorbent material, as know in the art. This may be done such that a channel or each channel of a first absorbent structure corresponds with a channel of the second absorbent structure.


The apparatus (1) and method herein may alternatively or in addition comprise the apparatus (1) unit/method step of folding the supporting sheet (200) over the absorbent material (100) to enclose it thereby. It may comprise a sealing unit, sealing step to seal the two supporting sheet (200) or the folded supporting sheet (200) along the peripheral edges of the absorbent layer.


The absorbent structure may alternatively or in addition be combined with other layers, such as an acquisition layer, or topsheet and the apparatus (1) and method herein may comprise according steps/units.


The method or apparatus (1) herein may be to produce an absorbent core or structure that comprises two or more of the above described absorbent structures; for example two such layers, superposed on one another such that the absorbent material (100) of a first layer and the absorbent material (100) of the other second layer are adjacent one another and sandwiched between the supporting sheet (200) of the first layer and the supporting sheet (200; 300) of the second layer. The apparatus (1) herein may thus be a combination apparatus, comprising two or more, e.g. two, of the apparatuses described herein, to produce two or more, e.g. two, absorbent structures, and then comprising a combining unit to combine the absorbent structures. The method may comprise according method step(s).


The absorbent structure produced with the method/apparatus (1) of the invention herein may also be combined with an absorbent structure produced by a method/apparatus (1) other than of the present disclosure, said combination may be done as set out above.


The apparatus (1) may comprise a pressure means (70), such as a pressure roll, that can apply pressure onto the absorbent structure, and typically an absorbent structure wherein the absorbent material (100) is sandwiched between the supporting sheet (200) and a further material; the pressure may be applied onto said supporting sheet (200) or on any of the further material/layer that placed over the absorbent layer, as described above in this section. The method herein may then comprise a corresponding method step.


This pressure application may optionally be done to selectively apply pressure only onto the channels of the absorbent structure, e.g. on the portions of the supporting sheet (200) that correspond to the channels, and that thus not comprise (on the opposed surface) absorbent material, to avoid compaction of said absorbent material (100) itself.


Thus, the apparatus (1) may comprise a pressure means (70) that has a raised pressuring pattern (71) corresponding to said pattern of the raised strip(s) and/or of said mating strip(s), in some optionally corresponding to the pattern of the mating strip(s). The method may have an according method step.


Absorbent Articles


The apparatus (1) and method of the invention are for example useful to produce absorbent structures, or absorbent cores (i.e. said structures combined with a further material, described herein) suitable for absorbent articles.


Absorbent articles may include diapers, including fastenable diapers and (refastenable) training pants; adult incontinence undergarments (pads, diapers) feminine hygiene products (sanitary napkins, panty-liners), breast pads, care mats, bibs, wound dressing products, and the like. Ins some preferred embodiments, the absorbent article is a diaper, or adult incontinent product.


The absorbent article herein may comprise in addition to the absorbent structure or absorbent core, a topsheet and backsheet, and for example one or more side flaps or cuffs. The topsheet or cuffs or side flaps may comprise a skin care composition or lotion or powder, known in the art, panels, including those described in U.S. Pat. Nos. 5,607,760; 5,609,587; 5,635,191; 5,643,588.


Preferred absorbent articles herein comprise a topsheet, facing the wearer in use, for example a nonwoven sheet, and/or an apertured sheet, including apertured formed films, as known in the art, and a backsheet.


The backsheet may be liquid impervious, as known in the art. In preferred embodiments, the liquid impervious backsheet comprises a thin plastic film such as a thermoplastic film having a thickness of about 0.01 mm to about 0.05 mm. Suitable backsheet materials comprise typically breathable material, which permit vapors to escape from the diaper while still preventing exudates from passing through the backsheet. Suitable backsheet films include those manufactured by Tredegar Industries Inc. of Terre Haute, Ind. and sold under the trade names X15306, X10962 and X10964.


The backsheet, or any portion thereof, may be elastically extendable in one or more directions. The backsheet may be attached or joined to a topsheet, the absorbent structure or core described herein, or any other element of the diaper by any attachment means known in the art.


Diapers herein may comprise leg cuffs and/or barrier cuffs; the article then typically has a pair of opposing side flaps and/or leg and/or barrier cuffs, each of a pair being positioned adjacent one longitudinal side of the absorbent structure or core, and extending longitudinally along said structure or core, and typically being mirror images of one another in the longitudinal-axis of the article; if leg cuffs and barrier cuffs are present, then each leg cuffs is typically positioned outwardly from a barrier cuff. The cuffs may be extending longitudinally along at least 70% of the length of the article. The cuff(s) may have a free longitudinal edge that can be positioned out of the X-Y plane (longitudinal/transverse directions) of the article, i.e. in z-direction. The side flaps or cuffs of a pair may be mirror images of one another in the Y-axis (longitudinal axis) of the article. The cuffs may comprise elastic material.


The diapers herein may comprise a waistband, or for example a front waistband and back waist band, which may comprise elastic material.


The diaper may comprise side panels, or so-called ear panels. The diaper may comprise fastening means, to fasten the front and back, e.g. the front and back waistband. Preferred fastening systems comprise fastening tabs and landing zones, wherein the fastening tabs are attached or joined to the back region of the diaper and the landing zones are part of the front region of the diaper.


The absorbent article may also include a sub-layer disposed between the topsheet and the absorbent structure or core, capable of accepting, and distributing and/or immobilizing bodily exudates. Suitable sublayers include acquisition layers, surge layers and or fecal material storage layers, as known in the art. Suitable materials for use as the sub-layer may include large cell open foams, macro-porous compression resistant non woven highlofts, large size particulate forms of open and closed cell foams (macro and/or microporous), highloft non-wovens, polyolefin, polystyrene, polyurethane foams or particles, structures comprising a multiplicity of vertically oriented, optionally looped, strands of fibers, or optionally apertured formed films, as described above with respect to the genital coversheet. (As used herein, the term “microporous” refers to materials that are capable of transporting fluids by capillary action, but having a mean pore size of more than 50 microns. The term “macroporous” refers to materials having pores too large to effect capillary transport of fluid, generally having pores greater than about 0.5 mm (mean) in diameter and more specifically, having pores greater than about 1.0 mm (mean) in diameter, but typically less than 10 mm or even less than 6 mm (mean).


All patents and patent applications (including any patents which issue thereon) assigned to the Procter & Gamble Company referred to herein are hereby incorporated by reference to the extent that it is consistent herewith.


The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”


All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present disclosure. To the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.


While particular embodiments of the present disclosure have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims
  • 1. A method for making an absorbent structure for use in a disposable absorbent article, the method comprising the steps of: a) providing a rotating roll or drum comprising a reservoir and at least two raised strips that are mirror images of one another with respect to a longitudinal axis of the reservoir and wherein each of said raised strips is positioned on either side of said longitudinal axis, portions of the reservoir being air permeable and in air communication with a vacuum system, and wherein the at least two raised strips are not in air communication with said vacuum system, and wherein the at least two raised strips extend at least 50% of an average length of the reservoir;b) providing a supply of absorbent material;c) depositing a portion of the supply of absorbent material into the reservoir;d) removing absorbent material residing directly above the at least two raised strips;e) providing a second moving endless surface comprising an air permeable receptacle having a receiving area and at least two air impermeable mating strips for receiving a supporting sheet, ande) associating the portion of the supply of absorbent material with the supporting sheet, wherein the at least two raised strips overlap the at least two mating strips with the supporting sheet therebetween to define an absorbent structure comprising at least two channels therein corresponding to the at least two raised strips.
  • 2. The method of claim 1, wherein the at least two raised strips have an average width of at least 5 mm and less than 20 mm.
  • 3. The method of claim 1, wherein at least two raised strips are straight.
  • 4. The method of claim 1, wherein the at least two raised strips are curved.
  • 5. The method of claim 1, wherein the reservoir comprises a front region, a back region and a central region and wherein the at least two raised strips are present in the central region of the reservoir.
  • 6. The method of claim 5, wherein the at least two raised strips extend into either or both of said front region and said back region.
Priority Claims (1)
Number Date Country Kind
11169396 Jun 2011 EP regional
US Referenced Citations (980)
Number Name Date Kind
1733997 Marr Oct 1929 A
1734499 Marinsky Nov 1929 A
1989283 Limacher Jan 1935 A
2058509 Rose Oct 1936 A
2271676 Bjornbak Feb 1942 A
2450789 Frieman Oct 1948 A
2508811 Best et al. May 1950 A
2568910 Condylis Sep 1951 A
2570796 Gross Oct 1951 A
2570963 Mesmer Oct 1951 A
2583553 Faure Jan 1952 A
2668786 Swope Feb 1954 A
2705957 Mauro Apr 1955 A
2714340 Brown Aug 1955 A
2788003 Van Norden Apr 1957 A
2788786 Dexter Apr 1957 A
2798489 Behrman Jul 1957 A
2807263 Newton Sep 1957 A
2830589 Doner Apr 1958 A
2890700 Lönberg-Holm Jun 1959 A
2890701 Weinman Jun 1959 A
2898912 Adams Aug 1959 A
2931361 Sostsrin Apr 1960 A
2977957 Clyne Apr 1961 A
3034180 Greiner May 1962 A
3071138 Gustavo Jan 1963 A
3150416 Such Sep 1964 A
3180335 Duncan et al. Apr 1965 A
3190791 Potter Jun 1965 A
3207158 Yoshitake et al. Sep 1965 A
3386442 Sabee Jun 1968 A
3561446 Jones Feb 1971 A
3572342 Lindquist et al. Mar 1971 A
3572432 Burton Mar 1971 A
3575174 Mogor Apr 1971 A
3578155 Small et al. May 1971 A
3606887 Roeder Sep 1971 A
3610244 Jones Oct 1971 A
3618608 Brink Nov 1971 A
3642001 Sabee Feb 1972 A
3653381 Warnken Apr 1972 A
3670731 Harmon Jun 1972 A
3688767 Goldstein Sep 1972 A
3710797 Marsan Jan 1973 A
3720578 Heiling Mar 1973 A
3731688 Litt et al. May 1973 A
3756878 Willot Sep 1973 A
3774241 Zerkle Nov 1973 A
3776233 Schaar Dec 1973 A
3814100 Nystrand et al. Jun 1974 A
3828784 Sabee Oct 1974 A
3840418 Sabee Oct 1974 A
3847702 Jones Nov 1974 A
3848594 Buell Nov 1974 A
3848595 Endres Nov 1974 A
3848597 Endres Nov 1974 A
3860003 Buell Jan 1975 A
3863637 MacDonald et al. Feb 1975 A
3882870 Hathaway May 1975 A
3884234 Taylor May 1975 A
3900032 Heurlen Aug 1975 A
3911173 Sprague, Jr. Oct 1975 A
3920017 Karami Nov 1975 A
3924626 Lee et al. Dec 1975 A
3926189 Taylor Dec 1975 A
3929134 Karami Dec 1975 A
3929135 Thompson Dec 1975 A
3930501 Schaar Jan 1976 A
3938523 Gilliland et al. Feb 1976 A
3968799 Schrading Jul 1976 A
3978861 Schaar Sep 1976 A
3981306 Krusko Sep 1976 A
3987794 Schaar Oct 1976 A
3995637 Schaar Dec 1976 A
3995640 Schaar Dec 1976 A
3999547 Hernandez Dec 1976 A
4014338 Schaar Mar 1977 A
4034760 Amirsakis Jul 1977 A
4055180 Karami Oct 1977 A
4074508 Reid Feb 1978 A
4084592 Tritsch Apr 1978 A
4100922 Hernandez Jul 1978 A
4232674 Melican Nov 1980 A
4257418 Hessner Mar 1981 A
4259220 Bunnelle et al. Mar 1981 A
4296750 Woon et al. Oct 1981 A
4315508 Bolick Feb 1982 A
4324246 Mullane et al. Apr 1982 A
4340706 Obayashi et al. Jul 1982 A
4341216 Obenour Jul 1982 A
4342314 Radel et al. Aug 1982 A
4381783 Elias May 1983 A
4388075 Mesek et al. Jun 1983 A
4461621 Karami et al. Jul 1984 A
4463045 Ahr et al. Jul 1984 A
4469710 Rielley et al. Sep 1984 A
4475912 Coates Oct 1984 A
4490148 Beckeström Dec 1984 A
4507438 Obayashi et al. Mar 1985 A
4515595 Kievet et al. May 1985 A
4527990 Sigl Jul 1985 A
4541871 Obayashi et al. Sep 1985 A
4573986 Minetola et al. Mar 1986 A
4578072 Lancaster Mar 1986 A
4585448 Enloe Apr 1986 A
4585450 Rosch et al. Apr 1986 A
4589878 Mitrani May 1986 A
4596568 Flug Jun 1986 A
4601717 Blevins Jul 1986 A
4606964 Wideman Aug 1986 A
4609518 Curro et al. Sep 1986 A
4610678 Weisman et al. Sep 1986 A
4623342 Ito et al. Nov 1986 A
4624666 Derossett Nov 1986 A
4629643 Curro et al. Dec 1986 A
4636207 Buell Jan 1987 A
4641381 Heran et al. Feb 1987 A
4662875 Hirotsu et al. May 1987 A
4666983 Tsubakimoto et al. May 1987 A
4670011 Mesek Jun 1987 A
4670012 Johnson Jun 1987 A
4680030 Coates et al. Jul 1987 A
4681579 Toussant et al. Jul 1987 A
4681581 Coates Jul 1987 A
4681793 Linman et al. Jul 1987 A
4690680 Higgins Sep 1987 A
4695278 Lawson Sep 1987 A
4699622 Toussant et al. Oct 1987 A
4704115 Buell Nov 1987 A
4704116 Enloe Nov 1987 A
4710189 Lash Dec 1987 A
4731066 Korpman Mar 1988 A
4731070 Koci Mar 1988 A
RE32649 Brandt et al. Apr 1988 E
4747846 Boland et al. May 1988 A
4773905 Molee Sep 1988 A
4784892 Storey et al. Nov 1988 A
4785996 Ziecker et al. Nov 1988 A
4787896 Houghton et al. Nov 1988 A
4795454 Dragoo Jan 1989 A
4802884 Fröidh et al. Feb 1989 A
4808176 Kielpikowski Feb 1989 A
4808178 Aziz Feb 1989 A
4834735 Alemany et al. May 1989 A
4834740 Suzuki et al. May 1989 A
4834742 Wilson et al. May 1989 A
4838886 Kent Jun 1989 A
4842666 Werenicz Jun 1989 A
4846815 Scripps Jul 1989 A
4846825 Enloe et al. Jul 1989 A
4861652 Lippert et al. Aug 1989 A
4869724 Scripps Sep 1989 A
4886697 Perdelwitz, Jr. et al. Dec 1989 A
4888231 Angstadt Dec 1989 A
4892528 Suzuki et al. Jan 1990 A
4892535 Bjornberg Jan 1990 A
4892536 DesMarais et al. Jan 1990 A
4894060 Nestegard Jan 1990 A
4894277 Akasaki Jan 1990 A
4904251 Igaue et al. Feb 1990 A
4900317 Buell Mar 1990 A
4909802 Ahr et al. Mar 1990 A
4909803 Aziz et al. Mar 1990 A
4936839 Molee Jun 1990 A
4940463 Leathers et al. Jul 1990 A
4940464 Van Gompel et al. Jul 1990 A
4946527 Battrell Aug 1990 A
4950264 Osborn Aug 1990 A
4960477 Mesek Oct 1990 A
4963140 Robertson et al. Oct 1990 A
4968313 Sabee Nov 1990 A
4990147 Freeland Feb 1991 A
4994053 Lang Feb 1991 A
5006394 Baird Apr 1991 A
5019063 Marsan et al. May 1991 A
5019072 Polski May 1991 A
5021051 Hiuke Jun 1991 A
5030314 Lang Jul 1991 A
5032120 Freeland et al. Jul 1991 A
5034008 Breitkopf Jul 1991 A
5037416 Allen et al. Aug 1991 A
5071414 Elliott Aug 1991 A
5072687 Mitchell Dec 1991 A
5085654 Buell Feb 1992 A
5087255 Sims et al. Feb 1992 A
5092861 Nomura et al. Mar 1992 A
5102597 Roe et al. Apr 1992 A
5114420 Igaue et al. May 1992 A
5124188 Roe et al. Jun 1992 A
5135522 Fahrenkrug et al. Aug 1992 A
5137537 Herron et al. Aug 1992 A
D329697 Fahrenkrug et al. Sep 1992 S
5143679 Weber et al. Sep 1992 A
5147343 Kellenberger Sep 1992 A
5147345 Young et al. Sep 1992 A
5149334 Roe et al. Sep 1992 A
5149335 Kellenberger et al. Sep 1992 A
5151091 Glaug Sep 1992 A
5151092 Buell et al. Sep 1992 A
5156793 Buell et al. Oct 1992 A
5167653 Igaue et al. Dec 1992 A
5167897 Weber et al. Dec 1992 A
5175046 Nguyen Dec 1992 A
5180622 Berg et al. Jan 1993 A
5190563 Herron et al. Mar 1993 A
5190606 Merkatoris et al. Mar 1993 A
5204997 Suzuki et al. Apr 1993 A
5221274 Buell et al. Jun 1993 A
5235515 Ungpiyakul et al. Aug 1993 A
5242436 Weil et al. Sep 1993 A
5246431 Minetola et al. Sep 1993 A
5246432 Suzuki et al. Sep 1993 A
5246433 Hasse et al. Sep 1993 A
5248309 Serbiak et al. Sep 1993 A
5260345 Desmarais et al. Nov 1993 A
5269775 Freeland et al. Dec 1993 A
5281683 Yano et al. Jan 1994 A
H1298 Ahr Apr 1994 H
5300053 Genaro Apr 1994 A
5300565 Berg et al. Apr 1994 A
5312386 Correa et al. May 1994 A
5331059 Engelhardt et al. Jul 1994 A
5336552 Strack et al. Aug 1994 A
5348547 Payne et al. Sep 1994 A
5358500 LaVon et al. Oct 1994 A
5366782 Curro et al. Nov 1994 A
5387207 Dyer et al. Feb 1995 A
5387209 Yamamoto et al. Feb 1995 A
5389095 Suzuki Feb 1995 A
5397316 Lavon et al. Mar 1995 A
5399175 Glaug Mar 1995 A
5401792 Babu et al. Mar 1995 A
5409771 Dahmen et al. Apr 1995 A
H1440 New et al. May 1995 H
5411497 Tanzer et al. May 1995 A
5415644 Enloe May 1995 A
5425725 Tanzer et al. Jun 1995 A
5429630 Beal Jul 1995 A
5433715 Tanzer et al. Jul 1995 A
5451219 Suzuki Sep 1995 A
5451442 Pieniak Sep 1995 A
5460622 Dragoo et al. Oct 1995 A
5462541 Bruemmer et al. Oct 1995 A
5476458 Glaug et al. Dec 1995 A
5486166 Bishop et al. Jan 1996 A
5490846 Ellis et al. Feb 1996 A
5492962 Lahrman et al. Feb 1996 A
5494622 Heath et al. Feb 1996 A
5499978 Buell et al. Mar 1996 A
5507736 Clear et al. Apr 1996 A
5507895 Suekane Apr 1996 A
5509915 Hanson et al. Apr 1996 A
5514104 Cole May 1996 A
5518801 Chappell et al. May 1996 A
5520674 Hines et al. May 1996 A
5522810 Allen, Jr. Jun 1996 A
5527300 Sauer Jun 1996 A
5531730 Dreier Jul 1996 A
5532323 Yano et al. Jul 1996 A
5542943 Sageser Aug 1996 A
5549592 Fries et al. Aug 1996 A
5549593 Ygge et al. Aug 1996 A
5549791 Herron et al. Aug 1996 A
5554145 Roe et al. Sep 1996 A
5560878 Dragoo et al. Oct 1996 A
5562646 Goldman et al. Oct 1996 A
5569234 Buell et al. Oct 1996 A
5571096 Dobrin et al. Nov 1996 A
5574121 Irie et al. Nov 1996 A
5580411 Nease et al. Dec 1996 A
5584829 Lavash et al. Dec 1996 A
5591152 Buell et al. Jan 1997 A
5591155 Nishikawa et al. Jan 1997 A
5593399 Tanzer et al. Jan 1997 A
5599335 Goldman et al. Feb 1997 A
5601542 Melius et al. Feb 1997 A
5607414 Richards et al. Mar 1997 A
5607537 Johnson et al. Mar 1997 A
5607760 Roe et al. Mar 1997 A
5609587 Roe Mar 1997 A
5609588 DiPalma et al. Mar 1997 A
5611879 Morman Mar 1997 A
5613959 Roessler et al. Mar 1997 A
5613960 Mizutani Mar 1997 A
5614283 Potnis et al. Mar 1997 A
5622589 Johnson et al. Apr 1997 A
5624423 Anjur Apr 1997 A
5624424 Saisaka et al. Apr 1997 A
5607416 Yamamoto et al. May 1997 A
5626571 Young et al. May 1997 A
5628741 Buell et al. May 1997 A
5635191 Roe et al. Jun 1997 A
5635271 Zafiroglu Jun 1997 A
5637106 Mitchell Jun 1997 A
5643238 Baker Jul 1997 A
5643243 Klemp Jul 1997 A
5643588 Roe et al. Jul 1997 A
5649914 Glaug Jul 1997 A
5650214 Anderson Jul 1997 A
H1674 Ames et al. Aug 1997 H
5658268 Johns et al. Aug 1997 A
5662634 Yamamoto et al. Sep 1997 A
5662638 Johnson et al. Sep 1997 A
5674215 Ronnberg Oct 1997 A
5683374 Yamamoto Nov 1997 A
5685874 Buell et al. Nov 1997 A
5690627 Clear et al. Nov 1997 A
5691035 Chappell et al. Nov 1997 A
5691036 Chappell et al. Nov 1997 A
5695488 Sosalla Dec 1997 A
5700254 McDowall et al. Dec 1997 A
5702376 Glaug Dec 1997 A
5714156 Schmidt et al. Feb 1998 A
5723087 Chappell et al. Mar 1998 A
5733275 Davis et al. Mar 1998 A
5749866 Roe et al. May 1998 A
5752947 Awolin May 1998 A
5756039 Mcfall et al. May 1998 A
H1732 Johnson Jun 1998 H
5762641 Bewick Sonntag et al. Jun 1998 A
5766388 Pelley Jun 1998 A
5766389 Brandon et al. Jun 1998 A
5772825 Schmitz Jun 1998 A
5776121 Roe et al. Jul 1998 A
5779831 Schmitz Jul 1998 A
5788684 Abuto et al. Aug 1998 A
5795345 Mizutani Aug 1998 A
5797892 Glaug Aug 1998 A
5797894 Cadieux et al. Aug 1998 A
5807365 Luceri Sep 1998 A
5810796 Kimura et al. Sep 1998 A
5810800 Hunter et al. Sep 1998 A
5814035 Gryskiewicz et al. Sep 1998 A
5820618 Roberts et al. Oct 1998 A
5827257 Fujioka Oct 1998 A
5830202 Bogdanski et al. Nov 1998 A
5833678 Ashton et al. Nov 1998 A
5837789 Stockhausen et al. Nov 1998 A
5843059 Niemeyer et al. Dec 1998 A
5846231 Fujioka et al. Dec 1998 A
5846232 Serbiak et al. Dec 1998 A
5849816 Suskind et al. Dec 1998 A
5851204 Mitzutani Dec 1998 A
5855572 Schmidt Jan 1999 A
5858013 Kling Jan 1999 A
5865823 Curro Feb 1999 A
5865824 Chen Feb 1999 A
5873868 Nakahata Feb 1999 A
5876391 Roe et al. Mar 1999 A
5891118 Toyoshima Apr 1999 A
5891544 Chappell et al. Apr 1999 A
5897545 Kline et al. Apr 1999 A
5904673 Roe et al. May 1999 A
5928184 Etheredge Jul 1999 A
5931825 Kuen et al. Aug 1999 A
5938648 Lavon et al. Aug 1999 A
5938650 Baer et al. Aug 1999 A
5941862 Haynes et al. Aug 1999 A
5944706 Palumbo et al. Aug 1999 A
5947949 Inoue et al. Sep 1999 A
5951536 Osborn, III et al. Sep 1999 A
5957908 Kline et al. Sep 1999 A
5968025 Roe et al. Oct 1999 A
5968029 Chappell et al. Oct 1999 A
5980500 Shimizu et al. Nov 1999 A
5981824 Luceri Nov 1999 A
5989236 Roe et al. Nov 1999 A
6004306 Robles et al. Dec 1999 A
6022430 Blenke et al. Feb 2000 A
6022431 Blenke et al. Feb 2000 A
6042673 Johnson et al. Mar 2000 A
6050984 Fujioka Apr 2000 A
6054631 Gent Apr 2000 A
6060115 Borowski et al. May 2000 A
6068620 Chmielewski May 2000 A
6080909 Osterdahl et al. Jun 2000 A
6083210 Young et al. Jul 2000 A
6090994 Chen Jul 2000 A
6091336 Zand Jul 2000 A
6099515 Sugito Aug 2000 A
6102892 Putzer et al. Aug 2000 A
6103814 Van Drongelen et al. Aug 2000 A
6107537 Elder et al. Aug 2000 A
6110157 Schmidt Aug 2000 A
6117121 Faulks et al. Sep 2000 A
6117803 Morman et al. Sep 2000 A
6120486 Toyoda et al. Sep 2000 A
6120487 Ashton Sep 2000 A
6120489 Johnson et al. Sep 2000 A
6120866 Arakawa et al. Sep 2000 A
6121509 Ashraf et al. Sep 2000 A
6129717 Fujioka et al. Oct 2000 A
6129720 Blenke et al. Oct 2000 A
6132411 Huber et al. Oct 2000 A
6139912 Onuschak Oct 2000 A
6143821 Houben Nov 2000 A
6152908 Widlund Nov 2000 A
6156023 Yoshioka Dec 2000 A
6156424 Taylor Dec 2000 A
6160197 Lassen Dec 2000 A
6165160 Suzuki et al. Dec 2000 A
6174302 Kumasaka Jan 2001 B1
6177606 Etheredge Jan 2001 B1
6177607 Blaney et al. Jan 2001 B1
6186996 Martin Feb 2001 B1
6210386 Inoue Apr 2001 B1
6210390 Karlsson Apr 2001 B1
6231556 Osborn, III May 2001 B1
6231566 Lai May 2001 B1
6238380 Sasaki May 2001 B1
6241716 Rönnberg Jun 2001 B1
6258996 Goldman Jul 2001 B1
6265488 Fujino et al. Jul 2001 B1
6306122 Narawa et al. Oct 2001 B1
6315765 Datta Nov 2001 B1
6322552 Blenke et al. Nov 2001 B1
6325787 Roe et al. Dec 2001 B1
6326525 Hamajima Dec 2001 B1
6334858 Rönnberg et al. Jan 2002 B1
6336922 Van Gompel et al. Jan 2002 B1
6340611 Shimizu Jan 2002 B1
6342715 Shimizu Jan 2002 B1
6402731 Suprise et al. Jan 2002 B1
6350332 Thomas et al. Feb 2002 B1
6368687 Joseph et al. Apr 2002 B1
6371948 Mizutani Apr 2002 B1
6372952 Lash et al. Apr 2002 B1
6375644 Mizutani Apr 2002 B2
6376034 Brander Apr 2002 B1
6383431 Dobrin et al. May 2002 B1
6383960 Everett et al. May 2002 B1
6394989 Mizutani May 2002 B2
6403857 Gross et al. Jun 2002 B1
6409883 Makolin Jun 2002 B1
6410820 McFall et al. Jun 2002 B1
6410822 Mizutani Jun 2002 B1
6402729 Boberg et al. Jul 2002 B1
6413248 Mizutani Jul 2002 B1
6413249 Turi et al. Jul 2002 B1
6414214 Engelhardt et al. Jul 2002 B1
6419667 Avalon et al. Jul 2002 B1
6423046 Fujioka et al. Jul 2002 B1
6423048 Suzuki et al. Jul 2002 B1
6423884 Oehmen Jul 2002 B1
6429350 Tanzer et al. Aug 2002 B1
6432094 Fujioka et al. Aug 2002 B1
6432098 Kline et al. Aug 2002 B1
6432099 Rönnberg Aug 2002 B2
6437214 Everett et al. Aug 2002 B1
6441268 Edwardsson Aug 2002 B1
6443933 Suzuki et al. Sep 2002 B1
6444064 Henry et al. Sep 2002 B1
6447496 Mizutani Sep 2002 B1
6458111 Onishi et al. Oct 2002 B1
6458877 Ahmed et al. Oct 2002 B1
6459016 Rosenfeld et al. Oct 2002 B1
6461034 Schaefer et al. Oct 2002 B1
6461342 Tanji et al. Oct 2002 B2
6472478 Funk et al. Oct 2002 B1
6475201 Saito et al. Nov 2002 B2
6494872 Suzuki et al. Dec 2002 B1
6494873 Karlsson et al. Dec 2002 B2
6500159 Carvalho Dec 2002 B1
6503233 Chen Jan 2003 B1
6503979 Funk et al. Jan 2003 B1
6506186 Roessler Jan 2003 B1
6506961 Levy Jan 2003 B1
6515195 Lariviere Feb 2003 B1
6517525 Berthou Feb 2003 B1
6518479 Graef Feb 2003 B1
6520947 Tilly et al. Feb 2003 B1
6521811 Lassen Feb 2003 B1
6521812 Graef Feb 2003 B1
6524294 Hilston et al. Feb 2003 B1
6525240 Graef Feb 2003 B1
6528698 Mizutani et al. Mar 2003 B2
6531025 Lender et al. Mar 2003 B1
6531027 Lender et al. Mar 2003 B1
6534149 Daley et al. Mar 2003 B1
6559081 Erspamer May 2003 B1
6559239 Riegel et al. May 2003 B1
6562168 Schmitt et al. May 2003 B1
6562192 Hamilton May 2003 B1
6569137 Suzuki et al. May 2003 B2
6573422 Rosenfeld Jun 2003 B1
6585713 LaMahieu et al. Jul 2003 B1
6585858 Otto et al. Jul 2003 B1
6602234 Klemp et al. Aug 2003 B2
6605070 Ludwig et al. Aug 2003 B2
6605172 Anderson et al. Aug 2003 B1
6605752 Magnusson et al. Aug 2003 B2
6610900 Tanzer Aug 2003 B1
6630054 Graef Oct 2003 B1
6632209 Chmielewski Oct 2003 B1
6632504 Gillespie et al. Oct 2003 B1
6645569 Cramer et al. Nov 2003 B2
6646180 Chmielewski Nov 2003 B1
6648869 Gillies et al. Nov 2003 B1
6648870 Itoh et al. Nov 2003 B2
6648871 Kusibojoska et al. Nov 2003 B2
6649807 Mizutani Nov 2003 B2
6649810 Minato et al. Nov 2003 B1
6657015 Riegel et al. Dec 2003 B1
6657102 Furuya Dec 2003 B2
6667424 Hamilton Dec 2003 B1
6670522 Graef Dec 2003 B1
6673982 Chen Jan 2004 B1
6673983 Graef Jan 2004 B1
6673985 Mizutani Jan 2004 B2
6682515 Mizutani et al. Jan 2004 B1
6682516 Johnston Jan 2004 B2
6689115 Popp et al. Feb 2004 B1
6689934 Dodge, II et al. Feb 2004 B2
6695827 Chen Feb 2004 B2
6700034 Lindsay et al. Mar 2004 B1
6703538 Lassen Mar 2004 B2
6705465 Ling et al. Mar 2004 B2
6706943 Onishi Mar 2004 B2
6710224 Chmielewski et al. Mar 2004 B2
6710225 Everett et al. Mar 2004 B1
6716205 Popp et al. Apr 2004 B2
6716441 Roe et al. Apr 2004 B1
6717029 Baker Apr 2004 B2
6726668 Underhill et al. Apr 2004 B2
6726792 Johnson et al. Apr 2004 B1
6734335 Graef May 2004 B1
6790798 Suzuki et al. Sep 2004 B1
6809158 Ikeuchi et al. Oct 2004 B2
6818083 Mcamish et al. Nov 2004 B2
6830800 Curro et al. Dec 2004 B2
6840929 Kurata Jan 2005 B2
6846374 Popp Jan 2005 B2
6858771 Yoshimasa Feb 2005 B2
6863933 Cramer et al. Mar 2005 B2
6863960 Curro et al. Mar 2005 B2
6867345 Shimoe et al. Mar 2005 B2
6867346 Dopps Mar 2005 B1
6878433 Curro et al. Apr 2005 B2
6880211 Jackson et al. Apr 2005 B2
6891080 Minato May 2005 B2
6904865 Klofta Jun 2005 B2
6911574 Mizutani Jun 2005 B1
6923797 Shinohara et al. Aug 2005 B2
6926703 Sugito Aug 2005 B2
6929629 Drevik et al. Aug 2005 B2
6939914 Qin et al. Sep 2005 B2
6946585 Brown Sep 2005 B2
6953451 Berba Oct 2005 B2
6955733 Henry et al. Oct 2005 B2
6962578 Lavon Nov 2005 B1
6962645 Graef Nov 2005 B2
6965058 Raidel Nov 2005 B1
6969781 Graef Nov 2005 B2
6972010 Pesce et al. Dec 2005 B2
6972011 Maeda et al. Dec 2005 B2
7001167 Venturino Feb 2006 B2
7014632 Takino et al. Mar 2006 B2
7015370 Watanabe Mar 2006 B2
7037299 Turi et al. May 2006 B2
7037571 Fish et al. May 2006 B2
7048726 Kusagawa et al. May 2006 B2
7056311 Kinoshita Jun 2006 B2
7067711 Kinoshita et al. Jun 2006 B2
7073373 La Fortune Jul 2006 B2
7078583 Kudo Jul 2006 B2
7090665 Ohashi Aug 2006 B2
7108759 You Sep 2006 B2
7108916 Ehrnsperger et al. Sep 2006 B2
7112621 Rohrbaugh et al. Sep 2006 B2
7122713 Komatsu Oct 2006 B2
7125470 Graef Oct 2006 B2
7132585 Kudo Nov 2006 B2
7147628 Drevik Dec 2006 B2
7150729 Shimada Dec 2006 B2
7154019 Mishima et al. Dec 2006 B2
7160281 Leminh et al. Jan 2007 B2
7166190 Graef Jan 2007 B2
7169136 Otsubo Jan 2007 B2
7183360 Daniel et al. Feb 2007 B2
7189888 Wang et al. Mar 2007 B2
7196241 Kinoshita Mar 2007 B2
7199211 Popp et al. Apr 2007 B2
7204830 Mishima Apr 2007 B2
7207978 Takino Apr 2007 B2
7219403 Miyamoto et al. May 2007 B2
7220251 Otsubo et al. May 2007 B2
7250481 Jaworek et al. Jul 2007 B2
7252657 Mishima Aug 2007 B2
7265258 Hamilton Sep 2007 B2
RE39919 Dodge, II et al. Nov 2007 E
7311968 Ehrnsperger et al. Dec 2007 B2
7312372 Miyama Dec 2007 B2
7318820 LaVon et al. Jan 2008 B2
7329244 Otsubo Feb 2008 B2
7329246 Kinoshita Feb 2008 B2
7335810 Yoshimasa et al. Feb 2008 B2
7377914 LaVon May 2008 B2
7429689 Chen Sep 2008 B2
7435244 Schroer et al. Oct 2008 B2
7465373 Graef Dec 2008 B2
7500969 Mishima Mar 2009 B2
7504552 Tamura Mar 2009 B2
7521109 Suzuki et al. Apr 2009 B2
7521587 Busam et al. Apr 2009 B2
7524449 Walsh et al. Apr 2009 B2
7537832 Carlucci et al. May 2009 B2
7547815 Ohashi Jun 2009 B2
7550646 Tamura Jun 2009 B2
7563257 Nakajima Jul 2009 B2
7588561 Kenmochi Sep 2009 B2
7594904 Rosenfeld Sep 2009 B2
7625363 Yoshimasa Dec 2009 B2
7641642 Murai et al. Jan 2010 B2
7648490 Kuroda Jan 2010 B2
7652111 Hermeling et al. Jan 2010 B2
7666173 Mishima Feb 2010 B2
7666174 Kawakami et al. Feb 2010 B2
7686790 Rasmussen et al. Mar 2010 B2
7687596 Hermeling et al. Mar 2010 B2
7695461 Rosenfeld Apr 2010 B2
7696402 Nishikawa Apr 2010 B2
7708725 Tamagawa May 2010 B2
7717150 Manabe May 2010 B2
7722587 Suzuki et al. May 2010 B2
7722590 Tsuji May 2010 B2
7727217 Hancock-Cooke Jun 2010 B2
7736351 Nigam Jun 2010 B2
7744576 Busam et al. Jun 2010 B2
7744578 Tanio et al. Jun 2010 B2
7750203 Busam et al. Jul 2010 B2
7754822 Daniel et al. Jul 2010 B2
7754940 Brisebois Jul 2010 B2
7759540 Litvay et al. Jul 2010 B2
7763004 Beck Jul 2010 B2
7767875 Olson Aug 2010 B2
7767878 Suzuki Aug 2010 B2
7772420 Hermeling et al. Aug 2010 B2
7786341 Schneider et al. Aug 2010 B2
7795492 Vartiainen Sep 2010 B2
7803145 Rosenfeld Sep 2010 B2
7825291 Elfsberg et al. Nov 2010 B2
7850672 Guidotti et al. Dec 2010 B2
7851667 Becker et al. Dec 2010 B2
7855314 Hanao Dec 2010 B2
7857797 Kudo Dec 2010 B2
7858842 Komatsu Dec 2010 B2
7884259 Hanao Feb 2011 B2
7888549 Jansson et al. Feb 2011 B2
7910797 Nandrea Mar 2011 B2
7935207 Zhao May 2011 B2
7935861 Suzuki May 2011 B2
7938813 Wang et al. May 2011 B2
7942858 Francoeur May 2011 B2
7951126 Nanjyo May 2011 B2
7982091 Konawa Jul 2011 B2
7993319 Sperl Aug 2011 B2
8007639 Gelli Aug 2011 B2
8017827 Hundorf et al. Sep 2011 B2
8029486 Nakajima Oct 2011 B2
8034991 Bruzadin et al. Oct 2011 B2
8039684 Guidotti et al. Oct 2011 B2
8052454 Polnyi Nov 2011 B2
8057620 Perego et al. Nov 2011 B2
8109915 Shimoe Feb 2012 B2
8133212 Takada Mar 2012 B2
8148598 Tsang et al. Apr 2012 B2
8163124 Moriura et al. Apr 2012 B2
8173858 Kuroda May 2012 B2
8178747 Venturino et al. May 2012 B2
8183430 Hakansson et al. May 2012 B2
8186296 Brown et al. May 2012 B2
8187240 Busam et al. May 2012 B2
8198506 Venturino et al. Jun 2012 B2
8211815 Baker Jul 2012 B2
8236715 Schmidt et al. Aug 2012 B2
8237012 Miyama Aug 2012 B2
8246594 Sperl Aug 2012 B2
8258367 Lawson et al. Sep 2012 B2
8268424 Suzuki Sep 2012 B1
8273943 Noda Sep 2012 B2
8283516 Litvay Oct 2012 B2
8317766 Naoto Nov 2012 B2
8317768 Larsson Nov 2012 B2
8319005 Becker et al. Nov 2012 B2
8343123 Noda Jan 2013 B2
8343296 Blessing et al. Jan 2013 B2
8361047 Mukai Jan 2013 B2
8377025 Nakajima Feb 2013 B2
8450555 Nahn et al. May 2013 B2
8496637 Hundorf et al. Jul 2013 B2
8519213 Venturino et al. Aug 2013 B2
8524355 Nakaoka Sep 2013 B2
8552252 Hundorf et al. Oct 2013 B2
8568566 Jackels Oct 2013 B2
8581019 Carlucci et al. Nov 2013 B2
8603058 Sprerl et al. Dec 2013 B2
8604270 Venturino et al. Dec 2013 B2
8633347 Bianco et al. Jan 2014 B2
8674170 Busam et al. Mar 2014 B2
8766031 Becker et al. Jul 2014 B2
8772570 Kawakami et al. Jul 2014 B2
8785715 Wright et al. Jul 2014 B2
8791318 Becker et al. Jul 2014 B2
9492328 Jackels et al. Nov 2016 B2
20010007065 Blanchard Jul 2001 A1
20010008964 Kurata et al. Jul 2001 A1
20010016548 Kugler et al. Aug 2001 A1
20010020157 Mizutani Sep 2001 A1
20010037101 Allan et al. Nov 2001 A1
20010044610 Kim Nov 2001 A1
20020007167 Dan Jan 2002 A1
20020007169 Graef et al. Jan 2002 A1
20020016122 Curro et al. Feb 2002 A1
20020016579 Stenberg Feb 2002 A1
20020045881 Kusibojoska et al. Apr 2002 A1
20020056516 Ochi May 2002 A1
20020062112 Mizutani May 2002 A1
20020062116 Mizutani et al. May 2002 A1
20020065498 Ohashi May 2002 A1
20020072471 Ikeuchi et al. Jun 2002 A1
20020082575 Dan Jun 2002 A1
20020087139 Popp et al. Jul 2002 A1
20020102392 Fish et al. Aug 2002 A1
20020115969 Maeda et al. Aug 2002 A1
20020123728 Graef et al. Sep 2002 A1
20020151634 Rohrbaugh et al. Oct 2002 A1
20020151861 Klemp et al. Oct 2002 A1
20020173767 Popp et al. Nov 2002 A1
20020192366 Cramer et al. Dec 2002 A1
20030036741 Abba et al. Feb 2003 A1
20030078553 Wada Apr 2003 A1
20030084983 Rangachari et al. May 2003 A1
20030088223 Vogt et al. May 2003 A1
20030105190 Diehl et al. Jun 2003 A1
20030114816 Underhill Jun 2003 A1
20030114818 Benecke et al. Jun 2003 A1
20030120235 Boulanger Jun 2003 A1
20030135181 Chen et al. Jul 2003 A1
20030135182 Woon et al. Jul 2003 A1
20030139712 Dodge Jul 2003 A1
20030139715 Dodge Jul 2003 A1
20030139718 Graef Jul 2003 A1
20030144642 Dopps Jul 2003 A1
20030144644 Murai et al. Jul 2003 A1
20030148684 Cramer et al. Aug 2003 A1
20030148694 Ghiam Aug 2003 A1
20030167045 Graef Sep 2003 A1
20030171727 Graef Sep 2003 A1
20030208175 Gross Nov 2003 A1
20030225385 Glaug Dec 2003 A1
20030233082 Kline et al. Dec 2003 A1
20030236512 Baker Dec 2003 A1
20040019338 Litvay et al. Jan 2004 A1
20040022998 Miyamoto et al. Feb 2004 A1
20040033750 Everett Feb 2004 A1
20040063367 Dodge Apr 2004 A1
20040064115 Arora Apr 2004 A1
20040064116 Arora Apr 2004 A1
20040064125 Justmann et al. Apr 2004 A1
20040065420 Graef Apr 2004 A1
20040082928 Pesce et al. Apr 2004 A1
20040097895 Busam et al. May 2004 A1
20040122411 Hancock-Cooke Jun 2004 A1
20040127871 Odorzynski Jul 2004 A1
20040127872 Petryk Jul 2004 A1
20040134596 Rosati et al. Jul 2004 A1
20040138633 Mishima et al. Jul 2004 A1
20040147890 Nakahata et al. Jul 2004 A1
20040158212 Ponomarenko et al. Aug 2004 A1
20040162536 Becker et al. Aug 2004 A1
20040167486 Busam et al. Aug 2004 A1
20040167489 Kellenberger et al. Aug 2004 A1
20040193127 Hansson Sep 2004 A1
20040215160 Chmielewski Oct 2004 A1
20040220541 Suzuki et al. Nov 2004 A1
20040225271 Dana et al. Nov 2004 A1
20040231065 Daniel et al. Nov 2004 A1
20040236299 Tsang et al. Nov 2004 A1
20040249355 Tanio et al. Dec 2004 A1
20040260259 Baker Dec 2004 A1
20050004543 Schroer et al. Jan 2005 A1
20050004548 Otsubo et al. Jan 2005 A1
20050008839 Cramer et al. Jan 2005 A1
20050038401 Suzuki et al. Feb 2005 A1
20050070867 Beruda et al. Mar 2005 A1
20050085784 LeMinh et al. Apr 2005 A1
20050090789 Graef Apr 2005 A1
20050137543 Underhill et al. Jun 2005 A1
20050148258 Chakravarty Jul 2005 A1
20050148990 Shimoe Jul 2005 A1
20050154363 Minato Jul 2005 A1
20050159720 Gentilcore Jul 2005 A1
20050165208 Popp et al. Jul 2005 A1
20050171499 Nigam et al. Aug 2005 A1
20050176910 Jaworek et al. Aug 2005 A1
20050203475 LaVon et al. Sep 2005 A1
20050215752 Popp et al. Sep 2005 A1
20050229543 Tippey Oct 2005 A1
20050245684 Daniel et al. Nov 2005 A1
20050288645 LaVon Dec 2005 A1
20050288646 LaVon Dec 2005 A1
20060004334 Schlinz et al. Jan 2006 A1
20060021695 Blessing et al. Feb 2006 A1
20060024433 Blessing et al. Feb 2006 A1
20060069371 Ohashi et al. Mar 2006 A1
20060073969 Torli et al. Apr 2006 A1
20060081348 Graef Apr 2006 A1
20060129114 Mason et al. Jun 2006 A1
20060142724 Watanabe Jun 2006 A1
20060155057 Hermeling et al. Jul 2006 A1
20060155254 Sanz et al. Jul 2006 A1
20060167215 Hermeling et al. Jul 2006 A1
20060177647 Schmidt et al. Aug 2006 A1
20060178071 Schmidt et al. Aug 2006 A1
20060184146 Suzuki Aug 2006 A1
20060184149 Kasai et al. Aug 2006 A1
20060189954 Kudo Aug 2006 A1
20060201643 Underhill Sep 2006 A1
20060202380 Bentley Sep 2006 A1
20060206091 Cole Sep 2006 A1
20060211828 Daniel et al. Sep 2006 A1
20060240229 Ehrnsperger et al. Oct 2006 A1
20060264860 Beck Nov 2006 A1
20060264861 Lavon et al. Nov 2006 A1
20070027436 Nakagawa et al. Feb 2007 A1
20070032770 LaVon et al. Feb 2007 A1
20070043191 Hermeling et al. Feb 2007 A1
20070043330 Lankhof et al. Feb 2007 A1
20070073253 Miyama Mar 2007 A1
20070078422 Glaug et al. Apr 2007 A1
20070088308 Ehrnsperger et al. Apr 2007 A1
20070093164 Nakaoka Apr 2007 A1
20070093767 Carlucci et al. Apr 2007 A1
20070100307 Nomoto May 2007 A1
20070118087 Flohr et al. May 2007 A1
20070123834 McDowall et al. May 2007 A1
20070156108 Becker et al. Jul 2007 A1
20070156110 Thyfault Jul 2007 A1
20070167928 Becker et al. Jul 2007 A1
20070179464 Becker et al. Aug 2007 A1
20070179469 Takahashi et al. Aug 2007 A1
20070191798 Glaug Aug 2007 A1
20070219521 Hird et al. Sep 2007 A1
20070219523 Bruun Sep 2007 A1
20070244455 Hansson et al. Oct 2007 A1
20070246147 Venturino et al. Oct 2007 A1
20070282288 Noda Dec 2007 A1
20070282290 Cole Dec 2007 A1
20070282291 Cole Dec 2007 A1
20080027402 Schmidt et al. Jan 2008 A1
20080032035 Schmidt et al. Feb 2008 A1
20080091159 Carlucci et al. Apr 2008 A1
20080119810 Kuroda May 2008 A1
20080125735 Busam et al. May 2008 A1
20080221538 Zhao Sep 2008 A1
20080221539 Zhao Sep 2008 A1
20080228158 Sue et al. Sep 2008 A1
20080262459 Kamoto Oct 2008 A1
20080268194 Kim et al. Oct 2008 A1
20080274227 Boatman et al. Nov 2008 A1
20080281287 Marcelo Nov 2008 A1
20080294140 Ecker et al. Nov 2008 A1
20080312617 Hundorf et al. Dec 2008 A1
20080312618 Hundorf et al. Dec 2008 A1
20080312619 Hundorf et al. Dec 2008 A1
20080312620 Ashton et al. Dec 2008 A1
20080312621 Hundorf et al. Dec 2008 A1
20080312622 Hundorf et al. Dec 2008 A1
20080312623 Hundorf et al. Dec 2008 A1
20080312624 Hundorf et al. Dec 2008 A1
20080312625 Hundorf et al. Dec 2008 A1
20080312627 Takeuchi Dec 2008 A1
20080312628 Hundorf et al. Dec 2008 A1
20090023848 Ahmed et al. Jan 2009 A1
20090056867 Moriura et al. Mar 2009 A1
20090062760 Wright et al. Mar 2009 A1
20090112173 Bissah Apr 2009 A1
20090112175 Bissah et al. Apr 2009 A1
20090157022 Macdonald Jun 2009 A1
20090192035 Stueven et al. Jul 2009 A1
20090240220 Macdonald Sep 2009 A1
20090247977 Takeuchi Oct 2009 A1
20090258994 Stueven et al. Oct 2009 A1
20090270825 Wciorka et al. Oct 2009 A1
20090298963 Matsumoto et al. Dec 2009 A1
20090299312 Macdonald Dec 2009 A1
20090306618 Kudo Dec 2009 A1
20090318884 Meyer et al. Dec 2009 A1
20100051166 Hundorf et al. Mar 2010 A1
20100062165 Suzuki Mar 2010 A1
20100062934 Suzuki Mar 2010 A1
20100063470 Suzuki Mar 2010 A1
20100068520 Stueven et al. Mar 2010 A1
20100100065 Bianco Apr 2010 A1
20100121296 Noda May 2010 A1
20100137773 Gross Jun 2010 A1
20100137823 Corneliusson Jun 2010 A1
20100198179 Noda Aug 2010 A1
20100228210 Busam et al. Sep 2010 A1
20100241097 Nigam et al. Sep 2010 A1
20100262099 Klofta Oct 2010 A1
20100274208 Gabrielii Oct 2010 A1
20100274210 Noda Oct 2010 A1
20100312208 Bond et al. Dec 2010 A1
20100324521 Mukai Dec 2010 A1
20100324523 Mukai Dec 2010 A1
20100331801 Kawakami et al. Dec 2010 A1
20110060303 Bissah Mar 2011 A1
20110066127 Kuwano Mar 2011 A1
20110071486 Harada Mar 2011 A1
20110092944 Sagisaka Apr 2011 A1
20110041999 Hundorf et al. May 2011 A1
20110112498 Nhan et al. May 2011 A1
20110125120 Nishitani May 2011 A1
20110130732 Jackels et al. Jun 2011 A1
20110130737 Sagisaka Jun 2011 A1
20110137276 Yoshikawa Jun 2011 A1
20110144602 Long Jun 2011 A1
20110144604 Noda Jun 2011 A1
20110144606 Nandrea Jun 2011 A1
20110152813 Ellingson Jun 2011 A1
20110166540 Yang et al. Jul 2011 A1
20110172630 Nomoto Jul 2011 A1
20110174430 Zhao Jul 2011 A1
20110208147 Kawakami et al. Aug 2011 A1
20110250413 Lu et al. Oct 2011 A1
20110268932 Catalan et al. Nov 2011 A1
20110274834 Brown et al. Nov 2011 A1
20110288513 Hundorf et al. Nov 2011 A1
20110288514 Kuroda Nov 2011 A1
20110319846 Rinnert et al. Dec 2011 A1
20110319848 McKiernan et al. Dec 2011 A1
20110319851 Kudo Dec 2011 A1
20120004633 R Marcelo Jan 2012 A1
20120016326 Brennan et al. Jan 2012 A1
20120022479 Cotton Jan 2012 A1
20120035566 Sagisaka Feb 2012 A1
20120035576 Ichikawa Feb 2012 A1
20120064792 Bauduin Mar 2012 A1
20120071848 Zhang Mar 2012 A1
20120165771 Ruman et al. Jun 2012 A1
20120165776 Rinnert et al. Jun 2012 A1
20120175056 Tsang Jul 2012 A1
20120184934 Venturino Jul 2012 A1
20120232514 Baker Sep 2012 A1
20120238977 Oku Sep 2012 A1
20120253306 Otsubo Oct 2012 A1
20120256750 Novak Oct 2012 A1
20120270715 Motegi et al. Oct 2012 A1
20120271262 Venturino Oct 2012 A1
20120312491 Jackels et al. Dec 2012 A1
20120316523 Hippe et al. Dec 2012 A1
20120316526 Rosati et al. Dec 2012 A1
20120316527 Rosati et al. Dec 2012 A1
20120316528 Kreuzer et al. Dec 2012 A1
20120316529 Kreuzer et al. Dec 2012 A1
20120323195 Ehrnsperger et al. Dec 2012 A1
20120323201 Bissah Dec 2012 A1
20120323202 Bissah Dec 2012 A1
20130035656 Moriya et al. Feb 2013 A1
20130041334 Prioleau Feb 2013 A1
20130211354 Tsuji et al. Aug 2013 A1
20130218115 Katsuragawa et al. Aug 2013 A1
20130226119 Katsuragawa et al. Aug 2013 A1
20130226120 Van De Maele Aug 2013 A1
20140005622 Wirtz et al. Jan 2014 A1
20140005623 Wirtz et al. Jan 2014 A1
20140039437 Van De Maele Feb 2014 A1
20140045683 Loick et al. Feb 2014 A1
20140135726 Busam et al. May 2014 A1
20140142531 Sasayama et al. May 2014 A1
20140163500 Roe et al. Jun 2014 A1
20140163501 Ehrnsperger et al. Jun 2014 A1
20140163502 Arizti et al. Jun 2014 A1
20140163503 Arizti et al. Jun 2014 A1
20140163506 Roe et al. Jun 2014 A1
20140163511 Roe et al. Jun 2014 A1
20140324007 Hundorf et al. Oct 2014 A1
20140324008 Hundorf et al. Oct 2014 A1
20170231828 Jackels et al. Aug 2017 A1
Foreign Referenced Citations (498)
Number Date Country
2001370 Apr 1990 CA
2291997 Jun 2000 CA
2308961 Nov 2000 CA
2487027 Dec 2003 CA
2561521 Mar 2007 CA
2630713 Nov 2008 CA
2636673 Jan 2009 CA
2712563 Aug 2010 CA
2702001 Oct 2010 CA
1238171 Dec 1999 CN
2362468 Feb 2000 CN
2527254 Dec 2002 CN
2535020 Feb 2003 CN
2548609 May 2003 CN
1539391 Oct 2004 CN
1939242 Apr 2007 CN
101292930 Oct 2008 CN
201263750 Jul 2009 CN
201591689 Sep 2010 CN
201855366 Jun 2011 CN
3205931 Sep 1983 DE
3608114 Sep 1987 DE
4 335 919 Apr 1995 DE
19732499 Feb 1999 DE
10204937 Aug 2003 DE
0083022 Jul 1983 EP
149880 Jul 1985 EP
0149880 Jul 1985 EP
0203289 Dec 1986 EP
0206208 Dec 1986 EP
209561 Jan 1987 EP
0297411 Jan 1989 EP
0304957 Mar 1989 EP
0374542 Jun 1990 EP
0394274 Oct 1990 EP
0403832 Dec 1990 EP
0481322 Apr 1992 EP
0530438 Mar 1993 EP
0547847 Jun 1993 EP
0555346 Aug 1993 EP
0559476 Sep 1993 EP
0591647 Apr 1994 EP
0597273 May 1994 EP
0601610 Jun 1994 EP
0632068 Jan 1995 EP
0640330 Mar 1995 EP
0668066 Sep 1995 EP
0685214 Dec 1995 EP
0687453 Dec 1995 EP
0 691 133 Jan 1996 EP
0689817 Jan 1996 EP
0724418 Aug 1996 EP
0725613 Aug 1996 EP
0725615 Aug 1996 EP
0725616 Aug 1996 EP
0758543 Feb 1997 EP
0761194 Mar 1997 EP
0769284 Apr 1997 EP
0781537 Jul 1997 EP
0783877 Jul 1997 EP
0787472 Aug 1997 EP
0788874 Aug 1997 EP
0796068 Sep 1997 EP
0799004 Oct 1997 EP
0822794 Feb 1998 EP
0826351 Mar 1998 EP
0844861 Jun 1998 EP
0863733 Sep 1998 EP
0971751 Sep 1998 EP
0875224 Nov 1998 EP
0880955 Dec 1998 EP
0891758 Jan 1999 EP
0893115 Jan 1999 EP
0904755 Mar 1999 EP
0916327 May 1999 EP
0925769 Jun 1999 EP
0933074 Aug 1999 EP
0937736 Aug 1999 EP
0941157 Sep 1999 EP
0947549 Oct 1999 EP
0951887 Oct 1999 EP
0951890 Oct 1999 EP
2295493 Oct 1999 EP
2305749 Oct 1999 EP
2330152 Oct 1999 EP
0953326 Nov 1999 EP
0978263 Feb 2000 EP
0985397 Mar 2000 EP
1005847 Jun 2000 EP
1008333 Jun 2000 EP
1013252 Jun 2000 EP
1018999 Jul 2000 EP
1019002 Jul 2000 EP
1019003 Jul 2000 EP
1022008 Jul 2000 EP
1023884 Aug 2000 EP
1053729 Nov 2000 EP
1059072 Dec 2000 EP
1063954 Jan 2001 EP
1071388 Jan 2001 EP
1078618 Feb 2001 EP
1088537 Apr 2001 EP
1116479 Jul 2001 EP
1132069 Sep 2001 EP
1173128 Jan 2002 EP
1175194 Jan 2002 EP
1184018 Mar 2002 EP
1192312 Apr 2002 EP
1196122 Apr 2002 EP
1199059 Apr 2002 EP
1199327 Apr 2002 EP
1208824 May 2002 EP
0793469 Jun 2002 EP
1210925 Jun 2002 EP
1224922 Jul 2002 EP
1225857 Jul 2002 EP
1262531 Dec 2002 EP
1263374 Dec 2002 EP
1275358 Jan 2003 EP
1275361 Jan 2003 EP
1293187 Mar 2003 EP
1304986 May 2003 EP
1332742 Aug 2003 EP
1339368 Sep 2003 EP
1374817 Jan 2004 EP
1388334 Feb 2004 EP
1402863 Mar 2004 EP
0962208 Aug 2004 EP
1447066 Aug 2004 EP
1447067 Aug 2004 EP
1460987 Sep 2004 EP
0963749 Nov 2004 EP
1495739 Jan 2005 EP
1524955 Apr 2005 EP
1920743 Apr 2005 EP
1541103 Jun 2005 EP
1551344 Jul 2005 EP
1586289 Oct 2005 EP
1588723 Oct 2005 EP
1605882 Dec 2005 EP
1609448 Dec 2005 EP
1 621 166 Feb 2006 EP
1621167 Feb 2006 EP
1632206 Mar 2006 EP
1642556 Apr 2006 EP
1656162 May 2006 EP
1669046 Jun 2006 EP
1688114 Aug 2006 EP
2314265 Aug 2006 EP
1723939 Nov 2006 EP
1738727 Jan 2007 EP
1754461 Feb 2007 EP
1787611 May 2007 EP
1813238 Aug 2007 EP
2008626 Dec 2008 EP
2055279 May 2009 EP
2093049 Aug 2009 EP
2130522 Dec 2009 EP
2444046 Apr 2012 EP
2532328 Dec 2012 EP
2532329 Dec 2012 EP
2532332 Dec 2012 EP
2679210 Jan 2014 EP
2740449 Jun 2014 EP
2740450 Jun 2014 EP
2740452 Jun 2014 EP
2213491 Aug 2004 ES
2566631 Jan 1986 FR
2612770 Sep 1988 FR
2 690 843 Nov 1993 FR
2810234 Dec 2001 FR
1333081 Aug 1971 GB
1307441 Feb 1973 GB
1513055 Jun 1978 GB
2101468 Jan 1983 GB
2170108 Jul 1986 GB
2262873 Jul 1993 GB
2288540 Jun 1994 GB
2354449 Mar 2001 GB
2452260 Oct 2007 GB
851769 Nov 1985 GR
0984KOL1999 Oct 2005 IN
212479 Mar 2007 IN
208543 Aug 2007 IN
0980MUM2009 Jun 2009 IN
55-72928 May 1980 JP
59-8322 Jan 1984 JP
63-0148323 Sep 1988 JP
03-224481 Oct 1991 JP
04-122256 Apr 1992 JP
06-269475 Sep 1994 JP
10-328232 Dec 1998 JP
11-033056 Feb 1999 JP
11-318980 Nov 1999 JP
2000-232985 Aug 2000 JP
2000-238161 Sep 2000 JP
2001-037810 Feb 2001 JP
2001-046435 Feb 2001 JP
2001-120597 May 2001 JP
2001-158074 Jun 2001 JP
2001-178768 Jul 2001 JP
2001-198157 Jul 2001 JP
2001-224626 Aug 2001 JP
03-420481 Nov 2001 JP
2001-353174 Dec 2001 JP
2002-052042 Feb 2002 JP
2002-113800 Apr 2002 JP
2002-165832 Jun 2002 JP
2002-165836 Jun 2002 JP
2002-272769 Sep 2002 JP
2002-325792 Nov 2002 JP
2002-325799 Nov 2002 JP
2002-369841 Dec 2002 JP
2003144487 May 2003 JP
2003-153955 May 2003 JP
2003-265524 Sep 2003 JP
2003-275237 Sep 2003 JP
2004-089269 Mar 2004 JP
03-566012 Jun 2004 JP
03-568146 Jun 2004 JP
03-616077 Nov 2004 JP
2004-337314 Dec 2004 JP
2004-337385 Dec 2004 JP
2004350864 Dec 2004 JP
03-640475 Jan 2005 JP
2005-000312 Jan 2005 JP
03-660816 Mar 2005 JP
03-676219 May 2005 JP
03-688403 Jun 2005 JP
03-705943 Aug 2005 JP
03-719819 Sep 2005 JP
03-724963 Sep 2005 JP
03-725008 Sep 2005 JP
03-737376 Nov 2005 JP
2006-014792 Jan 2006 JP
03-781617 Mar 2006 JP
2006-110329 Apr 2006 JP
03-801449 May 2006 JP
2006-116036 May 2006 JP
03-850102 Sep 2006 JP
03-850207 Sep 2006 JP
03-856941 Sep 2006 JP
03-868628 Oct 2006 JP
03-874499 Nov 2006 JP
03-877702 Nov 2006 JP
2006-325639 Dec 2006 JP
2006-346021 Dec 2006 JP
03-904356 Jan 2007 JP
2007-007455 Jan 2007 JP
2007-007456 Jan 2007 JP
03-926042 Mar 2007 JP
03-934855 Mar 2007 JP
2007054219 Mar 2007 JP
2007054219 Mar 2007 JP
2007-089906 Apr 2007 JP
2007-105198 Apr 2007 JP
2007-152033 Jun 2007 JP
03-986210 Jul 2007 JP
03-986222 Jul 2007 JP
2007-167453 Jul 2007 JP
2007-175515 Jul 2007 JP
2007-195665 Aug 2007 JP
2007-267763 Oct 2007 JP
2007-275491 Oct 2007 JP
04-035341 Nov 2007 JP
04-058281 Dec 2007 JP
04-061086 Dec 2007 JP
04-092319 Mar 2008 JP
2008-080150 Apr 2008 JP
2008-093289 Apr 2008 JP
04-124322 May 2008 JP
2008-119081 May 2008 JP
2008-136739 Jun 2008 JP
2008-136877 Jun 2008 JP
04-148594 Jul 2008 JP
04-148620 Jul 2008 JP
2008-154606 Jul 2008 JP
04-162609 Aug 2008 JP
04-162637 Aug 2008 JP
04-166923 Aug 2008 JP
04-167406 Aug 2008 JP
04-173723 Aug 2008 JP
04-190675 Sep 2008 JP
04-190693 Sep 2008 JP
04-208338 Oct 2008 JP
2008-246089 Oct 2008 JP
04-230971 Dec 2008 JP
2008-295475 Dec 2008 JP
2008-295713 Dec 2008 JP
04-261593 Feb 2009 JP
2009-112590 May 2009 JP
04-322228 Jun 2009 JP
2009-136601 Jun 2009 JP
2009-142401 Jul 2009 JP
2009-201878 Sep 2009 JP
04-392936 Oct 2009 JP
2009-232987 Oct 2009 JP
2009-261777 Nov 2009 JP
2009-291473 Dec 2009 JP
2009-297048 Dec 2009 JP
2010017342 Jan 2010 JP
04-458702 Feb 2010 JP
04-459013 Feb 2010 JP
2010-022560 Feb 2010 JP
04-481325 Mar 2010 JP
2010-051654 Mar 2010 JP
2010-063814 Mar 2010 JP
2010-063944 Mar 2010 JP
04-492957 Apr 2010 JP
2010-068954 Apr 2010 JP
2010-075462 Apr 2010 JP
2010-082059 Apr 2010 JP
2010-104545 May 2010 JP
2010-104547 May 2010 JP
2010-110535 May 2010 JP
2010-119454 Jun 2010 JP
2010-119605 Jun 2010 JP
2010-119743 Jun 2010 JP
2010-131131 Jun 2010 JP
2010-131132 Jun 2010 JP
2010-131206 Jun 2010 JP
2010-131297 Jun 2010 JP
2010-136917 Jun 2010 JP
2010-136973 Jun 2010 JP
04-540563 Jul 2010 JP
04-587947 Sep 2010 JP
2010-194124 Sep 2010 JP
2010-201093 Sep 2010 JP
2010-221067 Oct 2010 JP
04-620299 Nov 2010 JP
04-627472 Nov 2010 JP
04-627473 Nov 2010 JP
04-638087 Dec 2010 JP
04-652626 Dec 2010 JP
2010-273842 Dec 2010 JP
2010284418 Dec 2010 JP
2010-284418 Dec 2010 JP
2011-000480 Jan 2011 JP
2011-030700 Feb 2011 JP
04-693574 Mar 2011 JP
2011-067484 Apr 2011 JP
2011-072720 Apr 2011 JP
2011-104014 Jun 2011 JP
2011-104122 Jun 2011 JP
2011-120661 Jun 2011 JP
2011-125360 Jun 2011 JP
2011-125537 Jun 2011 JP
04-776516 Jul 2011 JP
2011-130797 Jul 2011 JP
2011-130799 Jul 2011 JP
2011-156032 Aug 2011 JP
2011-156070 Aug 2011 JP
2011-156254 Aug 2011 JP
04-824882 Sep 2011 JP
48-50272 Oct 2011 JP
04-855533 Nov 2011 JP
2011-239858 Dec 2011 JP
04-931572 Feb 2012 JP
04-937225 Mar 2012 JP
04-953618 Mar 2012 JP
04-969437 Apr 2012 JP
04-969640 Apr 2012 JP
04-974524 Apr 2012 JP
04-979780 Apr 2012 JP
49-71491 Apr 2012 JP
05-016020 Jun 2012 JP
05-027364 Jun 2012 JP
05-031082 Jul 2012 JP
05-042351 Jul 2012 JP
05-043569 Jul 2012 JP
05-043591 Jul 2012 JP
05-046488 Jul 2012 JP
2012-125625 Jul 2012 JP
05-053765 Aug 2012 JP
05-070275 Aug 2012 JP
05-079931 Sep 2012 JP
05-080189 Sep 2012 JP
05-084442 Sep 2012 JP
05-084476 Sep 2012 JP
05-089269 Sep 2012 JP
50-85770 Sep 2012 JP
05-113146 Oct 2012 JP
05-129536 Nov 2012 JP
05-105884 Dec 2012 JP
20010005620 Jan 2001 KR
20020035634 May 2002 KR
20080028771 Apr 2008 KR
9400916 Mar 1994 SE
9704893 Dec 1997 SE
WO9015830 Dec 1990 WO
WO9321237 Oct 1993 WO
WO9321879 Nov 1993 WO
WO9510996 Apr 1995 WO
WO9511652 May 1995 WO
WO9514453 Jun 1995 WO
WO9515139 Jun 1995 WO
WO9516424 Jun 1995 WO
WO9516746 Jun 1995 WO
WO9519753 Jul 1995 WO
WO9521596 Aug 1995 WO
WO9524173 Sep 1995 WO
WO9529657 Nov 1995 WO
WO9532698 Dec 1995 WO
WO9534329 Dec 1995 WO
WO9616624 Jun 1996 WO
WO9619173 Jun 1996 WO
WO9711659 Apr 1997 WO
WO9717922 May 1997 WO
WO9816179 Apr 1998 WO
WO9816180 Apr 1998 WO
WO9843684 Oct 1998 WO
WO9913813 Mar 1999 WO
WO9934841 Jul 1999 WO
WO9951178 Oct 1999 WO
WO2000000235 Jan 2000 WO
WO2000032145 Jun 2000 WO
WO2000059430 Oct 2000 WO
WO2001015647 Mar 2001 WO
WO2001026596 Apr 2001 WO
WO2002007663 Jan 2002 WO
WO2002032962 Apr 2002 WO
WO2002064877 Aug 2002 WO
WO2002067809 Sep 2002 WO
WO2003009794 Feb 2003 WO
WO2003039402 May 2003 WO
WO2003053297 Jul 2003 WO
WO2003105738 Dec 2003 WO
WO2004021946 Mar 2004 WO
WO2004049995 Jun 2004 WO
WO2004071539 Aug 2004 WO
WO2004084784 Oct 2004 WO
WO2004105664 Dec 2004 WO
WO2005018694 Mar 2005 WO
WO2005087164 Sep 2005 WO
WO2006104024 May 2006 WO
WO2006059922 Jun 2006 WO
WO2006062258 Jun 2006 WO
WO2006066029 Jun 2006 WO
WO2006083584 Aug 2006 WO
WO2006134904 Dec 2006 WO
WO2006134906 Dec 2006 WO
WO2007000315 Jan 2007 WO
WO2007046052 Apr 2007 WO
WO2007047598 Apr 2007 WO
WO2007049725 May 2007 WO
WO2007061035 May 2007 WO
WO2007142145 Dec 2007 WO
WO2007148502 Dec 2007 WO
WO2008018922 Feb 2008 WO
WO2008065945 Jun 2008 WO
WO2008146749 Dec 2008 WO
WO2008155699 Dec 2008 WO
WO2009004941 Jan 2009 WO
WO2009005431 Jan 2009 WO
WO2009139248 Jan 2009 WO
WO2009139255 Jan 2009 WO
WO2009041223 Apr 2009 WO
WO2009096108 Aug 2009 WO
WO2009107435 Sep 2009 WO
WO2009122830 Oct 2009 WO
WO 2009152018 Dec 2009 WO
WO2009155264 Dec 2009 WO
WO2009155265 Dec 2009 WO
WO2010071508 Jun 2010 WO
WO2010074319 Jul 2010 WO
WO2010107096 Sep 2010 WO
WO2010114052 Oct 2010 WO
WO2010117015 Oct 2010 WO
WO2011053044 May 2011 WO
WO2011118725 Sep 2011 WO
WO2011118842 Sep 2011 WO
WO2011145653 Nov 2011 WO
WO2011150955 Dec 2011 WO
WO2011163582 Dec 2011 WO
WO2012002252 Jan 2012 WO
WO2012014436 Feb 2012 WO
WO2012042908 Apr 2012 WO
WO2012043077 Apr 2012 WO
WO2012043078 Apr 2012 WO
WO2012052172 Apr 2012 WO
WO2012043082 May 2012 WO
WO2012067216 May 2012 WO
WO2012073499 Jun 2012 WO
WO2012074466 Jun 2012 WO
WO2012090508 Jul 2012 WO
WO2012091016 Jul 2012 WO
WO2012101934 Aug 2012 WO
WO2012102034 Aug 2012 WO
WO2012117824 Sep 2012 WO
WO2012132460 Oct 2012 WO
WO2012170778 Dec 2012 WO
WO2012170779 Dec 2012 WO
WO2012170781 Dec 2012 WO
WO2012170808 Dec 2012 WO
WO2012174026 Dec 2012 WO
WO2013001788 Jan 2013 WO
WO2013060733 May 2013 WO
WO2014078247 May 2014 WO
Non-Patent Literature Citations (5)
Entry
European Search Report, EP11169396.6, dated Oct. 21, 2011, 9 pages.
International Search Report, PCT/US2012/041522, dated Sep. 5, 2012, 13 pages.
All Office Actions U.S. Appl. No. 15/284,605.
All Office Actions U.S. Appl. No. 14/043,931.
All Office Actions U.S. Appl. No. 13/491,936.
Related Publications (1)
Number Date Country
20190038477 A1 Feb 2019 US
Continuations (3)
Number Date Country
Parent 15284605 Oct 2016 US
Child 16154061 US
Parent 14043931 Oct 2013 US
Child 15284605 US
Parent 13491936 Jun 2012 US
Child 14043931 US