1. Field of the Invention
Embodiments of the present invention generally relate to a telemetry system for communicating information from a downhole tool. Particularly, embodiments of the invention relate to a chemical telemetry system for communicating information from a downhole tool.
2. Description of the Related Art
Optimal oil production from the reservoir depends upon reliable knowledge of the reservoir characteristics. Traditional methods for reservoir monitoring include seismic log interpretation, well pressure testing, production fluid analysis, and production history matching. Due to the complexity of the reservoir, all information available is valuable in order to give the operator the best possible knowledge about the dynamics in the reservoir.
Fiber or electrical cables with a sensor have been used in the industry to communicate information to and from a downhole tool. However, one drawback of cable is that it requires a direct connection with the downhole tool. This direct connection increases the cost of the operation.
There is a need, therefore, for a telemetry system to communicate information about the wellbore from a downhole tool.
In one embodiment, a method of communicating a wellbore parameter from a downhole tool includes providing a plurality of tracers for representing a value of the wellbore parameter; measuring the wellbore parameter using a sensor; correlating the wellbore parameter to a value represented by one or more of the plurality of tracers; releasing the one or more of the plurality of tracers to travel upstream; detecting presence of the one or more of the plurality of tracers; and determining the wellbore parameter from the detected one or more of the plurality of tracers.
In another embodiment, a system for communicating a wellbore parameter from a downhole tool includes a plurality of tracers for representing a value of the wellbore parameter; a plurality of containers for storing the plurality of tracers; a first sensor for measuring the wellbore parameter; a downhole controller configured to correlate the wellbore parameter to one or more of the plurality of tracers and configured to release the one or more of the plurality of the tracers; an second sensor for detecting presence of the one or more of the plurality of tracers; and an uphole controller configured to determine the wellbore parameter from the detected one or more of the plurality of tracers.
In one or more of the embodiment disclosed herein, each of the plurality of tracers represents a different value of the wellbore parameter.
In one or more of the embodiment disclosed herein, each of the plurality of tracers comprises a chemical.
In another embodiment, a method of communicating a wellbore parameter from a downhole tool includes providing a plurality of tracers for representing a value of the wellbore parameter; measuring the wellbore parameter using a sensor; correlating the wellbore parameter to a value represented by a ratiometric amount of one or more of the plurality of tracers; releasing the ratiometric amount of one or more of the plurality of tracers to travel upstream; detecting presence of the ratiometric amount of one or more of the plurality of tracers; and determining the wellbore parameter from the detected ratiometric amount of one or more of the plurality of tracers.
In one or more of the embodiment disclosed herein, the method further includes releasing a calibration dosage of the plurality of tracers.
In another embodiment, a method of monitoring status of a downhole tool includes providing a plurality of tracers for representing a status of the downhole tool; changing the status of the downhole tool; and releasing a tracer representing the changed status of the downhole tool. In another embodiment, changing the status of the downhole tool comprises moving a component of the downhole tool. In yet another embodiment, the tracer is released in response to movement of the component.
In another embodiment, a method of monitoring a downhole tool includes storing the plurality of tracers in a plurality of chambers, wherein the tracers in each of the plurality of chambers represent a different position of a component of the downhole tool; moving the component to change the position of the component; sequentially opening the plurality of chambers as the component is being moved, thereby releasing the tracers from the opened chambers; detecting the tracers being released; and determining the position of the component. In another embodiment, the plurality of chambers are closed by the component. In yet another embodiment, the plurality of chambers are closed by a respective cover that is coupled to the component.
So that the manner in which the above recited features of the present invention can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only typical embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.
Embodiments of the present invention relate to a telemetry system and method for communicating a wellbore parameter such as fluid composition, temperature, and pressure. In one embodiment, a plurality of tracers is stored downhole, and each of the tracers represents a different value of the wellbore parameter. After measuring the wellbore parameter, the measured value is correlated to one or more of the plurality of tracers that is equivalent to the measured value of the downhole parameter. The one or more tracers representing the measured value are then released from their respective containers to travel upstream. A sensor located upstream may detect the one or more tracers, which are then correlated back to obtain the measured value of the wellbore parameter.
In one embodiment, a code may be used to convey information about a wellbore parameter, such as fluid composition, temperature, and pressure. The code may include a plurality of code elements. Each of the code elements may represent a different value of the wellbore parameter. The value represented may be a single value or a range of values. The code may be presented by a plurality of tracers, where each of the code elements is represented by a tracer or a combination of different tracers. In one embodiment, each of the plurality of tracers is initially stored in its respective container.
In operation, after obtaining a measured value of the wellbore parameter, the measured value is then ascribed to a code element CE1 in the code. The tracer or combination of tracers representing the code element is then released from its container. For example, if the plurality of tracers include Z1, Z2, and Z3, and the code element is represented by tracer Z1; then tracer Z1 will be released from its container and allowed to travel uphole. A sensor located uphole may detect the presence of tracer Z1 and determine the specific value or range of values of the wellbore parameter as a result of detecting the tracer Z1. In another example, the measured value may be ascribed to a different code element CE2 which may be represented by a combination of Z2 and Z3. In this instance, both tracer Z2 and tracer Z3 will be released from their respective container. When the uphole sensor detects the presence of both tracers, it may determine the specific value or range of values of the wellbore parameter. In another embodiment, the combination of tracers may be released simultaneously or sequentially. For example, tracers Z2 and Z3 may be released at the same time or sequentially.
In this respect, the number of tracers required to represent a set of code elements will be less than the number of code elements in the code. In the current example, three tracers may be used to represent a set of seven different code elements. In another example, two tracers may be used to represent a set of three code elements. Another advantage of this system is that the measured value is not communicated using the concentration of the tracer released into the wellbore. Instead, the measured value is communicated by the tracer or combination of different tracers released. As a result, in some embodiments, only the smallest amount of tracer needed for detection is required to be released. This advantage allows the container to be configured for a known number of releases. It is contemplated that communication using the code may be applicable in each of the embodiments described herein.
In one embodiment, the plurality of tracers may be used to convey information about a wellbore parameter, such as fluid composition, temperature, and pressure. Each of the tracers Z1, Z2, Z3 may represent a different value of the wellbore parameter. The value may be a specific value or a range. The plurality of tracers may be used in combination to represent a value that is outside of the value of an individual tracer. In one embodiment, each of the plurality of tracers is initially stored in its respective container. In operation, after obtaining a measured value of the wellbore parameter, the measured value is then correlated to an equivalent value represented by one or more of the tracers. For example, if the value represented by tracer Z1 is equivalent to the measured value; then tracer Z1 will be released from its container and allowed to travel uphole. A sensor located uphole may detect the presence of tracer Z1 and determine that the value of the wellbore parameter is within the value represented by tracer Z1. In another example, the measured value may be represented by a combination of the tracers. In this instance, the measured value may be represented by the total value represented by tracer Z2 and tracer Z3. In this respect, both tracer Z2 and tracer Z3 will be released from their respective container. When the uphole sensor detects the presence of both tracers, it will determine that the measured value is within a range represented by the combined value of tracers Z1 and Z2. In this respect, the number of tracers required to represent a set of values will be less than the number of values in the set. In the current example, three tracers may be used to represent a set of seven different values. In another example, two tracers may be used to represent a set of three different values. Another advantage of this system is that the measured value is not correlated to the concentration of the tracer released into the wellbore. Instead, the measured value is correlated to the tracer or combination of different tracers released. As a result, in some embodiment, only the smallest amount needed for detection is required to be released. This advantage allows the container to be configured for a known number of releases.
In one embodiment, the tracers may be chemicals that can travel in the wellbore without being consumed, and therefore, detected at another location. In another embodiment, the tracers may be chemicals not naturally found in the wellbore. Suitable chemicals may include radioactive or non-radioactive isotopes. Suitable non-radioactive tracers include salts of naphthalenesulfonic acids, salts of amino naphthalenesulfonic acids, fluorescein and fluorinated benzoic acids. 3H-labelled or 14C-labelled tracers of the same kind of components may also be applied. Radioactive tracers such as beta emitters may also be used. Exemplary tracers include chemicals that can be detected using spectroscopic or electromagnetic means, such as radiometric, magnetic, or optical devices. Additionally, particle size detection using tracers such as silicon or other nanoparticles is also contemplated. Other exemplary chemicals include fluorobenzoates, chlorobenzoates, fluoromethylbenzoates, perfluoroaliphatic acids, etc. Depending upon the natural chemistry of the wellbore and the types of chemicals being introduced for stimulation, remediation, fracturing, etc. the selection of chemicals for the tracer may be different.
Referring back to
In one embodiment, the controller 61 may be configured to send information about the water cut or other wellbore parameter at predetermined time periods. For example, the controller 61 may be configured to release the tracers daily, weekly, monthly, quarterly, or any suitable time frame. The controller 61 may be configured to release an amount of tracer that is sufficient for detection by the detection system 80. Because only a low amount of power is required to read the sensors, open and close the container, and operate the internal clock, the battery life of the system is increased. Thus, the telemetry system 100 may be a low power system that has a long life, or large number of iterations, or both.
In operation, the telemetry system 100 may be used to communicate a wellbore parameter such as the water cut of the wellbore fluid. In one embodiment, the controller 61 may be configured to communicate the water cut on a daily basis. To that end, the controller 61 may obtain the value of the water cut from the first sensor 41. The controller 61 may then correlate the measured value to the tracers that represent the measured value. In one example, if the measured value is 0.35, then the controller 61 may determine that the measured value is within the range represented by tracer B2 and then release tracer B2 from its container 52. The tracer B2 travels uphole to the surface and is detected by the detection system 80. The detection of tracer B2 communicates to the detection system 80 that the water cut in the first zone is between 0.25 and 0.375. One day later, the controller 61 may receive another measured value of the water cut from the first sensor 41. In another example, if the measured value of the water cut has increased to 0.4, then the controller 61 may correlate that to a value represented by a combination of tracers B1 and B2. As a result, the controller 61 will release tracers B1 and B2 from their respective containers 51, 52. The detection of tracers B1 and B2 communicates to the detection system 80 that the water cut in the first zone is between 0.375 and 0.5. In one embodiment, the tracers B1 and B2 may be released in a unique pattern. For example, tracer B1 and tracer B2 may be released sequentially or simultaneously. In another embodiment, the controller 61 may also communicate the water cut of the second zone 32 by obtaining the measured value from the second sensor 42 and releasing the equivalent tracers C1, C2, C3 of the second zone 32. The tracers selected for the second zone 32 are different from the tracers of the first zone 31 to help distinguish the zones 31, 32. The tracers of the second zone 32 may also be released on a daily basis. In one embodiment, the tracers of the second zone 32 are released at a different time during the day than the first zone 31. For example, the tracers of the second zone 32 may be released 12 hours after the first zone 31. The tracers C1, C2, C3 may be assigned the same water cut values as the tracers B1, B2, B3 from the first zone. The detection system 80 may be configured to detect the tracers C1, C2, C3 and determine the water cut value from the tracers. In another embodiment, the telemetry system 100 may include one or more groups of sensors and tracers for measuring other wellbore parameters such as temperature and pressure. In one example, tracers for conveying temperature may be released on a weekly basis, while tracers for conveying pressure may be released on a daily basis.
Although
In another embodiment, the telemetry system may be used in a fracturing operation.
In operation, when the fracture sleeve 142 opens, the controller opens the gate valve 152 in response. However, the tracer is not released until the check valve 154 is opened. While the fracturing fluid is being injected, the check valve 154 remains closed because the wellbore pressure generated by the fracturing fluid is greater than the annulus pressure. When the injection ceases and the wellbore pressure drops below annulus pressure, the check valve 154 opens to release the tracer from the container 150. The tracer is released into the wellbore and is carried up to the surface. Detection of the tracer at the surface indicates that the fracture sleeve 142 opened during the operation. However, if no tracers for a particular fracture sleeve are detected, then it is an indication that the particular fracture sleeve may have failed to open. In another embodiment, the measured values may be ascribed to a code element in a code, and each code element is assigned to a tracer of combination of tracers.
In another embodiment, the tracers may be used to indicate the open status of a sliding sleeve or other valve devices. For example, a valve may be controlled from surface between open, close, or partially open positions. However, it is generally difficult to determine the extent to which the valve is partially open. In one embodiment, the valve may include a sensor configured to measure the extent of opening of the valve. A plurality of containers may be used to store tracers E1, E2, E3, respectively, to communicate the status of the valve. In one embodiment, the containers may be pressurized and may be operated by a downhole controller. The controller is also connected to the sensor and may receive signals from the sensor regarding the extent of valve opening. The controller is configured to correlate the measured value to the tracers E1, E2, E3, or combination of tracers that represent the measured value. In one example, the tracers E1, E2, E3 may be used to represent ranges 1-7 as shown in
In operation, a signal may be sent to the valve to at least partially open the valve, for example, 60% open. The sensor measures the amount of opening of the valve and communicates the data to the controller. In turn, the controller releases one or more tracers to communicate to the surface the extent of the valve opening. For example, the controller may determine that the measured value of 60% open is within the range represented by tracer E3 and thus, release tracer E3 from its container. The tracer E3 travels up the wellbore and is detected by the detection system. The detection of tracer E3 communicates to the detection system that the valve is 50% to 62.5% open. Later, the controller may receive another measured value of the valve, for example, 70% open. Then, the controller may correlate the measured value to a value represented by a combination of tracers E1 and E3. As a result, the controller releases tracers E1 and E3 from their respective containers. The detection of tracers E1 and E3 indicates that the valve is opened in a range between 62.5% and 75%. In this manner, the tracers may be used as an encoding to communicate the status of the valve. It must be noted that the range designations of the tracers may be different from the ranges in
In another embodiment, the release of the tracers may be coupled directly to the opening of the sleeve of the downhole valve. In one example, the tracers may be stored in sequential chambers of a container or containers that are closed by the sleeve. Each chamber may store a different tracer or combination of tracers, which represents the open status of the sleeve. As the sleeve moves to open the downhole valve, it will sequentially uncover one or more of the chambers. The tracers in the chambers opened by the sleeve will be released into the flow stream, such as the tubing, the annulus between the tubing and casing, a hydraulic line, and combinations thereof. When detected, the tracers will be analyzed at surface to determine the valve position. In another embodiment, the sleeve may be coupled to a cover of the chambers. As the sleeve moves, it will also move the cover to open the respective chambers to release the tracers. Although the description relates to a downhole valve, it is contemplated that the system may be used to indicate the position status of any suitable downhole tool. In another embodiment, the chemical communication system may be used to communicate the position of a component of a downhole tool.
In one exemplary operation, five chambers may be used to represent the position of the sleeve in twenty percent increments.
In another embodiment, the release of the tracers may be controlled by a command such as receiving the command from the surface or from a controller. For example, after opening the sleeve opens three of the chambers 431-433, the release of the tracers may be delayed until a command is received. In one example, a controller may instruct all of the chambers 431-435 to release their tracers. However, only the tracers in chambers 431-433 will release into the flow stream because those chambers have been opened. The tracers in chambers 434-435 cannot release into the flow stream because those chambers are still blocked by the sleeve 400.
In another embodiment, the valves may be configured to send a chemical signal even though it is closed. For example, referring back to
In another embodiment, the telemetry system may be used to communicate the status of a subsurface safety valve. For example, a subsurface safety valve 200 may include a flapper 210 biased in a normally closed position. During operation, a shift sleeve 215 may be used to open the flapper 210 and lock the flapper 210 in the open position, as shown in
In another embodiment, the telemetry system may be used to facilitate control of a downhole pump by communicating wellbore condition adjacent the downhole pump.
In another embodiment, the telemetry system may be used to convey information regarding a steam assisted gravity drainage system (“SAGD”).
In another embodiment, the chemical communication system may be configured to release ratiometric amounts of a tracer to convey information about a wellbore parameter or a downhole tool. For example, each tracer may be released in ratiometric amounts such as a quarter dosage, half dosage, or full dosage. Each ratiometric dosage may represent a different value. In this respect, use of ratiometric dosage effectively increases the range or resolution of values represented by the tracer. It must be noted that the dosages are not limited to a quarter dosage or a half dosage, but can be in any suitable amounts, such as one third, one fifth, or one sixth. In one embodiment, each of the ratiometric dosage may represent equal values. For example, if only one tracer is used, each quarter dosage may represent a value of 0.1 such that the full dosage may represent a value of 0.4. If multiple tracers are used, then ratiometric amounts of one tracer may be combined with ratiometric amounts of one or more other tracers to represent a value. In another embodiment, each partial ratiometric dosage may represent a smaller value within a range of values represented by the full dosage, thereby providing a higher resolution of the measured value. For example, if the full dosage represents a range between 0.2 to 0.3, then each quarter dosage may be 25% of the range.
The system may release a calibration dosage in order to determine the environmental effects on the tracer. The calibration dosage may be used to normalize the data for the ratiometric values. In this instance, the calibration dosage may be referred to as a normalization dosage. In one embodiment, the normalization dosage may be a full dosage of the tracer. The value measured at the surface for the full dosage may be used to determine the ratiometric dosage of the tracer released either after or before the normalization dosage. For example, if the measured value of the ratiometric dosage is about 33% of the measured value of the calibration dosage, then the ratiometric dosage released is a one-third dosage. After determining the ratiometric dosage, the represented value may be obtained. The normalization dosage may be released at any time such as before and/or after releasing the ratiometric dosage. The frequency of release of normalization dosage may be controlled based on time intervals, such as hourly, daily, or weekly. The normalization dosage may also be released based on a particular event, such as prior to measurement, upon receipt of a command sent downhole, or upon measurement of a particular range where a more specific value is desirable. In another embodiment, a unique code represented by the tracers may be released to signal a normalization dosage will be sent.
In another embodiment, the tracers may be modulated as a function of time, e.g, width modulation.
In one exemplary embodiment, the system shown in
In another embodiment, the ratiometric values may be used to further define a range, i.e., to obtain a higher resolution of the measured value. For example, each of the tracers B1, B2, B3 represents a range of 0.125 in to
In operation, if the water cut value is 0.33, then the controller 61 will release a normal dose of tracer B2 into the wellbore. At surface, the detection system will determine the water cut range is between 0.25 and 0.375, as represented by the detection of a full dosage of tracer B2. Thereafter, the detection system may send a command to the controller 61 to communicate a more specific value. In response, the controller 61 may initially release a calibration dosage of each of the tracers B1, B2, B3 into the wellbore. The value of the calibration dosage measured by the detection system may be used to determine the ratiometric value of the tracers. The controller 61 will then release a half dosage of each of tracer B1 and tracer B2 to represent the more specific value of the water cut. Upon detection by the detection system, the value of the tracers is compared to the value of the calibration dosage. The determination is then made that only half dosage of each of tracers B1, B2 has been released, thereby representing a water cut in the range of 0.325-0.35. In this manner, a more specific value of a wellbore parameter, e.g., water cut, can be obtained using a chemical communication system.
It is contemplated that chemical communication involving ratiometric amounts and/or time based modulation can be used by any suitable downhole tool, including any downhole tool described herein. For example, the position of the sleeve of a downhole valve as described above may be communicated using ratiometric or time based modulation.
In another embodiment, the chemical communication system may be configured to communicate data in portions, which when combined, represents the full data. In one embodiment, the chemical communication system can be used to serially communicate a digit of a value. For example, to communicate a value, one or more tracers may be used to represent numbers 0 to 9. If four tracers are used, they may be assigned the numbers as follows:
To communicate a pressure of 356 psi, the controller may initially release tracer F4 to represent the number 3 for the first digit in the pressure value. After waiting a period of time sufficient to avoid overlap of tracers between releases, the controller will release tracers F1 and F3 to represent the number 5 for the second digit of the pressure value. Thereafter, the controller will release tracers F1 and F4 to represent the number 6 for the third digit. At surface, the detection system will detect these tracers in the sequence that they are released and determine the digit represented by each tracer or combination of tracers. From the release sequence of the tracers, the detection system will determine the actual value communicated is 356 psi. Optionally, the release of the tracers may be repeated to obtain a second reading to verify the actual value. Another normalization dosage may be optionally released in between the first and second readings to renormalize the tracers' values. In yet another embodiment, the normalization dosage may be sent at the end of the communication to verify the data. In another embodiment, the digits may be communicated in reverse order, such as, units, then tenth, then hundredth, and thousandth.
In another embodiment, each of the digits may be represented by at least two tracers, as follows:
In another embodiment, the numbers may be represented by ratiometric dosages of the tracer, thereby reducing the number of tracers necessary for communication.
Embodiments of the chemical communication system may be used for communication between two downhole devices. In one embodiment, referring back to
In another embodiment, a command signal such as a coded fluid pressure pulse targeting a specific device may be used to sample one or more devices in a wellbore. Referring again to
In yet another embodiment, tracers may be released from the surface to communicate with one or more downhole device. The tracers may be coded to communicate with a particular device or a group of devices. The downhole devices may be equipped with a detection system to detect the tracers released from surface. For example, a tracer or combination tracers targeting inflow control device 111 may be released from the surface. Upon detection of the tracers, the inflow control device 111 may be triggered to communicate a wellbore parameter or data about itself. Because the tracers are coded for the inflow control device 111, the other inflow control devices will ignore the tracers and not respond. In this manner, two-way communication using the tracers may be performed.
In another embodiment, the chemical communication system may be used to communicate information about a downhole device. For example, the tracers may be used to communicate the condition of a battery in the downhole device. In one example, the tracers or combination of tracers may be used to represent the percentage of battery life remaining.
In another embodiment, the chemical communication system may be used to communicate information about the fluid regime in the wellbore. For example, a tracer may be released multiple times to travel uphole toward the detection system. The measured value of each release may be compared against the measured value of another release. If the measured values of the releases are consistent, then it may be an indication that the fluid regime in the wellbore is laminar. However, if the measured values of the releases vary, then it may be an indication that the fluid regime in the wellbore is turbulent or an indication that a leakage has occurred.
In another embodiment, a method of communicating a wellbore parameter from a downhole tool includes providing a plurality of tracers to represent a code for communicating a value of the wellbore parameter, wherein the code includes a plurality of code elements and wherein each code element is represented by a tracer or a combination of different tracers; measuring the value of the wellbore parameter using a sensor; correlating the measured value of the wellbore parameter to a code element; releasing the tracer or combination of different tracers representing the code element to travel upstream; detecting presence of the tracer or combination of different tracers; and determining the specific value or range of values of the wellbore parameter from the detected tracer or combination of different tracers.
In another embodiment, a method of communicating a wellbore parameter from a downhole tool includes providing a plurality of tracer chemicals, whereby a code comprising a plurality of code elements correlates to a release of a single tracer chemical or a unique combination of a subset of the plurality of tracer chemicals to a specific value or a range of values of the wellbore parameter; measuring a value of the wellbore parameter using a sensor; ascribing the measured value to a code element; releasing one or more of the plurality of tracer chemicals corresponding to the code element; detecting the presence of the one or more of the plurality of tracer chemicals; and determining the specific value or range of values of the measured wellbore parameter from the detection of the one or more of the plurality of tracer chemicals.
In one or more of the embodiments described herein, ascribing the measured value to a code element is performed downhole.
In one or more of the embodiments described herein, detecting the presence of one or more of the plurality of tracer chemicals is performed at a surface of the wellbore.
In another embodiment, a method of communicating a wellbore parameter from a downhole tool includes generating a code comprising a plurality of code elements, wherein each discrete code element correlates a specific value or a range of values of the wellbore parameter to a unique pattern of releasing one or more of a plurality of tracer chemicals; providing the plurality of tracer chemicals at a location in a wellbore; measuring a value of the wellbore parameter using a sensor; ascribing the measured value to a discrete code element of the code; releasing one or more of the plurality of tracer chemicals in a unique pattern corresponding to the discrete code element; detecting the presence of the one or more of the plurality of tracer chemicals in the unique pattern; and determining the specific value or range of values of the measured wellbore parameter from the detection of the one or more of the plurality of tracer chemicals.
In one or more of the embodiments described herein, the pattern comprises a simultaneous release of two or more of the plurality of tracer chemicals.
In one or more of the embodiments described herein, the pattern comprises a sequential release of two or more of the plurality of tracer chemicals.
In another embodiment, a method of communicating a wellbore parameter from a downhole tool includes providing the plurality of tracer chemicals at a downhole location in a wellbore; measuring a value of the wellbore parameter using a sensor; releasing one or more of the plurality of tracer chemicals in a unique pattern corresponding to the measured value of the wellbore parameter; detecting at a surface location of the wellbore the presence of the one or more of the plurality of tracer chemicals in the unique pattern; and determining the specific value or range of values of the measured wellbore parameter from the detection of the one or more of the plurality of tracer chemicals.
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This application claims benefit of U.S. Provisional Patent Application No. 61/624,850, filed Apr. 16, 2012; U.S. Provisional Patent Application No. 61/650,421, filed May 22, 2012; U.S. Provisional Patent Application No. 61/798,767, filed Mar. 15, 2013; and U.S. Provisional Patent Application No. 61/800,614, filed Mar. 15, 2013; which applications are incorporated herein by reference in their entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/US2013/036839 | 4/16/2013 | WO | 00 |
Number | Date | Country | |
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61800614 | Mar 2013 | US | |
61798767 | Mar 2013 | US | |
61650421 | May 2012 | US | |
61624850 | Apr 2012 | US |