Method and apparatus for peeling a thin film from a liner

Abstract

A method and apparatus are provided for peeling a thin film, typically 100 microns or less in thickness, from a liner by use of a rotatable peel rod supported in an air bearing. The air bearing comprises a support plate having arcuate surfaces which are substantially coaxial with a cylindrical film-bearing segment of the peel rod. Air openings in the arcuate surfaces conduct a flow of air into an air bearing gap between the arcuate surfaces and the peel rod.

Description

FIELD OF THE INVENTION

[0001] This invention relates to a method and apparatus for peeling a thin film, typically 100 microns or less in thickness, from a liner by use of a rotatable peel rod supported in an air bearing.

BACKGROUND OF THE INVENTION

[0002] U.S. Pat. Nos. 5,556,499 and 5,762,753 disclose a peeler-delaminator method and apparatus employing a peel bar supported in a solid bearing that provides continuous bearing contact with the peel bar. The references also describe a peel bar bearing that includes an abrasive surface for continuously scrubbing the peel bar.

SUMMARY OF THE INVENTION

[0003] Briefly, the present invention provides an apparatus for removing a film from a liner that includes a rotatable peel rod supported in an air bearing. The air bearing comprises a support plate having arcuate surfaces which are substantially coaxial with a cylindrical film-bearing segment of the peel rod. Air openings in the arcuate surfaces conduct a flow of air into an air bearing gap between the arcuate surfaces and the peel rod.

[0004] In another aspect, the present invention provides a method for removing a film from a liner comprising the steps of passing a bilayer of a film and a liner over a rotatable peel rod supported in an air bearing, such that the film contacts the peel rod, and peeling the film from the liner. The film typically has a thickness of 100 microns or less.

[0005] What has not been described in the art, and is provided by the present invention, is a method and apparatus that employs a rotatable peel rod supported in an air bearing to peel a delicate or thin film from a liner.

[0006] It is an advantage of the present invention to provide a method and apparatus that facilitates the use of rolls of thin cast film in an automated manufacturing process.

BRIEF DESCRIPTION OF THE DRAWING

[0007] FIG. 1 illustrates a peeling mechanism according to the present invention.

[0008] FIG. 2 is a cross-section of the peeling mechanism depicted in FIG. 1.

[0009] FIG. 3 is a detail of FIG. 2 demonstrating the peel rod according to the present invention.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

[0010] With reference to FIGS. 1, 2 and 3, a peeling apparatus according to the present invention comprises frame members 10, 11, 12 and 13, which together form a supporting frame. Peel rod support plate 40 is attached to one or more of frame members 10, 11 and 12. Peel rod support plate 40 comprises arcuate surfaces 41 and 42 for receiving peel rod 50. Peel rod 50 is essentially cylindrical in its film-bearing middle segment. Peel rod 50 may be essentially cylindrical throughout it's length, or may have non-cylindrical end segments such as rounded ends or other adaptations for interaction with end caps 60 and 61. End caps 60 and 61 prevent escape of peel rod 50, which might otherwise occur either by transverse motion of peel rod 50, or by the absence of film 90, which might occur, e.g., at the end of a run. End caps 60 and 61 may comprise bearings for each end of peel rod 50, such as a needle bearings. End caps 60 and 61 may be attached to frame members 11 and 12 or to peel rod support plate 40, or to both. Where end caps 60 and 61 comprise bearings for each end of peel rod 50, end caps 60 and 61 may be attached to frame members 11 and 12 or to peel rod support plate 40 by a sliding attachment allowing motion of peel rod 50 closer or farther from air bearing gaps 51 and 52.

[0011] The curve of each arcuate surface 41 and 42 is substantially coaxial with the curve of the essentially cylindrical film-bearing middle segment of peel rod 50. In use, air bearing gaps 51 and 52 separate arcuate surfaces 41 and 42 from peel rod 50. Air is driven into air bearing gaps 51 and 52 through air openings, which may comprise a groove 43 separating arcuate surfaces 41 and 42, the groove 43 traversing substantially the entire length of the air bearing gap 51, 52 along the length of the film-bearing segment of peel rod 50. In another embodiment, the air openings might comprise a series of holes. The groove 43 or other air openings are fed by one or more air channels 44, which in turn are fed by air channels 101, 102 in manifold block 100 attached to peel rod support plate 40. Any suitable source of super-ambient air pressure may be used to feed air channels 44, 101, 102, such as an air pump. Any suitable level of air pressure or any suitable air flow rate may be used, provided that a suitable air bearing gap is maintained during operation.

[0012] Liner support roller 30 and film idler roll 20 are rotatably attached to frame members 11 and 12. Liner support roller 30 is positioned adjacent to peel rod 50 so as to form a nip. Film idler roll 20 is positioned so as to receive film 90 passing over peel rod 50 and maintain film 90 in a stable orientation relative to peel rod 50.

[0013] In operation, a bilayer 70 which comprises a liner 80 bearing a film 90 is directed into the nip formed by liner support roller 30 and peel rod 50. While liner 80 maintains contact with liner support roller 30, film 90 is peeled from liner 80 and follows the surface of peel rod 50. Peel rod 50 rotates as film 90 passes over peel rod 50. Film idler roll 20 receives film 90 passing over peel rod 50 and maintains film 90 in a stable orientation and tension relative to peel rod 50. Typically, the present apparatus is driven by a pulling force applied to a liner 80 by any suitable drive means. In addition, liner support roller 30 may also be driven.

[0014] The method according to the present invention is used to advantage with delicate or thin films. Typically, the present method may be used to peel films of 100 micrometers thickness or less, more typically 50 micrometers thickness or less, and more typically 30 micrometers thickness or less. The method according to the present invention may be used to advantage with films of polymer electrolyte membranes that are cast on a liner, including sulfonated fluoropolymer membranes such as Nafion™ or Flemion™. Any suitable liner may be used, including any suitably flexible polymeric sheet materials having a thickness of typically less than 1 millimeter, more typically less than 0.5 millimeter, and more typically less than 0.2 millimeter. Films may be cast from a solution or suspension of the film polymer by any suitable method, including coating or casting methods including bar coating, spray coating, slit coating, brush coating, and the like. Since the cast film may have uneven edges, the cast film may be cut on one or more edges to provide a clean edge. Typically, a continuous web of cast film can be die cut to provide clean side edges using controlled-depth die cutter.

[0015] This invention is useful in the manufacture of goods, such as membrane electrode assemblies used in fuel cells, from membranes of polymer electrolytes that are cast on a liner as thin films of 30 micrometer thickness or less.

[0016] Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and principles of this invention, and it should be understood that this invention is not to be unduly limited to the illustrative embodiments set forth hereinabove. All publications and patents are herein incorporated by reference to the same extent as if each individual publication or patent was specifically and individually indicated to be incorporated by reference.

Claims

1. An apparatus for removing a film from a liner comprising a rotatable peel rod supported in an air bearing.

2. The apparatus according to claim 1 wherein said peel rod comprises a film-bearing segment which is essentially cylindrical and has a center axis, and wherein said air bearing comprises a support plate having one or more arcuate surfaces which are substantially coaxial with said film-bearing segment of said peel rod, said support plate comprising one or more air openings in said arcuate surfaces for conducting a flow of air into an air bearing gap between said arcuate surfaces and said film-bearing segment of said peel rod.

3. The apparatus according to claim 2 additionally comprising a source of super-ambient air pressure functionally connected to said air openings so as to provide a flow of air into said air bearing gap.

4. The apparatus according to claim 3 wherein said air openings comprise a groove in said arcuate surface traversing substantially the entire length of said air bearing gap.

5. The apparatus according to claim 4 additionally comprising a liner support roller positioned adjacent to said peel rod so as to form a nip.

6. The apparatus according to claim 5 additionally comprising a film idler roll positioned so as to receive a film passing over said peel rod and maintain said film in a stable orientation relative to said peel rod.

7. The apparatus according to claim 6 additionally comprising a frame to which said film idler roll is rotatably attached, to which said liner support roller is rotatably attached, and to which said support plate is fixedly attached.

8. A method for removing a film from a liner comprising the steps of: passing a bilayer of a film and a liner over a rotatable peel rod supported in an air bearing such that said film contacts said peel rod; and peeling said film from said liner.

9. The method according to claim 8 wherein said peel rod comprises a film-bearing segment which is essentially cylindrical and has a center axis, and wherein said air bearing comprises a support plate having one or more arcuate surfaces which are substantially coaxial with said film-bearing segment of said peel rod, said support plate comprising one or more air openings in said arcuate surfaces for conducting a flow of air into an air bearing gap between said arcuate surfaces and said film-bearing segment of said peel rod.

10. The method according to claim 9, wherein said air openings comprise a groove in said arcuate surfaces traversing substantially the entire length of said air bearing gap.

11. The method according to claim 10, wherein said air openings are functionally connected to a source of super-ambient air pressure such that a flow of air into said air bearing gap is provided.

12. The method according to claim 11 wherein said step of passing a bilayer of a film and a liner over a rotatable peel rod comprises passing said bilayer into a nip formed between said peel rod and a liner support roller positioned adjacent to said peel rod.

13. The method according to claim 12, wherein contact is maintained between said liner and said liner support roller during said peeling step.

14. The method according to claim 13 additionally comprising the step of passing said film peeled from said liner over a film idler roll positioned so as to maintain said film in a stable orientation relative to said peel rod during said peeling step.

15. The method according to claim 8 wherein said film has a thickness of 100 micrometers or less.

16. The method according to claim 9 wherein said film has a thickness of 100 micrometers or less.

17. The method according to claim 12 wherein said film has a thickness of 100 micrometers or less.

18. The method according to claim 8 additionally comprising the step of casting said film on said liner.

19. The method according to claim 9 additionally comprising the step of casting said film on said liner.

20. The method according to claim 12 additionally comprising the step of casting said film on said liner.

21. The method according to claim 18 additionally comprising a step of cutting the cast film on one or more edges so as to provide a clean edge prior to removing said film from said liner.

22. The method according to claim 19 additionally comprising a step of cutting the cast film on one or more edges so as to provide a clean edge prior to removing said film from said liner.

23. The method according to claim 20 additionally comprising a step of cutting the cast film on one or more edges so as to provide a clean edge prior to removing said film from said liner.

24. The method according to claim 8 wherein said film is a polymer electrolyte membrane.

25. The method according to claim 9 wherein said film is a polymer electrolyte membrane.

26. The method according to claim 12 wherein said film is a polymer electrolyte membrane.