Information
-
Patent Grant
-
6409790
-
Patent Number
6,409,790
-
Date Filed
Friday, March 16, 200123 years ago
-
Date Issued
Tuesday, June 25, 200222 years ago
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Inventors
-
Original Assignees
-
Examiners
Agents
-
CPC
-
US Classifications
Field of Search
US
- 075 486
- 075 500
- 075 501
- 075 502
- 075 503
- 075 553
- 075 1012
- 075 1014
- 075 1015
- 075 378
- 266 144
- 266 89
- 266 149
- 373 140
-
International Classifications
-
-
Disclaimer
Terminal disclaimer
Abstract
An energy efficient, coal-based method and apparatus that are environmentally friendly which produce under pressure metallized/carbon product and molten metal directly from abundant coal or other carbonaceous material, and low cost fines (or ore concentrate) wherein the metal is devoid of gangue material and possesses the inherent advantage of retaining the heat for subsequent processing. This method and apparatus which are modular and highly integrated significantly reduce capital and operating costs; they also provide the capability selective placement of the reductant for the delivery of high levels of thermal energy input which leads to ease of desulflurization and high productivity. The technology herein disclosed is entirely closed and is applicable to various ores including ferrous and non-ferrous.
Description
INTRODUCTION
This invention relates to the production of metals from metallic oxides by making use of a carbonaceous material in furtherance of the disclosure contained in applicants' pending application bearing Ser. No. 09/241,649 filed on Feb. 1, 1999 now U.S. Pat. No. 6,214,085 and assigned to Art Unit 1742. Specifically this invention incorporates further developments to the subject matter disclosed in the referenced application particularly with respect to the feeding of raw materials, the heating of same, and reacting these raw materials with one another. Also additional developments are herein disclosed with respect to melting and slagging operations in order to provide an efficient integrated process and apparatus to practice same that are environmentally friendly and cost-competitive in the production of metals.
BACKGROUND
It is well known that existing methods to process raw metallic materials into ferrous and non-ferrous products are inefficient, polluting and very costly to finance, to operate and to maintain. Further, there are issues which relate to health hazards that affect workers in these fields by virtue of exposure to extremely high temperatures, and inhalation of injurious dusts and foul gases.
The method and apparatus disclosed herein have applicability to the processing of various metallic ores such as ores of iron, aluminum, copper, etc. including dusts, wastes and reverts of such metallic materials. Since iron ore is such a dominant feedstock in the field of metallurgy, by way of example, the disclosure in this application will focus on the processing of iron ore termed “carbotreating” with a carbonaceous material such as coal to produce an iron/carbon product which is melted with an oxidant termed “oxymelting” to make a molten iron.
OBJECTIVE OF THE INVENTION
The main object of this development is to provide a method and apparatus which are energy efficient to reduce greenhouse gases.
Another object of the instant invention is to provide a method and apparatus that are environmentally closed which will allow ease of permitting and acceptance by various entities including environmental protection agencies and the public.
Still another object of this invention is to provide a functionally efficient method and apparatus to practice same in order to produce a low cost product to enable industry to survive in a competitive global market.
Further still another object of this invention is to provide a method and apparatus that require low capital investment to enable industry to finance facilities and create jobs.
Further yet another object of this invention is to provide a method and apparatus that are not injurious to employees both from the standpoint of hazardous working conditions and long term deleterious effects regarding health.
Other objects of this invention will appear from the following description and appended claims. Reference is made to the accompanying drawings which describe certain apparatus structures to practice this method of making metallic units, and as they relate to making iron in the form of directly reduced iron, hot briquetted iron, iron/carbon product and molten iron. The molten iron may subsequently be converted into steel directly while molten or cast into pigs which are cooled and then transported as a solid to a processing plant. It is to be understood that the method and apparatus disclosed herein are not solely limited to the processing of iron bearing materials.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1
is a representation of the equipment used to carry out the method to make a metallized/carbon product which is then melted to make molten metal.
FIG. 2
is a section taken at
2
—
2
of a reactor shown in
FIG. 1
, within which the carbotreating takes place.
FIG. 3
is a variation of the reactor chamber shown in FIG.
1
.
FIG. 4
is an end view of
FIG. 1
, showing a plurality of reactors discharging into a single melter/homogenizer.
FIG. 5
is a configuration to produce directly reduced iron units and cooling such units before discharge into the atmosphere.
FIG. 6
is still another configuration to produce iron units which are brigquetted prior to their discharge into the atmosphere.
FIG. 7
represents discharging hot reduced metallic units into a container which is insulated and sealed to conserve energy and prevent re-oxidation.
FIG. 8
is a representation of the feed of materials into the system with sequential steps
8
-
1
through
8
-
6
showing various positions of the equipment to effect the feed wherein a core of fuel is created and such core is surrounded by the ore to be reduced.
FIG. 9
is a section taken at
9
—
9
of FIG.
8
.
Before describing in detail the present invention, it is to be understood that this invention is not limited to the details or the arrangement of the parts illustrated in the attached drawings, as the invention can be made operative by using other embodiments. Also it is to be understood that the terminology herein contained is for the purpose of description and not limitation.
DETAILED DESCRIPTION OF THE DRAWINGS
Referring to
FIG. 1
, numeral
10
denotes a reactor where the treating of iron ore with coal takes place to make an iron/carbon product; this treatment of the ore is hereinafter referred to as “carbotreating”. Numeral
11
denotes a melter/homogenizer where the iron/carbon product is melted with an oxidant to make molten metal and slag, hereinafter referred to as “oxymelting”. A standpipe denoted by numeral
12
is connected to melter/homogenizer
11
. A metal reservoir is provided for receiving the molten metal and the slag and is denoted by numeral
13
. Referring to
FIG. 4
, a storage system to contain the raw materials is denoted by numeral
14
; it comprises hoppers
58
,
59
and
60
to store feed materials such as ore, coal and flux respectively. A raw material mixer denoted by numeral
61
serves to blend the feed materials as they are conveyed to lockhopper
36
which is in turn equipped with upper valve
84
and lower feed control
62
.
Referring back to
FIG. 1
for a more detailed description of the structure that enables the method to be practiced, reactor
10
consists of a pushing device denoted by numeral
15
which is equipped with ram
16
at the charging end of reactor
10
, that serves to push the blended charge dropped from hopper
36
into cavity
17
. Ram
16
actuated by pushing device
15
, compresses the charge and advances it within a process chamber which is marked by numeral
28
and which is tapered along its length. Process chamber
28
is connected to cavity
17
, and is made-up of a pressure shell marked by numeral
26
, insulation
27
and wall heating element
25
. Burner
19
in turn communicates with heating element
25
via inlet port
29
. Heating element
25
is equipped with passages shown by numeral
53
in
FIG. 2
; they serve as a conduit to direct hot gases from burner
19
through inlet
29
to flow through passages (flues)
53
along the length of process chamber
28
and exit the chamber via outlet
30
. The discharging end of chamber
28
which is marked by numeral
20
attaches to elbow
21
. Elbow
21
is designed in such a way as to have reflective wall
23
backed by insulation and contained within a pressure casing, in order to form a radiant zone to reflect intense thermal energy against the material that is being carbotreated at discharging end
20
. A first lance (or a plurality of same) denoted by numeral
22
is mounted into elbow
21
; lance
22
is adapted to be advanced towards or retracted from the material being processed. Controller
24
serves to control air/oxygen and coolant to make lance
22
operative. Lance
22
may also contain fuel for start-up purposes.
Reactor
10
communicates with melter/homogenizer
11
by means of transition
32
that directs the reduced material (the iron/carbon product) from chamber
28
to melter/homogenizer
11
which comprises shell
85
, lining
86
, top
87
and bottom
88
. A second lance denoted by numeral
34
serves to supply oxidant in the form of air or oxygen (or a combination of the two) in order to react with the carbon in the iron/carbon product and with gases produced within the process to supply the heat needed to melt the reduced iron in the iron/carbon product to yield a molten iron
42
and a molten slag
43
which floats on top of molten iron
42
. Lance
34
which is kept cool, is raised and lowered by means of hoist
39
for adjusting its level to the working height within melter/homogenizer
11
. A drain/port denoted by
31
and disposed at the bottom of melter/homogenizer
11
, connects to standpipe
12
. Through drain/port
31
, the gasses, the molten iron and the molten slag flow. An off-gas discharge marked by numeral
47
is provided to standpipe
12
to divert a sidestrearn of such gases for control purposes which are directed to cyclone
46
via collecting main
37
. Both the molten iron and the molten slag drop into reservoir
13
while the bulk of the gases flows with the iron and slag. Cyclone
46
communicating with discharge
47
, removes particulate matter from the off-gas. The bottom of cyclone
46
is furnished with surge hopper
40
which feeds into lockhopper
41
; control valves
44
and
45
lock & unlock lockhopper
41
in order to discharge the particulate matter collected into bin
33
which is recycled with the materials charged into reactor
10
. A pressure controller denoted by numeral
50
which controls the back pressure of melter/homogenizer
11
and reactor
10
and standpipe
12
is located downstream of cyclone
46
; the side stream leaves the system via duct
49
for further treatment in a gas treatment facility which is not shown, but known in the art.
Bottom
88
of melter/homogenizer
11
is configured as a cone with drain/port
31
making connection with standpipe
12
which in turn makes connection with metal reservoir
13
in a submerged mode. Induction heating coil means denoted by numeral
35
is provided, to supply auxiliary heat to insure that molten metal and molten slag do not freeze when leaving melter/homogenizer
11
. In the event such freezing takes place especially when melter/homogenizer
11
is shut down, induction heating means
35
is energized to melt the frozen iron and slag. The lining of standpipe
12
is made of such material that would couple with induction heating means
35
. Metal reservoir
13
consists of a lined chamber adapted to rotate about roller segment bed
93
to effect the pouring of molten iron
42
via tap hole
55
into ladle
51
, and slag
43
via spout
54
into pot
52
.
Referring to
FIG. 3
, numeral
10
is a modified configuration wherein heating element
25
along the length of chamber
28
, is obviated. In this configuration the heat input is via lance
22
which is adapted to bore into bed
28
by means of an oxidant after ignition takes place. Lance
22
is equipped with an injection tip denoted by numeral
48
which may have multi-directional nozzles to inject oxidant in several directions. Auxiliary oxidant orifices shown by numeral
92
are provided to lance
22
to combust coal and coke in the mixture, as well as gases generated from the coal in the charge. Heating chamber
28
, may be made as a composite structure of which part is metallic as noted by numeral
117
and part refractory as noted by numeral
27
.
Referring again to
FIG. 4
which is a configuration wherein a plurality of reactors such as reactor
10
, are mounted side by side to form a battery denoted by numeral
104
, with reactors
10
discharging iron/carbon product into common melter/homogenizer
11
. Reactor
10
which is situated at ground level serves as a spare. A crane denoted by numeral
63
, may be added to service battery
104
.
In
FIG. 5
, the invention is configured to make directly reduced iron (DRI) or iron/carbon product which can be melted off-site. Numeral
10
is the reactor with a downstream surge hopper denoted by numeral
64
which is followed by cooler
65
. Cooler
65
may take one of several known approaches including a cooled screw feeder shown by numeral
38
. The cooler feeds the cooled DRI or iron/carbon product into surge hopper
66
. Below surge hopper
66
, a lockhopper denoted by numeral
67
makes possible the discharging of product DRI or iron/carbon product in a sealed manner into the atmosphere and onto conveyor
70
by making use of valves
68
and
69
. A cyclone similar to cyclone
95
shown in FIG.
6
and described hereunder, may be used for separation of entrained particulate matter.
Referring to
FIG. 6
, numeral
10
is the reactor and numeral
21
is the elbow. Beneath elbow
21
a transition denoted by numeral
94
is provided through which the carbotreated material is discharged via downcomer
73
into hot-briquetter
71
which is adapted to form briquettes from the carbrotreated material. A screw feed denoted by numeral
72
is disposed upstream of briquetter
71
to control the feed into the briquetter. Beneath briquetter
71
, surge hopper
74
followed by lockhopper
75
are provided to discharge the formed briquettes into the atmosphere and onto conveyor
70
. Valves
76
and
77
serve to lock and unlock lockhopper
75
.
Adjacent to transition
94
, cyclone
95
is mounted by making use of pipe
78
, in such a way as to pass hot gasses through cyclone
95
in order to remove particulate matter from the gasses. Transition
94
which is equipped with impact surfaces such as cascading baffles
89
tend to breakup the hot carbotreated material to release excess particulate matter; such matter which remains entrained in the off-gases, is disengaged in a cyclone denoted by numeral
95
. Cyclone
95
is equipped with pressure control means
98
, and surge hopper
96
is followed by lockhopper
97
. Collecting bin
79
is disposed below lockhopper
97
for receiving the particulate matter removed from the gases, which is recycled (not shown).
Referring to
FIG. 7
, a box denoted by numeral
118
may be provided beneath lockhopper
75
to contain the iron/carbon product and be transported by any one of known means such as a lift-truck for further processing. Box
118
is designed in such a way as to be insulated to accept hot product in order to conserve thermal energy and prevent re-oxidation of the product.
Reference is now made to
FIG. 8
for the description of the structure to feed the carbonaceous material as a core which is surrounded by the metallic ore. A materials storage arrangement is provided and denoted by numeral
80
which comprises hopper
81
to contain the carbonaceous material (fuel) and hopper
82
to contain the ore. Feeders
101
and
102
control the flow of the fuel and ore from hoppers
81
and
82
respectively. Valves
103
and
105
service lockhopper
81
and valves
104
and
106
service lockhopper
82
. Charging tube
83
is provided at the bottom of materials storage
80
, which is flanked by charging device
90
on one side and reactor
10
on the other side. Charging device
90
is made up of a pushing ram denoted by numeral
99
and pushing plunger
100
with ram
99
being advanced and retracted by actuator means such as cylinders
107
, and plunger
100
being advanced and retracted by actuator means such as cylinder
108
thus providing independent motion to either ram
99
or plunger
100
, with plunger
100
being housed within ram
99
which is annular in configuration and which is in turn housed within charging tube
83
. Ram
99
passes a charging hole
109
to permit the fuel to be dropped into a cavity when plunger
100
is in the retracted position. During the detailed description of the operation for the formation of the core which follows, further clarification will be disclosed with the aid of
FIGS. 8-1
through
8
-
6
.
DETAILED DESCRIPTION OF OPERATION
In explaining the operation of the method and apparatus disclosed herein, the description will be as follows:
(i) Mode of feeding ore and coal, and of heating such materials for carbotreating the ore to yield a metallized/carbon product; and
(ii) Melting the metallized/carbon product to yield molten metal via oxymelting.
With respect to carbotreating wherein a core of fuel is formed in the charged metallic oxide (ore), reference is made to
FIG. 8
, its sequential
FIGS. 8-1
through
8
-
6
, and FIG.
9
. In
FIG. 8-1
both ram
99
and plunger
100
are shown in the advanced position with the core of fuel being denoted by numeral
110
and the oxide surrounding it being denoted by numeral
111
. Plunger
100
is retracted to the position shown in
FIG. 8-2
by means of cylinder
108
while retaining ram
99
in the advanced position. A metered amount of fuel (coal) marked by numeral
112
is dropped into cavity
113
via charging hole
109
. Plunger
100
is then advanced part way to push fuel
112
towards that core of fuel which had been charged and compacted during the previous cycle as shown by
FIG. 8-3
. Next, ram
99
is retracted using the full stroke of cylinders
107
while plunger
100
is parked at the part way advanced position. A metered amount of oxide marked by numeral
114
, is dropped into cavity
115
as shown by
FIG. 8-4
which cavity surrounds plunger
100
. Following this step both ram
99
and plunger
100
are simultaneously advanced; initially, the loose materials begin to be compacted as shown in
FIG. 8-5
by numeral
116
, and as the advancement of ram
99
and plunger
100
proceeds the fuel and the oxide become fully compacted with the core being formed within the oxide with the oxide fully surrounding the core of fuel; the stroke of both ram
99
and plunger
100
keeps advancing after compaction and the entire contents of reactor
10
begin to move to result in hot metallized/carbon product being discharged from the discharging end of reactor
10
as illustrated in
FIG. 8
; the discharge of such product stops when ram
99
and plunger
100
are fully stroked to the advanced position. At the end of the stroke of ram
99
and plunger
100
, the relationship of the ram and the plunger is shown in
FIG. 8-6
which is the same as that shown in
FIG. 8-1
. At this point the cycle is completed. The formation of a fuel core
110
proceeds cyclically to result in providing core
110
being surrounded by oxide
111
shown in cross section in FIG.
9
. This repetitive cycle thus provides a core of fuel being surrounded with oxide along the length of chamber
28
of reactor
10
.
The operation of carbotreating with reference to
FIGS. 1
,
3
and
4
is as follows:
Assuming that the method is already at steady state and at pressure, and the ore (preferably in fine, concentrated form), the coal and the flux contained in materials delivery system
14
, are proportionately mixed and fed as a mixture via hopper
36
, into cavity
17
of process chamber
28
. Ram
16
is then actuated via pushing device
15
to compact the mixture to such an extent as to make it substantially impervious as shown by the densified representation (numeral
18
) at the charging end of reactor
10
. As the mixture is advanced in chamber
28
of reactor
10
, it is heated by any of the following manners of heating; namely, radiation, conduction, convection or any combination of these systems to cause the evolution of gases from the coal with the imperviousness of the mixture forcing the gases to flow within chamber
28
towards discharging end
20
. A portion of these gases is combusted at the discharging end to provide a highly radiant zone to reflect intensive thermal energy to the mixture to heat the mixture to such a temperature as to cause the oxygen in the ore to react with the highly reducing gases liberated from the coal and/or with residual carbon from the coal to reduce the ore to metallized iron. To enhance the heat transfer to the mixture, lances such as lance
22
are provided, which lances are adapted to inject an oxidant in the form of air, oxygen or a combination of both into the mixture of materials within chamber
28
, as this mixture advances in chamber
28
. Further these lances which are kept cool by means of a coolant are also adapted to be advanced and retracted for optimal heat transfer. Variations of oxidant lance injection may also take the form of penetration into the mixture itself as shown by
FIGS. 1 and 3
, with supplementary jets of oxidant (see number
92
) for post-combustion to further enhance heat transfer into the mixture. In the event that no conductive heat through the wall of chamber
28
is furnished, lance
22
may take the form of an oxygen-fuel (coal, gas or oil) burner to initiate the combustion and with the provision that once ignition of the coal gases and the carbon in the coal becomes stable the fuel input from the lance is shut-off, and the coal and its gases supplying the thermal energy needed for sustaining the reactions thus producing the iron/carbon product which is discharged into melter/homogenizer
11
. An alternate arrangement may be the supply of the fuel through lance
22
such as the injection of pulverized coal onto the ore or a combination of the arrangements described herein and others which are known in the art.
The iron/carbon product made by this method is relatively light as compared to the bulk density of iron ore and especially as compared to molten metal; further, the size of the iron/carbon product as it is discharged from reactor
10
is diverse in size and non-uniform. When such product is discharged into a melter containing molten metal and slag, the iron/carbon product tends to float on top of the slag and the molten metal causing delays in productivity and loss of energy by the inability to readily get the iron/carbon product into solution. It is for this purpose that a melter which also acts as a homogenizer devoid of a bath of molten metal and molten slag is provided which takes the form of melter/homogenizer
111
which is capable of draining the molten iron and molten slag as they are formed.
The oxymelting of the metallized/carbon product will now be described by making reference to FIG.
1
. Within melter/homogenizer
11
, lance
34
provides the oxidant to melt the hot iron/carbon product being fed from reactor
10
via downcomer
32
. The oxidant reacts with gases and with carbon from the carbotreating step to cause an intensive energy release which melts the iron in the iron/carbon product, the gangue which was part of the iron oxide, the ash of the coal as well as the flux/desuilirizer material used as additive, to result in making a molten iron and a molten slag, this combination continuously leaves melter/homogenizer
11
via drain/port
31
together with the various hot, pressurized gases produced. Such gases flowing through drain/port
31
keep the molten iron and the slag flowing out of melter/homogenizer
11
and into reservoir
13
by making use of standpipe
12
whose tip is submerged in the molten metal within reservoir
13
; this submergence provides a liquid seal which maintains the pressure in the system.
By means of control valve
50
the back pressure in reactor
10
, melter/homogenizer
11
and standpipe
12
is balanced while the gases generated during carbotreating in reactor
10
and the gases generated during oxymehing in melter/homogenizer
11
are guided together with the molten metal and molten slag to reservoir
13
where such gases bubble out of the bath and are combusted for additional energy release by injecting an oxidant through nozzle
119
. The off-gas is collected in hood
120
for treatment not shown but known in the art. The metallic dust, carbon and ash entrained in such gases remain in the bath by virtue of the bath serving as a wet scrubber which increases the yield of the molten metal. A side stream of such gases flowing through main
37
, is used for pressure control by means of valve
50
and are directed to cyclone
46
via discharge
47
for treatment. The particulate matter separated in cyclone
46
is recycled with the feedstocks and auxiliary heat if needed, is maintained in standpipe
12
by means of induction heating
35
. The operation in reactor
10
and in the melter/homogenizer
11
is intentionally maintained reducing to prevent re-oxidation of the iron and minimizing the formation of NO
x
and CO
2
, while providing efficient desulfurizing conditions to remove the sulfur which originates from the coal.
With respect to the application of this invention to the non-ferrous metals, variations to that which is disclosed may take place; however, the intention is not to depart from the spirit of this disclosure. All in all, it is submitted herein that the instant invention provides major improvement over conventional practice/metallurgy, which can use low cost raw materials, and which is energy efficient, environmentally friendly and requiring low capital investment.
Claims
- 1. A method for thermally processing a metallic oxide with a carbonaceous material in one or more chambers, wherein each of the one or more chambers has a charging end and a discharging end, to produce a hot metallized/carbon product which is subsequently melted in a melter to make a molten metal and a molten slag, comprising:feeding the metallic oxide and the carbonaceous material to the charging end of said one or more chambers and forcing the metallic oxide and the carbonaceous material toward the discharging end of said one or more chambers; injecting an oxidant in such a way as to utilize at least a portion of the energy contained in said carbonaceous material to release thermal energy and produce pressurized reducing gases to reduce the metallic oxide to form a hot metallized/carbon product; discharging said hot metallized/carbon product from said one or more chambers into the melter; heating the metallized/carbon product in the melter to produce a hot pressurized off-gas, a molten metal and a molten slag; and segregating the off-gas, the molten slag and the molten metal.
- 2. A method for thermally processing a metallic oxide with a carbonaceous material in one or more chambers, wherein each of the one or more chambers has a charging end and a discharging end, to produce a hot metallized/carbon product which is subsequently melted in a melter to make a molten metal and a molten slag, comprising:feeding the metallic oxide and the carbonaceous material to the charging end of said one or more chambers in such a way as to form a core with an annulus surrounding the core for the efficient reaction of the metallic oxide with the carbonaceous material, and forcing the metallic oxide and the carbonaceous material toward the discharging end of said one or more chambers; injecting an oxidant in such a way as to utilize at least a portion of the energy contained in said carbonaceous material to release thermal energy and produce pressurized reducing gases to reduce the metallic oxide to form a hot metallized/carbon product; discharging said hot metallized/carbon product from said one or more chambers into the melter; heating the metallized/carbon product in the melter to produce a hot pressurized off-gas, a molten metal and a molten slag; and segregating the off-gas, the molten slag and the molten metal.
- 3. The method set forth in claim 2 wherein the step of injecting an oxidant includes the injection of the oxidant into the discharging end of said one or more chambers.
- 4. The method set forth in claim 1 wherein a group of chambers are assembled together in battery form, with each chamber being a separate module for ease of scale-up and maintenance.
- 5. The method set forth in claim 1 wherein the heating of the metallized/carbon product in said melter comprises the step of consuming at least a portion of the carbon in said melter.
- 6. The method set forth in claim 1 further comprising, controlling pressure to maintain the steps of the method in balance.
- 7. The method set forth in claim 1 further comprising providing induction heating as supplemental heating to the melter.
- 8. The method set forth in claim 7 comprising adding an oxidant to supplement said induction heating.
- 9. The method set forth in claim 1 wherein the oxidant is substantially pure oxygen.
- 10. The method set forth in claim 1 wherein the oxidant comprises air.
- 11. The method set forth in claim 1 wherein the oxidant is air enriched with oxygen.
- 12. The method set forth in claim 1 further comprising providing a radiant heating zone downstream from the discharging end of said one or more chambers to reflect thermal energy towards the materials being processed in order to efficiently transfer heat by radiation to accelerate the conversion of said metallic oxide into a metallized/carbon product.
- 13. The method set forth in claim 1 further comprising heating said chamber by passing hot gases through flues provided in the wall of said chamber to additionally heat the materials in the chamber by conduction.
- 14. The method set forth in claim 1 wherein additional energy is introduced in said radiant zone by combusting gases therein to further accelerate the reduction of said metallic oxide.
- 15. The method set forth in claim 1 wherein the materials in said chamber are advanced and discharged from said chamber in such a way as to repeatedly provide a new face of the materials being processed at the discharging end of said chamber.
- 16. The method set forth in claim 1 further comprising guiding the molten metal and molten slag into a reservoir.
- 17. The method set forth in claim 16 further comprising guiding the molten metal and molten slag into a reservoir in a submerged mode to provide a liquid seal.
- 18. The method set forth in claim 1 wherein the method is environmentally closed to prevent polluting emissions.
- 19. The method set forth in claim 1 wherein said chamber includes a tapered portion that diverges towards the discharge end of said chamber.
- 20. The method set forth in claim 1 wherein the metallic oxide is comprised of an iron oxide.
- 21. The method set forth in claim 1 wherein the carbonaceous material is comprised of coal.
- 22. The method set forth in claim 1 further comprising guiding the molten metal and molten slag to a reservoir together with a flow of gases that are combusted to release thermal energy.
- 23. The method set forth in claim 1 further comprising homogenizing the molten metal in said melter.
- 24. The method set forth in claim 1 further comprising homogenizing the molten metal into iron.
- 25. The method set forth in claim 1 further comprising honogenizing the molten metal into steel.
- 26. The method set forth in claim 1 including the injecting of the oxidant by means of a lance.
- 27. The method set forth in claim 1 including the injecting of the oxidant by means of a plurality of lances.
- 28. The method set forth in claim 1 further comprising the addition of a flux material to the metallic oxide and carbonaceous material.
- 29. The method set forth in claim 1 further comprising the addition of a desulfturizing material to the metallic oxide and carbonaceous material.
- 30. The method set forth in claim 1 further comprising including at least a portion of said carbonaceous material in the metallic oxide to form a mix.
- 31. The method set forth in claim 1 further comprising charging said carbonaceous material into said chamber in such a way as to form a core of fuel.
- 32. The method set forth in claim 31 further comprising directing an oxidant towards said core of fuel from the discharging end of said chamber.
- 33. The method set forth in claim 32 wherein said oxidant penetrates said core of fuel.
- 34. A method for thermally processing a metallic oxide with a carbonaceous material in one or more chambers, wherein each of the one or more chambers has a charging end and a discharging end, to produce a hot metallized/carbon product which is subsequently melted in a melter to make a molten metal and a molten slag, comprising:feeding the metallic oxide and the carbonaceous material to the charging end of said one or more chambers and forcing the metallic oxide and the carbonaceous material toward the discharging end of said one or more chambers; injecting an oxidant in such a way as to utilize at least a portion of the energy contained in said carboniaceous material to release thermal energy and produce pressurized reducing gases to reduce the metallic oxide to form a hot metallized/carbon product; discharging said hot metallized/carbon product from said one or more chambers into a container, discharging the metallized/carbon product from said container into a melter, and heating the metallized/carbon product in the melter to produce a hot pressurized off-gas, a molten metal and a molten slag; and segregating the off-gas, the molten slag and the molten metal.
- 35. The method set forth in claim 33 wherein said container helps to maintain the heat and prevent the re-oxidation of the metallized/carbon product.
- 36. The method set forth in claim 34 further comprising cooling the metallized/carbon product in said container prior to exposing the product to the atmosphere.
- 37. The method set forth in claim 33 wherein the metallized/carbon product is briquetted prior to its discharge into said container.
- 38. The method set forth in claim 36 wherein the briqtuetted metallized/carbon product is cooled prior to exposing the product to the atmosphere.
- 39. Apparatus for thermally processing a metallic oxide and carbonaceous material in one or more chambers comprising:a reactor including a heating chamber having a charging end and a discharging end; a feeding device for feeding the metallic oxide and the carbonaeous material into the charging end of said chamber and forcing the metallic oxide and the carbonaceous material toward the discharging end of said chamber; oxidant injection means adapted to inject an oxidant to cause the carbonaceous material to rise in temperature and react with the metallic oxide to form a metallized/carbon product; a melter in communication with the discharging end of said chamber adapted to receive the metallized/carbon product from said chamber, said melter being adapted to heat the metallized/carbon product to produce a hot pressurized off-gas, molten metal and molten slag; and means for segregating the off-gas, molten slag and molten metal.
- 40. The apparatus set forth in claim 38 further comprising a reservoir for accepting molten metal and molten slag from said melter.
- 41. The apparatus set forth in claim 40 further comprising a reservoir for accepting molten metal and molten slag from said melter in a submerged mode.
- 42. The apparatus set forth in claim 40 wherein said reservoir is adapted to tap the molten metal separately from the molten slat.
- 43. The apparatus set forth in claim 39 wherein said chamber includes a radiant zone adapted to radiate thermal energy towards the discharging end of said chamber.
- 44. The apparatus in claim 39 further comprising pressure balancing means adapted to balance system pressure.
- 45. The apparatus in claim 38 wherein said oxidant injection means is adapted to be selectively advanced or retracted.
- 46. The apparatus in claim 39 further comprising oxidant injection means operatively connected with said melter.
- 47. The apparatus set forth in claim 39 further comprising induction heating means operatively connected with said melter.
- 48. The apparatus in claim 39 further comprising means for supplying supplemental heat to said melter.
- 49. The apparatus in claim 48 wherein said means for supplying supplemental heat to said melter comprises an induction heating means.
- 50. The apparatus in claim 48 wherein said means for supplying supplemental heat to said melter comprises an oxidant injection means.
- 51. The apparatus set forth in claim 39 further comprising a combination oxidant injection means adapted to inject oxidant as well as fuel.
- 52. The apparatus set forth in claim 51 wherein said fuel is gas.
- 53. The apparatus set forth in claim 51 wherein said fuel is pulverized coal.
- 54. Apparatus for thermally processing a metallic oxide and carbonaceous material in one or more chambers comprising:a reactor including a heating chamber having a charging end and a discharging end; a feeding device for feeding the metallic oxide and the cabonaceous material into the charging end of said chamber as a core with a surrounding annulus, and forcing the metallic oxide and the carbonaceous material toward the discharging end of said chamber; oxidant injection means adapted to inject an oxidant to cause the carbonaceous material to rise in temperature and react with the metallic oxide to form a metallized/carbon product; a melter in communication with the discharging end of said chamber adapted to receive the metallized/carbon product from said chamber, said melter being adapted to heat the metallized/carbon product to produce a hot pressurized off-gas, molten metal and molten slag; and means for segregating the off-gas, molten slag and molten metals.
- 55. The apparatus set forth in claim 54 further comprising means for the formation of said core from the carbonaceous material with the metallic oxide surrounding said core.
- 56. The apparatus set forth in claim 54 further comprising oxidant injection means adapted to direct the oxidant into said core.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
6214085 |
Calderon et al. |
Apr 2001 |
B1 |
6221123 |
Mann Sr |
Apr 2001 |
B1 |