Method and apparatus for practicing carbonaceous-based metallurgy

Information

  • Patent Grant
  • 6409790
  • Patent Number
    6,409,790
  • Date Filed
    Friday, March 16, 2001
    23 years ago
  • Date Issued
    Tuesday, June 25, 2002
    22 years ago
Abstract
An energy efficient, coal-based method and apparatus that are environmentally friendly which produce under pressure metallized/carbon product and molten metal directly from abundant coal or other carbonaceous material, and low cost fines (or ore concentrate) wherein the metal is devoid of gangue material and possesses the inherent advantage of retaining the heat for subsequent processing. This method and apparatus which are modular and highly integrated significantly reduce capital and operating costs; they also provide the capability selective placement of the reductant for the delivery of high levels of thermal energy input which leads to ease of desulflurization and high productivity. The technology herein disclosed is entirely closed and is applicable to various ores including ferrous and non-ferrous.
Description




INTRODUCTION




This invention relates to the production of metals from metallic oxides by making use of a carbonaceous material in furtherance of the disclosure contained in applicants' pending application bearing Ser. No. 09/241,649 filed on Feb. 1, 1999 now U.S. Pat. No. 6,214,085 and assigned to Art Unit 1742. Specifically this invention incorporates further developments to the subject matter disclosed in the referenced application particularly with respect to the feeding of raw materials, the heating of same, and reacting these raw materials with one another. Also additional developments are herein disclosed with respect to melting and slagging operations in order to provide an efficient integrated process and apparatus to practice same that are environmentally friendly and cost-competitive in the production of metals.




BACKGROUND




It is well known that existing methods to process raw metallic materials into ferrous and non-ferrous products are inefficient, polluting and very costly to finance, to operate and to maintain. Further, there are issues which relate to health hazards that affect workers in these fields by virtue of exposure to extremely high temperatures, and inhalation of injurious dusts and foul gases.




The method and apparatus disclosed herein have applicability to the processing of various metallic ores such as ores of iron, aluminum, copper, etc. including dusts, wastes and reverts of such metallic materials. Since iron ore is such a dominant feedstock in the field of metallurgy, by way of example, the disclosure in this application will focus on the processing of iron ore termed “carbotreating” with a carbonaceous material such as coal to produce an iron/carbon product which is melted with an oxidant termed “oxymelting” to make a molten iron.




OBJECTIVE OF THE INVENTION




The main object of this development is to provide a method and apparatus which are energy efficient to reduce greenhouse gases.




Another object of the instant invention is to provide a method and apparatus that are environmentally closed which will allow ease of permitting and acceptance by various entities including environmental protection agencies and the public.




Still another object of this invention is to provide a functionally efficient method and apparatus to practice same in order to produce a low cost product to enable industry to survive in a competitive global market.




Further still another object of this invention is to provide a method and apparatus that require low capital investment to enable industry to finance facilities and create jobs.




Further yet another object of this invention is to provide a method and apparatus that are not injurious to employees both from the standpoint of hazardous working conditions and long term deleterious effects regarding health.




Other objects of this invention will appear from the following description and appended claims. Reference is made to the accompanying drawings which describe certain apparatus structures to practice this method of making metallic units, and as they relate to making iron in the form of directly reduced iron, hot briquetted iron, iron/carbon product and molten iron. The molten iron may subsequently be converted into steel directly while molten or cast into pigs which are cooled and then transported as a solid to a processing plant. It is to be understood that the method and apparatus disclosed herein are not solely limited to the processing of iron bearing materials.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a representation of the equipment used to carry out the method to make a metallized/carbon product which is then melted to make molten metal.





FIG. 2

is a section taken at


2





2


of a reactor shown in

FIG. 1

, within which the carbotreating takes place.





FIG. 3

is a variation of the reactor chamber shown in FIG.


1


.





FIG. 4

is an end view of

FIG. 1

, showing a plurality of reactors discharging into a single melter/homogenizer.





FIG. 5

is a configuration to produce directly reduced iron units and cooling such units before discharge into the atmosphere.





FIG. 6

is still another configuration to produce iron units which are brigquetted prior to their discharge into the atmosphere.





FIG. 7

represents discharging hot reduced metallic units into a container which is insulated and sealed to conserve energy and prevent re-oxidation.





FIG. 8

is a representation of the feed of materials into the system with sequential steps


8


-


1


through


8


-


6


showing various positions of the equipment to effect the feed wherein a core of fuel is created and such core is surrounded by the ore to be reduced.





FIG. 9

is a section taken at


9





9


of FIG.


8


.











Before describing in detail the present invention, it is to be understood that this invention is not limited to the details or the arrangement of the parts illustrated in the attached drawings, as the invention can be made operative by using other embodiments. Also it is to be understood that the terminology herein contained is for the purpose of description and not limitation.




DETAILED DESCRIPTION OF THE DRAWINGS




Referring to

FIG. 1

, numeral


10


denotes a reactor where the treating of iron ore with coal takes place to make an iron/carbon product; this treatment of the ore is hereinafter referred to as “carbotreating”. Numeral


11


denotes a melter/homogenizer where the iron/carbon product is melted with an oxidant to make molten metal and slag, hereinafter referred to as “oxymelting”. A standpipe denoted by numeral


12


is connected to melter/homogenizer


11


. A metal reservoir is provided for receiving the molten metal and the slag and is denoted by numeral


13


. Referring to

FIG. 4

, a storage system to contain the raw materials is denoted by numeral


14


; it comprises hoppers


58


,


59


and


60


to store feed materials such as ore, coal and flux respectively. A raw material mixer denoted by numeral


61


serves to blend the feed materials as they are conveyed to lockhopper


36


which is in turn equipped with upper valve


84


and lower feed control


62


.




Referring back to

FIG. 1

for a more detailed description of the structure that enables the method to be practiced, reactor


10


consists of a pushing device denoted by numeral


15


which is equipped with ram


16


at the charging end of reactor


10


, that serves to push the blended charge dropped from hopper


36


into cavity


17


. Ram


16


actuated by pushing device


15


, compresses the charge and advances it within a process chamber which is marked by numeral


28


and which is tapered along its length. Process chamber


28


is connected to cavity


17


, and is made-up of a pressure shell marked by numeral


26


, insulation


27


and wall heating element


25


. Burner


19


in turn communicates with heating element


25


via inlet port


29


. Heating element


25


is equipped with passages shown by numeral


53


in

FIG. 2

; they serve as a conduit to direct hot gases from burner


19


through inlet


29


to flow through passages (flues)


53


along the length of process chamber


28


and exit the chamber via outlet


30


. The discharging end of chamber


28


which is marked by numeral


20


attaches to elbow


21


. Elbow


21


is designed in such a way as to have reflective wall


23


backed by insulation and contained within a pressure casing, in order to form a radiant zone to reflect intense thermal energy against the material that is being carbotreated at discharging end


20


. A first lance (or a plurality of same) denoted by numeral


22


is mounted into elbow


21


; lance


22


is adapted to be advanced towards or retracted from the material being processed. Controller


24


serves to control air/oxygen and coolant to make lance


22


operative. Lance


22


may also contain fuel for start-up purposes.




Reactor


10


communicates with melter/homogenizer


11


by means of transition


32


that directs the reduced material (the iron/carbon product) from chamber


28


to melter/homogenizer


11


which comprises shell


85


, lining


86


, top


87


and bottom


88


. A second lance denoted by numeral


34


serves to supply oxidant in the form of air or oxygen (or a combination of the two) in order to react with the carbon in the iron/carbon product and with gases produced within the process to supply the heat needed to melt the reduced iron in the iron/carbon product to yield a molten iron


42


and a molten slag


43


which floats on top of molten iron


42


. Lance


34


which is kept cool, is raised and lowered by means of hoist


39


for adjusting its level to the working height within melter/homogenizer


11


. A drain/port denoted by


31


and disposed at the bottom of melter/homogenizer


11


, connects to standpipe


12


. Through drain/port


31


, the gasses, the molten iron and the molten slag flow. An off-gas discharge marked by numeral


47


is provided to standpipe


12


to divert a sidestrearn of such gases for control purposes which are directed to cyclone


46


via collecting main


37


. Both the molten iron and the molten slag drop into reservoir


13


while the bulk of the gases flows with the iron and slag. Cyclone


46


communicating with discharge


47


, removes particulate matter from the off-gas. The bottom of cyclone


46


is furnished with surge hopper


40


which feeds into lockhopper


41


; control valves


44


and


45


lock & unlock lockhopper


41


in order to discharge the particulate matter collected into bin


33


which is recycled with the materials charged into reactor


10


. A pressure controller denoted by numeral


50


which controls the back pressure of melter/homogenizer


11


and reactor


10


and standpipe


12


is located downstream of cyclone


46


; the side stream leaves the system via duct


49


for further treatment in a gas treatment facility which is not shown, but known in the art.




Bottom


88


of melter/homogenizer


11


is configured as a cone with drain/port


31


making connection with standpipe


12


which in turn makes connection with metal reservoir


13


in a submerged mode. Induction heating coil means denoted by numeral


35


is provided, to supply auxiliary heat to insure that molten metal and molten slag do not freeze when leaving melter/homogenizer


11


. In the event such freezing takes place especially when melter/homogenizer


11


is shut down, induction heating means


35


is energized to melt the frozen iron and slag. The lining of standpipe


12


is made of such material that would couple with induction heating means


35


. Metal reservoir


13


consists of a lined chamber adapted to rotate about roller segment bed


93


to effect the pouring of molten iron


42


via tap hole


55


into ladle


51


, and slag


43


via spout


54


into pot


52


.




Referring to

FIG. 3

, numeral


10


is a modified configuration wherein heating element


25


along the length of chamber


28


, is obviated. In this configuration the heat input is via lance


22


which is adapted to bore into bed


28


by means of an oxidant after ignition takes place. Lance


22


is equipped with an injection tip denoted by numeral


48


which may have multi-directional nozzles to inject oxidant in several directions. Auxiliary oxidant orifices shown by numeral


92


are provided to lance


22


to combust coal and coke in the mixture, as well as gases generated from the coal in the charge. Heating chamber


28


, may be made as a composite structure of which part is metallic as noted by numeral


117


and part refractory as noted by numeral


27


.




Referring again to

FIG. 4

which is a configuration wherein a plurality of reactors such as reactor


10


, are mounted side by side to form a battery denoted by numeral


104


, with reactors


10


discharging iron/carbon product into common melter/homogenizer


11


. Reactor


10


which is situated at ground level serves as a spare. A crane denoted by numeral


63


, may be added to service battery


104


.




In

FIG. 5

, the invention is configured to make directly reduced iron (DRI) or iron/carbon product which can be melted off-site. Numeral


10


is the reactor with a downstream surge hopper denoted by numeral


64


which is followed by cooler


65


. Cooler


65


may take one of several known approaches including a cooled screw feeder shown by numeral


38


. The cooler feeds the cooled DRI or iron/carbon product into surge hopper


66


. Below surge hopper


66


, a lockhopper denoted by numeral


67


makes possible the discharging of product DRI or iron/carbon product in a sealed manner into the atmosphere and onto conveyor


70


by making use of valves


68


and


69


. A cyclone similar to cyclone


95


shown in FIG.


6


and described hereunder, may be used for separation of entrained particulate matter.




Referring to

FIG. 6

, numeral


10


is the reactor and numeral


21


is the elbow. Beneath elbow


21


a transition denoted by numeral


94


is provided through which the carbotreated material is discharged via downcomer


73


into hot-briquetter


71


which is adapted to form briquettes from the carbrotreated material. A screw feed denoted by numeral


72


is disposed upstream of briquetter


71


to control the feed into the briquetter. Beneath briquetter


71


, surge hopper


74


followed by lockhopper


75


are provided to discharge the formed briquettes into the atmosphere and onto conveyor


70


. Valves


76


and


77


serve to lock and unlock lockhopper


75


.




Adjacent to transition


94


, cyclone


95


is mounted by making use of pipe


78


, in such a way as to pass hot gasses through cyclone


95


in order to remove particulate matter from the gasses. Transition


94


which is equipped with impact surfaces such as cascading baffles


89


tend to breakup the hot carbotreated material to release excess particulate matter; such matter which remains entrained in the off-gases, is disengaged in a cyclone denoted by numeral


95


. Cyclone


95


is equipped with pressure control means


98


, and surge hopper


96


is followed by lockhopper


97


. Collecting bin


79


is disposed below lockhopper


97


for receiving the particulate matter removed from the gases, which is recycled (not shown).




Referring to

FIG. 7

, a box denoted by numeral


118


may be provided beneath lockhopper


75


to contain the iron/carbon product and be transported by any one of known means such as a lift-truck for further processing. Box


118


is designed in such a way as to be insulated to accept hot product in order to conserve thermal energy and prevent re-oxidation of the product.




Reference is now made to

FIG. 8

for the description of the structure to feed the carbonaceous material as a core which is surrounded by the metallic ore. A materials storage arrangement is provided and denoted by numeral


80


which comprises hopper


81


to contain the carbonaceous material (fuel) and hopper


82


to contain the ore. Feeders


101


and


102


control the flow of the fuel and ore from hoppers


81


and


82


respectively. Valves


103


and


105


service lockhopper


81


and valves


104


and


106


service lockhopper


82


. Charging tube


83


is provided at the bottom of materials storage


80


, which is flanked by charging device


90


on one side and reactor


10


on the other side. Charging device


90


is made up of a pushing ram denoted by numeral


99


and pushing plunger


100


with ram


99


being advanced and retracted by actuator means such as cylinders


107


, and plunger


100


being advanced and retracted by actuator means such as cylinder


108


thus providing independent motion to either ram


99


or plunger


100


, with plunger


100


being housed within ram


99


which is annular in configuration and which is in turn housed within charging tube


83


. Ram


99


passes a charging hole


109


to permit the fuel to be dropped into a cavity when plunger


100


is in the retracted position. During the detailed description of the operation for the formation of the core which follows, further clarification will be disclosed with the aid of

FIGS. 8-1

through


8


-


6


.




DETAILED DESCRIPTION OF OPERATION




In explaining the operation of the method and apparatus disclosed herein, the description will be as follows:




(i) Mode of feeding ore and coal, and of heating such materials for carbotreating the ore to yield a metallized/carbon product; and




(ii) Melting the metallized/carbon product to yield molten metal via oxymelting.




With respect to carbotreating wherein a core of fuel is formed in the charged metallic oxide (ore), reference is made to

FIG. 8

, its sequential

FIGS. 8-1

through


8


-


6


, and FIG.


9


. In

FIG. 8-1

both ram


99


and plunger


100


are shown in the advanced position with the core of fuel being denoted by numeral


110


and the oxide surrounding it being denoted by numeral


111


. Plunger


100


is retracted to the position shown in

FIG. 8-2

by means of cylinder


108


while retaining ram


99


in the advanced position. A metered amount of fuel (coal) marked by numeral


112


is dropped into cavity


113


via charging hole


109


. Plunger


100


is then advanced part way to push fuel


112


towards that core of fuel which had been charged and compacted during the previous cycle as shown by

FIG. 8-3

. Next, ram


99


is retracted using the full stroke of cylinders


107


while plunger


100


is parked at the part way advanced position. A metered amount of oxide marked by numeral


114


, is dropped into cavity


115


as shown by

FIG. 8-4

which cavity surrounds plunger


100


. Following this step both ram


99


and plunger


100


are simultaneously advanced; initially, the loose materials begin to be compacted as shown in

FIG. 8-5

by numeral


116


, and as the advancement of ram


99


and plunger


100


proceeds the fuel and the oxide become fully compacted with the core being formed within the oxide with the oxide fully surrounding the core of fuel; the stroke of both ram


99


and plunger


100


keeps advancing after compaction and the entire contents of reactor


10


begin to move to result in hot metallized/carbon product being discharged from the discharging end of reactor


10


as illustrated in

FIG. 8

; the discharge of such product stops when ram


99


and plunger


100


are fully stroked to the advanced position. At the end of the stroke of ram


99


and plunger


100


, the relationship of the ram and the plunger is shown in

FIG. 8-6

which is the same as that shown in

FIG. 8-1

. At this point the cycle is completed. The formation of a fuel core


110


proceeds cyclically to result in providing core


110


being surrounded by oxide


111


shown in cross section in FIG.


9


. This repetitive cycle thus provides a core of fuel being surrounded with oxide along the length of chamber


28


of reactor


10


.




The operation of carbotreating with reference to

FIGS. 1

,


3


and


4


is as follows:




Assuming that the method is already at steady state and at pressure, and the ore (preferably in fine, concentrated form), the coal and the flux contained in materials delivery system


14


, are proportionately mixed and fed as a mixture via hopper


36


, into cavity


17


of process chamber


28


. Ram


16


is then actuated via pushing device


15


to compact the mixture to such an extent as to make it substantially impervious as shown by the densified representation (numeral


18


) at the charging end of reactor


10


. As the mixture is advanced in chamber


28


of reactor


10


, it is heated by any of the following manners of heating; namely, radiation, conduction, convection or any combination of these systems to cause the evolution of gases from the coal with the imperviousness of the mixture forcing the gases to flow within chamber


28


towards discharging end


20


. A portion of these gases is combusted at the discharging end to provide a highly radiant zone to reflect intensive thermal energy to the mixture to heat the mixture to such a temperature as to cause the oxygen in the ore to react with the highly reducing gases liberated from the coal and/or with residual carbon from the coal to reduce the ore to metallized iron. To enhance the heat transfer to the mixture, lances such as lance


22


are provided, which lances are adapted to inject an oxidant in the form of air, oxygen or a combination of both into the mixture of materials within chamber


28


, as this mixture advances in chamber


28


. Further these lances which are kept cool by means of a coolant are also adapted to be advanced and retracted for optimal heat transfer. Variations of oxidant lance injection may also take the form of penetration into the mixture itself as shown by

FIGS. 1 and 3

, with supplementary jets of oxidant (see number


92


) for post-combustion to further enhance heat transfer into the mixture. In the event that no conductive heat through the wall of chamber


28


is furnished, lance


22


may take the form of an oxygen-fuel (coal, gas or oil) burner to initiate the combustion and with the provision that once ignition of the coal gases and the carbon in the coal becomes stable the fuel input from the lance is shut-off, and the coal and its gases supplying the thermal energy needed for sustaining the reactions thus producing the iron/carbon product which is discharged into melter/homogenizer


11


. An alternate arrangement may be the supply of the fuel through lance


22


such as the injection of pulverized coal onto the ore or a combination of the arrangements described herein and others which are known in the art.




The iron/carbon product made by this method is relatively light as compared to the bulk density of iron ore and especially as compared to molten metal; further, the size of the iron/carbon product as it is discharged from reactor


10


is diverse in size and non-uniform. When such product is discharged into a melter containing molten metal and slag, the iron/carbon product tends to float on top of the slag and the molten metal causing delays in productivity and loss of energy by the inability to readily get the iron/carbon product into solution. It is for this purpose that a melter which also acts as a homogenizer devoid of a bath of molten metal and molten slag is provided which takes the form of melter/homogenizer


111


which is capable of draining the molten iron and molten slag as they are formed.




The oxymelting of the metallized/carbon product will now be described by making reference to FIG.


1


. Within melter/homogenizer


11


, lance


34


provides the oxidant to melt the hot iron/carbon product being fed from reactor


10


via downcomer


32


. The oxidant reacts with gases and with carbon from the carbotreating step to cause an intensive energy release which melts the iron in the iron/carbon product, the gangue which was part of the iron oxide, the ash of the coal as well as the flux/desuilirizer material used as additive, to result in making a molten iron and a molten slag, this combination continuously leaves melter/homogenizer


11


via drain/port


31


together with the various hot, pressurized gases produced. Such gases flowing through drain/port


31


keep the molten iron and the slag flowing out of melter/homogenizer


11


and into reservoir


13


by making use of standpipe


12


whose tip is submerged in the molten metal within reservoir


13


; this submergence provides a liquid seal which maintains the pressure in the system.




By means of control valve


50


the back pressure in reactor


10


, melter/homogenizer


11


and standpipe


12


is balanced while the gases generated during carbotreating in reactor


10


and the gases generated during oxymehing in melter/homogenizer


11


are guided together with the molten metal and molten slag to reservoir


13


where such gases bubble out of the bath and are combusted for additional energy release by injecting an oxidant through nozzle


119


. The off-gas is collected in hood


120


for treatment not shown but known in the art. The metallic dust, carbon and ash entrained in such gases remain in the bath by virtue of the bath serving as a wet scrubber which increases the yield of the molten metal. A side stream of such gases flowing through main


37


, is used for pressure control by means of valve


50


and are directed to cyclone


46


via discharge


47


for treatment. The particulate matter separated in cyclone


46


is recycled with the feedstocks and auxiliary heat if needed, is maintained in standpipe


12


by means of induction heating


35


. The operation in reactor


10


and in the melter/homogenizer


11


is intentionally maintained reducing to prevent re-oxidation of the iron and minimizing the formation of NO


x


and CO


2


, while providing efficient desulfurizing conditions to remove the sulfur which originates from the coal.




With respect to the application of this invention to the non-ferrous metals, variations to that which is disclosed may take place; however, the intention is not to depart from the spirit of this disclosure. All in all, it is submitted herein that the instant invention provides major improvement over conventional practice/metallurgy, which can use low cost raw materials, and which is energy efficient, environmentally friendly and requiring low capital investment.



Claims
  • 1. A method for thermally processing a metallic oxide with a carbonaceous material in one or more chambers, wherein each of the one or more chambers has a charging end and a discharging end, to produce a hot metallized/carbon product which is subsequently melted in a melter to make a molten metal and a molten slag, comprising:feeding the metallic oxide and the carbonaceous material to the charging end of said one or more chambers and forcing the metallic oxide and the carbonaceous material toward the discharging end of said one or more chambers; injecting an oxidant in such a way as to utilize at least a portion of the energy contained in said carbonaceous material to release thermal energy and produce pressurized reducing gases to reduce the metallic oxide to form a hot metallized/carbon product; discharging said hot metallized/carbon product from said one or more chambers into the melter; heating the metallized/carbon product in the melter to produce a hot pressurized off-gas, a molten metal and a molten slag; and segregating the off-gas, the molten slag and the molten metal.
  • 2. A method for thermally processing a metallic oxide with a carbonaceous material in one or more chambers, wherein each of the one or more chambers has a charging end and a discharging end, to produce a hot metallized/carbon product which is subsequently melted in a melter to make a molten metal and a molten slag, comprising:feeding the metallic oxide and the carbonaceous material to the charging end of said one or more chambers in such a way as to form a core with an annulus surrounding the core for the efficient reaction of the metallic oxide with the carbonaceous material, and forcing the metallic oxide and the carbonaceous material toward the discharging end of said one or more chambers; injecting an oxidant in such a way as to utilize at least a portion of the energy contained in said carbonaceous material to release thermal energy and produce pressurized reducing gases to reduce the metallic oxide to form a hot metallized/carbon product; discharging said hot metallized/carbon product from said one or more chambers into the melter; heating the metallized/carbon product in the melter to produce a hot pressurized off-gas, a molten metal and a molten slag; and segregating the off-gas, the molten slag and the molten metal.
  • 3. The method set forth in claim 2 wherein the step of injecting an oxidant includes the injection of the oxidant into the discharging end of said one or more chambers.
  • 4. The method set forth in claim 1 wherein a group of chambers are assembled together in battery form, with each chamber being a separate module for ease of scale-up and maintenance.
  • 5. The method set forth in claim 1 wherein the heating of the metallized/carbon product in said melter comprises the step of consuming at least a portion of the carbon in said melter.
  • 6. The method set forth in claim 1 further comprising, controlling pressure to maintain the steps of the method in balance.
  • 7. The method set forth in claim 1 further comprising providing induction heating as supplemental heating to the melter.
  • 8. The method set forth in claim 7 comprising adding an oxidant to supplement said induction heating.
  • 9. The method set forth in claim 1 wherein the oxidant is substantially pure oxygen.
  • 10. The method set forth in claim 1 wherein the oxidant comprises air.
  • 11. The method set forth in claim 1 wherein the oxidant is air enriched with oxygen.
  • 12. The method set forth in claim 1 further comprising providing a radiant heating zone downstream from the discharging end of said one or more chambers to reflect thermal energy towards the materials being processed in order to efficiently transfer heat by radiation to accelerate the conversion of said metallic oxide into a metallized/carbon product.
  • 13. The method set forth in claim 1 further comprising heating said chamber by passing hot gases through flues provided in the wall of said chamber to additionally heat the materials in the chamber by conduction.
  • 14. The method set forth in claim 1 wherein additional energy is introduced in said radiant zone by combusting gases therein to further accelerate the reduction of said metallic oxide.
  • 15. The method set forth in claim 1 wherein the materials in said chamber are advanced and discharged from said chamber in such a way as to repeatedly provide a new face of the materials being processed at the discharging end of said chamber.
  • 16. The method set forth in claim 1 further comprising guiding the molten metal and molten slag into a reservoir.
  • 17. The method set forth in claim 16 further comprising guiding the molten metal and molten slag into a reservoir in a submerged mode to provide a liquid seal.
  • 18. The method set forth in claim 1 wherein the method is environmentally closed to prevent polluting emissions.
  • 19. The method set forth in claim 1 wherein said chamber includes a tapered portion that diverges towards the discharge end of said chamber.
  • 20. The method set forth in claim 1 wherein the metallic oxide is comprised of an iron oxide.
  • 21. The method set forth in claim 1 wherein the carbonaceous material is comprised of coal.
  • 22. The method set forth in claim 1 further comprising guiding the molten metal and molten slag to a reservoir together with a flow of gases that are combusted to release thermal energy.
  • 23. The method set forth in claim 1 further comprising homogenizing the molten metal in said melter.
  • 24. The method set forth in claim 1 further comprising homogenizing the molten metal into iron.
  • 25. The method set forth in claim 1 further comprising honogenizing the molten metal into steel.
  • 26. The method set forth in claim 1 including the injecting of the oxidant by means of a lance.
  • 27. The method set forth in claim 1 including the injecting of the oxidant by means of a plurality of lances.
  • 28. The method set forth in claim 1 further comprising the addition of a flux material to the metallic oxide and carbonaceous material.
  • 29. The method set forth in claim 1 further comprising the addition of a desulfturizing material to the metallic oxide and carbonaceous material.
  • 30. The method set forth in claim 1 further comprising including at least a portion of said carbonaceous material in the metallic oxide to form a mix.
  • 31. The method set forth in claim 1 further comprising charging said carbonaceous material into said chamber in such a way as to form a core of fuel.
  • 32. The method set forth in claim 31 further comprising directing an oxidant towards said core of fuel from the discharging end of said chamber.
  • 33. The method set forth in claim 32 wherein said oxidant penetrates said core of fuel.
  • 34. A method for thermally processing a metallic oxide with a carbonaceous material in one or more chambers, wherein each of the one or more chambers has a charging end and a discharging end, to produce a hot metallized/carbon product which is subsequently melted in a melter to make a molten metal and a molten slag, comprising:feeding the metallic oxide and the carbonaceous material to the charging end of said one or more chambers and forcing the metallic oxide and the carbonaceous material toward the discharging end of said one or more chambers; injecting an oxidant in such a way as to utilize at least a portion of the energy contained in said carboniaceous material to release thermal energy and produce pressurized reducing gases to reduce the metallic oxide to form a hot metallized/carbon product; discharging said hot metallized/carbon product from said one or more chambers into a container, discharging the metallized/carbon product from said container into a melter, and heating the metallized/carbon product in the melter to produce a hot pressurized off-gas, a molten metal and a molten slag; and segregating the off-gas, the molten slag and the molten metal.
  • 35. The method set forth in claim 33 wherein said container helps to maintain the heat and prevent the re-oxidation of the metallized/carbon product.
  • 36. The method set forth in claim 34 further comprising cooling the metallized/carbon product in said container prior to exposing the product to the atmosphere.
  • 37. The method set forth in claim 33 wherein the metallized/carbon product is briquetted prior to its discharge into said container.
  • 38. The method set forth in claim 36 wherein the briqtuetted metallized/carbon product is cooled prior to exposing the product to the atmosphere.
  • 39. Apparatus for thermally processing a metallic oxide and carbonaceous material in one or more chambers comprising:a reactor including a heating chamber having a charging end and a discharging end; a feeding device for feeding the metallic oxide and the carbonaeous material into the charging end of said chamber and forcing the metallic oxide and the carbonaceous material toward the discharging end of said chamber; oxidant injection means adapted to inject an oxidant to cause the carbonaceous material to rise in temperature and react with the metallic oxide to form a metallized/carbon product; a melter in communication with the discharging end of said chamber adapted to receive the metallized/carbon product from said chamber, said melter being adapted to heat the metallized/carbon product to produce a hot pressurized off-gas, molten metal and molten slag; and means for segregating the off-gas, molten slag and molten metal.
  • 40. The apparatus set forth in claim 38 further comprising a reservoir for accepting molten metal and molten slag from said melter.
  • 41. The apparatus set forth in claim 40 further comprising a reservoir for accepting molten metal and molten slag from said melter in a submerged mode.
  • 42. The apparatus set forth in claim 40 wherein said reservoir is adapted to tap the molten metal separately from the molten slat.
  • 43. The apparatus set forth in claim 39 wherein said chamber includes a radiant zone adapted to radiate thermal energy towards the discharging end of said chamber.
  • 44. The apparatus in claim 39 further comprising pressure balancing means adapted to balance system pressure.
  • 45. The apparatus in claim 38 wherein said oxidant injection means is adapted to be selectively advanced or retracted.
  • 46. The apparatus in claim 39 further comprising oxidant injection means operatively connected with said melter.
  • 47. The apparatus set forth in claim 39 further comprising induction heating means operatively connected with said melter.
  • 48. The apparatus in claim 39 further comprising means for supplying supplemental heat to said melter.
  • 49. The apparatus in claim 48 wherein said means for supplying supplemental heat to said melter comprises an induction heating means.
  • 50. The apparatus in claim 48 wherein said means for supplying supplemental heat to said melter comprises an oxidant injection means.
  • 51. The apparatus set forth in claim 39 further comprising a combination oxidant injection means adapted to inject oxidant as well as fuel.
  • 52. The apparatus set forth in claim 51 wherein said fuel is gas.
  • 53. The apparatus set forth in claim 51 wherein said fuel is pulverized coal.
  • 54. Apparatus for thermally processing a metallic oxide and carbonaceous material in one or more chambers comprising:a reactor including a heating chamber having a charging end and a discharging end; a feeding device for feeding the metallic oxide and the cabonaceous material into the charging end of said chamber as a core with a surrounding annulus, and forcing the metallic oxide and the carbonaceous material toward the discharging end of said chamber; oxidant injection means adapted to inject an oxidant to cause the carbonaceous material to rise in temperature and react with the metallic oxide to form a metallized/carbon product; a melter in communication with the discharging end of said chamber adapted to receive the metallized/carbon product from said chamber, said melter being adapted to heat the metallized/carbon product to produce a hot pressurized off-gas, molten metal and molten slag; and means for segregating the off-gas, molten slag and molten metals.
  • 55. The apparatus set forth in claim 54 further comprising means for the formation of said core from the carbonaceous material with the metallic oxide surrounding said core.
  • 56. The apparatus set forth in claim 54 further comprising oxidant injection means adapted to direct the oxidant into said core.
US Referenced Citations (2)
Number Name Date Kind
6214085 Calderon et al. Apr 2001 B1
6221123 Mann Sr Apr 2001 B1