Method and apparatus for quick-heating pouring tubes and nozzles

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to the field of molten metal processing and handling. More specifically, the invention relates to an improved method and apparatus for preheating pouring tubes and nozzles, such as submerged entry nozzles for a continuous casting machine.

2. Description of the Related Technology

Production of metals by use of the continuous casting technique has been increasing since its large-scale introduction about thirty-five years ago, and now accounts for a large percentage of the volume of steel, among other metals, produced each year worldwide. Continuous casting machines typically include a mold that has two essentially parallel and opposed wide walls, and two essentially parallel opposed narrow walls that cooperate with the wide walls to define a casting passage of rectangular cross section. Molten metal is supplied continuously into a top end of the casting passage, and the mold is designed to cool the metal so that an outer skin forms before the so-formed slab or strand exits a bottom of the casting passage. Spraying further cools the strand as it travels away from the mold, until it becomes completely solidified. It may then be processed further into an intermediate or finished metal product, such as steel plate, sheeting or coils by traditional techniques such as rolling.

In conventional continuous casting machines, molten steel is teemed from a ladle into a tundish that typically has a one or more of holes defined in its bottom, each of which is connectable to at least one removable submerged entry nozzle (SEN), which is constructed and arranged to guide the flow of molten steel from the tundish into the continuous casting mold. Special refractory slide gate valves and/or stopper rods are usually provided to control the flow of molten metal to and through the submerged entry nozzle. In addition to the submerged entry nozzle, other refractory pouring tubes are associated with the ladle and the tundish, such as ladle shrouds which are employed to protect the molten metal from ambient oxidation during the teeming/casting operations, and nozzles to guide the molten metal through the brick lining the bottom of the tundish. All of these refractory shapes, which may be referred to herein as molten metal contacting elements, are subjected to severe operating conditions and must be able to withstand thermal shock, as well as the chemical/erosive attack of molten steel and slag.

Molten metal contacting elements are commonly made from carbon containing compositions, including one or more refractory grains such as alumina, zirconia, clays, magnesia, silicon carbide, silica or other dense grains having a specific mesh size. These refractories also generally contain significant amounts of carbon in the form of graphite, carbon black, coke and like carbon sources plus a carbonaceous binder derived from sources such as pitch or resin. Such pressed and fired refractory shapes are known to possess good physical properties, particularly thermal shock, making them suitable for use in this severe operating environment.

Molten steels are commonly de-oxidized or “killed” by the addition of aluminum metal, ferromanganese or ferrosilicon. In the common case of aluminum killed steel, the added aluminum will react with dissolved oxygen or iron oxide to form finely dispersed aluminum oxide in the melt, some of which remains as highly dispersed microparticles in the solidified steel while a portion floats into a layer of slag that floats above the molten steel. During continuous casting, this extremely finely dispersed portion of alumina has a tendency to either precipitate out of the molten steel onto the cooler refractory surfaces or react with and bind to the refractory surfaces. This gradual build-up of alumina causes problems in the control of the flow of molten steel and may eventually cause blockage in the pouring nozzles. In addition, molten metal contacting elements such as submerged entry nozzles wear quickly due to factors such as friction and oxidation, and need to be replaced relatively often.

Before a submerged entry nozzle can be replaced, the new nozzle must be preheated in order to minimize thermal stress within the nozzle during start-up and to prevent the molten steel from solidifying within the nozzle before it reaches the mold. Conventionally, this preheating is performed with gas burners, which are directed inside the ports of the nozzle so that the combustion takes place within the nozzle itself. This method of heating takes from 30 to 60 minutes and has the undesired effect of causing oxidation in the inner working surface of the nozzle. It further has the effect of burning off or otherwise weakening the carbonaceous binder within the refractory material, which will ultimately shorten the working life of the nozzle. Elemental carbon is susceptible to air oxidation at temperatures above 500 degrees C. Since submerged entry nozzles often must be replaced on an unscheduled basis as the continuous casting machine operates, it is common for many steelmakers to keep a new submerged entry nozzle at the ready by the continuous casting machine in a constant preheated state to avoid expensive delays. This practice has several environmental and economic drawbacks. First, keeping a new nozzle preheated consumes an enormous amount of energy, which is not recoverable by the steel producer and tends to end up as waste heat that is introduced into the environment. Second, a new nozzle will only remain useful for a limited period of time while it is being kept in the preheated state, before excessive oxidation and binder degradation takes place. As a result, many new nozzles are discarded without ever being used, which represents a significant expense to the steel producer. Others are downgraded to a shorter life expectancy that is commensurate with the amount of extra time the nozzle remains in the preheated state.

A need exists for an improved method and system for preheating molten metal contacting elements such as submerged entry nozzles that is more energy efficient and environmentally and economically sound than methods and systems that have heretofore been known and used.

SUMMARY OF THE INVENTION

Accordingly, it is an object of the invention to provide an improved method and system for preheating molten metal contacting elements such as submerged entry nozzles that is more energy efficient and environmentally and economically sound than methods and systems that have heretofore been known and used.

In order to achieve the above and other objects of the invention, a method of preparing a molten metal contacting element for use in a system of the type that is designed to handle molten metal includes steps of preheating a molten metal contacting element by exposing the molten metal contacting element to intensive radiative beat transfer; and installing the preheated molten metal contacting element into a system of the type that is designed to handle molten metal, whereby the molten metal contacting element may be prepared for use more quickly and in an environmentally sounder manner than through conventional preheating processes.

A method of preparing a pouring tube for use in a continuous casting machine includes, according to a second aspect of the invention steps of preheating at least one portion of a pouring tube by exposing the pouring tube to intensive radiative heat transfer; and installing the preheated pouring tube into a continuous casting machine, whereby the pouring tube may be prepared for use more quickly and in an environmentally sounder manner than through conventional preheating processes.

According to a third aspect of the invention, an apparatus for preheating at least one portion of a molten metal contacting element that is of the type that is usable in a system of the type that is designed to handle molten metal includes radiative structure for emitting a high-intensity infrared radiation; and positioning structure for positioning the radiative structure in a predetermined position with respect to a molten metal contacting element that is of the type that is usable in a system of the type that is designed to handle molten metal, whereby at least one portion of the molten metal contacting element is preheatable via radiative heat transfer from the radiative structure.

According to a fourth aspect of the invention, an apparatus for preheating at least one portion of a pouring tube for use in a continuous casting machine includes radiative structure for emitting a high-intensity infrared radiation; and positioning structure for positioning said radiative structure in a predetermined position with respect to a pouring tube that is of the type that is usable in a continuous casting machine, whereby at least one portion of the pouring tube is preheatable via radiative heat transfer from the radiative structure.

These and various other advantages and features of novelty that characterize the invention are pointed out with particularity in the claims annexed hereto and forming a part hereof. However, for a better understanding of the invention, its advantages, and the objects obtained by its use, reference should be made to the drawings which form a further part hereof, and to the accompanying descriptive matter, in which there is illustrated and described a preferred embodiment of the invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1

is a diagrammatical depiction of a system that is constructed according to a preferred embodiment of the invention;

FIG. 2

is a diagrammatical depiction of a process according to the preferred embodiment of the invention;

FIG. 3

is a schematic depiction of a control system for the system that is depicted in

FIG. 1

;

FIG. 4

is a perspective view of a system that is constructed according to an alternative embodiment of the invention;

FIG. 5

is a cross-sectional view taken along lines

5

—

5

in

FIG. 4

; and

FIG. 6

is a diagrammatical view of a system constructed according to another embodiment of the invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT(S)

Referring now to the drawings, wherein like reference numerals designate corresponding structure throughout the views, and referring in particular to

FIG. 1

, an apparatus

10

for preheating at least one portion of a molten metal contacting element

12

, which in the preferred embodiment of the invention is a submerged entry nozzle

14

, includes radiative structure

15

for emitting a high intensity infrared radiation, and positioning structure

17

for positioning the radiative structure in a predetermined position with respect to the molten metal contacting elements

12

so that at least one portion of the molten metal contacting element

12

is preheatable via radiative transfer from the radiative structure

15

. Alternatively, the molten metal contacting element

12

could be any of a number of parts that handle molten metal and that could benefit from preheating, such as a ladle shroud, a tundish nozzle, a pouring nozzle, slide gate valve components and stopper rods. This list is intended to be exemplary, and not exhaustive.

As may be seen in

FIG. 1

, the submerged entry nozzle

14

is of a common construction, possessing a flange portion

16

of the type of that is commonly encased in metal and that is constructed and arranged to be attached to a tundish, and a tube portion

18

that has a cylindrical internal bore defined therein and at least one exit port

20

at a distal end that is constructed and arranged to permit molten metal to flow therefrom into the continuous casting mold during the continuous casting process.

Referring again to

FIG. 1

, positioning structure

17

includes in the preferred embodiment a cart

22

or other vehicle that preferably has a frame

24

, a plurality of supporting wheels

26

and a support structure

28

for holding a support rod

30

that extends outwardly from the cart

22

for supporting the submerged entry nozzle

14

in a horizontal position. Although not included in the preferred embodiment that is illustrated, the support structure

28

may include a bearing mechanism for permitting the support rod

30

to be rotated, which also would permit rotation of the submerged entry nozzle

14

within the radiative structure

15

. Support structure

28

further includes structure for securing the rod

30

to the cart

22

during operation, which in the preferred embodiment is at least one pivoting latch

32

. Alternatively, the support structure could be constructed in such a way (as shown in the embodiment of

FIG. 6

discussed below) that the radiative structure

15

could be positioned within the submerged entry nozzle

14

during preheating, so that the submerged entry nozzle

14

may be heated from the inside out.

Radiative structure of

15

is preferably embodied as a preheating assembly

34

that defines a heating chamber

36

that is constructed to substantially surround one or more submerged entry nozzles

14

during the preheating process, as is shown in FIG.

1

. Heating chamber

36

is supported at an appropriate elevation with respect to the underlying surface by means of a support structure

38

and is lined with insulation

40

, which is preferably fabricated from a thermal ceramic or firebrick material. A guide seat

42

is positioned within the chamber

36

for supporting the submerging entry nozzle

14

. Guide seat

42

is preferably fabricated from a metallic material that is resistant to the heat that will be developed within the chamber

36

and that may also act as a conductor of heat and/or re-radiator of infrared heat to the lower side of the submerged entry nozzle

14

during the preheating process. Preferably, guide seat

42

is fabricated from a material such as nickel aluminide or iron aluminide.

As may be seen in

FIG. 1

, an opening

44

is defined in the chamber

36

to permit the tube portion

18

of the submerged entry nozzle

14

to be positioned within the chamber

36

. It is generally considered not desirable to preheat the flange portion

16

to the extent of the rest of the SEN, which is typically encased in a metallic material. A source

35

of pressurized inert gas, preferably argon or nitrogen, is provided to provide a slight positive pressure of the inert gas within the chamber

36

. This is to prevent oxidation of the refractory material from which the submerged entry nozzle

14

is fabricated during the preheating process.

According to one important aspect of the invention, a high intensity infrared source

46

is provided in the preheating assembly

34

. Preferably, source

46

is of the type that emits infrared energy at a wavelength that is about within the range of 0.75 to 10 microns, that is more preferably within the range of 1 to 5 microns, and is most preferably within the range of 1-2 microns. The infrared source

46

is preferably of the short wave type that has a tungsten filament such as a QH2500T3/CL 460-480VAC 25 inch LL 2500W infrared quartz lamp that is commercially available from General Electric. This short wave emitter operates at a peak wavelength of 1.15 microns.

Referring briefly to

FIG. 3

, it will be seen that a temperature sensor

48

is provided within the preheating assembly

34

in order to sense the temperature of the submerged entry nozzle

14

during the preheating process. Temperature sensor

48

reports this information to a controller

50

, which in turn controls operation of the infrared source

46

. An operator input

52

is also provided to program or override the controller

50

insofar as such factors as the intensity of infrared heat that is to be applied to the submerged entry nozzle, the time for which the infrared radiation should be applied, and the final temperature to which the submerged entry nozzle

14

is to be heated. Alternatively, controller

50

may be constructed so as to be able to communicate with a broader control system for the entire continuous casting machine or subsystems thereof. Controller

50

further controls the application of pressurized inert gas from the source

35

into the chamber

36

.

A system that is constructed according to an alternative embodiment of the invention that will be the preferred embodiment in certain circumstances depending on customer preferences is depicted in

FIGS. 4 and 5

. In this embodiment of the invention, a preheating assembly

60

is provided together with positioning structure

62

, which in the illustrated embodiment is constructed as a trolley unit

64

. As may be seen in

FIG. 4

, the preheating assembly

60

includes a generally circular housing

66

defining an internal chamber

68

into which a submerged entry nozzle

14

may be inserted via the positioning structure

62

for preheating. As may be seen in

FIG. 5

, housing

66

preferably has a slot defined in a lower surface thereof to permit insertion and withdrawal of the positioning structure

62

in to and out of the chamber

68

. A guide seat

70

is provided on the trolley unit

64

for supporting the submerged entry nozzle

14

.

As may best be seen in

FIG. 5

, a plurality of high-intensity infrared light sources

72

are provided within the housing

66

, and are arrayed so as to substantially surround the portion of the chamber

68

into which the submerged entry nozzle

14

will be positioned for preheating. Through this geometry, the preheating assembly

60

will be able to irradiate the submerged entry nozzle

14

with heat energy at a greater heat flux density and more evenly that with the embodiment that is disclosed in

FIGS. 1 and 2

.

FIG. 6

depicts an embodiment of the invention wherein a tundish

80

having a tundish nozzle

82

is treated with a preheat unit

84

that is constructed and arranged to be positioned within the tundish nozzle

82

to heat the tundish nozzle

82

prior to startup. In this embodiment, the preheat unit

84

includes at least one but preferably a plurality of infrared sources

86

, which are positioned around the outer periphery of the unit

84

. The unit

84

may be cooled during operation by an internal water jacket or similar arrangement. As may further be seen in

FIG. 6

, preheat unit

84

is mounted on a positioning mechanism

88

, which includes a platform

92

for supporting the unit

84

and a vertical adjustment mechanism

90

for raising and lowering the unit

84

into and out of the tundish nozzle

82

.

In operation, a new molten metal contacting element

12

, such as a submerged entry nozzle

14

, will be positioned as shown in

FIG. 1

within the preheating assembly

34

and will be preheated according to the predetermined conditions that are programmed into controller

50

and to a final temperature that is desired. In the preferred embodiment, preheating is performed by applying infrared radiation to the submerged entry nozzle at a heat flux density at the source

46

that is preferably no less than 10 Watts per square inch, that is more preferably at least 75 Watts per square inch, and that is most preferably at least 100 Watts per square inch. The preheating is preferably performed to reach a temperature that is no less than 1000 degrees F, with a preferable minimum temperature of 1500 degrees F and most preferably to a temperature that is about 2000 degrees F. Preferably, the submerged entry nozzle receives at least 50 percent of its added heat during the preheating process via the radiative mode of heat transfer, as opposed to the convective or conductive modes of heat transfer, and most preferably receives at least 90 percent of its energy through radiative heat transfer. The preheating process is preferably performed in a period of time, measured from the initial application of the high intensity infrared radiation to the submerged entry nozzle to the reaching of the target preheat temperature, of no more than twenty minutes. More preferably, the period of time is no more than fifteen minutes, and most preferably this period of time is no more than ten minutes. It is anticipated that in most instances the preheating process will be able to be preformed within a period of seven to ten minutes.

Alternatively, the submerged entry nozzle

14

may be pre-positioned within the preheating assembly

34

as shown in

FIG. 1

, with the preheating process commencing at the point in time that it becomes apparent that a nozzle change will have to be made.

At or before this point, an old molten metal contacting element such as a submerged entry nozzle

14

will be removed from the continuous casting machine. The preheated submerged entry nozzle will then be installed in to the continuous casting machine according to conventional techniques.

It is to be understood, however, that even though numerous characteristics and advantages of the present invention have been set forth in the foregoing description, together with details of the structure and function of the invention, the disclosure is illustrative only, and changes may be made in detail, especially in matters of shape, size and arrangement of parts within the principles of the invention to the full extent indicated by the broad general meaning of the terms in which the appended claims are expressed.

Claims

1. A method of preparing a molten metal contacting element for use in a system that is designed to handle molten metal, comprising steps of:(a) preheating a molten metal contacting element by exposing the molten metal contacting element to intensive radiative heat transfer that is generated by a source having a heat flux density of at least 10 watts per square inch, and wherein said preheating is performed so as to heat the molten metal contacting element to a temperature of at least 1000 degrees F. within a period of time that is no greater than 20 minutes; and (b) installing the preheated molten metal contacting element into a system that is designed to handle molten metal, whereby the molten metal contacting element may be prepared for use more quickly and in an environmentally sounder manner than through conventional preheating processes.
2. A method according to claim 1, wherein step (a) comprises subjecting the molten metal contacting element to intensive infrared radiation.
3. A method according to claim 1, wherein the intensive infrared radiation has a heat flux density at a source of the radiation that is at least 75 watts per square inch.
4. A method according to claim 1, wherein the intensive infrared radiation has a heat flux density at a source of the radiation that is at least 100 watts per square inch.
5. A method according to claim 1, wherein step (a) is performed so as to heat the molten metal contacting element to a temperature that is within the range of 1500 degrees F.
6. A method according to claim 1, wherein step (a) is performed so as to heat the molten metal contacting element to a temperature that is within the range of 2000 degrees F.
7. A method according to claim 1, wherein step (a) is further performed so as to heat the molten metal contacting element to said temperature within a period of time that is no greater than fifteen minutes.
8. A method according to claim 7, wherein step (a) is further performed so as to heat the molten metal contacting element to said temperature within a period of time that is no greater than ten minutes.
9. A method according to claim 1, wherein step (a) is performed by positioning the molten metal contacting element within a confined space prior to preheating the molten metal contacting element by exposing the molten metal contacting element to intensive radiative heat transfer.
10. A method according to claim 1, wherein the radiative heat has a wavelength at its source that is within the range of 0.75 to 10 microns.
11. A method according to claim 10, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 5 microns.
12. A method according to claim 11, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 2 microns.
13. A method of preparing a pouring tube for use in a continuous casting machine, comprising steps of:(a) preheating at least one portion of a pouring tube to a temperature of at least 1000 degrees F. by exposing the pouring tube to electrically generated intensive radiative heat transfer for a period of time that is no more than twenty minutes; and (b) installing the preheated pouring tube into a continuous casting machine, whereby the pouring tube may be prepared for use more quickly and in an environmentally sounder manner than through conventional preheating processes.
14. A method according to claim 13, wherein step (a) comprises subjecting the pouring tube to intensive infrared radiation.
15. A method according to claim 14, wherein the intensive infrared radiation has a heat flux density at a source of the radiation that is at least 10 watts per square inch.
16. A method according to claim 15, wherein the intensive infrared radiation has a heat flux density at a source of the radiation that is at least 75 watts per square inch.
17. A method according to claim 16, wherein the intensive infrared radiation has a heat flux density at a source of the radiation that is at least 100 watts per square inch.
18. A method according to claim 13, wherein step (a) is per formed so as to heat the at least one location on the pouring tube to a temperature that is at least 1500 degrees F.
19. A method according to claim 18, wherein step (a) is performed so as to heat the at least one location on the pouring tube to a temperature that is at least 2000 degrees F.
20. A method according to claim 13, wherein step (a) is futher performed so as to heat the at least one location on the pouring tube to said temperature within a period of time that is no greater than fifteen minutes.
21. A method according to claim 20, wherein step (a) is further performed so as to heat the at least one location on the pouring tube to said temperature within a period of time that is no greater than ten minutes.
22. A method according to claim 13, wherein step (a) is performed by positioning the pouring tube within a confined space prior to preheating the pouring tube by exposing the pouring tube to intensive radiative heat transfer.
23. A method according to claim 13, wherein said pouring tube comprises a submerged entry nozzle for a continuous casting machine.
24. A method according to claim 13, wherein the radiative heat has a wavelength at its source that is within the range of 0.75 to 10 microns.
25. A method according to claim 24, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 5 microns.
26. A method according to claim 25, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 2 microns.
27. An apparatus for preheating at least one portion of a molten metal contacting element that is usable in a system that is designed to handle molten metal, comprising:radiative means for emitting a high-intensity infrared radiation, said radiative means being constructed and arranged to emit infrared radiation at an intensity that has a heat flux density at a source of the radiation that is at least 10 watts per square inch; and positioning means for positioning said radiative means in a predetermined position with respect to a molten metal contacting element that is usable in a system that is designed to handle molten metal, whereby at least one portion of the molten metal contacting element is preheatable via radiative heat transfer from said radiative means, and wherein said radiative means and said positioning means are constructed and arranged so that said heat energy reaching said molten metal contacting element during use will be at least 50 percent transmitted via radiation.
28. An apparatus according to claim 27, wherein said radiative means is constructed and arranged to emit infrared radiation at an intensity that has a heat flux density at a source of the radiation that is at least 75 watts per square inch.
29. An apparatus according to claim 28, wherein said radiative means is constructed and arranged to emit infrared radiation at an intensity that radiation has a heat flux density at a source of the radiation that is at least 100 watts per square inch.
30. An apparatus according to claim 27, wherein said positioning means comprises containment means for at least partially surrounding said molten metal contacting element during use.
31. An apparatus according to claim 27, wherein said radiative means and said positioning means are constructed and arranged to preheat said molten metal contacting element to a temperature of at least 1000 degrees F.
32. An apparatus according to claim 31, wherein said radiative means and said positioning means are constructed and arranged to preheat said molten metal contacting element to a temperature of at least 1500 degrees F.
33. An apparatus according to claim 32, wherein said radiative means and said positioning means are constructed and arranged to preheat said molten metal contacting element to a temperature of at least 2000 degrees F.
34. An apparatus according to claim 27 wherein the radiative heat has a wavelength at its source that is within the range of 0.75 to 10 microns.
35. An apparatus according to claim 34, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 5 microns.
36. An apparatus according to claim 35, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 2 microns.
37. An apparatus for preheating at least one portion of a pouring tube for use in a continuous casting machine, comprising:radiative means for emitting a high-intensity infrared radiation; and positioning means for positioning said radiative means in a predetermined position with respect to a pouring tube that is usable in a continuous casting machine, said positioning means comprising containment means for at least partially surrounding said pouring tube during use, said radiative means and said positioning means further being constructed and arranged so that said heat energy reaching said pouring tube during use will be at least 50 percent transmitted via radiation, whereby at least one portion of the pouring tube is preheatable via radiative heat transfer from said radiative means.
38. An apparatus according to claim 37, wherein said radiative means is constructed and arranged to emit infrared radiation at an intensity that radiation has a heat flux density at a source of the radiation that is at least 10 watts per square inch.
39. An apparatus according to claim 38, wherein said radiative means is constructed and arranged to emit infrared radiation at an intensity that radiation has a heat flux density at a source of the radiation that is at least 75 watts per square inch.
40. An apparatus according to claim 39, wherein said radiative means is constructed and arranged to emit infrared radiation at an intensity that radiation has a heat flux density at a source of the radiation that is at least 100 watts per square inch.
41. An apparatus according to claim 37, wherein said radiative means and said positioning means are constructed and arranged to preheat said pouring tube to a temperature of at least 1000 degrees F.
42. An apparatus according to claim 41, wherein said radiative means and said positioning means are constructed and arranged to preheat said pouring tube to a temperature of at least 1500 degrees F.
43. An apparatus according to claim 42, wherein said radiative means and said positioning means are constructed and arranged to preheat said pouring tube to a temperature of at least 2000 degrees F.
44. An apparatus according to claim 37, wherein the radiative heat has a wavelength at its source that is within the range of 0.75 to 10 microns.
45. An apparatus according to claim 44, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 5 microns.
46. An apparatus according to claim 45, wherein the radiative heat has a wavelength at its source that is within the range of 1 to 2 microns.

US Referenced Citations (2)

Number	Name	Date	Kind
4682578	Schmidt	Jul 1987
5190716	Bruckner et al.	Mar 1993

Method and apparatus for quick-heating pouring tubes and nozzles

Information

Patent Number

Date Filed

Date Issued

Inventors

Original Assignees

Examiners

Agents

CPC

US Classifications

Field of Search

US

International Classifications

Abstract

Description

Claims

US Referenced Citations (2)