This is a national stage application filed under 35 USC 371 based on International Application No. PCT/FI2013/050646 filed Jun. 12, 2013 and claims priority under 35 USC 119 of Finnish Patent Application No. 20125653 filed Jun. 13, 2012.
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The invention relates to a method for refining copper concentrate.
The invention also relates to an arrangement for refining copper concentrate.
The method includes using a suspension smelting furnace and the arrangement comprises a suspension smelting furnace. With a suspension smelting furnace is in this context meant for example a direct to blister furnace or a flash smelting furnace.
One problem with a prior art arrangement as shown in
The object of the invention is to solve the above identified problem.
The method comprises using a suspension smelting furnace comprising a reaction shaft and a settler. The reaction shaft of the suspension smelting furnace is provided with a concentrate burner for feeding copper concentrate such as copper sulfide concentrate and/or copper matte and additionally at least reaction gas into the reaction shaft of the suspension smelting furnace to obtain a blister layer containing blister and a first slag layer containing slag on top of the blister layer in the settler of the suspension smelting furnace. The method comprises using a slag cleaning furnace. The method comprises a step for feeding copper concentrate such as copper sulfide concentrate and/or copper matte and additionally at least reaction gas into the reaction shaft of the suspension smelting furnace to obtain a blister layer containing blister and a first slag layer containing slag on top of the blister layer in the settler of the suspension smelting furnace. The method comprises additionally a step for feeding slag from the first slag layer in the settler of the suspension smelting furnace and blister from the blister layer in the settler of the suspension smelting furnace from the suspension smelting furnace into the slag cleaning furnace. The method comprises additionally a step for treating blister and slag in the slag cleaning furnace with a reduction agent to obtain a bottom metal layer containing bottom metal copper and a second slag layer containing slag on top of the bottom metal layer in the slag cleaning furnace. The method comprises additionally a step for discharging bottom metal copper from the bottom metal layer in the slag cleaning furnace. The method comprises additionally a step for discharging slag from the second slag layer in the slag cleaning furnace.
The arrangement comprises a suspension smelting furnace comprising a reaction shaft and a settler. The reaction shaft of the suspension smelting furnace is provided with a concentrate burner for feeding copper concentrate such as copper sulfide concentrate and/or copper matte and additionally at least reaction gas into the reaction shaft of the suspension smelting furnace to obtain a blister layer containing blister and a first slag layer containing slag on top of the blister layer in the settler of the suspension smelting furnace. The arrangement comprises additionally feeding means for feeding blister from the blister layer in the settler of the suspension smelting furnace into the slag cleaning furnace and for feeding slag from the first slag layer in the settler of the suspension smelting furnace into the slag cleaning furnace. The slag cleaning furnace is configured for treating blister and slag in the slag cleaning furnace with a reduction agent to obtain a bottom metal layer containing bottom metal copper and a second slag layer containing slag on top of the bottom metal layer in the slag cleaning furnace. The arrangement comprises additionally bottom metal discharging means for discharging bottom metal copper from the bottom metal layer in the slag cleaning furnace. The arrangement comprises additionally slag discharging means for discharging slag from the second slag layer in the slag cleaning furnace.
The invention is based on feeding both slag and blister from the suspension smelting furnace to the slag cleaning furnace. By feeding both slag and blister from the suspension smelting furnace to the slag cleaning furnace will a greater amount of thermal energy be fed to the slag cleaning furnace in comparison to a situation where only slag is fed from the suspension smelting furnace to the slag cleaning furnace, as in the prior art arrangement shown in
In a preferred embodiment of the method, the method comprises feeding copper concentrate such as copper sulfide concentrate and/or copper matte and/or reaction gas into the reaction shaft of the suspension smelting furnace so that the temperature of the blister fed from the blister layer in settler of the suspension smelting furnace is between 1250 and 1400° C.
In a preferred embodiment of the method, the method comprises preferably, but not necessarily, feeding copper concentrate such as copper sulfide concentrate and/or copper matte and/or reaction gas into the reaction shaft of the suspension smelting furnace so that the temperature of the slag fed from the first slag layer in the settler of the suspension smelting furnace is between 1250 and 1400° C.
In a preferred embodiment of the method, the method comprises feeding copper concentrate such as copper sulfide concentrate and/or copper matte and/or reaction gas into the reaction shaft of the suspension smelting furnace so that the temperature of the blister fed from the blister layer in the settler of the suspension smelting furnace is between 1250 and 1400° C. and so that the temperature of the slag fed from the first slag layer in the settler of the suspension smelting furnace is between 1250 and 1400° C. Sometimes there is too much heat in the suspension smelting furnace and so off gas volume becomes large. This may be even be even beneficiancy now, because operating temperature can be set higher as the melt will be laundered into the slag cleaning furnace, where high heat poses no problems. The off-gas volume can be lower than normally as suspension smelting furnaces can be run hotter, which means lower off-gas volumes
Feeding blister and/or slag having temperature between 1250 and 1400° C. from the settler of the suspension smelting furnace reduces the need for thermal energy to be fed to the slag cleaning furnace for the reduction process, because the blister and/or the slag that is fed to the suspension smelting furnace is over hot i.e. contains excess thermal energy in addition to that needed for the reaction in the suspension smelting furnace. This excess thermal energy can be used in the reduction process in the slag cleaning furnace. Especially if an electric furnace is used as a slag cleaning furnace, this is particularly advantageous, because it is less expensive to create thermal energy by a suspension smelting furnace than to create thermal energy with an electric furnace.
The method comprises preferably, but not necessarily, feeding blister from the blister layer in the settler of the suspension smelting furnace into the slag cleaning furnace without refining the blister fed from the blister layer in the settler of the suspension smelting furnace prior feeding the blister fed from the blister layer in the settler of the suspension smelting furnace into the slag cleaning furnace.
The blister feeding means for feeding blister from the blister layer in the settler of the suspension smelting furnace into the slag cleaning furnace are preferably, but not necessarily, configured for feeding blister from the blister layer in the settler of the suspension smelting furnace into the slag cleaning furnace without refining the blister fed from the blister layer in the settler of the suspension smelting furnace prior feeding the blister fed from the blister layer in the settler of the suspension smelting furnace into the slag cleaning furnace.
Another advantage achievable with the method and the arrangement according to the invention is that it makes possible a simplified layout in comparison with the prior art method and arrangement shown in
In the following the invention will described in more detail by referring to the figures, which
The invention relates to a method and to an arrangement for refining copper concentrate 1.
First the method refining copper concentrate 1 and preferred embodiments and variants thereof will be described in greater detail.
The method comprises using a suspension smelting furnace 2 comprising a reaction shaft 5, a settler 6, and preferably, but not necessarily, an uptake 7.
The reaction shaft 5 of the suspension smelting furnace 2 is provided with a concentrate burner 8 for feeding copper concentrate 1 such as copper sulfide concentrate and/or copper matte and additionally at least reaction gas 9, and preferable also flux 10, into the reaction shaft 5 of the suspension smelting furnace 2 to obtain a blister layer 11 containing blister and a first slag layer 12 containing slag on top of the blister layer 11 in the settler 6 of the suspension smelting furnace 2.
The method comprises additionally using a slag cleaning furnace 3. The method comprises preferably using an electric furnace as the slag cleaning furnace 3.
The method comprises a step for feeding copper concentrate 1 such as copper sulfide concentrate and/or copper matte and additionally at least reaction gas 9, and preferable also flux 10, into the reaction shaft 5 of the suspension smelting furnace 2 to obtain a blister layer 11 containing blister and a first slag layer 12 containing slag on top of the blister layer 11 in the settler 6 of the suspension smelting furnace 2.
The method comprises additionally a step for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3 and for feeding blister from blister layer 11 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3.
The method comprises additionally a step for treating blister and slag in the slag cleaning furnace 3 with a reduction agent 16 such as coke to obtain a bottom metal layer 14 containing bottom metal copper and a second slag layer 15 containing slag on top of the bottom metal layer 14 in the slag cleaning furnace 3. In this step copper present in the slag fed from the first slag layer 12 in the suspension smelting furnace 2 moves from the second slag layer 15 to the bottom metal layer 14. The method comprises additionally a step for discharging bottom metal copper from the bottom metal layer 14 in the slag cleaning furnace 3.
The method comprises additionally a step for discharging slag 21 from the second slag layer 15 in the slag cleaning furnace 3.
In the method slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 and blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 may be fed together from the suspension smelting furnace 2 into the slag cleaning furnace 3, as shown in
In the method, slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 and/or blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 2 may be fed in batches into the slag cleaning furnace 3. Alternatively, slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 and/or blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 2 may be fed continuously into the slag cleaning furnace 3. By using continuous feeding, feeding means 16, 18, 23 for feeding blister from the blister layer 12 in the settler 6 of the suspension smelting furnace 2 and for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3 are easier to keep open.
The method comprises preferably, but not necessarily, a step for feeding bottom metal copper discharged from the bottom metal layer 14 in the slag cleaning furnace 3 to an anode furnace 4.
The method comprises preferably, but not necessarily, feeding copper concentrate 1 such as copper sulfide concentrate and/or copper matte and/or reaction gas 9 into the reaction shaft 5 of the suspension smelting furnace 2 so that the temperature of the blister fed from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 is between 1250 and 1400° C.
The method comprises preferably, but not necessarily, feeding copper concentrate 1 such as copper sulfide concentrate and/or copper matte and/or reaction gas 9 into the reaction shaft 5 of the suspension smelting furnace 2 so that the temperature of the slag fed from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 is between 1250 and 1400° C.
The method comprises preferably, but not necessarily, feeding inert gas or inert gas mixture into the slag cleaning furnace.
The method comprises preferably, but not necessarily, feeding blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3 without refining the blister fed from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 prior feeding the blister fed from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3.
The method may in some embodiments, as shown in
Next the arrangement for refining copper concentrate 1 and preferred embodiments and variants thereof will be described in greater detail.
The arrangement comprises a suspension smelting furnace 2 comprising a reaction shaft 5, a settler 6, and preferably, but not necessarily, an uptake 7.
The reaction shaft 5 of the suspension smelting furnace 2 is provided with a concentrate burner 8 for feeding copper concentrate 1 such as copper sulfide concentrate and/or copper matte and additionally at least reaction gas 9 and preferably also flux 11 into the reaction shaft 5 of the suspension smelting furnace 2 to obtain a blister layer 11 containing blister and a first slag layer 12 containing slag on top of the blister layer 11 in the settler 6 of the suspension smelting furnace 2.
The arrangement comprises additionally a slag cleaning furnace 3, which preferably, but not necessarily, is in the form of an electric furnace.
The arrangement comprises additionally feeding means 16, 18, 23 for feeding blister from the blister layer 12 in the settler 6 of the suspension smelting furnace 2 and for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3.
The slag cleaning furnace 3 is configured for treating blister and slag in the slag cleaning furnace 3 with a reduction agent 13 to obtain a bottom metal layer 14 containing bottom metal copper and a second slag layer 15 containing slag 21 on top of the bottom metal layer 14 in the slag cleaning furnace 3. In the slag cleaning furnace 3 copper present in the slag fed from the first slag layer 12 in the suspension smelting furnace 2 moves from the second slag layer 15 to the bottom metal layer 14.
The arrangement comprises additionally bottom metal discharging means 22 for discharging bottom metal copper from the bottom metal layer 14 in the slag cleaning furnace 3.
The arrangement comprises additionally slag discharging means 20 for discharging slag 21 from the second slag layer 15 in the slag cleaning furnace 3. The feeding means 18, 19, 23 for feeding blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 and for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 3 into the slag cleaning furnace 3 may, as shown in
The feeding means 18, 19, 23 for feeding blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 and for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 3 into the slag cleaning furnace 3 may, as shown in
The feeding means 18, 19, 23 for feeding blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 and for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 3 into the slag cleaning furnace 3 may, as shown in
The feeding means 16, 18, 23 may be configured for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 and/or blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 2 in batches into the slag cleaning furnace 3. Alternatively, the feeding means 16, 18, 23 may be configured for feeding slag from the first slag layer 12 in the settler 6 of the suspension smelting furnace 2 and/or blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 from the suspension smelting furnace 2 continuously into the slag cleaning furnace 3.
The bottom metal discharging means 22 for discharging bottom metal copper from the bottom metal layer 14 in the slag cleaning furnace 3 is preferably, but not necessarily as shown in
The arrangements shown in
The blister feeding means 18 for feeding blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3 are preferably, but not necessarily, configured for feeding blister from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3 without refining the blister fed from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 prior feeding the blister fed from the blister layer 11 in the settler 6 of the suspension smelting furnace 2 into the slag cleaning furnace 3.
The arrangement may comprise by gas feeding means for feeding inert gas or inert gas mixture into the slag cleaning furnace 3.
The arrangement may in some embodiments, as shown in
It is apparent to a person skilled in the art that as technology advanced, the basic idea of the invention can be implemented in various ways. The invention and its embodiments are therefore not restricted to the above examples, but they may vary within the scope of the claims.
Not Applicable.
Number | Date | Country | Kind |
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20125653 | Jun 2012 | FI | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FI2013/050646 | 6/12/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2013/186440 | 12/19/2013 | WO | A |
Number | Name | Date | Kind |
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1698443 | Lukens | Jan 1929 | A |
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4824362 | Kimura et al. | Apr 1989 | A |
6042632 | George | Mar 2000 | A |
20050217422 | Makinen et al. | Oct 2005 | A1 |
Number | Date | Country |
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9915706 | Apr 1999 | WO |
2008155451 | Dec 2008 | WO |
2009077653 | Jun 2009 | WO |
2009077651 | Jun 2009 | WO |
Entry |
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Finnish search report from priority Finnish Application No. 20125653, dated Apr. 3, 2013, 1 pg. |
International Search Report from corresponding PCT Application No. PCT/FI2013/050646, mailed Aug. 21, 2013, 4 pgs. |
Written Opinion from corresponding PCT Application No. PCT/FI2013/050646, mailed Aug. 21, 2013, 7 pgs. |
Extended European Search Report prepared by the European Patent Office for EP 13805141, Feb. 2, 2016, 3 pages. |
Number | Date | Country | |
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20150143951 A1 | May 2015 | US |