Patent Grant
10337084
The invention relates to a method for transporting reductant such as coke into a metallurgical furnace containing a bottom layer containing molten metal and a top layer on top of the bottom layer containing molten metal.
The invention also relates to a carrier for transporting reductant such as coke into a metallurgical furnace containing a bottom layer containing molten metal and a top layer on top of the bottom layer containing molten metal.
The invention relates also to a production method for producing reductant carriers.
The field of invention is especially reduction processes which are performed in slag cleaning electrical furnaces into which slag from suspension smelting furnaces are fed in order to, by means of the reduction process, recover metal such as copper or nickel from the slag that is fed into the slag cleaning electrical furnaces. In connection with this reduction process, a bottom layer containing metal is formed on the bottom of the slag cleaning electrical furnace and a top layer is formed on top of the top layer in the slag cleaning electrical furnace, and the purpose of the reduction process is to have metal to migrate (i.e. to sink) from the top layer in the slag cleaning electrical furnace to the bottom layer in the slag cleaning electrical furnace. The invention is however not limited to reduction processes, which are performed in slag cleaning electrical furnaces nor to reduction processes, which are performed after suspension smelting process to clean slag created in the suspension smelting process.
Coke is commonly used as a reductant in electric slag cleaning furnaces, which are used for recovering metal from slag originating from suspension smelting furnaces. The utilization of coke is however low, as the coke floats on top of the slag due to its low density. The reduction with coke can be improved by mixing, which results in better contact between coke and molten slag.
The object of the invention is to provide a method and a carrier for transporting reductant such as coke into a metallurgical furnace, which method and carrier provides for better contact between reductant such as coke and molten slag.
The invention is based on forming and on using carriers containing reductant such as coke and metal for transporting reductant such as coke into a metallurgical furnace containing a bottom layer containing molten metal and a top layer on top of the bottom layer containing molten metal.
The carriers will not just stay on the surface of the slag, as reductant for example in the form of coke alone does, but the carriers will sink into the slag. This is because the density the carriers are higher than the density of the reductant alone because of the metal in the carriers. The reductant in the carriers will thus not only react on the top layer/bottom layer interface i.e. at the surface of the top layer, but the carriers will be totally surrounded by slag. This will make the reduction reaction much more efficient.
As the carriers will disintegrate over time, the coke will move to the top of the slag, where it further acts as normal coke. How long this will take, depends mainly on the size of the carriers, but additionally also on how fast the metal in the carriers will melt.
The metal from the carriers will sink into the bottom layer of the metallurgical furnace and will contribute to the matte or metal phase.
In the following the method and the carrier will be described in greater detail by referring to the figures, of which
The invention relates to a method for transporting reductant such as coke into a metallurgical furnace 1 such as a slag cleaning electric furnace containing a bottom layer 2 containing molten metal such as copper or nickel and a top layer 3 on top of the bottom layer 2 containing molten metal. The top layer 3 may contain slag.
The invention relates also to a carrier 4 for transporting reductant 5 such as coke into a metallurgical furnace 1 containing a bottom layer 2 containing molten metal such as copper or nickel and a top layer 3 on top of the bottom layer 2 containing molten metal such as copper or nickel.
The metallurgical furnace 1 may be in the form of a slag cleaning electric furnace, which is used for recovering metal from slag originating from a suspension smelting furnace.
First the method and some preferred embodiments and variants of the method will be described in greater detail.
The method comprises a first providing step for providing reductant 5 and a second providing step for providing metal 6 such as copper or nickel.
The method comprises a forming step for forming carriers 4 containing reductant 5 and metal 6 of reductant 5 provided in the first providing step and metal 6 provided in the second providing step.
The method comprises a feeding step for feeding carriers 4 formed in the forming step into the metallurgical furnace 1.
The method comprises preferably, but not necessarily, forming carriers 4 containing reductant 5 and metal 6 in the forming step having at least the density of the top layer 3. In this case the method comprises preferably, but not necessarily, forming carriers 4 containing reductant 5 and metal 6 in the forming step having a density that is lower than the density of the bottom layer 2 containing molten metal.
The method comprises preferably, but not necessarily, forming carriers 4 containing reductant 5 and metal 6 in the forming step having a density of 90 to 200%, preferably 110 to 190%, more preferably 125 to 150%, of the density of the top layer 3. The forming step of the method comprises preferably, but not necessarily, pressing reductant 5 and metal 6 in the forming step by means of a press (not shown in the figures) such as a hydraulic press to form the carriers 4.
The method may comprise providing metal 6 in the second providing step in the form of copper scrap such as rejected cast anodes, spent cast anodes, and secondary copper. This provided that the bottom layer 2 containing molten metal contains copper. In such case the production method may comprise a chopping step for chopping the copper scrap, which chopping step is performed prior the forming step.
The method may comprise forming in the forming step carriers 4 containing reductant 5 and metal 6 in the form of copper so that the carriers 4 containing in mass percentages between 10 and 70% copper, preferably between 20 and 60% copper, more preferable between 25 and 50% copper, the rest being reductant 5 and optionally binder such as water and possible impurities originating from the reductant 5 provided in the first providing step and/or originating from the copper provided in the second provided step. The forming step may optionally include a drying step for strengthening of the carrier.
The method may comprise forming in the forming step carriers 4 containing reductant 5 and metal 6 having an average grain size between 10 and 200 mm.
Next the carrier 4 and some embodiments and variants thereof will be described in greater detail.
The carrier 4 contains reductant 5 and metal 6 such as copper or nickel.
The density of the carrier 4 is preferably between 3 and 7 g/cm3.
The carrier 4 contains preferably, but not necessarily, reductant 5 and metal 6 in the form of at least copper so that the carrier contains in mass percentages between 10 and 70% copper, preferably between 20 and 60% copper, more preferable between 25 and 50% copper, the rest being reductant 5 and optionally binder such as water and possible impurities originating from the reductant 5 and/or originating from the copper.
The carrier 4 may have an average grain size between 10 and 200 mm.
The invention relates also to a production method for producing carriers 4 as described earlier. The production method comprises a first providing step for providing reductant 5 and a second providing step for providing metal 6 such as copper or nickel. The production method comprises additionally a forming step for forming carriers 4 containing reductant 5 and metal 6 of reductant 5 provided in the first providing step and metal 6 provided in the second providing step.
The forming step of the production method comprises preferably, but not necessarily, pressing reductant 5 and metal 6 in the forming step by means of a press (not shown in the figures) such as a hydraulic press to form the carriers 4.
The production method may comprise providing metal 6 in the second providing step metal 6 in the form of copper scrap such as rejected cast anodes, spent cast anodes, and secondary copper. In such case, the production method may comprise a chopping step for chopping the copper scrap, which chopping step is performed prior the forming step.
The production method may comprise a drying step for strengthening of the carrier.
It is apparent to a person skilled in the art that as technology advanced, the basic idea of the invention can be implemented in various ways. The invention and its embodiments are therefore not restricted to the above examples, but they may vary within the scope of the claims.
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|---|---|---|---|
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| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/FI2015/050227 | 3/31/2015 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2015/150635 | 10/8/2015 | WO | A |
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| Number | Date | Country | |
|---|---|---|---|
| 20180179613 A1 | Jun 2018 | US |
