Patent Application
20080025939
The object of the present invention is a composition on the basis of a combination of an N-alkyl-2-mercaptoacetamide as a keratin reducing agent and at least one specific alkalizing agent for permanently shaping hair and a process therefore.
The classic technique for permanent hair shaping is typically based on two treatment steps. In the first step, the cystine-disulfide bridges of the keratin of the hair are opened by the action of a composition that contains a reducing agent (shaping composition). The hair is then put into the desired shape. In a second step, the cystine-disulfide bonds are closed again using a fixative, that is, a composition comprising an oxidant, usually hydrogen peroxide.
Thioglycolic acid, for instance in the form of its ammonium salt, is used as a classic hair keratin reducing agent but often causes considerable hair damage. Alkaline-adjusted preparations based on mercaptocarboxylic acid esters, despite being adequately effective, cause hair damage, which is expressed for instance in increased hair breakage. Often, these compositions also undesirably stress the scalp. Finally, the unpleasant odor of the conventional reducing agents used, particularly ammonia, requires intensive perfuming of the products. By using 2-mercaptopropionic acid (thiolactic acid), it is possible to solve some of these problems; however, in comparison to thioglycolic acid, which is widely used, thiolactic acid produces weaker waves and the smell is unpleasant as well.
For gentle permanent waving of damaged and especially bleached or dyed hair, waving compositions that are adjusted to be slightly acidic to neutral are preferably desired. From a professional standpoint, over the last 35 years, the thioglycolic acid esters have proved to be the reducing agents best suited for this purpose. A major disadvantage of acidic hair waving compositions based on thioglycolic acid esters, however, is that they are poorly tolerated by the eyes and skin, and the sensitizing effect of the thioglycolic acid esters. As a result the use of these hair waving compositions is widely avoided at present.
In European Patent No. 0969791 B1 it is reported that N-(3′-hydroxypropyl)-2-mercaptoacetamide has substantially lower sensitization rates than thioglycolic acid and the closest relatives in permanent waving ingredients, the N-alkyl-2-mercaptoacetamides, that is N-methylmercaptoacetamide and N-hydroxyethylmercaptoacetamide, known from the prior art documents, German Patent No. 1144440 C1 and European Patent No. EP-A 0455457 A1. Nevertheless by using an N-(3′-hydroxypropyl)-2-mercapto-acetamide with ammonia as the hair keratin reducing agent the smell still needs improvement.
The main goal of the present invention is therefore to provide a composition and a method for permanent shaping hair which improves the odor of the treated hair significantly during and after the hair shaping process and which is superior to former compositions and thus enhances the customer's acceptance of permanent hair shaping products.
Another goal of the present invention is to provide a composition and a method for permanent shaping of hair which causes less hair damage.
A further goal of the present invention is to provide a composition for permanent shaping of hair which penetrates well into the hair but less into the skin.
Yet, another goal of the present invention is to provide a composition for permanent shaping of hair which's skin compatibility is improved.
The above problems are solved by a composition for permanent hair shaping comprising:
The first essential component of the permanent hair shaping composition, the N-alkyl-2-mercaptoacetamide of formula (I), is contained in the composition for permanent shaping hair in a quantity of from about 1% to about 30% by weight, preferably from about 5 to about 20% by weight and most preferred from about 8% to about 14% by weight of the composition. The preferred salts of N-alkyl-2-mercaptoacetamide of formula (I) are the chloride, the sulfate, the acetate, or the citrate. From the N-alkyl-2-mercaptoacetamides of formula (I) the N-(3′-hydroxypropyl)-2-mercaptoacetamide is preferred.
Alkalizing Agent
The second essential component of the hair shaping composition of the invention comprises at least one alkalizing agent selected from the group consisting of lithium hydroxide, earth alkali metal hydroxides, hydroxylalkylamines with about 1 to about 4 carbon atoms in the alkyl residue and one or two hydroxygroups on at least one alkyl residue, 2,2-iminobisethanoliminourea (guanidine carbonate), tetrahydro-1,4-oxazine, 2-aminoethansulfonic acid, alkaline amino acids, and the derivatives thereof.
The preferred alkalizing agents are selected from the group consisting of 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol, tris(hydroxylmethyl)-aminomethane, 2-amino-1-butanole, tris-(2-hydroxypropyl)-amine, 2-amino-5-guanidin-valeric acid, 2-aminoethansulfonic acid, ethanolamine, diethanolamine, triethanolamine, N-methyl ethanolamine, isopropanolamine, diisopropanolamine, triisopropanolamine, arginine, lysine, glucamine, 2,2-iminobisethanoliminourea (guanidine carbonate), tetrahydro-1,4-oxazine, lithium hydroxide and magnesium oxide.
It is especially preferred that the alkalizing agent be selected from the group consisting of ethanolamine, diethanolamine, triethanolamine, arginine, and tris(hydroxylmethyl)-aminomethane.
The preferred amount of the alkalizing agent is from about 0.1% by weight to about 15% by weight, more preferred from about 1% by weight to about 10% by weight, most preferred from about 2% by weight to about 9% by weight.
Further Hair Keratin Reducing Agent
Although it is preferred that the N-alkyl-2-mercaptoacetamide of formula (I) is the sole keratin reducing agent in the composition of the invention, it is possible that the hair shaping composition of the invention comprises at least one further hair keratin reducing agent selected from the group consisting of thioglycolic acid, thiolactic acid, 3-mercaptopropionic acid, 2-hydroxy-3-mercaptopropionic acid, cysteine, cysteamine, alkyl- or acylcysteamine with 1 to 4 carbon atoms in the alkyl residue, or the salts thereof; cysteine-(2-hydroxyethyl)ester, L-cysteine glycerine ester and glycerine mono thioglycolate. From these keratin reducing agents, thioglycolic acid, thiolactic acid, cysteine, and cysteamine are preferred.
The preferred amount of the further keratin reducing agent is from about 0.5% by weight to about 10% by weight, more preferred from about 1% by weight to about 8% by weight, most preferred from about 1% by weight to about 5% by weight.
The preferred ratio between the hair keratin-reducing agent N-alkyl-2-mercaptoacetamide of formula (I) and the further keratin-reducing agents or the mixture thereof is preferably from about 5:1 to about 2:1.
The permanent shaping composition may comprise the keratin-reducing agents, i.e., the mixture of N-alkyl-2-mercaptoacetamide of formula (I) with the other hair keratin reducing agents, particularly thioglycolic acid, thiolactic acid, and cysteine or the salts thereof, in a total amount of from about 2% to about 30% by weight, preferably from about 5% by weight to about 20% by weight and most preferred from about 6% to about 15% by weight of the composition. It is further preferred that the other hair keratin-reducing agent be a salt.
Hair Swelling and Penetration Enhancing Substances
So-called swelling agents and penetration enhancing substances may be added to the hair shaping composition, examples being urea, melamine; ethers, e.g., dipropyleneglycol mono-methyl ether; 2-pyrrolidon, imidazolidin-2-one, 1-methyl-2-pyrrolidone; alkali or ammonium thiocyanate, polyvalent alcohols, isopropanol. These agents are preferably contained in a quantity of from about 1% to about 30% by weight, more preferred from about 2% to about 10% by weight of the composition.
Disulfides
It is further advantageous if the permanent hair shaping composition, in order to avoid making the hair too kinky, contains the disulfide of a hair keratin-reducing compound (thiol), particularly 2,2′-dithio-bis[N-(3-hydroxypropyl)-acetamid], 2,2′-dithio-bis[N-(2-hydroxypropyl)-acetamid], dithioglycolic acid, dithiolactic acid and their salts. The preferred quantity for use is from about 0.1% to about 20% by weight, more preferably from about 0.5% to about 15% by weight and most preferred from about 1% to about 10% by weight of the composition, wherein the ratio between the hair keratin-reducing agents and the disulfides is preferably from about 20:1 to about 1:2, and particularly from about 10:1 to about 1:1.
Additives
It is understood that the hair shaping composition may contain all the usual and known additives for such compositions, such as thickeners, e.g., kaolin, bentonite, fatty acids, higher fatty alcohols, starches, cellulose derivatives, alginates, polyacrylic acid and its derivatives, cellulose derivatives, alginates, vaseline, and paraffin oils; wetting agents or emulsifiers from the classes of anionic, cationic, amphoteric or nonionic surface-active substances, such as fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl sulfonates, alkylbenzene sulfates, quaternary ammonium salts, alkyl betaines, ethoxylated alkylphenols, fatty acid alkanolamides or ethoxylated fatty acid esters; and opacifiers, such as polyethyleneglycol esters; alcohols, such as ethanol, propanol, isopropanol; water-soluble polyhydric alcohols having two or more hydroxyl groups in the molecule. Typical examples of such polyhydric alcohols are dihydric alcohols such as ethylene glycol, 1,2- or 1,3-propanediol, 1,2-pentanediol and glycerine; further, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol; trihydric alcohols, such as glycerine, trimethylol propane, 1,2,6-hexanetriol and the like; tetrahydric alcohols, such as penthaerythritol; pentahydric alcohols, such as xylytol, etc.; hexahydric alcohols such as sorbitol, mannitol; polyhydric alcohol polymers such as diethylene glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerine, polyethylene glycol, triglycerine, tetraglycerine, polyglycerine; dihydric alcohol alkyl ethers, such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether; dihydric alcohol alkyl ethers, such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether; dihydric alcohol ether esters, such as ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diadipate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate; glycerin monoalkyl ethers, such as xyl alcohol, selachyl alcohol, batyl alcohol; sugar alcohols, such as sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch sugar, maltose, xylytose, starch sugar reduced alcohol, glysolid, tetrahydrofurfuryl alcohol, POE tetrahydrofurfuryl alcohol, POP butyl ether, POP POE butyl ether, tripolyoxypropylene glycerin ether, POP glycerin ether, POP glycerin ether phosphoric acid, POP POE pentanerythritol ether; sugars, such as D-glucose; solubilizers, stabilizers, buffer substances, perfume oils, dyes, and hair-conditioning and hair-care ingredients, such as lanolin derivatives, cholesterol, pantothenic acid, and betaine.
Cationic Additives
Cationic surfactants that can be preferably used in the cosmetic composition of the present invention contain amino or quaternary ammonium moieties. Among the quaternary ammonium-containing cationic surfactant materials useful herein are those of the general formula (II)
[NR4,R5,R6,R7]+·X− (II)
wherein R4 to R7 are independently an aliphatic group of from about 1 to about 22 carbon atoms or an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkylaryl group having from about 1 to about 22 carbon atoms; and X− is a salt-forming anion such as those selected from halogen (e.g., chloride, bromide, iodide), acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfate and alkylsulfate radicals.
The aliphatic groups may contain, in addition to carbon and hydrogen atoms, either linkages, and other groups, such as amino groups. The longer chain aliphatic groups, e.g., those of about 12 carbons, or higher, can be saturated or unsaturated. Especially preferred are di-long chain (e.g., di C12-C22, preferably C16-C18, aliphatic, preferably alkyl) and di-short chain (e.g., C1-C3 alkyl, preferably C1-C2 alkyl) ammonium salts. Salts of primary, secondary, and tertiary fatty amines are also suitable cationic surfactant materials. The alkyl groups of such amines preferably have from about 12 to about 22 carbon atoms, and may be substituted or unsubstituted. Such amines, useful herein, include stearamido propyl dimethyl amine, diethyl amino ethyl stearamide, dimethyl stearamine, dimethyl soyamine, soyamine, myristyl amine, tridecyl amine, ethyl stearylamine, N-tallowpropane diamine, ethoxylated (5 moles E.O.) stearylamine, dihydroxy ethyl stearylamine, and arachidylbehenylamine. Suitable amine salts include the halogen, acetate, phosphate, nitrate, citrate, lactate, and alkyl sulfate salts. Such salts include stearylamine hydrochloride, soyamine chloride, stearylamine formate, N-tallowpropane diamine dichloride, and stearamidopropyl dimethylamine citrate. Preferred cationic surfactants are cetyl trimethyl ammonium salts, as for example, Genamin® CTAC, i.e., cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium salts, e.g., behenyl trimethyl ammonium chloride; dimethyl ditallow ammonium salts; stearyl amidopropyl dimethylamine; esterquats, as for example, tetradecyl betainester chloride, diesterquats, as for example, dipalmitylethyl dimethylammoniumchloride (Armocare® VGH70 of Akzo, Germany), or a mixture of distearoylethyl hydroxyethylmonium methosulfate and cetylstearyl alcohol (Dehyquart® F-75 of Henkel, Germany).
Useful are also a cationic copolymer, a cationic cellulose polymer, or a cationic silicon polymer, where the quaternary nitrogen groups are contained either in the polymer chain or preferably as substituents on one or more of the monomers. The ammonium group-containing monomers can be copolymerized with non-cationic monomers. Suitable cationic monomers are unsaturated, radical polymerizable compounds carrying at least one cationic group, particularly ammonium-substituted vinyl monomers, such as trialkyl methacryl oxyalkyl ammonium, trialkyl acryloxyalkyl ammonium, dialkyl diallyl ammonium, and quaternary vinyl ammonium monomers with groups containing cyclic, cationic nitrogen, such as pyridinium, imidazolium, or quaternary, e.g., alkyl vinyl imidazolium, alkyl vinyl pyridinium, or alkyl vinyl pyrrolidone salts. The alkyl groups of these monomers are preferably lower alkyl groups, such as C1 to C7 alkyl groups, with C1 to C3 alkyl groups being especially preferred.
The ammonium group-containing monomers can be copolymerized with non-cationic monomers. Suitable co-monomers are, for example, acrylamide, methacrylamide, alkyl- and dialkyl acrylamide, alkyl- and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl caprolactam, vinyl pyrrolidone, vinyl ester, e.g., vinyl acetate, vinyl alcohol, propylene glycol, or ethylene glycol, wherein the alkyl groups of these monomers are preferably C1 to C7 alkyl groups, with C1 to C3 alkyl groups being especially preferred.
Preferred polymers with quaternary amine groups are polymers selected from those described in the CTFA Cosmetic Ingredient Dictionary (10th edition of 2004) under the designations as follows: the polymers sold by the company Rhodia Inc. under the trade names Mirapol® A15 (POLYQUATERNIUM-2); Mirapol® AD1 (POLYQUATERNIUM-17), Mirapol® AZ1 (POLYQUATERNIUM-18) and Mirapol® 175 (POLYQUATERNIUM-24); the copolymer of dimethyldiallylammonium chloride and acrylamide, sold by the company Ondeo Nalco under the trade names Merquat® 550, Merquat® 550L and Merquat® S (POLYQUATERNIUM-7); quaternized hydroxyethyl cellulose (POLYQUATERNIUM-10); vinyl pyrrolidone/dimethyllamino ethylmethacrylate methosulfate copolymer, sold under the trade names Gafquat® 755 N and Gafquat® 734 (POLYQUATERNIUM-11) by Gaf Corp. in the USA; Gafquat® 734 is especially preferred; copolymer of acrylamide and betamethacrylyloxyethyl trimethyl ammonium chloride, sold by Rohm GmbH in Germany under the trade name Rohagit® KF 720 (POLYQUATERNIUM-15); a copolymer sold by BASF in Germany under the trade name LUVIQUAT® FC 550, LUVIQUAT® FC905 and LUVIQUAT® HM 552 consisting of polyvinyl pyrrolidone and imidazolimine methochloride (POLYQUATERNIUM-16); the copolymer of diallyldimethylammonium chloride and acrylic acid (80/20), sold by the company Calgon under the trade name Merquat® 280 (POLYQUATERNIUM-22); polymers sold under the trade name Quatrisoft® LM 200 by the company Amerchol, defined as polymeric quaternary ammonium salt of hydroxyethyl cellulose reacted with a lauryl dimethyl ammonium substituted epoxide (POLYQUATERNIUM-24); the copolymer of acrylamide and dimethylaminoethyl methacrylate (20/80 by weight) quaternized with methyl chloride, sold as a 50% by weight dispersion in a mineral oil under the trade name Salcare® SC92 by the company Ciba Specialty Chemicals (POLYQUATERNIUM 32); the methosulfate of the copolymer of methacryloyloxyethyl trimethylammonium and methacryloyloxyethyl dimethylacetylammonium, sold under the trade name Plex® 7525L and Plex® 3074L by the company Rohm GmbH/Germany (POLYQUATERNIUM-35); a terpolymer sold by Calgon in the USA under the trade name Merquat® Plus 3300 consisting of dimethyl diallyl ammonium chloride, sodium acrylate and acrylamide (POLYQUATERNIUM-39); a terpolymer from ISP in the USA, sold under the trade name Gaffix® VC 713 consisting of vinyl pyrrolidone, dimethylamino ethyl methacrylate, and vinyl caprolactam; and the copolymer sold by the company Gaf under the trade name Gafquat® HS 100 consisting of vinyl pyrrolidone/methacrylamidopropyltrimethyl ammonium chloride; the cationic polymer sold under the trade name Polymer SL®-60 (CTFA: POLYQUATERNIUM-67) by the company Amerchol.
Suitable cationic polymers that are derived from natural polymers are cationic derivatives of polysaccharides, for example, cationic derivatives of cellulose, starch, or guar. Furthermore, chitosan and chitosan derivatives are suitable. Suitable cationic polysaccharides display the general formula
G-O—B—N+RaRbRc Y− (III)
G is an anhydroglucose residue, for example, starch or cellulose anhydroglucose;
B is a divalent bonding group, for example, alkylene, oxyalkylene, polyoxyalkylene, or hydroxy-alkylene;
Ra, Rb, and Rc are independently from one another alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, or alkoxyaryl each having about 1 to about 18 carbon atoms, wherein the total number of carbon atoms in Ra, Rb, and Rc is preferably a maximum of 20;
Y− is an anion, preferably chloride, bromide, sulfate, or methosulfate.
A suitable cationic cellulose is sold by Amerchol under the trade name Polymer® JR and has the INCI and CTFA designation POLYQUATERNIUM-10. A further cationic cellulose has the INCI and CTFA designation POLYQUATERNIUM-24 and is sold by Amerchol under the trade name Polymer® LM-200. A suitable cationic guar derivative is sold under the trade name Jaguar® R and has the INCI and CTFA designation Guar Hydroxypropyltrimonium Chloride.
Other suitable cationic polymers are chitosan, chitosan salts, and chitosan derivatives. The chitosans are completely or partially de-acetylated chitins (POLYQUATERNIUM-29). To produce a chitosan, one preferably starts with the chitin contained in the shell residues of crustaceans, which, as a cheaper and natural raw material, is available in large quantities. The molecular weight of the chitosan can be distributed across a broad spectrum, for example, of from about 20,000 g/mol to about 5 million g/mol. For example, a suitable low-molecular-weight chitosan is one with a molecular weight of from about 30,000 g/mol to about 70,000 g/mol. Preferably, however, the molecular weight is greater than 100,000 g/mol, or especially preferred is a molecular weight of from about 200,000 g/mol to 700,000 g/mol. The level of deacetylation is preferably from about 10% to about 99% by weight, with about 60% to about 99% by weight being especially preferred.
A suitable chitosan is sold, for example, by Kyowa Oil&Fat in Japan under the trade name Flonac®. It has a molecular weight of about 300,000 g/mol to about 700,000 g/mol and is de-acetylated to about 70% to about 80%. A preferred chitosan salt is chitosonium pyrrolidone carboxylate, which, for example, is sold under the name Kytamer® PC by Amerchol in the USA. The chitosan contained therein has a molecular weight of about 200,000 g/mol to about 300,000 g/mol and is de-acetylated to about 70% to about 85%. Quaternized, alkylated, or hydroxyalkylated derivatives, for example, hydroxyethyl or hydroxybutyl chitosans can be considered as useful chitosan derivatives.
The chitosans or chitosan derivatives are preferably present in their neutralized or partially neutralized form. The level of neutralization for the chitosan or the chitosan derivative is preferably at least 50% by weight, with about 70% to about 100% by weight being especially preferred, based on the number of free base groups. In principle, all cosmetically compatible inorganic or organic acids can be used as neutralizers, such as, formic acid, malic acid, succinic acid, tartaric acid, citric acid, malonic acid, oxalic acid, and pyrrolidone carboxylic acid, of which the citric acid is preferred.
Other suitable cationic polymers that can be contained in the permanent shaping composition according to the present invention are cationic modified protein derivatives or cationic modified protein hydrolysates and are, for example, known under the INCI designations Lauryldimonium Hydroxypropyl Hydrolyzed Wheat Protein, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, or Hydroxypropyltrimonium Hydrolyzed Wheat, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxypropyltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, and Hydroxypropyltrimonium Hydrolyzed Vegetable Protein.
Suitable cationically derived protein hydrolysates are substance mixtures, which, for example, receive glycidyl trialkyl ammonium salts or 3-halo-2-hydroxypropyl trialkyl ammonium salts via the conversion of alkaline, acidic, or enzyme-hydrolyzed proteins. Proteins that are used as starting materials for the protein hydrolysates can be of plant or animal origin. Customary starting materials are, for example, keratin, collagen, elastin, soy protein, rice protein, milk protein, wheat protein, silk protein, or almond protein. The hydrolysis results in material mixtures with mole masses in the range of about 100 to about 50,000. Customary, mean mole masses are in the range of about 500 to about 1,000. It is advantageous if the cationically derived protein hydrolysates have one or two long C8 to C22 alkyl chains and two or one short C1 to C4 alkyl chain accordingly. Compounds containing one long alkyl chain are preferred.
Suitable cationic silicon polymers either have at least one least one ammonium group, examples are POLYSILICONE-9; preferred are diquaternary polysiloxanes as defined in European Patent No. 0714654 A1 and those having the chemical name Dimethylsiloxane, 3-(3-((3-cocoamidopropyl)dimethylammonio)-2-hydroxypropoxy)propyl group terminated acetate (CAS 134737-05-6), defined in the CTFA as QUATERNIUM-80 and sold under the trade names Abil Quat® 3270, Abil® Quat 3272 and Abil® Quat 3474 by the company Th. Goldschmidt AG, Germany.
The most preferred cationic polymers which may be comprised in the composition of the invention are cationic polymers selected from the group consisting of the polymer of dimethyl diallyl ammonium chloride (CTFA: POLYQUATERNIUM-6); vinylpyrrolidon/dimethylaminoethylmethacrylat methosulfate (CTFA: POLYQUATERNIUM-11); aminoethylaminopropylsiloxane/dimethylsiloxan-copolymer emulsion; quaternized vinylpyrrolidon/dimethylaminoethylmethacrylate-copolymer; copolymer of methylvinylimidazoliumchloride and vinylpyrrolidone (CTFA: POLYQUATERNIUM-16); the quaternary ammonium salt of the terpolymer of acrylic acid/diallyldimethylammonium chloride/acrylamide; ethanaminium, N,N,N-trimethyl-2-[(methyl-1-oxo-2-propenyl)oxy]-chloride homopolymer (CTFA: POLYQUATERNIUM-37); the copolymer of hydroxyethyl cellulose and diallyldimethylammonium chloride; the copolymer of acrylamide and diallyldimethylammonium chloride (CTFA: POLYQUATERNIUM-7); the copolymer of acrylamide and betamethacrylyloxyethyl trimethyl ammonium chloride (CTFA: POLYQUATERNIUM-5); the copolymer of methacrylamide and betamethacrylyloxyethyl trimethyl ammonium chloride (CTFA: POLYQUATERNIUM-15); the copolymer of polyvinyl pyrrolidone and imidazolimine methochloride; the copolymer of diallyldimethyl ammonium chloride and acrylic acid (CTFA: POLYQUATERNIUM-22); the copolymer of vinyl pyrrolidone and methacrylamidopropyl trimethyl ammonium chloride (CTFA: POLYQUATERNIUM-28); the methosulfate of the copolymer of methacryloyloxyethyl trimethylammonium and methacryloyloxyethyl dimethylacetylammonium, quaternized hydroxyethyl cellulose (CTFA: POLYQUATERNIUM-10); copolymer of hydroxyethyl cellulose and diallyldimethylammonium chloride (CTFA: POLYQUATERNIUM-4); dimethylsiloxane 3-(3-((3-cocoamidopropyl)dimethylammonio)-2-hydroxypropoxy)propyl group terminated acetate; dimethylsiloxane, 3-(3-((3-cocoamidopropyl)dimethylammonio)-2-hydroxypropoxy)propyl group terminated acetate (CTFA: QUATERNIUM-80); N-(3-chloroallyl)hexaminium chloride (QUATERNIUM-15); the polyethylene glycol derivative of aminoethylaminopropylsiloxane/dimethylsiloxan-copolymer; a quaternary ammonium compound sold under the trade name Finquat® CT by the company Finetex (CTFA: QUATERNIUM-75; see CTFA 10th Edition, page 1604) and cationic silicone polymers.
Silicone Conditioning Agents
The permanent hair shaping compositions hereof can also include volatile or nonvolatile, soluble or insoluble silicones as conditioning agents. By soluble what is meant is that the silicone conditioning agent is miscible with the aqueous carrier of the composition so as to form part of the same phase. By insoluble what is meant is that the silicone forms a separate, discontinuous phase from the aqueous carrier, such as in the form of an emulsion or a suspension of droplets of the silicone.
Soluble silicones include silicone copolyols, such as dimethicone copolyols, e.g., polyether siloxane-modified polymers, such as, polypropylene oxide, polyethylene oxide modified polydimethylsiloxane, wherein the level of ethylene and/or propylene oxide sufficient to allow solubility in the composition.
Preferred, however, are insoluble silicones. The insoluble silicone hair conditioning agent for use herein will preferably have viscosity of from about 1,000 mPa·s to about 2,000,000 mPa·s at 25° C., more preferably from about 10,000 mPa·s to about 1,800,000 mPa·s, even more preferably from about 100,000 mPa·s to about 1,500,000 mPa·s at 25° C. The viscosity can be measured by means of a glass capillary viscometer as set forth in Dow Corning Corporate Test Method CTM0004, Jul. 20, 1970.
Suitable insoluble, nonvolatile silicone fluids include polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, dimethylpolysiloxane containing terminal hydroxyl groups, methylphenyl polysiloxane containing terminal hydroxyl groups and mixtures thereof. Specific examples thereof include hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, and hexadecamethylheptasiloxane.
Other insoluble, nonvolatile silicone fluids having hair conditioning properties can also be used. The term “nonvolatile” as used herein shall mean that the silicone has a boiling point of at least about 260° C., preferably at least about 275° C., more preferably at least about 300° C. Such materials exhibit very low or no significant vapor pressure at ambient conditions. The term “silicone fluid” shall mean silicone materials capable of flowing and having a viscosity of less than 1,000,000 mPa·s at 25° C. Generally, the viscosity of the fluid will be between about 5 mPa·s and 1,000,000 mPa·s at 25° C., preferably between about 10 mPa·s and about 300,000 mPa·s at 25° C.
The preferred silicones are polydimethyl siloxane, polydiethylsiloxane, and polymethylphenylsiloxane. Polydimethylsiloxane is especially preferred. The nonvolatile polyalkylsiloxane fluids that may be used include, for example, polydimethyl siloxanes. These siloxanes are available, for example, from the General Electric Company in their ViscasilR® and SF® 96 series, and from Dow Corning in their Dow Corning 200® series.
The polyalkylaryl siloxane fluids that may be used, also include, for example, polymethylphenylsiloxanes. These siloxanes are available, for example, from the General Electric Company as SF 1075 methyl phenyl fluid or from Dow Coming as 556 Cosmetic Grade Fluid.
Suitable insoluble, volatile silicone fluids include low molecular weight oligomeric polydimethylsiloxane or cyclic polydimethylsiloxane, having a viscosity of no more than 10 mPa·s at 25° C. and a boiling point under atmospheric pressure of no more than 250° C. Volatility can be achieved in linear organopolysiloxanes by selection of oligomeric organopolysiloxanes with at most 6 to 10 silicone atoms in the organopolysiloxanes backbone, e.g., Dow Corning DC200 Fluid®, having a viscosity of from about 0.65 mPa·s to about 2 mPa·s at 25° C. Preferably cyclic organopolysiloxanes having from 3 to 6 silicon atoms are utilized, for example, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane (e.g., DC 244, DC 245, DC 345 of Dow Corning).
Especially preferred, for enhancing the shine characteristics of hair, are highly arylated silicones, such as highly phenylated polyethyl silicone having refractive indices of about 1.46 or higher, especially about 1.52 or higher. When these high refractive index silicones are used, they should be mixed with a spreading agent, such as a surfactant or a silicone resin, as described below to decrease the surface tension and enhance the film forming ability of the material.
The polyether siloxane copolymers that may be used include, for example, a polypropylene oxide modified polydimethylsiloxane (e.g., Dow Corning DC-1248®) although ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used. The ethylene oxide and polypropylene oxide level should be sufficiently low to prevent solubility in the composition hereof.
Another silicone hair conditioning material that can be especially useful in the silicone conditioning agents is insoluble silicone gum. The term “silicone gum,” as used herein, means polyorganosiloxane materials having a viscosity at 25° C. of greater than or equal to 1,000,000 mPa·s. The “silicone gums” will typically have a mass molecular weight in excess of about 200,000, generally between about 200,000 mPa·s and about 1,000,000 mPa·s. Specific examples include polydimethylsiloxane, (polydimethylsiloxane) (methylvinylsiloxane) copolymer, poly(dimethylsiloxane) (diphenyl siloxane) (methylvinylsiloxane) copolymer and mixtures thereof. Preferably the silicone hair treating agent comprises a mixture of a polydimethylsiloxane gum, having a viscosity greater than about 1,000,000 mPa·s and polydimethylsiloxane fluid having a viscosity of from about 10 mPa·s to about 100,000 mPa·s at 25° C., wherein the ratio of gum to fluid is from about 30:70 to about 70:30, preferably from about 40:60 to about 60:40.
Further silicones for use herein which are preferred are amino functional siloxanes which conform to the general formula (IV)
wherein R8═OH or CH3 and Z represents the propyl, isopropyl or isobutyl group. These silicones, e.g., copolymer of amino ethyl amino propyl siloxane and dimethyl siloxane are available from Dow Corning and sold under the trade name Dow Corning 2-8566 Amino Fluid® or as a mixture with polyethylenglycol ether of tridecyl alcohol and cetyl trimethyl ammonium chloride, sold as Dow Corning 929 Cationic Emulsion®.
Silicone polymers that are specially preferred are CTFA: QUATERNIUM-80 and AMODIMETHICONE. Also preferred are volatile silicones, such as, e.g. CTFA: DIMETHICONE and CYCLOMETHICONE.
The silicone hair conditioning agent can be used in the compositions hereof at levels of from about 0.1% by weight to about 20% by weight of the composition, preferably from about 0.5% by weight to about 15% by weight, more preferably from about 1% by weight to about 10% by weight and most preferably from about 3% by weight to about 8% by weight by weight.
Additional Conditioning Agents
The cosmetic hair shaping compositions of the present invention can also comprise one or more additional conditioning agents, such as, those selected from the group consisting of liquid oils and fats such as avocado oil, tsubaki oil, turtle oil, macademia nuts oil, corn oil, mink oil, olive oil, rape seed oil, yolk oil, sesame oil, parsic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cotton seed oil, perilla oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, Chinese tung oil, Japanese tung oil, hohoba oil, germ oil, triglycerine, trioctanoic acid glycerine, triisopalmitic acid glycerine; solid fats, such as, cacao fat, coconut oil, horse fat, hardened coconut fat, palm oil, tallow, sheep fat, hardened tallow, palm kernel oil, jojoba oil, lard, ox bone fat, wood wax kernel oil, hardened castor oil; waxes, such as, beeswax, apple wax, canderilla wax, cotton wax, carunauba wax, bayberry wax, insect wax, whale wax, montan wax, rice bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, cane wax, isopropyl lanolin fatty acid, hexyllaurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether; hydrocarbons, nonvolatile hydrocarbons and hydrocarbon esters, such as, fluid paraffin, solid paraffin, vaseline, ozocerite, squalane, pristan, ceresin, squalane, petrolatum, isododecane, microcrystalline wax; fatty acid oils, ester oils, such as, cetyl octanoate, isopropyl myristate; betaine, carnitin, carnitin esters, creatine, amino acids, peptides, proteins, vitamins, phospholipids, e.g., lecithines or ceramides. Useful are also imidazolidinyl derivatives as, for example, (CTFA: QUATERNIUM-87) sold under the trade name Rewoquat® W 575 by Witco, Germany.
The amount of fatty substances preferably ranges from about 0.5% by weight to about 30% by weight, better still from about 1% by weight to about 15% by weight and most preferred from about 2% by weight to about 10% by weight of the total weight of the composition. These ranges include all specific values and sub-ranges there between, including 3%, 8%, 10%, 15%, 20%, 25%, and 30% by weight.
Fatty Alcohols
The cosmetic compositions of the present invention may also comprise at least one nonvolatile low melting point fatty alcohol. The fatty alcohols hereof have a melting point of 30° C. or less, preferably about 25° C. or less, more preferably about 22° C. or less. The unsaturated fatty alcohols hereof are also nonvolatile. By nonvolatile what is meant is they have a boiling point at 1.0 atmospheres of at least about 260° C., preferably at least about 275° C., more preferably at least about 300° C. Suitable fatty alcohols include unsaturated monohydric straight chain fatty alcohols, saturated branched chain fatty alcohols, saturated C8-C12 straight chain fatty alcohols, and mixtures thereof. The unsaturated straight chain fatty alcohols will typically have one degree of unsaturation. Di- and tri-unsaturated alkenyl chains may be present at low levels, preferably less than about 5% by total weight of the unsaturated straight chain fatty alcohol more preferably less than about 2% by weight, most preferably less than about 1% by weight. Preferably, the unsaturated straight chain fatty alcohols will have an aliphatic chain size of from C12-C22, more preferably from C12-C18, most preferably from C16-C18. Exemplary alcohols of this type include oleyl alcohol, and palmitoleic alcohol. The branched chain alcohols will typically have aliphatic chain sizes of from C12-C22, preferably C14-C20, more preferably C16-C18.
Exemplary branched chain alcohols for use herein include stearyl alcohol, cetyl alcohol, isostearyl alcohol, octyl dodecanol, and octyl decanol. Examples of saturated C8-C12 straight chain alcohols include octyl alcohol, caprylic alcohol, decyl alcohol, and lauryl alcohol. The low melting point fatty alcohols hereof are used at a level of from about 0.1% by weight to about 10% by weight of the composition, more preferably from about 0.2% by weight to about 8% by weight, most preferably from about 0.5% by weight to about 6% by weight.
It may be desirable to use waxy fatty alcohols for their conditioning benefits. In the event that such saturated fatty alcohols are present, the weight ratio of the liquid to waxy fatty alcohols is preferably no greater than about 0.25, more preferably no greater than about 0.15, more preferably than about 0.10. The total amount of fatty alcohols in the composition is preferably about 0.5% by weight to about 10% by weight, more preferably from about 1.0% by weight to about 7% by weight, and most preferably from about 2% by weight to about 5% by weight.
Other Ingredients
The cosmetic compositions herein can contain a variety of other optional components suitable for rendering such compositions more cosmetically or aesthetically acceptable or to provide them with additional usage benefits. Such conventional optional ingredients are well-known to those skilled in the art. The composition of the invention may thus comprise lipophilic or hydrophilic adjuvants which are standard in the cosmetics or dermatological fields, such as, surfactants, in particular foaming surfactants, preservatives, antioxidants, sequestering agents, solvents, fragrances, fillers, screening agents, odor absorbers, coloring materials, and lipid vesicles.
A wide variety of additional ingredients can be formulated into the present cosmetic composition. These include: hair-hold polymers, detersive surfactants, such as, anionic, nonionic, amphoteric, and zwitterionic surfactants; additional thickening agents and suspending agents, such as, xanthan gum, guar gum, starch, viscosity modifiers, such as, methanolamides of long chain fatty acids, cocomonoethanol amide, crystalline suspending agents; pearlescent aids, such as, ethylene glycol distearate; UV-filters and sunscreens, e.g., such as, p-methoxy cinnamic acid isoamylester, lipophilc cinnamic acid esters, salicylic acid esters, 4-amino benzoic acid derivatives or hydrophilic sulfonic acid derivatives of benzophenones or 3-benzyliden campher; antioxidants, such as, tocopheroles; agents for combating free radicals; preservatives, such as, benzyl alcohol, methyl paraben, propyl paraben and imidazolidinyl urea; polyvinyl alcohol; acidic pH adjusting agents, such as citric acid, formic acid, glyoxylic acid, acetic acid, lactic acid, pyruvic acid, sodium citrate, succinic acid, phosphoric acid; salts, in general, such as, sodium carbonate; sodium and potassium acetate, sodium and potassium chloride or sulfate; coloring agents, such as, any of the FD&C or D&C dyes; perfumes, sequestering agents, such as, disodium ethylenediamine tetra-acetate, and polymer plasticizing agents, such as, glycerin, disobutyl adipate, and butyl stearate.
From the nonionic surfactants optionally used those are preferred having an HLB (Hydrophilic Lipophilic Balance) of greater than 12 and the primary emulsion comprises at least one nonionic surfactant having an HLB of less than 8. The nonionic surfactant of HLB greater than 12 optionally present in the emulsion may be, for example, an ethoxylated or ethoxylated/propoxylated fatty alcohol with a fatty chain comprising from about 12 to about 22 carbon atoms, ethoxylated sterols, such as, stearyl- or lauryl alcohol (EO-7); PEG-16 soya sterol or PEG-10 soya sterol, polyoxyethylene polyoxypropylene block polymers (poloxamers) and their mixtures. Ethoxylated sterols and of poloxamers are preferred. The nonionic surfactant of HLB less than 8 can be chosen in particular from glyceryl esters, such as, mono-, di- or triglyceryl mono-, di- or triisostearate or -oleate, sugar esters, such as, sucrose or methyl glucose mono- or diisostearate or -oleate, alkylpolyglucoside ethers, such as, sorbitan isostearate, oleyl- or isostearylpolyglucoside; polyoxyethylene (20) sorbitan monostearate (CTFA: POLYSORBATE-60), and their mixtures. Sugar esters and alkylpolyglucoside ethers are preferred.
The amount of nonionic surfactant in the cosmetic composition preferably can range from about 0.1% by weight to about 5% by weight and more preferably from about 1% by weight to about 3% by weight of the total weight of the emulsion.
The additives are used in quantities usual for such purposes; for example, the wetting agents and emulsifiers in concentrations of a total of about 0.2% to about 30% by weight, the alcohols in a total quantity of about 0.1% by weight to about 20% by weight, the opacifiers, perfume oils and dyes in a quantity of about 0.01% by weight to about 1% by weight each, the buffer substances in a total quantity of about 0.1% by weight to about 10% by weight, and sugars, solubilizers, stabilizers, and hair-conditioning and hair-care ingredients in a quantity of about 0.1% by weight to about 5% by weight each, while the thickeners and solubilizers may be contained in this composition in a total quantity of about 0.5% by weight to about 20% by weight. Surfactants are preferably contained at levels of from about 0.1% by weight to about 5% by weight, more preferably from about 0.2% by weight to about 1.5% by weight, most preferably from about 0.4% by weight to about 0.8% by weight, by weight of the composition.
pH-Value
By varying the pH value, a composition can be made available that is universally suitable for every hair structure, optionally with the additional application of heat. The composition brings about an elastic, durable, and uniform waving from the root of the hair to the ends, without eliciting allergic or sensitizing reactions.
The hair shaping composition preferably has a pH value of from 2.0 to 9.5, more preferably from 4.0 to 9.0 and most preferred from 5.5 to 8.5. To establish an acidic pH value, hydrochloric acid, phosphoric acid, acetic acid, lactic acid, or citric acid can be used in particular. The acidic pH can be also adjusted with a buffer such as a phosphate buffer, a TRIS buffer or a citric buffer. The buffers may be used alone or in combination with an acid.
If the shaping composition is adjusted to be acidic (for example, to a pH=5.0 to 6.9), then esters of mercapto carboxylic acids may be present as co-agents, such as, for example, monothioglycol acid glycol esters or glycerin esters, with mercapto acetamides or 2-mercaptopropionic acid amides being preferred, in a concentration of from about 1% by weight to about 8% by weight; or the salts of the sulfuric acid, for example, sodium, ammonium, or monoethanol ammonium sulfite, in a concentration of from about 3% by weight to about 8% by weight (calculated as SO2).
Viscosity
The hair shaping composition of the present invention preferably has a viscosity at 25° C. of about 0.1 mPa·s to about 10,000 mPa·s, preferably from about 1 mPa·s to about 3,000 mPa·s, more preferably from about 2 mPa·s to about 1,000 mPa·s. Viscosity is determined—if not otherwise defined—by a HAAKE Rotation Viscometer VT 550 with cooling/heating vessel and sensor systems according to DIN 53019 (NV-DIN, SV-DIN), the shear rate is 12.9 s−1.
Packages
The shaping composition may be sold in single- or dual- or triple-component packages; the composition may be in the form of an aqueous solution, or an emulsion, or a aerosol foam, or in thickened water-based form, especially a cream, gel, foam, or paste.
Method for Permanent Hair Shaping
Details of the method are given as follows: First the hair (which is washed and towel-dried) is separated into multiple sections and then these sections are rolled onto curlers. The curlers used for permanent waves have a diameter of about 5 mm to about 13 mm, while the curlers used for straightening must have a diameter greater than 13 mm. After the rolling on curlers is finished, the curlers are thoroughly wetted down using the required quantity of the permanent shaping composition, preferably about 60 g to about 120 g.
The amount of time the permanent shaping composition stays on the hair is from about 1 minute to about 30 minutes, preferably from about 2 minutes to about 20 minutes, most preferred about 8 minutes to about 15 minutes. This action time can be shortened by adding heat via the use of a heat radiator or a hood dryer.
After the action time has elapsed that is sufficient for the permanent shaping, which is depending on hair quality, the pH value, the shaping effectiveness of the shaping composition, the desired level of change as well as on the application temperature, the hair is rinsed with water or treated with an intermediate treatment composition. Thereafter the hair is oxidatively post-treated (“fixed”). The fixing composition is used in a quantity of about 50 g to about 200 g, preferably about 80 g to about 100 g, depending on hair thickness and length. Any oxidizing composition that has been used before in fixing compositions can be used for the fixation. Examples of such oxidizing agents are potassium bromate, sodium bromate, sodium perborate, dehydroascorbic acid, hydrogen peroxide, and urea peroxide. Hydrogen peroxide is preferred. The concentration of the oxidizing agent varies depending on application time (normally about 3 minutes to about 15 minutes, or preferably about 5 minutes to about 10 minutes) and application temperature (25° C. to 50° C.). The concentration of the oxidant varies, depending on the application time (as a rule, about 5 minutes to about 10 minutes) and the application temperature. Normally, oxidizing agents are used in a concentration of from about 0.5% by weight to about 12.0% by weight, preferably from about 1% by weight to about 3% by weight, in the aqueous fixing composition.
The fixing composition can obviously contain other materials, for example, weak acids or peroxide stabilizers. The fixing composition can naturally also include other substances, such as, wetting agents, hair-care substances such as cationic polymers, weak acids, buffer substances, or peroxide stabilizers. These typical additives may be contained in the fixing composition in a quantity of from about 0.1% by weight to about 10% by weight, in particular.
Both the permanent shaping composition of the invention and the fixing composition can be present in the form of an aqueous solution or an emulsion, as well as in a thickened form on an aqueous basis, particularly as a cream, gel, or paste. It is also possible to fill these compositions into aerosol cans under pressure and to release them as aerosol foam. It is especially preferred that the fixing composition be in low viscosity liquid form. It is preferred that the fixing composition be an oxidation agent-containing, liquid preparation with a viscosity of from about 1 mPa·s to about 500 mPa·s at 25° C., wherein viscosity of from about 10 mPa·s at 25° C. is especially preferred. These viscosity values are based on measurements with a Haake rotational viscometer, type VT 501, at a shear speed of 64.5 per second.
After an action period required for the fixing composition of from about 3 minutes to about 15 minutes, preferably about 5 minutes to about 10 minutes, the curlers are removed. If necessary, the hair, after being taken down from the curlers, is oxidatively post-treated yet again, then the fixing composition is rinsed from the hair with water. The hair is then optionally treated with a known acidic rinse. It is advantageous if the hair is then finally shaped into a water wave and then dried.
It is completely surprising that the method and composition for permanent hair shaping of the invention leads to improved results in a number of respects compared to the compositions comprising the widely used shaping agent thioglycolic acid or its salt with ammonia, but mainly in that the smell of the hair treated is significantly better and the hair suffers less damage. Surprisingly also the odor during application of the compositions of the invention is significantly better compared to compositions on the basis of the widely used hair shaping agent thioglycolic acid or its salt with ammonia.
The composition and method of the invention further does not have the disadvantages of glyceryl thioglycolate and thioglycolic acid and its salts but possesses the advantages of displaying no sensitization problem and no skin irritation, whereby showing superior hair care effects. The excellent condition of hair treated with composition and method of the invention was shown by an improved soft feel of wet and dry hair, an improved uniformity of the curls from the roots to the tips, an improved elasticity of hair, and durable waving of the hair.
The following examples are intended to explain the subject of the invention in further detail, but without limiting the subject to these examples.
The pH of the composition is adjusted with tris(hydroxymethyl)aminomethane to 8.4.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 40° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of the formula given below is applied onto the curler.
Fixing Composition
The fixing composition is left on the hair for about 6 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair shows in dry and wet condition a well groomed look, a good touch, and a fine wet combing property. The hair displays a good elasticity from the tips to the roots. Even after 10 days the hair keeps its pleasant smell in the dry or wet condition.
The pH of the composition is adjusted with arginine to 8.2.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 40° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions used commonly. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 are applied onto the curler.
The fixing composition is left on the hair for about 6 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair, even at the hair tips, shows in dry and wet condition a well groomed look, a good touch, and fine wet combing properties. It exhibits a good elasticity from the tips to the roots. Even after 5 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritations were noticed.
The pH of the composition is adjusted with 2-amino-2-methyl-1-propanol to 8.2.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 38° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 5 minutes. Finally the hair is rinsed again with lukewarm water and the curlers are removed. The hair, even at the hair tips, shows in dry and wet condition a well groomed look, a good touch, and fine wet combing properties. Even after 5 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
The pH of the composition is adjusted with monoethanolamine to 8.9.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. An infrared drying hood is used at a temperature of 40° C. The permanent waving composition is left on the curlers for about 14 minutes. During the treating time a much better and more pleasant smell is noticed by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 4 minutes. Finally the hair is rinsed again with lukewarm water and the curlers are removed. The hair, even at the hair tips, shows in dry and wet condition a well groomed look, a good touch, and fine wet combing properties. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
Immediately before use about 60 g of Component 1 are mixed with about 15 g of Component 2. The pH-value of the ready to use hair shaping composition is 6.8. About 75 g of the ready-to-use hair shaping composition are uniformly applied on the hair wound on curlers of about 8 mm diameter. The permanent waving composition is left on the curlers for about 15 minutes at room temperature (25° C.). During the treating time a much better and more pleasant smell is noticed by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for 5 about minutes. Thereafter the hair is again rinsed with lukewarm water and the curlers are removed. The hair shows a well groomed look, a good touch, fine wet combing properties and a uniform curl all over the head. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
The pH of the gel composition is 8.6.
After winding the hair on curlers, the above permanent waving composition in form of a gel is uniformly applied with a brush on the re-growth (upper layer on curlers). The permanent waving composition is left on the curlers for about 10 minutes at 25° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions used commonly. The hair is then rinsed with lukewarm water. Thereafter 60 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 10 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair shows a good wave in the re-growth area, a good touch, and excellent elasticity.
After winding the hair on curlers the above permanent waving liquid (Phase 1) of pH=8.2, having a viscosity of about 8 mPa·s at 25° C., is uniformly applied onto the curlers. Immediately thereafter on each of the curlers the above permanent waving gel (Phase 2) of pH=8.6, having a viscosity of about 2,800 mPa·s at 25° C., is applied with a brush on the hair re-growth. The permanent waving composition is left on the curlers for about 10 minutes at room temperature (25° C.). During the treating time a much better and more pleasant smell is noticed by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. Then the hair is rinsed with lukewarm water. Thereafter 60 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 8 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair exhibits a uniform curl from the tips to the roots and an excellent elasticity and the hair tips show a good structure. The hair has a good touch and fine wet combing properties. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
Compounding:
Although all usual propellants may be used, dimethyl ether is preferred. The above cream therefore is blended with about the same weight amount (50:50) of the propellant dimethyl ether in a conventional container of 150 ml volume. A valve with a valve diameter of about 0.5 mm and a valve cone of about 0.25 mm is used to close the container.
Application Procedure
After winding the hair on curlers, the above permanent waving composition in form of a cream is uniformly applied from the aerosol container through the spray nozzle onto on the hair re-growth (upper layer of the curlers). The permanent waving cream is left on the curlers for about 10 minutes at 25° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 is applied onto the curlers.
The fixing composition is left on the hair for about 8 minutes. Then the hair is again rinsed with lukewarm water and the curlers are removed.
Since only the hair re-growth was curled the hair now exhibits a uniform curl from the tips to the roots and has an excellent elasticity. The hair tips show a good structural condition. The hair has an excellent touch and fine wet combing properties. Over a time period of more than 2 weeks a good fastness to humidity, particularly sweat, is noticed. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
Further the customer benefits from the drop fastness of the waving cream.
The pH of this composition is adjusted with tris-(2-hydroxypropyl)amine to 8.6.
Normal hair, not previously damaged, is washed, dried with a hand towel, and wound onto curlers with a diameter of about 6 mm. After that the hair is moistened thoroughly and evenly with the above-described hair waving composition. After an action time of about 15 minutes, the hair is rinsed thoroughly with water and then oxidatively post-treated with about 80 g of about 3% by weight aqueous hydrogen peroxide solution. After the curlers are taken out, the hair is rinsed again with water, set for a water wave, and then dried. The thus-treated hair has a uniform, lively curliness. It displays a good fastness, even over a long period after the treatment, to humidity particularly sweat. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
The pH of this composition is adjusted with 2-amino-2-methyl-1,3-propandiol to 8.6.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 40° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to commonly used permanent waving compositions. The hair is then rinsed with lukewarm water. Thereafter 80 g of the fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 4 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair shows in dry and wet condition a well groomed look, a good touch, and a fine wet combing property. The hair displays a good elasticity from the tips to the roots. Even after 10 days the hair keeps its pleasant smell in the dry or wet condition.
The pH of the composition is adjusted with aqueous sodium hydroxide solution (25%) to 8.2.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 38° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 5 minutes. Finally the hair is rinsed again with lukewarm water and the curlers are removed. The hair, even at the hair tips, shows in dry and wet condition a well groomed look, a good touch, and fine wet combing properties. Even after 5 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
The pH of this composition is adjusted with an aqueous solution of sodium carbonate (20% by weight) to 8.6.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 40° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to commonly used permanent waving compositions. The hair is then rinsed with lukewarm water. Thereafter 80 g of the fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 4 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair shows in dry and wet condition a well groomed look, a good touch, and a fine wet combing property. The hair displays a good elasticity from the tips to the roots. Even after 10 days the hair keeps its pleasant smell in the dry or wet condition.
The pH of the composition is adjusted with an aqueous solution of potassium carbonate (20% by weight) to 8.9.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. An infrared drying hood is used at a temperature of 40° C. The permanent waving composition is left on the curlers for about 14 minutes. During the treating time a much better and more pleasant smell is noticed by the hairdresser as well as by the customer compared to permanent waving compositions commonly used. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 is applied onto the curler.
The fixing composition is left on the hair for about 4 minutes. Finally the hair is rinsed again with lukewarm water and the curlers are removed. The hair, even at the hair tips, shows in dry and wet condition a well groomed look, a good touch, and fine wet combing properties. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
The pH of the composition is adjusted with an aqueous solution potassium hydroxide (20% by weight) to 8.2.
After winding the hair on curlers the above permanent waving composition is uniformly applied onto the curlers. The permanent waving composition is left on the curlers for about 10 minutes. An infrared drying hood is used at a temperature of 40° C. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent waving compositions used commonly. The hair is then rinsed with lukewarm water. Thereafter 80 g of a fixing composition of example 1 are applied onto the curler.
The fixing composition is left on the hair for about 6 minutes. Finally the hair is again rinsed with lukewarm water and the curlers are removed. The hair, even at the hair tips, shows in dry and wet condition a well groomed look, a good touch, and fine wet combing properties. It exhibits a good elasticity from the tips to the roots. Even after 5 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritations were noticed.
The pH of this composition is 8.2.
The above hair straightening cream is applied onto the dry hair by a brush. Thereafter the hair is combed several times to smooth said hair. After the treating time of about 20 minutes at a temperature of 25° C. the hair is rinsed with water and then oxidatively post-treated with about 90 g of the fixing composition of example 1. After the treating time of about 8 minutes the hair is rinsed again with water. Thereafter the hair is ironed with a hot iron. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent straightening compositions commonly used. Even after 10 days the hair keeps its pleasant smell either in dry or in wet condition. Not the slightest skin irritation was noticed.
The pH of this composition is 9.3.
The above hair straightening cream is applied onto the dry hair with a brush. Thereafter the hair is combed several times to smooth said hair. After the treating time of about 16 minutes at a temperature of 28° C. the hair is rinsed with water and then oxidatively post-treated with about 80 g of the fixing composition of example 1. After the treating time of about 7 minutes the hair is rinsed again with water. Thereafter the hair is ironed with a hot iron. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent straightening compositions commonly used. Not the slightest skin irritation was noticed.
The above hair straightening cream is applied onto the dry hair with a brush. Thereafter the hair is combed several times to smooth said hair. After the treating time of about 16 minutes at a temperature of 28° C. the hair is rinsed with water and then oxidatively post-treated with about 80 g of the fixing composition of example 1. After the treating time of about 7 minutes the hair is rinsed again with water. Thereafter the hair is ironed with a hot iron. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to commonly used permanent straightening compositions.
The above hair straightening cream is applied onto the dry hair with a brush. Thereafter the hair is combed several times to smooth said hair. After the treating time of about 16 minutes at a temperature of 28° C. the hair is rinsed with water and then oxidatively post-treated with about 80 g of the fixing composition of example 1. After the treating time of about 7 minutes the hair is rinsed again with water. Thereafter the hair is ironed with a hot iron. During the treating time a much better and more pleasant smell is notices by the hairdresser as well as by the customer compared to permanent straightening compositions commonly used.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
All documents cited in the Detailed Description of the Invention are, are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this written document conflicts with any meaning or definition of the term in a document incorporated by reference, the meaning or definition assigned to the term in this written document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 06015215.4 | Jul 2006 | EP | regional |
