The invention relates to a method and a device for drying a fluid film applied to a substrate, said fluid film containing a vaporisable liquid.
According to the prior art, it is known to coat the surfaces of web materials. The web materials may be, for example, paper, plastics films, textiles or metal strips. In order to coat the surface, a fluid film is applied, which contains a vaporisable liquid and non-vaporisable components. The fluid film is solidified by vaporisation of the vaporisable liquid. This process is referred to as drying of the fluid layer.
For solidification or drying of the fluid film, it is known for example from DE 39 27 627 A1 to expose both an underside of the substrate and an opposed upper side, provided with the fluid film, to a flow of a heated transport gas. In order to direct such a flow onto the upper side, first and second filter plates arranged in succession in the transport direction are provided. Supply air is fed by the first filter plates. The exhaust air, enriched with vapours and solvents, is discharged by the second filter plates. The provision of the filter plates contributes to a relatively slow flow velocity, such that the supply air and exhaust air flows substantially in a laminar manner. Signs of flecks on the surface of the fluid film can thus be avoided.
It is known from WO 82/03450 to feed supply air by means of a distributor plate provided at a distance above the fluid film. Due to the effect of the distributor plate, the flow of the transport gas is decelerated in the region above the fluid layer. Turbulent flows are avoided. A liquid vapour escaping from the fluid film, however, cannot be discharged particularly quickly. This drying method is not particularly efficient.
In the case of the drying methods known in accordance with the prior art, large volume flows of transport gas are required, which then have to be purified and/or regenerated in a complex manner.
One object of the invention is to overcome the disadvantages according to the prior art. In particular, a method and a device are to be specified, with which a fluid film applied to a substrate can be dried whilst avoiding signs of flecks and with improved energy efficiency. In accordance with a further object of the invention, a quantity of transport gas necessary to discharge the vaporised liquid is to be kept as small as possible.
These objects are achieved by the features of claims 1 and 19. Expedient embodiments of the invention will emerge from the features of claims 2 to 18 and 20 to 35.
In accordance with the invention, a method for drying a fluid film applied to a substrate surface of a substrate, the fluid film containing a vaporisable liquid is proposed, said method comprising the following steps:
transporting the substrate on a transport surface of a transport device along a transport direction through a drying assembly,
vaporising the liquid by means of a number of heat sources arranged in succession in the transport direction, wherein each of the heat sources has a heating surface, which is arranged at a distance from 0.1 mm to 15.0 mm opposite the substrate surface, and
discharging the vaporised liquid by a first discharge opening provided between two successive heating surfaces.
In the case of the proposed method, in contrast to the prior art, the liquid is vaporised by means of a heat source provided opposite the substrate. Since the heating surface of the heat source is arranged merely at a distance from 0.1 mm to 15.0 mm opposite the substrate surface, the heat in the method according to the invention is fed to the fluid film substantially by direct heat conduction. As a result, the fluid film is advantageously heated in the direction of the substrate surface, starting from the boundary surface of the fluid film facing the heating surface. In contrast to the input of heat by means of heat radiation, where said heat is absorbed substantially at the substrate surface, a particularly effective and uniform vaporisation of the liquid can be achieved by the method according to the invention.
In accordance with a further concept of the invention, the heat is input onto the substrate by means of a plurality of heating surfaces arranged in succession in the transport direction, wherein a first discharge opening for discharging the vaporised liquid is provided between two successive heat surfaces. Thus it is possible to discharge the vaporised liquid or a transport gas absorbing the vaporising liquid particularly quickly from a drying channel, which is formed by the heating surfaces, the transport surface and also side walls running in the transport direction. With the method proposed in accordance with the invention, drying rates of up to 20 g/m2s can be achieved. This corresponds to approximately 10 times the drying rates that can be achieved with the methods known in accordance with the prior at. The required quantities of transport gas can be reduced by a factor of up to 100. The outlay for heating and purifying the transport gas can be considerably reduced. The proposed method enables a particularly efficient drying of a fluid film applied to a substrate surface of a substrate.
In accordance with an advantageous embodiment of the invention, it is proposed for the transport gas to be fed through a feed opening provided between two successive heating surfaces. The transport gas is advantageously discharged and fed alternately in the transport direction by alternately arranged discharge and feed openings.
The feed openings are formed in particular such that the transport gas is thus fed to the drying channel in a direction substantially parallel to the transport direction. The formation of a laminar flow in the drying channel can thus be assisted. The feed openings are advantageously formed such that a flow directed therewith to the first slots runs in the transport direction. However, the feed openings can also be formed such that a flow directed against the transport direction is formed from the feed openings to the discharge openings.
A distance between the discharge and the feed openings is advantageously 20 to 100 mm, preferably 40 to 70 mm.
The transport gas can be fed through the feed openings at a rate from 1 to 10 m/s. It can be discharged through the discharge openings at a further rate from 1 to 10 m/s.
In accordance with a further advantageous embodiment of the invention, the transport gas, prior to being fed, is heated to a temperature from 50° C. to 300° C., preferably 100° C. to 250° C. The relative humidity of the transport gas can be less than 50%, advantageously less than 30%. For this purpose, the transport gas is advantageously dried prior to being fed to the feed opening. The transport gas is expediently only heated following the drying.
In accordance with an advantageous embodiment, a first temperature TG of the heating surface is controlled depending on a boundary surface temperature TI of the fluid film. Here, the first temperature TG is set such that the necessary transport of the released fluid vapour away from the surface is ensured.
The heat is advantageously transferred from the heating surface to the fluid film substantially by means of direct heat conduction. Due to the short distance between heating surface and boundary surface of the fluid film and due to the arrangement of the heating surface above the boundary surface, there is hardly any convection in the transport gas. Equally, the heat contained in the transport gas by molecule movement is transferred to the fluid film similarly to “direct heat transfer”. The heat radiation irradiated from the heating surface is absorbed substantially by the substrate and/or the transport surface. It is transferred from there to the fluid film.
The first temperature TG is expediently controlled in the range from 50° C. to 200° C., preferably in the range of 80° C. and 150° C.
In accordance with a further advantageous embodiment, the transport surface is heated by means of a further heat source. A second temperature TH of the transport surface generated by the further heat source is advantageously controlled depending on the boundary surface temperature TI. Here, the second temperature TH can be controlled in particular such that the following relationship is satisfied:
T
H
=T
I
+ΔT, wherein
TI is in the range from 10° C. to 50° C. and
ΔT is in the range from 10° C. to 40° C., preferably 20° C. to 30° C.
Due to the vaporisation of the liquid, the transport surface is cooled. In order to increase the mass flow of the vaporised liquid, the transport surface is heated to a second temperature TH by means of a further heat source. Here, the second temperature TH is set such that it is greater than the boundary surface temperature TI. A particularly high mass flow of the vaporised liquid is then advantageously achieved when the difference ΔT between the boundary surface temperature TI and the second temperature TH lies in the range from 2° C. to 30° C.
Air or a non-combustible gas can be used as transport gas. The vaporisation of the liquid is expediently carried out in a non-combustible gas atmosphere, preferably a nitrogen or carbon dioxide atmosphere. An ignition of a combustible liquid vaporised within the drying assembly can thus be avoided securely and reliably.
In accordance with a further particularly advantageous embodiment, the heating surface facing the substrate is arranged at a distance from 0.2 mm to 10.0 mm, preferably 0.2 to 5.0 mm, opposite the substrate surface. The proposed short distance between the heating surface and the substrate surface enables a particularly homogeneous heating of the fluid film and therefore a uniform vaporisation of the liquid. Here, a thickness of the fluid film is of course selected such that it is smaller than the aforementioned distance. By way of example, the fluid film may have a thickness in the range from 5 μm to 300 μm, preferably 10 μm to 100 μm.
In accordance with a further advantageous embodiment, the second temperature TH is controlled such that it is always less than the first temperature TG. A temperature difference between the first TG and the second temperature TH can be controlled in particular such that a predefined temperature difference profile is set along the transport direction. The temperature gradient or the temperature difference between the first temperature TG and second temperature TH can change along the transport direction in a predefined manner. The fact that the quantity of the liquid to be vaporised decreases in the transport direction is thus taken into consideration. The change of the temperature gradient can be caused by a suitable control of the first temperature TG and/or second temperature TH or also by a change of the distance of the heating surface from the boundary surface.
An electric heating source, preferably a heating source equipped with resistance heating elements, is expediently used as heat source. Here, the resistance heating elements for example can be arranged in a grid-like manner. It is also possible to use at least one heat exchanger as heat source. Such a heat exchanger can be formed such that a liquid can flow through, similarly to a radiator for motor vehicles. A plurality of heat exchangers can also be provided in the transport direction one after the other, wherein a gap can be provided between each of the heat exchangers. Due to the gaps, the vaporised liquid can be discharged from the surface of the fluid film.
In accordance with a further advantageous embodiment of the invention, at least one rotatable drum is used as a transport device, the outer lateral surface of said drum forming the transport surface. Such a transport device can be formed in a relatively compact manner. It may also be combined with a slot die tool for applying the fluid film. In the case of the use of a rotatable drum as transport device, the heat source is formed in a manner corresponding to the outer lateral surface of the drum, that is to say the heating surfaces are arranged at a predefined short distance from the outer lateral surface. The further heat source is arranged for example within the drum. By means of the further heat source, the transport surface is heated from an underside of the transport device opposite the substrate, preferably by means of direct heat conduction. By way of example, the transport surface can be electrically heated by means of resistance heating elements. Such an electric heating enables a particularly simple control of the temperature of the transport surface.
In accordance with a further stipulation of the invention, a device for drying a fluid film applied to a substrate surface of a substrate, the fluid film containing a vaporisable liquid is proposed, said device comprising:
a transport device for transporting the substrate on a transport surface along a transport direction,
a plurality of heat sources arranged opposite the substrate in succession in the transport direction, wherein each of the heat sources has a heating surface which is arranged opposite the substrate surface at a distance from 0.1 mm to 15.0 mm, and,
an assembly for discharging the vaporised liquid, said assembly comprising a discharge opening provided between two successive heating surfaces in order to discharge the vaporised liquid.
The proposed device enables an efficient drying of a fluid film applied to a substrate. Here, the liquid is vaporised by a number of heat sources provided opposite substrate. The heating surfaces of the heat sources are arranged, in contrast to the prior art, merely at a distance from 0.1 to 15.0 mm, preferably 0.2 to 10.0 mm, from the substrate surface. A discharge opening is provided between two successive heating surfaces. The discharge opening is part of an assembly for discharging the vaporised liquid. It is thus possible to discharge the vaporised liquid quickly from the drying channel. The proposed device enables an efficient drying of a fluid film applied to a substrate surface of a substrate.
In accordance with an advantageous embodiment of the invention, an assembly for feeding transport gas is provided, said assembly comprising a feed opening provided between two successive heating surfaces in order to feed the transport gas. The discharge and the feed openings are advantageously provided alternately between the heating surfaces arranged in succession in the transport direction. A distance between the discharge and the feed openings is for example 10 mm to 100 mm, preferably 30 mm to 70 mm. The proposed alternate arrangement of the discharge and feed openings enables an efficient discharge of the vaporised liquid.
In accordance with a further advantageous embodiment, the transport gas is fed through the feed openings at a rate from 1 to 10 m/s by means of the feeding assembly. Here, the feed openings are expediently formed such that the transport gas is fed to the drying channel in a direction running substantially parallel to the transport direction. The transport gas can be fed to the drying channel both in the transport direction and against the transport direction.
A heater for heating the transport gas to a temperature from 150° C. to 300° C., preferably 100° C. to 250°, can be provided. The assembly for heating the transport gas can be combined with an assembly for drying the transport gas. Due to the short distance between the heating surfaces and the substrate proposed in accordance with the invention, only a small quantity of transport gas is required. The heater and an optionally provided drying device can be formed smaller and more cost effectively compared with the devices known in accordance with the prior art.
In accordance with a particularly advantageous embodiment of the invention, the discharging assembly is formed from a plurality of modules arranged in succession in the transport direction, wherein each of the modules has two heating surfaces and an interposed discharge opening, which, based on a flow direction of the discharged transport gas, is arranged upstream of a discharge channel. The modular design enables a simple and efficient production of devices with drying assemblies of different length in the transport direction. Furthermore, the proposed device can be easily repaired. By way of example, in the case of a failure of a heating surface, the module in question can be quickly and easily replaced.
Two successive modules are advantageously arranged such that the feed opening is formed therebetween. For this purpose, corresponding spacers and/or a connection device can be provided on the module, said connection device enabling a connection of two successive modules, thus forming the feed opening.
In accordance with a further advantageous embodiment, a feed channel and a fan for feeding the transport gas are provided upstream of the feed opening, based on the flow direction of the fed transport gas. All feed openings are expediently connected to a common feed channel.
In accordance with an advantageous embodiment, a further heat source for heating the transport surface is provided. The further heat source is expediently provided on an “underside” of the transport device opposite the substrate. For example, this further heat source may be a resistance heater.
In accordance with a further advantageous embodiment, a first control assembly for controlling a first temperature TG produced by the heating surface depending on a boundary surface temperature TI of the fluid film is provided. The control variable, specifically the first temperature TG of the heating surface, is set in accordance with a predefined algorithm depending on the boundary surface temperature TI, which forms the reference variable. Here, the first temperature TG can be controlled for example such that a predefined temperature gradient is formed between the boundary surface temperature TI and the first temperature TG.
Furthermore, a second control assembly for controlling a second temperature TH of the transport surface depending on the boundary surface temperature TI is advantageously provided. In this case, the boundary surface temperature TI is measured as a reference variable. Depending on the measured boundary surface temperature TI, the second temperature TH is set or updated by means of the control assembly. Here, the second temperature TH is expediently set or updated in such a way that a predefined boundary surface temperature TI is kept substantially constant.
The first TG and the second temperature TH can be measured for example by means of conventional thermocouples. The boundary surface temperature TI can be detected contactlessly, for example by means of an infrared measuring unit.
The first control assembly can also be omitted. In this case, the first temperature TG is kept constant. The first and the second control assembly can also be coupled. A temperature gradient between the first temperature TG and the second temperature TH can be controlled in accordance with a further predefined algorithm, such that a predefined temperature difference profile between the transport surface and the heating surface is set along the transport direction.
With regard to the advantageous embodiment of the device, reference is made to the description of the embodiments of the method. The embodiment features described with regard to the method also form embodiments of the device correspondingly.
The invention will be explained in greater detail hereinafter on the basis of the drawings, in which:
Theoretical principles of the method according to the invention will be explained briefly hereinafter on the basis of one-dimensional equations for the diffusive mass transport in accordance with temperature.
The variables used in the following equations are substantially apparent from
The temperature gradient in the air gap above the boundary surface of the fluid film satisfies the energy equation which can be specified as follows for the gas phase:
If this diffusion equation is solved, the following general solution is obtained:
wherein c1 and c2 represent two integration constants yet to be defined. These can be determined via suitable boundary conditions. These boundary conditions are as follows:
if the above equations are solved by using the boundary conditions according to c1 and c2, values are obtained for these variables that make it possible to specify the temperature profile in the gas phase as follows:
T=T1 is obtained for y=0. The boundary surface temperature T1, that is to say the temperature at the free surface of the fluid film, can thus be calculated as follows:
The mass diffusion rate per unit of area can be calculated as follows on the basis of the temperature gradient present at the free surface:
The drying time for the material to be coated can be calculated as follows:
Due to the above set of equations, the one-dimensional diffusion heat transfer problem and the problem of the associated mass release and of mass transport can be solved analytically.
With use of the boundary conditions described hereinafter, the mass diffusion rate of the vaporised liquid and the drying time were calculated inter alia. The calculation is performed under the following assumptions:
H=300 μm, h=10 μm, δG=300 μm
f=0.2, TG=350 K, TH=295 K
The following material properties were assumed to be constant, in spite of the temperature changes:
μG=1.8×10−5 kg/(ms), λG=0.024 W/(mK), CP=1.012 KJ/(KgK)
λL=0.6 W/(mK), ρL=1000 kg/m3, ΔhLH=2260 KJ/Kg
The drying of the fluid film is determined inter alia by a check of the second temperature TH on the transport surface and by the first temperature TG of the heat source. The heat source is fitted at a distance δG from the boundary surface of the fluid film facing the gas phase.
As can be seen in particular from
As can be seen in particular from
The drying assembly 7 has a further housing 12. The further housing 12 is provided with suction assemblies 14, by means of which a liquid vapour escaping from the fluid film F is sucked up.
In
The device according to the invention shown in
The further drying assembly 15 comprises a plurality of heating elements 17 arranged in succession in the transport direction T, said heating elements possibly being plate-shaped resistance heating elements. A heating surface G of the heating elements 17 is arranged at a distance δG from 2 to 10 mm from a substrate surface. Reference sign 18 denotes a further transport surface. The further transport surface 18 can be heatable. In particular, a predefined heating profile can be adjusted along the further transport surface 18. The further transport surface 18 can also be cooled.
Discharge openings 19 and feed openings 20 are provided alternately between the heating elements 17. The discharge openings 19 and/or feed openings 20 are expediently formed in a slot-like manner. In particular, the feed openings 20 can be provided with a flow-guiding assembly (not shown here). The flow-guiding assembly is formed such that the transport gas is fed to the drying channel in a direction that is substantially parallel to the boundary surface I.
In the case of the method according to the invention, the fluid film is dried not only by diffusion, but also by the convection of the transport gas in the drying channel.
A feed opening 20 for feeding transport gas, for example air L, is formed in each case between two modules arranged one after the other in the transport direction T. The feed openings 20 are also formed in a slot-like manner. A slot width of the feed openings 20 is larger than a slot width of the discharge openings 19. It is expediently twice, preferably 3 to 5 times, a slot width of the discharge openings 19.
Number | Date | Country | Kind |
---|---|---|---|
10 2012 210 431.3 | Jun 2012 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2013/051476 | 1/25/2013 | WO | 00 |