Method and device for producing three-dimensional models with a temperature-controllable print head

Information

  • Patent Grant
  • 11097469
  • Patent Number
    11,097,469
  • Date Filed
    Thursday, October 10, 2013
    11 years ago
  • Date Issued
    Tuesday, August 24, 2021
    3 years ago
Abstract
The present invention relates to a method for producing three-dimensional models by a layering technique, particulate build material being applied to a build space, and binder material subsequently being selectively applied to the build material with the aid of a printer, the binder material containing a moderating agent and subsequently being sintered with the aid of a heat lamp, the print head being protected against overheating by active and/or passive cooling.
Description
CLAIM OF PRIORITY

This application is a national phase filing under 35 USC § 371 from PCT Application serial number PCT/DE2013/000588 filed on Oct. 10, 2013, and claims priority therefrom. This application further claims priority from German Patent Applications DE 20 2012 009 796.2 filed on Oct. 15, 2012 and DE 10 2013 004 9407 filed on Mar. 22, 2013. PCT/DE2013/000588, DE 20 2012 009 796.2 and DE 10 2013 004 940.7 are each incorporated herein in their entireties by reference.


FIELD OF THE INVENTION

The invention relates to a method and a device for producing three-dimensional models according to the definition of the species in Patent Claim 1.


BACKGROUND OF THE INVENTION

A method for producing three-dimensional objects from computer data is described in the European patent specification EP 0 431 924 131. In this method, a particulate material is deposited in a thin layer onto a platform, and a binder material is selectively printed on the particulate material, using a print head. The particle area onto which the binder is printed sticks together and solidifies under the influence of the binder and, if necessary, an additional hardener. The platform is then lowered by a distance of one layer thickness into a build cylinder and provided with a new layer of particulate material, which is also printed as described above. These steps are repeated until a certain, desired height of the object is achieved. A three-dimensional object is thereby produced from the printed and solidified areas.


After it is completed, this object produced from solidified particulate material is embedded in loose particulate material and is subsequently removed therefrom. This is done, for example, using an extractor. This leaves the desired objects, from which the remaining power is removed, for example by brushing.


Other powder-supported rapid prototyping processes work in a similar manner, for example selective laser sintering or electron beam sintering, in which a loose particulate material is also deposited in layers and selectively solidified with the aid of a controlled physical radiation source.


All these methods are referred to collectively below as “three-dimensional printing methods” or 3D printing methods.


Of all the layering techniques, 3D printing based on powdered materials and the supply of liquid binder is the fastest method.


Different particulate materials, including polymer materials, may be processed using these methods. However, the disadvantage here is that the particulate material feedstock may not exceed a certain powder density, which is usually 60% of the density of the solid.


Nevertheless, the strength of the desired components depends to a significant extent on the density reached. For a high strength of the components, it would therefore be necessary to add 40% and more of the particulate material volume in the form of the liquid binder. This is a relatively time-consuming process, not only due to the single-drop supply, but also due to many process problems which arise, for example, from the inevitable reduction of the amount of liquid during solidification.


In another embodiment, which is known to those skilled in the art as “high-speed sintering,” abbreviated as HSS, the particulate material is solidified by supplying infrared radiation. The particulate material is physically bound using a melting operation. The comparatively poor absorption of thermal radiation in colorless plastics is utilized here. However, this absorption may be increased many times by introducing an IR acceptor, also known as a moderating agent, into the plastic. The IR radiation may be introduced in different ways, e.g., using a rod-shaped IR lamp, which is moved evenly over the build space. The selectivity is achieved by printing the particular layer with an IR acceptor in a targeted manner. The IR radiation is coupled into the particle material in the areas that are printed much more effectively than into the unprinted areas. This results in a selective heating in the layer beyond the melting point and thus to selective solidification. This process is described, for example, in EP1740367B1 and EP1648686B1. In these publications, a simple device is also demonstrated, which, however, is operational only on a small scale and is not suitable for printing larger build spaces, since it lacks a corresponding temperature management system.


The object of the present invention is thus to provide a scalable device, with the aid of which the HSS process is facilitated or which at least improves the disadvantages of the prior art.


The device according to the invention comprises a build plane, onto which the layers of the particulate material are deposited. The build plane is moved layer by layer through a build space, using a linear positioning unit. The build space may be defined, for example, by a job box, which may be removed from the device at the end of the process. The device parts for applying the layers move within a process chamber. The device for applying the layer may be, for example, a vibration coater (DE10216013B4) or a counter-driven roller (EP0538244B1) or a simple scraper, which applies the particulate material to the build space in a thin layer that is 20 μm to 300 μm thick, preferably 50 μm to 200 μm thick.


A print head, which has at least one nozzle end prints the particular layer with an IR acceptor, is also situated in the process chamber.


in principle, it is possible to deposit the IR acceptor in a vector-like manner onto the build space in the form of a jet or in the form of single drops. To achieve a suitable resolution, the jet or drop size should be in a range from 20 to 200 μm. To achieve higher process speeds, it is advantageous to use a print head which generates single drops with the aid of a large number of nozzles and moves over the build plane in a grid-like pattern. An IR lamp, which illuminates the build plane as a whole or parts of the build plane in the form of a spot or a line, is also situated in the process chamber. In the latter two cases, the IR lamp must be moved over the build space with the aid of a positioning unit in order to illuminate the entire build space. A rod-shaped IR lamp has proven to be advantageous, which extends over the entire width of the build space and lights up a relatively narrow area in the positioning direction. The positioning units for moving the coater, the print head and the IR lamp may be designed independently of each other or in combination. The lamp embodied in the shape of a rod is advantageously situated on the back side of the coater unit. In this manner, the coater may carry out the exposure to light when returning to the starting position, while the movement in the other direction is used for coating, possibly with reduced lamp power. The print head in this embodiment may be mounted on another moving axis farther behind [sic; the] lamp.


The build plane preferably moves in a build cylinder which is open at least on the side of the build plane and forms the build space together therewith. The build space may advantageously be removed from the device at the end of the printing process. The device may then carry out a new layering process by inserting another build space.


The HSS process may be used to process many polymer materials in particulate form, for example polyamide. Graphite, for example, may be used as the IR acceptor, which is mixed in a carrier fluid in the form of a suspension. Various easy-to-print fluids, such as isopropyl alcohol, din/ethyl succinate and, with restrictions, ethyl alcohol or water, are suitable as carrier fluids.


The process must be set in such a way that the temperature in the printed areas is above the melting point of the particulate material, at least for a short period of time. In the case of polyamide 12, or PA 12 for short, this temperature is approximately 180° C. On the other hand, the temperature in the unprinted areas should be as low as possible, since the polymer material may change irreversibly even at lower temperatures.


The quantity of IR energy introduced into the particulate material may be set, for example, by means of the lamp power or by means of the speed at which the rod-shaped lamp moves over the build space. The disadvantage of the method is that the carrier fluid for the IR acceptor evaporates in the printed areas and, during this process, the temperature thereby decreases in the areas. It is therefore advantageous to increase the temperature in the build space to a higher level with the aid of suitable measures in order to minimize the necessary temperature difference that must be overcome with the aid of the lamp. Care should also be taken to avoid selecting too high a temperature in order to minimize damage to the particulate material. In principle, it is also possible to preheat the particulate material prior to coating. However, it has been demonstrated that the particulate material very quickly adapts to the ambient temperature during and after coating and dissipates the thermal energy again. A temperature range of 60° C.-120° C. for PA 12 has been demonstrated to be advantageous for a build space atmosphere. A temperature range of 75° C. to 95° C. is even more advantageous. It is possible that the particulate material would already begin to react with the oxygen in the air at these temperatures. It may therefore be necessary to apply a protective gas to the build space. Nitrogen, for example, is suitable as the protective gas; other gases such as argon may also be used.


To increase the temperature in the build space to the desired level, it may be necessary to provide additional heating means in the device. This may be done, for example, in the form of IR radiators above the build space, which heat the entire build space as evenly as possible. However, it would also be conceivable to remove the air from the process chamber, heat it using corresponding means, such as a heater battery, and blow it back into the process chamber in a targeted manner. Moreover, it is advantageous if the heat in the process chamber is maintained at a preferably constant level. For this purpose, a temperature controller is advantageous, which regulates the heating means in the build space in interaction with a temperature sensor. The temperature gradient on the build space should not exceed 10° C. To simplify the temperature regulation, it is desirable if as little heat as possible is lost to the surroundings. It is therefore necessary to insulate the process chamber using suitable measures and to provide corresponding seals on doors and flaps. The same applies to the build space, which is also designed in such a way that little heat is dissipated to the surroundings. This is done by providing the build cylinder with a double-walled design, including corresponding insulation at the contact points. In principle, it is also possible to compensate for the temperature loss in the build space by means of an active heating, e.g., of the inner walls of the build cylinder and/or the building platform. Another option is to actively introduce preheated gas into the build space, which acts as an energy carrier and transfers the heat to the particulate material feedstock. The gas may be introduced, for example, by means of bores in the building platform.


So-called filament dispensers, which deflect a fluid stream onto the build space via a nozzle, may be used as the print head. The fluid stream contains the IR acceptor, e.g., in the form of solid graphite particles in a solvent suspension. The nozzle should have a diameter of 0.1-0.5 mm for a suitable print resolution. A valve may be inserted upstream from the nozzle, which is able to quickly switch the fluid stream. The nozzle should be moved over the build space at a short distance of only a few mm to ensure the positioning accuracy of the deposition of the fluid stream. The filament dispenser is moved over the build space in a vector-like manner with the aid of at least two linear axes. The kinematics preferably comprise a portal with three linear axes. In principle, other kinematics of motion are also conceivable, for example, an articulated arm robot, which guides the filament dispenser over the build space.


In one preferred embodiment, the IR acceptor is dispensed in fluid form onto the build space using a print head which includes a large number of single-drop generators. Print heads of this type are known from many applications, including 3D printing, where a binder instead of the IR acceptor is dispensed in layers onto a particulate material.


Drop generators of this type work according to different principles, for example the piezo principle or the bubblejet principle. In addition to these so-called drop-on-demand single drop generators, continuous systems are also known, in which a switchable stream of single drops is generated. In principle, all these systems are suitable for the aforementioned task; however, the piezo systems have significant advantages with regard to lifespan, performance and economic feasibility.


Piezoelectric printing systems work with one or multiple open nozzles. The nozzle diameters are usually less than 80 μm. A pressure pulse is briefly applied to the fluid in equally small pump chambers with the aid of a piezoelectric actuator. The fluid is significantly accelerated in the nozzles and emerges therefrom in the form of drops. Due to this functionality, certain limits are imposed on the present device. Thus, the fluid must have a relatively low viscosity. The viscosity should preferably be less than 20 mPas. In addition, the IR acceptor particles mixed into the carrier fluid must be much smaller than the narrowest channel width in the printing system. As a result, the particles are preferably smaller than 5 μm and even more preferably smaller than 1 μm. Due to the operating principle of the printing system using the pressure surge, it is necessary for all channels and the pump chambers to be filled with the fluid without any gas bubbles. To maintain this condition during operation as well, it is necessary either to select a carrier fluid which has an evaporation temperature above the operating temperature or to control the temperature of the fluid in such a way that no phase transition of the fluid takes place. Moreover, the piezoelectric actuators have a limit temperature up to which they usually may be heated without sustaining irreversible damage. This temperature is usually under 120° C.


It is apparent from the above discussion that the printing system must be protected against excessive IR radiation in the process chamber, on the one hand, and the temperature of the printing system must be regulated independently with respect to the process chamber temperature, on the other hand.


The printing system may be protected against the IR radiation by means of corresponding shielding and/or by the distance to the radiation sources. This may be effectively accomplished with radiation sources from above and from the sides. However, it is difficult to protect the print head against radiation from below, since it must move at a very short distance of 1-5 mm, preferably 2-3 mm from the powder bed. This short distance is necessary to ensure a precise positioning of the small fluid droplets on the build space. For this reason, it is necessary to keep the dwell time of the print head over the hot build space as short as possible.


Despite the aforementioned measures, the desired temperature of the printing system, which is 40° C.-60° C., is much lower than the temperature of the process chamber. Corresponding cooling measures must be provided therefor.


These measures are divided into internal cooling, external cooling and partitioning. Only a combination of different measures facilitates a precise regulation. Regulating the temperature is necessary, since the viscosity of the print fluid is greatly dependent on the temperature. The dispensing capacity of the print head, in turn, is linked to the viscosity. Consequently, an imprecise regulation may result in fluctuating supply of the moderating agent. The print head may be cooled at reversing points in the build space by passing the print head over cooled metal plates.





This may result in component distortion. For the purpose of more detailed explanation, the invention is described in greater detail below on the basis of preferred exemplary embodiments with reference to the drawing.


In the drawing:



FIG. 1 shows a method known from the prior art.



FIG. 2 shows a diagram of the process sequence of a 3D printer which operates according to the HSS principle;



FIG. 3 shows a graphic representation of the dwell times of the print head above the heated build space in a process according to FIG. 2;



FIG. 4 shows a representation of the structure of the print head according to the prior art;



FIG. 5 shows a diagram of the control of the temperature of a print head according to the prior art;



FIG. 6 shows an expanded diagram of the control of the temperature of a print head according to the prior art, including internal or external print head cooling;



FIG. 7 shows a diagram of the cooling process by means of flushing or nozzle actuation;



FIG. 8 shows an isometric view and a side view of a print module, with an indication of the flaw lines of the cooling air,



FIG. 9 shows a sectional view of the coolant channels for cooling the modules and the cover plate;



FIG. 10 shows a sectional view of the Peltier elements for actively cooling the print head with the aid of massive cooling lines;



FIG. 11 shows a sectional view of a print head, including surfaces for cooling through evaporation;



FIG. 12 shows a top view of a preferred device having partitioning in a block diagram;



FIG. 13 shows side view one preferred embodiment, including a partition wall;



FIG. 14 shows a top view of one preferred embodiment, including different partitioning means;



FIG. 15 shows a side view of one preferred embodiment, including an air curtain;



FIG. 16 shows a side view of one preferred embodiment, including a print head air cooling means;



FIG. 17 shows a side view of a device for active contacting with a fluid-cooled cleaning device and a cooling block;



FIG. 18 shows a top view of a device according to the invention, including cooled build space edges;



FIG. 19 shows a top view of one preferred embodiment, including a linear lamp, segmented activation and a diagram for the movement speed.






FIG. 1 shows a known device according to the prior art. It is used to produce bodies such as object 103. Body 103 may have a nearly arbitrary complexity. The device is referred to below as a 3D printer.


The process of constructing a body 103 begins in that movable building platform 102 is moved to its highest position in device 104. At least one layer thickness is also present between building platform 102 and the lower edge of coater 101. The coater is moved to a position in front of build space 111 with the aid of an axis system, which is not illustrated. In this position, coater 101, including its stock 113 of particulate material, is caused to vibrate. The particulate material flows out of gap 112. Outflowing material 110 fills the still empty layer due to a forward movement 106 of coater 101.


Subsequently or even during the movement of coater 101, print head 100 is set in motion by an axis system, which is also not illustrated. The latter follows a meandering path 105, which passes over the build space. According to the sectional diagrams of body 103 to be produced, the print head dispenses drops of binder 109 and solidifies these areas. This basic principle remains the same regardless of print head 100 used. Depending on the size, in extreme cases, meandering path 105 is reduced to a simple forward and backward movement.


After printing, building platform 102 is moved in direction 108. A new layer 107 for coater 101 is generated thereby. The layer cycle begins all over again when coater 101 returns to its starting position. Repeatedly carrying out this cycle produces component [sic; body] 103 in the end. After the building process, component [sic: body] 103 may be removed from the loose powder still surrounding it.


The solidification process described above, in which the particles of the particulate material are sintered, is one variant of this process. FIG. 2 shows the sequence of a method of this type. It is an expansion of the 3D printer described above.


The representation under I shows the printing process, which takes place in a manner similar to the above description. Print head 100 undergoes a meandering movement and deposits drops, including moderating agent 109, in the area of component [sic: body] 103. In terms of many of its parts, device 104 is structured like a 3D printer. The drop generation is preferably based on the piezoelectric principle, since print heads having maximum lifespans may be built hereby. This effect may be used only up to a certain limit temperature TLimit. Above this temperature, the drop generation is disturbed, or the drop generator sustains irreversible damage.


Step II deviates from the above description. A heat lamp, which generates radiation 201 adapted to the moderating agent, is guided over the build space. When it reaches the printed sites, the heat is effectively coupled into the particulate material and causes it to be sintered. The rest of the build space also absorbs not inconsiderable amounts of heat.


Process steps III and IV are again entirely similar to the description of 3D printing. Building platform 102 is first lowered into device 104 in direction 108. Coater 101 then fills layer 110 with new particulate material.



FIG. 3 shows a top view of a preferred device according to the invention. Print head 100 is omitted for the purpose of better illustrating meandering print head path 105. It is apparent that the print head executes large sections of its movement over build space 111. Simplified, the build space has a fixed temperature T111. At the beginning of the process, the print head has temperature T100=TBegin. FIG. 3 also shows a schematic representation of the dwell time of print head 100 over build space 111. The diagram shows the process steps from FIG. 2.


Assuming that the build space has temperature T111, the following conditions arise, which are illustrated in the other diagrams in FIG. 3. The print head heats up over the build space. Afterwards, it may again transfer heat to the surroundings in its idle position. Depending on the heat absorption over the build space and the heat dissipation in the idle position, a stationary temperature between start temperature TStart and build space temperature T111 sets in. It is demonstrated that, if a higher printing capacity is desired, the print head must be protected against overheating above TLimit with the aid of active and/or passive cooling. To ensure uniform dispensing capacities, the print head must also be maintained within a very narrow temperature range. Temperatures of 40-60° C. are particularly preferred in this case. According to experience, a control of ±2° C. delivers good print results.



FIG. 4 shows the structure of a print head 100 according to the prior art. Various assemblies are integrated into housing 212. Print modules 400 are essential for drop generation 109. These print modules contain the nozzles, the piezoelectric drives and the fluid system for distributing the fluid. A heater is usually also integrated for temperature regulation. These modules 400 are frequently purchased from print head manufacturers such as Dimatix, Xaar, Seico, Epson, Konica or Kyocera. Intervention into the inner structure is not possible. Modules 400 are connected to a storage tank 401, which contains print fluid 408, by hoses, a valve 406 and a filter 407. Electrical connections exist to heating controller 413 and data electronics 414. The connections are run to the outside (415, 416). The storage tank is connected to underpressure, overpressure and the refill line by additional lines switched by valves (409, 410 and 411). These lines are again run to the outside (417, 418 and 419).


On the underside, the print head is protected against the penetration of fluids or contaminants by a cover plate 402. The modules and the cover plate absorb heat 404 in the form of radiation and convection during the travel over build space 111. If the temperature exceeds the setpoint of the heating controller, the temperature may no longer be held at a constant level.



FIG. 5 shows the heating controller of existing print heads as a block diagram. Heating system 501 itself is controlled by a power controller 503. It receives its control signals from a controller 504, which, together with a sensor 500, detects the temperature directly in module 400 and thus implements a closed control circuit. The heat losses due to heat conduction to the surrounding parts, the convection in the housing and the thermal radiation losses are identified by 502. Energy is also transferred along with heated fluid drops 109 if the temperature of the drops is higher than the temperature of the refilled fluid. All losses must be compensated for by the heating system. The temperature at the lower end of the module is relevant for drop formation.



FIG. 6 shows the design of a print head according to the invention. A massive heat flow 404 is added to the aforementioned variables in this case. In the HSS process described above, this heat flow is greater than the dissipated amounts of heat. The control by the print head-internal heating system may be facilitated only by introducing additional cooling 600. Cooling system 600 may include all preferred embodiments according to the invention.


The form of heat dissipation illustrated in FIG. 7 is also covered by 600. In principle, two options exist. On the one hand, cold print fluid may be pressed through the print head. For this purpose, an overpressure 700 is applied to module 400 or to storage tank 401 (FIG. 4). A large amount of fluid is dispensed, and colder fluid enters module 400. In one preferred embodiment of the invention, the fluid enters print head 100 or print module 400 from a reservoir outside the build space at room temperature via insulated lines. This form of cooling may likewise take place via the drop generator of the print head. As in standard operation, an overpressure 702 is present at the tank.


The intensity of this form of cooling must be ascertained by controller 504 of print head heating system 501. If the temperature leaves the control range in the upward direction, more intensive cooling is required. This scenario may be detected by the switching times of heating system 501.


The cooling of module 400 may also be achieved via its housing. For this purpose, compressed air 800 may flow to the housing to compensate for heat absorption 404 from below. The compressed air nozzles may also be disposed in such a way that the flow rises vertically on the print module. In both embodiments of the invention, cover plate 402 (FIG. 4) must seal the modules toward the build space so that no particulate material is swirled up.



FIG. 9 shows another preferred embodiment of the invention. In this case, heat 404 to be dissipated is transferred from module 400 to a fluid by heat conduction. For this purpose, contact blocks 900 on module 400 and cover plate 402 are disposed in a way that facilitates good heat transfer. Contact blocks 900 have bores 903, in which cooling fluid 901 may flow. Connections 902 connect the contact blocks to a hose system, which passes out of the print head and the warm build space. The hose system has an insulated design. Depending on the accumulating heat, cooling fluid 901 is then cooled passively or actively.



FIG. 10 shows a likewise preferred device. In this case, excess heat 404 at module 400 is also dissipated via contact blocks 1000. In this case, the latter are in contact with Peltier elements 1002 via massive copper connections 1001. The Peltier elements pump the heat out of print head housing 412 when a voltage is applied to contacts 1004.


The evaporation of a liquid may also be used for cooling. FIG. 11 shows an arrangement of this type. Heat 404 at module 400 is dissipated to cover plate 402 by heat conduction. A fluid 1102, which has a suitable evaporation point, is continuously redispensed thereto. The energy is taken from steam 1100 and guided out of the print head using a discharge system 1101 to avoid harmful condensation. For example, if water is selected as the fluid, temperatures around 100° C. may be controlled.



FIG. 12 shows one preferred embodiment in the form of a block diagram. Print head 100 is separated from the build space by a partition 1200. In the phase of sintering, lowering and coating (FIG. 3, II, III, IV), print head 100 may thus cool without absorbing any more radiation from build space 111. The convection is also reduced. In the same manner, another partition 1201 may ensure that no additional heat reaches print head 100 due to the still warm lamp 200 during the passage of print head 105.



FIG. 13 shows a side view of one preferred embodiment of the invention. Partition 1300 for print head 100 is rotatably supported. Print head 100 may thus strike the partition and reach build space 111. An energy exchange takes place only when it passes through. Partition 1300 forms a chamber for the print head in which it may cool. Likewise, partition 1301 may be designed for coater 101 and lamp 200.


The partitions illustrated in FIG. 13 may also be designed to be active, as shown in FIG. 14. Once again, one partition 1400 may be provided for print head 100, and one partition 1401 may be provided for coater 101 and lamp 200. Compared to the rotatably supported partition, this has the advantage of lesser restrictions in the movement of the units in build space 111. The opening times may also be designed to be very short. For example, pneumatic actuators or electrically driven spindles are suitable as drives.



FIG. 15 shows one preferred embodiment of the partitioning means. Moving parts are dispensed with, Nozzles 1501, 1500, 1502 allow air having different temperatures to flow in the direction of build space 111 as a curtain. If a laminar flow is set, only a limited mixing of the air masses 1503, 1505 and 1504 takes piece. The temperature may be controlled and also regulated in segments via corresponding heating and cooling units.


According to the invention, it is not only possible to cool print head 100 by partitioning or from the inside, but the print head may also be cooled from the outside. FIG. 16 shows a design of this type. Print head 100 is flushed with cooling air 1601 and 1603. This air is discharged from nozzles 1600 and 1602. The flow of cooling air should not interact with the particulate material. It is therefore particularly preferred to combine the cooling with a partitioning.



FIG. 17 shows another means of cooling the print head from the outside. Print head 100 is brought directly into contact with a heat-dissipating material. This may be a fluid which absorbs the heat. This may be combined with a cleaning device for the print head. A counter-rotating roller 1700 may be brought into contact with print head 100 moving in direction 105. The roller, which has been moistened by a shower 1702 or a fluid-filled basin 1703, absorbs heat from the print head. A good thermally conductive body 1701 may also be pressed onto cover plate 102 of print head 100. This body, in turn, is passively or actively cooled, for example using a cooling fluid 1704.


Print head 100 may cool not only in its idle position but also on its path 105 on the edge of build space 111. For this purpose, build space edges 1800 must be colder than the build space. This may be achieved by the fact that edges 1800 of build space 111 are designed as pipes through which cooling air 1801 flows.



FIGS. 19 and 20 show of one particularly preferred embodiment of the invention FIG. 19 shows the design of lamp 200 in an essentially linear embodiment. A homogeneous illumination of build space 111 is achieved. Due to the control, the direct influence of the print head may be minimized. Since cooler areas may occur on the edge of the build space, despite a uniform radiation power, due to the air circulation, additional segments 2000 may be mounted here, or a lamp with segmented control of the power may be used.



FIG. 19 also shows a diagram for a particularly preferred control of the lamp movement of a linearly designed lamp. Due to the convection on build space 111, it is sensible to irradiate the edges at a slower movement speed while maintaining a constant power. It is likewise possible to adjust the power. The inertia of the lamp imposes limits on the method.


LIST OF REFERENCE NUMERALS




  • 100 Print head


  • 101 Coater


  • 102 Building platform


  • 103 Body


  • 104 Device


  • 105 Print head path


  • 106 Coater path


  • 107 Built layers


  • 108 Direction of building platform


  • 109 Microdrops


  • 110 Particulate material roll


  • 111 Build space


  • 112 Coater gap


  • 113 Powder stock


  • 200 Heat lamp


  • 400 Print module


  • 401 Storage tank


  • 402 Cover plate


  • 403 Heated surface


  • 404 Heat transfer


  • 406 Valve


  • 407 Filter


  • 408 Printing fluid


  • 409 Valve for underpressure


  • 410 Valve for overpressure


  • 411 Valve for refilling


  • 412 Print head housing


  • 413 Heating controller


  • 414 Data electronics


  • 415 Feed-through for data electronics


  • 416 Feed-through for heating controller


  • 417 Feed-through for underpressure line


  • 418 Feed-through for overpressure line


  • 419 Feed-through for refilling line


  • 500 Temperature sensor


  • 501 Heating


  • 502 Heat dissipation


  • 503 Power controller


  • 504 Controller


  • 600 Cooling


  • 700 Overpressure


  • 701 Overpressure jet


  • 702 Underpressure


  • 800 Flow, horizontal


  • 801 Flow, vertical


  • 802 Air nozzles


  • 900 Contact block


  • 901 Cooling fluid


  • 902 Cooling line*


  • 903 Cooling pipe


  • 1000 Contact block


  • 1001 Massive heat conductors


  • 1002 Peltier element


  • 1003 Pumped-off heat


  • 1004 Electrical contacting


  • 1100 Steam


  • 1102 Fluid


  • 1101 Steam guidance


  • 1200 Print head partition


  • 1201 Coater partition


  • 1300 Rotatable print head partition


  • 1301 Rotatable coater partition


  • 1400 Movable print head partition


  • 1401 Movable coater partition


  • 1500 Air nozzles for build space flow


  • 1501 Air nozzle for print head flow


  • 1502 Air nozzle for coater flow


  • 1503 Print head flow


  • 1504 Coater flow


  • 1505 Build space flow


  • 1800 Build space edge


  • 1801 Cooling air for build space edge


  • 2000 Additional lamps


Claims
  • 1. A device for producing three-dimensional models by a layering technique, particulate build material being applied to a build space in a process chamber, a moderating agent subsequently being selectively applied with the aid of an ink-jet print head, and the printed areas being solidified by supplying energy that controls a temperature of the build space, characterized in that the print head is protected against overheating by active and/or passive cooling by a cooling component that independently regulates a temperature of the print head relative to the temperature of the process chamber, wherein the cooling component acts to cool the temperature of the print head lower than the temperature of the build space; wherein the cooling takes place with the aid of the print medium to be printed; orthe cooling takes place with the aid of cooling air which is flushed around sensitive parts in the interior of the print head; orthe cooling of the print head takes place by dissipating heat with the aid of an additional fluid medium; orthe cooling takes place with the aid of Peltier elements.
  • 2. The device according to claim 1, characterized in that the device has a temperature sensor, a temperature controller and a cooling and heating unit including the cooling component.
  • 3. The device according to claim 1, characterized in that the print head is protected against the residual energy of the build space and the particulate material and active energy supply on the build space by partitioning.
  • 4. The device according to claim 3, wherein the device is characterized by one or any combination of the following: i) the print head is moved behind a flexible or fixed wall in the build space; orii) a collision with the wall is detected by sensors in the print head or the wall; oriii) the partitioning takes place using a movable wall; oriv) an air curtain partitions off the print head.
  • 5. The device according to claim 1, characterized in that the print head is protected by an external cooling means.
  • 6. The device according to claim 5, wherein the external cooling means includes: actively moving cooling air to flow around the print head; orthe print head is brought into contact with a cool object or a fluid from the outside; orthe print head is passively cooled in a cooled chamber.
  • 7. The device according to claim 1 characterized in that the condensate formation on the print head is prevented by temperature control and by controlling the humidity.
  • 8. The device according to claim 7, wherein the device includes metal cooling plates positioned at reversing points in the build space for cooling the print head by passing the print head over the metal cooling plates.
  • 9. The device according to claim 1, wherein an evaporator is disposed in the print head.
  • 10. The device according to claim 1, wherein the device has a cooling system including a temperature sensor, a temperature controller and the cooling component for cooling the print head; andthe print head is protected against the residual energy of the build space and the particulate material and active energy supply on the build space by partitioning.
  • 11. The device of claim 1, wherein the device includes an insulated build cylinder to reduce heat loss.
  • 12. The device of claim 1, wherein the process chamber is insulated.
  • 13. The device of claim 1, wherein the print head is characterized by a drop size of about 20 to 200 μm.
  • 14. The device of claim 1, wherein the print head moves at a distance of about 1-5 mm above the particulate material in the build space, and the print head is maintained at a temperature of 40 to 60° C.
  • 15. The device of claim 1, wherein the device provides a control a temperature of the print head of +/−2° C.
  • 16. The device of claim 1, wherein a lamp is used to supply energy which emits an essentially linearly distributed radiation and which is guided over the build space in such a way that the radiation essentially evenly covers the entire build space, wherein the build space is in an insulated process chamber.
  • 17. The device according to claim 16, characterized in that the power of the lamp is controlled in segments and may thus also be regulated.
  • 18. The device according to claim 17, wherein the lamp essentially emits IR radiation in the wavelength range of 1 μm to 4 μm.
  • 19. The device according to claim 18, wherein the lamp is separated from the print head by partitioning in its idle position or the lamp is spatially located at a distance from the print head in its idle position.
  • 20. The device of according to claim 19, wherein the partitioning is included and the partitioning takes place with the aid of a flexible or fixed wall; orthe partitioning takes place with the aid of an air curtain; orthe partitioning takes place with the aid of a movable wall.
  • 21. A device for producing three-dimensional models by a layering technique, particulate build material being applied to a build space in a process chamber, a moderating agent subsequently being selectively applied with the aid of an ink-jet print head, and the printed areas being solidified by supplying energy, characterized in that the print head is protected against overheating by active or passive cooling, wherein the cooling takes place with the aid of the print medium to be printed, wherein an excess of the print medium is applied from a reservoir to the print head.
Priority Claims (2)
Number Date Country Kind
20 2012 009 796.2 Oct 2012 DE national
10 2013 004 940.7 Mar 2013 DE national
PCT Information
Filing Document Filing Date Country Kind
PCT/DE2013/000588 10/10/2013 WO 00
Publishing Document Publishing Date Country Kind
WO2014/059958 4/24/2014 WO A
US Referenced Citations (371)
Number Name Date Kind
3913503 Becker Oct 1975 A
4247508 Housholder Jan 1981 A
4575330 Hull Mar 1986 A
4591402 Evans et al. May 1986 A
4600733 Ohashi et al. Jul 1986 A
4665492 Masters May 1987 A
4669634 Leroux Jun 1987 A
4711669 Paul et al. Dec 1987 A
4752352 Feygin Jun 1988 A
4752498 Fudim Jun 1988 A
4863538 Deckard Sep 1989 A
4938816 Beaman et al. Jul 1990 A
4944817 Bourell et al. Jul 1990 A
5017753 Deckard May 1991 A
5031120 Pomerantz et al. Jul 1991 A
5047182 Sundback et al. Sep 1991 A
5053090 Beaman et al. Oct 1991 A
5059266 Yamane et al. Oct 1991 A
5076869 Bourell et al. Dec 1991 A
5120476 Scholz Jun 1992 A
5126529 Weiss et al. Jun 1992 A
5127037 Bynum Jun 1992 A
5132143 Deckard Jul 1992 A
5134569 Masters Jul 1992 A
5136515 Helinski Aug 1992 A
5140937 Yamane et al. Aug 1992 A
5147587 Marcus et al. Sep 1992 A
5149548 Yamane et al. Sep 1992 A
5155324 Deckard et al. Oct 1992 A
5156697 Bourell et al. Oct 1992 A
5182170 Marcus et al. Jan 1993 A
5204055 Sachs Apr 1993 A
5216616 Masters Jun 1993 A
5229209 Gharapetian et al. Jul 1993 A
5248456 Evans, Jr. et al. Aug 1993 A
5252264 Forderhase et al. Oct 1993 A
5263130 Pomerantz et al. Nov 1993 A
5269982 Brotz Dec 1993 A
5284695 Barlow et al. Feb 1994 A
5296062 Bourell et al. Mar 1994 A
5316580 Deckard May 1994 A
5324617 Majima et al. Jun 1994 A
5340656 Sachs et al. Aug 1994 A
5342919 Dickens, Jr. et al. Aug 1994 A
5352405 Beaman et al. Oct 1994 A
5354414 Feygin Oct 1994 A
5382308 Bourell et al. Jan 1995 A
5387380 Cima et al. Feb 1995 A
5398193 deAngelis Mar 1995 A
5418112 Mirle et al. May 1995 A
5427722 Fouts et al. Jun 1995 A
5431967 Manthiram et al. Jul 1995 A
5433261 Hinton Jul 1995 A
5459498 Seccombe Oct 1995 A
5482659 Sauerhoefer Jan 1996 A
5490962 Cima et al. Feb 1996 A
5503785 Crump et al. Apr 1996 A
5506607 Sanders, Jr. et al. Apr 1996 A
5518060 Cleary et al. May 1996 A
5518680 Cima et al. May 1996 A
5555176 Menhennett et al. Sep 1996 A
5573721 Gillette Nov 1996 A
5589222 Thometzek et al. Dec 1996 A
5597589 Deckard Jan 1997 A
5616294 Deckard Apr 1997 A
5616631 Kiuchi et al. Apr 1997 A
5637175 Feygin et al. Jun 1997 A
5639070 Deckard Jun 1997 A
5639402 Barlow et al. Jun 1997 A
5647931 Retallick et al. Jul 1997 A
5658412 Retallick et al. Aug 1997 A
5665401 Serbin et al. Sep 1997 A
5717599 Menhennett et al. Feb 1998 A
5730925 Mattes et al. Mar 1998 A
5740051 Sanders, Jr. et al. Apr 1998 A
5747105 Haubert May 1998 A
5749041 Lakshminarayan et al. May 1998 A
5753274 Wilkening et al. May 1998 A
5807437 Sachs et al. Sep 1998 A
5837960 Lewis et al. Nov 1998 A
5851465 Bredt Dec 1998 A
5884688 Hinton et al. Mar 1999 A
5902441 Bredt et al. May 1999 A
5902537 Almquist et al. May 1999 A
5904889 Serbin et al. May 1999 A
5934343 Gaylo et al. Aug 1999 A
5940674 Sachs et al. Aug 1999 A
5943235 Earl et al. Aug 1999 A
5989476 Lockard et al. Nov 1999 A
5997795 Danforth Dec 1999 A
6007318 Russell et al. Dec 1999 A
6036777 Sachs Mar 2000 A
6042774 Wilkening et al. Mar 2000 A
6048188 Hull et al. Apr 2000 A
6048954 Barlow et al. Apr 2000 A
6133353 Bui et al. Oct 2000 A
6146567 Sachs et al. Nov 2000 A
6147138 Hochsmann et al. Nov 2000 A
6155331 Langer et al. Dec 2000 A
6164850 Speakman Dec 2000 A
6165406 Jang et al. Dec 2000 A
6169605 Penn et al. Jan 2001 B1
6175422 Penn et al. Jan 2001 B1
6193922 Ederer Feb 2001 B1
6210625 Matsushita Apr 2001 B1
6216508 Matsubara et al. Apr 2001 B1
6217816 Tang Apr 2001 B1
6259962 Gothait Jul 2001 B1
6270335 Leyden et al. Aug 2001 B2
6305769 Thayer et al. Oct 2001 B1
6316060 Elvidge et al. Nov 2001 B1
6318418 Grossmann et al. Nov 2001 B1
6335052 Suzuki et al. Jan 2002 B1
6335097 Otsuka et al. Jan 2002 B1
6350495 Schriener et al. Feb 2002 B1
6355196 Kotnis et al. Mar 2002 B1
6375874 Russell et al. Apr 2002 B1
6395811 Nguyen et al. May 2002 B1
6401001 Jang et al. Jun 2002 B1
6403002 Van Der Geest Jun 2002 B1
6405095 Jang et al. Jun 2002 B1
6416850 Bredt et al. Jul 2002 B1
6423255 Hoechsmann et al. Jul 2002 B1
6460979 Heinzl et al. Oct 2002 B1
6476122 Leyden Nov 2002 B1
6485831 Fukushima et al. Nov 2002 B1
6500378 Smith Dec 2002 B1
6554600 Hofmann et al. Apr 2003 B1
6596224 Sachs et al. Jul 2003 B1
6610429 Bredt et al. Aug 2003 B2
6616030 Miller Sep 2003 B2
6658314 Gothait Dec 2003 B1
6672343 Perret et al. Jan 2004 B1
6713125 Sherwood et al. Mar 2004 B1
6722872 Swanson et al. Apr 2004 B1
6733528 Abe et al. May 2004 B2
6742456 Kasperchik et al. Jun 2004 B1
6764636 Allanic et al. Jul 2004 B1
6827988 Krause et al. Dec 2004 B2
6830643 Hayes Dec 2004 B1
6838035 Ederer et al. Jan 2005 B1
6855205 McQuate et al. Feb 2005 B2
6896839 Kubo et al. May 2005 B2
6972115 Ballard Dec 2005 B1
6989115 Russell et al. Jan 2006 B2
7004222 Ederer et al. Feb 2006 B2
7037382 Davidson et al. May 2006 B2
7048530 Gaillard et al. May 2006 B2
7049363 Shen May 2006 B2
7087109 Bredt et al. Aug 2006 B2
7120512 Kramer et al. Oct 2006 B2
7137431 Ederer et al. Nov 2006 B2
7153463 Leuterer et al. Dec 2006 B2
7204684 Ederer et al. Apr 2007 B2
7220380 Farr et al. May 2007 B2
7291002 Russell et al. Nov 2007 B2
7296990 Devos et al. Nov 2007 B2
7332537 Bredt et al. Feb 2008 B2
7348075 Farr et al. Mar 2008 B2
7378052 Harryson May 2008 B2
7381360 Oriakhi et al. Jun 2008 B2
7387359 Hernandez et al. Jun 2008 B2
7402330 Pfeiffer et al. Jul 2008 B2
7431987 Pfeiffer et al. Oct 2008 B2
7435072 Collins et al. Oct 2008 B2
7435368 Davidson et al. Oct 2008 B2
7455804 Patel et al. Nov 2008 B2
7455805 Oriakhi et al. Nov 2008 B2
7497977 Nielsen et al. Mar 2009 B2
7531117 Ederer et al. May 2009 B2
7550518 Bredt et al. Jun 2009 B2
7578958 Patel et al. Aug 2009 B2
7597835 Marsac Oct 2009 B2
7641461 Khoshnevis Jan 2010 B2
7665636 Ederer et al. Feb 2010 B2
7722802 Pfeiffer et al. May 2010 B2
7807077 Ederer et al. May 2010 B2
7736578 Ederer et al. Jun 2010 B2
7748971 Hochsmann et al. Jul 2010 B2
7767130 Elsner et al. Aug 2010 B2
7795349 Bredt et al. Sep 2010 B2
7799253 Höchsmann et al. Sep 2010 B2
7879393 Ederer et al. Feb 2011 B2
7887264 Naunheimer et al. Feb 2011 B2
7927539 Ederer Apr 2011 B2
8020604 Hochsmann et al. Sep 2011 B2
8096262 Ederer et al. Jan 2012 B2
8186415 Marutani et al. May 2012 B2
8349233 Ederer et al. Jan 2013 B2
8506870 Hochsmann et al. Aug 2013 B2
8524142 Unkelmann et al. Sep 2013 B2
8574485 Kramer Nov 2013 B2
8715832 Ederer et al. May 2014 B2
8727672 Ederer et al. May 2014 B2
8741194 Ederer et al. Jun 2014 B1
8911226 Gunther et al. Dec 2014 B2
8951033 Höchsmann et al. Feb 2015 B2
8956140 Hartmann Feb 2015 B2
8956144 Grasegger et al. Feb 2015 B2
8992205 Ederer et al. Mar 2015 B2
9174391 Hartmann et al. Nov 2015 B2
9174392 Hartmann Nov 2015 B2
9242413 Hartmann et al. Jan 2016 B2
9321934 Mögele et al. Apr 2016 B2
9327450 Hein et al. May 2016 B2
9333709 Hartmann May 2016 B2
9358701 Gnuchtel et al. Jun 2016 B2
20010045678 Kubo et al. Nov 2001 A1
20010050031 Bredt et al. Dec 2001 A1
20020000163 Shen Feb 2002 A1
20020015783 Harvey Feb 2002 A1
20020026982 Bredt et al. Mar 2002 A1
20020079601 Russell et al. Jun 2002 A1
20020090410 Tochimoto et al. Jul 2002 A1
20020111707 Li et al. Aug 2002 A1
20020155254 McQuate et al. Oct 2002 A1
20020167100 Moszner et al. Nov 2002 A1
20030004599 Herbak Jan 2003 A1
20030006963 Barlow et al. Apr 2003 A1
20030065400 Beam et al. Apr 2003 A1
20030083771 Schmidt May 2003 A1
20030113729 DaQuino et al. Jun 2003 A1
20030114936 Sherwood et al. Jun 2003 A1
20030156147 Misumi Aug 2003 A1
20040003738 Imiolek et al. Jan 2004 A1
20040012112 Davidson et al. Jan 2004 A1
20040025905 Ederer et al. Feb 2004 A1
20040026418 Ederer et al. Feb 2004 A1
20040035542 Ederer et al. Feb 2004 A1
20040036200 Patel et al. Feb 2004 A1
20040038009 Leyden et al. Feb 2004 A1
20040045941 Herzog et al. Mar 2004 A1
20040056378 Bredt et al. Mar 2004 A1
20040009405 Kasperchik et al. May 2004 A1
20040084814 Boyd et al. May 2004 A1
20040104515 Swanson Jun 2004 A1
20040112523 Crom Jun 2004 A1
20040138336 Bredt et al. Jul 2004 A1
20040145088 Patel et al. Jul 2004 A1
20040170765 Ederer et al. Sep 2004 A1
20040187714 Napadensky et al. Sep 2004 A1
20040207123 Patel et al. Oct 2004 A1
20040002325 Monsheimer et al. Nov 2004 A1
20040232583 Monsheimer Nov 2004 A1
20040239009 Collins et al. Dec 2004 A1
20050000173 Harrysson Jan 2005 A1
20050003189 Bredt et al. Jan 2005 A1
20050017394 Hochsmann et al. Jan 2005 A1
20050074511 Oriakhi et al. Apr 2005 A1
20050093194 Oriakhi et al. May 2005 A1
20050167872 Ederer et al. Aug 2005 A1
20050174407 Johnson et al. Aug 2005 A1
20050179167 Hachikian Aug 2005 A1
20050212163 Bausinger et al. Sep 2005 A1
20050218549 Farr et al. Oct 2005 A1
20050219942 Wallgren Oct 2005 A1
20050280185 Russell et al. Dec 2005 A1
20050283136 Skarda Dec 2005 A1
20060013659 Pfeiffer et al. Jan 2006 A1
20060105102 Hochsmann et al. May 2006 A1
20060108090 Ederer et al. May 2006 A1
20060159896 Pfeifer et al. Jul 2006 A1
20060176346 Ederer et al. Aug 2006 A1
20060208388 Bredet et al. Sep 2006 A1
20060237159 Hochsmann Oct 2006 A1
20060251535 Pfeifer et al. Nov 2006 A1
20060254467 Farr et al. Nov 2006 A1
20060257579 Farr et al. Nov 2006 A1
20070045891 Martinoni Mar 2007 A1
20070054143 Otoshi Mar 2007 A1
20070057412 Weiskopf et al. Mar 2007 A1
20070065397 Ito et al. Mar 2007 A1
20070126157 Bredt Jun 2007 A1
20070215020 Miller Sep 2007 A1
20070238056 Baumann et al. Oct 2007 A1
20080001331 Ederer Jan 2008 A1
20080018018 Nielsen et al. Jan 2008 A1
20080047628 Davidson et al. Feb 2008 A1
20080138515 Williams Jun 2008 A1
20080187711 Alam et al. Aug 2008 A1
20080233302 Elsner Sep 2008 A1
20080237933 Hochsmann et al. Oct 2008 A1
20080241404 Allaman et al. Oct 2008 A1
20080260945 Ederer et al. Oct 2008 A1
20080299321 Ishihara Dec 2008 A1
20090011066 Davidson et al. Jan 2009 A1
20090068376 Philippi et al. Mar 2009 A1
20090261497 Ederer et al. Oct 2009 A1
20100007062 Larsson et al. Jan 2010 A1
20100026743 Van Thillo et al. Feb 2010 A1
20100152865 Jonsson et al. Jun 2010 A1
20100212584 Ederer et al. Aug 2010 A1
20100002443 Ederer et al. Sep 2010 A1
20100207288 Enrico Sep 2010 A1
20100243123 Ederer et al. Sep 2010 A1
20100247742 Shi et al. Sep 2010 A1
20100272519 Ederer et al. Oct 2010 A1
20100279007 Briselden et al. Nov 2010 A1
20100291314 Kashani-Shirazi Nov 2010 A1
20100323301 Tang et al. Dec 2010 A1
20110059247 Kuzusako et al. Mar 2011 A1
20110177188 Bredt et al. Jul 2011 A1
20110223437 Ederer et al. Sep 2011 A1
20110232855 Crump Sep 2011 A1
20110308755 Hochsmann Dec 2011 A1
20120046779 Pax et al. Feb 2012 A1
20120009725 Hartmann Apr 2012 A1
20120094026 Ederer et al. Apr 2012 A1
20120012645 Abe et al. May 2012 A1
20120113439 Ederer May 2012 A1
20120189102 Maurer, Jr. et al. Jul 2012 A1
20120291701 Grasegger et al. Nov 2012 A1
20120329943 Hicks et al. Dec 2012 A1
20130000549 Hartmann et al. Jan 2013 A1
20130004610 Hartmann et al. Jan 2013 A1
20130026680 Ederer et al. Jan 2013 A1
20130029001 Gunther et al. Jan 2013 A1
20130092082 Ederer et al. Apr 2013 A1
20130157193 Moritani et al. Jun 2013 A1
20130189434 Randall et al. Jul 2013 A1
20130199444 Hartmann Aug 2013 A1
20130215203 Chen Aug 2013 A1
20130234355 Hartmann et al. Sep 2013 A1
20130302575 Mogele et al. Nov 2013 A1
20130313757 Kashani-Shirazi Nov 2013 A1
20140048980 Crump et al. Feb 2014 A1
20140002023 Ederer et al. Jul 2014 A1
20140212677 Gnuchtel et al. Jul 2014 A1
20140227123 Gunster Aug 2014 A1
20140236339 Fagan Aug 2014 A1
20140271961 Khoshnevis Sep 2014 A1
20140306379 Hartmann et al. Oct 2014 A1
20140322501 Ederer et al. Oct 2014 A1
20150042018 Gunther et al. Feb 2015 A1
20150069659 Hartmann Mar 2015 A1
20150110910 Hartmann et al. Apr 2015 A1
20150165574 Ederer et al. Jun 2015 A1
20150210822 Ederer et al. Jul 2015 A1
20150224718 Ederer et al. Aug 2015 A1
20150026623 Ederer et al. Sep 2015 A1
20150273572 Ederer et al. Oct 2015 A1
20150290881 Ederer et al. Oct 2015 A1
20150375418 Hartmann Dec 2015 A1
20150375419 Gunther et al. Dec 2015 A1
20160000015 Hartmann et al. Jan 2016 A1
20160052165 Hartmann Feb 2016 A1
20160052166 Hartmann Feb 2016 A1
20160318251 Ederer et al. Mar 2016 A1
20160001073 Hartmann et al. Apr 2016 A1
20160114533 Grassegger et al. Apr 2016 A1
20160263828 Ederer et al. Sep 2016 A1
20160303762 Gunther Oct 2016 A1
20160311167 Gunther et al. Oct 2016 A1
20160311210 Gunther et al. Oct 2016 A1
20170028630 Ederer et al. Feb 2017 A1
20170050378 Ederer Feb 2017 A1
20170050387 Ederer Feb 2017 A1
20170106595 Gunther et al. Apr 2017 A1
20170136524 Ederer et al. May 2017 A1
20170151727 Ederer et al. Jun 2017 A1
20170210037 Ederer et al. Jul 2017 A1
20170297263 Ederer et al. Oct 2017 A1
20170305139 Hartmann Oct 2017 A1
20170355137 Ederer et al. Dec 2017 A1
20180079133 Ederer et al. Mar 2018 A1
20180141271 Gunter et al. May 2018 A1
20180326662 Gunther et al. Nov 2018 A1
20180369910 Gunter et al. Dec 2018 A1
20190047218 Ederer et al. Feb 2019 A1
20190084229 Gunther Mar 2019 A1
20200055246 Gunther et al. Feb 2020 A1
Foreign Referenced Citations (69)
Number Date Country
720255 May 2000 AU
101942659 Jan 2011 CN
3221357 Dec 1983 DE
3930750 Mar 1991 DE
4102260 Jul 1992 DE
4305201 Apr 1994 DE
4 325 573 Feb 1995 DE
29506204 Jun 1995 DE
4440397 Sep 1995 DE
19525307 Jan 1997 DE
19530295 Jan 1997 DE
19528215 Feb 1997 DE
29701279 May 1997 DE
19545167 Jun 1997 DE
69031808 Apr 1998 DE
19853834 May 2000 DE
10216013 Oct 2003 DE
69634921 Dec 2005 DE
201 22 639 Nov 2006 DE
10 2006 040 305 Mar 2007 DE
102006003765 Jul 2007 DE
102006029298 Dec 2007 DE
102007040755 Mar 2009 DE
102007047326 Apr 2009 DE
102011053205 Mar 2013 DE
102015006363 Dec 2016 DE
102015008860 Jan 2017 DE
102015011503 Mar 2017 DE
102015011790 Mar 2017 DE
361847 Apr 1990 EP
0538244 Apr 1993 EP
0431924 Jan 1996 EP
0870622 Oct 1998 EP
1457590 Sep 2004 EP
1648686 Apr 2006 EP
1740367 Jan 2007 EP
1381504 Aug 2007 EP
2297516 Aug 1996 GB
S62275734 Nov 1987 JP
2003136605 May 2003 JP
2004082206 Mar 2004 JP
2009202451 Sep 2009 JP
0140866 Jun 2001 WO
2001078969 Oct 2001 WO
2004014637 Feb 2004 WO
2005105412 Nov 2005 WO
2006100166 Sep 2006 WO
2007114895 Oct 2007 WO
WO 2007114895 Oct 2007 WO
2008049384 May 2008 WO
2008061520 May 2008 WO
2011063786 Jun 2011 WO
2013075696 May 2013 WO
2014090207 Jun 2014 WO
2014166469 Oct 2014 WO
2015078430 Jun 2015 WO
2015081926 Jun 2015 WO
2015085983 Jun 2015 WO
2015090265 Jun 2015 WO
2015090567 Jun 2015 WO
2015096826 Jul 2015 WO
2015149742 Oct 2015 WO
2015180703 Dec 2015 WO
2016019937 Feb 2016 WO
2016019942 Feb 2016 WO
2016058577 Apr 2016 WO
2016095888 Jun 2016 WO
2016101942 Jun 2016 WO
2016146095 Sep 2016 WO
Non-Patent Literature Citations (16)
Entry
US 4,937,420 A, 06/1990, Deckard (withdrawn)
International Search Report, Application No. PCT/DE2013/000588, dated Mar. 7, 2014.
International Preliminary Report on Patentability and Written Opinion, Application No. PCT/DE2013/000588, dated Apr. 21, 2015.
Marcus et al., Solid Freedom Fabrication Proceedings, Nov. 1993.
Cima et al., “Computer-derived Microstructures by 3D Printing: Bio- and Structural Materials,” SFF Symposium, Austin, TX, 1994.
Marcus, et al., Solid Freeform Fabrication Proceedings, Sep. 1995, p. 130-133.
Gebhart, Rapid Prototyping, pp. 118-119, 1996.
Feature Article—Rapid Tooling—Cast Resin and Sprayed Metal Tooling by Joel Segal, Apr. 2000.
EOS Operating Manual for Laser Sintering Machine with Brief Summary Feb. 22, 2005.
Sachs, E., P. Williams, D. Brancazio, M. Cima, and K. Kremmin, Three dimensional printing: Rapid Tooling and Prototypes Directly from a CAD Model. In Proceedings of Manufacturing International 1990 (Atlanta, GA, Mar. 25-28). ASME, New York, 1990, pp. 131-136.
Sachs et al., “Three-Dimensional Printing: Rapid Tooling and Prototypes Directly from a CAD Model”, Massachusetts Institute of Technology, pp. 143-151, Jan. 1990.
Williams, “Feasibility Study of Investment Casting Pattern Design by Means of Three Dimensional Printing”, Department of Mechanical Engineering, abstract only; Sep. 25, 2001.
Armin Scharf, “Erster 3D—Endlosdrucker”, zwomp.de, http://www.zwomp.dc/2012/11/06/voxeljet-endlosdrucker/ dated Nov. 6, 2012.
Voxeljet's VXconcept—Continuous 3D printing for sand casting, You-Tube, Nov. 16, 2011, XP002713379, retrieved from the Internet URL: http://www.youtube.com/watch?v=hgIrNXZjIxU retrieved on Sep. 23, 2013.
Screen shots of URL: http://www.youtube.com/watch?v=hgIrNXZjIxU taken in approximately 5 second intervals on Nov. 12, 2015.
Translation of Chinese Second Office Action, CN Application No. 2013/80053982.4 dated Oct. 27, 2016.
Related Publications (1)
Number Date Country
20150266238 A1 Sep 2015 US