Patent Application
20080268395
The invention relates to a method and devices for short-time heat treatment and/or quenching of bulk materials and can be used at the stage of thermochemical activation in producing catalysts, carriers, adsorbents, dehydrators, fillers, ceramics, magnetic materials, inorganic pigments, solid electrolytes, medical and cosmetic preparations, etc., in processes of drying/cooling in chemical, food, woodworking and other industries.
A method for activating crystalline oxygen-containing compounds by quick heating at the rate of hundreds and thousands degrees/minute of powder particles due to their contact with gas flow, for example smoke fumes, or solid heat carrier (the method for thermochemical activation/TCA/) is known (SU 517564, C01F7/30, 1975; SU 967028, C01F7/02, 1981; RU 2064435, C01F7/44, 1994). Such heating results in formation of decomposition products having valuable chemical properties. Products of activation are subjected to cooling-quenching at an outlet from a hot zone for fixation of amorphous state. The disadvantages of this method are dust-laden gas emissions containing hazardous admixtures (NOx, SOx, CO, hydrocarbons), contamination of initial substances by fuel admixtures and products of incomplete burning, relatively long time required for cooling-quenching process (10 minutes up to temperature 60° C.) and low efficiency of using energy of heat carriers leading to high specific power inputs.
An analogous method for heat treatment of initial of bulk materials is its heating by moving along the surface of a vibrating groove in the field of radiation gas burners at a temperature from 400 to 600° C. for 5-30 s (SU 528733, C01F7/44, 1973). Heating due to heat transfer in contact of initial material particles with hot metal is more effective than heating particles through their contacts between themselves or due to convective heat exchange in hot air flow. The disadvantage of the known method is relatively low speed of material movement along the groove and difficulties in providing uniform distribution of initial bulk material along the heated surface of the groove due to its vibration. This disadvantage is practically impossible to overcome when attempting to increase the size of the groove for achieving output of more than 2 kg/hour.
Similar technical solution is an installation for pulse heat treatment of bulk materials (patent RU 2115634, C04B35/52, 20 Jul. 1998). The installation comprises a tank for an initial material, heaters and a drive for rotation. In the patent a method for pulse heat treatment of bulk materials is also disclosed; the method comprises feeding, distributing and moving initial material along a heated surface wherein particles of the material are in relative motion and contact, and discharge of finished product in a storage accumulator.
A device and a method for pulse heat treatment of bulk materials are a most similar to the present invention (patent RU 2186616, 7 B01J8/10, 10 Aug. 2002).
The invention according to the closest prior art solves the following problems:
controlling flow rate of bulk materials; even and dense distributing along a heated surface; increasing the rate of heating a bulk material tights; fast cooling-quenching of the thermal treatment product for fixing a metastable structure; increasing productivity; decreasing power consumption.
The above problems are solved by using the method of pulse heat treatment of bulk materials including feeding, distribution and movement along a heated surface of initial material with particles being in relative displacement and contact; discharge of the finished product in a storage reservoir. After feeding the initial material is mixed and at the same time heated, then it is metered, evenly distributed and moved along rotating surface heated to 100-1500° C., superheated vapor is bled off, and at the moment of leaving the heated surface the product is quenched.
Relative movement of the material and contacts of the particle with then heated surface are due to centrifugal force, and the time of the contact and the force of pressing material against the heated surface are controlled by the speed of rotation. Heating of the initial material particles is due to heat transfer during the contact with the plate. In addition to gravity the compression of particles due to the centrifugal force increases the tightness of their contact with the operative heated surface of the plate and enhances the heat transfer process. Such method of heating provides for increased speed of particle relative movements thereby increasing productivity of the process.
Quenching at the moment when product leaves the heated surface is provided by contact with cooled side surface of the device. The product is cooled to a temperature of at most 150° C. for not more than 5 s. The process of heating-quenching takes 0.5 to 5.0 s. Vapor is extracted in the plate zone at a maximum pressure of superheated vapor. For metering bulk material the metering gap area is controlled. In metering the flow rate of the bulk material remains constant when the number of plate turns is changed.
Objectives according to the closest prior art are achieved by using a device for pulse heat treatment of bulk materials, the device comprising a vertical shaft with a drive and attached plate mounted in a housing; a tank for an initial material with a flow rate regulator in the lower part; a storage enclosure. The device is equipped with heaters, a superheated steam evacuation system, a cooling-quenching system for the products of pulse heat treatment, wherein the operational (upper) surface of the plate is conical or has a curvature providing upward widening.
The plate heater can be placed on the plate or above it. The heat sources are electric heaters, gas or other fuel burners. The heater is secured in thermally insulated base of the device housing. The upper part of the thermally insulated housing of the device is designed to be displaced in axial direction forms a slot with the operational surface of the plate; said slot transforms into a cooling zone. The cooling zone for the product of pulse heat treatment is a cavity defined by the side housing and the bottom surfaces of the device. The side housing and the bottom surfaces are subjected to forced cooling. The cooling zone is connected with the inside of the storage for collecting product. The side surface of the device housing is conical or has another shape narrowing downwards. Initial material flow rate regulator is a movable in axial direction bushing interacting with conical (or of another shape) portion extending in the feeding surface of the plate. The storage for the initial bulk material is equipped with a heater. The slot between the plate and the upper part of the housing is connected with the cavities for evacuated superheated vapor and for heating the storage for initial product.
The axial moves of the flow rate regulator between the bushing lower end and a conical part of the vertical shaft allows controlling bulk material flow rate.
The side surface of the bottom and the side surface of the housing define the cooling cavity and they are provided with a system of cooling liquid supply. The cooling cavity transforms into a conical cavity of the product storage.
The known solution has the following disadvantages: low effectiveness of impulse heat treatment of bulk materials due to complicated configuration of the heat carrier (the plate) which does not provide for uniform distribution of treated material on the heated surface. Moreover, the known device is highly inertial in terms of heating/cooling. In case of heavy thermal insulation of the housing and a large size of the plate (a diameter of 1 m and thickness of 1 cm), the time required for heating from 20 to 300° C. is about 1 hour when the power of heaters is 50 kW. In case of halting operations of the device according to the prior art it can be opened only after cooling the plate for a few hours. What is more during the process of heating/cooling the plate must continue rotation to avoid skewing.
It is an object of the present invention to solve the problem of enhancing effectiveness of bulk material pulse heat treatment.
The present invention offers a method for pulse heat treatment of powdered bulk materials practically free of the disadvantages of the closest prior art and other analogues due to optimal method of treatment with the same result but at lower temperatures allowing the use of a wide range of high-temperature and corrosion-resistant materials for the rotating heated surface and of centrifugal activator of simple design. What is more, it becomes possible to treat in one step both dry and wet bulk materials. It makes the treatment method economical and competitive. As the treatment process for wet materials is more complex than for dry materials, further description is focused on processing wet materials. The method and device for treatment of dry material are similar but the method is simpler and carried out according to specially selected modes.
FIG. 1—A device for pulse heat treatment of bulk materials
The object is accomplished by using the claimed method and device for implementing thereof.
The method of pulse heat treatment of bulk materials comprises the following steps: evaporation surface moisture; fast heating to a required temperature and consequent cooling with simultaneous feeding particles on a rotating surface heated to a temperature above 100° C., contacting particles with the heated surface under the action of centrifugal force wherein the contacting time and pressure of the particles against the surface are controlled by changing the speed of rotation; and the step of quenching particles on the surface of a cooler by fast cooling an then collecting the finished product in the storage.
Treatment of moving bulk material particles is carried out on the surface of a truncated cone or a cylinder rotating around a vertical axis, and the steps of vaporization and heating to a required temperature are combined. Time of motion of the material on the heated surface under gravity is controlled by the friction force and the friction force is controlled by changing the speed of rotation.
A bulk material having moisture content of 5.0 wt % is fed in the form of extrusion granules. The process of pulse heat treatment is carried out on the inner surface of a dram having the shape of a vertically rotating cylinder or a truncated cone, and the material is fed from above. The time of treated material movement on the rotating heated surface increases when the speed of rotation is increased. Under the condition that the time of contact is predetermined the productivity of the activator is increased if the diameter of the drum is increased and the speed of rotation is decreased. Depending on the drum diameter selected for determined productivity the initial material is fed on one or a few sectors of a distributing ring from above. The number of sectors depends on the area of distribution along the surface of the drum without overlapping of the distribution areas. The quenching step is carried out on the surface of the cooler located below the drum by rapid cooling in not more than 3 s to a temperature not higher than 150° C. Total treatment time at all steps is not less that 1 s.
A method of pulse heat treatment of powdered bulk materials comprises: feeding wet material with moisture content of up to 20 wt %, removal of surface moisture from particles with simultaneous heat pulse on the rotating surface heated to a temperature higher than 100° C.; consequent rapid quenching by cooling to a temperature not higher than 150° C. for not longer than 3 s, and collecting the finished product in a storage. There are the following requirements for conducting the steps of this method:
1. The wet material is fed in the form of not very strong microgranules having a diameter of up to 3 mm produced by any known process (for example, by extrusion on a screw type extruder). The granules moves along a groove in the mode of broken flow (to avoid blockage due to hang-ups) to the heated rotating surface.
2. Contact of wet granules with the surface heated to 600-700° C. results in their immediate heating and breakage by vapor of moisture evaporating from the surface of the particles since the bonds (adhesion) between particles in granules is not strong. Tests has shown that for breaking granules having a diameter of up to 3 mm it is enough to let them fall from the groove arranged at some height on the heated rotating surface. The duration of evaporation and heat pulse is about 1 s.
Thus this process provides for continuous treatment of wet material in one step with the heat pulse.
3. In the claimed method as well as in the closest prior art the basic part is treatment of particles on a rotating heated surface in the field of action of gravitational and centrifugal forces but the difference of the claimed method is in that gravitational forces have determining influence on the particle movements along the heated surface and centrifugal forces provide for creation of friction on the surface, and friction controls the speed of powder motion, i.e. it controls the time of contacts. The weight of powder material does not depend on the shape of contact surfaces, and centrifugal forces always acting in one direction perpendicular to the axis of rotation are practically the same in such contacts. It means that such resolution of forces can be achieved not on a horizontal surface but on a vertical one in a shape of cylindrical drum of corresponding height feeding particles on the inside surface from above. As the centrifugal forces are perpendicular to the surface and commensurable with the particle weight, the force pressing them against the drum and the speed of their sliding is easy to control changing the speed of drum rotation, and the centrifugal force determining the time of particle contact is constant for any cylindrical surface.
It is known that the formula of centrifugal force is Fc=mω2r where is a particle mass, ω is an angular velocity (turning speed) and r is a radius of drum circumference. If values of Fc and m are constant, an increase in r should be followed by a decrease in ω=2πn, i.e. a decrease in number of turns n per unit of time.
Thus use of centrifugal force not contrary to gravitational force leads to a positive result: with increase of the drum diameter and simultaneous decrease its speed of rotation the action of the gravitational forces and centrifugal force on particles remains the same. Therefore the productivity of centrifugal activators depends only on the size of the drum and its number of turns: the bigger is drum diameter, the lower is the number of turns. It is reasonably reliable solution for a design. It also allows flexible control over the process for treatment of bulk materials with wide range of parameters. Choice of drum size is limited by its surface area required for heat transfer of determined amount of heat from heaters and their arrangement in the drum of big size.
4. Material is fed uniformly on one or a few sectors (depending on the diameter of the drum chosen for required productivity) in the upper part of the drum. If there are a few places of supply, each particle flow slides on the surface along a helical curve and scatters along the surface of the quenching cooler in sectors of certain length when leaving the edge of the drum. There should be no overlapping of these sectors if there is no overlapping when dissipating along the drum surface. It determines the number of points for powder feed at the beginning.
5. The design of the drum is very simple and can be produced from thin sheets quick to be heated (it is important at start of an activator) and cooled down at stops. Material for the dram can be any heat-resistant stainless steel. A drum can be quickly replaced when worn-out.
6. After leaving the hot surface the material is quenched due to contact with the surface of a cooler. Cooling is controlled by regulating supply of a refrigerant. The product is cooled to a temperature not higher than 150° C. in not more than 3 s.
7. The complete process of evaporating-heating-quenching of bulk material particle is carried out in the wide range of time. It can be a short-time treatment for 0.5-1.0 s as well as longer one for more than 1 s. Temperature is controlled by zones with the help of thermocouples placed in zones of the heater, product storage, inlet and outlet of refrigerant and outlet of vapor.
The inventive method is implemented using a device, a centrifugal activator, for pulse heat treatment of bulk materials. The device comprises a vertical console shaft arranged in a housing with a remote electric drive for its rotation, one end on the shaft is mounted in a housing cover in cooled bearing box; one or more ducts for feeding the initial material on the rotating surface; a surface for pulse heat treatment in the shape of vertical cylindrical or conical drum; a unit of cooling-quenching the product after pulse heat treatment; and a storage unit for the product. The activator is equipped with heaters of the drum and a unit for discharging superheated vapor.
The heater can be arranged outside and/or inside the drum. Electric heaters in heat-insulating housings are used. The unit of cooling-quenching the product is a cylindrical quenching cooler consisting of one or more cooling chambers with individual control of refrigerant supply in each chamber. The storage unit is an extension of the cooler body with an annular slot of 2-3 mm between them for avoiding heat transfer between the housings of the cooler and the storage. If such slot is not arranged, the storage upper part can be cooled resulting in particle sticking to it. The storage has a distribution ring arranged outside with openings into its zone.
The method for treatment of bulk materials is realized in the device, the centrifugal activator, shown on
The device is operated in the following way.
At first a refrigerant is filled in quenching cooler 3 and in bearing housing 10 and fix packaging 24 from the bottom. Then drum 6, 8 is heated by electric heaters 9 to predetermined temperature. At the next step the drive of shaft 11 is switched on, the ventilator at the vapor outlet is switched on, and granules of wet bulk material flow is directed through duct 26 to rotating distribution ring 14. Under the action of centrifugal force the particles of the bulk material are pressed to the inner surface of the drum and move downwards in rotational-translational motion along a trajectory of a helical curve. The particles are under the action of a vertical gravitational force and friction force controlled by a centrifugal force (a number of turns). The frictional force determines the speed of particle sliding along the surface thereby providing predetermined time of contact. When leaving the drum lower edge, the powder retains its acquired circumferential component of speed and falls on the conical surface of quenched cooler 3. Wet vapor escaping from particles is removed through the central opening of distribution ring 14 and further through outlet tube 26.
The material further slides along the surface of cooler 3 at a temperature controlled by refrigerant supply and cools to a required temperature.
The zone of storage 4 is a continuation of the zone of cooler 3. There is gap 20 (3-5 mm) between the zones for preventing cooling of the storage upper part from the cooler and particle sticking in the zone. Then the product accumulates in storage 4 on gate 5 (closed) and eventually poured into packaging 24. After the packaging is filled to certain weight fixed by floor scales 25, storage 4 is closed with gate 5 while the packaging is replaced.
Outside air is supplied through inlet tube 27 for additional cooling of shaft 11 (basic cooling is in housing 10). The air is either removed by the vapor ventilator or forced in case vapor is evacuated through a hood depending on the mode of operation.
During operation in some modes dry air for partial ventilation of the inner part of the activator is supplied through openings 22 in distribution collector 21.
Further the invention is illustrated with the following examples:
A wet powder of technical alumina hydrate Al(OH3) (mudstone) comprising particles having sizes between 0-150 μm and moisture of 17 wt % after being discharge from a screw extruder in the form of granules of 2-3 mm is continuously fed along an inclined groove in the rotating drum of 200 mm in diameter heated to a temperature of 650° C.±10° C. The powder is fed in one point of the distribution ring in the amount of 5 kg/h. The gap between the drum and the distribution ring is 5 mm. The speed of rotation is determined experimentally at 90 rev/min providing for the contact of the powder with the drum operational surface for about 1 s. The flow rate of water in the cooling system of the quenching cooler is 150 l/h, 50 l/h per each chamber. Power consumption of the device is 6.8 kW. After cooling the powder passes into a storage bin. The amount of the activated product in the storage bin is 4.2 kg after one hour of operation. X-ray phase analysis shows that the product of the heat treatment has an amorphous structure and enhanced reactivity revealed by a speed of dissolving in an alkali that is 5 times higher that for the initial substance. The initial substance—aluminum (III) hydroxide—is present in the product in the amount less than 5%.
Example 2 is similar to Example 1. The difference is only in that a preliminary dried non-granulated powder of mudstone is treated. The gap between the ring and the drum is 2 mm. The result of the heat treatment of the particles is the same as in Example 1, and the initial substance is present in the product in the amount not more than 3%.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2004109970 | Apr 2004 | RU | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/RU2005/000139 | 3/28/2005 | WO | 00 | 7/2/2008 |
