The present application relates to a method and device for realizing advanced nitrogen removal of mature landfill leachate and excess sludge reduction by using sludge fermentation liquid as carbon source, and belongs to the technical field of biological nitrogen removal of mature landfill leachate with a low carbon-nitrogen ratio.
In recent years, with the development of economy and the improvement of people's living standards, the output of municipal solid waste has also continued to increase, and treatment methods include landfill, incineration, and composting. The landfill method has gradually become the most widely used treatment and disposal method in the world due to its simple operation mode. However, the landfill method can also cause harm to the atmosphere, soil, water sources, etc. If leachate produced by the landfill method is not collected in time and properly treated, it will seriously pollute the surface water or groundwater. The landfill leachate is a kind of wastewater containing high concentration of organic matters and ammonia nitrogen, has the characteristics of complex water quality constituents, large changes in water volume, imbalanced ratio of microbial nutrient elements, etc, and will cause serious pollution to the environment, making the treatment of the landfill leachate one of unsolved problems with an international scope. Traditional wastewater biological nitrogen removal converts NH4+−N into NO3-−N through nitrification, and then converts NO3-−N into nitrogen to escape from water through denitrification. In the denitrification stage, microorganisms use NO3-−N as an electron acceptor and organic matters as an electron donor, and finally ammonia nitrogen is converted into nitrogen, nitrogen removal is finished, and wastewater is discharged when meeting the emission standards. However, the water quality of landfill leachate varies greatly in different periods. For mature landfill leachate, a carbon source thereof is very small, carbon and nitrogen are relatively low, and a carbon source needed by the microorganisms for denitrification is not met, so the nitrogen removal efficiency of the mature landfill leachate cannot be improved, advanced removal of the mature landfill leachate is difficult to complete by a traditional biological nitrogen removal process, and addition of an organic carbon source will greatly increase the wastewater treatment cost.
Due to the insufficient carbon source, an additional carbon source must be added in the treatment process, which in turn leads to a large increase in heterotrophic bacteria and a large excess sludge output. Therefore, as a by-product of an activated sludge process, the treatment and disposal of a large amount of excess sludge is also another big problem. The excess sludge is rich in organic carbon source. A large amount of short-chain fatty acids can be produced through alkaline anaerobic fermentation, and may be added as a high-quality carbon source to the treatment process of the landfill leachate, and the excess sludge reduces the weight by 50%-60% while providing the carbon source. In terms of operating cost, a sludge fermentation mixture is directly used instead of sludge fermentation liquid produced by centrifugation of a sludge fermentation product, which saves the centrifugal cost of sludge and water separation and saves floor space.
A method and device for realizing advanced nitrogen removal of mature landfill leachate and sludge reduction by using sludge fermentation products as carbon source takes excess sludge and the mature landfill leachate with a high ammonia nitrogen concentration as research objects, and adopts an anoxic/anaerobic/oxic mode in a PNA-SBR for operating. After raw water enters an anoxic stage, organic matters are used to convert the excess part of nitrite nitrogen and nitrate nitrogen in the last cycle into nitrogen; after the water enters an anaerobic stage, an anaerobic ammonia oxidation reaction occurs, and part of ammonia nitrogen and the excess nitrite nitrogen in the raw water are removed at the same time to generate nitrate nitrogen; and then the water enters an oxic stage, the excess ammonia nitrogen is converted into nitrite nitrogen. Discharged water containing nitrite nitrogen and nitrate nitrogen is pumped into a DN-SBR, an excess sludge fermentation mixture is added at the same time, the reactor operates in an anaerobic/oxic/anoxic mode, the carbon source required for denitrification is derived from the excess sludge fermentation mixture on the one hand, and the storage of microorganisms in the anaerobic stage on the other hand, and is released in the anoxic stage. The microorganisms in the activated sludge use two parts of carbon sources for denitrification and remove a nitrogen element from the landfill leachate. According to the process, under the conditions that ammonia nitrogen, total nitrogen and COD concentrations of fed water are 1150±40 mg/L, 1421±55 mg/L and 1503±150 mg/L, the TN removal rate of the discharged water reaches 96.0%. The process uses excess sludge for fermentation as the carbon source, which not only saves the treatment and disposal cost of the excess sludge, but also provides the carbon source for advanced nitrogen removal of wastewater treatment, and can achieve the effect of reducing the excess sludge.
In view of defects of the prior art, the present application provides a method and device for realizing advanced nitrogen removal of mature landfill leachate and sludge reduction by using sludge fermentation products as carbon source. Specifically, the mature landfill leachate first enters a partial nitrification-Anammox integrated reactor which operates in an anoxic/anaerobic/oxic (A/A/O) mode, and after raw water enters an anoxic stage, organic matters are used to convert an excess part of nitrite nitrogen and nitrate nitrogen in the last cycle into nitrogen; after the water enters an anaerobic stage, an anaerobic ammonia oxidation reaction occurs, and part of ammonia nitrogen and the excess nitrite nitrogen in the raw water are removed at the same time to generate nitrate nitrogen; and then the water enters an oxic stage, the excess ammonia nitrogen is converted into nitrite nitrogen. Discharged water containing nitrite nitrogen and nitrate nitrogen is pumped into a DN-SBR, an excess sludge fermentation mixture is added at the same time, the reactor operates in an anaerobic/oxic/anoxic (A/O/A) mode, the carbon source required for denitrification is derived from the excess sludge fermentation mixture on the one hand, and the storage of microorganisms in the anaerobic stage on the other hand, and is released in the anoxic stage. Two ways of carbon sources are used to reduce a nitrogen element into nitrogen, so as to realize the advanced nitrogen removal of the mature landfill leachate and sludge reduction.
The present application is realized by the following technical solutions:
A device for realizing advanced nitrogen removal of mature landfill leachate and sludge reduction by using sludge fermentation products as carbon source includes: a raw water tank (1), a partial nitrification/anaerobic ammonia oxidation integrated reactor (2), a middle tank (3), an excess sludge alkaline fermentation tank (4), a fermentation product storage tank (5), a denitrification reactor (6), and a water outlet tank (7).
The raw water tank is provided with an overflow pipe (1.1) and a water outlet (1.2); the partial nitrification/anaerobic ammonia oxidation integrated reactor (2) is provided with an air compressor (2.1), a gas flow meter (2.2), an aeration head (2.10), a first water inlet (2.3), a first sampling port (2.8), a first drainage port (2.9), a first blow-down pipe (2.6), a first agitator (2.5), a first water inlet peristaltic pump (2.11), a first water outlet peristaltic pump (2.12), a pH/DO real-time monitoring device (2.7), and an ORP real-time monitoring device (2.4); the excess sludge alkaline fermentation tank (4) is completely sealed and attached with a thermal insulation layer outside, and is provided with a temperature control device (4.1), a first sludge inlet (4.2), a second agitator (4.3), a pH/DO real-time monitoring device (4.4), and a first sludge outlet (4.5); and the denitrification reactor (6) is provided with an air compressor (6.1), a gas flow meter (6.2), an aeration head (6.10), a second water inlet (6.3), a second sampling port (6.8), a second sampling port (6.8), a second drainage port (6.9), a second blow-down pipe (6.6), a third agitator (6.5), a second water inlet peristaltic pump (6.11), a second water outlet peristaltic pump (6.12), and a pH/DO real-time monitoring device (6.7).
The raw water tank (1) is connected with the first water inlet (2.3) of the partial nitrification/anaerobic ammonia oxidation integrated reactor through the first water inlet peristaltic pump (2.11); the first drainage port (2.9) of the partial nitrification/anaerobic ammonia oxidation integrated reactor (2) is connected with a water inlet (3.1) of the middle tank through the first water outlet peristaltic pump (2.12), and air passes through the air compressor (2.1) and the gas flow meter (2.2) and finally is driven into the partial nitrification/anaerobic ammonia oxidation integrated reactor (2) through the aeration head (2.10); a water outlet (3.3) of the middle tank is connected with the denitrification reactor (6) through the second water inlet peristaltic pump (6.11); the first sludge outlet (4.5) of the excess sludge alkaline fermentation tank (4) is connected with the fermentation product storage tank (5); the fermentation product storage tank (5) is connected with a second sludge inlet (6.4) of the denitrification reactor (6); and the water outlet tank (7) is connected with the second drainage port (6.9) of the denitrification reactor through the second water outlet peristaltic pump (6.12).
A method for realizing advanced nitrogen removal of mature landfill leachate and sludge reduction by using a sludge fermentation carbon source through the device includes the following steps:
The mature landfill leachate first enters the PNA-SBR which operates in the A/A/O mode, and after the raw water enters the anoxic stage, the organic matters are used to convert an excess part of nitrite nitrogen and nitrate nitrogen in the last cycle into nitrogen; after the water enters the anaerobic stage, the anaerobic ammonia oxidation reaction occurs, and part of ammonia nitrogen and the excess nitrite nitrogen in the raw water are removed at the same time to generate nitrate nitrogen; and then the water enters the oxic stage, the excess ammonia nitrogen is converted into nitrite nitrogen. The discharged water containing nitrite nitrogen and nitrate nitrogen is pumped into the DN-SBR, the excess sludge fermentation mixture is added at the same time, the reactor operates in the A/O/A mode, after the water enters the anaerobic section, part of the organic matters in the sludge fermentation mixture are used to first denitrify nitrite nitrogen and nitrate nitrogen in the fed water, and the microorganisms store the internal carbon source; at the oxic section, the ammonia nitrogen produced in the fermentation mixture is converted into the nitrite nitrogen and the nitrate nitrogen; and at the final anoxic stage, the nitrite nitrogen and the nitrate nitrogen are reduced to nitrogen, and advanced removal of the nitrogen element and reduction of the excess sludge are completed in the denitrification reactor at the same time.
The device and method for realizing advanced nitrogen removal of mature landfill leachate and sludge reduction by using sludge fermentation products as carbon source according to the present application have the following advantages:
(1) The present application realizes the true advanced nitrogen removal of the mature landfill leachate through the organic combination of partial nitrification, anaerobic ammonia oxidation, excess sludge fermentation and endogenous denitrification, and achieves the effects of cost saving, advanced nitrogen removal and sludge reduction.
(2) In the partial nitrification/anaerobic ammonia oxidation integrated reactor, the partial nitrification of ammonia oxidation bacteria can save 60% of aeration volume, and the anaerobic ammonia oxidation bacteria do not generate N2O in the metabolic process, so the process has less greenhouse gas for emission.
(3) In the partial nitrification/anaerobic ammonia oxidation integrated reactor, both the partial nitrification reaction and the anaerobic ammonia oxidation process may be carried out. Compared with a traditional two-stage process of partial nitrification coupled with anaerobic ammonia oxidation, the device is simple and easy to operate.
(4) In the denitrification reactor, the carbon source needed for the reaction is from the internal carbon source stored in the anaerobic stage on the one hand, and from the added excess sludge fermentation mixture on the other hand, which achieves “zero addition” of carbon sources and greatly saves the required cost.
(5) The process does not have a reflow device, which saves the cost and is easy to operate.
The present application will be further described in detail below with reference to the accompanying drawings and specific implementations.
As shown in
The raw water tank is provided with an overflow pipe (1.1) and a water outlet (1.2); the partial nitrification/anaerobic ammonia oxidation integrated reactor (2) is provided with an air compressor (2.1), a gas flow meter (2.2), an aeration head (2.10), a first water inlet (2.3), a first sampling port (2.8), a first drainage port (2.9), a first blow-down pipe (2.6), a first agitator (2.5), a first water inlet peristaltic pump (2.11), a first water outlet peristaltic pump (2.12), a pH/DO real-time monitoring device (2.7), and an ORP real-time monitoring device (2.4); the excess sludge alkaline fermentation tank (4) is completely sealed and attached with a thermal insulation layer outside, and is provided with a temperature control device (4.1), a first sludge inlet (4.2), a second agitator (4.3), a pH/DO real-time monitoring device (4.4), and a first sludge outlet (4.5); and the denitrification reactor (6) is provided with an air compressor (6.1), a gas flow meter (6.2), an aeration head (6.10), a second water inlet (6.3), a second sampling port (6.8), a second sampling port (6.8), a second drainage port (6.9), a second blow-down pipe (6.6), a third agitator (6.5), a second water inlet peristaltic pump (6.11), a second water outlet peristaltic pump (6.12), and a pH/DO real-time monitoring device (6.7).
The raw water tank (1) is connected with the first water inlet (2.3) of the partial nitrification/anaerobic ammonia oxidation integrated reactor through the first water inlet peristaltic pump (2.11); the first drainage port (2.9) of the partial nitrification/anaerobic ammonia oxidation integrated reactor (2) is connected with a water inlet (3.1) of the middle tank through the first water outlet peristaltic pump (2.12), and air passes through the air compressor (2.1) and the gas flow meter (2.2) and finally is driven into the partial nitrification/anaerobic ammonia oxidation integrated reactor (2) through the aeration head (2.10); a water outlet (3.3) of the middle tank is connected with the denitrification reactor (6) through the second water inlet peristaltic pump (6.11); the first sludge outlet (4.5) of the excess sludge alkaline fermentation tank (4) is connected with the fermentation product storage tank (5); the fermentation product storage tank (5) is connected with a second sludge inlet (6.4) of the denitrification reactor (6); and the water outlet tank (7) is connected with the second drainage port (6.9) of the denitrification reactor through the second water outlet peristaltic pump (6.12).
The specific operation process is as follows:
A continuous test result shows:
After the process runs stably, under the conditions that ammonia nitrogen, total nitrogen and COD concentrations of the fed water are 1150±40 mg/L, 1421±55 mg/L and 1503±150 mg/L, the TN removal rate reaches 96.0%, and the TN removal speed can reach 0.64 kg/(m3·d).
Number | Date | Country | Kind |
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202011011157.6 | Sep 2020 | CN | national |
This application is a filing under 35 U.S.C. 371 of International Application No. PCT/CN2021/107611 filed on Jul. 21, 2021, entitled “METHOD AND EQUIPMENT FOR IMPLEMENTING ADVANCED NITROGEN REMOVAL AND SLUDGE REDUCTION OF OLD LANDFILL LEACHATE BY USING SLUDGE FERMENTATION CARBON SOURCE,” which claims priority to Chinese Patent Application No. 202011011157.6, entitled “METHOD AND DEVICE FOR REALIZING ADVANCED NITROGEN REMOVAL OF MATURE LANDFILL LEACHATE AND SLUDGE REDUCTION BY USING SLUDGE FERMENTATION PRODUCTS AS CARBON SOURCE,” filed Sep. 24, 2020, which applications are incorporated by reference herein in their entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/CN2021/107611 | 7/21/2021 | WO |