The present invention relates to a method and a device for the preparation of mould sand using a mixing process in a mixer, wherein the preparation takes place at least partially under vacuum.
The preparation of sand for the manufacture of moulds is intended to produce the correct mixing ratio of grain sizes and of proportions of quartz sand, binding agent, coal dust, optionally other additives as well as recycled and new sand, to homogenise the mixture and, in this context, to coat the grains with the binding agent to a large extent, to adjust the correct moisture content, to adjust the correct temperature of the mould sand and finally to convey the ready-prepared sand to the places of use.
Recycled sand generally has an increased temperature, for example, of between 100° C. and 140° C. Because sand temperatures above approximately 50° C. can present considerable problems to the moulding equipment, and at excessively high temperatures, uncontrollable evaporation losses over the distance between the mixer and the moulding equipment can lead to fluctuations in moisture in the ready sand, the sand must be cooled in this case. Conveyor belt coolers, through which the sand passes continuously as a result of vibrating or agitating movements of a screen mesh, are mostly used for this purpose.
An alternative cooling method has been proposed in DE 295 24 03 C2. This cooling method provides the concurrent preparation and cooling of clay-bound foundry moulding sands in a vacuum mixer. In this context, the individual components are initially placed into the mixer. After a short prehomogenizing process, the temperature and moisture of the mixture are measured and the necessary quantity of water is added. Finally, during the preparation process, the pressure in the mixture is gradually reduced. As soon as the pressure corresponds to the vapour pressure curve of water, the water in the sand begins to boil and removes the necessary evaporation heat from the sand. As a result, an extremely effective cooling method is achieved in an economical manner. According to the disclosure of DE 199 45 569, alongside the cooling effect on the mould sand, the described cooling of mould sand under vacuum also leads to an increase in quality of the mould sand prepared. Accordingly, DE 199 45 569 suggests preparation under vacuum even for recycled sand which has already been cooled.
It has been shown that the best mould sand quality can be achieved with the assistance of vacuum preparation. However, the known stages of the method and the devices and/or peripheral equipment used and their method of operation are only suitable to a limited extent or not at all for use in a fully automated foundry moulding plant. According to experience, error-free and above all economically optimized operation is not possible with the known method.
This is because, among other factors, the filling and emptying of the mixer is very time-consuming. For the ventilation of the mixer, a mixer cover is provided, in all known versions, which, in the closed condition, must be vacuum-tight to allow vacuum operation, and which is opened for the purpose of charging the mixer. In this context, the cover is generally connected to the mixer in a rotatable manner by means of a rotating axis. The cover can be designed in such a manner that it is rotated outwards or inwards in order to open the container. If it is rotated inwards, the closing mechanism must press the cover outwards against the sealing surface of the mixer with considerable force during vacuum operation. In order to manufacture the closing mechanism in an economical manner, the mixer cover must therefore be very small, because only a small force need then be applied by the closing mechanism.
If the cover is opened outwards, the closing mechanism can be designed to be weaker and can therefore be manufactured more economical ly, because the necessary pressing force can be generated by the pressure difference between the mixing container and the surroundings alone. However, with this version, the design must take into consideration that sufficient rotational clearance remains above the cover so that the cover can be opened without it coming into contact with any objects. Accordingly, dosage funnels or dosage devices must be attached at an appropriate distance above the mixer opening. This distance necessarily increases in proportion with the size of cover. However, when filling the mixer, it is important to ensure that the sealing surface of the charging opening remains as a free from contamination as possible, in order to guarantee a vacuum-tight closability. However, the probability of contamination of the sealing surface increases considerably as the distance between the dosage funnel and filling opening and/or the dropping height of the substance to be charged increases. For this reason, it is currently assumed, that a generic mixer cannot be manufactured economically with a large charging opening. Accordingly, the known mixers all possess only a relatively small opening in the pressure casing of the mixer, and, in the case of the equipment known so far, the mixture is added only in a very fine flow. This results in a very long charging time and therefore also a very low plant performance. If the mixer is loaded too quickly, an excess air pressure rapidly builds up as a result of compression of the air in the mixer. This excess pressure generally leads to the emission from the mixer of dust-like components of the mixture, which can, for example, also be deposited on very sensitive machine components, such as cogwheels and gaskets. This means that the plant must be cleaned more frequently which, once again, is associated with higher costs and undesired interruptions of operation. For this reason, it has generally been considered that, on the one hand, the charging rate cannot be further increased, because larger input openings cannot be realized in an economical manner. And, on the other hand, it has been considered that a larger charging rate will lead to the disadvantages described and must therefore be avoided.
The object of the present invention is therefore to provide a method and a device for preparation of mould sand, which can be used economically without errors, and provides mould sands of uniform temperature and uniformly high quality in an economical manner and which, in comparison with the known mixers, has an increased charging rate.
With regard to the method, this object is achieved by the material to be charged being added at least at times in a volume flow of at least 100-800 l/s through an opening with a diameter of at least 150 mm, preferably at least 300 mm, and particularly preferably at least 500 mm.
In this context, the pressure difference between the ambient pressure and the pressure in the mixing chamber of the mixer is preferably used either as the exclusive or predominant drive for at least one feeder process for water or for a mixture component or for accelerating the feeder process. According to the invention, therefore, the dosage devices and charging devices are coupled with the mixing unit in terms of the design and method. As a result, the vacuum prevailing in the mixer can be used; for example, to accelerate the charging processes, and even during the charging phase, to improve the distribution of the additives and the fluids to be added. In particular in combination with a large charging opening, the consistent use of pressure difference can achieve a significant reduction in charging time. Moreover, this method causes no additional costs, because the evacuation device necessary for the preparation method is already present.
Particularly preferred is a method in which at least a portion of the quality-determining mixture components is fed into the mixer during the charging and/or mixing process. The quality-determining mixture components are the additives already mentioned, such as, for example, bentonite, coal dust, etc., which are added to the recycled sand, in order to adjust the quality of the prepared mould sand. The vacuum pressure in the mixer, which is used to suck in the components to be filled, also effectively prevents the emission of dust-like mixture components from the mixer and their being deposited, for example, on sensitive machine parts.
A particularly expedient version of the method according to the invention additionally provides that the individual mixture components are introduced into the mixer one after another according to a predetermined sequence. However, for special cases of application, it may be advantageous if the water is only introduced into the mixer after the other mixture components have been introduced into the mixer essentially concurrently. As a result, after the other mixture components have been introduced, it is possible to determine the residual moisture and temperature of the recycled sand and from this, to calculate the appropriate quantity of water to be added.
In particular, in order to be able to mix the water to be added as well as possible with the mixture, a preferred version of the method provides that at least one portion of the water to be added is introduced directly into the mixture with the assistance of a preferably rotating feeder device. In this context, by rotating is meant rotating relative to the mixer, so that it is irrelevant whether the feeder device rotates or the feeder device remains stationary and the mixer rotates around the stationary feeder device, or whether both the mixer and the feeder device rotate. This direct method of feeding, that is, below the mixture level, can enable a very good mixing of the water with the mixture.
A particularly effective version of the method provides that at least one portion of the water is introduced into the mixture via a feeder device, which is coupled with a mixing tool or even integrated into a mixing tool. This is particularly advantageous if the mixer already provides a mixing tool. Moreover, as a result of this stage of the method, the water can be mixed directly with the filling substance.
It is also particularly expedient if the quality-determining mixture components, such as e.g. bentonite and coal dust, are introduced into the mixer below the filling level of the mixture. This measure also guarantees a very good mixing of the quality-determining mixture components with the mixture in the mixer.
The quality-determining mixture components are preferably introduced centrally and directly inside the vertically and tangentially flowing mixture bed. This further enhances miscibility.
For some cases of application, it may also be advantageous if at least one portion of the quality-determining mixture components is first mixed with air, and this air/solid mixture is then introduced into the mixer, i.e. preferably below the filling level. After preparation of the mould sand, the mixer must necessarily be ventilated again, that is, the pressure difference between the mixing container and the ambient pressure must be equalized. This can be achieved, for example, simply by opening the container cover. However, a method, in which the mixing chamber is ventilated via a feeder which terminates in the mixing chamber below the filling level of the mixture, is particularly preferred. As a result, the mould sand is compressed to a lesser extent. By contrast, if the equalization air is fed in above the sand level, a kind of pressure cushion will be formed on the surface of the sand as a result of the pressure difference prevailing above and below the filling substance, which leads to definite, temporary compression at least of the uppermost layer of sand.
Of course, it is also possible to use the feeder, which is provided for feeding the quality-determining mixture components, for ventilation and/or pressure equalization. With regard to the device, the object mentioned initially is achieved by a device for the preparation of mould sand with a mixer, which has a vacuum chamber or is arranged in a vacuum chamber, which can be closed in an essentially vacuum-tight manner, with devices for feeding the components to be mixed, at least one mixing tool as well as a device for removing the ready mixture, wherein a closable feeder connection for the components to be mixed exists or can be manufactured between the mixing container and the outside, wherein the feeder opening has a cross-sectional area of at least 0.25 m2, preferably at least 0.4 m2 and particularly preferably at least 0.5 m2.
In principle, the feeder opening can have any cross-sectional form, round or rectangular forms being preferred, however.
Feeding preferably takes place through the feeder opening either exclusively through the pressure difference between the ambient pressure and the pressure in the mixing chamber of the mixer, or feeding is at least accelerated by this pressure difference.
Through this at least one closable feeder connection, the pressure difference between the ambient pressure and the pressure in the mixing chamber of the mixer can be exploited as a driving force. If the feeder connection is opened, as a result of the vacuum pressure existing in the mixing chamber, material to be supplied is drawn into the mixing container from the outside. In general, an additional pump is not necessary for this purpose. The feeder therefore requires no additional energy and is, moreover, essentially maintenance-free.
Particularly preferred is a version in which an essentially vacuum-tight, closable filling opening of the mixer can be connected via an essentially vacuum-tight intermediate space to the outlet opening of at least one dosage device which is preferably designed as a dosage weighing device. Recycled sand, for example, can be introduced into the mixer through this opening. For this purpose, the mixer must first be placed under a vacuum. Following this, the filling opening of the mixer is opened, so that the mixing chamber is connected to the essentially vacuum-tight intermediate space. After this, the outlet opening of at least one feeder device is opened so that the charging materials from the feeder device are first conveyed into the intermediate space and then into the mixing chamber. This charging takes place very quickly because the pressure in the mixing chamber of the mixer and in the intermediate space is significantly lower than the pressure in the feeder device. Particularly preferably, the filling opening of the mixer and/or the outlet opening of the feeder device have a cover with lateral cheeks, which, with the assistance of the lateral cheeks, forms a kind of conveyor chute in the opened state. With the assistance of this conveyor chute, the supplied filling materials can be conveyed from the outlet opening of the feeder device at a high flow rate directly into the inlet opening of the mixer. Particularly preferably, the inlet opening of the mixer and also the outlet opening of the feeder device have a cover with lateral cheeks, each of which therefore form a conveyor chute in the opened state.
For particular cases of application, it could be advantageous if a further movable chute component is provided which can be moved independently of one of the covers. For the purpose of feeding in this case, the cover of the inlet opening of the mixer can first be opened, preferably by means of a control device, then the movable chute component can be brought into its functional position and finally the cover of the feeder device can be opened. The three chutes are then preferably arranged in such a manner that they form a passage for the substance to be filled and guarantee a rapid and targeted charging of the mixer with the substance to be filled. The chutes are preferably arranged in such a manner that they project into the openings and thereby prevent the substances to be filled from coming into contact with the edges of the opening. Contact of this kind could, under some circumstances, impair the sealing function of the cover of the inlet opening of the mixer.
A particularly preferred version of the device according to the invention provides that the mixing chamber of the mixer is arranged in a pressurized container and that, inside the pressurized container but outside the mixing chamber, a closable air feeder is provided. The pressurized container is advantageously connected via appropriate seals to the mixing chamber arranged in the pressurized container. These seats necessarily allow the passage of air, but are intended to hold the components of the mixture in the mixing chamber as firmly as possible. It is not desirable for mixture to escape from the mixing chamber into the pressurized container because contamination of the seals and movable drive components and bearings can occur there. If the mixing chamber is then rapidly loaded with the substance to be filled without vacuum, the pressure in the mixing chamber will rise very rapidly. The seals generally used between the mixing chamber and the pressurized container are, however, not capable of sustaining their sealing function under such an abrupt rise in pressure. It can therefore occur that material from the mixing chamber, which then has a higher pressure than the pressurized chamber, enters the pressurized chamber. As a result of the closable air feeder arranged according to the invention inside the pressurized container but outside the mixing chamber, the pressure in the pressurized container outside the mixing chamber can be increased by the air feeder during the charging process, so that the pressure in the pressurized container is higher than pressure in the mixing chamber. In this way, any transfer of material from the mixing chamber into the pressurized chamber is prevented.
Particularly preferred is a version in which a control unit is provided which opens the air feeder when the mixture components are supplied and closes the air feeder when the vacuum container is closed in a vacuum-tight manner. This control unit is preferably automated, so that, depending on the stage of the method, it is possible to evacuate the pressurized container and also to allow a build-up of pressure in the pressurized container, in order to counteract any abrupt rise in pressure in the mixing chamber as a result of the feeding of mixture components. It is self-evident that the air feeder described can be used outside the mixing chamber but inside the vacuum chamber even with known mixers. Even if the known mixers do not use the pressure difference between the pressurized chamber and the surroundings as a driving force, and consequently, the abrupt rise in pressure resulting from the charging process is significantly smaller, a transfer of material from the mixing chamber into the pressurized chamber will be prevented even with known mixing containers.
A further particularly preferred version of the present invention provides that a feeder device for water is arranged in such a manner that the water is supplied through or along a preferably eccentrically arranged mixing tool with mixing paddles and fed into the mixture essentially in the region of the ends of the mixing paddles. Also in this case, according to the invention, the pressure difference between the mixing chamber and the outside environment is exploited. If water is to be fed into the mixture, a valve merely has to be opened. As a result of the vacuum pressure prevailing in the mixing chamber, the water is sucked through the feeder device directly into the mixture. The arrangement of the feeder device along a mixing tool has the advantage that the water can be fed directly into the mixture at different positions. In this context, the fluid outlet openings in the water feeder device are preferably arranged at different depths below the level of the mixture. Adequate mixing can therefore be achieved extremely quickly.
Particularly preferably, the feeder device for water has a dosage weighing device, the dosage weighing device and mixer being connected by a preferably at least partially resilient pipe, which can be closed by a valve, the valve being preferably arranged on the cover of the mixer.
The so-called quality-determining mixture components are preferably fed with the assistance of a feeder lance, if possible below the level of the mixture. In this context, the outlet opening of the feeder lance is, if possible, oriented tangentially to the direction of flow of the mixture and preferably points in the direction of flow. This guarantees that, as a result of the flow of mixture emphasized by the rotation of the mixture, the quality-determining mixture components, which are sucked into the mixing chamber as a result of the vacuum pressure prevailing in the mixing chamber, are drawn along with the mixture in the direction of flow and are rapidly and effectively mixed with the latter.
Further advantages, features and possible applications of the present invention are explained with reference to the following description of preferred versions and the associated figures.
There are shown in:
a) and 1b) a lateral view of the arrangement of a feeder device and a feeder opening of the mixer in an opened and in a closed position,
a) and 4b) a schematic representation of the connection between a fluid dosage weighing device and mixing container,
a) and 5b) a lateral view and a top view of the feeder elements for fluids in the mixing chamber,
a) and 1b) show the outlet region of a solids weighing device 10 and the inlet region of the mixer 1. The solids weighing device 10 is used for determining the quantity of recycled sand to be supplied or optionally also of other mixture components. In
An inlet connecting piece 2 is arranged at the upper side of the mixer 1. This inlet connecting piece 2 is sealed in a vacuum-tight manner through the container cover 3 with the assistance of the lever arm 5, which is driven, for example, by a hydraulic cylinder. It can be seen that the container cover 3 provides one lateral cheek 4 at both of its lateral outer edges.
The solids weighing device 10 also has an outlet flap 11, which provides lateral cheeks 11′ at both of its lateral outer edges. This flap can be opened or closed via the lever 12.
Moreover, this version has a conveyor chute 13. The conveyor chute 13 also has lateral cheeks 13′ at both of its lateral outer edges. The conveyor chute 13 can be moved with the assistance of the parallel guide 14 and the lifting drive 15 into the intermediate space between the solids weighing device 10 and the mixer 1. As a result of the lateral cheeks, the outlet flap 11, filling flap 3 and conveyor chute 13 provide an essentially U-shaped cross-section, the lateral cheeks forming the two arms of the U-shape.
The conveyor chute 13 is arranged in such a manner that, in the extended position, when the outlet cover 11 of the solids weighing device 10 is open, together with the outlet flap 11 and the lateral cheeks 11′, 14′, it forms a channel with an essentially rectangular cross-section.
This channel is further extended by the open filling cover 8 with its lateral cheeks 4, so that, in the conveying position, the situation shown in
The entire range of movement of the flaps 3, 11 and of the conveyor chute 13 is surrounded by a housing 6 and/or 6′. In the version shown, the housing is designed in two parts; and the two housing parts 6, 6′ are connected to one another via a flexible preferably sealing connection 7. The charging process is as follows. First, the two covers 3, 11 of the mixer 1 and the solids weighing device 10 are closed. If the mixer is to be charged with materials which are located in the solids weighing device 10, the cover 3 of the mixer 1 is first opened. Next, the conveyor chute 13 is moved into the region between the solids weighing device 10 and the mixer 1. This has not hitherto been possible because, in the extended state, the conveyor chute 13 is located within the rotational range of the filling cover 3 of the mixer 1. If the outlet flap 11 of the solids weighing device 10 is then opened, the materials from the solids weighing device will be filled directly and rapidly into the mixing chamber of the mixer 1 via the channel formed by the outlet flap 11, inlet cover 3 and conveyor chute 13. In this manner, the mould sand from the solids weighing device 10 is conveyed into the mixer 1 without significant material loss and without substantial emissions of dust, through a large cross-section and in a short time.
As shown in the diagrams, additionally arranged in the housing 6, 6′ are air nozzles 8, 9 which direct an air-flow onto the seal of the inlet cover 3 and the drive mechanism of the inlet cover 3, so that, after each filling process, those places are fanned on which a deposit of sand may have a negative effect, in order to guarantee a secure and sealed closure of the inlet cover 3.
The inlet cover 3 of the mixer 1 according to the invention does not have any particularly complicated design for the sealing elements. Rather, it is simply pressed by the vacuum pressure prevailing in the mixer 1 against the opening of the mixer 1, so that the opening or the cover 3 merely needs to be surrounded by a sealing ring. However, this version of the inlet cover 3 necessarily requires a certain distance between the solids weighing device 10 and the mixer 1, because the cover 3 requires sufficient clearance for rotation. As described, this distance is bridged by the material guiding channel, which is formed from the flaps 3, 11 and the conveyor chute 15 and lateral cheeks 4, 11′, 13′. According to the invention, the charging time for a mixer of this kind is reduced from approximately 30-40 seconds, which is entirely standard for mixers available on the market, to less than 10 seconds.
The mixing chamber 16 of a vacuum mixer 1 is normally arranged in a vacuum chamber 17. The basic structure is shown in
It is evident that the air feeder does not necessarily require a pressure fan 19 or a similar device; for some cases of application, it may be adequate if only a closable opening is provided as the air feeder, which is simply opened at the beginning of the charging process, so that the pressure in the vacuum chamber and/or the intermediate space 17 and the mixing chamber 16 rises in an approximately synchronized manner.
At the start of the preparation of the mould sand under vacuum, the air feeder must be switched off again or closed.
a) and 4b) show the charging of the mixer with the necessary quantity of mixing water. Between 0.5 and 4% mixing water are normally added to the mixture. The exact quantity of water to be added is determined by measuring the residual moisture of the recycled sand before placing in the mixer or even in the mixer. The residual moisture of the recycled sand and therefore also the quantity of mixing water to be added depends on the preliminary thermal loading of the recycled sand. Moreover, it must be borne in mind that the vacuum-cooling process also consumes a certain quantity of water because, as described above, it is based upon the removal of evaporation heat, so that an additional quantity of water must be added, which evaporates during the vacuum phase.
a) shows a conventional arrangement. A weighing container 25 is shown which is suspended by means of a carrier structure 24 on a weighing cell 23. The weighing cell 23 measures the weight of the weighing container 25 including the carrier structure and content of water. When the valve 26 is opened, the water leaves the weighing container 25 via an outlet pipe 27 and flows into an inlet pipe 30. The inlet pipe 30 is connected rigidly to the pressurized container of the mixer. The inlet pipe 30 and outlet pipe 27 are expediently surrounded by a pressure-resistant but flexible sleeve 29. To allow the water to be added very quickly, water is drawn from the weighing container 25 and the quantity is determined via the weight loss, which is detected by the weighing cell 23.
The pressure difference between the mixing chamber and the surroundings or, in this case, the weighing container 25 can also be used advantageously in the context of the water supply, in order to significantly accelerate the charging process. This is possible in a similar manner to the charging of mould sand described with reference to
In the case of the arrangement shown in
As a result of this arrangement, the weighing container 25 can reliably be filled with the desired quantity when the valve 26 is closed. The weighing error while the valve is open can easily be corrected by means of a tare correction.
For particularly accurate dosages, the tare correction can be carried out with the assistance of the dosage computer 31 and the dosage meter 33. The dosage meter 33 registers the current pressure in the mixing chamber and passes this value to the dosage computer 31. The dosage computer 31 calculates the drawing force exerted by the mixing chamber on the weighing cell 23 and corrects the weighing result, so that the mixing water can be metered very accurately.
The duration of filling can be considerably reduced by exploiting the pressure difference between the mixing chamber and the ambient pressure. For example, the cross-section d′ of the outlet pipe can be reduced, so that the falsifying influence of the drawing force can be further reduced. As a result, the rate of filling is necessarily increased, but this is more than compensated by the vacuum-filling process.
Introducing the mixing water under vacuum has the additional advantage that the water is immediately finely distributed and spreads in a nebulous manner in the mixing chamber.
The thorough mixing of the mixing water with the mixture can be further improved and above all accelerated if the mixing water is supplied via a device, as shown in
An alternative version of the present invention is shown in FIG. 6. In this case, powdered additives are successfully utilized by exploiting the pressure difference (principle of suction conveyance) between the mixing container and the atmosphere.
These additives, often also referred to as quality-determining mixture components, are normally blown into the mixer under pressure. However, for this purpose, appropriate pressure stores must be provided for the pumping air. In addition to the undesirable additional space requirement, the consumption of expensive compressed air is not to be ignored. Moreover, the vacuum cooling process cannot be implemented while the additives are being supplied, because the supply of additives under pressure is also necessarily associated with an increase in pressure in the mixing container. Furthermore, the charge of compressed air in the mixing chamber can have disadvantageous consequences. In addition to restricting the sealing function of the seal 8, as described in the context of
According to the invention, the disadvantages described can be overcome by supplying the powdered additives with the assistance of a preferably stationary mixing tool 39 or its carrier arm 41. The stationary mixing tool 39 is used primarily for guiding the material. With reference to the arrangement shown in
As a result of this sophisticated arrangement and the exploitation according to the invention of the pressure difference, additives can be supplied simply and economically. Moreover, mixing is extremely effective and, above all, rapid.
The hollow tool designed for supplying additives can also advantageously be used for ventilation, that is, for pressure equalization of the mixing container, when the vacuum cooling process is completed. For this purpose, air is simply sucked in through the feeder 44 into the mixing container. Feeding the air directly into the mixture, that is, below the level of the mixture, provides the important advantage that the mixture is not temporarily compressed by the resulting pressure wave, which is not the case with the conventional mixers, and the air can therefore be mixed into the mixture.
This version allows the addition of the mixture under vacuum. The filling procedure is as follows. Initially, the closure cap 11 of the weighing container 49 is closed. The mixing container 1 is evacuated so that vacuum pressure prevails even inside the conveyor funnel 46 and the pressure-resistant housing 47. The mixture is then filled into the weighing container 49, and the quantity to be filled is determined via the pressure transducer 50. When measuring the quantity to be filled, it should be taken into account that the pressure difference between the housing 47 and the interior of the weighing container 49 falsifies the weighing via the force transducer 50. This must be taken into account when calculating the net weight. The weighing container 49 and the housing 47 rigidly connected to the weighing container can readily be displaced in a vertical; direction depending on the filling weight and the pressure difference. This vertical movement is allowed by the flexible connection 48, which is clearly shown in
In the next stage, the closure mountings 51, which enclose the closure cap in the manner of a clamp, are rotated outwards around the axis 53, as shown in
It is self-evident that all of the versions described can also be realized with smaller mixing container openings, although this necessarily means that the charging rate will be somewhat lower. Depending on the individual case of application, however, one of the versions described may be advantageous in combination with a smaller charging opening.
Number | Date | Country | Kind |
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100 30 675 | Jun 2000 | DE | national |
This application is a 371 of PCT/DE01/02259 filed on Jun. 16, 2001.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCTDE01/02259 | 6/16/2001 | WO | 00 | 6/2/2003 |
Publishing Document | Publishing Date | Country | Kind |
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WO0198001 | 12/27/2001 | WO | A |
Number | Name | Date | Kind |
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5588471 | Lowe | Dec 1996 | A |
5915833 | Kruse | Jun 1999 | A |
6030111 | Tokuyoshi et al. | Feb 2000 | A |
6402361 | Reinemuth | Jun 2002 | B1 |
Number | Date | Country |
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2 066 683 | Jul 1981 | GB |
WO 0121341 | Mar 2001 | WO |
Number | Date | Country | |
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20040020623 A1 | Feb 2004 | US |