Method and installation for the production of containers

Information

  • Patent Grant
  • 8354051
  • Patent Number
    8,354,051
  • Date Filed
    Wednesday, September 16, 2009
    15 years ago
  • Date Issued
    Tuesday, January 15, 2013
    11 years ago
Abstract
The invention relates to a method of producing a container from a thermoplastic blank (2), comprising: a step in which the blank (2) is heated using at least one beam (22) of coherent electromagnetic radiation, and a step in which the container is formed from the blank (2) thus heated. The invention also relates to an installation (1) which is used to produce containers (2) and which comprises a unit (16) for heating the blanks (2) in order to form containers from the blanks (2) thus heated. The inventive installation (1) defines a path (23) along which the blanks (2) travel inside the heating unit (16). In addition, the heating unit (16) comprises at least one coherent electromagnetic radiation source (26) which is directed towards a zone (25) that is located on the aforementioned path (23).
Description
TECHNICAL FIELD

The invention relates to the production of containers.


It relates more particularly to a method and an installation for producing containers—especially bottles—from thermoplastic parisons.


BACKGROUND ART

Such a method involves a first step during which the parisons are heated, within an appropriate heating unit, then a second step during which the parisons are introduced, hot, into a multiple-mold blow-molding or stretch-blow-molding unit where they are shaped into containers.


On leaving the blow-molding or stretch-blow-molding unit, the containers thus formed will be directed either toward a storage unit to await subsequent filling or directly toward a filling unit.


Let us remember that a container parison comprises a neck, intended to take the closure that seals the container that is to come and which is already at its final dimensions, extended by a body, the shaping of which will lead to the actual container proper.


The heating of the parisons is generally performed within an oven equipped with an array of tubular halogen lamps past which the parisons progress, while being rotated on themselves. More specifically, an oven contains several elementary modules, each containing several lamps, each of the lamps being controlled individually so that, ultimately, on leaving the oven, the temperature of the body of each of the parisons is above the glass transition temperature of their constituent material and a heating profile is obtained on each parison, which profile is predetermined such that the distribution of material is optimized in the container that is to be obtained.


This method of heating does have a certain number of disadvantages.


First, its energy efficiency (that is to say the ratio of the power absorbed by the parisons to the power consumed by the lamps) is extremely low, of the order of 11 to 15%. This is because of the spatial diffusion of the radiation emitted by the lamps, only a fraction of which reaches the body of the parisons. The low value displayed by this efficiency has a negative impact on production rates.


Next, the heating profile (that is to say the plot of temperatures measured along the length of the parison) cannot be obtained precisely; given the diffusion effect, the radiation from the lamps interferes with each other which means that seeking precisely to regulate the intensity of the combined radiation at a given distance from the lamps is an extremely fanciful notion.


In order to alleviate this disadvantage, there has already been the idea to make the parisons file past the lamps at the closest possible range. However, this then gives rise to an undesirable problem of overheating at the surface of the parisons, which phenomenon cannot be lessened unless an expensive ventilation system is fitted and operated.


Furthermore, there is also a significant phenomenon of thermal convection whereby the ascending air streams transfer some of the emitted radiation to the capital part of the parison. Now, the neck of this parison needs to be kept at a modest temperature so that it maintains its original dimensions.


Hence, in order to limit the incident heating of the neck by thermal convection, it has become judicious to orient the parisons neck down. As such a precaution proved to be insufficient in certain instances, it was combined with ventilation of the neck. Whatever the case, this orientation of the parisons entails, on entering the heating unit, an operation of inverting the preforms, because the preforms are generally introduced into the oven neck up, and also an operation of inverting either the preforms before they are introduced into the mold when the stretch-blow-molding step is performed neck up (which is the more common scenario), or of the containers as they leave the installation so that they can be stored or filled. These inverting operations entail installing and operating appropriate devices which make the installation more complicated and have a negative impact on cost.


SUMMARY OF THE INVENTION

In order in particular to alleviate the aforementioned disadvantages, the method according to the invention for producing a container from a thermoplastic parison involves:

    • a step of heating the parison performed by means of at least one beam of coherent electromagnetic radiation, then
    • a step of forming the container from the parison thus heated.


The invention also proposes an installation for producing containers from thermoplastic parisons, which comprises a heating unit for heating the parisons with a view to forming the containers from the parisons thus heated. The installation defines a path that the parisons are intended to follow within the heating unit, which comprises at least one source of coherent electromagnetic radiation directed toward a region situated on the path of the parisons.


The radiation can thus be concentrated on to a localized part of the parison, making it possible to obtain a temperature profile close to a predetermined profile, the almost-total absence of diffusion and thermal convection allowing the parison to be heated while it is oriented neck up without this neck experiencing incident heating liable to alter its dimensions.


More specifically, the beam of electromagnetic radiation (such as a laser emitted for example by a laser diode) is preferably directed toward the body of the parison. The radiation is preferably emitted in the near infrared, in other words at a wavelength ranging between about 700 nm and 1600 nm.


The heating of the parison is preferably performed by means of a plurality of adjacent and/or superposed beams of electromagnetic radiation. In practice, heating may be performed by means of a plurality of juxtaposed and/or superposed laser diodes, for example, in the form of one or more arrays.


The or each beam may be linear or planar; it is, for example, directed in a predetermined overall direction, while the parison, at least locally is made to follow a path either substantially perpendicular or substantially parallel to the direction of the beam.


In the heating step, the parison is preferably rotated about a predetermined axis, for example, an axis that coincides with an axis of revolution of the parison, so as to obtain uniform heating around the circumference of this parison.


Furthermore, the neck of the parison may be ventilated in order to remove the overflow of hot air.


According to one embodiment, in the heating step, the beam is reflected at least once off a reflective surface.


The heating unit comprises, for example, a chamber comprising a first wall and a second wall facing one another and substantially parallel to the path of the parisons, these walls being positioned one on each side of this path and together delimiting an internal volume, the first wall being equipped with a plurality of superposed parallel slits facing each of which there is positioned, on the opposite side to the internal volume, a row of radiation sources.


According to one embodiment, the second wall at least has, on the same side as the internal volume, a reflective internal surface.


In order to ventilate the neck of the parison, the heating unit may comprise a ventilation system able to generate an air flow passing through a region situated vertically in line with said chamber.


According to an embodiment variant, the installation comprises two successive heating units of this type.


According to another embodiment, with the path of the parisons being substantially circular, the heating unit comprises a plurality of successive chambers positioned along the path, each chamber having two cylindrical walls facing each other and positioned one on each side of the path and together defining an internal cavity, each wall having several adjacent reflective facets facing toward the cavity, the source of electromagnetic radiation being directed toward one of these facets.


The heating unit, for example comprises an opaque screen adjacent to one of the facets, to absorb the beam after it has been reflected several times off the facets.


Whatever the embodiment adopted, the heating unit preferably comprises means for rotating the parisons about their axis of revolution.





BRIEF DESCRIPTION OF THE DRAWINGS

Other objects and advantages of the invention will emerge from the description given hereinafter with reference to the attached drawings in which:



FIG. 1 is a schematic view of an installation for producing containers from thermoplastic parisons;



FIGS. 2 and 3 are perspective views of a block and of an array of laser diodes which may be chosen to equip an installation according to the invention;



FIG. 4 is a schematic perspective view showing the internal structure of an array of laser diodes;



FIG. 5 is a diagram illustrating the compared efficiency of three different laser sources for heating a PET;



FIG. 6 is a schematic perspective view illustrating a heating unit for an installation for producing containers according to a first embodiment;



FIG. 7 is an elevation in cross section illustrating the heating unit of FIG. 6;



FIG. 8 is a schematic perspective view showing a container parison exposed to a laser beam in a heating unit as depicted in FIG. 7;



FIG. 9 is a schematic perspective view illustrating a heating unit for an installation for producing containers according to a second embodiment;



FIG. 10 is a schematic perspective view similar to FIG. 9 also illustrating a heating unit according to a variant of the second embodiment;



FIG. 11 is a schematic plan view, from above, illustrating the heating unit for an installation for producing containers according to a third embodiment;



FIG. 12 is a plan view, from above, on a larger scale, of a detail of the heating unit depicted in FIG. 11; and



FIG. 13 is a view illustrating, in perspective, the detail depicted in FIG. 12.





DESCRIPTION OF THE PREFERRED EMBODIMENT


FIG. 1 depicts an installation 1 for producing containers, such as bottles, from parisons 2, in this instance preforms, made of thermoplastic. It is recalled here that the term “parison” covers not only a preform, but also any intermediate part between the preform and the finished container. Some methods actually involve two successive shaping steps, namely a first step of forming an intermediate container from the preform then, after a certain time has elapsed, a second step of forming the finished container from the intermediate container.


A parison 2 in the form of a preform is depicted on a large scale in FIG. 8. It is a molded component in the form of a test specimen exhibiting symmetry of revolution about an axis A and having a neck 3 intended, as far as possible, not to undergo any deformation during the forming of the container, and a body 4 ending in a bottom 5 and intended to be heated and then shaped. Without implying any limitation to such an application, it is assumed in the remainder of the description that the containers are formed directly from preforms, which means that, for the sake of convenience, this term will be used arbitrarily to denote parisons or preforms.


The containers are, for example, made of polyethylene terephthalate (PET), of polyethylene naphthalate (PEN), or another appropriate thermoplastic.


As depicted in FIG. 1, the installation 1 comprises a feed unit 10 which supplies the preforms 2 to a forming unit 6. The feed unit 10 comprises, for example, a hopper 11 into which the preforms 2, produced beforehand by molding, are loaded loose, this hopper 11 being connected to an inlet 12 of the forming unit 6 by a sorting machine 13 which isolates and positions the preforms 2 (which are cold, that is to say at ambient temperature) on a slide 14.


The preforms 2 are then mounted on a transfer line 15 then heated, as they pass through a heating unit 16, before being introduced hot into a blow-molding unit 17 (or stretch-blow-molding unit) of the multiple-mold carousel type.


The containers are then transferred, by means of a conveyer 18, such as a wheel with cavities, from the molds of the blow-molding unit 17 to an outlet of the forming unit 6.


Within the heating unit 16, the preforms 2 are heated by means of at least one beam 22 of coherent electromagnetic radiation.


For this, the installation 1 defines, within the heating unit 16, a predetermined path 23 that the preforms 2 follow during the heating step. More specifically, this path 23 is defined by a conveyer (not depicted) equipped with links articulated to one another and from which the preforms 2 are suspended. This driving technique is well known to those skilled in the art and will not be described in detail; let us nonetheless specify that each link comprises attachment means in the form of a hanger, known as a “spinner” in the terms of the art, which fits into or on to the neck 3 of the preform 2, this hanger having a pinion-shaped part which meshes with a fixed rack running alongside the line, so that as the line advances, the hangers, with their preforms are rotated.


The heating unit 16 comprises at least one source 24 of coherent electromagnetic radiation directed toward a target region 25 situated on the path 23 of the preforms 2, and through which these pass, as we shall see later.


The description which follows first of all sets out the choice of the source 24 of electromagnetic radiation for heating the preforms (§1), and then, describes the heating unit 16 and the corresponding heating method, in three exemplary embodiments (§2).


1. Choice of the Source of Electromagnetic Radiation


Tests have shown that, across the light spectrum, the radiation that is of use for heating a thermoplastic such as a PET (the material from which container preforms for the most common applications are conventionally made) lies in the field of the near infrared, that is to say at wavelengths ranging between 700 nm and 1600 nm.


Several lasers available on the market have proved satisfactory in application to the heating of thermoplastics (the tests conducted by the inventors were conducted using a PET).


A PET preform generally has a wall thickness ranging between 1 mm and 3 mm, entirely dependent on the type of container that is to be obtained.


A first test was conducted by the inventors on PET test specimens 3 mm thick using three laser sources emitting in the near infrared, namely:

    • 1. first of all, a laser of the Nd:YAG type (this type of laser comprises a neodymium-doped yttrium aluminum garnet amplifier with a power of 4.4 kW, generating an infrared beam with a wavelength of 1064 nm,
    • 2. secondly, a laser diode of the hybrid type, with a power of 3 kW, generating an infrared beam combining two wavelengths of 808 nm and 940 nm respectively, and
    • 3. thirdly, a laser diode with a power of 500 W generating an infrared beam with a wavelength of 808 nm.


The diagram in FIG. 5 shows, for each of these lasers, the plot of the time taken for the material to reach the core temperature of 130° C. (this is in fact the temperature to which PET preforms need to be heated), as a function of the transmitted power density.


It can be seen that, while the efficiency of the Nd:YAG laser seems to be superior to that of the diode lasers, the plots are, nonetheless, similar, which shows that the laser can be chosen on the basis of parameters other than efficiency alone, particularly on the basis of the shape of the beam, the size of the source and, of course, its cost.


Furthermore, it has been found that the choice of laser is also dependent on the need to safeguard the material from uncontrolled crystallization. A compromise is therefore needed. Although the Nd:YAG has proven its efficiency, the diode laser will take preference over it, being less expensive and less bulky, for an imperceptible difference in efficiency in the application to the heating of thermoplastic preforms.


While tests have shown that the domain adopted for the radiation is that of the near infrared, they have also shown that, before 1000 nm, the choice in wavelength has little impact on the heating quality (“heating quality” is to be understood as meaning heating which not only gives a lower exposure time, but also gives good accuracy and good diffusion of the radiation through the thickness of the material).


By contrast, for the same wavelength, the following parameters: beam shape, energy profile, power density, have an important effect on the heating quality.


As we shall see hereinafter, the first exemplary embodiment uses a planar beam 22, generated by a laser diode 26 to which a spreading lens is added. Various manufacturers offer laser diodes which either come individually or assembled into arrays as depicted in FIGS. 2 and 3.



FIG. 2 depicts a block 27 of stacked diodes 26 with a total power of 1200 W, marketed by Thales, under the references TH-C17xx-M1 or TH-C55xx-M1. Each diode 26 generates a planar laser beam so that the block generates several superposed planar beams which may be parallel or divergent.



FIG. 3 depicts an array 28 of diodes 26 with a power of 40 W each, each diode 26 generating a planar beam. The array 28 thus generates a planar beam, formed by the juxtaposition of the beams generated by all the diodes. An array of this type is marketed by Thales, under the references TH-C1840-P or TH-C1841-R.


As can be seen in FIGS. 2 and 3, the block 27 and the array 28 are both equipped with an internal water-cooling circuit, the water inlet 29 and outlet 30 pipes of which can be seen in the figures.



FIG. 4 schematically depicts the structure of an array 28 of diodes 26. The diodes 26 are jointly mounted and soldered onto a support 31 equipped with ducts 32 perpendicular to the beams 22 and through which the cooling fluid runs.


2. Producing the Heating Unit

The heating unit is now described in greater detail according to three distinct exemplary embodiments with reference to FIGS. 6 to 11.


2.1 EXAMPLE 1

The first exemplary embodiment is described with reference to FIGS. 6 to 8.


As can be seen in FIG. 6, the path 23, represented by a chain line, that the preforms 2 follow within the heating unit 16 is substantially rectilinear and defines a direction L termed the longitudinal direction.


In this example, the heating unit 16 comprises a chamber 33 comprising a first wall and a second wall 34, 35 which are vertical and face one another and run substantially parallel to the path 23, being positioned one on each side thereof.


The walls 34, 35 together delimit an internal volume 36 through which the preforms 2 pass longitudinally.


As can be seen in FIG. 7, the walls 34, 35 extend over a height substantially equal to the length of the body 4 of the preform 2. This preform is oriented neck up, the neck 3 protruding out of the chamber 33 above the walls 34, 35. The chamber 33 is open at the bottom to allow an ascending air flow 37 to circulate to provide the chamber 33 with a certain degree of ventilation in order to remove the heat emitted by the body 4 of the heated parison 2.


Each wall 34, 35 has a respective internal face 38, 39 facing toward the internal volume 36 and a respective opposite external face 40, 41.


The first wall 34 is equipped with a plurality of superposed horizontal parallel slits 42 facing each of which there is positioned, on the external face 40 side, an array 28 of laser diodes, as described hereinabove.


As can be seen in FIG. 6, the heating unit thus comprises a matrix 43 of laser diodes formed by a plurality of superposed arrays 28, which runs substantially facing the entire height of the body 4 of the preforms 2. The arrays 28 may be cooled by means of their own circuits, which are connected to a common cooling liquid supply 29 and discharge 30 duct.


Each diode emits a beam 22 oriented in an overall direction T that is transverse to the path 23, and runs in a horizontal mid-plane P parallel to this path 23.


Each slit 42 subjects the beam 22 passing through it to a diffusion effect which means that the beam 22 has a tendency to diverge on each side of the horizontal midplane P.


Furthermore, the internal faces 38, 39 of the walls 34, are reflective which means that the beam 22 undergoes several successive reflections and therefore crosses the preform 2 several times before it loses its energy. This results in an improvement in the energy efficiency and in a reduction in the time taken to heat the preforms 2.


To produce the matrix 43 of diodes, it is possible to use several superposed arrays 28 of 40 W diodes of the type explained hereinabove (cf. §1) and illustrated in FIG. 3.


In FIG. 7, the angle of divergence of the beam 22 is exaggerated in order to demonstrate this dual phenomenon of divergence and reflection.


Rotating the preform 2 about its axis A makes it possible, on leaving the heating unit, to obtain a temperature profile that is substantially constant around the circumference of the body 4.


Furthermore, it is possible to regulate the power of the diodes 26 in such a way as to obtain the desired temperature profile which is non-uniform over the length of the preform 2, for example, with a view ultimately to obtaining a container of curved shape. In such an example, the middle arrays 28 will be set to a lower power than the lower and upper arrays 28 so as to keep the central part of the body 4 at a temperature that is lower (for example at around 115° C.) than the temperature of its end parts (which will be raised to around 130° C.)


Although the phenomenon of thermal convection in the chamber 33 is limited because of the use of coherent radiation, particularly so that the neck 3 does not experience any heating liable to soften it and cause an alteration to its dimensions during the blowing (which, as has been stated, allows the preforms 2 to be oriented neck up), it may prove preferable to ventilate at least the upper part of the chamber 33, so as to create a cool air flow around the neck 3.


Hence, as has been depicted in FIG. 7, the heating unit 16 is equipped with a ventilation system 44 generating an air flow 45 which, vertically in line with the chamber 33, circulates transversely in order to remove the heat energy drained away by the upward air flow 37 due to natural thermal convection. This ventilation system 44 for example comprises a fan 46 arranged in a casing 47 positioned on the external face 41 side of the second wall 35 and having an opening 48 extending vertically in line with an upper edge 49 of the wall 35, able to route the air flow 37 from the fan 46 transversely.


Each preform 2 is heated as follows.


The preform 2 originating from the feed unit 10 enters the heating unit 16 along the longitudinal path 23 locally defined by the conveyer.


The preform 2 is rotated about its axis A. The laser beams 22 emitted by the diodes 26 strike it along the entire path that it follows through the chamber 33. Initially at ambient temperature, the body 4 of the preform 2 is quickly raised to a temperature of around 120° C., while its neck 3 is kept at ambient temperature.


On leaving the chamber 33, the preform 2 is transferred to the stretch-blow-molding unit 18 to be shaped into a container.


2.2 EXAMPLE 2

The second exemplary embodiment is now described with reference to FIGS. 9 and 10. This second example comprises a first embodiment illustrated in FIG. 9, whereby the installation 1 comprises a single heating unit 16, and a second embodiment which, illustrated in FIG. 10, constitutes a variant of the first in that the installation 1 comprises two successive heating units 16.


According to the first embodiment, the path 23 followed by the preforms 2 within the heating unit 16 is locally rectilinear, in a longitudinal direction L, between an upstream transfer region 50 where the cold preforms 2 are brought into the heating unit 16 by an upstream transfer wheel 51, and a downstream transfer region 52, where the hot preforms 2 are removed from the heating unit 16 by a downstream transfer wheel 53.


The heating unit 16 comprises several superposed laser sources 24 positioned at a downstream end of the path 23, along the axis thereof. The sources 24 here consist of collimating lenses 54 each connected by an optical fiber 55, to a diode laser generator 56 and together form a vertical block 57 of a height substantially equal to the bodies 4 of the preforms 2.


As can be seen in FIG. 9, the lenses 54 are oriented in such a way as to generate longitudinal (linear or planar) beams 22 which strike the preforms 2 in succession before encountering an opaque screen 58 forming an energy sink, positioned transversely in the continuation of the path 23, beyond the upstream transfer wheel 51.


Thus, along the path 23, each preform 2 is progressively heated by the laser beams 22 whose energy, transferred successively to the preforms 2 that they strike and pass through is, first of all, from the point of view of the preform, low at the exit of the upstream transfer wheel 51, then increases as the preform 2 gradually nears the sources 24 before reaching a maximum in the vicinity of these sources before the preform 2 is taken up by the downstream transfer wheel 53.


It is thus possible to heat the preforms 2 gradually using only a block of laser sources, rather than a matrix as explained in the first example described above.


However, in order to avoid excessively rapid dissipation of the energy of the laser beams, it is preferable to use laser diodes of a higher power. Thus, the laser adopted here is a diode laser of the type set out hereinabove (cf. §1), with an individual power of 500 W.


As illustrated in FIG. 9, the heating unit 16 comprises a confinement chamber 59 comprising two walls 60, 61 facing each other and positioned one on each side of the path 23, between the upstream 51 and downstream 53 transfer wheels.


These walls 60, 61 have reflective internal faces which confine the laser beams 22 by reflecting their transverse components resulting from the diffraction through the preforms 2. Thus energy losses are limited while at the same time improving the safety of the installation.


Although this is not shown in FIG. 9, the heating unit 16 may be equipped with a ventilation system similar to the one described hereinabove in the first exemplary embodiment.


According to the second embodiment, the installation 1 comprises two heating units 16, similar to the heating unit 16 described hereinabove in the first embodiment and positioned in succession in the path of the preforms 2, namely a first heating unit 16a designed to raise the preforms 2 to an intermediate temperature (that is to say to a temperature between ambient temperature, which corresponds to the initial temperature of the preforms, around 20° C., and the final temperature, prior to forming, of around 120° C.), and a second heating unit 16b designed to raise the preforms 2 to their final temperature (of around 120° C.)


The path 23a followed by the preforms 2 within the first heating unit 16a is locally rectilinear, in a longitudinal direction L between an upstream transfer region 51 where the cold preforms 2 are supplied to the first heating unit 16a by an upstream transfer wheel 51, and an intermediate transfer region 62 where the warm preforms 2 are transferred from the first heating unit 16a to the second 16b.


In the example depicted in FIG. 10, the heating units 16a, 16b are arranged parallel to one another, and the path 23b followed by the preforms in the intermediate transfer region 62 is curved. This arrangement makes it possible to avoid interference between the beams 22 of the first heating unit 16a and those of the second 16b.


The path 23c followed by the preforms 2 within the second heating unit 16b is, also, locally rectilinear and longitudinal, between the intermediate transfer region 62 and a downstream transfer region 52 where the hot preforms 2 are taken up transversely by a downstream transfer wheel 53.


Each heating unit 16a, 16b comprises a block 27 of superposed laser diodes of a height substantially equal to that of the bodies 4 of the preforms 2 and arranged at a downstream end of the corresponding path 23a, 23c along the axis thereof.


The blocks 27 of diodes are, for example, of the kind set out hereinabove (cf. §1) and illustrated in FIG. 2.


As can be seen in FIG. 10, the first heating unit 16a comprises an opaque screen 58 forming an energy sink, that the laser beams 22 strike once they have passed in succession through the preforms 2 present on the path 23a, and which is positioned transversely in the continuation of the path 23a beyond the upstream transfer wheel 51.


The second heating unit 16b also comprises such an opaque screen 58, for its part positioned in the continuation of the path 23c, on the same side as the intermediate transfer region 62.


Furthermore, as can be seen in FIG. 10, each heating unit 16a, 16b comprises a confinement chamber 59 of which the reflective walls 60, 61, positioned one on each side of the corresponding path 23a, 23c, prevent the lateral dispersion of the laser beams 22.


Thus, the preforms 2 are first of all raised to an intermediate temperature, for example of around 80° C., within the first heating unit 16a, and then, from there, are raised to a final temperature of about 120° C. within the second heating unit 16b before being transferred to the stretch-blow-molding unit 18.


It should be noted that for particular applications, more than two heating units could be envisioned.


2.3 EXAMPLE 3

The third exemplary embodiment is now described with reference to FIGS. 11 to 13.


In this example, the path 23 of the parisons 2 within the heating unit 16 is substantially circular and, as can be seen in FIG. 11, the heating unit 16 comprises a plurality of adjacent chambers 63 arranged along the path 23 and through which the preforms 2 pass in succession.


The path 23 is defined between an upstream transfer wheel 51 which brings the preforms 2 from the feed unit 10, and a downstream transfer wheel 53 carrying the stretch-blow-molding molds.


Each chamber 63 has two cylindrical walls facing each other, namely an internal wall 64 and an external wall 65, positioned one on each side of the path 23, and together defining an internal cavity 66 in which the preform 2 is positioned, its axis A therefore being temporarily coincident with an axis of symmetry of the chamber 63.


Each wall 64, 65 has several adjacent reflective facets 64a, 64b, 64c, 65a, 65b, 65c facing toward the cavity 66, each facet 64a, 64b, 64c of one wall 64 being positioned facing a corresponding facet 65a, 65b, 65c of the wall 65 opposite, these facets 64a, 64b, 64c, 65a, 65b, 65c not being exactly parallel with their pair but together defining an angle α of a few degrees, as can be seen in FIG. 12.


An upstream gap 67 and a downstream gap 68 are defined between the walls 64, 65, through which gaps 67, 68 each preform 2 in turn enters and then leaves.


Furthermore, the heating unit 16 comprises, for each chamber 63, an opaque screen 58 adjacent to one facet 64c of the internal wall 64, on the same side as the downstream gap 68.


For each chamber 63, the heating unit 16 comprises a block 27 of stacked laser diodes positioned facing one 64a of the facets of the internal wall 64, bordering the upstream gap 67. The laser diodes, directed toward this facet 64a are designed each to generate a beam 22 that is either linear or contained in a vertical plane that is transverse with respect to the path 23 of the preforms 2, the beam 22 making an acute angle with the normal to the facet 64a (FIG. 12).


Thus, each beam 22 undergoes several successive reflections off the facets 64a, 65a, 64b, 65b, 64c, 65c before striking the screen 58 which, as it forms an energy sink, completely absorbs the beam 22 (FIG. 12).


When a preform 2 is positioned at the center of the chamber 63, neck up, each beam 22 thus strikes it several times in distinct regions distributed at its circumference, as can be seen in FIG. 12.


As is apparent from FIG. 11, each preform 2 passes in succession through all the chambers 63 and the diodes can be set in such a way that their power increases along the path 23, the temperature of the preforms 2 therefore increasing as they gradually progress through the heating unit 16.


As before, the preforms 2 may be rotated about their axis of revolution A, their progress within the heating unit 16 preferably being stepwise, each preform 2 for example remaining in each chamber 63 for a fraction of a second.


It is perfectly conceivable for the progress of the preforms through the heating unit 16 to be continuous, because of the good ability that the laser beams have to penetrate through the material of which the bodies of the preforms are made.


Of course, irrespective of the embodiment adopted, it is possible to regulate the speed at which the preforms 2 travel through the heating unit.


In fact, the various settings (rate of travel, power of diodes, length of chamber) will be chosen by the person skilled in the art according to the material to be used for the preforms, and the machine rates dictated by production.


As we have seen, the method and the installation described hereinabove allow parisons, such as preforms, to be heated both more quickly and more precisely than can be achieved by the known methods and installations.


This speed means that the size of the heating unit can be limited, while tests have shown it is possible, using coherent electromagnetic beams, to achieve energy efficiencies of 50%, something which seemed unthinkable with the known methods and installations.


Tests have in fact demonstrated a laser energy penetration into the materials commonly used in this application, that is superior to that of the radiation of the halogen lamps conventionally employed for heating, thus improving the uniformity of the temperature of the material through the thickness of the preform.


The precision of the heating makes it possible to obtain a vertical heating profile which more precisely matches the desired profile. More specifically, this precision makes it possible to achieve heating profiles which hitherto were impossible to obtain. That in particular means that the design of the preforms can be revised so that the weight (which in practice means the wall thickness) of the preforms can be distributed differently according to the desired temperature profile for a particular profile of the container.


Furthermore, the small amount of heating of the ambient air additionally means that the preforms can be kept in the neck up orientation throughout the container production process, thus avoiding inverting operations.

Claims
  • 1. A method of thermally treating thermoplastic parisons for use in blow molding operations, the method comprising the steps of: transporting a series of parisons through a path of a heating unit of a blow molding machine, wherein each of the parisons has a neck and the heating unit is configured to heat the parisons while the parisons are oriented neck up in the heating unit;irradiating the parisons using one or more sources of coherent electromagnetic radiation at one or more wavelengths in a wavelength band between 700 nm and 1600 nm; andheating the parisons to at least one desired temperature,wherein the path is defined by opposing a first wall and a second wall which comprises: slits disposed on a side of the second wall proximate the path, andthe sources of coherent electromagnetic radiation which are disposed on other side of the second wall, distally from the path, and emit the coherent electromagnetic radiation through the slits across the path toward the first wall and across substantially an entire length of a body of each parison which follows the path.
  • 2. The method as claimed in claim 1, wherein said source of coherent electromagnetic radiation is an infrared-emitting device.
  • 3. The method as claimed in claim 1, wherein said source of coherent electromagnetic radiation is an infrared-emitting laser.
  • 4. The method as claimed in claim 1, wherein said source of coherent electromagnetic radiation is a near infrared-emitting device.
  • 5. The method as claimed in claim 1, wherein said source of coherent electromagnetic radiation is a near infrared-emitting laser.
  • 6. The method as claimed in claim 1, wherein said source of coherent electromagnetic radiation is a near infrared-emitting laser diode.
  • 7. The method as claimed in claim 1, wherein the one or more wavelengths are selected to increase the energy absorbed by the parisons.
  • 8. The method as claimed in claim 1, wherein the one or more wavelengths are selected for efficiently heating the parisons.
  • 9. The method as claimed in claim 1, wherein the one or more wavelengths are selected to reduce the exposure time required to heat the parisons to a desired temperature.
  • 10. The method as claimed in claim 1, wherein the one or more wavelengths are selected to achieve a desired amount of energy absorbed by the parisons for a given power density.
  • 11. The method as claimed in claim 1, wherein the one or more wavelengths are selected to achieve a desired heating quality of the parisons.
  • 12. The method as claimed in claim 1, wherein the one or more wavelengths are selected to achieve good diffusion of the radiant energy through the at least one predetermined thickness of the parisons.
  • 13. The method as claimed in claim 1, wherein the method comprises heating at least one section of the parisons to a temperature of about 80° C.
  • 14. The method as claimed in claim 1, wherein the method comprises heating at least one section of the parisons to a temperature of about 115° C.
  • 15. The method as claimed in claim 1, wherein the method comprises heating at least one section of the parisons to a temperature of about 120° C.
  • 16. The method as claimed in claim 1, wherein the method comprises heating at least one section of the parisons to a temperature of about 130° C.
  • 17. The method as claimed in claim 1, wherein the method comprises a first step of heating at least one section of the parisons to a temperature of about 80° C. and a second step of heating at least one section of the parisons to a temperature of about 130° C.
  • 18. The method as claimed in claim 1, wherein the method comprises a first step of heating at least one section of the parisons to a temperature of about 120° C. and a second step of heating at least one section of the parisons to a temperature of about 130° C.
  • 19. The method as claimed in claim 18, wherein the first step and the second step are performed in different heating units of the blow molding machine.
  • 20. The method as claimed in claim 1, wherein the parisons have at least one wall section having a thickness between 1 mm and 3 mm.
  • 21. The method as claimed in claim 1, wherein the parison has a non-uniform wall thickness, in which the weight of the thermoplastic material is distributed according to a desired temperature profile for producing a particular profile of a container to be produced from the parison.
  • 22. The method as claimed in claim 1, wherein at least two sections of the parisons are heated to different temperatures.
  • 23. The method as claimed in claim 1, wherein at least three sections of the parisons are heated to different temperatures.
  • 24. The method as claimed in claim 22 or 23, wherein the step of heating the parisons produces a non-uniform temperature profile over the length of the parisons.
  • 25. The method as claimed in claim 22 or 23, wherein the step of heating the parisons produces a non-uniform vertical heating profile of the parisons.
  • 26. The method as claimed in claim 23, wherein a middle section of the parison is heated to a temperature that is lower than the temperature to which two end sections of the parison are heated.
  • 27. The method as claimed in claim 23, wherein the middle section of the parison is heated to a temperature of about 115° C. and the two end sections are heated to a temperature of about 130° C.
  • 28. The method as claimed in claim 7 or 8, wherein the energy efficiency of the method is greater than 15%.
  • 29. The method as claimed in claim 7 or 8, wherein the energy efficiency of the method is from greater than 15% to 50%.
  • 30. The method as claimed in claim 10, further comprising heating said parisons for less than about 6 minutes at a power density of about 25 W/mm2.
  • 31. The method as claimed in claim 10, further comprising heating said parisons for less than about 3 minutes at a power density of about 40 W/mm2.
  • 32. The method as claimed in claim 10, further comprising heating said parisons for less than about 2.5 minutes at a power density of about 50 W/mm2.
  • 33. The method as claimed in claim 10, further comprising heating said parisons for less than about 2 minutes at a power density of about 55 W/mm2.
  • 34. The method as claimed in claim 10, further comprising heating said parisons for less than about 3 minutes at a power density of about 10 W/mm2.
  • 35. The method as claimed in claim 10, further comprising heating said parisons for less than about 1.5 minutes at a power density of about 20 W/mm2.
  • 36. The method as claimed in claim 10, further comprising heating said parisons for less than about 1 minute at a power density of about 30 W/mm2.
  • 37. The method as claimed in claim 11, comprising selecting one or more of selecting beam shape, energy profile and power density to increase heating quality.
  • 38. The method as claimed in claim 1, wherein the heating step is performed at a power adapted to prevent uncontrolled crystallization of the thermoplastic material.
  • 39. The method as claimed in claim 1, wherein the thermoplastic parisons comprise polyethylene terephthalate (PET).
  • 40. The method as claimed in claim 1, wherein the thermoplastic parisons comprise polyethylene naphthalate (PEN).
  • 41. The method as claimed in claim 38, wherein the source of coherent electromagnetic radiation comprises at least one laser diode.
  • 42. The method as claimed in claim 38, wherein the source of coherent electromagnetic radiation comprises at least one near infrared laser diode emitting radiation at a wavelength of 808 nm.
  • 43. The method as claimed in claim 38, wherein the source of coherent electromagnetic radiation comprises at least two near infrared laser diodes emitting radiation at wavelengths of 808 nm and 940 nm.
  • 44. The method as claimed in claim 1, wherein the heating step is conducted in the absence of broader wavelength heating radiation.
  • 45. The method as claimed in claim 1, wherein the one or more wavelengths are selected to provide good diffusion through the thickness of the thermoplastic material.
  • 46. The method as claimed in claim 1, wherein the one or more wavelengths are selected to provide uniform diffusion through the thickness of the thermoplastic material.
  • 47. The method as claimed in claim 1, further comprising regulating the power of selected diodes to attain a desired temperature profile of the parisons.
  • 48. The method as claimed in claim 1, further comprising regulating the power of at least one array of diodes to attain a desired temperature profile of the parisons.
  • 49. The method as claimed in claim 1, further comprising regulating the power of separate arrays of diodes to attain a desired non-uniform temperature profile of the parisons.
  • 50. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 700 and 1064 nm.
  • 51. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 700 and 940 nm.
  • 52. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 700 and 808 nm.
  • 53. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 808 and 1600 nm.
  • 54. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 808 and before 1000 nm.
  • 55. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 808 and 1064 nm.
  • 56. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 808 and 940 nm.
  • 57. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 940 and 1600 nm.
  • 58. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 940 and before 1000 nm.
  • 59. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 940 and 1064 nm.
  • 60. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 1000 and 1600 nm.
  • 61. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 1000 and 1064 nm.
  • 62. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 1064 and 1600 nm.
  • 63. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within at least one wavelength of 808 nm, 940 nm, and 1064 nm.
  • 64. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within at least two wavelengths of 808 nm, 940 nm, and 1064 nm.
  • 65. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy at two wavelengths of 808 nm and 940 nm.
  • 66. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy at a wavelength of 808 nm.
  • 67. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy at a wavelength of 940 nm.
  • 68. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy at a wavelength of 1064 nm.
  • 69. The method as claimed in claim 1, wherein the near infrared laser diodes are operative to emit radiant energy at a wavelength of 1064 nm.
  • 70. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 700 and 1600 nm.
  • 71. The method as claimed in claim 1, wherein the near infrared laser diode heating elements are operative to emit radiant energy within a wavelength range between 700 and before 1000 nm.
  • 72. The method as claimed in claim 1, wherein the transporting comprises: transporting the series of parisons through the path by retaining the bodies of the parisons between and within the first and second walls and projecting the necks of the parisons above the first and second walls, during the irradiating of the parisons.
Priority Claims (1)
Number Date Country Kind
04 12372 Nov 2004 FR national
CROSS REFERENCE TO RELATED APPLICATIONS

This is a continuation application of application Ser. No. 11/667,958 filed Jul. 16, 2007, which is a 371 National Stage Application of PCT Application No. PCT/FR2005/002826 filed Nov. 15, 2005, which claims foreign priority to FR 04 12372, filed on Nov. 22, 2004. The entire disclosure of application numbers U.S. Ser. No. 11/667,958, PCT/FR2005/002826, and FR 04 12372 are hereby incorporated by reference.

US Referenced Citations (197)
Number Name Date Kind
2769117 Pirillo Oct 1956 A
3309553 Kroemer Mar 1967 A
3626143 Fry Dec 1971 A
3627989 Heidler Dec 1971 A
3640671 Reilly Feb 1972 A
3768314 Metzler et al. Oct 1973 A
3957618 Spirig May 1976 A
3974016 Bondybey et al. Aug 1976 A
3975618 Goos et al. Aug 1976 A
4020232 Kohmura et al. Apr 1977 A
4050887 Berggren et al. Sep 1977 A
4058699 van Vloten Nov 1977 A
4079104 Dickson et al. Mar 1978 A
4097715 Frizzi Jun 1978 A
4135077 Wills Jan 1979 A
4147487 Dickson et al. Apr 1979 A
4163238 Esaki et al. Jul 1979 A
4204111 Yonko May 1980 A
4224096 Osborne Sep 1980 A
4234297 Kontz Nov 1980 A
4304978 Saunders Dec 1981 A
4313720 Spurr Feb 1982 A
4331858 Wagner May 1982 A
4338114 Brockway et al. Jul 1982 A
4374678 Castro Feb 1983 A
4409455 Belcher et al. Oct 1983 A
4456811 Hella et al. Jun 1984 A
4459458 Vetsch et al. Jul 1984 A
4481405 Malick Nov 1984 A
4486639 Mittelsteadt Dec 1984 A
4507538 Brown et al. Mar 1985 A
4606723 Pasternicki Aug 1986 A
4617439 Lespinats et al. Oct 1986 A
4665298 La Rocca May 1987 A
4672169 Chambers Jun 1987 A
4692583 Kimura et al. Sep 1987 A
4720480 Ito et al. Jan 1988 A
4754141 Mindock Jun 1988 A
4810092 Auth Mar 1989 A
4816694 Kuppenheimer, Jr. et al. Mar 1989 A
4820682 Shimomura et al. Apr 1989 A
4820686 Ito et al. Apr 1989 A
4840933 Usami et al. Jun 1989 A
4856978 Voss et al. Aug 1989 A
4857501 Usami et al. Aug 1989 A
4894509 Chalco et al. Jan 1990 A
4900891 Vega et al. Feb 1990 A
4923847 Ito et al. May 1990 A
4924957 Gigla May 1990 A
4929411 Usami et al. May 1990 A
4948937 Blank et al. Aug 1990 A
4989791 Ridenour Feb 1991 A
4999333 Usami et al. Mar 1991 A
5010231 Huizinga Apr 1991 A
5010659 Treleven Apr 1991 A
5028580 Shimomura et al. Jul 1991 A
5066222 Roos et al. Nov 1991 A
5068512 Van Geel et al. Nov 1991 A
5110209 Elshoud et al. May 1992 A
5130292 Ito et al. Jul 1992 A
5146239 Ono Sep 1992 A
5160556 Hyde et al. Nov 1992 A
5163179 Pellegrini Nov 1992 A
5178990 Satake et al. Jan 1993 A
5206039 Valyi Apr 1993 A
5208434 Minamida et al. May 1993 A
5246910 Koshizuka et al. Sep 1993 A
5256341 Denis et al. Oct 1993 A
5260258 Ito et al. Nov 1993 A
5260715 Kishimi Nov 1993 A
5261415 Dussault Nov 1993 A
5270285 Ito et al. Dec 1993 A
5308233 Denis et al. May 1994 A
5318362 Schietinger et al. Jun 1994 A
5322651 Emmer Jun 1994 A
5349211 Kato Sep 1994 A
5352652 Ito et al. Oct 1994 A
5382441 Lentz et al. Jan 1995 A
5394492 Hwang Feb 1995 A
5408488 Kurihara et al. Apr 1995 A
5439872 Ito et al. Aug 1995 A
5457299 Blais et al. Oct 1995 A
5501759 Forman Mar 1996 A
5509733 Danley Apr 1996 A
5509796 Di Settembrini Apr 1996 A
5565119 Behun et al. Oct 1996 A
5589210 De La Luz Martinez et al. Dec 1996 A
5589715 Nishitani et al. Dec 1996 A
5618489 Weissmann Apr 1997 A
5658667 Yoshida et al. Aug 1997 A
5681521 Emmer et al. Oct 1997 A
5698866 Doiron et al. Dec 1997 A
5714249 Yoshida et al. Feb 1998 A
5740314 Grimm Apr 1998 A
5741583 Yoshida Apr 1998 A
5759200 Azar Jun 1998 A
5773149 Yoshida et al. Jun 1998 A
5780524 Olsen Jul 1998 A
5820820 Pierce Oct 1998 A
5834313 Lin Nov 1998 A
5865546 Ganthier et al. Feb 1999 A
5880710 Jaberi et al. Mar 1999 A
5882797 Yoshida et al. Mar 1999 A
5883362 Pettibone et al. Mar 1999 A
5886313 Krause et al. Mar 1999 A
5888644 Yoshida et al. Mar 1999 A
5925710 Wu et al. Jul 1999 A
5935709 Yoshida Aug 1999 A
5953356 Botez et al. Sep 1999 A
5975935 Yamaguchi et al. Nov 1999 A
5976288 Ekendahl Nov 1999 A
5976450 Mreijen Nov 1999 A
5980229 Collombin Nov 1999 A
5985203 Bowkett Nov 1999 A
RE36561 Saito et al. Feb 2000 E
6022920 Maxwell et al. Feb 2000 A
6038786 Aisenberg et al. Mar 2000 A
6069345 Westerberg May 2000 A
6080146 Altshuler et al. Jun 2000 A
6080353 Tsuchiya Jun 2000 A
6104604 Anderson et al. Aug 2000 A
6113837 Erickson Sep 2000 A
6113840 Emmer et al. Sep 2000 A
6146677 Moreth Nov 2000 A
6174388 Sikka et al. Jan 2001 B1
6174404 Klinger Jan 2001 B1
6193931 Lin et al. Feb 2001 B1
6246935 Buckley Jun 2001 B1
6294769 McCarter Sep 2001 B1
6357504 Patel et al. Mar 2002 B1
6361301 Scaglotti et al. Mar 2002 B1
6372318 Collette et al. Apr 2002 B1
6387089 Kreindel et al. May 2002 B1
6417481 Chen et al. Jul 2002 B2
6437292 Sikka et al. Aug 2002 B1
6441510 Hein et al. Aug 2002 B1
6444946 Korte Sep 2002 B1
6450941 Larson Sep 2002 B1
6451152 Holmes et al. Sep 2002 B1
6461929 Löbl et al. Oct 2002 B1
6476345 Sator Nov 2002 B1
6482672 Hoffman et al. Nov 2002 B1
6503586 Wu et al. Jan 2003 B1
6507042 Mukai et al. Jan 2003 B1
6560893 Bakalar May 2003 B1
6573527 Sugiyama et al. Jun 2003 B1
6617539 Koinuma et al. Sep 2003 B1
6621039 Wang et al. Sep 2003 B2
6632087 Armellin et al. Oct 2003 B1
6638413 Weinberg et al. Oct 2003 B1
6667111 Sikka et al. Dec 2003 B2
6670570 Giacobbe et al. Dec 2003 B2
6710281 Wachnuk Mar 2004 B1
6756697 Mizutani et al. Jun 2004 B2
6815206 Lin et al. Nov 2004 B2
6845635 Watanabe Jan 2005 B2
6857368 Pitz Feb 2005 B2
6892927 Rumer et al. May 2005 B2
6905326 Voth et al. Jun 2005 B2
6949217 Silverbrook Sep 2005 B2
6991704 Broadbent Jan 2006 B2
7009140 Partio et al. Mar 2006 B2
7015422 Timans Mar 2006 B2
7060942 Friedl et al. Jun 2006 B2
7063820 Goswami Jun 2006 B2
7155876 VanderTuin et al. Jan 2007 B2
7220378 Cochran et al. May 2007 B2
7307243 Farkas et al. Dec 2007 B2
7425296 Cochran et al. Sep 2008 B2
20010019045 Chen et al. Sep 2001 A1
20020056707 Pinho et al. May 2002 A1
20020125234 Chen et al. Sep 2002 A1
20030118686 Voth et al. Jun 2003 A1
20040010298 Altshuler et al. Jan 2004 A1
20040056006 Jones et al. Mar 2004 A1
20040161486 Pickel Aug 2004 A1
20040231301 VanderTuin et al. Nov 2004 A1
20050146065 Cochran et al. Jul 2005 A1
20050161866 Batlaw et al. Jul 2005 A1
20050193690 Schoeneck Sep 2005 A1
20060011604 Avrard et al. Jan 2006 A1
20060011898 Melzig et al. Jan 2006 A1
20060019846 Fan et al. Jan 2006 A1
20060048881 Evans et al. Mar 2006 A1
20060056673 Dehmeshki Mar 2006 A1
20060097417 Emmer May 2006 A1
20060118983 Cochran et al. Jun 2006 A1
20060232674 Cochran Oct 2006 A1
20060280825 Cochran et al. Dec 2006 A1
20070009635 Voisin Jan 2007 A1
20070096352 Cochran May 2007 A1
20070188023 Kraus et al. Aug 2007 A1
20070284788 Kurosaki Dec 2007 A1
20090102083 Cochran Apr 2009 A1
20100007061 Feuilloley et al. Jan 2010 A1
20100127435 Feuilloley May 2010 A1
20110002677 Cochran et al. Jan 2011 A1
Foreign Referenced Citations (55)
Number Date Country
2005-311723 Jun 2006 AU
2 449 508 Nov 2002 CA
2 546 517 Jul 2005 CA
3518204 Oct 1986 DE
3339613 May 1993 DE
4234342 Apr 1994 DE
196 03 974 Aug 1997 DE
197 50 263 May 1999 DE
101 06 607 Sep 2002 DE
10131620 Jan 2003 DE
101 49 934 Apr 2003 DE
10149934 Apr 2003 DE
0 564 354 Oct 1993 EP
0 571 262 Nov 1993 EP
0 620 099 Oct 1994 EP
0 680 620 Nov 1995 EP
0938962 Sep 1999 EP
0939358 Sep 1999 EP
1 242 229 Sep 2002 EP
1 412 684 Apr 2004 EP
2 561 986 Oct 1985 FR
2 762 799 Nov 1998 FR
2 848 906 Dec 2002 FR
2 872 734 Jul 2004 FR
2 878 185 May 2006 FR
2095611 Oct 1982 GB
2165493 Apr 1986 GB
2230740 Oct 1990 GB
2324756 Nov 1998 GB
2399542 Sep 2004 GB
57-80030 May 1982 JP
59-184626 Oct 1984 JP
2007-0097033 Oct 2007 KP
2007-006611 Jul 2007 MX
9514251 May 1995 WO
9842050 Sep 1998 WO
0027576 May 2000 WO
0139959 Jun 2001 WO
0198870 Dec 2001 WO
02095382 Nov 2002 WO
03-002922 Jan 2003 WO
2004-009318 Jan 2004 WO
2004030857 Apr 2004 WO
2005065917 Jul 2005 WO
2005-067591 Jul 2005 WO
2005068161 Jul 2005 WO
2005123367 Dec 2005 WO
2006010694 Feb 2006 WO
2006045926 May 2006 WO
2006056573 Jun 2006 WO
2006056673 Jun 2006 WO
2006060690 Jun 2006 WO
2006069261 Jun 2006 WO
2007149221 Dec 2007 WO
2008154503 Dec 2008 WO
Non-Patent Literature Citations (37)
Entry
“Combination Therapies Offer New Management Options for Acne and Rosacea,” American Academy of Dermatology—Public Resources, Press Release, New York, NY, Oct. 17, 2001.
“Diode Array for Wheel Alignment,” CorkOpt Ltd., Date not available.
“Infrared Heat for Glass Processing,” Heraeus Noblelight, Aug. 2001.
“Intense Pulsed Light,” www.yestheyrefake.net/intense—pulsed—light.htm, Aug. 6, 2003.
“Lasers Offer New Medical and Cosmetic Treatment Options for Patients with Skin of Color,” American Academy of Dermatology—Public Resources, Press Release, Chicago, IL, Jul. 27, 2003.
“Low Energy Photon (LEPT)—Light Emitting Diode (LED)—Light Therapy,” Allied Light Therapy, www.alliedlighttherapy.com/page1.html., Mar. 3, 2004.
“MID-IR LEDS—1.6 μm . . . 5.0 μm” www.roithner-laser.com/LED—MID—IR.htm., Aug. 4, 2004.
“Rosacea: Pulse-Light Treatments Get the Red Out,” UT-Houston—Health Leader, www.uthouston.edu/hLeader/archive/skinhealth/010927/index.html, Mar. 3, 2004.
“Skin Contact Monochromatic Infrared Energy: Technique to Treat Cutaneous Ulcers, Diabetic Neuropathy and Miscellaneous Musculoskeletal Conditions,” Blue Cross of California, Medical Policy 2.01.22, Jun. 25, 2003.
Alaiti, S., et al. “Tacrolimus (FK506) ointment for atopic dermatitis: A phase I study in adults and children,” Journal of the American Academy of Dermatology, 38 (1), pp. 69-76, Jan. 1998.
Feldman, S.R., et al. “Destructive Procedures are the Standard of Care for Treatment of Actinic Keratoses,” Journal of the American Academy of Dermatology, 40 (1), pp. 43-47, Jan. 1999.
Fleischer, A.B., et al., “Procedures for Skin Diseases Performed by Physicians in 1993 and 1994: Analysis of data from the National Ambulatory Medical Care Survey,” Journal of the American Academy of Dermatology, Part 1, 37 (5), pp. 719-724, Nov. 1997.
Friedlander, S.F., et al., “Severe and Extensive Atopic Dermatitis in Children as Young as 3 Months,” Journal of the American Academy of Dermatology. 46 (3), pp. 387-393, Mar. 2002.
Goings, J. & E. Stephens, “Microchannel cooling ups power capacity for laser-diode bars,” Laser Focus World, May 1, 2006.
Gold, M.H. “A Single Center, Open Label Investigator Study of Photodynamic Therapy in the Treatment of Sebaceous Gland Hyperplasia with Topical 20% 5-Aminolevulinic Acid with Visible Blue Light or Intense Pulsed Light,” Journal of the American Academy of Dermatology, Abstract P638, Part 2, 50 (3), p. P164, Mar. 2004.
Goyal, A.K., et al., “Wavelength Beam Combining of Mid-IR Semiconductor Lasers,” Lasers and Electro-Optics Society, The 14th Annual Meeting of the IEEE, WQ3 2:15pm-2:30pm, pp. 532-533, 2001.
Hanifin, J.M., et al. “Thcrolimus Ointment for the Treatment of Atopic Dermatitis in Adult Patients: Part I, Efficacy.” Journal of the American Academy of Dermatology. Jan. 2001, part 2, vol. 44, No. 1, pp. S28-S38.
Hecker, D., et al., “Interactions between tazarotene and ultraviolet light,” Journal of the American Academy of Dermatology, 41 (6), pp. 927-930, Dec. 1999.
Ivey, A., et al., “Medical Issue: Laser Treatement of Rosacea,” Google Answers, May 6, 2003.
Janis, M.D., “On Courts Herding Cats: Contending with the “Written Description” Requirement (and Other Unruly Patent Disclosure Doctrines),” Re-Engineering Patent Law, vol. 2:55, pp. 55-108, 2000.
Jeffes, E.W., et al., “Photodynamic therapy of actinic keratoses with topical aminolevulinic acid hydrochloride and fluorescent blue light,” Journal of the American Academy of Dermatology, Abstract, Part 1, 45 (1), Jul. 2001.
Lebwohl, M., et al., “Interactions between calcipotriene and ultraviolet light.” Journal of the American Academy of Dermatology, 37 (1), pp. 93-95, Jul. 1997.
Mallozzi, J., “Thin-Disk Lasers Position Themselves in Industry,” R&D Magazine, pp. 21-23, Apr. 2005.
Morton, C.A., et al., “The Efficacy of Violet Light in the Treatment of Acne,” Journal of the American Academy of Dermatology, Abstract P638, Part 2, 50 (3), p. P15, Mar. 2004.
Nestor, M.S., “Combination Phototherapy and Adapalene in the Treatment of Acne Vulgaris,” Journal of the American Academy of Dermatology, Abstract P664, Part 2, 50 (3), p. P170, Mar. 2004.
Paller, A., et al., “A 12-Week Study of Tacrolimus Ointment for the Treatment of Atopic Dermatitis in Pediatric Patients,” Journal of the American Academy of Dermatology, 44 (1), pp. S47-S57, Jan. 2001.
Rattunde, M., et al., “Power efficiency of GaSb based 2.0μm diode Lasers,” Lasers and Electro-Otics Society, The 14th Annual Meeting of the IEEE, WQ2 2:00pm-2:15pm, pp. 530-531, 2001.
Soter, N. A., et al., “Tacrolimus ointment for the treatment of atopic dermatitis in adult patients: Part II, Safety,” Journal of the American Academy of Dermatology, 44 (1), pp. S39-S46, Jan. 2001.
Tanzi, E.L., et al., “Lasers in dermatology: Four decades of progress,” Journal of the American Academy of Dermatology, Abstract, Part 1, 49 (1), Jul. 2003.
Thomson Hybrides, “Saut Technologique Pour Une Nouvelle Structure de Diodes Laser de Puissance,” Du Cote de la Rue Descartes, pp. 12-13. (Date not available).
Wagner, J. “Diode Lasers for High-Power Applications at 2 pm,” Fraunhofer IAF, Achievement and Results, pp. 24-25, 2001.
Wiese, A., “Potential Savings for Preform Heating by Using NIR Technology,” PETnology Europe 2007 Conference Presentation, Mar. 26, 2007.
Wolfe, W.L. & G.J. Zissis, Eds., “The Infrared Handbook: revised edition” Environmental Research Institute of Michigan, pp. 5-56-5-57, 1989.
Woodcock, J., Letter to M. Macdonald, D.A. Jaskot and J.F. Hurst re ANDA from Department of Health & Human Services, Center for Drug Evaluation and Research, Jun. 11, 2002.
Zanolli, M., “Phototherapy treatment of psoriasis today,” Journal of the American Academy of Dermatology, Abstract, Part 2, 49 (2), Aug. 2003.
Nagasaka, K., et al., “Micro-bonding laser chips using arrayed beams,” SPIE Newsroom, Micro/Nano Lithography & Fabrication, Jul. 24, 2008.
PerkinElmer, “Superior Chip-on-Board Technology for the most demanding LED applications,” www.optoelectronics.perkinelmer.com, 2006.
Related Publications (1)
Number Date Country
20100072673 A1 Mar 2010 US
Continuations (1)
Number Date Country
Parent 11667958 US
Child 12561198 US