Magnetic memories, particularly magnetic random access memories (MRAMs), have drawn increasing interest due to their potential for high read/write speed, excellent endurance, non-volatility and low power consumption during operation. An MRAM can store information utilizing magnetic materials as an information recording medium. One type of MRAM is a spin transfer torque random access memory (STT-RAM). STT-RAM utilizes magnetic junctions written at least in part by a current driven through the magnetic junction. A spin polarized current driven through the magnetic junction exerts a spin torque on the magnetic moments in the magnetic junction. As a result, layer(s) having magnetic moments that are responsive to the spin torque may be switched to a desired state. Further, multiple memory cells may be included in a single memory stack.
For example,
The conventional memory stack 10 is typically formed by depositing all of the layers 14, 16, 18, 20, 21, 24, 26, 28, and 30. A portion of the layers 14, 16, 18, 20, 21, 24, 26, 28, and 30 is covered by a mask and the MTJ 12 or 22 is defined. The mask is removed and another mask corresponding to the other MTJ 22 or 12 and the other MTJ 22 or 12 defined. For example, a mask covering a smaller area may be provided and the MTJ/memory cell 22 defined. A larger mask may then be provided and the MTJ/memory cell 12 defined.
Although the conventional memory stack 10 and MTJs 12 and 22 function, other methods for forming a multiple bit memory cell 22 are desired.
A method and system for providing a magnetic device including a plurality of memory cells is described. Each of the memory cells is capable of storing a plurality of bits corresponding to a plurality of data storage layers. At least one desired spacing and at least one desired junction angle are determined for the data storage layers in each of the memory cells. The desired junction angle(s) and the desired spacing(s) correspond to the data storage layers having a plurality of spin transfer switching currents. A magnetoresistive stack including layers for each of the memory cells is deposited. The memory cells include the plurality of data storage layers. A data storage layer of plurality of data storage layers is spaced apart from a nearest data storage layer of plurality of data storage layers by a distance corresponding to the desired spacing(s). A mask corresponding to the memory cells is provided on the layers. The memory cells are defined such that each of the memory cells has the desired junction angle(s) and the desired spacing(s) and such that the data storage layers for each memory cell is self-aligned.
The exemplary embodiments relate to magnetic junctions usable in magnetic devices, such as magnetic memories, the devices using such magnetic junctions, and methods for fabricating such magnetic devices. The following description is presented to enable one of ordinary skill in the art to make and use the invention and is provided in the context of a patent application and its requirements. Various modifications to the exemplary embodiments and the generic principles and features described herein will be readily apparent. The exemplary embodiments are mainly described in terms of particular methods and systems provided in particular implementations. However, the methods and systems will operate effectively in other implementations. Phrases such as “exemplary embodiment”, “one embodiment” and “another embodiment” may refer to the same or different embodiments as well as to multiple embodiments. The embodiments will be described with respect to systems and/or devices having certain components. However, the systems and/or devices may include more or less components than those shown, and variations in the arrangement and type of the components may be made without departing from the scope of the invention. The exemplary embodiments will also be described in the context of particular methods having certain steps. However, the method and system operate effectively for other methods having different and/or additional steps and steps in different orders that are not inconsistent with the exemplary embodiments. Thus, the present invention is not intended to be limited to the embodiments shown, but is to be accorded the widest scope consistent with the principles and features described herein.
Methods and systems for providing a magnetic junction as well as a magnetic memory utilizing the magnetic junction are described. The exemplary embodiments provide methods and systems for providing a magnetic junction usable in a magnetic device. A method and system for providing a magnetic device including a plurality of memory cells is described. Each memory cell is capable of storing multiple bits corresponding to multiple data storage layers. Desired spacing(s) and desired junction angle(s) are determined for the data storage layers in each of the memory cells. The desired junction angle(s) and the desired spacing(s) correspond to the data storage layers having a plurality of spin transfer switching currents. A magnetoresistive stack including layers for each of the memory cells is deposited. The memory cells include the plurality of data storage layers. A data storage layer of plurality of data storage layers is spaced apart from a nearest data storage layer of plurality of data storage layers by a distance corresponding to the desired spacing(s). A mask corresponding to the memory cells is provided on the layers. The memory cells are defined such that each of the memory cells has the desired junction angle(s) and the desired spacing(s) and such that the data storage layers for each memory cell is self-aligned. In at least some embodiments, each memory cell includes at least one magnetic junction. The magnetic junction includes a pinned layer, a plurality of nonmagnetic spacer layers, and a plurality of free layers. The plurality of free layers is interleaved with the plurality of nonmagnetic spacer layers. A first nonmagnetic spacer layer of the plurality of nonmagnetic spacer layers is between the plurality of free layers and the pinned layer. Each of the plurality of free layers is configured to be switchable between a plurality of stable magnetic states when a write current is passed through the magnetic memory cell. Each of the plurality of free layers has a critical switching current density. The critical switching current density of one of the plurality of free layers changes monotonically from the critical switching current density of an adjacent free layer of the plurality of free layers. The adjacent free layer is between the pinned layer and the one of the plurality of free layers.
The exemplary embodiments are described in the context of particular magnetic junctions and magnetic memories having certain components. One of ordinary skill in the art will readily recognize that the present invention is consistent with the use of magnetic junctions and magnetic memories having other and/or additional components and/or other features not inconsistent with the present invention. The method and system are also described in the context of current understanding of the spin transfer phenomenon, of magnetic anisotropy, and other physical phenomenon. Consequently, one of ordinary skill in the art will readily recognize that theoretical explanations of the behavior of the method and system are made based upon this current understanding of spin transfer, magnetic anisotropy and other physical phenomenon. However, the method and system described herein are not dependent upon a particular physical explanation. One of ordinary skill in the art will also readily recognize that the method and system are described in the context of a structure having a particular relationship to the substrate. However, one of ordinary skill in the art will readily recognize that the method and system are consistent with other structures. In addition, the method and system are described in the context of certain layers being synthetic and/or simple. However, one of ordinary skill in the art will readily recognize that the layers could have another structure. Furthermore, the method and system are described in the context of magnetic junctions and/or substructures having particular layers. However, one of ordinary skill in the art will readily recognize that magnetic junctions and/or substructures having additional and/or different layers not inconsistent with the method and system could also be used. Moreover, certain components are described as being magnetic, ferromagnetic, and ferrimagnetic. As used herein, the term magnetic could include ferromagnetic, ferrimagnetic or like structures. Thus, as used herein, the term “magnetic” or “ferromagnetic” includes, but is not limited to ferromagnets and ferrimagnets. The method and system are also described in the context of single magnetic junctions and substructures. However, one of ordinary skill in the art will readily recognize that the method and system are consistent with the use of magnetic memories having multiple magnetic junctions and using multiple substructures. Further, as used herein, “in-plane” is substantially within or parallel to the plane of one or more of the layers of a magnetic junction. Conversely, “perpendicular” corresponds to a direction that is substantially perpendicular to one or more of the layers of the magnetic junction.
The desired spacing(s) and junction angle(s) for the memory cell are determined, via step 102. The desired spacing(s) and junction angle(s) correspond to data storage layers (such as free layers) having different geometries. In some embodiments, the junction angle(s) are desired to be at least sixty and not more than ninety degrees. In some such embodiments, the junction angle(s) are desired to be not more than eighty-five degrees. The combination of the separation between data storage layers and the junction angles result in data storage layers having different sizes. These differences in geometry (as well as other differences such as magnetic moment or other anisotropies) may result in the data storage layers having different switching currents for spin transfer-based switching. For example, in some embodiments, the size (e.g. width and/or length) of the data storage layer may differ by at least ten percent. This may correspond to a switching current difference of ten percent or more. In other embodiments, the difference in size of adjacent data storage layers is desired to be up to thirty percent. In other embodiments, the sizes of adjacent data storage layers are desired to be thirty through fifty percent different (or more). In some embodiments, the data storage layers have the same footprint or shape as viewed in the plan view. However, as discussed above the sizes of the data storage layers differ, resulting in different switching currents. In such embodiments, therefore, it is only a difference in size that results in the different switching currents. In other embodiments, the footprints of the data storage layers in the memory cell may differ. Stated differently, the data storage layers have different shapes as seen in the plan view. In such embodiments, therefore, the difference in switching current may be attributable to both size and shape,
A magnetoresistive stack including layers for the memory cells is deposited, via step 104. In some embodiments, step 104 includes depositing layers for multiple magnetoresistive junctions. Each magnetoresistive junction includes at least a pinned layer, a nonmagnetic spacer layer such as Cu or MgO, and a free layer that serves as the data storage layer. A pinning layer such as an AFM layer that adjoins the pinned layer may also be provided. The pinned layer is magnetic, may be a single layer or may be a synthetic antiferromagnet, and/or may be another multilayer. The free layer/data storage layer may be a single layer or a multilayer. The layers for one magnetoresistive junction are separated by the layers for another magnetoresistive junction by a nonmagnetic, conductive spacer layer. In some embodiments, the spacer layers are nonmagnetic and conductive. In such embodiments, the spacer layers may not significantly contribute to the resistance of memory cell. In other embodiments, a single pinned layer and multiple free layers/data storage layers interleaved with the spacer layers may be deposited in step 104. The thickness(es) of the spacer layer(s) between the magnetic junctions/data storage layers correspond to the desired spacing.
A mask is provided on the magnetoresistive stack, via step 106. The mask may be a hard mask suitable for ion milling, reactive ion etching and/or another removal process. A single mask having portions covering parts of the magnetoresistive stack may be used. Portions of the mask cover regions corresponding to the tops of the memory cells. In some embodiments, step 106 includes depositing hard mask layer(s) on the magnetoresistive stack and photolithographically patterning the hard mask layer(s) to form a hard mask. However, other methods for forming the mask may be used.
The memory cells are defined from the magnetoresistive stack, via step 108. In some embodiments, step 108 includes ion milling or reactive ion etching the magnetoresistive stack such that each of memory cells has the desired junction angle(s) and the desired spacing(s). Therefore, a portion of the magnetoresistive stack is removed to provide the desired geometry of the data storage and other layers. Stated differently, the pressure, gasses, gas flow, power, substrate bias, and other parameters of the etch are configured such that step 108 removes the desired portion of the magnetoresistive stack. The memory cell(s) left have the desired junction angle(s) and desired spacing. Further, as the same mask has been used for all of the data storage layers in each memory cell, the memory cells are self-aligned.
The magnetic junctions 210 and 230 are separated by a spacer layer 220 having a thickness, d. In some embodiments, the spacer layer 220 is at least ten and not more than twenty nanometer thick. Although two magnetic junctions 210 and 230 are shown, another number may be fabricated. In such embodiments, the magnetic junctions are still interleaved with spacer layer(s) analogous to the spacer layer 220. Also shown is the junction angle, 8, for the memory cell 200.
Referring to
Also using the method 100, the layers 212, 214, 216, 220, 232, 234, and 236 may be blanket deposited in step 104. The spacer layer 220 has the thickness, d, determined to provide the desired spacing between the free layers 216 and 236 determined in step 102. A hard mask (not shown in
The memory cell 200 thus includes two data storage layers/free layers 216 and 236 corresponding to two magnetic junctions 210 and 230, respectively, in the same memory cell/stack 200. Because the method 100 has been used to fabricate the memory cell 200, the switching currents of the free layers 216 and 236 differ. For example, the switching currents may differ by at least ten percent. In other embodiments, the switching currents differ by at least twenty percent. In still other embodiments, the switching current may differ by at least thirty and not more than fifty percent. Note that in addition to the geometry, other properties of the free layers 216 and 236 and/or the magnetic junctions 210 and 230 may be tailored to achieve the desired difference in switching currents. Thus, the free layers 216 and 236 may be independently switched. The memory cell 200 may thus store multiple bits. Further, because the method 100 has been used, the free layers 216 and 236 and the magnetic junctions 210 and 230 are self-aligned. Although they differ in size, the free layers 216 and 236 may be defined using the same mask. As a result, misalignments between the free layers 216 and 236 and the magnetic junctions 210 and 230 may be reduced or eliminated. As a result, performance and reliability of the memory cell 200 may be improved.
Also shown in the memory cell 200′ are seed layer 202, capping layer 204 and AFM layers 211 and 231 of magnetic junctions 210′ and 230′, respectively. Thus, the layers 202, 204, 211, and 231 are deposited as part of the stack deposition in step 104 of the method 100. Thus, the thickness of the layer 231 may be accounted for in determining the desired thickness, d′, of the spacer layer 220′ and the desired spacing between the free layers 216′ and 236′.
Using the method 100, the magnetic memory cell 200′ may be formed. Thus, a single mask having a footprint corresponding to the footprint of the free layer 236′ may be used in defining the memory cell 200′. The memory cell 200′ may thus share the benefits of the memory cell 200. For example, the memory cell 200′ may store multiple bits, may be self-aligned, and may have improved performance and/or reliability.
The upper data storage layer(s) are defined, via step 112. Thus, a portion of the top layers of the magnetoresistive stack deposited in step 104 are removed. The removal process of step 112 is configured to achieve a first junction angle. The removal process is, however, terminated after the top data storage layer is defined, but before the spacer layer has been completely defined. An additional spacer layer is then deposited, via step 114. In some embodiments, this spacer layer is conformal. Thus, the spacer layer resides on the top surface of at last part of the spacer layer and on the sides of at least the top data storage layer. In some embodiments, the spacer layer is thin. For example, the additional spacer layer may be at least ten nanometers and not more than twenty nanometers thick. The additional spacer layer is also insulating. For example, silicon oxide, silicon nitride, aluminum oxide, and/or other insulators might be used. In other embodiments, metal(s) might be used for at least part of the additional spacer layer.
The additional spacer layer is anisotropically removed, via step 116. In some embodiments, the anisotropic removal process is a reactive ion etch approach. However, other removal processes might be used. The anisotropic removal process removes the spacer layer vertically (perpendicular to the plane of the layers). Thus, at least part of the additional spacer layer on the sidewalls of the top portion of the memory cell remains. The bottom portion of the magnetoresistive stack is, however, exposed.
The lower data storage layer(s) are defined, via step 118. The removal process in step 118 is analogous to that in step 112. However, the removal process may be configured such that a different junction angle is formed for the next lower data storage layer. The next lower data storage layer in the memory cell is thus defined. Further, because of the presence of the additional spacer layer, the upper portion of the magnetic memory cell is not removed. Steps 114-118 may then be optionally repeated. Each time steps 114-118 are repeated, a new junction angle may be achieved as the parameters of the removal process are changed.
In addition, the memory cell 200″ has junction angles θ1 and θ2. The junction angle θ1 corresponds to the removal process of step 112, while the junction angle θ2 corresponds to the removal process of step 118. The removal process of step 112 is stepped within the spacer layer 220″.
Using the methods 100 and 108′, the magnetic memory cell 200″ may be formed. Thus, a single mask having a footprint corresponding to the footprint of the free layer 236″ may be used in defining the memory cell 200″. Further, due to the use of the additional spacer layer, the upper magnetic junction 220″ may not be removed during the step of defining the lower magnetic junction 210″. The memory cell 200″ may thus share the benefits of the memory cells 200 and 200′. For example, the memory cell 200″ may store multiple bits, may have different switching currents for the layers 216″ and 236″ due to the spacer layer 220″ and junction angles θ1 and θ2, may be self-aligned, and may have improved performance and/or reliability.
Also shown in the memory cell 200″′ are seed layer 202′, capping layer 204′ and AFM layers 211′ and 231′ analogous to the seed layer 202, capping layer 204, and AFM layers 211 and 231 of the magnetic memory cell 200′. Thus, the layers 202′, 204′, 211′, and 231′ are deposited as part of the stack deposition in step 104 of the method 100. Thus, the thickness of the layer 231′ may be accounted for in determining the desired thickness, d″′, of the spacer layer 220″′ and the desired spacing between the free layers 216″ and 236″.
Using the methods 100 and 108′, the magnetic memory cell 200″′ may be formed. The memory cell 200″′ may thus share the benefits of the memory cells 200, 200′, and 200″. For example, the memory cell 200″′ may store multiple bits, may have different switching currents for the layers 216″′ and 236″′ due to the spacer layer 220″′ and junction angles θ1′ and θ2′, may be self-aligned, and may have improved performance and/or reliability.
Using the method 100, the magnetic memory cell 300 may be formed. The memory cell 300 may thus share the benefits of the memory cells 200, 200′, and 200″. For example, the memory cell 300 may store multiple bits due to the presence of the free layers 310, 320, 330, 340, and 350. Thus, the memory cell 300 may store five bits. In other embodiments, another number of free layers might be used. Because a single mask is used in defining the free layers 210, 320, 330, 340, and 350, the layers 310, 320, 330, 340, and 350 are self-aligned. The free layers 310, 320, 330, 340, and 350 may have different switching currents due at least in part to the spacer layers 312, 322, 332, and 342 and junction angle 8, may be self-aligned, and may thus have improved performance and/or reliability.
Using the method 100 and 108′, the magnetic memory cell 300′ may be formed. The memory cell 300′ may thus share the benefits of the memory cells 200, 200′, 200″, 200″′ and 300. For example, the memory cell 300′ may store multiple bits, may have different switching currents for the layers 320, 330, 340, and 350 due to the spacer layers 312′, 322′, 332′, and 342′ and junction angles θ1′, θ2′, and θ3′ may be self-aligned, and may have improved performance and/or reliability.
The magnetic memory cells 200, 200′, 200″, 200″′, 300′, and 300′ formed using the methods 100 and/or 108′ may be used in a magnetic memory.
Various magnetic storage cells 200, 200′, 200″, 200″′, 300, and 300′ formed using the methods 100/108′ have been disclosed. Note that various features of the magnetic storage cells 200, 200′, 200″, 200″′, 300, and 300′ may be combined. Thus, one or more of the benefits of the magnetic storage cells 200, 200′, 200″, 200″′, 300, and 300′ such as higher density and self-aligned properties may be achieved.
A method and system for providing a magnetic junction and a memory fabricated using the magnetic junction has been described. The method and system have been described in accordance with the exemplary embodiments shown, and one of ordinary skill in the art will readily recognize that there could be variations to the embodiments, and any variations would be within the spirit and scope of the method and system. Accordingly, many modifications may be made by one of ordinary skill in the art without departing from the spirit and scope of the appended claims.
This application claims the benefit of provisional patent application Ser. No. 61/533,584, filed Sep. 12, 2011, assigned to the assignee of the present application, and incorporated herein by reference.
This invention was made with U.S. Government support under Grant/Contract No. HR0011-09-C-0023 awarded by DARPA. The U.S. Government retains certain rights in this invention.
Number | Date | Country | |
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61533584 | Sep 2011 | US |