Patent Application
20150345355
The present application relates to a method and a system for purifying the exhaust gases of a combustion engine by injecting exclusively ammonia gas, and more particularly ammonia gas that is released from one or several solid absorbing matrices where it is stored by sorption.
Legislation on vehicle and truck emissions stipulates, amongst other things, a reduction in the release of nitrogen oxides NOx into the atmosphere. One known way to achieve this objective is to use the SCR (Selective Catalytic Reduction) process which enables the reduction of nitrogen oxides by injection of a reducing agent, generally ammonia, into the exhaust line. This ammonia may be obtained by using different techniques. One known technique is based on the use of a solid absorbing matrix where the ammonia is trapped by sorption. Generally, the solid absorbing matrix is stored in a container (or tank) (called hereafter matrix storage container) mounted on the vehicle. According to this known technique, the ammonia is released by heating the solid absorbing matrix, and then the released ammonia is injected into the exhaust line.
This known technique offers high performance since it allows to send pure NH3 in the exhaust gases of the vehicle.
However, the main disadvantage of this known technique is the complexity of the refilling procedure (i.e. the solid absorbing matrix regeneration). Indeed, the actual refilling procedure consists of connecting the matrix storage container to an external ammonia source, typically a highly pressurized cylinder. In this procedure, the matrix storage container has to be dismounted from the vehicle for ammonia loading. Moreover, sending a high pressure of ammonia in the solid matrix results in a huge heat generation due to exothermal sorption reaction (tens of thousands J/mol NH3, as a likely order of magnitude), hence the need of a cooling unit as heat sink. High temperature can damage parts of the system and induce long regeneration time.
In view of the above-mentioned disadvantage, there exists a need for an improved method for the regeneration of the solid absorbing matrix.
An object of the present invention is to solve this above-mentioned problem by proposing an SCR method for purifying the exhaust gases of an internal combustion engine of a vehicle, according to which ammonia gas is exclusively metered in the exhaust gases, the method comprising a step of releasing ammonia gas from at least one solid absorbing matrix where it is stored by sorption and a step of metering the released ammonia gas in the exhaust gases. According to one aspect of the present invention, the method comprises a step of regenerating the solid absorbing matrix that consists in:
Thus, it is proposed an in situ regeneration procedure. In other words, the regeneration of the solid absorbing matrix takes place on board the vehicle. More precisely, the regeneration procedure according to the invention is based on the decomposition of an ammonia precursor. Such decomposition is obtained by using a biochemical decomposition unit mounted on board the vehicle. The biochemical decomposition unit according to the invention stores one or several protein component(s) that catalyze a chemical reaction. More precisely, the protein component(s) is(are) adapted to catalyze the hydrolysis (i.e. decomposition) of the ammonia precursor to ammonia. This decomposition results in the generation of a refilling ammonia gas. The refilling ammonia gas is then directed (i.e. transmitted) to the solid absorbing matrix where it is stored thereon. According to the invention, no external ammonia source is used and no disassembly manual operations are needed for the regeneration of the solid absorbing matrix(ces). Thus, the regeneration procedure according to the invention is simple, faster and safer.
In a preferred embodiment, a predetermined amount of ammonia precursor is stored on board the vehicle. For example, during vehicle (engine) operation, it is calculated a desired amount of ammonia precursor to be injected into the biochemical decomposition unit. Such calculation can be made as a function of information relative to the amount of ammonia gas that has been injected into the exhaust line. In a particular embodiment, such information may derive from data provided by a temperature sensor, a pressure sensor or a flow meter, or any combination of these sensors. In another particular embodiment, such information may derive from data provided by a device configured to measure the concentration of ammonia stored in the solid absorbing matrix. In another particular embodiment, this information may be derived from an estimation of the consumption of ammonia.
Advantageously, the protein component (stored in the biochemical decomposition unit) comprises at least one enzyme. In particular, thermophile-type enzymes are well suited. In a preferred embodiment, the biochemical decomposition unit can store urease. Urease can be stored in any suitable manner. For example, in a first embodiment urease can be immobilized in different layers of resin. In a second embodiment urease can be fixed on membranes.
The SCR method according to the present invention is aiming at injecting exclusively ammonia gas in the exhaust gases. In other words, no ammonia precursor is injected in the exhaust gases.
In a particular embodiment, the ammonia precursor is an aqueous urea solution.
The terms “urea solution” are understood to mean any, generally aqueous, solution containing urea. The invention gives good results with eutectic water/urea solutions for which there is a quality standard: for example, according to the standard ISO 22241, in the case of the AdBlue® solution (commercial solution of urea), the urea content is between 31.8% and 33.2% (by weight) (i.e. 32.5+/−0.7 wt %) hence an available amount of ammonia between 18.0% and 18.8%. The invention may also be applied to the urea/ammonium formate mixtures, also in aqueous solution, sold under the trade name Denoxium™ and of which one of the compositions (Denoxium-30) contains an equivalent amount of ammonia to that of the AdBlue® solution. The latter have the advantage of only freezing from −30° C. onwards (as opposed to −11° C.), but have the disadvantages of corrosion problems linked to the possible release of formic acid. The invention can also apply to guanidinium formate. The present invention is particularly advantageous in the context of eutectic water/urea solutions, which are widely available in gas stations.
According to the invention, no urea solution is injected in the exhaust gases. There is no line (or conduit) for transporting the urea solution up to the exhaust line and there is no metering device for injecting the urea solution in the exhaust gases. According to the invention, the urea solution is exclusively transported to the biochemical decomposition unit, where it enters into a chemical reaction with the enzyme so as to generate the refilling ammonia gas.
In a particular embodiment, the urea solution can be partially stored in a chamber located within the biochemical decomposition unit, before it is chemically decomposed.
In another particular embodiment, the solid absorbing matrix is stored in a first tank and the ammonia precursor is stored in a second tank. Advantageously, the second tank (storing the ammonia precursor) is connected in a communicating manner to said biochemical decomposition unit, and said biochemical decomposition unit is connected in a communicating manner to the first tank (storing the solid absorbing matrix). In a first embodiment, the first tank and the second tank can be separate storage tanks. In a second embodiment, the first tank and the second tank can be two separate chambers of a same container.
It should be noted that it exists well known refilling standards and systems for ammonia precursor, in particular for the AdBlue® solution (commercial solution of urea). The refilling of the storage tank of the ammonia precursor is trivial. For example, this can be achieved by using available standard-designed nozzle and/or bottles with dedicated interfaces.
In a particular embodiment, the biochemical decomposition unit can be located below the storage tank of the ammonia precursor. In this particular embodiment, a stream (i.e. part) of the ammonia precursor can be transported towards the biochemical decomposition unit by gravity.
According to the invention, if the ammonia precursor generates water by thermal decomposition, this water is separated from the ammonia, collected and preferably prevented from being stored on the solid absorbing matrix. Separation of the water from the ammonia, and generally from the eventual other thermal decomposition products (generally gases like CO2), can be made using a liquid-vapour separator unit. For example, the liquid-vapour separator unit can comprise (or be) a condenser or one or several membranes like disclosed in U.S. Pat. No. 4,758,250 for instance, which is a polymeric membrane. The condenser may be a specific one comprising a specific shaped tube having different parts at different temperatures (as described in example 2 below); a phase change material, or any other means for cooling and condensing the gases. Alternatively, the condenser may be part of a device already onboard the vehicle, for instance: part of the vehicle air conditioning system.
The water collected may be vaporised in the exhaust gases and/or at least part of it can be stored for instance to be available for dissolving excess ammonia that would pressurize unduly the storage tank of the solid absorbing matrix (see embodiment with pressure relief valve described below).
The ammonia is metered using a gas line which may comprise a non return valve close to the metering point.
The method according to the invention uses two separate storage tanks: one for the ammonia precursor and one for the solid absorbing matrix which stores ammonia by sorption. As described in patent application WO 2006/012903, metal ammine salts (preferably alkaline earth metal chlorides) can be used as solid storage media for ammonia.
Advantageously, the biochemical decomposition unit is equipped with a heater. Such heater can provide the optimum temperature for the desired activity of the enzyme or protein. For example, the heater can be configured to maintain within the biochemical decomposition unit a temperature range between 30° C. and 60° C.
More generally, the heater is a chamber whose temperature is controlled within predetermined ranges; in case the predetermined range falls below the temperature of the environment, cooling means will also be made available within the heater. In other words, the heater can either be controlled so as to rise up the temperature within the chamber or controlled so as to cool down the temperature within the chamber.
In a particular embodiment, the heater is configured to work within at least one predetermined temperature range corresponding to the activation of the protein component when conversion is needed, and within at least another predetermined temperature range corresponding to the preservation of the protein component, so as to extend its lifetime.
In a particular embodiment of the invention, the heater can comprise resistive heating elements. These resistive heating elements may be metallic heating filaments (wires), flexible heaters, (that is to say heaters comprising one or more resistive track(s) affixed to a film or placed between two films (that is to say two substantially flat supports, the material and thickness of which are such that they are flexible)) or any other type of resistive elements that have a shape, size and flexibility suitable for being inserted into and/or wound around the components of the SCR system. PTC (Positive Temperature Coefficient) elements are more particularly suitable for heating.
In another particular embodiment of the invention, the heater uses the dissipated heat of the engine (for instance, a flow of the liquid engine cooling system) and/or exhaust line (gases) for heating the biochemical decomposition unit.
According to the invention, after generating the refilling ammonia gas, it can be compressed by means of a gas pressurisation unit. The function of this gas pressurisation unit is to compress the refilling ammonia gas to a suitable pressure for absorption by the solid absorbing matrix.
When heating the solid absorbing matrix to release ammonia, it can be that too high ammonia pressure build up occurs inside the system, due to thermal inertia or to a potential failure of the heating power regulation. In order to release the pressure above a given set-point, the excess of gaseous ammonia is preferably released by a safety valve and either directly returned to the ammonia precursor tank (preferred embodiment in the case of a solid ammonia precursor), or first dissolved in an adequate amount of water, for instance coming from the evaporation of the precursor solution the case being, and stored on purpose, and at a composition involving an amount of available ammonia identical to the one of the precursor solution (preferred embodiment in the case of urea precursor solutions). In another preferred embodiment, the excess of ammonia released can merely be dissolved in water and the ammonia solution so obtained can be used later on for thermal ammonia generation and storage on the solid absorbing matrix.
The present invention also concerns a system for applying the SCR method as described above, said system comprising:
Preferably, the storage tank for the solid absorbing matrix comprises or is connected to a pressure release valve as described above.
The means for directing the stream of ammonia precursor solution to the biochemical decomposition unit generally comprise a pipe, a valve and eventually a pump, although if the biochemical decomposition unit is located below the storage tank of the ammonia precursor solution, the stream can merely be generated by gravity.
The means for separating the water from the ammonia may be a condenser and/or a membrane as set forth above.
The means for directing the refilling ammonia gas to the storage tank of the solid storage absorbing matrix may be a simple tube (pipe) and said refilling ammonia gas may be mixed with other gaseous decomposition product(s) like CO2 for instance.
In one embodiment, the system of the invention also comprises a pressure relief valve enabling to release pressure above a given set point in the storage tank of the solid absorbing matrix. Preferably, it also comprises means for dissolving the gases so released into a given amount of water and means for returning the so obtained solution to the storage tank of an ammonia precursor solution.
The present invention is illustrated in a non limitative way by the examples below relying on
As illustrated in
The SCR system of the invention is designed to exclusively inject ammonia gas (NH3) in the exhaust gases. Thus, the SCR system of the invention is simple and efficient, since only pure NH3 is sent in the exhaust gases (no liquid solution or solid compound is injected in the exhaust gases).
According to one aspect of the invention, the biochemical decomposition unit [3] receives a stream (i.e. part) of the ammonia precursor. The biochemical decomposition unit [3] contains an enzyme (for example, urease) that catalyzes the hydrolysis (i.e. decomposition) of the ammonia precursor to ammonia. Thus, the biochemical decomposition unit [3] generates the refilling ammonia gas for the regeneration of the solid absorbing matrix.
According to another particular embodiment of the present invention, the tank [2] can comprise a plurality of cells connected in series and/or in parallel.
As illustrated in
According to another aspect of the invention, no liquid solution is injected in the exhaust pipe [5]. As illustrated in
The liquid solution stored in tank [1] is preferably a 32.5% urea solution commercially available under the brand name Adblue®, but other soluble ammonia compounds (like ammonium carbamate or guanidinium formate) are also suitable. A stream (i.e. part) of the solution enters inside the biochemical decomposition unit [3], where water evaporation and urea decomposition occur. The water is further separated in the condenser [4], and the remaining gaseous flow (i.e. the refilling ammonia gas) goes through the tank [2] where ammonia is trapped on the solid absorbing matrix.
In a particular embodiment, for example when the solid absorbing matrix is saturated with ammonia, a stream (i.e. part) or all of the refilling ammonia gas can flow through the injection line [10] and can be metered in the exhaust pipe [5]. In this particular embodiment, the stream or all of the refilling ammonia gas can flow through the solid absorbing matrix, i.e. the stream or all of the refilling ammonia gas is not trapped on the solid absorbing matrix.
As illustrated in
In a particular embodiment, the refilling ammonia gas generated by the biochemical decomposition unit can be compressed to a suitable pressure before absorption by the solid absorbing matrix. To this aim, a gas pressurisation unit (not shown) can be mounted between the biochemical decomposition unit [3] and the condenser [4]. In a particular embodiment, the gas pressurisation unit can comprise a pump. In another embodiment, the gas pressurisation unit can comprise a piston system. In yet another embodiment, the gas pressurisation unit can comprise a controllable valve system.
As regards the content of the tank [2], any material showing ammonia sorption properties is convenient; however, a matrix containing alkaline earth metal chloride is particularly adapted. The excess of carbon dioxide is either trapped in the condensed water or released in the exhaust pipe [5], when the pressure inside the tank [2] reaches a pre-set level. In vehicle operation, ammonia is desorbed from the solid which is stored in the tank [2], and carried to the exhaust line [5], upstream of the SCR catalyst. The condensed water can be further vaporized in the exhaust line of the vehicle.
In a particular embodiment, an ammonia adsorption loop can also be used, for example in the form of a convection system with a carrier gas used for ammonia depletion of the biochemical decomposition unit [3], and transfer of the ammonia gas to the solid absorbing matrix. After absorption, the ammonia-free carrier gas is available to be enriched with ammonia by flowing again through the decomposition unit [3].
This example, relying on
In this example, the condenser of example 1 is removed and the water/gas separation is made effective by using a membrane or a series of membranes at the outlet of the biochemical decomposition unit [3].
In this case, tank [1] is filled with a solid state ammonia precursor, for example: urea or ammonium carbamate, in the form of powder, pellets or flakes. A stream (part) of the solid is drawn to the biochemical decomposition unit [3] where ammonia is generated, and further trapped in a solid material in the tank [2]. No separator device (water condenser, for example) is needed in this example.
In this example, relying on
In a preferred embodiment, which is not illustrated in
This can be done for instance by storing a given amount of water in the chamber, by deducing the amount of ammonia released from the pressure difference since the beginning of the pressure release and by returning the solution to the tank when the right ammonia concentration is reached.
| Number | Date | Country | Kind |
|---|---|---|---|
| 12199278.8 | Dec 2012 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2013/076942 | 12/17/2013 | WO | 00 |
