Patent Application
20190249364
The present invention relates to a method and system for treating spent pulping liquor comprising lignin from a kraft pulping process to recover spent cooking chemicals.
The kraft pulping process for conversion of wood into wood pulp is well known. A white liquor that contains active cooking chemicals including NaOH (sodium hydroxide) and Na2S (sodium sulfide) is used to solubilize lignin and liberate fibers from wood chips to produce pulp and spent pulping liquor. The pulp recovered after cooking the wood is also known as brown stock pulp. The spent pulping liquor is also known as black liquor and contains organic substances, active cooking chemicals including mainly NaHS, Na2S, and NaOH as well as spent cooking chemicals including Na2CO3 (sodium carbonate), Na2SO4, NaS2O3, and NaSO3. The black liquor is concentrated in an evaporation plant and is then incinerated in a recovery boiler to produce steam and a smelt of molten salts that consists mainly of Na2CO3 and Na2S. The smelt is dissolved in water (or a process water known as weak white liquor) to produce a solution of Na2CO3 and Na2S known as green liquor. The Na2CO3 in the green liquor is then converted to NaOH by mixing the green liquor with calcium oxide to regenerate the white liquor containing NaOH and Na2S for use as active cooking chemicals in the pulping process.
High content of inorganic solids and lignin in the concentrated black liquor from the evaporator lead to increased viscosity and may lead to precipitation of solids which causes undesired plugging in evaporators and pipes. The evaporation plant capacity is a function of evaporation of water from the black liquor and the composition of black liquor. It may desirable to off-load the evaporation plant for example by reducing the charge of spent liquor solutions or aqueous solutions charged to the evaporators in a kraft pulp mill. Higher load of organic material in the black liquor may cause overloading of the recovery boiler. The recovery boiler thus may become a “bottle-neck”, for example, if the mill is planning to increase pulp production capacity. Further, recovery boilers and evaporation plants are expensive to upgrade or to replace.
Attempts have been made to reduce the load on the evaporator or recovery boiler to alleviate the plugging and fouling i.e. “off-load” the overall cooking chemical recovery process. These attempts have focused on reducing the thermal load on the recovery boiler since this is usually the bottle-neck of the pulp mill and is the most expensive unit to upgrade or replace. The quantity of organic substances, especially lignin, in the concentrated black liquor determines the limit at which the recovery boiler operates.
WO 2013/137790 and WO 2016/007550 disclose methods for separating lignin from black liquor by acidification then separation of a lignin solid. In WO 2015/150626, a method for handling spent wash solution produced in the washing of lignin that has been precipitated by acidification and then separated from spent alkaline pulping liquor is disclosed. At least part of the spent wash solution is introduced into the chemical recovery cycle. However, acidifying the black liquor increases costs for the requisite acid and alkali since the sodium-sulphur concentrations have to be balanced and leads to problems with increased purge of sodium sulphate, such as ash from an electrostatic precipitator.
WO 2015/137861 discloses a method for membrane filtering of black liquor to obtain a lignin fraction having a desired molecular weight distribution. WO 2015/121477 discloses a process for treating black liquor involving filtering the black liquor with a membrane filter, lowering the pH to precipitate organic matter, adding ammonia and an alcohol to the organic matter, and subjecting the solution to cracking. The obtained lignin may be made into a liquid fuel.
A process for lignin valorization into bio oils by ultrafiltration of spent cooking liquor into various lignin size fractions, acidifying/precipitating the lignin followed by catalytic depolymerization of lignin fractions is described in A. Toledano et. al. Chemical Engineering Journal, vol. 193-194, 2012, p. 396-403.
While systems for recovery and upgrade of lignin in pulp mills are known in the art, it would be desirable to provide improved systems and methods for reducing the load on evaporators and recovery boilers in pulp mills and allow for valorizing the lignin into useful products whilst continuing to recover substantially all of the cooking chemicals used in the pulping process.
Consequently, the present invention seeks to mitigate, alleviate, eliminate or circumvent one or more of the above-identified deficiencies in the art and disadvantages singly or in any combination by providing in a first aspect a system for treating spent pulping liquor comprising lignin to provide green liquor, the system comprising:
an evaporator for concentrating a first stream of the spent pulping liquor to provide a concentrated pulping liquor;
a recovery boiler for incinerating the concentrated pulping liquor to provide a smelt;
at least one filter for filtering a second stream of the spent pulping liquor to remove lignin therefrom to provide a permeate; and
a green liquor plant for dissolving the smelt from the recovery boiler in at least a part of the permeate from the at least one filter to provide green liquor.
According to an embodiment, the system comprises at least two filters. A first filter for filtering the second stream of the spent pulping liquor to provide a first retentate and a first permeate and a second filter for filtering the first permeate to provide a second retentate and a second permeate. According to such an embodiment at least part of the second permeate is used to dissolve the smelt in the green liquor plant. The first filter may be a membrane filter with a molecular weight cut-off between 0.5 and 20 kDa. The second filter may be a membrane filter with a molecular weight cut-off lower than the one of the first filter. The molecular weight cut-off of the second filter may be between 0.2 and 0.8 kDa.
In some embodiments the system comprises at least one filter for filtering a second stream of the spent pulping liquor to provide a retentate and a permeate. In these embodiments the system further comprises a de-polymerization reactor for treating the retentate to provide a de-polymerized lignin stream.
According to a second aspect there is provided a method for treating spent pulping liquor comprising lignin to provide green liquor, the method comprising:
(a) dividing the spent pulping liquor into a first stream and a second stream;
(b) evaporating the first stream to provide a concentrated pulping liquor;
(c) incinerating the concentrated pulping liquor to provide a smelt;
(d) filtering the second stream to remove lignin, thereby obtaining a permeate with reduced content of lignin;
(e) dissolving the smelt in at least a portion of the permeate to provide green liquor.
According to an embodiment, the filtering step (d) may comprise at least two filtering steps. In the first filtering step, the second stream of the spent pulping liquor is filtered to remove a first portion of lignin to provide a first retentate and a first permeate. In the second filtering step, the first permeate is filtered to remove a second portion of lignin to provide a second retentate and a second permeate. Subsequently, at least part of the second permeate is used to dissolve the smelt in the green liquor plant in step (e). The molecular weight cut-off is typically higher in the first filtering step than in the second filtering step. The molecular weight cut-off may be between 0.5 and 20 kDa in the first filtering step and between 0.2 and 0.8 kDa in the second filtering step. The first retentate and the second retentate may be combined into a single stream comprising the removed lignin.
According to an embodiment, the second stream is between about 5 to 50% by volume of the spent pulping liquor, preferably about 10 to 50% by volume of the spent pulping liquor. Preferably, the first stream is the major stream and the second stream is the minor stream. The volume ratio may thus be at least 2:1.
Spent pulping liquor is very alkaline and there is no need to precipitate lignin in the present process to be able to separate it. Actually, it is preferred to maintain the lignin dissolved to facilitate further processing thereof. Processing of lignin in precipitated form is challenging, as it is very sticky. The pH of permeate resulting from the filtration of the second stream is thus typically highly alkaline. According to an embodiment, the pH of the permeate used to dissolve the smelt is at least 11, such as at least 12. The pH of the permeate may be about 13.
In some embodiments step (d) of the method comprises filtering the second stream to obtain a retentate and a permeate. In these embodiments the method further comprises a step of de-polymerizing the retentate to provide a de-polymerized lignin stream. In embodiments wherein the method comprises more than one filtering step, some but not all of the resulting retentates may be subject to de-polymerization before being combined. By de-polymerization of lignin with higher molecular weight, the molecular weight distribution in the combined retentate will be more narrow. In a method comprising two filtering steps, the first but not the second retentate may be subject to de-polymerization.
In some embodiments, part of the permeate is sent to the evaporator. By sending part of the permeate to the evaporator the concentration of high-molecular compounds in the stream of spent pulping liquor to be evaporated will be lowered, though the content of low molecular weight compounds, e.g. inorganic salts, remains the same. Lowering the concentration of high-molecular compounds in the stream of spent pulping liquor to be evaporated will lower the viscosity of the spent pulping liquor to be evaporated. Thereby the spent pulping liquor to be evaporated may be concentrated to a higher dry content before being incinerated.
These and other aspects, features and advantages of which the invention is capable of will be apparent and elucidated from the following description of an embodiment of the present invention, reference being made to the accompanying drawings, in which:
The following description focuses on an embodiment of the present invention applicable to a system and method for treating spent pulping liquor to provide green liquor. However, it will be appreciated that the invention is not limited to this application but may be applied to other systems and methods which involve treating spent liquor e.g. soda liquor from a soda cooking process.
The table below lists features of the system 10 in
As used herein the terms “spent pulping liquor” and “black liquor” are used interchangeably.
Spent pulping liquor 14 is separated into a first stream 18 and a second stream 54. As already mentioned, spent pulping liquor 14, apart from lignin, comprises spent inorganic cooking chemicals, such as Na2CO3, Na2SO4, NaS2O3, and NaSO3. Typically, the pH of the spent pulping liquor 14 is 12 or higher, such as about 13.
The first stream 18 enters evaporator 22 wherein it is concentrated to form condensate 26 and concentrated pulping liquor 30. The concentrated liquor 30 then enters recovery boiler 34 for incineration. Flue gases 38 evolve from recovery boiler 34 and a smelt 42 is produced. Smelt 42 is then dissolved in an aqueous second permeate 82 obtained from treatment of the second stream 54 as will be described below. As already mentioned, the smelt comprises molten salts that consist mainly of Na2CO3 and Na2S. Additional aqueous liquids or process water available in the kraft mill (not shown) may be used to dissolve the smelt 42 if the quantity of second permeate 82 is insufficient. Dissolution of smelt 42 occurs in green liquor plant 46 to form green liquor 47 which is re-causticized using calcium hydroxide in white liquor plant 48. The regenerated white liquor 50, comprising NaOH and Na2S, from the white liquor plant 48 is recycled back to the wood cooking plant of the kraft pulping process (not shown).
The second stream 54 of spent pulping liquor enters first filter 58 wherein stream 54 is separated into a first retentate 62 and a first permeate 66. The first retentate 62 is rich in organic substances, including lignin, while the first permeate 66 is depleted of organic substances. The first retentate 62 is sent to de-polymerization reactor 70 wherein it is treated to produce a de-polymerized lignin stream 71. The first permeate 66 enters second filter 74 to yield a second retentate 78 and a second permeate 82 further depleted of organic substances. Optionally, some of the first permeate 66 is sent to evaporator 22 (cf. dashed line in
The first filter 58 and the second filter 74 are membrane filters operating in cross-flow mode. The membrane of the first filter 58 is an ultrafiltration membrane or an open nanofiltration membrane with a molecular weight cut-off in the range of 0.5 to 20 kDa, preferably about 1 kDa. The molecular weight cut-off of the membrane in the second filter 74 is lower than of the first filter 58 and is preferably between 0.1 and 0.8 kDa, such as about 0.2 kDa.
The second stream 54 that is fed to the first filter 58 is typically a weak spent pulping liquor (i.e. black liquor containing about 15% solids) from the wood digesters of the kraft pulping process as described above. Alternatively, the second stream 54 may be an intermediate black liquor (containing about 20-30% solids) from the black liquor evaporator 22 or a combination of a weak black liquor and an intermediate black liquor. An advantage of using an intermediate black liquor as the second stream 54 is that rosin soaps have usually been removed from the liquor. The rosin soaps may negatively affect the filtering process. Further are the rosin soaps a valuable by-product.
The second stream 54 is between about 10 to 50% by volume of the spent pulping liquor 14. Commonly, the first stream 18 is the major stream and the second stream 54 is the minor stream. The second stream 54 may be about 25% by volume and the first stream 18 may be about 75% by volume of the spent pulping liquor 14.
The present applicant has surprisingly found that the method and system of the invention significantly reduces the load on both the evaporation plant and the recovery boiler in a pulp mill whilst simultaneously recovering substantially all of the cooking chemicals for re-use in the pulping process. Avoiding a trade-off between reducing the load of the evaporation plant and the recovery boiler on the one hand, and the recovery of the cooking chemicals on the other is a major advantage. Thus, the present process allows for pulp production capacity of a kraft pulping mill to be increased whilst dispensing with the need to upgrade or replace the recovery boiler and/or evaporation plant. Further, the method and system of the invention allows for valorizing part of the lignin in the wood into useful products, contributing to the overall process economy.
The system 10 was operated as follows. Weak black liquor 14 from the digestion of softwood was used. The membrane of the first filter 58 had a molecular weight cut-off of 1 kDa while the membrane of the second filter 74 had a molecular weight cut-off of 0.2 kDa. The weak black liquor 14 was divided into a first stream 18 that was sent to the evaporator 22, recovery boiler 34 etc. as described above and a second stream 54 that was filtered through the first filter 58 operated with cross-flow velocities between 3 and 5 m/s, transmembrane pressures of 5 to 35 bar and at a temperature between 70° C. and 120° C. The first filter 58 separated between 75 and 90 wt. % of the lignin from the second stream 54. The first retentate 62 had a lignin concentration between 190 and 280 g/l (compared with 55 to 70 g/l in the initial weak black liquor 14 and second stream 54). The first retentate 62 was subjected to base catalysis in de-polymerization reactor 70 at a temperature between 250 and 290° C. for between 10 minutes and 4 hours to de-polymerize the lignin. The de-polymerization reactor 70 may contain one or more catalysts. The catalysts may be homogenous or heterogeneous. The catalyst may be selected from the group consisting of nickel, copper, molybdenum, and zirconium catalysts on a support, calcium compounds, sodium hydroxide, and potassium carbonate. Hydrogen gas, a hydrogen donor solvent, or a solvent such as phenol, cresol, or methanol may also be added to the de-polymerization reactor 70. The molecular weight distribution of the lignin was reduced from between 1 and 10 kg/mole in first retentate 62 to between 0.2 and 1.4 kg/mole in de-polymerized lignin stream 71. The first permeate 66 was filtered through second filter 74 at similar conditions to the first filter 58. The obtained second permeate 82 contained lignin and hemicellulose in concentrations of only about 2 wt. % of their concentrations in the second stream of black liquor 54. The second permeate 82 has low organic content and a high content of cooking chemicals including Na2CO3. Further, the organic compounds in this stream have a low molecular weight (less than 0.2 kDa). Aqueous streams with low content of organic material may be charged to green liquor plants which are not able to tolerate particulate organics in any quantities, though being equipped with efficient green liquor filters, but rather to tolerate salts and water. The second permeate 82 was sent to the green liquor plant 46. The obtained second retentate 78 contained lignin with a molecular weight distribution between that of the membrane filters i.e. between 0.2 and 1 kDa. This distribution was similar to the lignin in the de-polymerized lignin stream 71. The second retentate 78 was combined with the de-polymerized lignin stream 71 to produce a combined lignin stream 86 suitable for manufacture of lignin bio-oil or other useful products.
Although the present invention has been described above with reference to specific illustrative embodiments, it is not intended to be limited to the specific form set forth herein. Any combination of the above mentioned embodiments should be appreciated as being within the scope of the invention. Rather, the invention is limited only by the accompanying claims and other embodiments than the specific above are equally possible within the scope of these appended claims.
In the claims, the term “comprises/comprising” does not exclude the presence of other species or steps. Additionally, although individual features may be included in different claims, these may possibly advantageously be combined, and the inclusion in different claims does not imply that a combination of features is not feasible and/or advantageous. In addition, singular references do not exclude a plurality. The terms “a”, “an”, “first”, “second” etc. do not preclude a plurality.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1651205-5 | Sep 2016 | SE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2017/072204 | 9/5/2017 | WO | 00 |
