Patent Application
20230392320
The invention relates to a method for bleaching pulp formed from recycled textile material comprising cellulose, which method comprises ozone bleaching. The invention also relates to a corresponding system.
Over the recent years, recycling of textile material has gained interest. The company Renewcell has developed a process for recycling cellulose from textile material comprising cellulose, see for instance WO2018/073177A1. Recycled cellulose can be used for different purposes, for example for producing viscose. In the above-mentioned publication, the need for de-colorization/bleaching of the recycled textile material is identified, and it is suggested to use a combination of oxygen and ozone bleaching.
Ozone bleaching of cellulose pulp from wood material is well known in the art, where ozone reacts with and de-composes lignin originating from the wood material. When it comes to bleaching of pulp from textile material, the purpose of the ozone bleaching is somewhat different—mainly to bleach or decompose color pigments contained in the pulp, which pulp mainly consists of cellulose and liquid (water). Despite the use of ozone, it has, however, proven challenging to achieve sufficient brightness of the resulting pulp. Further, the oxidative properties of ozone will also attack the cellulose fibers and may reduce the viscosity of the resulting pulp to an unsatisfactorily low level. Thus, there is a need for an improved method for bleaching/de-colorizing pulp from recycled textile material.
An object of the invention is to solve or improve on at least some of the problems mentioned above in the background section.
These and other objects are achieved by the present invention by means of a method according to the independent claim.
According the invention, a method for bleaching pulp formed from recycled textile material comprising cellulose is provided. The method comprises ozone bleaching of said pulp by means of adding ozone in two subsequent steps at an overall charge of at least 12 kg/odt, or even more advantageously at a charge of at least 15 kg/odt, where the unit “odt” stands for oven dried ton, where 1 ton is 1000 kg.
When bleaching/delignifiying cellulose pulp from wood material, ozone charges of 8 kg/odt or less are normally used, based on the knowledge that higher charges do not improve the brightness of the resulting pulp. Contrary to this conventional practice within the field of ozone bleaching, the present invention is based on the insight that significantly higher charges, such as 12 kg/odt or even 15 kg/odt, further improve the brightness of the resulting pulp to a surprising extent when the cellulose pulp being bleached is formed from recycled textile material. Experimental data have shown that unbleached pulp having an ISO brightness of about 65% can bleached to a brightness of about 80% solely using two ozone bleaching steps as defined by the inventive method. By supplementing the ozone bleaching with further bleaching steps such as a peroxide bleaching step and/or a chlorine dioxide bleaching step, a satisfactory final brightness of about 90% is obtainable or even higher.
In embodiments, the method comprises pretreating the pulp prior to said ozone bleaching, wherein the pretreating comprises adding at least one acid to reduce the pH of the pulp, and adding one or more additives. The one or more additives may be added together with, or simultaneously with the at least one acid. Alternatively, the one or more additives may be added prior to, or after the at least one acid. The at least one acid may comprise sulphuric acid. The at least one acid may be added at a charge such that the pH is reduced to within a range from 2 to 3, preferably from 2 to 2.5 or from 2.5 to 3. The one or more additives may comprise one or more chelating agents and/or radical scavengers. Chelating agents provide the effect that selectivity in the ozone bleaching step is improved by reducing the content of metal ions in the pulp, which metal ions catalyze the degradation of ozone to free radicals, which in turn cause cellulose degradation. Radical scavengers have a similar effect by scavenging the metal ions. The use of chelating agents and radical scavengers has proven particularly advantageous together with the unusually high ozone charges used in the present invention, which otherwise may cause excessive cellulose degradation and consequently too low viscosity of the resulting pulp. The one or more additives may be chosen from a group comprising oxalic acid, acetic acid, ethylenediaminetetraacetic acid, EDTA, diethylenetriaminepentaacetic acid, DTPA, magnesium sulfate or calcium chloride.
In embodiments, the additives may be added at charge of 1-2 kg/odt. Ozone may be added as a gas mixture, for example with 8-14% ozone by weight in an ozone-air mixture. The ozone bleaching steps may be performed for a duration of 1-10 minutes, for example at a temperature of 40-70° C., for example at a pulp consistency of 30-42%, preferably 34-40%.
In embodiments, the method comprises one or more further bleaching steps after the ozone bleaching. For example, the method may comprise a hydrogen peroxide bleaching step after the ozone of the pulp. The method may further comprise, after the peroxide bleaching, a chlorine dioxide bleaching step. In other embodiments, the chlorine dioxide bleaching step is performed prior to the peroxide bleaching step. In yet other embodiments, a chlorine dioxide bleaching step is performed after the ozone bleaching without a preceding or following peroxide bleaching step.
In embodiments comprising a peroxide bleaching step and a subsequent chlorine dioxide bleaching step, the method preferably comprises, prior to or during the peroxide bleaching, adding a radical scavenger such as magnesium sulfate. Addition of a radical scavenger in this manner has surprisingly proven to have a positive effect on the viscosity after the chlorine dioxide bleaching step. More specifically, the radical scavenger has not proven to have any significant effect on the (loss of) viscosity over the peroxide step, but has an effect on the chlorine dioxide bleaching step in the sense that the viscosity loss is substantially reduced or even prevented.
In embodiments, the pulp has a consistency of at least 30%, preferably within a range from 35-42% prior to the ozone bleaching step. Ozone bleaching of this kind of pulp has proven to be difficult to carry out on medium-consistency pulp since the high amount of liquid may in this case prevent the ozone to penetrate into the dry content (cellulose) of the pulp. It is therefore advantageous to provide the pulp at high consistency (at least 30%, preferably 35-42% consistency) to the ozone bleaching steps. In other words, the method comprises providing the pulp at such high consistency, or alternatively providing the pulp at low or medium consistency whereafter the pulp is subjected to a dewatering/thickening step prior to the ozone bleaching steps. Dewatering/thickening of cellulose pulp is well known in the art and will not be described in further detail here.
In embodiments, the method comprises oxygen bleaching of the pulp prior to the ozone bleaching. In embodiments comprising pretreating, the oxygen bleaching step is performed prior to said pretreating step. In other embodiments, the method comprises oxygen bleaching of the pulp after the ozone bleaching. Oxygen bleaching, i.e. bleaching by means of adding oxygen is well known in the art and will not be described in further detail here.
It is understood that the method for bleaching normally comprises one or more washing steps, between the bleaching steps, for instance after the ozone bleaching, i.e. prior to any further bleaching steps.
The features of the embodiments described above are combinable in any practically realizable way to form embodiments having combinations of these features. Further, all features and advantages of embodiments described above with reference to the first aspect of the invention may be applied in corresponding embodiments of the second aspect of the invention.
Above discussed and other aspects of the present invention will now be described in more detail using the appended drawings, which show presently preferred embodiments of the invention, wherein:
The description above and the appended drawings are to be considered as non-limiting examples of the invention. The person skilled in the art realizes that several changes and modifications may be made within the scope of the invention. For example, depending on the required brightness of the resulting pulp, one or more of the bleaching step(s) prior to or after the ozone bleaching step(s) may be omitted, for example the chlorine dioxide bleaching step (along with the related addition of a radical scavenger step) may be omitted, or the peroxide bleaching step may be omitted. Furthermore, the ozone bleaching may be performed using fewer or further sub steps.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2051513-6 | Dec 2020 | SE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/SE2021/051110 | 11/8/2021 | WO |
