This is the U.S. National Phase application of PCT/JP2019/008262, filed Mar. 4, 2019, which claims priority to Japanese Patent Application No. 2018-066476, filed Mar. 30, 2018, the disclosures of these applications being incorporated herein by reference in their entireties for all purposes.
The present invention relates to a method for charging raw materials into a blast furnace that includes a bell-less-type charging device.
In recent years, there has been a demand for reducing CO2 emissions for the prevention of global warming. In the steel industry, approximately 70% of the amount of CO2 emission is associated with blast furnaces, and, therefore, there is a demand for reducing the amount of CO2 emission associated with blast furnaces. Reducing CO2 emission associated with blast furnaces can be achieved by reducing reduction agents used in blast furnaces, such as coke, pulverized coal, and natural gas.
However, reducing a reduction agent, particularly coke, which serves to ensure the gas permeability of the burden layer in a furnace, results in an increase in the gas permeation resistance of the burden layer of the furnace. In a common blast furnace, when the ore charged from the furnace top reaches a temperature at which the ore begins to soften, the ore is deformed while filling voids; this occurs because of the weight of the raw materials existing in an upper region. As a result, in a lower region of the blast furnace, a cohesive zone is formed in which the gas permeation resistance of an ore layer is very high, and thus little gas flows. The gas permeability of the cohesive zone has a significant influence over the gas permeability of the entire blast furnace and, therefore, limits the productivity of the blast furnace.
It is known that one effective way to improve the gas permeation resistance of the cohesive zone to increase the reducibility of ore and thus lower the Reducing agent rate is to mix coke into an ore layer. Many proposals have been made regarding methods for mixing coke into an ore layer. Patent Literature 1 discloses a method in which high-reactivity coke (coke having a JIS reactivity index of 30% or greater) is mixed with low-reactivity ore (ore having a low JIS reducibility index) to efficiently react the low-reactivity ore and thus increase the reducibility of the ore.
Patent Literature 2 discloses a method for charging raw materials into a blast furnace. In the method, a plurality of raw materials are simultaneously charged from a plurality of main hoppers.
PTL 1: Japanese Examined Patent Application Publication No. 7-76366
PTL 2: International Publication No. 2013/172045
Unfortunately, in the method disclosed in Patent Literature 1, it is necessary to use high-reactivity coke, which has lower strength than ordinary coke, and, therefore, the method cannot be applied to a blast furnace operation in which only ordinary coke is used. Specifically, in an example disclosed in Patent Literature 1, ore having a JIS reducibility index of 55% is used exclusively as ore, and coke partially substituted with high-reactivity coke is mixed with the low-reactivity ore. In the example, however, if ordinary coke is exclusively used, it is impossible to sufficiently ensure a reducibility of the low-reactivity ore.
Patent Literature 2 presents a method for charging raw materials into a blast furnace in which a plurality of raw materials are simultaneously charged from a plurality of main hoppers. However, when the raw materials are to be charged into the blast furnace, a pressure adjustment time is necessary for replacing the atmosphere within the main hoppers with an atmosphere corresponding to the blast furnace interior atmosphere. From the standpoint of maintaining a production volume, using a hopper exclusively for a small amount of raw material is not practical.
An object according to aspects of the present invention is to provide methods for charging raw materials into a blast furnace, the methods being designed to solve problems associated with the related art technologies, including the problems described above. Specifically, the methods make it possible for low-reactivity ore to be reduced efficiently in a blast furnace including a bell-less-type charging device, even in a case where ordinary coke is used.
A summary of aspects of the present invention, which solves the problems described above, is as follows.
In accordance with aspects of the present invention, low-reactivity ore (low-reducibility ore) can be charged exclusively to a region having a low reduction load in a blast furnace radial direction, and thus, even in a case where ordinary coke is used, low-reactivity ore can be reduced efficiently.
In accordance with aspects of the present invention, a bell-less charging device including a plurality of main hoppers and an auxiliary hopper at a furnace top portion is used. The auxiliary hopper has a smaller capacity than the main hoppers. Ordinary ore, that is, ore (x) having a JIS reducibility index (RI) of greater than 55%, is charged into at least one of the plurality of main hoppers, and low-reactivity ore (y) having a JIS reducibility index (RI) of 55% or less is charged into the auxiliary hopper. The low-reactivity ore (y) is an amount of the low-reactivity ore (y) for a plurality of charges. An amount of the ore (x) per charge is charged in batches into a furnace from at least one of the main hoppers, and an amount of the low-reactivity ore (y) per charge is charged in batches into the furnace from the auxiliary hopper. In such raw material charging, a ratio of mixing of the low-reactivity ore (y) can be varied by adjusting the amounts of raw materials to be discharged from the main hoppers and the auxiliary hopper, and, therefore, the low-reactivity ore (y) can be easily controlled in a manner such that a preferred mixed state is achieved.
Typically, the JIS reducibility index (RI) of ore used as a main raw material in a blast furnace is greater than 55% (typically, less than approximately 80%), and, therefore, ore having a JIS reducibility index (RI) of 55% or less can be regarded as having low reactivity. In accordance with aspects of the present invention, the low-reactivity ore (y) is ore having a JIS reducibility index (RI) of 55% or less. Among others, ore having a JIS reducibility index (RI) of 40% or less is particularly hard to reduce, and, therefore, aspects of the present invention are particularly useful in a case where such ore is used. Note that the JIS reducibility index (RI) can be measured by using the reducibility testing method specified in JIS (Japanese Industrial Standards) M 8713.
In accordance with aspects of the present invention, the term “ore” (ore (x) and low-reactivity ore (y)) refers to one or more of sintered ore, lump ore, pellets, and the like, which are iron sources. In a case where one or more auxiliary raw materials (e.g., limestone, silica stone, serpentinite, and the like), which are used mainly for the purpose of slag component adjustment, are mixed with the ore (x), the ore includes such auxiliary raw materials.
Coke used in accordance with aspects of the present invention may be so-called ordinary coke, that is, coke having a JIS reactivity index (JIS reactivity index measured by using the reactivity testing method specified in JIS (Japanese Industrial Standards) K 2151:2004) of 30% or less.
In an operation of a blast furnace, raw materials are charged in a manner such that ore layers and coke layers are alternately formed within the blast furnace. An amount of ore to be used to form one ore layer is referred to as an amount of ore per charge. The amount of ore per charge is to be charged in batches into the blast furnace. According to aspects of the present invention, methods for charging raw materials into a blast furnace are concerned with methods for charging ore (ore (x) and low-reactivity ore (y)) that is charged on a per-batch basis.
If a particle diameter of the raw materials that are charged on a per-batch basis varies, the gas flow within the furnace may become unstable. Accordingly, it is preferable to ensure that the downward flow of the raw materials within the auxiliary hopper is a mass flow, thereby enabling the raw materials charged in the auxiliary hopper to be discharged from the auxiliary hopper in the order in which the raw materials are charged. It is preferable that a diameter d2 of a hopper body of the auxiliary hopper satisfy d1<d2 1.5×d1, where d1 is a diameter of an outlet of the auxiliary hopper, and d2 is the diameter of the hopper body. This configuration ensures that the downward flow of the raw materials within the auxiliary hopper is a mass flow.
In the above-described bell-less charging devices 1a and 1b of the embodiments, the ore (x) discharged from the main hoppers 2 and the low-reactivity ore (y) discharged from the auxiliary hopper 3 are charged into the furnace from a rotating chute 4 by way of a collecting hopper 5. In
A flow regulating valve (not illustrated) is provided at the outlet of the auxiliary hopper 3 to control a rate of discharge of the low-reactivity ore (y).
Details of methods for charging raw materials according to aspects of the present invention will now be described with reference to examples, in which the bell-less charging device 1a or 1b described above is used.
As illustrated in
As can be seen from
Accordingly, in accordance with aspects of the present invention, in a case where the ore (x) charged in a main hopper 2 is discharged and then sequentially charged from the furnace center side toward the furnace wall side by using the rotating chute 4 (a first method for charging raw materials according to aspects of the present invention), only the ore (x) is charged from the rotating chute 4 after the charging of the ore (x) is started, at least until charging of 45 mass % of the ore (x) is completed based on the total amount of the ore (x) to be charged per batch; then, at a point in time, the charging of the low-reactivity ore (y) charged in the auxiliary hopper 3 is started; and then, the low-reactivity ore (y) is charged together with the ore (x) from the rotating chute 4 for a time period. The time at which the charging of the low-reactivity ore (y) is to be started may be the point in time at which the charging of 45 mass % of the ore (x) is completed based on the total amount of the ore (x) to be charged or may be some point in time after a certain time period elapses after the charging of 45 mass % of the ore (x) is completed based on the total amount of the ore (x) to be charged. The charging of the low-reactivity ore (y) may be performed until the charging of the total amount of the ore (x) is completed or may be stopped before the charging of the total amount of the ore (x) is completed. The time at which the charging of the low-reactivity ore (y) is to be started and the time period during which the charging of the low-reactivity ore (y) is to be performed may be determined in accordance with the low-reactivity ore (y) mixed state that is required.
In a case where the ore (x) charged in a main hopper 2 is discharged and then sequentially charged from the furnace wall side toward the furnace center side by using the rotating chute 4 (a second method for charging raw materials according to aspects of the present invention), the charging of the low-reactivity ore (y) charged in the auxiliary hopper 3 is started simultaneously with the start of the charging of the ore (x) or at a point in time after the start of the charging, then the low-reactivity ore (y) is charged together with the ore (x) from the rotating chute 4, and the charging of the low-reactivity ore (y) is stopped at least before the point in time at which charging of 56 mass % of the ore (x) is completed based on the total amount of the ore (x) to be charged per batch. In this case, too, the time at which the charging of the low-reactivity ore (y) is to be started and the time period during which the charging of the low-reactivity ore (y) is to be performed may be determined in accordance with the low-reactivity ore (y) mixed state that is required.
In the case where raw materials including the low-reactivity ore (y) are to be charged into a region defined by specific dimensionless radii (region defined by specific charge ratios) such as that described above, it is necessary to ensure that the charge center position is within the specified range (the region defined by specific dimensionless radii) as indicated by a heap a1 of charged raw materials illustrated in
By charging the low-reactivity ore (y) into the furnace at a target timing as described above, the low-reactivity ore (y) can be charged into a region having a low reduction load without being charged into regions on the furnace center side or regions having a high reduction load. As a result, the low-reactivity ore (y) can be reduced efficiently even in a case where ordinary coke is used. Furthermore, deterioration of gas permeability that may occur if the low-reactivity ore (y) is charged to a central portion of the furnace is inhibited, and, therefore, the gas flow and the reduction state of the ore can be stabilized effectively. Consequently, the Reducing agent rate in a blast furnace operation can be lowered.
In a case where the bell-less charging device 1a of
In accordance with aspects of the present invention, an amount of the low-reactivity ore (y) for a plurality of charges is charged into the auxiliary hopper 3, and, from the auxiliary hopper 3, an amount of the low-reactivity ore (y) per charge is charged in batches into a blast furnace. Accordingly, the pressure adjustment time associated with the discharging of raw materials can be reduced, and as a result, the production volume of a blast furnace can be maintained even in a case where a small amount of raw material is to be charged into the blast furnace by using a discrete auxiliary hopper.
A charging test for ore (x) and low-reactivity ore (y) was conducted by using a 1/20-scale model testing device.
The ore (x) used was ore (sintered ore) having a JIS reducibility index (RI) of 65%, and the low-reactivity ore (y) used was ore (lump ore) having a JIS reducibility index (RI) of 50%. The coke used was ordinary coke. In Invention Examples, ore (x) was charged into main hoppers, and low-reactivity ore (y) was charged into the auxiliary hopper. The low-reactivity ore (y) was discharged from the auxiliary hopper during a portion of the time period during which the ore (x) was discharged from the main hoppers. On the other hand, in Comparative Examples, only main hoppers were used, in accordance with a method of the related art, that is, ore (x) and low-reactivity ore (y) were charged into the main hoppers such that a predetermined condition was achieved, and the ore (x) and the low-reactivity ore (y) were discharged from the main hoppers.
With the model testing device, a charge test was conducted in association with a case in which raw materials are sequentially charged from the furnace center side toward the furnace wall side by using a rotating chute, and the ratio of the low-reactivity ore (y) in the discharged raw materials was measured in the manner described above.
As shown in
Similarly, with the model testing device, a charge test was conducted in association with a case in which raw materials are sequentially charged from the furnace wall side toward the furnace center side by using a rotating chute, and the ratio of the low-reactivity ore (y) in the discharged raw materials was measured in the manner described above.
As shown in
Table 1 summarizes the results of an evaluation of the operation conditions of Examples and Comparative Examples, which was conducted by using a blast furnace operation prediction model. As shown in Table 1, Invention Examples 1 to 3 had a lower Reducing agent rate and a lower pressure drop of the filled layer than Comparative Examples 1 and 2. Since the low-reactivity ore (y) was discharged at a target time as described above, it was possible to charge the low-reactivity ore (y) into a region having a low reduction load. It was confirmed that consequently, the reduction state of the ore was stabilized, and deterioration of gas permeability and an increase in heat loss that might occur if the low-reactivity ore (y) had been charged to a region on the blast furnace center side was inhibited, which resulted in a lowering of the Reducing agent rate of a blast furnace.
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PCT/JP2019/008262 | 3/4/2019 | WO |
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WO2019/187998 | 10/3/2019 | WO | A |
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