Patent Application
20130234165
The invention relates to a method for coating micromechanical components of a micromechanical system, in particular a watch movement, in order to provide a reduction of the surface roughness, an enhancement of the tribological performances and reduction of dust accumulation on working surfaces. The invention also relates to the corresponding micromechanical component for a micromechanical system, in particular a watch movement. The invention can be used in micromechanical watch movements, in particular for the realisation of escapement wheels and pallets and other friction-relevant components.
The technical demands on micromechanical components are growing. Beside highest precision, there is a need to provide highest energy efficiency in the mechanical system, long lifetime and complete abdication of lubricants insofar as possible.
In the last few years, a lot of documents dealing with this subject have been published. The described approaches fulfil some of the tasks without being able to deliver a complete solution mainly due to the restrictions on the materials used.
Micromechanical components produced by mechanical machining (die cutting or shape cutting) exhibit two major disadvantages. First, they are either high priced or economically profitable only in mass production because investments are required for expensive production tools. Second, these processes reach their technical limits with an accuracy level lying by +/−5 micrometers.
Thus several alternative approaches have been discussed in literature. One of the most promising ideas relates to the etching of micromechanical parts from silicon wafers achieving highest precision, even exceeding the results of the machining techniques by far. The tolerances can be reduced to the sub-micrometer range, but at the expense of lifetime: in practical results it was shown that the mechanical strength as well as the abrasive wear of these parts could not meet the demands in the absence of lubricant. One solution to the problem has been demonstrated in EP patent No 1 904 901: by treating the surface of the micromechanical parts with oxygen. The strength and the lifetime could be extended, but without achieving an ultimate solution however.
The energy efficiency could be enhanced by using special oils in mechanical systems, however at the expense of the demand for a dry running system.
The longest lifetime is achieved by classical machined parts made of steel, but these systems have reached their limits in regard to high accuracy and have to be further lubricated.
A further problem of the lubricated systems is the necessity for frequent service intervals, where the movements have to be cleaned and re-lubricated. Thus the cycles of operation are limited and additional costs arise. These service intervals are necessary due to aging of the used oils which loose their properties with time.
Numerous approaches to fulfil all these requirements with one system have been undertaken.
In EP0732635B1 an approach is described where the micromechanical parts are etched from a silicon wafer and then coated with diamond films. The diamond films obtained via this method have a surface roughness higher than 400 nm. These films require therefore a subsequent polishing if the diamond coated parts are used in sliding contact applications.
EP1233314 discloses a mechanical clockwork assembly for watches having a mechanical escapement with an escapement wheel and an anchor wherein the functional elements of the escapement wheel are at least partially coated on their operating surfaces with a DLC (diamond like carbon) coating. DLC has a high sp2 content (ranging from 30-100%) and is amorphous carbon which hardness is not sufficient for effective wear protection applications.
EP1622826 discloses a micromechanical component comprising a first surface and a second surface, which are substantially perpendicular in relation to one another wherein the first and/or the second surface consist at least partially of diamond.
U.S. Pat. No. 5,308,661 discloses a process for the pre-treatment of a carbon-coated substrate to provide a uniform high density of nucleation sites thereon for the subsequent deposition of a continuous diamond film without the application of a bias voltage to the substrate.
EP1182274A1 discloses a method for the post-treatment of diamond coatings where a coarse-grained (micrometer regime) diamond coating is deposited on machining tools and subsequently treated be means of plasma processes. The aim of this post-treatment is the degradation of the top layers of the sp3-hybridised diamond coating into sp2-hybridised carbon species. The expectation is a filling of the “surface valleys” between the coarse grains protruding from the surface to achieve a more flat surface. The result of such method is a film having a coarse grain sp3 diamond on top of which is a top layer of several hundred nanometres of sp2 hybridised amorphous carbon. The top layer is relatively soft and will wear off quickly in applications involving high friction.
All the solutions described above can solve only partly the problem of providing micromechanical components featuring coefficient of friction lower than 0.05, and thus a large-scale production was prevented which is however demanded in the watch industry for instance.
In particular, when using diamond-coated silicon, the solutions described above raised the following problems: the diamond coated micromechanical components often exhibit a high coefficient of friction because of the microcrystalline structure of the diamond coatings. This high coefficient of friction severely limits the efficiency of the micromechanical system.
It is well known that surfaces with a roughness above several hundred nanometres cannot achieve low coefficients of friction. Moreover, utilising coarse diamond films in mechanical systems require a very smooth counterpart. In such cases the rough diamond film would grind into its corresponding counterpart leading to a very quick abrasive wear of the system.
In theory, a special case is imaginable, where different roughness's modules are fitting special conditions and therefore produce a low coefficient of friction. However the pressure on the single grains would be too high leading to a breaking and/or interlocking of the grains. The mechanical system would thus lose its properties very quickly ending up in a high coefficient of friction and thus a blocking of the system. After the breakdown of the coating, the whole system will collapse.
Solutions suggesting a polishing after the diamond-coating and therewith a smoothening of the surface of the micromechanical components failed because of high costs, the low efficiency and an essential technical reason: the most important functional surfaces are the flanks of the micromechanical parts which are not accessible for mechanical polishing when mounted in a wafer. A polishing after removing the parts from the wafers is not possible and moreover uneconomic because of the multitude and the diminutiveness of the micromechanical parts. Solutions with plasma etching of a diamond coated wafer comprising the micromechanical parts have also failed due to non-homogeneity of the plasma polishing especially on the flanks of the parts, which are the most important areas (see above).
Approaches using smaller crystal sizes (of a few hundreds nanometres) suffered similar problems in smaller dimensions. For instance, plasma etching of the flanks is not feasible because these processes affects mainly the grain boundaries and etches the surfaces in an anisotropic way.
Additionally, anisotropy of the etching treatment can arise from several parameters. The etching efficiency depends strongly on the crystallographic orientations of the diamond crystals. As diamond films grown on substrates other than diamond (silicon in most cases), they exhibit a mixture of crystallographic orientations, making etching non-uniform, which can even increase the surface roughness of diamond instead of decreasing it.
A general aim of the invention is therefore to provide a process that allows providing micromechanical components for a micromechanical system, in particular a watch movement, providing a longest lifetime.
A further aim of the invention is to provide a process allowing providing micromechanical components for a micromechanical system, in particular a watch movement, reducing service intervals.
A further aim of the invention is to provide a process allowing providing micromechanical components for a micromechanical system, in particular a watch movement, reducing friction.
Still another aim of the invention is to provide micromechanical components for a micromechanical system, in particular a watch movement, enhancing tribological performances.
A further aim of the invention is to provide a process allowing providing micromechanical components for a micromechanical system, in particular a watch movement, reducing dust accumulation at the surface of the components.
These aims are achieved thanks to a process for coating micromechanical components of a micromechanical system, in particular a watch movement, and a micromechanical component for a micromechanical system, as defined in the claims.
There is accordingly provided a method for coating micromechanical components of a micromechanical system, in particular a watch movement, comprising:
Such dual coating enables to get the advantages of two complementary technologies. The first coating provides long-term stability due to hardness of diamond and the high adherence between diamond and the silicon substrate. The second coating is highly resistant to wear while providing low friction and substantially high conductivity. The high conductivity reduces dust accumulations at the surface of the coating.
In a preferred embodiment, said sp2 content is substantially between 1% and 45%, and most preferably between 15% and 30%.
In another embodiment, the first diamond coating is doped with boron, or phosphorus or sulphur or aluminum.
In yet another embodiment, the first and second diamond coatings are provided by CVD in a reaction chamber.
The reaction time for providing the second layer is preferably shorter than the reaction time for providing the first layer.
The thickness of the first layer is preferably between 500 nm and 100 micrometer, and most preferably less than 10 micrometer.
The thickness of the second layer is preferably between 1 and 100 micrometer, and most preferentially less than 10 micrometers.
In a still further embodiment, the micromechanical component is an escapement wheel and wherein during process, the escapement wheel is provided on a refractory wire, so that the rotation axis of the escapement wheel is substantially horizontal.
The increase of carbon content may be obtained by increasing the proportion of carbon containing reactant gas, or by adding an additional carbon containing gas, or by increasing the temperature and/or pressure within the processing reaction chamber, or by adding gaseous nitrogen to the reaction chamber, or by replacing hydrogen by argon, or by adding at least one rare gas.
The invention further provides a micromechanical component for a micromechanical system, in particular a watch movement, obtained by a method as previously described. In an advantageous embodiment, the surface layer has a gradual increase of sp2 hybridized carbon content. In a preferred example, the component is an escapement wheel. In a further example, the component is a pallet.
Such mechanical components, produced for micromechanical systems allow the running of the mechanical system under dry (unlubricated) conditions, feature high tribological performances (very low friction coefficient, reduced wear, etc), are long-time stable and feature high energy efficiency.
The foregoing and other purposes, features, aspects and advantages of the invention will become apparent from the following detailed description of embodiments, given by way of illustration and not limitation with reference to the accompanying drawings, in which:
a and 2b are schematic representations of the surface structure of a diamond film deposited according to the method of the invention for different grain sizes, resulting in a low roughness, and therefore a low coefficient of friction, when the grain size is the smallest;
Once the substrates to be coated have been properly prepared, the coating process, including two main steps, may be started.
In step one, a nanocrystalline diamond layer doped with boron is applied on the substrates. The application time is long enough to allow a diamond layer of several micrometers: that is to say between one hour to about one hundred hours, and most preferably around ten hours.
If escapement wheels and pallets are being coated, during the application phase, the escapement wheels are advantageously provided on a support wire, specially adapted to resist very high temperatures. This enables the rotational axis of the wheels to be in a substantially horizontal position.
More details about the application of the first layer are given further in this document.
Step two of the coating process consists in the application of a nanocrystalline diamond layer, while providing an important supply of carbon and boron, in order to get the most advantageous properties. During this step, the sp2 carbon quantity is gradually increased up to substantially 25%. This proportion is based on an estimation made during gaseous phase. The application time is long enough to allow growing a diamond layer of several micrometers: that is to say between one hour to about one hundred hours, and most preferably around ten hours. The application time for the second layer may be shorter than the application time of the first layer.
According to an example concerning escapement wheels and pallets, the following thicknesses are provided:
The nanocrystalline diamond films are produced by a CVD (chemical vapor deposition) process. In the special CVD process (discloses in AT399726B incorporated herein by reference) a carbon containing gas species (for example methane) is thermally activated and is deposited on a substrate as diamond (sp3-hybridised carbon), as graphite (sp2-hybridised carbon) as well as carbonhydrates or other carbon species (mixtures of sp2- and sp3-hybridised carbon). To obtain a pure diamond layer it is necessary to use a second gas: hydrogen. The hydrogen gas (H2) is also thermally activated resulting in mono-atomic hydrogen, where, as an important process step, the efficiency of the activation process is extremely high (more than 50%), preferably more than 75% and achieving in special cases 90% and more. Such a method is described in AT399726B.
With this process, the nanocrystalline diamond coatings 1 (
X-Ray Diffraction—and Atomic Force Microscopy analysis of films obtained by the method disclosed in AT399726B is shown in
In step two, during the growth of the diamond film the process is tuned in a way to achieve a gradual increase of sp2-hybridised carbon content 6 in the sp3-hybridised layer matrix in the vicinity of the surface of a substrate 4, as shown in
The following methods have been demonstrated leading to such a gradual sp2 enrichment (without being limited to these methods):
The solution of the described dust-problem due to electrostatic charging effect can be achieved by increasing the electrical conductivity of the diamond films thereby decreasing the resulting resistivity of the nanocrystalline diamond film down to a few Ohm·cm, and preferentially down to 10-2 Ohm·cm.
A sufficient conductivity of the diamond layer and the change of its surface polarity (hydrophilic/hydrophobic) can be achieved using the following methods or processes:
The ionisation energy of boron is 0.37 eV and thus very low. This allows the generation of a sufficient quantity of the free charge carriers even at room temperature. The availability of free charge carriers (in this case holes) increases the electrical conductivity of the diamond film. The electrostatic charges are thus evacuated to the bulk of the diamond film. The attraction of dust is therefore considerably reduced or totally eliminated. The higher the boron concentration in the reaction chamber, the higher is the conductivity, in the range of 1016-1021 cm-3. The resistivity can decrease down to 10-2 Ohm·cm.
The invention can be used in micromechanical watch movements, in particular for the realisation of escapement wheels and pallets and other friction-relevant systems.
The above detailed description with reference to the drawings illustrates rather than limits the invention. There are numerous alternatives, which fall within the scope of the appended claims. For instance, the invention can also be used to enhance tribological performances in others macroscopic or microscopic mechanisms where at least one part/piece can be coated with diamond. Application examples are Micro-Electro-Mechanical Systems (MEMS), Nano-Electro-Mechanical Systems (NEMS), Electrical motors, in particular micro-motors, pumps, in particular micro-pumps, vacuum systems, static and/or kinetic systems such as engines, etc., without departing from the invention.
The word “comprising” does not exclude the presence of other elements or steps than those listed in a claim. The word “a” or “an” preceding an element or step does not exclude the presence of a plurality of such elements or steps. The mere fact that respective dependent claims define respective additional features, does not exclude a combination of additional features, which corresponds to a combination of dependent claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10191391.1 | Nov 2010 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2011/068371 | 10/20/2011 | WO | 00 | 5/16/2013 |
