Patent Application
20210078039
The invention relates to a method for coating the visible surfaces of motor vehicle wheel rims made of aluminium or steel, in which firstly a polymer base layer (A) is applied to the mechanically processed metallic surface of the rim, said layer compensating for the unevenness of the mechanical processing, following which an intermediate polymer layer (B) is applied to the surface of the polymer base layer (A), then a decorative layer (C) is applied to the surface of the polymer intermediate layer (B), said decorative layer (C) consisting of a heat-cured polymer layer with embedded platelet-shaped metal pigments covering the visible surfaces of the decorative layer (C), and finally the surface of the decorative layer is covered with a polymer top layer (D).
Such a method is known for example from EP 2 123 366 A1.
To the extent that the present patent application refers to polymer coatings or layers, it refers to all paint coatings commonly used in automotive engineering whose physically or chemically curing film forming substances essentially consist of synthetic polymers, as, for example, alkyd resins, acrylic resins, epoxy resins, polyester resins, polyurethane resins, etc.
Another process as described in WO 2017/083730 A1, which is also known from other sources, provides for the metallically shiny decorative layer to be produced by the use of metal vapour in a PVD process. In this method, this metal vapour layer is applied directly to the high-gloss surface of the polymer intermediate layer and finally coated with the polymer top layer. This coating process, which for physical reasons can only be realised in a vacuum at 10-4 to 10-5 mbar, requires complex apparatus in order to produce the vacuum and the metal vapour, so that this coating process is to be viewed extremely expensive. Furthermore, with the coating produced in this manner, there is the additional problem in the event of the polymer top layer (D) being damaged that the decorative layer underneath, which essentially consists only of metal, may caused to be damaged by oxide formation that undermines the polymer top layer (D).
In contrast, WO 2013 041395 A1 discloses a considerably more cost-effective method for producing a shiny metallic rim coating. In all this method, a polymer layer containing platelet-shaped metal pigments (flakes) is applied underneath the polymer top layer said layer being intended to create the metallic lustre. Nevertheless, the visual appearance of the visible surfaces coated in this manner falls far short of the appearance that is achieved by a metallic surface that has been polished. Similar to the method according to EP 2 123 366 A1 mentioned above, this may be due to the fact that the platelet-shaped metal pigments do not align sufficiently parallel to the surface.
In contrast, a very good metallic lustre can be achieved with the electroplating technology that is still the state-of-the-art approach, as described for example in publications DE 102 42 555 A1 or DE 10 2004 006 127 A1. However, as described in these publications, the electrochemical precipitation of metallic particles on the substrate or its coating is problematic in terms of environmental pollution and disposal expenses.
It is therefore the objective of the present invention to further develop the method of the kind first mentioned above in such a way that wheel rims coated according to this method achieve the appearance of polished metal without causing significant additional costs.
To achieve this object, the invention proposes, starting from the method of the type mentioned at the outset, that the polymer intermediate layer (B) is produced with a high-gloss surface with a gloss grade according to DIN67530/ISO2813 of more than 95 and that the decorative layer (C) is applied to the high-gloss surface of the polymer intermediate layer (B) by wet spraying with a maximum thickness of 2 μm and dried there at ambient temperature and, before application of the polymer cover layer (D), is fixed to the polymer intermediate layer (B) by a thermal aftertreatment such that it adheres to the surface with a cross cut tear strength according to DIN EN ISO 2409 from Gt=0 to Gt=2.
The visible surfaces of motor vehicle wheel rims made of aluminium or steel coated in accordance with the teachings of the invention surprisingly achieve, without any additional treatment steps needed, the appearance of polished metallic surfaces consisting of the metal of which the platelet-shaped metallic pigments consist that are used in the decorative layer. As a result, it is easily possible to provide the rims with a selectable metallic appearance, for example the appearance of polished metallic aluminium, polished copper, polished brass or polished stainless steel.
The effect thus achieved as proposed by the present invention is due to the fact that as a result of the high-gloss surface of the polymer intermediate layer, the special application technique (wet spraying process), the minor layer thickness (2 μm), the drying at ambient temperature and the subsequent thermal fixation the platelet-shaped metal pigments contained in the decorative layer (C) are kept parallel to the high-gloss surface of the polymer intermediate layer to such an extent that they remain substantially parallel to this high-gloss surface during the final application of the covering polymer top layer (D) and thus retain the optical impression of a coherent, polished metallic surface. The high cross-cut pull-off strength lends the necessary cohesion to the entire coating system.
It is of special advantage that for the method proposed by the invention no vacuum systems or galvanic baths are needed and that hardly any oxidative damage to the metal pigments is to be feared in the event of the polymer top layer being damaged, because each of them is safely embedded in the polymer of the decorative layer (C).
The thermal fixation of the decorative layer (C) is to be carried out at a minimum temperature of 140° C. Excellent fixation results are achieved if this thermal fixation is performed at temperatures ranging between 180° C. and 200° C. Certainly, at such low temperatures there is no risk of damage to the metal of the wheel rims.
An appropriate further development of the invention provides for additional colour pigments to be added to the decorative layer (C). This enables the metallically shining look of the coating surface to be further enhanced with additional colour nuances suited to complement the visual impression in a special way.
The impression of a polished metal surface is even perfected if appropriate measures are taken to the effect that the area of the decorative layer (C) which is covered by the platelet-shaped metallic pigments is absolutely gapless. To achieve this, it is expedient if the summarized surfaces of the platelet-shaped metal pigments contained in the decorative layer (C) that the observer looks at are at least by a factor of 3 larger than the surface of the decorative layer (C). This can be accomplished by introducing a sufficient amount of the platelet-shaped metal pigments into the film forming material of the decorative layer (C).
An embodiment example of the invention is explained in more detail hereinafter on the basis of the drawing in which a section through an inventive coating system is illustrated.
In the FIGURE, the substrate to be coated, in this case a motor vehicle wheel rim made of aluminium or steel, is marked with the reference letter S.
For the purpose of implementing the method proposed by the present invention, the surface of this substrate S to be coated is first treated by means of the usual mechanical processes, i.e. smoothed and cleaned to the extent possible.
Following this, a polymer primer layer A is applied to this surface of the substrate—with or without chemical pre-treatment—by adopting customarily known methods, said layer compensating for any unevenness the mechanical processing may have caused. This polymer primer layer A contains a sufficient amount of fillers to even out any coarse unevenness in the metallic surface of the substrate.
Subsequently, a high-gloss powder coating is applied to the surface of this polymer primer layer A which forms polymer intermediate layer B, said powder coating being described for instance in publication DE 31 43 060 C2. It is of major significance that the surface of this polymer intermediate layer B really has high-gloss characteristics, i.e. features a gloss level of more than 95 according to DIN 67530/150 2813. Basically, such high-gloss surfaces can be brought about by adopting various paint systems. For the method proposed by the invention, a PU powder coating system is preferably adopted for the polymer intermediate layer B.
A decorative layer C is subsequently applied to the polymer intermediate layer B, the film forming material of which is a thermally curable polymer that, for decorative purposes, contains platelet-shaped metal pigments, so-called flakes, said pigments covering the visible surface of the decorative layer C. This decorative layer C is applied to the high-gloss surface of polymer intermediate layer B by wet spraying at a maximum film thickness of 2 μm and consists of a coating compound which at this film thickness dries at an ambient temperature of between 15° C. and 25° C. in less than 10 seconds. After drying and by heating to a minimum temperature of 140° C., preferably of between 180° C. and 200° C., this coating compound is applied onto the high-gloss surface of the polymer intermediate layer B in such a way that a cross-cut pull-off strength of Gt=0 to Gt=2 as per DIN EN ISO 2409 specification is achieved on the surface of the polymer intermediate layer B.
Various kinds of coating compounds having these physical properties are available on the market.
The platelet-shaped metal pigments contained in the very thin decorative layer C as provided by the invention, are oriented in the inventive method substantially parallel to the high-gloss surface of the polymer intermediate layer B and in this manner create the visual impression of a coherent, polished metallic surface. As a result of the decorative layer C having been additionally applied onto the high-gloss surface of the polymer intermediate layer by the heating process explained hereinbefore, this orientation is retained even after the polymer top layer D has finally been applied.
The impression of a coherent polished metallic surface is considered to be optimal when the sum of the surfaces of the platelet-shaped metallic pigments contained in decorative layer C that the observer looks at is at least three times larger than the surface of decorative layer C.
In the event further decorative colour effects are desired, additional colour pigments can be added to the film forming material of decorative layer C.
The finally applied polymer top layer D possesses the usual properties of such coating systems and protects the entire coating including the coated substrate against mechanical damage such as stone chipping or the like.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2017 129 434.1 | Dec 2017 | DE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2018/084268 | 12/11/2018 | WO | 00 |
