Claims
- 1. A method of coating a substrate with a wet or moist surface including a surface immersed under water, comprising the steps of:
- a. thoroughly mixing, to provide a non-aqueous coating composition:
- A. an epoxy resin consisting of a polyepoxide having a plurality of vic-epoxy groups and containing only members of the group consisting of carbon, hydrogen, oxygen and chlorine, and
- B. a stoichiometric amount of an amine curing agent which is substantially insoluble in water and not water-sensitive and chosen from the group consisting of
- 1. an amine of the formula ##STR8## where R.sub.1 is chosen from the group consisting of ether radicals of which one of the alkyl or alkylene radicals has at least eight carbon atoms, and
- 2.
- 2. a condensation product of a small proportion of a polyepoxide having a plurality of vic-epoxy groups and containing only members of the group consisting of C, H, O, and Cl, and a large proportion of a fatty amine of the formula: ##STR9## where R.sub.2 is chosen from the group consisting of alkyl radicals having at least eight carbon atoms and ether radicals of which one of the alkyl or alkylene radicals has at least eight carbon atoms,
- b. applying said coating composition to said surface, and
- c. leaving alone said surface with the applied coating composition until it
- cures. 2. The method of claim 1 wherein the curing takes a time between 1 and 15 hours at room temperature for the coating to start hardening and between 5 and 20 hours at room temperature to cure substantially fully.
- 3. The method of claim 1 in which the amine curing agent (B) consists of a condensation product of 3 parts by weight of an amine with said formula R.sub.2 --NH--CH.sub.2 --CH.sub.2 --CH.sub.2 --NH.sub.2, and 1 part by weight of epoxy resin, with an equivalent weight per epoxy-unit of about 180.
- 4. The method of claim 3 wherein the curing agent (B) is prepared by heating a mixture of the amine and epoxy resin for about one hour to about 100.degree. C. and cooling the resulting product for about 15 hours.
- 5. The method of claim 1 wherein the amine curing agent (B) is a condensation product of 70 parts by weight of N-oleyl propylene diamine and 30 parts by weight of an epoxy resin with an average molecular weight of about 575.
- 6. The method of claim 5 wherein the curing agent (B) is prepared by heating a mixture of the amine and epoxy resin for two hours at 100.degree. C., and then cooling the resulting product to room temperature.
- 7. The method of claim 1 wherein the amine curing agent (B) comprises a condensation product of
- 2 parts N-tall oil fatty acid derived propylene diamine wherein R is a mixture of C.sub.18 H.sub.33 and C.sub.18 H.sub.31, and
- 1 part said polyepoxide.
- 8. The method of claim 1 wherein part (A) consists of:
- 80 parts of weight of a low-molecular weight epoxy resin containing 11% butyl glycidyl ether, and
- wherein part (B) consists of 180 parts by weight of
- 76parts of the reaction product of 70% N-oleyl propylene diamine and 30% polyepoxide,
- 76 parts calcium carbonate,
- 14 parts asbestos fiber, and
- 14 parts titanium dioxide pigment.
- 9. The method of claim 1 in which the polyepoxide of part (A) is mixed with a glycol before adding the amine curing agent (B) in order to obtain a faster curing process and a better brushing resistance.
- 10. The method of claim 9, in which the glycol is propylene glycol.
- 11. A method as in claim 1 wherein said amine curing agent is chosen from the group consisting of: N-tall oil fatty acid-propylene diamine, N-oleyl propylene diamine, and tridecylproplether propylene amine.
- 12. A method of caulking wet or damp masonry, comprising
- blending 80 parts (A) comprising a low molecular weight polyepoxide having at least two vic-epoxy groups and containing only members of the group consisting of C, H, O, and Cl, with
- 100 parts (B) consisting essentially of
- 500 parts of a reaction product between
- 70% N-oleyl propylene diamine and 30% said polyepoxide,
- 500 parts calcium carbonate,
- 90 parts asbestos fiber,
- 90 parts titanium dioxide pigment,
- and forcing the mixture before it cures into the areas to be caulked.
- 13. A method of coating a structural material with a wet or moist surface including a surface immersed under water, comprising the steps of:
- a. thoroughly mixing, to provide a non-aqueous coating composition:
- A. an epoxy resin consisting of a polyepoxide having a plurality of vic-epoxy groups and containing only members of the group consisting of carbon, hydrogen, oxygen and chlorine, and
- B. a stoichiometric amount of an amine curing agent which is substantially insoluble in water and not water-sensitive and chosen from the group consisting of
- 1. an amine of the formula ##STR10## where R.sub.1 is chosen from the group consisting of ether radicals of which one of the alkyl or alkylene radicals has at least eight carbon atoms, and
- 2. a condensation product of a small proportion of a polyepoxide having a plurality of vic-epoxy groups and containing only members of the group consisting of C, H, O, and Cl, and a large proportion of a fatty amine of the formula: ##STR11## where R.sub.2 is chosen from the group consisting of alkyl radicals having at least eight carbon atoms and ether radicals of which one of the alkyl or alkylene radicals has at least eight carbon atoms,
- b. applying said coating composition to said surface, and
- c. leaving alone said surface with the applied coating composition until it cures.
- 14. A method of coating a structural material chosen from the group consisting of metal, wood, masonry, brick, porous ceramic building brick and concrete and having a wet or moist surface including a surface immersed under water, comprising the steps of:
- a. thoroughly mixing, to provide a non-aqueous coating composition:
- A. an epoxy resin consisting of a polyepoxide having a plurality of vic-epoxy groups and containing only members of the group consisting of carbon, hydrogen, oxygen and chlorine, and
- B. a stoichiometric amount of an amine curing agent which is substantially insoluble in water and not water-sensitive and chosen from the group consisting of
- 1. an amine of the formula ##STR12## where R.sub.1 is chosen from the group consisting of ether radicals of which one of the alkyl or alkylene radicals has at least eight carbon atoms, and
- 2. a condensation product of a small proportion of a polyepoxide having a plurality of vic-epoxy groups and containing only members of the group consisting of C, H, O, and Cl, and a large proportion of a fatty amine of the formula: ##STR13## where R.sub.2 is chosen from the group consisting of alkyl radicals having at least eight carbon atoms and ether radicals of which one of the alkyl or alkylene radicals has at least eight carbon atoms,
- b. applying said coating composition to said surface, and
- c. leaving alone said surface with the applied coating composition until it cures.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation of Ser. No. 408,454 filed Oct. 23, 1973 and now abandoned, which was a division of application Ser. No. 196,778, filed Nov. 8, 1971, which was a continuation-in-part of application Ser. No. 157,638, filed June 28, 1971 and now abandoned.
US Referenced Citations (4)
Foreign Referenced Citations (3)
Number |
Date |
Country |
455,105 |
Aug 1965 |
CH |
806,196 |
Dec 1958 |
UK |
1,216,136 |
Dec 1970 |
UK |
Divisions (1)
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Number |
Date |
Country |
Parent |
196778 |
Nov 1971 |
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Continuations (1)
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Number |
Date |
Country |
Parent |
408454 |
Oct 1973 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
157638 |
Jun 1971 |
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