Patent Application
20170335471
This invention relates to methods and devices for generation of hydrogen peroxide (H2O2) suitable for industrial and domestic applications.
WO/2016/103246 discloses method and device for generation of hydrogen peroxide which operate on the principle of conversion of water vapor to hydrogen peroxide by conveying the vapor through the corona discharge zone generated between a rotating electrode formed as a hollow rotor of a centrifugal fan and a fixed electrode. WO/2016/103246 does not relate to the manner of conversion of water into vapor, which is assumed to occur external to the device, electrically and mechanically independent thereof. The need for an external and independent source of water vapor increases costs.
Furthermore, the device disclosed in WO/2016/103246 requires the use of an air capacitor for conveying high voltage AC from a stationary power source to the rotating electrode. This complicates the construction and imposes limitations on the frequency of the high voltage AC source, which should exceed 30 kHz.
An object of the invention is to simplify and reduce the cost of a device for converting water to hydrogen peroxide.
This object is achieved through the use of a rotating electrode formed as a hollow rotor for conversion of water into vapor just before delivering it to the corona discharge zone generated between the rotating and fixed electrodes when high AC voltage is applied to them from a stationary power source.
To this end, the rotating electrode is positioned inside a fixed electrode at a specified distance from the insulation layer thereof, and water is fed from a reservoir to the rotating electrode cavity. As a result, water is converted to vapor due to water encountering the electrode rotating at a high speed which is brought to the corona discharge zone by the centrifugal force generated by the electrode.
In order to feed water from the reservoir to the rotating electrode cavity, there is provided a channel having a lower end located in the water reservoir and an upper end in the rotating electrode cavity. The water level in the channel is raised by a rotating screw thread mounted inside the channel on the lower end of the rotating electrode.
Such an arrangement obviates the need for a separate water to vapor converter. Furthermore, converting water to vapor immediately prior to conveying the vapor through the corona discharge zone serves to cool the electrodes by 2 to 5° C. owing to the water to vapor conversion which is an adiabatic process. In addition such an arrangement allows high voltage from a stationary AC power source to be fed directly to the rotating electrode without the need for an air capacitor owing to electrolysis of the water between the water feeding channel and the rotating electrode, which greatly increases the water conductivity and thereby enables high voltage from the AC high voltage source to be conducted through the water feeding channel to the rotating electrode. This requires forming the rotating electrode and the water feeding channel from electrically conductive materials.
The proposed method for conversion of water into hydrogen peroxide is much simpler and cheaper because of a number of multi-functional elements used for its implementation. Thus, the rotating electrode in addition to functioning as one of the electrodes generating the corona discharge zone also performs the water to vapor conversion. Likewise, the water feeding channel in addition to feeding water to the rotating electrode serves for high AC voltage transmission from a stationary power source to the rotating electrode.
A device realizing the proposed method comprises an AC high voltage power source with high and low voltage output terminals and a split housing, an upper section of which accommodates the following elements: a motor with power supply terminals and a shaft, and a rotating electrode formed as a hollow rotor of a centrifugal fan that is mounted on a shaft with a helical spiral wound around its lower end.
Furthermore, the upper section of the housing contains a fixed electrode with an insulation layer and a hydrogen peroxide reservoir and an opening for removing peroxide from the device. The lower section of the housing contains a water reservoir with a water-feeding opening and a channel for water transfer from the lower section of the housing to the upper section of the housing. The rotating electrode shaft with the surrounding helical spiral is located inside the channel.
In order to understand the invention and to see how it may be carried out in practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
Referring to the figures there is shown a device 10 according to an embodiment of the invention for converting water to H2O2. The device 10 includes a split housing 11 containing at an upper end an electric motor 12 having power supply terminals 13 and a motor shaft 14 that is connected to an electrode shaft 15 rotatably mounted within the housing and which supports a rotating annular electrode 16 formed as a hollow rotor of a centrifugal fan having a cavity 17 and fan blades 18 (see
The device 10 operates as follows: water 25 is fed to the reservoir 24 via the inlet 26, so that the water level in the reservoir 24 is lower than the level at the bottom of the hydrogen peroxide reservoir 30. Power is fed to the motor 12 from an external low voltage supply (not shown) and the AC high voltage power source 22 is connected between the fixed electrode 19 and the water supply channel 27 via the power supply terminals 23′ and 23″, respectively. Corona discharge is generated in the gap 21 between the rotating electrode 16 and the insulation layer 20 of the fixed electrode 19. The gap 21 thus constitutes a corona discharge zone. At the same time, owing to the presence of the helical spiral 29, water in the reservoir 24 is elevated to the upper level of the cavity 17 in the rotating electrode 16 via the opening 28 in the water supply channel 27 and is converted to vapor in a zone 33 toward the top of the cavity 17. The liquid to vapor conversion causes a drop in vapor temperature, which is used to cool the electrodes during the vapor transmission through the corona discharge zone.
The vapor is delivered to the corona discharge zone within the gap 21 by the centrifugal force created by the rotating electrode 16, where it is converted to hydrogen peroxide during high-energy electrolysis. This can be seen from
A thin film of hydrogen peroxide is formed on the insulation layer 20, and rotates in a descending spiral until it escapes the corona discharge zone in the gap 21 whereupon the film of hydrogen peroxide is gradually destroyed and turns into droplets of hydrogen peroxide drops, which fall into the reservoir 30. The generated hydrogen peroxide is removed from the reservoir 30 to outside the device via the outlet 32.
It will be understood that prior to corona discharge between the fixed electrode 19 and the rotating electrode 16, the water supply channel 27 is at ground potential as is the rotating electrode 16. Application of high voltage AC between the fixed electrode 19 and the rotating electrode 16 raises the voltage on the rotating electrode 16 relative to the water supply channel 27 owing to the corona discharge which conveys charge from the fixed electrode 19 to the rotating electrode 16. Since the rotating electrode 16 is fixed to the shaft 15, which is itself formed of electrically conductive material, there is formed a potential difference between the electrode shaft 15 and the channel 27, which remains at ground potential. This potential difference induces electrolysis of the water inside the channel 27, with the result that the electrical conductivity of the water in the channel greatly increases by a factor of several thousand and provides a low-resistance contact between the water supply channel 27 and the shaft 15 of the rotating electrode 16. This low-resistance contact enables high voltage from the AC high voltage source 22 to be conducted through the channel to the rotating electrode.
This low-resistance contact does not depend on any of: the current frequency of the corona discharge; the polarity of the power source 22; the frequency of rotation of the shaft 15 in the channel 27; or the water temperature. Therefore the proposed method is simpler and more efficient than methods previously used to provide an electrical contact between stationary and rotating elements.
The water consumption determined by the volumetric rate at which water is fed to the rotating electrode 16 depends on the rotational velocity of the electrode shaft 15, the length and pitch of the helical spiral 29 and the water level in the reservoir 24. All the parameters that determine the water consumption in the reservoir 24 are determined experimentally to ensure that the water level in the reservoir 24 are maintained constant during operation of the device, this being determined, for example, by means of an external dosage meter operating in a continuous or pulsed mode.
Hydrogen peroxide can be removed through the outlet 32 either continuously or periodically depending on the volume of the hydrogen peroxide collection reservoir 30. Since the housing 11 does not have air inlets and outlets, any ozone that is produced together with the hydrogen peroxide in the corona discharge zone in the gap 21 circulates inside the housing 11 without being released to the environment.
The inventor has constructed a pilot conversion device with the following parameters:
| Number | Date | Country | Kind |
|---|---|---|---|
| 245718 | May 2016 | IL | national |
