The present invention relates to a method for extraction of sugar from a sugar containing biomass.
In conventional methods for extraction of sugar from sugar containing raw material, e.g. sugar-beets, in a sugar refinery plant, the raw material is first pre-treated by washing and elimination of stones, gravel, tops and other undesirable material and by cutting of said raw material into chips or cassettes, i.e. pieces having a shape and size similar to French fries. This is followed by boiling of the chips in large amounts of water with a view to releasing the sugar in the sugar-beets, and by compression with a view to extracting or leaching out as much sugar as possible from the sugar containing raw material.
In a conventional method for production of granulated and powdered sugar from sugar-beets, the sugar-beets are initially pre-treated as described above.
The sugar-beet chips are then fed to an extraction tower to which hot water is added, whereby sugar is extracted from the sugar-beet chips and is separated in a sugar containing solution.
The sugar-beet pulp from which sugar has been extracted is then compressed with a view to reducing the water content thereof. This compressed sugar-beet pulp may then be marketed as a dry fodder or may be dried together with molasses to a product called “betfor” (a Swedish term for dried beet with molasses), a more high-grade fodder product.
The sugar containing solution, i.e. the raw juice, extracted from the sugar-beet chips is purified by treatment with lime and CO2. The precipitation obtained is then separated by filtration and may be used as a soil enhancing product. The purified raw juice, i.e. the “thin juice”, is concentrated by evaporation several times to a “thick juice” which then is cooked in three boiling steps until it is so concentrated that all sugar becomes crystallised.
The sugar concentrate is added in the first boiling step to an intermediate container (maisch), in which further crystallization takes place, followed by a centrifugation step. After the centrifugation of the sugar containing solution from the first boiling step, the separated sugar is fed to a sugar dryer for production of granulated sugar. From the remaining sugar juice from the centrifugation step of the first boiling step, sugar is extracted in two further boiling steps, each involving crystallization and centrifugation. The extracted sugar obtained in the second and the third boiling step is then again added to the first boiling step for further purification. The rest product from the third boiling step, i.e. molasses, may be marketed as a fodder or is refined to “betfor”.
Depending on the quality and type of sugar-beets, normally about 17-18% sugar can be extracted from sugar-beets, which normally have a sugar content of 15-20% by weight. The methods for extraction of sugar from other sugar containing raw material than sugar-beets follow the same principles as stated above. However, one common characteristic is that all such sugar extraction methods hitherto known are operated at underpressure during the boiling steps. Further, conventional methods for sugar extraction, e.g. for production of granulated sugar, are rather energy consuming, require addition of several additives, require a lot of process equipment and involve a risk of contamination with microbes or bacteria in the process system, thus jeopardizing the quality of the fodder by-products obtained.
Thus, there is a need for an improved method for extraction of sugar from sugar containing raw material, e.g. sugar-beets or other sugar containing crops, which reduces or eliminates the above-mentioned drawbacks, while still allowing at least the same or essentially the same degree of sugar extraction.
The object of the present invention is to reduce or eliminate the above-mentioned problems experienced in connection with known techniques for extraction of sugar from a sugar containing biomass or raw material.
This object has been achieved with a method for extraction of sugar from a sugar containing biomass, wherein the sugar containing biomass
In one embodiment of said method, the steam treated sugar containing biomass fed to the central part (7) of the extraction device (1) is subjected to
The present invention will be described below with reference to
In the method according to the present invention the sugar containing biomass or raw material is introduced in an extraction device 1 in which the extraction of the sugar is to take place.
The terms “sugar containing biomass” and “sugar containing raw material” used throughout the present application are intended to mean any form, e.g. cut or decomposed to chips, cossettes, slices or other forms, of a natural product or crop from which sugar can be extracted and is of interest to extract, e.g. root vegetables, fruits, pot-herbs, or other sugar containing crops of any origin in the world. Particular examples of sugar containing raw materials are sugar-beets (Beta vulgaris), sugar canes, beetroots, fodder beets, bananas, and pineapples. The sugar containing biomass may also be a mixture of two or more of these sugar containing crops prepared in any form, and may also be included in a medium containing other ingredients, e.g. additives for dissolution or homogenisation of the original crop.
The term “sugar” used throughout the present application is intended to mean essentially the carbohydrate sucrose, which is useful as additive in e.g. food, but also includes other carbohydrates, such as glucose, and fructose, as well as mixtures thereof, useful for different applications. The term “cane sugar” is also intended to fall within the definition of the word “sugar”.
The sugar containing biomass introduced in the extraction device 1 may first be pre-treated in a conventional way, as initially described. As to sugar-beets, they are initially evaluated and tested as to quality, added to open containers filled with water (“svämmor”) in order to dissolve soil, tops are eliminated, and washing steps are normally performed, optionally also homogenisation and dissolution steps. With a view to facilitating the sugar extraction, the sugar-beets are normally cut into pieces, preferably chips or cossettes, having a size and a shape similar to that of food chips or French fries.
The sugar containing biomass, such as sugar-beets, is added to the extraction device 1 in a conventional way. In one embodiment chips of sugar-beets are fed to an inlet of the extraction device 1, e.g. on a conventional conveyor belt. As the interior of the extraction device 1 has to be maintained at overpressure throughout the sugar extraction method according to the present invention, the inlet of the extraction device 1 is provided with an inlet sluice valve device 2, which allows the feeding of the sugar containing biomass into the extraction device 1 while maintaining the overpressure in the extraction device 1. The inlet sluice valve device 2 may be any conventional sluice valve device having the above-mentioned feeding and sealing function. In one embodiment, which is shown in
When the sugar containing biomass has been introduced in the extraction device 1 through the inlet sluice valve device 2, it is subjected to treatment with steam having a temperature of 103-124° C., preferably 109-120° C., wherein the cell walls of the sugar containing biomass collapses due to this chock heating. Due to the cell wall collapse, the sugar molecules within the cells become available. The chips of the sugar containing biomass normally contain in the case of sugar-beets 75-78% by weight of water, 17-18% by weight of sugar, and about 5% by weight of fibres, proteins, etc. The water steam is introduced into the extraction device 1 through one or more steam nozzles 3. Said chips may be treated with the steam when they are fed on a web 8 collecting the chips introduced into the extraction device 1. Said web 8 may be arranged in connection with the inlet part of the extraction device 1 in such a way that the chips are falling or sliding down onto the start end of said web 8. In the embodiment shown in
The overpressure in the extraction device 1 is obtained due to the steam introduced through the steam nozzles 3, optionally supported with compressed air through nozzles therefor, if needed. The overpressure in the extraction device 1 is 0.2-1.5 bar, preferably 0.4-1.2 bar, compared to the surrounding atmospheric pressure, i.e. an absolute pressure of 1.2-2.5 bar, preferably 1.4-2.2 bar. These overpressure ranges correspond to the steam temperature ranges of 103-124° C., and 109-120° C., respectively. The number of steam nozzles 3, the positioning thereof in relation to the web 8 (i.e. the arrangement close to the web 8) supporting or feeding the bed of chips, and the amount of steam sprayed on the bed of chips through said steam nozzles 3, are not critical as long as a satisfactory degree of collapse of the cell walls of the sugar containing biomass is obtained and the overpressure required is attained and maintained. However, in the embodiment shown in
The overpressure in the extraction device may be monitored by one or more sensors during the sugar extraction method, and if the overpressure would reach a maximum of 1.5 bar during a normal operation according to the invention, the sensor/sensors instruct/s one or more pressure regulation valves to regulate the pressure. Any conventional pressure sensoring and regulating equipment may be used and may be located anywhere in the sugar extraction device. Alternatively, a simple mechanical pressure regulating valve may be used, as well as a valve device having both the pressure sensoring and regulating functions.
In the central part 7 of the extraction device 1 the chips of sugar containing biomass, which has been subjected to steam treatment thereby inducing cell collapse, are then subjected to a first hot water treatment step.
At the outlet of the channel surrounding the web 8 and at the inlet of the central part 7 of the extraction device 1 the chips of steam treated sugar containing biomass in the embodiment shown in
In the embodiment shown in
Thereafter, the compressed bed of sugar containing biomass is subjected to a further treatment with hot water with hot water nozzles 11 in a second hot water treatment step, e.g. under the same conditions as in the above-mentioned first hot water treatment step. The nozzles 9 and 11 used in the two hot water treatment steps, respectively, may be any conventional nozzles of the same or different types. The number of nozzles, the positioning thereof (i.e. the arrangement close to the transport device 4) and the amount of hot water added, are not critical as long as satisfactory extraction of sugar during the hot water treatment steps is obtained. In the embodiment shown in
Then the bed of sugar containing biomass, which has been subjected to a first and a second hot water treatment step and an intermediate compression step, is subjected to a hard compression step by the use of a compression device 6, e.g. a roller press or a belt press containing one or more rolls with a view to extracting further sugar from the bed of sugar containing biomass. The compression force in the hard compression step is higher compared to the compression force in the intermediate compression step. The sugar containing solution obtained from this hard compression step, which is flowing downwardly from the compression device 6 towards the bottom of the extraction device 1, is also collected from the extraction device 1, e.g. in the same way as for the sugar containing solution from the first and the second hot water treatment step and the intermediate compression step, respectively. In the embodiment shown in
Then the sugar containing biomass, from which sugar has been extracted in the preceding steps, is subjected to a final compression step by the use of a final compression device 12, such as a continuous screw press, e.g. a so-called hydropress. This step is conventional and extracts the final part of sugar from the sugar containing biomass. Further, the final compression device 12 also acts as a pressure guard in the outlet end of the extraction device 1, thereby maintaining the overpressure therein. The sugar containing solution extracted from the screw press 12, as appears from the embodiment shown in
Further, as shown in
The dimensions of the extraction device 1 and the devices belonging thereto and included therein are not critical and may be adapted in accordance with the process conditions desired. In the embodiment shown in
It could also be added that the second hot water treatment step may be followed by one or more further hot water treatment steps, optionally also by one or more further compression steps in addition to those disclosed above
The concentration of sugar in the sugar containing solution obtained from the method depends on the original sugar content of the original sugar containing raw material or biomass and may vary in view of the type of sugar containing raw material or biomass and also from year to year. For sugar-beets, normally having a sugar content of 16-18% by weight, a sugar containing solution having a sugar content of 14-15% may be obtained, e.g. 14.5%.
The total process feed rate from the input to the inlet sluice valve device 2 to the outlet of the final compression device 12 in the extraction device 1, is 20-60 tons of sugar containing biomass per hour, preferably 35-40 tons per hour. The total process time for the inventive method is normally 1-10 min, preferably 3-6 min. The speed of the transport device 4 is not critical and depends on the type of biomass to feed and the feed rate used.
The advantage of the present invention compared to prior art is that the same amount of sugar may be extracted from the sugar containing biomass, but at a reduced energy consumption (up to 70% reduction). Another advantage is that the process may be performed completely continuously at overpressure due to the inlet sluice valve device 2. Further, equipment such as specific boiling tanks and subsequent separation devices, as well as certain additives, e.g. lime, are not required in the process according to the present invention. The conveyor belt used as a transport device 4 also acts a process surface making the sugar containing biomass more available for treatment compared to known techniques.
Another advantage of the inventive process is that the total process time is reduced, as the release of sugar from the sugar containing total biomass is much quicker than in prior art techniques. The heat treatment at overpressure also kills any contaminating microbes or sporulating bacteria in the process system, thereby increasing the hygienic safety for the beet pulp by-product intended for use as a fodder. Further, the amount of water added to the sugar extraction process may be largely reduced with more than 50% compared to prior art, as the present inventor has taken advantage of the high water content in the sugar containing raw material as such.
With reference to
Experiments have been performed in an extraction device essentially constructed as the extraction device 1 in
About 50 experiments have been performed with slight variations of the overpressure, temperature and time parameters, however, within the ranges defined in claim 1, and the results defined above have been obtained in each experiment.
Number | Date | Country | Kind |
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0701375-8 | Jun 2007 | SE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/SE2008/050636 | 5/30/2008 | WO | 00 | 10/28/2010 |