The present invention relates to a method for fabricating a semiconductor optical device. This application claims the benefit of priority from Japanese Patent Application No. 2017-160145 filed on Aug. 23, 2017, which is herein incorporated by reference in its entirety.
Japanese Unexamined Patent Application Publication No. 2012-43928, referred to as Patent Document 1, discloses a plasma processing method and a plasma processing apparatus. Japanese Unexamined Patent Application Publication No. 2007-201404, referred to as Patent Document 2, discloses a plasma processing method and a plasma processing apparatus.
A method for fabricating a semiconductor optical device according to one aspect of the present invention: preparing a product having a supporting base with a top face and a back face, a semiconductor product mounted on the top face, and an adhesive film including a pressure sensitive material, the adhesive film being between the semiconductor product and the supporting base in the product, and the semiconductor product including a semiconductor laminate and a patterned resist layer on the semiconductor laminate; applying force to the product to produce an intermediate product from the product, the adhesive film bonding the semiconductor product and the top face of the supporting base to each other; disposing the intermediate product on a stage of an etching apparatus; and etching the semiconductor product in the intermediate product with the patterned resist layer in the etching apparatus while the semiconductor product being cooled through the stage.
The above-described objects and the other objects, features, and advantages of the present invention become more apparent from the following detailed description of the preferred embodiments of the present invention proceeding with reference to the attached drawings.
A substrate is bonded to a tray with a heat-peelable adhesive film which has a base sheet and two adhesive layers on respective sides of the base sheet. The substrate and the tray thus bonded to each other are loaded to a plasma-processing apparatus to dispose them on the table thereof. The plasma-processing apparatus processes the surface of the substrate on the tray with plasma. This plasma treatment is followed by separating the substrate away from the tray by heating the tray.
Specifically, fabricating a semiconductor optical device includes growing a semiconductor laminate on a wafer to form the substrate, and processing the semiconductor laminate with a mask by plasma etching, such as reactive ion etching. The reactive ion etching uses ion species in the plasma that collide with the surface of the semiconductor laminate in the reaction chamber. The collision of the ion species enables both sputtering and chemical reaction of the semiconductor laminate, resulting in etching the semiconductor laminate.
The plasma etching also heats the semiconductor laminate to raise the temperature thereof. A too high temperature may deteriorate resist of the mask. In order to dissipate the heat through the tray, the plasma-processing apparatus cools the tray during the plasma etching.
Some of the semiconductor laminates on the wafers, which are thus etched while the tray is cooled, are defective because of deterioration of their resist masks. The inventor's teachings reveal that the deterioration of resist may be caused by temperature rise of the semiconductor laminate. What is needed is to reduce the temperature rise of the resist mask during the plasma etching. The insufficient cooling of the wafer may be associated with loose contact between the heat-peelable adhesive film and the tray and wafer. The loose contact therebetween prevents the wafer from being sufficiently cooled through the tray, so that the poor heat dissipation raises the temperature of the wafer, resulting in deteriorating the resist of the mask. The mask of deteriorated resist cannot overcome the bombardment of ions and particles in the plasma, and makes the etched product defective, leading to reduction in production yield.
In etching the semiconductor laminate on the wafer that is attached to the tray through the heat-peelable adhesive film, the wafer may be peeled off from the tray during the plasma etching. The inventor's findings reveal that there are voids at the interfaces between the heat-peelable adhesive film and the tray and wafer, so that the wafer that is peeled from the tray is not firmly attached to the tray with the heat-peelable adhesive film. These voids may reduce the heat transfer. What is needed is to bring the wafer into close contact with the tray for plasma etching.
It is an object of one aspect of the present invention to provide a method for fabricating a semiconductor optical device that can allows a close contact between the tray for plasma etching and a product to be etched.
A description will be given of embodiments according to the above aspect.
A method for fabricating a semiconductor optical device according to an embodiment: (a) preparing a product having a supporting base with a top face and a back face, a semiconductor product mounted on the top face, and an adhesive film including a pressure sensitive material, the adhesive film being between the semiconductor product and the supporting base in the product, and the semiconductor product including a semiconductor laminate and a patterned resist layer on the semiconductor laminate; (b) applying force to the product to produce an intermediate product from the product, the adhesive film bonding the semiconductor product and the top face of the supporting base to each other; (c) disposing the intermediate product on a stage of an etching apparatus; and (d) etching the semiconductor product in the intermediate product with the patterned resist layer in the etching apparatus while the semiconductor product being cooled through the stage.
The fabricating method uses a film containing pressure sensitive material disposed between the tray and the wafer. The pressure sensitive film changes its color in response to a pressure applied thereto. Applying a pressing force between the wafer and the tray causes non-uniform discoloration of the pressure sensitive film over the surface of the wafer. The variation in discoloration of the pressure sensitive film shows a variation in contact between the tray and the wafer. The discoloration can be observed through the back side of the tray, and this observation can determine that the pressing force has changed the pressure sensitive film in color to a desired level, whereby the pressing step brings the intermediate product to completion. The intermediate product allows the heat, applied to the epitaxial wafer during plasma etching, to dissipate through the tray.
In the determining step of the above fabricating method, the ratio of the discolored area, which indicates change in color in the pressure sensitive film, to the predetermined area of the pressure sensitive film reaches or exceeds the predetermined ratio. This makes it possible to judge whether the wafer uniformly adheres to the tray over the wafer. Specifically, imaging the back face of the pressure sensitive film through the other side of the tray allows the observation of the discolored area of the pressure sensitive film, and this observation with the images allows the judgment of the completion of the intermediate product in view of uniformity in the discoloration with a computer.
In the preparation step of the fabricating method, the wafer may adhere to the pressure sensitive film with a double-sided adhesive film having a heat-peelable adhesive on the face to which the wafer adheres. This heat-peelable adhesive easily can separate the tray and the pressure sensitive film from the wafer after the plasma etching.
In the preparation step of the above fabricating method, the pressure sensitive film may adhere to the tray with another double-sided adhesive film having a heat peelable adhesive on the face to which the tray adheres. This heat-peelable adhesive ensures the separation of the tray and the pressure sensitive film from the wafer after the plasma etching.
In the above fabricating method, the semiconductor optical device may include a vertical cavity surface emitting laser (abbreviated as VCSEL). Fabricating the VCSEL excludes using both wet etching with hydrofluoric acid and dry etching with a fluorocarbon gas, so that a silicon oxide film or a silicon nitride film cannot be used as an etching mask. The etching mask in fabrication of the VCSEL includes resist. Using the resist mask in the fabricating method is particularly effective in fabricating the VCSEL.
In the method according to and embodiment, the stage of the etching apparatus is coupled to a cooler, and the stage is in contact with the back face of the supporting member.
In the method according to and embodiment, etching apparatus processes the semiconductor product by plasma-etching.
In the method according to and embodiment, the adhesive film has a heat-peelable adhesive sheet between the semiconductor product and the top face of the supporting base.
In the method according to and embodiment, the adhesive film has a heat-peelable adhesive sheet between the supporting base and the semiconductor product.
In the method according to and embodiment, the adhesive film has a first heat-peelable adhesive sheet between the adhesive film and the top face of the supporting base, and a second heat-peelable adhesive sheet between the adhesive film and the semiconductor product.
In the method according to and embodiment, the semiconductor product includes semiconductor layers for an upper distributed Bragg reflector, an active layer and a lower distributed Bragg reflector.
In the method according to and embodiment, the semiconductor optical device includes a vertical cavity surface emitting laser, and the patterned resist layer defines a mesa shape for the vertical cavity surface emitting laser.
In the method according to and embodiment, the supporting base is made of quartz glass.
In the method according to and embodiment, applying force to the product includes disposing an O-ring on the patterned resist layer, disposing a lid on the O-ring and the patterned resist layer to form a hermetically sealed cavity, and depressurizing the hermetically sealed cavity to apply the force to the intermediate product while illuminating the back face with rays of light.
The teachings of the present invention can be readily understood by considering the following detailed description with reference to the accompanying drawings shown as examples.
Referring to the accompanying drawings, embodiments according to a method for fabricating a semiconductor optical device will be illustrated below. When possible, the same portions will be denoted by the same reference numerals.
The semiconductor base 2 can be a group III-V semiconductor substrate, for example, an i- or n-type GaAs substrate. The semiconductor base 2 includes an n-type semiconductor, which is doped with n-type dopant, such as Te (tellurium) and Si (silicon). Group III-V semiconductor includes one or more group III elements, such as Al (aluminum), Ga (gallium) and In (indium), and one or more group V elements, such as As (arsenic) and Sb (antimony).
The semiconductor base 2 has a thickness of, for example, 100 to 200 micrometers, which results from a semiconductor wafer product, which has been thinned, for example by polishing, in the method for fabricating the semiconductor laser 1, for the semiconductor base 2. The semiconductor laser 1 thus thinned is mounted on the circuit board.
The first laminate 3 serves as a lower distributed Bragg reflector (a lower DBR), which is under the active layer 4, and includes multiple semiconductor layers. The first laminate 3 is disposed on the front face 2a of the semiconductor base 2, and has, for example, a first superlattice structure 11, a contact layer 12, and a second superlattice structure 13. The first superlattice 11, the contact layer 12, and the second superlattice 13 are sequentially arranged on the face 2a of the semiconductor base 2 in the direction T such that the contact layer 12 is disposed between the first and second superlattice structures 11 and 13.
The first superlattice structure 11 is made of i-type semiconductor. The first superlattice 11 has an arrangement of unit structures each including multiple semiconductor layers different from each other. Each structure unit structures includes, for example, an AlGaAs layer (having an Al composition of 0.12) and an AlGaAs layer (having an Al composition of 0.90). The first superlattice 11 has a stacking number of the unit structures in the range of, for example, 50 to 100. The first superlattice 11 has a thickness of, for example, 4000 to 6000 nm.
The contact layer 12 made of n-type semiconductor, which is in contact with the electrode 9 of the semiconductor laser 1, forming a single layer. The contact layer 12 is made of, for example, a GaAs doped with Si. The contact layer 12 has a first portion 12a and a second portion 12b, which can be different in thickness from each other. The first and second portions 12a and 12b are arranged along the front face of the semiconductor base 2. The first portion 12a is outside the semiconductor mesa M to make contact with the electrode 9. The second portion 12b has one part and another part contained by the semiconductor mesa M. The first portion 12a has a thickness equal to or less than that of the second portion 12b, for example, 250 to 500 nm in view of contact resistance. The second portion 12b has a thickness of not less than that of the first portion 12a, for example not more than 500 nm.
The second superlattice 13 is made of n-type semiconductor doped with, for example Si, and is disposed on the second portion 12b of the contact layer 12. The second superlattice 13, which is similar to the first superlattice 11, has an arrangement of unit structures including multiple semiconductor layers different from each other. Each unit structure includes, for example, an AlGaAs layer (having an Al composition of 0.12) and an AlGaAs layer (having an Al composition of 0.90). The second superlattice 13 has a stacking number of unit structures in the range of, for example, 10 to 30. The second superlattice structure 13 has a thickness of, for example, 1000 to 2000 nm.
The active layer 4 is disposed on the second superlattice 13 of the first laminate 3 and can generate light through recombination of electrons and holes and. The active layer 4 has a lower spacer layer 21, a multiple quantum well structure 22, and an upper spacer layer 23, which are sequentially stacked on the first laminate 3 in the direction T. The multiple quantum well structure 22 is disposed between the lower and upper spacer layers 21 and 23. The active layer 4 has a thickness of, for example, 50 to 300 nm.
The lower spacer layer 21 is disposed between the second superlattice 13 and the multiple quantum well structure 22, and is made of semiconductor doped with an n-type dopant, such as a Si-doped AlGaAs layer (having an Al composition of 0.30). The multiple quantum well structure portion 22 includes, for example, GaAs layers each of which serves as a well layer, and AlGaAs layers each of which serves as a barrier layer. The GaAs layers and the AlGaAs layers are alternately arranged in the direction T. The upper spacer layer 23 includes an undoped semiconductor layer and a semiconductor layer doped with a p-type dopant. The undoped semiconductor layer is made, for example, an AlGaAs layer (having an Al composition of 0.30). The semiconductor layer is doped with a p-type dopant, such as zinc (Zn), and is especially Zn-doped AlGaAs (having an Al composition of 0.90). The p-type dopant encompasses Be (beryllium), Mg (magnesium), C (carbon), or Zn (zinc).
The current constricting layer 5 is disposed in the semiconductor mesa M to restrict current (carriers) into the active layer 4. The current constricting layer 5 has a high-resistance portion 31 and a low-resistance portion 32. The high resistance portion 31 encircles the low-resistance portion 32 on an axis extending in the direction T. The high-resistance portion 31 is made of group III oxide, the low-resistance portion 32 is formed of III-V compound semiconductor, for example, an AlGaAs layer of a high Al composition (for example, an Al composition of 0.98). The III-V compound semiconductor is provided with a high Al composition that allows an oxidant atmosphere to oxidize the III-V compound semiconductor. The low resistance portion 32 has an electrical resistance lower than that of the high resistance portion 31, and excludes aluminum oxide. The current constricting layer 5 has a thickness of, for example, 10 to 50 nm. The current constricting layer 5 allows current to flow through the low resistance portion 32, thereby narrowing the current path.
The second laminate 6 serves as an upper distributed Bragg reflector (an upper DBR) to the active layer 4, and includes multiple semiconductor layers. The second laminate 6 incorporates the current constricting layer 5, and alternatively is disposed on the current constricting layer 5. The second laminate 6 has, for example, a superlattice 41 and a contact layer 42. The superlattice 41 and the contact layer 42 are stacked in order along the direction T on the active layer. If needed, the superlattice 41 has a first part and a second part and the current constricting layer 5 is between the first part and the second part. The first and second parts of the superlattice 41 are arranged to form the upper DBR.
The superlattice 41 has a p-type conductivity. The superlattice 41 has an arrangement of units, which are similar to the first superlattice 11. Each unit structure includes, for example, an AlGaAs layer (having an Al composition of 0.12) and an AlGaAs layer (having an Al composition of 0.90). The superlattice 41 has a stacking number of unit structures in the range of, for example, 50 to 100. The superlattice 41 has a thickness of, for example, 3000 to 5000 nm. The superlattice 41 is doped with, for example, Zn. The contact layer 42 has a single semiconductor film that is in contact with the electrode 8. The contact layer 42 is made of, for example, Zn-doped GaAs. The contact layer 42 has a thickness of, for example, 100 to 300 nm.
The insulating film 7 serves as a protective film, which covers semiconductor layers in the semiconductor laser 1, and is made of, for example, inorganic insulating material. The inorganic insulating film includes a silicon-based inorganic film, such as a silicon oxide film, a silicon nitride film, and a silicon oxynitride film. The insulating film 7 has an opening portion 7a on the semiconductor mesa M and an opening portion 7b on an area apart from the semiconductor mesa M. The openings 7a and 7b penetrate through the insulating film 7 in the direction T, such that the opening 7a reaches the contact layer 42 and the opening 7b reaches the first portion 12a of the contact layer 12. The insulating film 7 may have a thickness of 200 to 500 nm, which can provide the semiconductor laser 1 with a high reflectance.
The electrode 8 is disposed on the semiconductor mesa M and has a part embedding in the opening portion 7a. The electrode 8 is in contact with the contact layer 42 via the opening 7a. The electrode 8 may have a laminate structure including, for example, a titanium layer, a platinum layer, and a gold layer.
The electrode 9 is disposed apart from the semiconductor mesa M and is embedded in the opening 7b. The electrode 9 is in contact with the first portion 12a of the contact layer 12 via the opening 7b. The electrode 9 may include, for example, a gold-germanium-nickel alloy layer.
With reference to
The fabricating method begins with preparation of an epitaxial wafer 100 as shown in
The epitaxial wafer 100 (the surface on the semiconductor laminate S) is etched with the resist mask R by plasma etching (for example, reactive ion etching). As shown in
As shown in
As shown in
As shown in
As shown in
As shown in
A description will be given of the etching step (shown in FIG.
2B) in detail. The above-described etching process applies plasma radiation in the etching (for example, reactive ion etching) to the semiconductor laminate S of the epitaxial wafer 100. The plasma etching heats the epitaxial wafer 100 to raise the temperature of the wafer during the etching. The resist mask R on the epitaxial wafer 100 is also subjected to the heating, but the epitaxial wafer 100 is cooled through the quartz tray, which is attached to the back face of the wafer 10. This cooling through the quartz tray can prevent the mask from deteriorating during the etching, thereby avoiding excess temperature rise in the etching.
An insufficient adhesion between the tray and the wafer results from voids therebetween to raise the temperature of the wafer, resulting in undesired cooling which may deteriorate the resist mask R and be finally peeled off from the tray during plasma etching.
In the present embodiment, sticking the wafer 10 on the tray with an adhesive film, which contains pressure-sensitive material, can bring the wafer 10 into close contact with the tray, thereby providing an intermediate product 18. The intermediate product 18 is loaded into an etching apparatus, which can apply the product to the plasma etching.
The apparatus 50 includes a container 51, a lid 52, O-rings 53 and 54, a gas-supply pipe 55, an exhaust pipe 56, an imager 57, and an illuminating device 58. The structure body 18 is accommodated in the apparatus 50. The intermediate product 18 includes an epitaxial wafer 100, an adhesive film, and a supporting base, such as a tray 60. The adhesive film includes a film 62, and the film 62 contains pressure-sensitive material. The adhesive film further includes a double-sided adhesive film 61 and a double-sided adhesive film 63.
The tray 60 is transparent to, for example, visible light and has a flat face. The tray 60 is made of, for example, quartz. In the present embodiment, the tray 60 has flat faces 60a and 60b opposite to each other. The wafer 10 has a principal face 10a and a back face 10b, which are opposite to each other. In the present embodiment, the wafer 10 adheres to the tray 60 with an adhesive film including the film 62 containing pressure sensitive material, and if needed, the double-sided adhesive films 61 and 63. The faces 60a and 60b each have an area larger than that of the back face 10b of the wafer 10.
The film 62 includes a sheet-like (thin film) base containing pressure sensitive material, such as PRESCALE (registered trademark) supplied by Fuji Film, and the pressure sensitive material changes its color in accordance with the magnitude of pressure (internal stress) applied thereto. The PRESCALE exhibits white in an initial color and is changed to pink in the presence of a predetermined pressure or more. The film 62 is fixed to the one face 60a of the tray 60 with the double-sided adhesive film 61 therebetween, and the film 62 is fixed to the front face 60b of the tray 60 with the double-sided adhesive film 63 therebetween, thereby forming the adhesive film.
Referring again to
The lid 52 is disposed on the upper opening of the upper cavity 51c of the container 51. The lid 52 has, for example, a plate-like shape and includes a flat face 52a. The lid 52 closes the top opening of the container 51 with the O-ring 53. The O-ring 53 is disposed between the face 52a and the top face of the side wall extending upward from the extension stage that defines the top opening. The O-ring 53 is in contact with both the lid 52 and the container 51 to hermetically seal the upper cavity 51c. The lid 52 can be pressured by an actuator to be moved downward (an arrow A1 in the drawing) and. The magnitude of the pressure ranges from, for example, 0.01 MPa to 0.4 MPa.
The O-ring 54 is disposed between the lower face 52a of the lid 52 and the outer annular area of the top face of the epitaxial wafer 100 (the semiconductor lamination S), and is brought into contact with the lid 52 and the epitaxial wafer 100 to form a pressing space. The pressing space is hermetically sealed with the lid 52, the epitaxial wafer 100, and the O-ring 54 therebetween.
The air-supply pipe 55 penetrates the lid 52 to supply pressing gas to the pressing space, which is defined by the O-ring 54, the lid 52 and the epitaxial wafer 100 (the arrow A2 in the drawing). The gas includes, for example, nitrogen gas. The pressure of the supply gas is, for example, 0.3 MPa. The exhaust pipe 56 penetrates the container 51 outside the O-ring 54, and is used to evacuate the upper cavity 51c outside the pressing space (the arrow A3 in the drawing). The exhaust pressure is, for example, −70 kPa. Using the external force A1, which is applied to the lid 52, and the pressure difference between spaces inside and the outside the O-ring 54 allows the uniform application of the pressing force therefrom to the film between the tray 60 and the principal surface of the epitaxial wafer 100 (the surface on the semiconductor laminate S), thereby uniformly enhancing the adhesion strength between the wafer 100 and the tray 60 over the entire epitaxial wafer 100.
The container 51 is provided with the imager 57, such as a camera, on the bottom 51b of the lower cavity 51d, and the imager 57 can take images of the film 62 through the back face 60b of the tray 60. The difference between images before and after applying the pressing force shows change in color of the film 62. The imager 57 is sensitive to optical wavelengths of indicator range of the film 62. The illuminating device 58 is disposed in the lower cavity 51d to illuminate the lower cavity 51d. The illuminating device 58 emits, for example, visible light. The illuminating device 58 is disposed lateral to the imager 57 in the lateral recess 51e of the lower cavity 51d so as to prevent the illuminating device 58 from directly illuminating the imager 57.
A description will be given of a method of attaching the epitaxial wafer 100 to the tray 60 using the above-described apparatus 50, resulting in that the method forms the intermediate product.
After forming the stack product, the epitaxial wafer 100 is placed on the double-sided adhesive film 63 of the stack product (in step S4). The epitaxial wafer 100 is handled in the step S4, and what is needed is to cause the epitaxial wafer 100 to make contact with the double-sided adhesive film 63 of the stack product with no strong pressing force being applied thereto. The epitaxial wafer 100 is placed on the double-sided adhesive film 63 and a light press is applied to the epitaxial wafer 100 with no strong pressing force being applied thereto. The above steps S1 to S4 bring the intermediate product 18 to completion. The intermediate product thus prepared is loaded to the upper cavity 51c of the apparatus 50. Then, the upper cavity 51c is sealed with the lid 52 of the apparatus 50 by use of the actuator (in step S5).
In this step, the actuator applies pressing load to the intermediate product through the lid 52, and the application of the load change the film 62 in color. This change in color can be imaged by the imager 57 through the other side 60b of the tray 60 (in step S6, referred to as the first confirmation step).
A further increase in the pressing force patterns the film 62 in change in color into an annular closed shape, which is associated with the shape of the O-ring 54, as shown in
After forming the intermediate product, an additional pressing force is applied to the inner section between the tray 60 and the face of the epitaxial wafer 100 (in step S7). Specifically, the supply of gas is started, so that the gas is introduced to the inner section, formed by the O-ring 53, the lid 52 and the epitaxial wafer 100, through the air-supply pipe 55, and the exhaust of the upper cavity 51c is started, so that the upper cavity 51c is exhausted through the exhaust pipe 56. An exemplary process is as follows: the exhaust for 1 minute; and thereafter, both the evacuation and the supply for 1 minute (to provide pressurization).
the application of the air pressure through the inner section to the epitaxial wafer 100 causes change in color of the film 62. The imager 57 takes images through the other side face 60b of the tray 60 during the pressing process. The images show that a sufficiently high pressure can bring the epitaxial wafer into close contact with the stack product entirely. Specifically, two images from the imager before and after the pressurization have respective discolored areas B in the film 62, the color of which has changed, in the inner section that is defined by the O-ring 54. The difference in the ratio of the area of the discolored region B to the total area of the inner section between the two images show that the desired contact between the stack product and the epitaxial product has been achieved over the principal surface of the epitaxial product (for example, 80% or 90% or more), e.g., the total area of the inner section (in step S8, hereinafter referred to as the second checking step).
The above supply and exhaust process forms a sufficiently large pressure difference between the inside and outside of the O-ring 54, which creates a uniform pressing force that entirely presses the inside area of the epitaxial wafer 100 against the tray 60, as shown in
As such, the above steps can produce the intermediate product 18, which is unloaded out from the apparatus 50 (in step S10), with the area ratio of not less than the predetermined value. The above steps S1 to S10 bring the intermediate product 18 to completion.
The intermediate product 18 is loaded to an etching apparatus enabling plasma etching, and the semiconductor laminate S of the epitaxial wafer 100 in the intermediate product 18 is etched with the resist mask (in etching step).
As shown in
After the cooling, the etching apparatus starts to supply an etching gas to the vacuum chamber 81 while cooling the tray. The etching gas may contain chlorine-based gas, for example, BCl3 gas or a mixture of BCl3 and Cl2, and further contains inert gas (for example, Ar gas), which are supplied to the vacuum chamber 81. The gas is supplied to the vacuum chamber 81 by a total flow rate of, for example, 100 sccm. Specifically, in the chlorine-based gas of BCl3, the etching gas contains BCl3, which is supplied in the flow rate of 30 sccm; and Ar, which is supplied in the flow rate of of 70 sccm. In a mixture of the chlorine-based gas, the etching gas contains BCl3, which is supplied in the flow rate of 20 sccm; Cl2, which is supplied in the flow rate of 10 sccm; and Ar, which is supplied in the flow rate of 70 sccm. Plasma-ignition starts to turn the etching gas into plasma in the vacuum chamber 81, and ion species in the plasma P collide with the upper face of the epitaxial wafer 100 (the semiconductor laminate S). Both sputtering by ions and chemical reaction with the etching gas occur in the vacuum chamber 81 to etch the surface of the epitaxial wafer 100 with the resist mask.
After the etching, the intermediate product thus etched is loaded out from the vacuum chamber 81. Then, the epitaxial wafer 100 thus etched is separated from the film 62 (in the separation step). In the intermediate product that provides, with heat peelable adhesive, the adhesive layers 71 (as shown in see
A description will be given of advantageous effects of the method for fabricating the optical device according to the above-described embodiment.
The epitaxial wafer 100 may not sufficiently adhere to the tray 60 because of voids left at interfaces between the double-sided adhesive film 63 and the tray 60 and epitaxial wafer 100. The voids at the interfaces are evacuated during the plasma etching to make the thermal conductance between the epitaxial wafer 100 and the tray 60 reduced, thereby leading to insufficient cooling of the epitaxial wafer 100 through the tray 60. The reduced thermal conductance raises the temperature of the epitaxial wafer 100 during the plasma etching. An excessive temperature rise may deteriorate the resist mask R on the epitaxial wafer 100 to make the resist mask R defective. A defective resist mask makes the etching undesired, so that the epitaxial wafer 100 is subjected to the etching with the defective resist mask to produce a defective etched product from the epitaxial wafer 100, resulting in reduced yield.
The intermediate product according to the embodiment is provided with the film 62 between the tray 60 and the epitaxial wafer 100 to avoid the reduction in the thermal conductance between the epitaxial wafer 100 and the tray 60. The film 62 changes its color in response to the pressing force. Specifically, the change in color may vary over the surface of the epitaxial wafer 100, and can be observed through the back face 60b of the tray 60. The observation of the change in color in the film 62 in view of uniformity shows whether the application of a pressing force to between the epitaxial wafer 100 and the tray 60 cannot bring the tray 60 and the epitaxial wafer 100 into close contact with each other. If needed, the pressing and the observation are conducted repeatedly to obtain an intermediate product with an acceptable variation in color over the surface of the epitaxial wafer 100. Containing the film 62 in the stack product can visualize the distribution of the insufficient adhesion between the tray 60 and the epitaxial wafer 100 over the face of the epitaxial wafer 100. The fabricating method according to the present embodiment can prevent the resist mask in the intermediate product from becoming defective during plasma etching, thereby avoiding the reduction in yield.
The fabricating method according to the embodiment can detect a foreign particle between the epitaxial wafer 100 and the tray 60. The foreign material, left between the epitaxial wafer 100 and the tray 60, may break the epitaxial wafer 100 during the depressurization with the apparatus 50, and can be found, based on a difference in the shape of the discolored region B, by the observation of the intermediate product before the pressing. The foreign material thus found is removed by separating the epitaxial wafer 100 from the tray 60. After excluding a foreign material, a new intermediate product is produced from the epitaxial wafer 100 and the tray 60, thereby reducing the occurrence of cracking of the epitaxial wafer 100.
In the embodiment, the film 62 can be provided with the ratio of the area of the region B to the inside area within the O-ring 54 is not less than 80% or 90%, and after this ratio in color change has been given to the film 62, the present method can determine whether or not an intermediate product is provided with a uniform adhesion between the tray 60 and the epitaxial wafer 100 over the inside area of the entire surface of the epitaxial wafer 100. Analyzing images from the imager 57 on a controller, such as a computer, allows the automatic determination.
In the embodiment, the intermediate product 18 may be provided with the stack product, which includes the film 62 and the double-sided adhesive films 61 and 63, having a heat peelable adhesive making close contact with the epitaxial wafer 100. The intermediate product 18 may be provided with the stack product, which includes the film 62 and the double-sided adhesive films 61 and 63, having both a heat peelable adhesive making close contact with the epitaxial wafer 100 and a heat peelable adhesive making close contact with the film 62. One or more heat peelable adhesives make it easy to separate the film 62 and the epitaxial wafer 100 from each other after the plasma etching.
In the present embodiment, the intermediate product 18 may be provided with the stack product, which includes the film 62 and the double-sided adhesive films 61 and 63, having a heat peelable adhesive making close contact with the tray 60. The intermediate product 18 may be provided with the stack product, which includes the film 62 and the double-sided adhesive films 61 and 63, having both a heat peelable adhesive making close contact with the tray 60 and a heat peelable adhesive making close contact with the film 62. One or more heat peelable adhesives make it easy to separate the film 62 and the tray 60 from each other after the plasma etching.
The present embodiment can fabricate the semiconductor optical device, such as VCSEL. The fabrication of VCSEL excludes processes for wet-etching with hydrofluoric acid and dry-etching with a fluorocarbon gas, so that silicon-based inorganic material, such as silicon oxide and silicon nitride cannot be used for an etching mask, whereby the fabrication of VCSEL needs a resist mask for etching. The fabricating method that cools the resist mask through the epitaxial wafer according to the embodiment is particularly effective.
(Modification)
A description will be given of a modified example according to the embodiment below.
The method of fabricating a semiconductor optical device according to the present invention is not limited to the above-described embodiments, and various other modifications are possible. For example, the method for fabricating a VCSEL can be applied to the methods for fabricating a light receiving or emitting device. Further, the above embodiment uses a heat peelable adhesive but may use various other adhesive materials.
Having described and illustrated the principle of the invention in a preferred embodiment thereof, it is appreciated by those having skill in the art that the invention can be modified in arrangement and detail without departing from such principles. We therefore claim all modifications and variations coining within the spirit and scope of the following claims.
Number | Date | Country | Kind |
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2017-160145 | Aug 2017 | JP | national |