Patent Application
20230392230
The invention relates to a method for the granulation of a metallurgical slag, wherein liquid slag is atomized by blowing air onto it, and the slag particles granulated in this way are collected.
A method of this kind is known from WO 2015/184533 A1. The granulation of metallurgical slag occurs here by addition of water, wherein water is supplied to the slag by means of nozzles (see water nozzle 42 in the figure of the document). Water is also applied directly to the incoming liquid slag (see water nozzle 26 in the figure of the document).
A similar solution is shown in DE 27 35 390 C2. Here, the granulation of the slag occurs in a two-stage process, comprising for this purpose two rotary cylinders in succession. The slag is atomized by means of an air stream and blown into a first rotary tube, serving as a first waste heat boiler. The still warm granulate is then conveyed to a second rotary tube, in which it is further cooled down. The warm exhaust air from both rotary tubes is utilized to recover energy. At first, in a first step, only a very rough granulation is performed, and then the particles are treated in an intermediate grinding step. The high-temperature grinding is laborious and expensive.
Other similar solutions are shown by JP 11181508 A, DE 10 2009 042 874 A1, DE 1 583 200 A1, JP 11236609 A, JP 54159302 A, WO 2011/160551 A1 and WO 2016/095031 A1. However, all of these solutions have certain technological drawbacks, for example too low a temperature of the exhaust gas, too much dust in the exhaust gas, and a slag product which is not immediately economically usable.
In some of the known solutions, the liquid slag is thus finely atomized by means of a blower and then granulated in flight. The slag is usually atomized with water injection, i.e., the slag is sprayed with water. The granulated particles are then sufficiently cooled down as they strike the floor and possess a spherical shape. However, many of the known methods are uneconomical, so that they are not used in industrial practice.
It is the object of the invention to further develop a method of the type mentioned so that the quality of the granulate is enhanced and the costs for its production can be further reduced, especially as regards the cost of energy which must be spent on carrying out the method. Doing so aims at ensuring a high quality of the granulate in the most energy efficient manner.
Achieving the object by the invention is characterized in that the atomization is done by blowing the a heated air jet free from the addition of water onto the liquid slag and the slag is supplied to a working chamber, wherein the granulated slag particles are collected in the floor region of the working chamber, wherein the air escaping from the working chamber is either supplied to a heat exchanger, which preheats the air jet blown onto the liquid slag, or directly recirculated in order to atomize the liquid slag.
Preferably, only a single working chamber is used for the method.
The slag is preferably kept free from the addition of water from supplying to depositing it in the floor region of the working chamber. Accordingly, a pure dry granulation is provided.
The air blown onto the liquid slag is preferably preheated to at least 60° C., preferably to at least 80° C., especially preferably to at least 100° C. and very preferably to at least 120° C. or the air has this temperature.
After the atomization of the liquid slag has been performed with the air, the air preferably has a temperature of at least 250° C., especially preferably at least 400° C.
A portion of the energy contained in the escaping air can also be used to supply a consumer. The consumer is, according to one embodiment of the invention, a steam generator, which is preferably connected to a steam turbine/generator system for generating electrical energy.
According to another embodiment of the invention, the consumer is a heating system, which is used to heat facilities or buildings.
According to an especially preferred embodiment of the invention a further air stream is blown onto the granulated slag particles in order to heat the air, the heated air being supplied to a heat exchanger; the slag particles are also cooled in this way. Once again, the heat recovered in the heat exchanger can be used to supply a consumer; here as well, the consumer may be a steam generator, which is preferably connected to a steam turbine/generator system for generating electrical energy, or a heating system, which is used to heat facilities or buildings.
The metallurgical slag is preferably nonferrous slag.
In order to ensure a highly clean operation, various further measures are very advantageous: accordingly, it is proposed in particular that supplying the liquid slag and blowing air onto it occurs in a first section of the working chamber (especially in the front region of the working chamber) and that the granulated slag particles accumulate in a second section of the working chamber (especially in the rear region of the working chamber), at a distance from the first section, and the air escaping from the working chamber is removed from the working chamber in the region of the first section.
For this purpose, the first section and the second section of the working chamber can be separated from each other by a baffle plate located in the ceiling region of the working chamber.
In this way, the air in the working chamber, after the granulate has trickled down, is forced back into the front region of the working chamber and then out from it, so that it hardly carries any more granulate particles. This ensures a lower dust burden.
The venting site of the escaping air advantageously is vertically above the site for supplying the liquid slag and blowing air onto it. This is understood to mean essentially that the escaping air, looking in top view, leaves the working chamber at the site where it entered. Of course, a slight offset is possible for the supplying site and the escaping site, which is preferably not greater than 2 m, advantageously not greater than 1 m.
The air after escaping from the working chamber can be guided at first vertically upward, then be deflected by 180°, then guided vertically downward, and then supplied again to the working chamber through the blower. This affords the further possibility of particles still present in the air to leave the air and moreover a sufficient distance which can be utilized for heat exchange from the hot air.
This concept also includes the possibility of the air, after escaping from the working chamber, being deflected at first by 90°, and then the described heat exchange occurs, after which a further deflection by 90° occurs for the purpose of being guided vertically downward.
Instead of the mentioned vertical channeling of the air, one can of course also provide a channeling at a slight angle to the vertical, preferably by as much as 30°.
An optimal removal of the resulting granulate and disposal of defective products, respectively, is facilitated by having a receiving or removal element for defective products which is located in the first section of the working chamber and at least one receiving or removal element for granulated slag particles which is located in the second section of the working chamber.
It can also be provided that the floor of the working chamber is partitioned into multiple sections, whereby two oppositely slanted floor sections in each case collect granulated slag particles with a certain parameter (especially a certain size). The granulate can then be taken away beneath the two slanted floor regions (this is shown in
Thus, with the proposed method, a dry granulation is done with preheated air. On the one hand, the slag is finely atomized and granulated, so that a commercially viable product is obtained. It is also possible to use heated air for the atomization, having been preheated by energy recovery. The air used for the atomization according to one preferred embodiment of the invention recirculates in the system. Thus, the efficiency of the overall system is increased. The granulation occurs in a single process step, so that there are advantages as compared to some of the known solutions (see above).
As compared to known solutions in which the granulation of liquid slag takes place with addition of water, the dry granulation according to the invention has the major advantage that less energy escapes from the process and thus the efficiency of the energy recovery can be improved.
The atomization of the liquid slag occurs in the dry air stream with little or no formation of filaments.
The method is suitable for use in many pyrometallurgical processes where slag is obtained. A use with nonferrous slag is especially preferred.
With the proposed solution, an optimization of the energy required for the metallurgical process can be accomplished. This is achieved by the recovery of the energy contained in the slag and which would otherwise be lost.
Hence, an effective recovery of energy from the liquid slag is ensured, and at the same time the particle of slag solidify and immediately become a valuable (marketable) granulate material. Thus, the economic utility of the slag is improved.
The blowing of air onto the liquid slag for purposes of atomization should be understood to mean that an intense air stream is introduced into the incoming flow of liquid slag, so that the desired atomization occurs. In particular, the slag is conveyed through a channel; as the slag falls out, the intense air stream is then supplied from the bottom.
Exemplary embodiments of the invention are represented in the drawing, in which:
The aforementioned prior art offers various solutions for the technology of slag granulation and also for the recovery of energy contained in the slag. By contrast, the present invention is based on a combination of dry granulation and energy recovery.
To this end,
The air 5 escaping from the working chamber 4 (having a temperature of around 500° C.) is guided to a heat exchanger 6, where the escaping air 5 preheats intake air and guides it to the blower 10 (along the path shown schematically by broken lines) in order to atomize liquid slag 1.
Alternatively, it is also equally possible for the air 5 escaping from the working chamber to be conveyed directly (without a heat exchanger) to the blower 10 and used for the atomization of the liquid slag 1. In the latter case, the air is guided in a closed circuit (recirculating) and used in its heated state for the atomizing of the liquid slag 1.
A combination of the two mentioned procedures is also possible: accordingly, the air 5 escaping from the working chamber 4 is recirculated, i.e., again guided to the blower 10 and used to atomize liquid slag 1. Prior, however, the escaping air 5 passed through the heat exchanger 6, so that a concept can be realized as shown in
At the left of the figure, still schematically, it is illustrated how air 2 is used for atomizing the liquid slag 1. The air 5 escaping from the working chamber 4 passes through the heat exchanger 6, while the granulated slag particles 3 are collected in a floor region of the system.
At the right side of the figure it is indicated that the heat obtained from the escaping air 5 in the heat exchanger 6 is reused. Two alternative or additive possibilities are outlined for this at the right side of the figure.
In the upper area on the right side of the figure there is shown a consumer 7 in the form of a steam generator 7′, in which water is evaporated by using the recovered energy. The steam is supplied to a steam turbine/generator system 8, in which electrical energy can be produced in familiar manner.
In the lower area at right side of the figure there is shown a consumer 7 in the form of a heating system 7″. The energy from the escaping air 5 is used for heating purposes in this case.
The escaping air 5 that was guided through the heat exchanger 6 can be guided back to the starting point in order to be used as air 2 for atomizing the liquid slag 1. If recirculating air is used, this air should have a temperature not less than 120° C. upon reaching the blower 10.
For this purpose, a further air stream 9 is guided through the bottom region, which heats up as it is passed through the slag particles 3 and supplied to a heat exchanger 6 (this may be the same heat exchanger as mentioned above, as shown, but it can also be a separate one). The heat from the heated air stream 9 can be utilized in the described manner and be made available to one or more consumers 7. It is desirable to remove as much heat as possible from the slag particles by the further air stream 9, so that the slag particles only have a temperature of around 80° C.
Of course, the removal of heat from the slag particles need not occur directly in the floor region of the working chamber 4. It is also possible to select a downstream location for this purpose, such as the region of the conveyor belt 11.
It would also be possible to utilize the heated further air stream 9 by supplying it to the blower 10 and performing the atomization of the liquid slag 1 by means of the air which has thus been preheated.
In either case, the floor of the working chamber can be configured either as a simple sheet or as a perforated sheet in order to pass air through the resulting granulate material, so that it becomes possible on the one hand to further cool the granulate material and on the other hand to also remove further energy from the granulate material, which can then be utilized elsewhere (see above). The perforated sheet is designated as the air baffle 23 in
As a result, the air enters into the working chamber in the left end region of the working chamber 4 (see
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2020 201 290.3 | Feb 2020 | DE | national |
| 10 2020 209 057.2 | Jul 2020 | DE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2021/051984 | 1/28/2021 | WO |
