The disclosure generally relates to a method for laminating a lithium metal anode.
A battery cell includes an anode, a cathode, an electrolyte, and a separator. The anode and the cathode include reactive materials which exchange ions through the electrolyte and the separator for the purpose of providing an electrical current through an attached circuit. In one embodiment, an anode may include a current collector, for example, a copper current collector, and a lithium coating upon the copper current collector.
A method for laminating a lithium metal anode is provided. The method includes procuring a current collector, including a portion of the current collector to be covered with a lithium foil lamination, and procuring a plurality of lithium foil portions. The plurality of lithium foil portions each include a length configured for matching one of a length of the portion of the current collector to be covered with the lithium foil lamination or a width of the portion of the current collector to be covered with the lithium foil lamination. The method further includes disposing the plurality of lithium foil portions upon the portion of the current collector to be covered with the lithium foil lamination, wherein the plurality of lithium foil portions is arranged side-by-side, and applying heat and pressure to join the plurality of lithium foil portions to the current collector.
In some embodiments, the plurality of lithium foil portions each include a rectangular shape including two elongated sides and two relatively narrow sides and a longitudinal axis defined by the two elongated sides. The current collector is rectangular in shape including a longitudinal axis of the current collector.
In some embodiments, disposing the plurality of lithium foil portions upon the portion of the current collector to be covered with the lithium foil lamination includes arranging the plurality of lithium foil portions such that the longitudinal axis of each of the plurality of lithium foil portions is parallel to the longitudinal axis of the current collector.
In some embodiments, disposing the plurality of lithium foil portions upon the portion of the current collector to be covered with the lithium foil lamination includes arranging the plurality of lithium foil portions such that the longitudinal axis of each of the plurality of lithium foil portions is perpendicular to the longitudinal axis of the current collector.
In some embodiments, the plurality of lithium foil portions each include a rectangular shape including two elongated sides and two relatively narrow sides and a longitudinal axis defined by the two elongated sides. The portion of current collector to be covered with the lithium foil lamination is rectangular in shape and defines the length of the portion of the current collector to be covered with the lithium foil lamination, the width of the portion of the current collector to be covered with the lithium foil lamination, and a longitudinal axis of the current collector.
In some embodiments, disposing the plurality of lithium foil portions upon the portion of the current collector to be covered with the lithium foil lamination includes arranging the plurality of lithium foil portions such that the longitudinal axis of each of the plurality of lithium foil portions is parallel to the longitudinal axis of the current collector.
In some embodiments, disposing the plurality of lithium foil portions upon the portion of the current collector to be covered with the lithium foil lamination includes arranging the plurality of lithium foil portions such that the longitudinal axis of each of the plurality of lithium foil portions is perpendicular to the longitudinal axis of the current collector.
In some embodiments, the plurality of lithium foil portions includes a first plurality of lithium foil portions. The method further includes disposing a second plurality of lithium foil portions upon a reverse side of the current collector. Applying the heat and the pressure to join the first plurality of lithium foil portions to the current collector simultaneously joins the second plurality of lithium foil portions to the current collector.
In some embodiments, the plurality of lithium foil portions includes a first plurality of lithium foil portions. The method further includes, subsequent to applying the heat and the pressure to join the first plurality of lithium foil portions to the current collector, disposing a second plurality of lithium foil portions upon a reverse side of the current collector. The method further includes supplying heat and pressure a second time to join the second plurality of lithium foil portions to the current collector.
In some embodiments, applying the heat and the pressure to join the plurality of lithium foil portions to the current collector is performed once to join the plurality of lithium foil portions to the current collector simultaneously.
In some embodiments, applying the heat and the pressure to join the plurality of lithium foil portions to the current collector is performed sequentially to join the plurality of lithium foil portions to the current collector one-by-one.
According to one alternative embodiment, a method for laminating a lithium metal anode is provided. The method includes procuring a current collector, including a rectangular shaped portion of the current collector to be covered with a lithium foil lamination, wherein the current collector includes a longitudinal axis. The rectangular shaped portion of the current collector to be covered with the lithium foil lamination includes a length parallel to the longitudinal axis. The method further includes procuring a plurality of lithium foil portions. The plurality of lithium foil portions each are rectangular shaped and include a length configured for matching the length of the portion of the current collector to be covered with the lithium foil lamination and a relatively narrow width. The method further includes disposing the plurality of lithium foil portions upon the portion of the current collector to be covered with the lithium foil lamination. The plurality of lithium foil portions is arranged side-by-side and perpendicular to the longitudinal axis. The method further includes applying heat and pressure to join the lithium foil portions to the current collector.
In some embodiments, the plurality of lithium foil portions includes a first plurality of lithium foil portions. The method further includes disposing a second plurality of lithium foil portions upon a reverse side of the current collector. Applying the heat and the pressure to join the first plurality of lithium foil portions to the current collector simultaneously joins the second plurality of lithium foil portions to the current collector.
In some embodiments, the plurality of lithium foil portions includes a first plurality of lithium foil portions. The method further includes, subsequent to applying the heat and the pressure to join the first plurality of lithium foil portions to the current collector, disposing a second plurality of lithium foil portions upon a reverse side of the current collector. The method further includes applying heat and pressure a second time to join the second plurality of lithium foil portions to the current collector.
In some embodiments, applying the heat and the pressure to join the plurality of lithium foil portions to the current collector is performed once to join the plurality of lithium foil portions to the current collector simultaneously.
In some embodiments, applying the heat and the pressure to join the plurality of lithium foil portions to the current collector is performed sequentially to join the plurality of lithium foil portions to the current collector one-by-one.
According to one alternative embodiment, a method for laminating a lithium metal anode is provided. The method includes providing a flow of sheet material useful as a current collector. The method further includes providing a flow of a plurality of lithium strips, wherein the plurality of lithium strips is each relatively narrow as compared to the flow of sheet material. The method further includes directing the flow of the plurality of lithium strips upon the flow of sheet material, wherein the plurality of lithium strips is arranged side-by-side and collectively cover a top surface of the flow of sheet material. The method further includes applying heat and pressure to join the flow of the plurality of lithium strips to the flow of sheet material and create a flow of laminated material and segmenting the flow of laminated material to create the lithium metal anode.
In some embodiments, the method further includes providing a second flow of a plurality of lithium strips, directing the second flow of the plurality of lithium strips upon the flow of sheet material, and applying the heat and the pressure to additionally join the second flow of the plurality of the lithium strips to the flow of sheet material.
In some embodiments, the method further includes, prior to segmenting the flow of laminated material, storing the flow of laminated material upon a roll.
The above features and advantages and other features and advantages of the present disclosure are readily apparent from the following detailed description of the best modes for carrying out the disclosure when taken in connection with the accompanying drawings.
Lithium may be provided as a foil or a thin sheet of material. Such a lithium foil may be provided upon a roll of material and may be created through extrusion. Lithium foil may be provided in relatively thin strips from such a roll of material, where the lithium foil has a defined width and may have a desired length. The lithium foil may be un-spooled from the roll of material and cut to the desired length. Lithium foil may be provided at a defined width which is thinner or not as wide as may be desired to cover an entire current collector surface to be used for an anode.
A method for laminating a lithium metal anode is provided. A current collector including a planar surface including a length and a width is provided. In one embodiment the current collector may be rectangular in shape. In another embodiment, a portion of the current collector to be covered with a lithium foil lamination may be rectangular in shape. An elongated strip of lithium foil with an initial strip length and a relatively narrow width is provided. The elongated strip of lithium foil is segmented into a plurality of lithium foil portions by cutting the lithium foil with at least one cut made perpendicular to the initial strip length of the lithium foil. Each of the lithium foil portions are rectangular in shape and include a portion length and the relatively narrow width of the elongated strip of lithium foil. Each of the lithium foil portions may include a same or common portion length. The plurality of lithium foil portions may be disposed to the planar surface of the current collector. The current collector with the plurality of lithium foil portions disposed thereto (or placed thereupon or situated thereto) may be put through a lamination operation, where heat and pressure are applied to the current collector and the plurality of lithium foil portions, such that the plurality of lithium portions are joined to the current collector.
A plurality of the lithium foil portions may be utilized side-by-side to cover a portion of the current collector that a single lithium foil portion could not. Each of the plurality of lithium foil portions includes a relatively narrow width and a portion length. The plurality of lithium foil portions may include a selected portion length configured for covering either a length or a width of a portion of the current collector to be laminated. By aligning a plurality of the lithium foil portions side-by-side or with the side of the lithium foil portions including the portion length aligned to/in contact with each other, a current collector of various sizes may be covered and laminated with lithium foil. In one example, a longitudinal axis of the plurality of lithium foil portions may be aligned with a longitudinal axis of the current collector. In such an example, a length of a portion of the current collector to be laminated may be utilized to set the portion length of the plurality of lithium foil portions. In such an example, the plurality of lithium foil portions may be aligned side-by-side, with multiple iterations of the relatively narrow width of the lithium foil portions being utilized to cover the width of the portion of the current collector to be laminated.
In another example, the longitudinal axis of the plurality of lithium foil portions may be aligned perpendicular to the longitudinal axis of the current collector. In such an example, a width of the portion of the current collector to be laminated may be utilized to set the portion length of the plurality of lithium foil portions. In such an example, the plurality of lithium foil portions may be aligned side-by-side, with multiple iterations of the relatively narrow width of the lithium foil portions being utilized to cover the length of the portion of the current collector to be laminated.
Lithium may be laminated onto or into an electrode structure including a metal conducting layer with an active material mixture of, for example, a nano-composite of silicon monoxide, together with graphite and a binder, such as polyvinyl di-fluoride (PVDF). The lamination of lithium metal onto or into the electrode structure reduces the amount of irreversible capacity by readily supplying an amount of lithium ions to form the initial solid electrolyte interface (SEI).
In one embodiment, in order to laminate lithium metal onto or into the negative electrode, the lithium is first deposited onto a carrier, which is then used to laminate the lithium metal onto or into the electrode structure. The coated electrode material and the lithium-deposited plastic is placed between two rollers or two plates. Plates are heated to about 120° C. or within the range of 25° C. to 250° C. A pressure of 50 kg/cm2 to 600 kg/cm2 is applied to the rollers. The speed of movement of the materials through the roller pair or the plate pair may be approximately 0.1 m/min. The method may be used for either single-sided or double-sided coating.
Referring now to the drawings, wherein like reference numbers refer to like features throughout the several views,
The cathode 120 includes a current collector 122 and may include a first coating 124A and/or a second coating 124B.
The anode 110 and the cathode 120 may each include additional materials, constructions, and treatments, may include different shapes, thickness, and aspect ratios, and are not intended to be limited to the embodiments described herein.
A second group of lithium foil portions 118 may be disposed upon a bottom surface of the current collector 112 and may collectively be described as lithium foil lamination 114B′. In another embodiment, the lithium foil lamination 114B′ may be omitted from the anode 110.
A second group of lithium foil portions 118 may be disposed upon a bottom surface of the current collector 112 and may collectively be described as lithium foil lamination 114B″. In another embodiment, the lithium foil lamination 114B″ may be omitted from the anode 110.
The lithium foil portions 118 of
The method 200 and the method 300 illustrate how one side of a current collector may be laminated with a plurality of lithium foil portions. Either method may be utilized similarly to create a current collector with lithium foil laminations on both side of the current collector. In one embodiment, both sides may be laminated simultaneously, with the lithium foil portions being disposed to both side of the current collector prior to heat and pressure being applied. In another embodiment, one of the method 200 and the method 300 may be employed to laminate a first side of the current collector, and then one of the method 200 and the method 300 may be employed to laminate a second side of the current collector. In another embodiment, each of the lithium foil portions may individually be laminated to the current collector, with a sequence of individual lamination operations joining the lithium foil portions to the current collector one by one.
While the best modes for carrying out the disclosure have been described in detail, those familiar with the art to which this disclosure relates will recognize various alternative designs and embodiments for practicing the disclosure within the scope of the appended claims.