Patent Application
20090293446
The present invention relates to a method for ultra-low NOx combustion of fuels. The present invention provides a method for lowering combustor pressure drop in space limited turbines.
With energy usage directly related to economic growth, there has been a steady increase in the need for increased energy supplies. There is also a need to maximize the efficiency of energy use. Increase in energy use results in emissions of pollutants. Thus, there is a pressing need for power plants which are cleaner and more efficient. The need to reduce emissions can impact system efficiency. For gas turbines, low NOx combustion systems must exhibit pressure losses no higher than the system they replace in order to avoid efficiency loss and, except for new designs, fit within the engine. With NOx levels as low as 2 ppm now required, even for smaller turbines, it is crucial that compact, low pressure drop combustion systems be available.
Accordingly, improved combustion systems are needed. Thus the present invention is directed at allowing operation of an ultra-low NOx combustor at a lower pressure drop.
It has now been found that using a reactor such as that described in U.S. Pat. No. 6,394,791, a portion of the combustion air can bypass the reactor and be admixed with the reactor product streams in the postmix zone without impairing emissions at the same fuel flows. Pressure drop is reduced since air flow through the reactor is reduced. In the present invention, a fuel rich mixture is partially combusted and a portion of the heat of reaction is transferred to a quantity of cooling air insufficient to yield low NOx combustion if premixed with said fuel. Both streams commingle on exiting the reactor and are immediately mixed with penetrating jets of additional combustion air to produce a product stream of a given equivalence ratio of a value suitable for low NOx combustion. The product stream may be combusted to yield a low NOx effluent.
As shown for the example combustor 10 in
On passage through reactor 10, a mixture of the two streams would have an equivalence ratio of a value too high for low NOx combustion. In order to form a mixture suitable for low NOx combustion, an amount of air 20 sufficient to lower the equivalence ratio to a value for low NOx combustion at the lower temperature is injected such that the three streams intermix. Flow recirculation should be avoided. Depending on the engine requirements, the amount of by-pass air required may be as little as ten or twenty percent of the total primary zone combustion air to over fifty percent, such as sixty or seventy percent. On combustion, NOx emissions of under one ppm have been obtained.
To illustrate the advantage of the present invention two designs were compared.
A conventional design using the methods of U.S. Pat. No. 6,394,791 was used to produce NOx emissions below three ppm for a small gas turbine. All the combustion air passes to the reactor with a design split of about eight percent to the catalyst channel and ninety two percent to the cooling tubes. Mixing of the two streams produced the equivalence ratio fed to the combustor. The maximum number of tubes that would fit in the allowable diameter were used, sixty one. In engine testing of a full engine set, pressure drop was greater than six percent. At full load, NOx was under three ppm with levels under one ppm at part load. Redesign to reduce pressure drop was needed but no space was available to increase reactor diameter.
To meet both the emission and efficiency goal, a unit of the present invention was designed and an engine set built. The new injectors are interchangeable with the conventional Dry Low NOx (DLN) commercial injectors. Using twenty eight of the same catalyst tubes as in the above reactor, slightly smaller diameter reactors were built and tested. Air flow comprised sixty percent bypass air and forty percent reactor air, as tested. The latter was divided six percent to the catalytic channels and thirty four percent to the cooling channels. For full load fuel flow, this represents an equivalence ratio of about 0.79, a value much too high for low NOx combustion. On injection of the bypass air into the exiting reactor streams, the equivalence ratio in the postmix zone was reduced to 0.317. Combustion NOx was 0.8 ppm and pressure drop less than three percent.
While the present invention has been described in considerable detail, other configurations exhibiting the characteristics taught herein for efficient and effective reactor heat transfer are contemplated. For example, other catalytic reactor designs are contemplated as well as non-catalytic gas phase combustion. Therefore, the spirit and scope of the invention should not be limited to the description of the preferred embodiments described herein.
This application claims the benefit of U.S. Provisional Application No. 60/846,489 filed Sep. 22, 2006.
| Number | Date | Country | |
|---|---|---|---|
| 60846489 | Sep 2006 | US |
