Claims
- 1. A method of making a polymeric electrolyte for use in an electrochemical device, comprising melt-blending a mixture of:
- (a) an inorganic salt;
- (b) an organic polymer that is capable of permitting sufficient transfer of dissociated ions of the salt that the blend can function as an electrolyte in the device in the substantial absence of liquid; and
- (c) a plasticiser in an amount from about 5 to about 60% by weight based on the total weight of salt and polymer, the plasticiser having a dielectric constant of at least about 15:
- and forming the blended mixture into a film.
- 2. A method as claimed in claim 1, in which the blend comprises from about 25 to about 40% by weight of the plasticiser based on the total weight of salt and polymer.
- 3. A method as claimed in claim 1, in which the dielectric constant of the plasticiser is at least about 30.
- 4. A method as claimed in claim 1, in which the plasticiser is selected from the group consisting of propylene carbonate, ethylene carbonate, tetramethylene sulphone, gammabutyrolactone and dimethylformamide.
- 5. A method as claimed in claim 1, in which the salt is lithium trifluorosulphonate.
- 6. A method as claimed in claim 1, in which the polymer has the repeat unit: ##STR4## where R is hydrogen or a group Ra, --CH.sub.2 ORa, --CH.sub.2 OReRa or --CH.sub.2 N(CH.sub.3).sub.2, and R" is Ra or ReRa, Ra being C.sub.1 to C.sub.16 alkyl or cycloalkyl group and Re being an ether group of the formula --(CH.sub.2 CH.sub.2 O).sub.p where p is a number from 1 to 100.
- 7. A method as claimed in claim 7, in which the polymer is poly (ethylene oxide).
- 8. A method as claimed in claim 1, in which the film is formed by pressing a quantity of the blended material between two surfaces.
- 9. A method as claimed in claim 1, in which the film is formed by melt-extrusion.
- 10. A method as claimed in claim 9, in which the blended mixture is extruded onto an alkali or alkaline earth metal electrode.
Priority Claims (2)
Number |
Date |
Country |
Kind |
8333388 |
Dec 1983 |
GBX |
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84308708 |
Dec 1984 |
EPX |
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Parent Case Info
This application is a Divisional Application which claims priority from application Ser. No. 06/942,911 (filed 17 Dec. 1986), now U.S. Pat. No. 4,818,643 which was a Continuation Application claiming priority from U.S. application Ser. No. 06/780,546 (filed 26 Sept. 1985), which was a continuation Application claiming priority from U.S. application Ser. No. 06/675,909 (filed 28 Nov. 1984), which was a Continuation-in-Part Application claiming priority from Application Ser. No. 06/618,104 (filed 7 June 1984) the rest now all abandoned.
US Referenced Citations (5)
Foreign Referenced Citations (2)
Number |
Date |
Country |
145498 |
Jun 1985 |
EPX |
2442513 |
Jul 1980 |
FRX |
Divisions (1)
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Number |
Date |
Country |
Parent |
942911 |
Dec 1986 |
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Continuations (1)
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Number |
Date |
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Parent |
780546 |
Sep 1985 |
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