This application claims priority to European Patent Application No. 14195477.6 filed Nov. 28, 2014, the contents of which are hereby incorporated in its entirety.
The present invention relates to the technology of additive manufacturing processes. It refers to a method for manufacturing a component using an additive manufacturing process according to the preamble of claim 1.
SLM (Selective Laser Melting)-generated articles have different microstructure compared to conventionally cast materials of the same alloy. The microstructure is much more homogeneous, does show finely distributed precipitates and practically no segregation and has a several factors smaller grain size. These characteristics are optimal e.g. for tensile strength and LCF (Low Cycle Fatigue) strength and for these properties, standard SLM manufactured components exceed their cast counterparts significantly.
On the other hand, especially for high temperature properties, the small grain size is a drawback due to the facilitated diffusion that grain boundaries provide. High temperature properties such as creep or oxidation resistance are therefore lower than that of similar cast material, which is especially relevant to materials such as nickel based, cobalt based or iron based alloys used at high temperature (e.g. in gas turbines).
To avoid these problems, a recrystallization heat treatment (HT) has been developed for such additively manufactured superalloys, which results in an almost complete crystallographic isotropy and in a considerably larger grain size than what is obtained after standard HT (see document EP 2 586 887 A1). However, while this considerably increases the creep strength of SLM-generated superalloys, it might also decrease the LCF, TMF and tensile properties. Therefore it would be desirable to tailor the grain size within the part, for example according to the prevailing load type.
Document EP 2 586 887 A1 discloses a method to recrystallize SLM generated parts to increase the grain size and thereby improve creep and oxidation properties. However, using this method, the grain size cannot be locally tailored and the microstructure homogeneously recrystallizes in the whole SLM-generated part.
This is a good solution to improve creep properties. However, as the grain size cannot be tailored within a component, one needs to choose between improved creep and improved LCF properties.
Document EP 2 586 548 A1 discloses the general idea to tailor the grain size in an entire article according to the load type/requirements amongst others for SLM-generated parts through adjustment of the process parameters.
In document EP 2 586 548 A1, the grain size is directly generated in the SLM process, e.g. by different melt pool sizes, use of a second laser or other means.
This direct approach only allows a very limited variation in grain size. Furthermore, it requires lasers with different intensity distributions (e.g. multi-laser system, core-shell principle (lasers with large and small beam diameter)).
Document US 2009/0263624 A1 discloses the principle of subdividing a component in multiple parts in order to process them with different parameters optimized for the part characteristics. However, no intention to optimize the microstructure is given.
The prior art documents referred to in document EP 2 586 548 A1 and the related search report neither allow to selectively tailor the grain size nor refer to selective laser melting.
The recrystallization of SLM-generated superalloys has also been observed in F. Liu, X. Lin, M. Song, W. Zhao, J. Chen, and W. Huang, “Effect of intermediate heat treatment temperature on microstructure and notch sensitivity of laser solid formed Inconel 718 superalloy,” Journal of Wuhan University of Technology-Materials Science Edition, vol. 26, no. 5, pp. 908-913, 2011 In this document, it was shown that in an overlap region, the recrystallization behavior is different from that in the weld center.
It is an object of the present invention to teach a method for manufacturing a component, especially for being used in gas turbines and other turbo machinery, which is optimized for its use by local variations of its microstructure.
This object is obtained by a method according to claim 1.
The method according to the invention for manufacturing a component, especially for gas turbines and other thermo machinery, comprises the steps of:
An optimized component is achieved in that:
said additive manufacturing process is executed with one of said at least two process parameters being used during manufacturing a first of said at least two component volumes, resulting in a first recrystallization behavior in said first component volume, and with the other of said at least two process parameters being used during manufacturing a second of said at least two component volumes, resulting in a second recrystallization behavior different from said first recrystallization behavior, in said second component volume; and
According to an embodiment, the recrystallization behavior comprises a recrystallization temperature, the first recrystallization behavior comprises a first recrystallization temperature and the second recrystallization behavior comprises a second recrystallization temperature, and that said manufactured component is subjected to a heat treatment, with a holding temperature that lies between said first and second recrystallization temperatures. This results in a temperature above the recrystallization temperature of at least one of said at least two volumes, resulting in recrystallization of all volumes having a recrystallization temperature below the holding temperature, whereas the typical small grained, anisotropic microstructure of the as-built condition is maintained in all volumes having a recrystallization temperature above the holding temperature.
According to an embodiment, the recrystallization behavior comprises a change in grain size (recrystallized grain size), the first recrystallization behavior comprises a first grain size and the second recrystallization behavior comprises a second grain size different from the first grain size, and wherein the holding temperature (T_HT) lies above a recrystallization temperature of at least two of said at least two component volumes. This results in a first grain size in at least one of said at least two volumes and in a second grain size in the other of said at least two volumes. Different recrystallization behaviors can result in different grain sizes.
According to an embodiment, at least three different component volumes are provided, namely a first component volume, a second component volume and a third component volume, are defined and three process parameters (A, B, C) are chosen such that after the heat treatment at the holding temperature (T_HT) the first component volume has a first grain size (which may be unchanged from the first grain size prior to heat treatment, in which case it is still the non-recrystallized grain size), the second component volume has a second grain size and the third component volume has a third grain size, wherein the first grain size, the second grain size and the third grain size are different from one another. Preferably, the first component volume has a recrystallization temperature above the holding temperature, and the second and third component volumes have recrystallization temperatures below the holding temperature.
According to an embodiment of the invention said additive manufacturing process is a Selective Laser Melting (SLM) process.
Specifically, the material of said component is one of a high temperature Ni-, Co- and Fe-based alloy.
Specifically, said at least two process parameters differ in at least one of the following characteristics:
According to another embodiment of the invention in use of said component the first of said at least two different component volumes is subjected to a creep load and the second of said at least two different component volume is subjected to an LCF load, and said process parameters and said subsequent heat treatment temperature are chosen such that a coarse recrystallized grain structure is established in said first component volume, and a fine grain structure is established in said second component volume.
According to another embodiment of the invention said component is part of a turbo machine, especially a gas turbine. Specifically, said component is a blade of a gas turbine. Even more specifically, said blade has a leading edge and a trailing edge, that component volumes at said leading edge and said trailing edge are manufactured with a fine grain structure suitable for LCF-loaded areas, and the component volume between said leading edge and said trailing edge is manufactured with a coarse recrystallized grain structure suitable for creep-loaded areas.
Preferably said component processed by SLM is made of a Ni-based superalloy, that said at least two process parameters (A, B) are chosen, such that the resulting recrystallization start temperatures (T_RX_A, T_RX_B) lie in a range around 1200° C. and differ by at least 20° C.
Preferably, the heat treatment comprises the step of applying fast heating with a heating rate of at least 25° C./min.
Preferably, the step of manufacturing includes building up a crystallographic orientation (a preferred crystallographic orientation), and the heat treatment removes the crystallographic orientation in at least one component volume. The crystallographic orientation may comprise one or more orientations, for example a primary orientation and a secondary orientation. The heat treatment may remove one or more of the orientations.
The present invention is now to be explained more closely by means of different embodiments and with reference to the attached drawings.
The present invention discloses a method to produce parts/components, especially for differently loaded parts of turbo machines like gas turbines, fabricated by additive manufacturing techniques (e.g. selective laser melting SLM) with selectively tailored grain size, which is for example optimized for the site-specific load. By applying different specific process parameter settings to different areas of the part, the recrystallization behavior can be tuned such that after a suitable heat treatment, different microstructures are obtained in the different areas of the manufactured part. For example, the start temperatures of these areas can be tuned such that a heat treatment temperature can be found at which only the desired areas recrystallize. In another example, the grain size resulting after recrystallization can be tailored such that after heat treatment at a temperature where more than one of the different areas recrystallize, different grain sizes are obtained in these different, recrystallized areas.
Choosing suitable process parameters and subsequent heat treatment temperatures, grain structures can be locally set. For example, coarse recrystallized grain structures and/or fine recrystallized grain structures can be locally set, for example in creep loaded regions (or volumes) (e.g. between leading and trailing edge of a blade), while a fine grain structure (such as a fine anisotropic non-recrystallized grain structure) is kept in other regions, for example LCF (Low Cycle Fatigue) loaded regions (e.g. at the leading and trailing edge of a blade).
The present invention is based upon the finding that the recrystallization behavior (for example the recrystallization temperature and/or the recrystallization grain size) of SLM-generated material strongly depends on the processing parameters applied. The recrystallization temperature (or recrystallization start temperature) is the minimum temperature at which recrystallization occurs. The recrystallization temperature depends on the driving force for recrystallization in the material, mainly the dislocation density, residual stresses and initial grain size before heat treatment. The resulting grain size after recrystallization is determined by the grain nucleation density, which mainly depends on the dislocation density and the initial grain size before heat treatment. These driving forces and the grain nucleation density can be influenced by the SLM processing parameters (laser power, scan velocity, layer thickness, hatch distance, laser beam diameter, second area exposure, etc.).
It is proposed to define two or more process parameters A and B, which result in different driving forces in the SLM-processed material and therefore in different recrystallization start temperatures T_RXA and T_RX_B (RX stands for recrystallization), whereas T_RX_A>T_RX_B, meaning that a higher heat treatment (HT) temperature is required in order that a material processed with parameter settings A recrystallizes.
The component to be manufactured, e.g. a turbine blade or vane, is then divided into volumes in which a coarse recrystallized grain size is desired (CA2 in blade 10 of
After slicing the 3D file of the component (blade 10 in
After the SLM process, a component is obtained in which the microstructure is mostly homogenous and does not or only slightly differs between A volumes CA1, CA3 and B volume CA2 (see
The part (in this case blade 10) is then subjected to a recrystallization heat treatment HT, whose holding temperature T_HT lies between T_RX_A and T_RX_B (see
If three or more different process parameters are used, by said approach three or more component volumes can be obtained in which one or more volumes have a recrystallization start temperature below the heat treatment holding temperature, resulting in an recrystallized microstructure in which the grain size, which depends on the internal driving force, is defined by the process parameters, and in which further volumes can have recrystallization start temperatures above the heat treatment holding temperature which result in a non-recrystallized microstructure.
The sizes of the one or more different volumes which are processed with at least two different process parameters can be in the region of the component size itself down to sizes in the micrometer range, limited only by the thickness of the layer or the scan line dimensions used in the selected additive manufacturing process. The different volumes can be related to the part's geometry or loading, for example.
In one example, in the three different regions shown in
The methods are similar with three or more process parameters to the description above for two process parameters. After slicing the 3D file of the component into layers, areas which lay within A volumes CA1 and CA3 are processed with process parameter A, areas laying in B volume CA2 are processed with parameter set B (see
After the SLM process, a component is obtained in which the grain microstructure is mostly homogenous and does not or only slightly differs between A volumes CA1, CA3, B volume CA2 (see
The part (in this case blade 10) is then subjected to a recrystallization heat treatment HT, whose holding temperature T_HT lies between T_RX_A and T_RX_C/T_RX_B (see
An example HT is as follows:
1) heat the component from room temperature (RT) up to a temperature T1, wherein T1 is 50 to 100° C. less than a temperature Ts, at which a drop of the coefficient of thermal expansion starts, then
2) hold the component for a time t1 at T1 to achieve a uniform component temperature, then
3) heat the component by applying a fast heating with a heating rate of at least 25° C./min to a temperature T2 of at least 850° C., then
4) apply further time/temperature steps to the component depending on the purpose of the heat treatment.
This HT could be appropriate for a component made of a gamma prime strengthened superalloy based on Ni or Co or Fe or combinations thereof, for example, such as in European patent application number EP14167904.3 (method for post-built heat treatment of additively manufactured components made of gamma-prime strengthened superalloys), which is hereby incorporated by reference, particularly with reference to claims 1 to 6.
Using this method, the grain size can be easily tailored in the component with no geometric restriction regarding the different areas. As shown in
An SLM-generated material shows a considerable crystallographic anisotropy, for instance, in case of Ni-based alloys, a strong preferential [100] orientation in the build-up direction. By adjustment of a suitable scanning strategy, also a second preferential axis can be created in the build-up plane, resulting in a pseudo-SX like crystallographic microstructure (polycrystalline, but with three distinct preferred crystallographic directions). An additional embodiment/advantage can also be that the preferred crystallographic [100] orientation (=low Young's modulus) can be maintained at regions (volumes) where it is advantageous (e.g. TMF loaded regions) and recrystallized in regions where no such anisotropy is desired. If the part geometry allows a suitable build orientation, the resulting preferred orientation can be optimized to the prevailing load type (e.g. by choosing a [100] direction (low Young's modulus) along a direction where thermomechanical fatigue is dominant). However, the prevailing load type and direction is likely to change throughout a component and it is possible that the part geometry does not allow using the optimal build up direction. Therefore the anisotropy is not always desired. Further details of this method are described in European patent application EP 12008074.2 (published as EP 2737965) and European patent application EP 13157266.1 (published as EP 2772329), both of which are hereby incorporated by reference. In particular, claims 1 to 12 of EP 12008074.2 and claims 1 to 17 of EP 13157266.1 are relevant.
In order to result in a different driving force for recrystallization and therefore in a different recrystallization behavior (e.g. a different recrystallization temperature T_RX or a different recrystallization grain size), the process parameters (e.g. A and B or A, B and C) must differ in at least one of the following characteristics:
This can be various different shapes and depths)
The method presented here is most interesting for materials such as Ni-, Co-, Fe-based alloys used at high temperature.
However, the general approach is not limited to this class of materials, but can also be applied for all other metal classes processed with SLM where there is an advantage in tailoring the mechanical properties within a component.
As an example, for SLM generated parts made of a Ni-based superalloy recrystallization start temperatures T_RX_A and T_RX_B around 1200° C. may be achieved with a difference between both temperatures of 20° C. or more.
The SLM process can be executed with following parameter ranges:
1. Parameter range:
2. Value of how much the parameters should be changed:
3. Parameter effects (examples):
Number | Date | Country | Kind |
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14195477.6 | Nov 2014 | EP | regional |