Patent Grant
9975270
The invention relates to a method for manufacturing an aerogel-containing composite and the novel aerogel-containing composite produced by that method. The invention also relates to an apparatus suitable for carrying out the method of the invention.
It has previously been attempted to provide an aerogel-containing composite for use as an insulating material. For example WO 97/10187 A1 relates to a composite aerogel material and a method for manufacturing an aerogel containing composite comprising the steps of providing fibres in an amount of from 0.1 to 40%-vol, providing an aerogel particulate material having an average particle diameter smaller than 0.5 mm in an amount of from 5 to 97%-vol, providing a resin binder, mixing the ingredients, and consolidating the ingredients by subjecting the material to hot pressing. No information is provided in the specification regarding the method used to mix the various components of the composite and how this affects the properties of the finished product. In particular, the skilled man is unable to achieve a homogeneous composite based on the information disclosed.
Another example can be found in US 2003/0077438 A1, which also relates to a composite aerogel material and a method for providing a composite aerogel material comprising the steps of providing fibres in an amount of from 0.1 to 40%-vol, providing an aerogel particulate material having an average particle diameter of at least 0.5 mm in an amount of from 5 to 97%-vol, providing a resin binder, mixing the ingredients, and consolidating the ingredients by subjecting the material to hot pressing. However, this document provides no information regarding the method used to mix the components of the composite and how this affects the properties of the composite. It does not teach the skilled person how to achieve a high level of homogeneity in the composite.
One of the main problems of previous aerogel containing composites and methods for manufacturing thereof is lack of cohesion and mechanical strength of the composites.
It is therefore an object of the present invention to provide an aerogel-containing composite having high mechanical strength and cohesion, and a method for manufacturing the composite.
According to the invention this object is achieved with a method for manufacturing an aerogel-containing composite, said method comprising the steps of: providing fibres, at least some of which are first fibres, such as mineral fibres, polymer fibres, cellulose fibres, or other types of fibres, in an amount of from 3 to 80 wt % of the total weight of starting materials, providing an aerogel particulate material in an amount of from 10 to 75 wt % of the total weight of starting materials, providing a binder in an amount of from 1 to 30 wt % of the total weight of starting materials, suspending the fibres in a primary air flow and suspending the aerogel particulate material in the primary air flow, thereby mixing the suspended aerogel particulate material with the suspended fibres, mixing the binder with the fibres and/or aerogel particulate material before, during or after mixing of the fibres with the aerogel particulate material, collecting the mixture of fibres, aerogel particulate material and binder and pressing and curing the mixture to provide a consolidated composite with a density of from 120 kg/m3 to 800 kg/m3.
The percentages mentioned are based on dry weight of starting materials.
With the method according to the invention as defined above a very versatile and cost efficient method for manufacturing an aerogel containing composite is achieved. A wide range of properties in terms of e.g. mechanical strength, thermal insulation capability etc can be produced by altering the quantity of each component. This means that with the same method a variety of different composites can be made that are tailor-made for specific purposes.
Furthermore it has been found that mixing the fibres and the aerogel particulate material as a suspension in an air flow provides a surprisingly homogeneous composite, especially considering the considerable differences in the aerodynamic properties of these materials. This high level of homogeneity in the composite results generally in an increased level of mechanical strength relative to the composites of the prior art for a given combination of quantities of the components. The increased homogeneity of the product also has other advantages such as aesthetic appeal and consistency of properties throughout a single product.
We believe that as a result of mixing the aerogel particulate material with the fibres when suspended in an air flow, as in the present invention, the aerogel particulate material is allowed to penetrate into the tufts of fibres that are present. In contrast, when the mixing process involves physical contact of, for example, a stirrer with the fibres, the fibres tend to form compact balls, which the aerogel particulate material cannot penetrate easily. The result of this can be that, in cases where the mixing process involves physical contact, the final product contains areas where the aerogel and the fibres are visibly separated in distinct zones.
Adding further materials may change specific properties of the composite produced by the method.
According to an embodiment the method comprises an intermediate step of providing second fibres of a material different from the material of the first fibres, such as mineral fibres, polymer fibres, cellulose fibres, or other types of fibres, in an amount of 3 to 80 wt % of the total weight of starting materials. Second fibres can be added in the process on top of the first fibres or as a substitute for some of the first fibres. Hereby the method can be made more versatile producing composites tailor made for a specific purpose.
Preferably, the total quantity of fibres in the composition does not exceed 80% by weight of the total weight of starting materials.
According to an embodiment the first fibres are mineral fibres, such as stone wool fibres. Mineral fibres are strong, fire-proof and inorganic, and hence resistant to e.g. mould. Stone wool fibres have been tested with good results in the process.
According to an embodiment the second fibres are polymer fibres. When heated polymer fibres get sticky, and this characteristic can be beneficial in some processes and products. Polymer fibres can substitute some of the binder.
In a particularly preferred embodiment, the first fibres are mineral fibres and the second fibres are polymer fibres. This embodiment in particular provides high levels of strength and cohesion.
Binder can be added at any suitable point in the process, however according to an embodiment, the step of mixing binder with the fibres is performed before suspending the fibres in the primary air flow, such as at production of the fibres. It should be understood that the binder can be a liquid binder added during production of the fibres as is conventional at production of for example mineral wool fibres. Alternatively or supplementarily, liquid or dry binder can be added at any convenient time and place in the process. Supplying liquid binder at production of the fibres is a relatively easy and low-cost solution. On the other hand the liquid binder may contaminate the process line requiring more cleaning and maintenance. Further, it may be advantageous to add binder later in the process to enable more precise and variable amounts of binder.
An aspect of the invention relates to an aerogel-containing composite obtainable by the method of the invention.
The invention further relates to an aerogel-containing composite comprising:
first fibres in an amount of from 3 to 80 wt % of the total weight of starting materials, aerogel particulate material in an amount of from 10 to 75 wt % of the total weight of starting materials, binder in an amount of from 1 to 30 wt of the total weight of starting materials, wherein the composite is substantially homogeneous and is cured and pressed to a density between 120 kg/m3 and 800 kg/m3.
By the wording “substantially homogeneous” it should be understood that the composite is visually homogeneous at a scale related to the largest discrete ingredient, e.g. 10 times the size of the largest particulate. For a particle size of say 1 mm (largest dimension) a visual investigation of an area of e.g. 100 mm2 is (substantially) identical to other samples of the mixture. It further means that after mixing, the materials are distributed substantially evenly within the composite, i.e. that the aerogel particulates are present in substantially the same amount in the whole composite with no visual accumulations.
An embodiment of the invention relates to a composite further comprising second fibres of a material different from the material of the first fibres, such as mineral fibres, polymer fibres or cellulose fibres, in an amount of 3 to 80 wt % of the total weight of starting materials. Such second fibres may be added to provide certain properties of the composite or to facilitate the production method, or substitute some of the first fibres in order to save cost or provide certain properties of the composite.
It has also been found that the composites of the present invention as a result of their homogeneity can be machinable in a similar way to wood. By “machinable” it should be understood that the composite can be machined in ordinary wood forming machinery, such as saws and shaping machines, e.g. grooving machines, surface milling cutters etc.
The composites according to the invention have a variety of uses, predominantly as building elements. In particular, the products can be in the form of panels. In general, the products are used in applications where mechanical stability and an even surface finish as well as insulating properties are important. In some applications, the panels can be used as acoustically absorbing ceiling or wall panels. In other applications, the panels can be used as insulating outer cladding for buildings.
In an embodiment the aerogel-containing composite further comprises a fleece cover layer on at least one of the composite surfaces. The fleece cover layer may be a web of woven or non-woven glass fibre fleece or felt. Such a fleece cover layer can increase the integrity of the composite and lower the risk of damage to the surface of the composite. The fleece cover layer may be adhered to the composite surface after production or as an integral part of the production. For example the composite raw materials may be collected directly on the fleece cover layer and subsequently cured and pressed with the fleece cover layer acting as carrier web during production. Hereby the composite surface will be protected during production.
Preferably the thickness of the panel is from 4 to 25 mm. In some embodiments, especially where the panel is used as cladding on a building, the thickness of the panel is preferably from 4 to 12 mm, more preferably from 5 to 10 mm and most preferably from 6 to 8 mm. In alternative embodiments, especially where the panel is used as an insulation panel for a wall of a ceiling, the thickness of the panel is preferably from 12 to 25 mm, more preferably from 15 to 23 mm and most preferably from 18 to 21 mm.
“Aerogel” when used in the broader sense means a gel with air as the dispersion medium. Within that broad description, however, exist three types of aerogel, which are classified according to the conditions under which they have been dried.
These materials are known to have excellent insulating properties owing to their very high surface areas, and high porosity. They are manufactured by gelling a flowable sol-get solution and then removing the liquid from the gel in a manner that does not destroy the pores of the gel.
Where a wet gel is dried at above the critical point of the liquid, there is no capillary pressure and therefore relatively little shrinkage as the liquid is removed. The product of such a process is very highly porous and is known as an aerogel, the term being used in the narrow sense. On the other hand, if the gel is dried by evaporation under sub-critical conditions, the resulting product is a xerogel. In the production of a xerogel, the material usually retains porosity and a large surface area in combination with a small pore size.
In the wider sense of the word, aerogels also encompass dried gel products, which have been dried in a freeze-drying process. These products are generally called cryogels.
The term “aerogel” in its broader sense of “gel having air as the dispersion medium” encompasses each of aerogels in the narrower sense, xerogels and cryogels. As used herein, the term “aerogel” denotes aerogels in the broader sense of a gel having air as the dispersion medium.
The aerogel used in the present invention is in particulate form. In a preferred embodiment, the particles of aerogel will have an average diameter of from 0.2 to 5 mm. More preferably, the average diameter of the particles in the aerogel particulate material will be from 0.3 to 4 mm. and most preferably the average diameter of particles in the aerogel particulate material will be from 0.7 to 1.2 mm. These particle sizes are measured as weight averages and refer to the particle size of the starting material, rather than that present in the final composite.
During the method of the invention, in some embodiments, the average particle size of the aerogel can be reduced, as a result of the method steps used.
The aerogel particulate material can be any type of aerogel. In particular, the aerogel can be organic or inorganic. In view of their fire-resistant properties, inorganic aerogels are usually preferred. Organic aerogels include carbon aerogels and polymeric aerogels. Organic aerogels generally have a lower price and better insulation properties. Preferred inorganic aerogels are based on metal oxides. Particularly preferred materials are silica, carbides and alumina. Silica aerogels, such as “Nanogel® Aerogel” from Cabot International are most preferred.
The aerogel particulate materials have a low density, typically from 0.01 g/cm3 to 0.3 g/cm3. The thermal conductivity of the aerogel particulate material is preferably from 5 to 20 mW/mK, more preferably from 7 to 16 mW/mK and most preferably from 9 to 12 mW/mK.
The precise quantity of fibres used in the method and present in the composite of the invention is chosen so as to maintain appropriate strength and appropriate thermal insulation value, depending on the appropriate application. The type of fibre and the amount of fibres will influence the strength and the thermal insulation value of the composite. It should be noted that the amount of fibres is measured in terms of weight percentage for practical reasons, so the relative amount of fibres (number of fibres or volume percentage of fibres) is dependent on the density of the fibres, and also dependent on the density of other materials in the composite. A high quantity of fibres increases the strength of the composite, but decreases the thermal insulation value. This means that the lower limit of 3 wt % results in a composite having unusually good thermal insulation properties, and only adequate strength, which may be advantageous for some composites, where the strength is less important. If the quantity of fibres is low, extra binder may be added in order to increase strength.
The first and/or second fibres can be non-mineral wool fibres, such as polymer fibres or cellulose fibres. These fibres have inherent densities in the 800 to 1200 kg/m3 range, about one third that of mineral wool fibres (2800 kg/m3). While the properties of the final composite depend on the choice of fibre, it is clear that mechanically robust insulating composites can be prepared at lower fibre mass loadings, i.e from 3 to 30%, 7 to 30%, 15 to 30%, by replacing mineral wool fibres one for one with non-mineral wool fibres.
Alternative fibre materials include for example aramid fibres and polyethylene fibres (PE). Such alternative fibres may be added to obtain a more cost effective composite or in order to further improve strength. PE fibres will get sticky when heated and hence act as an additional binder.
If strength of the composite is particularly important the amount of first fibres, and in particular mineral fibres, can be increased to the upper limit of 80 wt %, but this will generally result in only adequate thermal insulation properties. For a majority of applications a suitable composition will include a first fibre amount of from 30 to 70 wt % or from 40 to 70 wt % if the fibres are relatively heavy fibres, such as stone wool fibres. Most usually, a suitable quantity of first fibres will be from 50 to 60 wt % especially if the fibres are for example stone wool fibres. If relatively light fibres are used for the first fibres, such as cellulose fibres, the weight percentages of first fibres may be lowered by e.g. up to one third. Hence the first fibre amount may then be from 10 to 25 wt % or from 14 to 25 wt %, such as from 16 to 20 wt %. If second fibres are added, the amount of first fibres may be reduced as discussed above. Similarly the weight percentage of first or second fibres may be reduced by addition of fillers, which add to the total weight of the product.
Similarly the amount of aerogel particulate material used is chosen in order to provide both appropriate strength and thermal insulation value, as a high amount of aerogel particulate material decreases the strength of the composite, but increases the thermal insulation value. This means that the lower limit of 10 wt % aerogel particulate material results in a composite having excellent strength, but mediocre thermal insulation properties, which may be advantageous for some composites, where the strength is very important. If thermal insulation value of the composite is important the amount of aerogel particulate material can be increased to the upper limit of 75 wt %, but this will result in mediocre strength. For a majority of applications a suitable composition will include an aerogel particulate material amount of from 30 to 60 wt %, from 35 to 55 wt % or most typically from 40 to 50 wt %. Again the relative amount of aerogel is influenced by the densities of other materials added, which should be kept in mind.
The amount of binder is also chosen on the basis of desired strength and cost, plus properties such as reaction to fire and thermal insulation value. The lower limit of 1 wt % results in a composite with a lower strength, which is however adequate for some applications, and has the benefit of relatively low cost and potential for good thermal insulation properties. In applications where a high mechanical strength is needed, a higher amount of binder should be used, such as up to the high limit of 30 wt %, but this will increase the cost of the resulting product and further the reaction to fire will often be less favourable, depending on the choice of binder.
It is believed that the binder does not connect to the aerogel particles. Instead only the fibres are connected by the binder, and the aerogel particles are believed to be entrapped between the fibres in the composite after curing of the binder. Advantages of the indirect, mechanical retention of aerogel particles include that the mechanical properties of the resulting composite will not be compromised by the relatively brittle aerogel particles. Further the insulation properties of the aerogel particles will not be compromised by the binder, which would be the case if binder connected to the surface of the aerogel particles. Furthermore the small aerogel particles would consume a lot of binder due to the large surface area. The connection of fibres to other fibres by the binder, but not of fibres with aerogel is particularly prevalent in embodiments in which the aerogel particles are hydrophobic and highly non-polar, and in which the binder used is a polar binder such as novolac dry binder. In these embodiments especially, the binder will bind to the surfaces of the fibres, but will not bind to the surface of the aerogel particulate material.
A further advantage of the aerogel particles being entrapped between the fibres in the composite is that this makes it possible to glue together composite boards. Pure aerogel boards are very difficult to glue together because of the hydrophobic and highly non-polar nature of the aerogel. By having the aerogel particles entrapped in a fibre structure it is possible to glue together composite boards, which is believed to be due to the glue bond to the fibre structure.
In embodiments in which the first fibres and/or second fibres are mineral fibres, the mineral fibres (also known as man-made vitreous fibres or MMVF) could be any mineral fibres, including glass fibres, ceramic fibres or stone fibres, but preferably, stone fibres are used. Stone wool fibres generally have a content of iron oxide at least 3% and alkaline earth metals (calcium oxide and magnesium oxide) from 10 to 40%, along with the other usual oxide constituents of mineral wool. These are silica; alumina; alkali metals (sodium oxide and potassium oxide) which are usually present in low amounts; and can also include titania and other minor oxides. Fibre diameter is often in the range 3 to 20 microns, in particular 5 to 10 microns, as conventional.
In one embodiment, the mineral fibres include glass fibres preferably in an amount up to 20%, more preferably up to 15% and most preferably up to 10% of the total weight of starting materials. The remaining mineral fibres are preferably stone fibres. The glass fibres preferably have a length of from 10 mm to 50 mm, more preferably from 15 mm to 40 mm and most preferably from 20 mm to 30 mm. These glass fibres serve to reinforce the composite.
In one embodiment, the fibres are provided in the form of a collected web and the method further comprises subjecting the collected web of fibres to a disentanglement process. The disentangled fibres are subsequently suspended in the primary air flow.
As used herein, the term “collected web” is intended to include any fibres (e.g. mineral fibres) that have been collected together on a surface, i.e. they are no longer entrained in air, e.g. granulate, tufts or recycled web waste.
The collected web could be a primary web that has been formed by collection of fibres on a conveyor belt and provided as a starting material without having been cross-lapped or otherwise consolidated. Alternatively, the collected web could be a secondary web that has been formed by cross-lapping or otherwise consolidating a primary web. Preferably, the collected web is a primary web.
A feeding mechanism may be provided for feeding in a web. The feeding mechanism may comprise a set of driven feed rollers. For example the web may be gripped between the feed rollers to be driven by the feed rollers for controlled advancing of the web to the disentanglement process.
In one embodiment, the disentanglement process comprises feeding the web of fibres (e.g. mineral fibres) from a duct with a lower relative air flow to a duct with a higher relative air flow. In this embodiment, the disentanglement is believed to occur, because the fibres that enter the duct with the higher relative air flow first are dragged away from the subsequent fibres in the web. This type of disentanglement is particularly effective for producing open tufts of fibres, which can be penetrated by the aerogel particulate material.
The speed of the higher relative air flow is from 20 m/s to 150 m/s or from 30 m/s to 120 m/s. More preferably it is from 40 m/s to 80 m/s and most preferably from 50 m/s to 70 m/s. The higher relative air flow can be separate from the primary air flow, but more usually, it will feed into the primary air-flow.
Preferably, the difference in speed between the lower relative air flow and the higher relative air flow is at least 20 m/s, more preferably at least 40 m/s and most preferably at least 50 m/s.
As used herein, the term “air flow” should be understood broadly so as to include not only a flow of air comprising gases in the proportions present in the atmosphere of Earth, but also a flow of any suitable gas or gases in any suitable proportions.
According to a particularly preferred embodiment, the disentanglement process comprises feeding the collected web to at least one roller which rotates about its longitudinal axis and has spikes protruding from its circumferential surface. In this embodiment, the rotating roller will usually also contribute at least in part to the higher relative air flow. Often, rotation of the roller is the sole source of the higher relative air flow.
In some embodiments there are at least two rollers. These rollers may operate in tandem or sequentially. The rollers are described in further detail in relation to the apparatus of the invention.
The roller may be of any suitable size, but in a preferred embodiment, the roller has a diameter based on the outermost points of the spikes of from 20 cm to 80 cm or more preferably from 30 cm to 70 cm. Even more preferably the diameter is from 40 cm to 60 cm and most preferably from 45 cm to 55 cm.
The roller may rotate at any suitable speed. For most embodiments a suitable rate of rotation for the roller is from 500 rpm to 5000 rpm, preferably from 1000 rpm to 4000 rpm, more preferably from 1500 rpm to 3500 rpm, most preferably from 2000 rpm to 3000 rpm.
The dimensions and rate of rotation of the roller can be selected to provide a given speed at the circumference of the roller. In general, a high speed will result in a more effective disentanglement process, although this will depend on the type of web of mineral fibres use and the exact form of the roller. In most embodiments it will be suitable for the outermost points of the spikes of the roller to move at a speed of from 20 m/s to 150 m/s, preferably from 30 m/s to 120 m/s, more preferably from 40 m/s to 80 m/s and most preferably from 50 m/s to 70 m/s.
The spikes may be permanently fixed to the roller for optimum resistance to wear and tear. For example the spikes may be fixed by gluing or welding the spikes in blind holes arranged in the roller outer periphery. Alternatively the spikes may be replaceable. This can for example be accomplished by the roller being a hollow cylinder with through holes in the cylindrical wall. The spikes can then for example have a head and be inserted through the holes from inside through the holes. Hereby spikes can be replaced if they are broken or worn. Further by having replaceable spikes it is possible to change the pattern of the spikes. Hereby it is possible to optimize the pattern for different types of material to be disentangled, e.g. loose mineral wool fibres, or a collected web of mineral wool fibres impregnated with a liquid binder.
The roller is preferably positioned within a substantially cylindrical chamber. The chamber will have an inlet duct through which the fibres (e.g. mineral fibres) and optionally the aerogel particulate material and binder are fed to the roller. The chamber will also have an outlet through which the disentangled mineral fibres and optionally the aerogel particulate material and binder are expelled. Preferably, they are expelled in the primary air flow through the outlet.
In preferred embodiments, the fibres and optionally the binder and aerogel particulate material are fed to the roller from above. It is also preferred for the disentangled fibres (e.g. mineral fibres) and optionally the binder and aerogel particulate material to be thrown away from the roller laterally from the lower part of its circumference. In the most preferred embodiment, the fibres are carried approximately 180 degrees by the roller before being thrown off.
The roller preferably occupies the majority of the chamber. Preferably the tips of the spikes are less than 10 cm, more preferably less than 7 cm, and most preferably less than 4 cm from the curved wall of the substantially cylindrical chamber. This results in the air flow created by the roller being greater and a more thorough disentanglement of the fibres by the air flow and by the spikes themselves.
Preferably, the fibres are fed to the roller from above.
The disentangled fibres are generally thrown off the roller in the primary air flow. In some embodiments, the roller will contribute to the primary air flow. In other embodiments, the roller will be the sole source of the primary air flow.
When present, the second fibres may be added at any suitable point in the process. In a preferred embodiment, the second fibres are provided to the primary air flow. This allows thorough mixing of the second fibres with the first fibres, aerogel particulate material and binder. Where a disentanglement process is carried out, the second fibres are preferably subjected to the disentanglement process together with the first fibres to further improve mixing.
The aerogel particulate material can be carried to the primary air flow in any suitable manner.
In one embodiment, a disentanglement process is used and the aerogel particulate material is added to the collected fibre web prior to the fibre disentanglement process and is suspended in the primary air flow together with the disentangled fibres. This method of addition of the aerogel particulate material generally promotes the most effective mixing of the components. In this embodiment, the aerogel particulate material can be pre-mixed with the collected mineral fibre web and optionally the binder in any suitable manner.
Alternatively, the aerogel particulate material can be carried to the primary air flow suspended in a tributary air flow. The tributary air flow is combined with the primary air flow, thereby mixing the aerogel particulate material with the fibres.
In some embodiments, it is not necessary to use a fibre disentanglement process. In one embodiment, the fibres (e.g. mineral fibres) are provided as fibres entrained in air direct from a fibre-forming process. By this it should be understood that the fibres, having been entrained in air in the formation process (e.g. having been thrown from a spinner) are not collected on a surface, but are transported as a suspension in air into the primary air flow.
In this embodiment, the aerogel particulate material may be supplied direct to the primary air flow, or carried to the primary air flow suspended in a tributary air flow. The tributary air flow is combined with the primary air flow, thereby mixing the aerogel particulate material with the fibres.
Where a tributary air flow carries suspended aerogel particulate material to the primary air flow, the speed of the tributary air flow is generally lower than that of the primary air flow. Typically, the tributary air flow has a speed of from 1 to 20 m/s, preferably from 1 to 13 m/s, more preferably from 2 to 9 m/s and most preferably from 3 to 7 m/s.
According to the invention, the fibres and the aerogel particulate material are suspended in a primary air flow. This allows the components to mix intimately. An advantage of mixing as a suspension in an air flow is that unwanted particles or agglomerations can be sifted out. Such particles are e.g. pearls of the fibres and agglomerations are inter alia heavy chunks of wool, which have not been properly opened up to fibres, such as so-called chewing gum. In tests, mixing in an air flow performed surprisingly well, as it was expected that the very different physical and aerodynamic properties of the particles and the fibres would make this type of mixing impossible. It is remarkable that superior mixing takes place in spite of the difference in density and shape of the particles and fibres. The density of the aerogel particles is in the order of 140 kg/m3, whereas for example mineral wool fibres have a density in the order of 2,800 kg/m3. This might be expected to cause serious problems in the mixing process using an air flow, but surprisingly does not.
The primary air flow is generally not free from turbulence. In preferred embodiments, there is significant turbulence within the primary air flow as this promotes mixing of the aerogel particulate material with the mineral fibres. According to the present invention, the speed of the primary air flow at its source is preferably from 20 m/s to 150 m/s, more preferably from 30 m/s to 120 m/s, even more preferably from 40 m/s to 80 m/s and most preferably from 50 m/s to 70 m/s.
The primary air flow is preferably a generally lateral air flow. In embodiments where the aerogel particulate material is carried to the primary air flow suspended in a tributary air flow, the primary air flow is preferably generally lateral and the tributary air flow is generally upwards.
The primary air flow preferably enters a mixing chamber. In the mixing chamber, turbulence within the primary air flow allows more intimate mixing of the components.
In order to effect a thorough mixing of the fibres and particulate material, it is preferred to configure the apparatus such that the average dwell time of the aerogel particulate material and the fibres within the mixing chamber is at least 0.5 s, more preferably at least 2 s, or even at least 3 s.
However, due to the effectiveness of mixing the aerogel particulate material and the fibres suspended in a gas, it is usually not necessary for the average dwell time of the particulate material and the fibres within the mixing chamber to be greater than 10 s. More usually, the average dwell time is less than 7 s and most usually the average dwell time is less than 5 s.
The ambient temperature within the mixing chamber, when used, is usually from 20° C. to 100° C., more usually from 30° C. to 70° C. The temperature could be dependent on outside air temperature, i.e. cold in winter and hot in summer. Elevated temperatures of up to 100° C. could be used for providing a pre-curing of the binder in the mixing chamber.
In specific embodiments, the binder is a material that, under certain conditions, dries, hardens or becomes cured. For convenience, these and similar such processes are referred to herein as “curing”. Preferably, these “curing” processes are irreversible and result in a cohesive composite material.
Inorganic as well as organic binders can be employed. Organic binders are preferred. Further, dry binders as well as wet binders can be used. Specific examples of binder materials include but are not limited to phenol formaldehyde binder, urea formaldehyde binder, phenol urea formaldehyde binder, melamine formaldehyde binder, condensation resins, acrylates and other latex compositions, epoxy polymers, sodium silicate, hotmelts of polyurethane, polyethylene, polypropylene and polytetrafluoroethylene polymers etc.
In an embodiment a dry binder is used. Any suitable dry binder could be used, but it is preferred to use a phenol formaldehyde binder, as this type of binder is easily available and has proved efficient. It may be an advantage to use a dry binder as in some events mixing may be easy, and further the need for maintenance of the equipment is low. Further the binder is relatively stable and storable.
According to an alternative embodiment a wet binder is used. Wet binders have the advantage of low cost compared to dry binders, and it is often possible to reduce the amount of binder using wet binder compared to dry binders. A reduction in the amount of binder further results in a better reaction of the composite to fire. Any suitable wet binder could be used, but it is preferred to use a phenol formaldehyde binder, as this type of binder is easily available and has proved efficient.
The binder may be mixed with the fibres and/or aerogel particulate material before, during or after mixing of the fibres with the aerogel particulate material. In some embodiments, especially where the binder is wet, it is preferred to mix the binder with the fibres prior to the mixing of the fibres with the aerogel particulate material. In particular, the fibres can be in the form of an uncured collected web containing wet binder.
Alternatively, wet binder could be sprayed onto fibres entrained in air as they are carried to the primary air flow direct from a fibre-forming process.
When dry binder is used, this could, for example, be pre-mixed with a collected web of mineral fibres and optionally aerogel particulate material. Alternatively it could be supplied to the primary air flow separately and mixed in the primary air flow.
The fibres (e.g. mineral fibres), binder and aerogel particulate material, when suspended in the primary air flow, are, in some embodiments, subjected to a further air flow in a different direction to the primary air flow. This helps to generate further turbulence in the primary air flow, which assists mixing further. Usually the primary air flow is generally lateral and the further air flow is generally upwards. In some embodiments, a plurality of further air flows is provided.
Preferably the further air flow has a speed of from 1 to 20 m/s, more preferably from 1 to 13 m/s, even more preferably from 2 to 9 m/s and most preferably from 3 to 7 m/s.
The mixture of fibres, aerogel particulate material and binder is collected from the primary air flow by any suitable means. In one embodiment, the primary air flow is directed into the top of a cyclone chamber, which is open at its lower end and the mixture is collected from the lower end of the cyclone chamber.
In an alternative embodiment, the primary air flow is directed through a foraminous surface, which catches the mixture as the air flow passes through.
In embodiments where there is a disentanglement process before the fibres are suspended in the primary air flow, the mixture of fibres, aerogel particulate material and binder is preferably subjected to a further fibre disentanglement process after the mixture has been suspended in the primary air flow, but before the mixture is pressed and cured.
The further disentanglement process may have any of the preferred features of the disentanglement process described previously.
In a particularly preferred method, the mixture of fibres, binder and aerogel particulate material is removed from the primary air flow, preferably in a cyclone chamber, and fed to a rotating roller having spikes protruding from its circumferential surface. The roller of the further disentanglement means may have any of the features described above in relation to the roller to which the collected web can be fed initially.
The mixture of fibres, aerogel particulate material and binder is preferably thrown from the further disentanglement process into a forming chamber.
Having undergone the further disentanglement process, the mixture of fibres, aerogel particulate material and binder is collected, pressed and cured. Preferably, the mixture is collected on a foraminous conveyor belt having suction means positioned below it.
In a preferred method according to the invention, the mixture of aerogel particulate material, binder and fibres, having been collected, is scalped before being cured and pressed.
The method may be performed as a batch process, however according to an embodiment the method is performed at a mineral wool production line feeding a primary or secondary mineral wool web into the fibre separating process, which provides a particularly cost efficient and versatile method to provide composites having favourable mechanical properties and thermal insulation properties in a wide range of densities.
According to a special embodiment the method is performed as an on-line process in a mineral wool production line.
Once the mixture of fibres, aerogel particulate material and binder has been collected, it is pressed and cured to produce a composite of the desired density.
Pressure, temperature and holding time for the curing and pressing is dependent inter alia on the type of binder used. Examples of temperatures and holding times used in preliminary tests are mentioned below.
It should be noted that any of the preferred features of the final product described in relation to the method apply equally to the composite of the invention where relevant.
The invention also relates to novel apparatuses suitable for carrying out the method of the invention.
An apparatus for the production of an aerogel-containing composite comprising:
a fibre-forming apparatus for producing a supply of fibres entrained in air, binder supply apparatus for supplying binder to the fibres, a first collector arranged to receive the fibres from the fibre-forming apparatus, suction apparatus for applying suction through the collector and thereby collecting the fibres on the collector as a web, a disentanglement apparatus for disentangling the web to provide disentangled fibres, web supply apparatus for supplying the web to the disentanglement apparatus, aerogel particulate material supply apparatus positioned before or after the disentanglement apparatus, air supply apparatus for supplying a primary air flow in which to suspend disentangled fibres, a second collector for collecting the disentangled fibres, binder and aerogel particulate material, a press for pressing the collected fibres, binder and aerogel particulate material.
In one embodiment, the fibre-forming apparatus is a mineral fibre-forming apparatus. The mineral fibre-forming apparatus can be any apparatus suitable for that purpose, for example, a cascade spinner or a spinning cup. In preferred embodiments of the apparatus, the mineral fibre-forming apparatus is a cascade spinner. In each case, a mineral melt is supplied and fibres are produced by the effect of centrifugal action of the apparatus.
The binder supply means supplies binder to the fibres (e.g. mineral fibres). It can be positioned at any point before the second collector, but is preferably positioned between the fibre-forming apparatus and the first collector. In another embodiment, the binder supply means is positioned between the first collector and the second collector. In another preferred embodiment, the binder supply means is positioned between the first collector and the disentanglement means.
The binder supply means could be adapted to supply wet binder or to supply dry binder.
The first collector is preferably in the form of a continuously operated first conveyor belt. The belt is pervious to air. The fibres form a primary web on the belt. Suction means are positioned behind the first collector to allow an air flow through the collector.
The first apparatus may optionally comprise means for treating the primary web in any manner known to the person skilled in the art. For example, the apparatus can comprise a pendulum belt for cross-lapping the primary web onto a further continuously operated conveyor belt, to form a secondary mineral fibre web.
In a preferred embodiment, the first collector is in the form of a conveyor belt leading to an inlet duct. The inlet may have conveying rollers at its upper edge to assist with the movement of the fibres (e.g. mineral fibres) through the inlet duct.
Between the first collector and the disentanglement apparatus, in some embodiments, there is a substantially vertical duct. Often the substantially vertical duct will be narrower at its lower end than at its upper end.
The first apparatus comprises disentanglement means for disentangling the primary or secondary web to form disentangled fibres. In one embodiment, the disentanglement apparatus has a first duct for carrying the primary or secondary web and a second duct adjoined to the first duct. In this embodiment, the disentanglement apparatus comprises means for supplying an air flow in the second duct with a higher speed than is present in the first duct.
In particular, the disentanglement means can be in the form of a roller as described above in relation to the method of the invention. An embodiment of the roller is described in more detail below with reference to the drawing.
The first apparatus of the invention also requires air supply means for supplying the primary air flow. This air supply means can be formed as part of the disentanglement apparatus. For example, the means for supplying an air flow in the second duct with a higher speed than is present in the first duct could also be the supply of the primary air flow.
It is also possible for the roller to act as the means for generating the primary air flow itself as it creates a flow of disentangled mineral fibres suspended in an air flow.
According to an embodiment, the apparatus further comprises a supply means to supply optional second fibres. This supply means may be positioned at any suitable point before the press. In a preferred embodiment, the supply means to supply optional second fibres is arranged to supply the second fibres before the disentanglement apparatus. In another preferred embodiment, the supply means to supply optional second fibres is arranged to supply second fibres to the primary air flow.
According to an embodiment the apparatus may comprise a further disentanglement apparatus positioned to receive the mixture of fibres and aerogel particulate material. With such an extra disentanglement apparatus the mixture of fibres and aerogel particulate material may become very homogeneous.
An alternative apparatus for the production of an aerogel-containing composite comprises: a fibre supply apparatus for producing a supply of fibres suspended in a primary air flow, air supply apparatus for supplying the primary air flow, binder supply apparatus for supplying binder to the fibres, aerogel particulate material supply apparatus for supplying aerogel particulate material to the primary air flow, a collector for collecting the fibres, binder and aerogel particulate material, a press for pressing the collected fibres, binder and aerogel particulate material.
The fibre supply means may be any opening or conveyor to supply fibres to the apparatus. The fibres may be loose fibres or fibres collected to form a web. Where the fibres are in the form of a collected web, it may be necessary to provide a disentanglement apparatus to break up the web.
In one embodiment, the second apparatus further comprises a fibre-forming apparatus. The fibre-forming apparatus is preferably a mineral fibre-forming apparatus.
The mineral fibre-forming apparatus of the second apparatus of the invention, when present, can also be any apparatus suitable for that purpose, for example, a cascade spinner or a spinning cup. In preferred embodiments of the apparatus, the mineral fibre-forming apparatus is a cascade spinner.
In the second apparatus of the invention, air supply means are required for supplying the primary air flow. This can be in the form of a supply of cooling gas directed axially to the rotating wheels of a cascade spinner, in which fibres are carried from the spinner having been thrown off the wheel.
Binder supply means are positioned to supply binder, usually in the form of a spray to the fibres suspended in an air flow.
In both apparatuses of the invention, aerogel particulate material supply means are required. The aerogel particulate material supply means may comprise a hopper containing aerogel particulate material. Dosed supply of aerogel particulate material may be obtained by a screw feeder, weighing cell or any suitable means for precise dosing of particulate material.
In the first apparatus, although the aerogel particulate material must eventually be supplied to the primary air flow, it is not necessary that it is supplied from the supply means direct to the air flow. In fact, it is preferred to position the aerogel particulate material supply means to supply aerogel particulate material to the web of fibres (e.g. mineral fibres) and feed these together to the disentanglement apparatus. Where it is positioned before the disentanglement means, the aerogel particulate material is supplied to the primary air flow together with the disentangled fibres.
However, the aerogel particulate material supply means could also be positioned after the disentanglement means.
In the second apparatus and optionally in the first apparatus, the aerogel particulate material supply means is positioned to supply aerogel particulate material to the primary air flow. Optionally, a tributary air flow supply means can be positioned to supply a tributary air flow for carrying the aerogel particulate material to the primary air flow.
In both apparatuses, a further air flow supply means may be present for supplying a further air flow to the primary air flow.
Each of the apparatuses of the invention may further comprise a mixing chamber. The tributary and/or further air flow supply means, when present, are preferably positioned at the lower end of the mixing chamber and configured to supply an upwards flow of air within the mixing chamber. The primary air flow supply means is preferably positioned at the side of the mixing chamber and is configured to supply an air flow laterally across the chamber.
When present, the further air flow supply means may have a gauze disposed across its opening to prevent the entry of solid materials.
At the lower end of the mixing chamber, there is preferably a discharge opening into which heavy pellets or compacted fibres fall.
In preferred embodiments, the fibres, aerogel particulate material and binder enter the mixing chamber together at one side suspended in the primary air flow. The mixture is then blown upwards and further mixed by a further air supply means positioned at the lower end of the chamber. The mixture then leaves the mixing chamber via a removal duct at the upper end of the mixing chamber.
The removal duct leads eventually to a collector. In the first apparatus of the invention, this is the second collector. The collector may be in the form of a foraminous belt, behind which suction means are positioned.
Alternatively, the collection means could comprise a cyclone chamber capable of separating the mixture of mineral fibres, binder and aerogel particulate material from the primary air flow. In this embodiment, the cyclone chamber has an opening at its lower end, through which the mixture is ejected, whilst the air flow is removed through a duct at the upper end. The cyclone chamber has a greater diameter at its upper end than at its lower end.
In one embodiment the mixture is ejected from the cyclone chamber onto a conveyor belt.
In the first apparatus of the invention, there is preferably a further disentanglement apparatus positioned to receive the mixture of fibres, aerogel particulate material and binder. The further disentanglement apparatus may have any of the preferred features described in relation to the disentanglement apparatus for disentangling the collected web of fibres.
Preferably, the further disentanglement apparatus is positioned to receive the mixture of fibres, aerogel particulate material and binder from the opening at the lower end of the cyclone chamber.
Preferably, there is a forming chamber positioned to receive fibres from the further disentanglement apparatus. Preferably, the forming chamber comprises a foraminous conveyor belt for collecting the mixture of fibres, aerogel particulate material and binder.
In each of the apparatuses of the invention, it is preferred to provide scalping means prior to the press. The apparatus can be configured to recycle the scalped material.
Each of the apparatuses according to the present invention comprises a press for pressing and curing the collected mixture of mineral fibres, binder and aerogel particulate material. The press is suitable for pressing the composite to a density of from 120 kg/m3 to 800 kg/m3. Generally, the press is adapted to heat the composite in order to cure the binder.
Any of the preferred features described in relation to the method of the invention apply equally in relation to the apparatus. Similarly, any of the apparatus features disclosed above apply equally in relation to the method of the invention.
The invention will be described in the following by way of example and with reference to the drawings in which
Apparatus suitable for use in the method of the present invention can be seen in
Supply means to supply second fibres (not shown) can also be provided to supply second fibres to the inlet duct 1.
The apparatus comprises an inlet duct 1 for starting materials, e.g. aerogel particles, binder and mineral fibres and for specific raw materials the apparatus may comprise a shredder (not shown) at the inlet duct 1 to at least partly cut up bulky material. At the lower edge of the inlet duct, there is a conveyor 2 that carries the raw materials through the inlet duct 1. At the upper edge of the inlet duct, conveying rollers 3 assist with feeding the starting materials through the inlet duct 1. At the end of the inlet duct 1, a first set of mutually spaced elongate elements 4 extend across the end of the inlet duct 1. These serve to break up larger pieces of the starting materials, for example the mineral fibre web. In some embodiments, the elongate elements 4 are in the form of rotating brushes that draw the starting materials between them as they rotate.
The starting materials that pass through the end of the inlet then fall downwards into a substantially vertical duct 5. In the embodiment shown, a second set of mutually spaced elongate elements 6 extend across the upper end of the duct. The second set of elongate element is usually more closely spaced than the first. In the embodiment shown, the second set of elongate elements rotate so as to allow sufficiently small pieces of the mineral fibre web to pass through, but carry larger pieces away via a starting material recycling duct 7.
The vertical duct 5 generally becomes narrower at its lower end. In the embodiment shown, the lower end of the vertical duct forms the inlet 8 to the substantially cylindrical chamber 9. As shown, the inlet 8 is at an upper part of the substantially cylindrical chamber 9. In use, starting materials pass through the vertical duct 5 and through the inlet 8 into the cylindrical chamber 9.
The cylindrical chamber 9 houses a roller 10 having spikes 11 protruding from its circumferential surface 12. The roller 10 shown in
In the embodiment shown, the primary air flow is created by the rotation of the roller 10 within the cylindrical chamber 9, and in particular by the movement of the spikes 11 and starting material through the space between the circumferential surface of the roller and the curved wall 13 of the cylindrical chamber 9. The pattern of spikes 11 on the roller 10 may have some effect on the mixing process.
The mixing process is very complex and difficult to investigate. With the embodiment shown it is believed that most of the mixing takes place by the influence of the roller 10 and the spikes 11, whereas only a relatively small additional mixing takes place in the mixing chamber 14. It is believed there is some physical shearing and mixing of aerogel particulates and fibres effected by the spikes of the roller, but that the main effect of the spikes is the sudden increase in speed and turbulence of the air flow.
The mixing chamber 14 shown in
The further air flow meets the primary air flow containing the disentangled fibres in the mixing chamber. The further air flow has the effect of carrying the mixture of disentangled fibres, binder and aerogel particulate material upwards within the mixing chamber 14. Some more compacted fibres and pearls of mineral material will not be carried upwards in the mixing chamber, but fall to the lower end and through the discharge opening 16.
The desired mixture of disentangled fibres, aerogel particulate material and binder is carried to the upper part of the mixing chamber 14 where a removal duct 18 is positioned to carry the mixture from the mixing chamber 14. A first air recycling duct 19 is adjoined to the removal duct 18 and recycles some of the air from the removal duct 18 back to the further air supply means 15.
The removal duct leads to a cyclone chamber 20. The cyclone chamber 20 has a second air recycling duct 22 leading from its upper end to the further air supply means 15. A filter 21 is adjoined to the second air recycling duct. In use, the filter 21 removes any stray mineral fibres, aerogel particulate material and binder from the second air recycling duct 22. As air is removed from the upper end of the cyclone chamber 20, the mixture of disentangled fibres, aerogel particulate material and binder falls through a cyclone chamber outlet 23 at the lower end of the cyclone chamber 20.
A collector 24 is positioned below the cyclone chamber outlet 23. In the embodiment shown, the collector 24 is in the form of a conveyor, which carries the collected fibres to a pressing and curing apparatus (not shown).
Foraminous conveyor belt 27 carries the mixture to a press (not shown).
The photo in
The microscope photo of
The microscope photograph of
Similarly the microscope photograph of
A series of tests were carried out with different amount of the various ingredients, different types of binder etc. as can be seen in table 1 below. Panels were produced with dry powder binder, different types of aerogel, different types of fibres and different percentages of the ingredients. The table also show that it is possible to produce composites in a broad range of densities and ingredients showing the versatility of the method and apparatus according to the invention. As mentioned above it is believed that this versatility is mainly due to the homogeneous mixing with the apparatus and method.
As reflected by the tests listed in the table above composites of a wide range of compositions and densities were produced and with a lambda as low as 20.
The powder binder in the test is a dry phenol formaldehyde polymer binder of the type sold by Dynea under the trade name “Prefere 94 8182U7”.
The liquid binder in the test is a phenol formaldehyde binder.
Fibre type “Rockpanel” is loose stone wool fibres, whereas fibre type “Line 2” is an uncured web of stone wool fibres impregnated with a liquid binder.
Curing lasted approximately 15 minutes.
In tests, aerogel particulate material of the type “Nanogel® Aerogel” from Cabot International was used and showed excellent results.
The tests were carried out with stone wool fibres having a density of approximately 2,800 kg/m3.
In some tests fibres were provided in the form of a collected web and the collected web of fibres subjected to a disentanglement process. In other tests fibres were provided in the form of loose fibres.
The requirement for the composite of being substantially homogeneous is, in this case, considered fulfilled with a maximum variation of 5% in an X-Y plane co-planar with the major surfaces of the composite panel. A higher variation is accepted in the Z-plane, i.e. the thickness of the composite panel.
Similarly,
| Number | Date | Country | Kind |
|---|---|---|---|
| 10171506 | Jul 2010 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2011/063171 | 7/29/2011 | WO | 00 | 9/23/2013 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2012/013817 | 2/2/2012 | WO | A |
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| 20030077438 | Frank et al. | Apr 2003 | A1 |
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| Number | Date | Country | |
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| 20140087119 A1 | Mar 2014 | US |
| Number | Date | Country | |
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| 61369136 | Jul 2010 | US |
