The disclosure of Japanese Patent Application No. 2014-000082 filed on Jan. 6, 2014 including the specification, drawings and abstract, is incorporated herein by reference in its entirety.
1. Field of the Invention
The invention relates to manufacturing methods of an electricity storage device such as a capacitor and a battery.
2. Description of the Related Art
Japanese Patent Application Publication Nos. 2007-220696 (JP 2007-220696 A) and 2008-258222 (JP 2008-258222 A) and Japanese Patent No. 4441976 describe electricity storage devices such as a capacitor and a battery, which include an electricity storage member in which positive electrode foils and negative electrode foils are alternately stacked with separator foils interposed therebetween.
The electricity storage member described in JP 2007-220696 A is manufactured by placing folded separator foils between the positive electrode foils and the negative electrode foils, and moving the positive electrode foils and the negative electrode foils toward each other. The electricity storage member described in JP 2008-258222 A is manufactured by stacking a positive electrode material foil having a length equal to the sum of the lengths of a multiplicity of positive electrode foils, a negative electrode material foil having a length equal to the sum of the lengths of a multiplicity of negative electrode foils, and separator foils interposed between the positive and negative electrode material foils, and winding or zigzag-folding the stack. The electricity storage member described in Japanese Patent No. 4441976 is manufactured by stacking a positive electrode material foil having a length equal to the sum of the lengths of a multiplicity of positive electrode foils, a negative electrode material foil having a length equal to the sum of the lengths of a multiplicity of negative electrode foils, and separator foils interposed between the positive and negative electrode material foils, and zigzag-folding the stack.
The region where the positive electrode foil and the negative electrode foil overlap each other affects performance of the capacitor or the battery. If the positive electrode foil and the negative electrode foil are offset from each other, this overlapping region is reduced, and the size of the capacitor or the battery need be increased accordingly in order to ensure the electricity storage capacity. It is therefore desired to accurately position the positive electrode foils and the negative electrode foils in order to reduce the size while improving performance.
In the electricity storage member described in JP 2007-220696 A, it is not easy to accurately position the positive electrode foils and the negative electrode foils. In this electricity storage member, the positive electrode foils and the negative electrode foils can be positioned by using fold lines in the separator foils. However, this is not easy because of low rigidity of the separator foils.
The electricity storage member described in JP 2008-258222 A is formed by winding or zigzag-folding the stack of the positive electrode material foil, the negative electrode material foil, and the separator foil. Accordingly, the area of the region (non-deposited portion) that does not affect performance is increased as the number of turns is increased. The size of the electricity storage member is therefore increased as the number of turns is increased. In the electricity storage member described in Japanese Patent No. 4441976, it is not easy to fold the strip-shaped positive electrode material foil, the strip-shaped separator foil, and the strip-shaped negative electrode material foil at accurate folding positions. Accordingly, the size of this electricity storage member may be increased as the number of stacks is increased.
It is an object of the invention to provide a method for manufacturing an electricity storage device capable of achieving both improved performance and a reduced size.
A method for manufacturing an electricity storage device according to one aspect of the invention is a method for manufacturing an electricity storage device including an electricity storage member in which positive electrode foils and negative electrode foils are alternately stacked with separator foils interposed therebetween, including:
a positive electrode folding in which a positive electrode material foil having a length equal to a sum of lengths of two of the positive electrode foils is folded in a middle;
a negative electrode folding in which a negative electrode material foil having a length equal to a sum of lengths of two of the negative electrode foils is folded in a middle;
an initial arranging in which the positive electrode material foil and the negative electrode material foil are arranged with the separator foils interposed therebetween such that an opening of the folded positive electrode material foil faces an opening of the folded negative electrode material foil; and
a positioning in which the positive electrode material foil and the negative electrode material foil are positioned by relatively moving the folded positive electrode material foil and the folded negative electrode material foil closer to each other so as to insert one end of a second material foil among the positive and negative electrode material foils from the opening of a first material foil among the positive and negative electrode material foils toward a bottom of a valley of the first material foil, and in which the one end of the second material foil is restrained with the bottom of the valley of the first material foil.
As described above, the electricity storage member uses the positive electrode material foil having a length equal to the sum of the lengths of the two positive electrode foils and the negative electrode material foil having a length equal to the sum of the lengths of the two negative electrode foils. The positive electrode material foil and the negative electrode material foil are positioned as the one end of the folded second material foil is restrained by the bottom of the valley of the folded first material foil. Because the positive electrode material foil is more rigid than the separator foil, rigidity at the bottom of the valley of the first material foil is higher than that at the fold line of the separator foil. The positive electrode material foil and the negative electrode material foil are thus accurately positioned by the above positioning method. As a result, the electricity storage device manufactured as described above can achieve both improved performance and a reduced size.
The foregoing and further features and advantages of the invention will become apparent from the following description of example embodiments with reference to the accompanying drawings, wherein like numerals are used to represent like elements and wherein:
A first embodiment of the invention will be described below with reference to the accompanying drawings. First, the configuration of an electricity storage device will be described. The electricity storage device is a capacitor, a battery, etc. In the present embodiment, a lithium ion capacitor 1 will be described as an example of the electricity storage device. As shown in
The electricity storage member 10 includes a plurality of positive electrode foils 11a, 11b, a plurality of negative electrode foils 12a, 12b, a plurality of separator foils 13, positive external terminals 14a, 14b, and negative external terminals 15a, 15b. As shown in
The positive external terminals 14a, 14b are provided integrally with the ends (upper right ends in
As shown in
The positive electrode material foil 30 includes a positive current collector foil 31 and positive electrode active material layers 32, 33 provided on both surfaces of the positive current collector foil 31. Each of the positive electrode foils 11a, 11b therefore includes the positive current collector foil 31 and the positive electrode active material layers 32, 33 provided on both surfaces thereof. The positive current collector foil 31 is made of aluminum, an aluminum alloy, etc. The positive electrode active material layers 32, 33 are made of a carbon material capable of reversibly supporting anions and cations, a binder, a conducting agent, etc. Carbon black such as acetylene black or Ketjen black, natural graphite, thermal expansion graphite, carbon fibers, etc. is used as the conducting agent. A fluorine-containing resin such as polytetrafluoroethylene or polyvinylidene fluoride, a rubber binder such as styrene-butadiene rubber, a thermoplastic resin such as polypropylene or polyethylene, etc. is used as the binder.
As shown in
The negative electrode material foil 40 includes a negative current collector foil 31 and negative electrode active material layers 42, 43 provided on both surfaces of the negative current collector foil 41. Each of the negative electrode foils 12a, 12b therefore includes the negative current collector foil 41 and the negative electrode active material layers 42, 43 provided on both surfaces thereof. The negative current collector foil 41 is made of copper, a copper alloy, nickel, stainless steel, etc. The negative electrode active material layers 42, 43 are made of a carbon material such as graphite or amorphous carbon, a binder, a conducting agent, etc. The conducting agent and the binder are similar to those of the positive electrode active material layers 32, 33.
As shown in
A single continuous strip-shaped separator foil 13 is interposed between the positive electrode material foil 30 and the negative electrode material foil 40. Paper made of viscose rayon or native cellulose, nonwoven fabric made of polyethylene or polypropylene, etc. is used as the separator foil 13. The separator foil 13 need be made of an insulating material the electrolyte solution 22 easily penetrates.
As shown in
In the lithium ion capacitor 1 configured as described above, the plurality of positive electrode foils 11a, 11b and the plurality of negative electrode foils 12a, 12b are stacked with the separator foils 13 interposed therebetween. The larger the area where the active material layers 32, 33, 42, 43 of each electrode foil 11a, 11b, 12a, 12b face each other in the lithium ion capacitor 1 is, the higher the performance of the lithium ion capacitor 1 is. The size of the outer shape of the lithium ion capacitor 1 depends on the size of each electrode foil 11a, 11b, 12a, 12b and the magnitude of a positional offset of each electrode foil 11a, 11b, 12a, 12b. That is, the larger the positional offset of each electrode foil 11a, 11b, 12a, 12b is, the larger the size of the lithium ion capacitor 1 becomes. Lithium ion capacitors are desired to have both improved performance and a reduced size. The lithium ion capacitor 1 of the present embodiment achieves both improved performance and a reduced size by using the above configuration and a method for manufacturing the electricity storage member 10 described below.
A method for manufacturing the electricity storage member 10 will be described with reference to
The negative electrode material foil 40 having a length equal to the sum of the lengths of the two negative electrode foils 12a is prepared. This negative electrode material foil 40 is folded in the middle to form the folded negative electrode material foil 40 (negative electrode folding step). The negative electrode material foil 40 in this state is formed so that the distance between the two sides of the folded negative electrode material foil 40 increases toward the opening. A plurality of such folded negative electrode material foils 40 are prepared.
Then, the separator foil 13 is held by upper rollers 61, 61 and lower rollers 62, 62 and adjusted so as to be subjected to predetermined tension (separator foil placing step). In the present embodiment, the separator foil 13 is formed in a strip shape with no fold line.
As shown in
More specifically, as shown in
Then, as the holding device 70 is moved, the plurality of positive electrode material foils 30 are simultaneously brought into contact with the separator foil 13 and moved to a predetermined position shown in
Thereafter, as shown in
As shown in
Subsequently, as shown in
Advantageous effects of the present embodiment will be described below. As described above, the electricity storage member 10 uses the positive electrode material foils 30 each having a length equal to the sum of the lengths of two positive electrode foils 11a, and the negative electrode material foils 40 each having a length equal to the sum of the lengths of two negative electrode foils 12a. One end of the folded negative electrode material foil 40 is restrained by the bottom of the valley of the folded positive electrode material foil 30, whereby the positive electrode material foil 30 and the negative electrode material foil 40 are positioned. Because the positive electrode material foil 30 and the negative electrode material foil 40 are more rigid than the separator foil 13, rigidity at the bottoms of the folds of the positive electrode material foil 30 and the negative electrode material foil 40 is higher than that at the fold line of the separator foil 13. The positive electrode material foil 30 and the negative electrode material foil 40 are thus accurately positioned in a manner described above. The manufactured lithium ion capacitor 1 can thus achieve both improved performance and a reduced size.
Moreover, the positive electrode material foil 30 and the negative electrode material foil 40 are accurately positioned in each unit 50. The multi-layer electricity storage member 10 is formed by positioning and stacking the plurality of units 50. The lithium ion capacitor 1 capable of achieving both improved performance and a reduced size is manufactured. Moreover, the positive electrode material foil 30 includes the active material layers 32, 33 on both surfaces of the positive current collector foil 31, and the negative electrode material foil 40 includes the active material layers 42, 43 on both surfaces of the negative current collector foil 41. The electricity storage member 10 is manufactured by stacking the plurality of units 50 as follows. As shown in
In particular, the holding device 70 restricts relative movement of the plurality of positive electrode material foils 30. The plurality of positive electrode material foils 30 can therefore be accurately positioned with respect to each other. In this state, the positive and negative electrode material foils 30, 40 are moved toward each other, whereby the positive and negative electrode material foils 30, 40 are positioned so that each positive electrode material foil 30 overlaps a corresponding one of the negative electrode material foils 40. In each unit 50, the positive and negative electrode material foils 30, 40 are accurately positioned as one end of the negative electrode material foil 40 is restrained by the bottom of the valley of the positive electrode material foil 30 as described above. Moreover, because relative movement of the plurality of positive electrode material foils 30 is restricted, positioning accuracy of the plurality of units 50 depends on the initial positions of the plurality of positive electrode material foils 30 held by the holding device 70. That is, the plurality of units 50 can be accurately positioned. The electricity storage member 10 can therefore achieve both improved performance and a reduced size.
The separator foil 13 is formed in the shape of a single strip. In the initial arranging step, the separator foil 13 is interposed between the plurality of positive electrode material foils 30 and the plurality of negative electrode material foils 40. Because the separator foil 13 need not be cut into pieces, manufacturing can be facilitated.
In particular, in the present embodiment, the separator foil 13 is formed in a strip shape with no fold line, and the separator foil 13 is folded as the folded positive electrode material foil 30 and the folded negative electrode material foil 40 are relatively moved toward each other in the positioning step. Because no fold line need be formed in advance in the separator foil 14, manufacturing cost can be reduced. In this case, the separator foil 13 is folded by the positive electrode material foil 30 and the negative electrode material foil 40.
A second embodiment of the invention will be described below. As shown in
A third embodiment of the invention will be described below. In the first embodiment, the positive electrode material foil 30 has the active material layers 32, 33 on both surfaces of the current collector foil 31, and the negative electrode material foil 40 has the active material layers 42, 43 on both surfaces of the current collector foil 41. Alternatively, positive and negative electrode material foils 130, 140 having an active material layer 32, 42 only on one surface of the current collector foil 31, 41 can be used, respectively. A method for manufacturing the electricity storage member 10 in this case will be described with reference to
In the initial arranging step, as shown in
Then, as shown in
Number | Date | Country | Kind |
---|---|---|---|
2014-000082 | Jan 2014 | JP | national |