The present invention relates to an apparatus and a method of manufacturing a fiber reinforced article, and more particularly to a fiber reinforced article having a tailored multidirectional fiber orientation.
Composite materials, also referred to as composites, are a combination of two or more materials that are mixed or joined on a macroscopic level. They are used in engineering applications where a pure material cannot provide the specific set of properties that are required. They can be thought of as a single material that has been enhanced by the addition of another material.
Fibers are added as a means of reinforcement and provide strength, stiffness, or any other desired property to the composite. One of the problems associated with the above arrangement is how to preserve the desired multidirectional fiber orientation of a complex-shaped article during the manufacturing phase.
An object of the present invention is thus to provide a method to solve the above problems related to manufacturing the articles with desired fiber orientations. The desired fiber orientation may be just a simple uniaxial orientation or complex multilayer multidirectional orientation depending on the end product requirements. The objects of the invention are achieved by a method and an apparatus which are characterized by what is stated in the independent claims. The preferred embodiments of the invention are disclosed in the dependent claims.
The invention is based on the idea of using radial molding and forming a fiber reinforced article, which comprises a tailored fiber orientation, from the mold cavity, wherein the continuous reinforcing fibers follow to a surface design of said article.
In the following the invention will be described in greater detail by means of preferred embodiments with reference to the attached drawings, in which
This invention is focused on fiber reinforced thermoplastic polymer composites, which can be especially used in medical devices such as bone screws and fasteners. Said medical devices are usually made of stainless steel or titanium alloys. However, these materials tend to have certain challenges, such as mechanical mismatch with mechanical properties of bone tissue which may cause further challenges such as stress shielding. Metallic implant may also cause disturbance in imaging such as in MRI. This has led engineers to search for alternative materials which can meet the desired effects and properties.
One of the alternatives is the fiber reinforced polymer composite. This type of composites is composed of a combination of reinforcing fibers, and a thermoplastic polymer matrix material, that surrounds the fibers. Fibers add strength and stiffness to an otherwise viscoelastic polymer that, without reinforcement, lacks the mechanical properties needed in certain applications. Fibers and matrix work together in synergy providing a composite material with characteristic properties benefiting from the contribution of both elements.
Fibers are added as a means of reinforcement and provide strength, stiffness, or any other desired property to the composite. The matrix bonds the fibers together, protects the fibers from damage, and distributes the load from one fiber to another. The properties of the composite are determined by the properties of the fibers, their length, diameter, orientation, and amount, as well as the properties of the matrix, and the bonding between the matrix and the fibers. When using reinforcing fibers, the fibers can be chopped and/or continuous.
When the continuous fibers are aligned, they provide maximum strength along the direction of alignment. The composite can be considerably weaker along other directions and can therefore be highly anisotropic. This anisotropy can be overcome by fibers aligned in desired directions, i.e. fiber orientations.
One of the problems associated with the above arrangement is how to preserve the desired fiber orientation of a complex-shaped article during the manufacturing phase. On laminated planar structures this can be easily overcome by aligning fibers on desired fiber orientations on distinct layers or by selecting pre-manufactured sheets with desired fiber orientations. If the fiber reinforced article being manufactured is a simple rotationally symmetrical object the desired fiber orientation can be achieved by means of filament winding. On more complex shapes the desired fiber orientation may be manufactured by means of automatic composite manufacturing techniques, such as automatic tape placement and/or automatic fiber placement. If, however, the complex fiber orientation is to be manufactured on small size products which need to be mass produced on large quantity on industrial scale, the preferable manufacturing techniques include compression molding and injection molding.
During the conventional compression moulding, the fiber orientation of a preform changes or it is considerably challenging to preserve on certain geometry articles. Preserving the desired fibre orientation on planar structures is somewhat straightforward, but more complex geometries are not that easy to reproduce with predictable fibre orientation. For example, when compression molding a rotationally symmetrical solid object, the shape transformation of a preform is not uniform along the surfaces of the object when compressing the preform to mold defining the final shape of the article. Thus, the initial fiber orientation of preform distort, shuffle and/or disarrange at different amounts on different sections due to non-uniform shape transformation.
On injection molding the desired fiber orientation of the article being manufactured can be achieved by using an insert containing the fibers having desired fiber orientation. The insert is placed inside the mold defining the final shape of the article before injecting the matrix polymer which fills the mold. The largest outer dimensions of the insert need to be smaller than the smallest outer dimensions of the mold, because otherwise the fiber insert would squeeze on between the mold parts when the mold closes making the injection molding impossible.
The present invention relates to a continuous fiber reinforced structure forming method, which utilizes radial molding. Continuous fiber reinforced structure obtained by this method for certain product geometries can comprise a layer structure with defined fiber orientation on each layer which can be tailored having desired properties. Using conventional methods such as compression molding, such layer structure and/or fiber orientation tends to shuffle and disarrange during the molding, which causes the desired properties of the finished product to weaken and on some occasion, even render it useless. Using radial molding, the construction/structure of desired fiber orientation of final product can be tailored/predicted as the shape transformation during the mold closing is uniform radially surrounding the longest dimension of the preform. Ideally the fiber orientation structure can even remain unchanged in the finished product, which maximizes benefits of the desired properties. Such properties can be, for example, toughness, stiffness, or any other desired mechanical property.
The thermoplastic materials are materials which shape can be transformed when heating them to certain material specific temperatures (e.g. glass transition temperature, melting temperature, etc.). Certain material properties, such as degree of crystallinity, strength properties, etc., of thermoplastic polymers may also be altered as a function of temperature and time. When thermoplastics are heated to certain temperature (glass transition temperature Tg), they soften, and their shape can be transformed. Semi-crystalline and crystalline thermoplastic polymers melt when they are heated to their melting point (Tm) or above melting point. Amorphous thermoplastic polymers do not have a melting point. Usually thermoplastic polymers are molded on temperatures above the Tg or above the Tm. They solidify to a glassy state when cooled below their glass transition temperature. There are many different types of fibers that can be used to reinforce polymer matrix composites. The most common are carbon fibers (AS4, IM7, etc.) and fiberglass (S-glass, E-glass, etc.). Fibre preforms are often manufactured in sheets, continuous mats, tubular structures or as continuous filaments or continuous filaments/tapes impregnated using matrix polymer.
The second step 102 comprises loading the preform inside a radial molding apparatus, either manually or automatically by a machine. Said radial molding apparatus comprises at least three adjacent die segments next to each other forming a mold cavity having an initial volume in an initial position and a final volume in a compressed position, which is smaller than the initial volume. The final volume of the mold cavity also defines a final volume and shape of the finished fiber reinforced article.
Each die segment can be identical, such as wedge-shaped with planar surfaces, which are arranged to form an approximately cylindrical central cavity. However, other shapes can also be formed depending on the design of the cavity surface. The wedges can be hinged and driven in unison to change the diameter, and consequently the volume, of the cavity. The die segment can have any design comprising two adjacent sides forming a 120° or less angle.
The third step 103 comprises molding the preform by moving said die segments. Each die segment is in direct contact with each other during end positions and movement of the mold, such as opening and closing as well as during the initial and compressed position. During this step, the compression applies similar or identical radial force and deformation towards the longitudinal axis of the preform.
Radial molding is a technique where the molded article is formed by a moldable continuous fiber reinforced preform material from the initial volume to the final volume along a plurality of radial directions. These radial directions are substantially perpendicular to a common longitudinal axis and arranged to lie in different planes. In this context the common longitudinal axis refers to the axis along which preform is loaded and perpendicular to the compression.
The said movable radial die segments are movable concurrently between the initial position and the final compression position which respectively define said initial volume and said final volume. The volume of the mold cavity in the compressed position can be smaller than or equal to the volume of the preform. Additionally, the volume of the preform can be smaller than the volume of the mold cavity in the initial position, and transverse dimension of the preform in the initial position can be larger than the transverse dimension of finished article in the compressed position. The transverse dimension of the preform in the initial position can also be smaller than or equal to the transverse dimension of the finished article in the compressed position, wherein the preform is additionally compressed from an end along the common longitudinal axis of the preform.
Linear or curved path actuators can be used to move said die segments between their initial and compressed positions. The said radial die segments can move along either linear or curved paths during which the interface surfaces on between the adjacent radial die segments can be then either linear or curved.
The radial mold comprised of at least three mold die segments described in this invention may also be used as a mold for injection molding. In injection molding the mold which opens radially, as described in this invention, enables to use continuous fiber inserts which have even larger initial diameter than the molded final product. With conventional mold there are always gaps on between the mold parts, also known as dies, when the mold opens and thus the use of such larger diameter inserts would be impossible, as the insert would get squeezed between the mold parts when the mold closes. If the mold opens and closes radially as explained in this invention such squeezing will not happen. This enables to use such continuous fiber reinforced inserts in overmolding injection molding which are impossible to use when using any other type of molds in injection molding.
The fourth step 104 comprises opening the mold cavity, by returning the die segments to the initial position, wherein each die segment is in direct contact with adjacent die segments during the movement. Both compression and release movements can be actuated by actuators to forcedly move said die segments between their initial and compressed positions. Said actuator can be hydraulic power cylinder, for instance, attached to the die segments. Operation of the die segments can be controlled by a valve. The power cylinders can be simultaneously connected to compress and, after compression, to reverse flow through the valve.
The fifth step 105 comprises removing the obtained fiber reinforced article from the mold cavity, either manually or automatically by a machine. The finished article comprises a tailored orientation and layer structure, wherein the continuous reinforced fibers follow or conform to a surface contour of said article. The initial fiber orientation structure can even remain unchanged in the finished article, which maximizes benefits of the desired properties. The obtained article comprises desired properties such as better toughness, as well as compression, torsion, impact resistance, or any other desired property.
In another embodiment, the method further comprises a heating step, wherein the preform is heated to above the glass transition temperature or melting temperature of matrix polymer. Heating the preform facilitates formability of the preform. Said heating step can be arranged inside the radial molding apparatus before the molding step or before loading the preform inside the radial molding apparatus. In some embodiments, the die segments can be heated using heating elements placed inside the desired locations in the compression die body and transfer the heat to the preform located in mold cavity. The preform is then cooled down inside the mold cavity by conduction or the finished article is cooled down after the molding step by any suitable cooling means such as air cooling.
In yet another embodiment, before or after or during the molding step, the method further comprises sliding at least one piston inside the mold cavity along the common longitudinal axis of the preform to further facilitate the compression of the preform by sealing the mold cavity from at least one end. In this context, the piston refers to any rod or stick or similar arranged to fit and move inside the molding apparatus. For example, one piston on each longitudinal end of the mold cavity can be provided, and during molding step, said pistons slide towards the preform and thus further compresses the preform from both ends. With the combination of the mold segments and the pistons all sides of the product can be formed. Preferably the pistons slide towards the preform after the die segments are moved to final compression position. A separate actuator may move the piston or both pistons. The piston may comprise a feature penetrating the whole mold cavity from one piston to another piston. Such embodiment is beneficial particularly when molding parts which have hollow opening trough the longest dimension of part. An example of such part is a cannulated screw.
A distal end of the piston may comprise a mold with an inverse design which is reproduced at an end portion of the obtained fiber reinforced article. The mold can be made of plastic such as polyetheretherketone (PEEK), which has excellent mechanical and chemical resistance properties that are maintained at high temperatures. The distal end in this context refers to the end contacting the preform. The design can be for instance a screw head and/or screw tip. On another embodiment the piston can include a separate part which is used as an insert and which is joined to the part being manufactured during the radial molding phase. Such insert is temporarily attached to piston prior to compression molding phase and it is permanently attached to the part being radial molded during the molding phase. Such insert may be composed of same material as part being manufactured or it may be composed of different material such as a metal, ceramic, etc. Such insert may comprise the whole tip of the part being manufactured. Such tip can be for instance threaded and used in applications where a mixture of two or more materials is more advantageous.
In yet another embodiment, the preform is provided in a continuous manner by loading and compressing the preform, returning the die segments and removing the obtained fiber reinforced article in such way that the preform is moved equally or less than the length of the mold cavity in the direction of the common longitudinal axis without separating the preform and the obtained fiber reinforced article from each other. The loading can be performed automatically or manually. When automated the actuator may move the preform to mold cavity on continuous manner explained below:
Continuous process:
The outcome is a continuous radially molded article having desired fiber orientation and shape.
In yet another embodiment, before the molding step, the method further comprises sliding at least one piston with specifically designed mold sealing feature at the distal end of the piston along the common longitudinal axis of the preform to further facilitate mold sealing. The sealing feature stops at the edge of the mold cavity. In this context, the piston includes a geometrical feature which seals the mold at the stage where mold cavity is “open” (
In a yet another embodiment, the piston 4, 5 may further comprise a sealing feature 7 at the interface of the mold cavity 3 along the common longitudinal axis A of the preform 1 to further facilitate mold sealing. The term “interface of the mold cavity 3” in this context refers to the border where the mold cavity 3 is defined by the final volume. The sealing feature 7 is shaped to seal the interface of at proximal and/or distal end of the mold cavity 3 when the die segments 2 are still at the initial position and arranged to focus and lock against rotation of the die segments 2 at the compressed position. The sealed interface at the end of the mold cavity 3 thus prevents leakage of moldable preform 1 to these directions and thus the sealed interfaces improve pressure regulation during the molding phase. When the sealing feature 7 is utilized, the diameter of the pistons 4, 5 may be smaller than the diameter of the mold cavity 3 in the compressed stage. The sealing feature 7 may be manufactured of any suitable sealant material such as rubber, metal or plastics such as PEEK. The sealing feature 7 may also be composed of same material as the rest of the pistons. The sealing feature 7 may also be a geometrical feature of the piston 4, 5, which is integrated or seamlessly joined to the piston 4, 5 and which is composed of any suitable material.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2020/083887 | 11/30/2020 | WO |